WO2020218170A1 - 鉄鉱石ペレットの製造方法 - Google Patents
鉄鉱石ペレットの製造方法 Download PDFInfo
- Publication number
- WO2020218170A1 WO2020218170A1 PCT/JP2020/016785 JP2020016785W WO2020218170A1 WO 2020218170 A1 WO2020218170 A1 WO 2020218170A1 JP 2020016785 W JP2020016785 W JP 2020016785W WO 2020218170 A1 WO2020218170 A1 WO 2020218170A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- pellets
- organic binder
- raw material
- raw
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
- C22B1/242—Binding; Briquetting ; Granulating with binders
- C22B1/244—Binding; Briquetting ; Granulating with binders organic
Definitions
- the present invention relates to a method for producing iron ore pellets.
- Iron ore pellets are made from iron ore fine powder of several tens of ⁇ m with improved quality to properties suitable for blast furnaces (for example, size, strength, reducibility, etc.).
- the iron ore pellets are produced by three consecutive steps in this order: a granulation step, a firing step, and a cooling step.
- an iron ore raw material whose water content and particle size are adjusted is put into a granulator (for example, a pan pelletizer) and rolled to granulate raw pellets having a diameter of more than 10 mm and in the form of mud dumplings. To do.
- a granulator for example, a pan pelletizer
- the raw pellets immediately after granulation are placed on a metal pallet to prepare a packed layer, and the raw pellets are dried by transporting the raw pellets and allowing hot air to pass through the packed layer.
- the raw pellets are preheated and fired until they have a strength that does not pulverize when firing while rolling.
- the pellets preheated and fired are baked and hardened at about 1200 ° C.
- the pellets baked in the firing step are placed on a metal pallet and cooled by allowing cold air to pass through to produce iron ore pellets.
- Patent Document 1 describes a method of producing pellets having stable operation and stable quality while using existing Great Kiln equipment using high water of crystallization ore. Specifically, in the preheating firing, the preheating chamber temperature and / and the preheating time are increased by a predetermined amount according to the strength of the preheat pellets to be reduced by containing water of crystallization.
- Patent Document 2 describes a method for producing pellets, which prevents bursting and improves the yield and productivity of calcined pellets. Specifically, a predetermined amount of organic fibers, clayey substances, and organic adhesives are dissolved in water to form a slurry, which is added to a mixed raw material for pellets, mixed, granulated, and fired by a conventional method.
- Patent Document 3 describes a pretreatment method effective for increasing the layer thickness of the sinter raw material bed and achieving an improvement in sinter production while using a large amount of malamamba iron ore as the sinter compounding raw material. ing. Specifically, both water and a binder are added to a sintered raw material containing Malamamba iron ore for granulation, and the obtained granulated sintered raw material is dried by heating and drying at the same time as or after granulation. Pretreatment is performed as a raw material for grain sintering.
- Patent Document 4 describes a method for granulating a sintering raw material that produces uniform pseudo-particles and improves pseudo-granulation. Specifically, when water is added to the sintered compound raw material for granulation, an additive for granulation that lowers the surface tension of water is added to form uniform pseudo-particles, and the viscosity of water is further increased. Pseudo-granulation property is improved by adding an additive for granulation to be increased.
- the pellets are pulverized, and the pellet powder blocks the pellet filling layer and deteriorates the air permeability.
- the air permeability deteriorates, the amount of air passing through the pellet packing layer decreases, drying is delayed, and the productivity of iron ore pellets decreases. Therefore, in order to improve the productivity of iron ore pellets, it is required to suppress the occurrence of bursting.
- Patent Documents 1 to 3 do not describe or suggest specific production conditions for raw pellets for suppressing bursting. Further, also in Patent Document 4, no description or suggestion is made regarding specific conditions for use of the water of crystallization-containing ore and the binder.
- the present invention can produce raw pellets that suppress the occurrence of bursting when a raw material containing iron ore and an auxiliary raw material is charged into a granulator, and the productivity of iron ore pellets can be produced. It is an object of the present invention to provide a method for producing iron ore pellets which can improve.
- the method for producing iron ore pellets comprises a step of putting a raw material containing iron ore and an auxiliary raw material and an organic binder into a granulator and rolling them to granulate raw pellets.
- the blending amount of the organic binder when the raw material and the organic binder are put into the granulator satisfies the following formula 1.
- X [mPa ⁇ s] is the viscosity of the aqueous solution developed when the organic binder in the raw pellet is dissolved in water.
- Y [mass%] is a blending ratio of the water of crystallization ore having a water of crystallization content of 5% by mass or more in the raw material, and is an amount represented by the following formula 2. Whether or not the water of crystallization-containing ore "has a water of crystallization content of 5% by mass or more" shall be judged from the average content of water of crystallization for each brand of the iron ore. When the brand is applicable, "the mass of iron ore having a water of crystallization content of 5% by mass or more" is the total.
- the amount of an organic binder charged is adjusted so as to satisfy the above formula 1 to suppress the occurrence of bursting.
- Raw pellets can be produced, and the productivity of iron ore pellets can be improved.
- FIG. 1 is a diagram schematically showing an outline of a vertical electric furnace.
- FIG. 2 is a graph showing the relationship between the mixing ratio Y of the water of crystallization-containing ore having a water of crystallization content of 5% by mass or more and the bursting rate.
- FIG. 3 is a graph showing the relationship between the blending ratio of the organic binder and the bursting ratio.
- FIG. 4 is a diagram schematically showing an outline of a process of drying raw pellets immediately after granulation.
- FIG. 5 is a graph showing the relationship between the viscosity X of the aqueous solution in the raw pellet and the mixing ratio Y of the water of crystallization-containing ore having a water of crystallization content of 5% by mass or more.
- pellets granulated by rolling of a granulator such as a bread pelletizer, that is, pellets immediately after granulation are also referred to as "raw pellets”.
- the dried raw pellets are also called “dried pellets”
- the baked and hardened dried pellets are also called "iron ore pellets”.
- Iron ore pellets are made from iron ore fine powder of several tens of ⁇ m with improved quality to properties suitable for blast furnaces (for example, size, strength, reducibility, etc.).
- the iron ore pellets are produced by three consecutive steps in this order: a granulation step, a firing step, and a cooling step.
- an iron ore raw material whose moisture and particle size are adjusted is put into a granulator (for example, a pan pelletizer) and rolled to produce a mud dumpling-shaped raw pellet having a diameter of a dozen mm.
- a granulator for example, a pan pelletizer
- the raw pellets immediately after granulation are placed on a metal pallet to prepare a packed layer, and the raw pellets are dried by conveying this and allowing hot air to pass through the packed layer.
- the raw pellets are preheated and fired until they have a strength that does not pulverize when firing while rolling. Further, in a kiln furnace, the pellets preheated and fired are baked and hardened at about 1200 ° C.
- the pellets baked in the firing step are placed on a metal pallet and cooled by allowing cold air to pass through to produce iron ore pellets.
- Crystal water is contained in iron ore, which is a natural product.
- Water of crystallization is water contained in iron ore in combination with water of crystallization, and exists as FeO ⁇ OH.
- the water of crystallization content in the iron ore can be measured by a method such as JIS-M8211: 1995 (iron ore-combined water quantification method).
- the amount of water of crystallization in iron ore varies depending on the place of origin and brand. For example, according to "Japan Steel Association, Steel Property Value Handbook, Ironmaking, p.40", the water of crystallization content in the high-grade ore Carajás ore produced in Hakusan is as low as 3% by mass or less, but it is a poor quality ore. A certain Australian lobe river ore has a high water of crystallization content of 5% by mass or more.
- This water of crystallization is known to induce bursting. That is, if iron ore having a high water of crystallization content is used, the production of iron ore pellets may be hindered.
- "The Iron and Steel Institute of Japan, Steel Handbook (5th Edition) p.72" states that "it is necessary to pay attention to the content of water of crystallization that causes bursting.”
- the iron ore containing water of crystallization used in the present invention includes a water of crystallization-containing ore having a water of crystallization content of at least 5% by mass or more.
- water of crystallization-containing ore includes a water of crystallization-containing ore having a water of crystallization content of at least 5% by mass or more.
- inferior raw materials are specified. That is, the iron ore used in the present invention contains inferior raw materials.
- the upper limit of the water of crystallization content is not particularly limited, but is 10.13% by mass as the theoretical maximum value (theoretical limit value).
- FeO ⁇ OH 1 / 2Fe 2 O 3 -1 / 2H 2 O Therefore, 1/2 molecule of water can be fixed per Fe atom.
- Y indicates the mixing ratio of iron ore having a water of crystallization content of 5% by mass or more, and can be specified by the following formula 2.
- the auxiliary raw materials include generated products and the like. The mass of the auxiliary raw material is based on the dry weight of the adhering water dried.
- the raw pellets produced by increasing the mixing ratio Y of the water of crystallization-containing ore will increase the bursting rate.
- a granulation experiment and an evaluation test of the bursting rate were conducted.
- Table 1 shows the components of the raw materials used in this experiment.
- Table 2 shows the raw material composition No. of this experiment. 1 to No. The raw material compounding condition of 3 is shown.
- Table 3 shows the raw material formulation numbers for this experiment. 4-No. The raw material compounding conditions of 9 are shown.
- Table 4 shows the raw material composition No. of this experiment. 10-No. The raw material compounding conditions of 13 are shown.
- each raw material composition includes ore D (high-grade ore having a water of crystallization content of less than 5% by mass) and ore E (water of crystallization content of 5% by mass or more).
- the mixing ratio Y of the water of crystallization-containing ore was adjusted by distributing the mixing ratio of.
- the ores A to C are iron ores having a water of crystallization content of less than 5% by mass.
- auxiliary raw material A is dolomite
- auxiliary raw material B is limestone
- auxiliary raw material C is silica stone.
- the water content was 7% by mass or more and 10% by mass or less.
- the granulation test was carried out using a dish-type granulator (pan pelletizer). Table 5 shows the experimental conditions of the granulation test.
- FIG. 1 schematically shows an outline of the vertical electric furnace 1.
- the raw pellets produced in the granulation test (immediately after granulation) were sized so as to have a diameter of 11.2 mm or more and 13.2 mm or less, and as shown in FIG. was installed in the Amikago 2 and charged into the electric furnace 1 at a constant speed using the elevating device 3 and rapidly heated to generate bursting (steam burst phenomenon).
- the material of Amikago 2 is SUS304, and it has a cylindrical shape with a diameter of 55 mm.
- the moving speed of Amikago 2 at the time of insertion was set to 34 mm / min.
- the inner diameter of the core tube is 70 mm and the length is 1000 mm
- the average tropical temperature in the furnace is 1000 ° C.
- the average tropical width is 60 mm.
- the temperature inside the electric furnace 1 was controlled as shown in the graph shown in FIG.
- Table 6 shows the raw material formulation No. 1 to No. The number of pellets having a diameter of 11.2 mm or more and 13.2 mm or less before and after this experiment of No. 3 is shown.
- the bursting rate was determined by using the following formula 3 as the number ratio of pellets having a diameter of 11.2 mm or more and 13.2 mm or less on the Amikago 2 after the test.
- FIG. 2 shows the relationship between the mixing ratio Y of the water of crystallization-containing ore having a water of crystallization content of 5% by mass or more and the bursting rate.
- bursting is a phenomenon that occurs when water vapor generated inside the raw pellet during drying causes a pressure loss when passing through the pores in the raw pellet, that is, by increasing the internal pressure of the raw pellet. is there. Therefore, in order to suppress the occurrence of bursting, it is considered effective to increase the porosity in the raw pellets and reduce the water vapor emission load.
- the porosity in the raw pellets the pore size distribution of the dried raw pellets (hereinafter, also referred to as "dried pellets") was measured.
- An automatic porosimeter manufactured by Shimadzu Corporation: Autopore III 9400 was used to measure the pore size distribution.
- the method for measuring the pore size distribution was based on JIS-R1655: 2003 (a method for testing the pore size distribution of a molded body by a mercury press-fitting method for fine ceramics).
- the present inventors in order to suppress the occurrence of bursting while increasing the blending ratio Y of the water of crystallization-containing ore having a water of crystallization content of 5% by mass or more, the dry pellets are +0. It was considered important to increase the 2 ⁇ m open porosity. Therefore, as a result of intensive research, the present inventors have added an organic binder to the raw material containing iron ore and an auxiliary material for the +0.2 ⁇ m open porosity of the dry pellet, which is important for suppressing the occurrence of bursting. , Found to be controllable. That is, it was found that there is an appropriate range of conditions capable of suppressing the occurrence of bursting according to the above-mentioned compounding ratio Y. The details will be described below.
- organic binder applicable to the present invention examples include natural substances such as starch and chemical synthesis systems such as CMC (Carboxymethyl Cellulose).
- CMC Carboxymethyl Cellulose
- organic binder A is a mixture of cornstarch in an amount of 60% by mass, tapioca in an amount of 30% by mass, and potatoes in an amount of 10% by mass, and bentonite added in an external number of 10% by mass.
- the raw material of the organic binder B is 100% by mass of cornstarch, to which 20% by mass of bentonite is added.
- the raw material of the organic binder C is a mixture of 80% by mass of starch and 20% by mass of bentonite.
- a binder obtained by drying these raw materials, pregelatinizing them, and pulverizing them to about 200 ⁇ m is called an organic binder.
- the organic binders A, B, and C used in the present invention are examples.
- the viscosity of the aqueous solution was increased by dissolving the organic binder A, the organic binder B or the organic binder C in water.
- a viscometer manufactured by Toki Sangyo Co., Ltd .: TVB15 type viscometer
- the method for measuring the viscosity of the aqueous solution was based on JIS-Z8803: 2011. Table 7 shows the results of measuring the viscosities of the aqueous solutions dissolved in water for the organic binder A, the organic binder B and the organic binder C.
- the viscosity of the aqueous solution can be adjusted by the organic binder.
- the viscosity X of the aqueous solution in the raw pellet produced by blending the organic binders A, B, and C was determined by the following formula 4 using the result of the above-mentioned viscosity test (measured value of the viscosity of the aqueous solution).
- the unit of the viscosity X of the aqueous solution in the raw pellet is mPa ⁇ s.
- the molecule is equal to the blending ratio (1.0% by mass) of the organic binder in the viscosity test, and the following formula 5 is established.
- the blending ratio of organic binders A, B, and C is calculated as an outside number of raw material blends.
- the viscosity of the aqueous solution in the raw pellets when the organic binder was not blended was 1.0 mPa ⁇ s.
- the organic binder A was blended with the raw material (including iron ore and auxiliary raw material) which is the source of the raw pellet, and the raw pellet was produced by a granulation test.
- water was added to the raw material and an organic binder was added (added) to the raw material containing the water before charging the pelletizer.
- FIG. 3 shows the relationship between the blending ratio of the organic binder and the bursting ratio.
- the present inventors have stated that when an organic binder is blended, the occurrence of bursting can be suppressed even when a water of crystallization-containing ore having a water of crystallization content of 5% by mass or more is used. Found.
- the +0.2 ⁇ m open porosity of the dried pellets was high. It was confirmed that the occurrence of bursting could be suppressed by this increase in the +0.2 ⁇ m open porosity.
- the bursting rate can be suppressed below the standard value by setting the +0.2 ⁇ m open porosity of the dried pellets to 14% or more.
- the pores of the pellet are formed in the region where water and fine ore (fine particles) are present in the raw pellet immediately after granulation.
- the water evaporates and the fine ore moves to the contact points between the coarse ores and aggregates, thereby forming pores. That is, it is considered that the water content in the raw pellets and the fine ore greatly act on the formation of the pores.
- the organic binder in the raw pellets increases the viscosity of the aqueous solution, and is thought to promote the movement of fine ore during drying.
- an appropriate mixing ratio of the organic binder according to the mixing ratio Y of the water of crystallization-containing ore having a water of crystallization content of 5% by mass or more was determined by a granulation test and a bursting test.
- FIG. 5 shows a summary of the above experimental results, that is, the relationship between the viscosity X [mPa ⁇ s] of the aqueous solution in the raw pellet and the mixing ratio Y [mass%] of the water of crystallization-containing ore.
- the bursting rate of raw pellets granulated under the condition that the water of crystallization-containing ore having a water of crystallization content of 5% by mass or more and an organic binder is not blended is set as a reference value (marked with ⁇ in FIG. 5), and the reference value is used.
- the bursting rate was higher than the value, it was worsened (x mark in FIG. 5), and when the bursting rate was lower than the reference value, it was improved ( ⁇ mark in FIG. 5). From this experimental result, the condition range in which the occurrence of bursting can be suppressed to the reference value or less while increasing the mixing ratio Y of the water of crystallization-containing ore having a water of crystallization content of 5% by mass or more was determined. The following equation 1 was obtained.
- Table 8 shows examples and comparative examples carried out according to the method for producing iron ore pellets of the present invention.
- Example 1 (raw material compounding No. 1) is a reference value for evaluating the effect of the present invention.
- Examples 5, 7, 8, 11, 12 (raw material compounding Nos. 5, 7, 8, 11, 12) satisfy the above formula 1 (“A” is added to “appropriateness” in Table 8) and compared.
- Examples 2, 3, 4, 6, 9, 10 and 13 (raw material compounding No. 2, 3, 4, 6, 9, 10, 13) do not satisfy the above formula 1 (see “Appropriateness” in Table 8). (Attached with “B”).
- the "evaluation” of the bursting rate the one having a bursting rate lower than that of Example 1 as a reference was "A", and the one having a bursting rate of Example 1 or higher was “B". The lower the bursting rate, the better.
- Raw material formulations 1 to 3 do not contain organic binders.
- the raw material formulations 4 to 9 contain an organic binder A
- the raw material formulations 10 and 11 contain an organic binder B
- the raw material formulations 12 and 13 contain an organic binder C, respectively.
- organic binders such as natural substances such as starch and chemical synthesis systems such as CMC, so the effect of improving the viscosity of the aqueous solution differs depending on the properties and compounding ratio.
- the crystal water-containing ore is used by adjusting the blending amount of the organic binder so as to satisfy the above formula 1. It can be seen that the occurrence of bursting can be suppressed and the productivity of the raw pellets, which are the source of the iron ore pellets, can be maintained and improved.
- raw pellets are granulated by charging and rolling a raw material containing iron ore and an auxiliary raw material and an organic binder into a granulator. It is characterized in that, in the granulation step, the blending amount of the organic binder when the raw material and the organic binder are put into the granulator satisfies the following formula 1.
- X [mPa ⁇ s] is the viscosity of the aqueous solution developed when the organic binder in the raw pellet is dissolved in water.
- Y [mass%] is a blending ratio of the water of crystallization ore having a water of crystallization content of 5% by mass or more in the raw material, and is an amount represented by the following formula 2.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
FeO・OH=1/2Fe2O3-1/2H2O
であるので、Fe1原子当たり1/2分子の水が固着可能である。この場合、このFeO・OH1分子当たりの結晶水含有量は、62.86/55.85×1/2×(2+16)=10.13質量%となる。全てのFe原子が結晶水を含有している場合に結晶水含有量が最大となるから、結晶水含有量の理論上の最大値は、10.13質量%となる。
2 アミカゴ
3 昇降装置
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR112021018309-4A BR112021018309B1 (pt) | 2019-04-23 | 2020-04-16 | Método para produzir pelotas de minérios de ferro |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2019081932 | 2019-04-23 | ||
JP2019-081932 | 2019-04-23 | ||
JP2020072579A JP7366832B2 (ja) | 2019-04-23 | 2020-04-14 | 鉄鉱石ペレットの製造方法 |
JP2020-072579 | 2020-04-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2020218170A1 true WO2020218170A1 (ja) | 2020-10-29 |
Family
ID=72942603
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2020/016785 WO2020218170A1 (ja) | 2019-04-23 | 2020-04-16 | 鉄鉱石ペレットの製造方法 |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2020218170A1 (ja) |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0310026A (ja) * | 1989-06-07 | 1991-01-17 | Nippon Yakin Kogyo Co Ltd | 粘土質Ni鉱石の団鉱方法 |
JP2007077484A (ja) * | 2005-09-16 | 2007-03-29 | Kobe Steel Ltd | 炭材内装塊成化物の製造方法 |
JP2007138244A (ja) * | 2005-11-17 | 2007-06-07 | Nippon Steel Corp | 焼結鉱の製造方法 |
JP2008189994A (ja) * | 2007-02-05 | 2008-08-21 | Jfe Steel Kk | 造粒焼結原料の製造方法 |
JP2008261016A (ja) * | 2007-04-12 | 2008-10-30 | Nippon Steel Corp | 焼結鉱の製造方法 |
JP2010138445A (ja) * | 2008-12-11 | 2010-06-24 | Jfe Steel Corp | 造粒焼結原料の予備処理方法 |
JP2010236081A (ja) * | 2009-03-12 | 2010-10-21 | Kobe Steel Ltd | 炭材内装塊成化物の製造方法 |
JP2013082972A (ja) * | 2011-10-11 | 2013-05-09 | Nippon Steel & Sumitomo Metal Corp | 非焼成含炭塊成鉱の製造方法 |
WO2017150428A1 (ja) * | 2016-03-04 | 2017-09-08 | Jfeスチール株式会社 | 焼結鉱の製造方法 |
-
2020
- 2020-04-16 WO PCT/JP2020/016785 patent/WO2020218170A1/ja active Application Filing
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0310026A (ja) * | 1989-06-07 | 1991-01-17 | Nippon Yakin Kogyo Co Ltd | 粘土質Ni鉱石の団鉱方法 |
JP2007077484A (ja) * | 2005-09-16 | 2007-03-29 | Kobe Steel Ltd | 炭材内装塊成化物の製造方法 |
JP2007138244A (ja) * | 2005-11-17 | 2007-06-07 | Nippon Steel Corp | 焼結鉱の製造方法 |
JP2008189994A (ja) * | 2007-02-05 | 2008-08-21 | Jfe Steel Kk | 造粒焼結原料の製造方法 |
JP2008261016A (ja) * | 2007-04-12 | 2008-10-30 | Nippon Steel Corp | 焼結鉱の製造方法 |
JP2010138445A (ja) * | 2008-12-11 | 2010-06-24 | Jfe Steel Corp | 造粒焼結原料の予備処理方法 |
JP2010236081A (ja) * | 2009-03-12 | 2010-10-21 | Kobe Steel Ltd | 炭材内装塊成化物の製造方法 |
JP2013082972A (ja) * | 2011-10-11 | 2013-05-09 | Nippon Steel & Sumitomo Metal Corp | 非焼成含炭塊成鉱の製造方法 |
WO2017150428A1 (ja) * | 2016-03-04 | 2017-09-08 | Jfeスチール株式会社 | 焼結鉱の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
BR112021018309A2 (pt) | 2021-11-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2239344B1 (en) | Self-fluxing pellets for use in a blast furnace and process for the production of the same | |
JP4887728B2 (ja) | 焼結原料の造粒方法 | |
US9988695B2 (en) | Method for producing an agglomerate made of fine material containing metal oxide for use as a blast furnace feed material | |
EP3892744B1 (en) | Sintered ore manufacturing method | |
WO2020218170A1 (ja) | 鉄鉱石ペレットの製造方法 | |
JP4935133B2 (ja) | フェロコークスおよび焼結鉱の製造方法 | |
JP4630304B2 (ja) | 高炉用自溶性ペレットおよびその製造方法 | |
JP7366832B2 (ja) | 鉄鉱石ペレットの製造方法 | |
JP2007113088A (ja) | 焼結原料の造粒用バインダー及び造粒方法 | |
JP5935979B2 (ja) | 焼結鉱製造用擬似粒子の製造方法および焼結鉱の製造方法 | |
JP2008189994A (ja) | 造粒焼結原料の製造方法 | |
JP2003096521A (ja) | 高アルミナ鉄鉱石配合の焼結鉱及びその製造方法 | |
JPS63219534A (ja) | 自溶性ペレットの製造方法 | |
JP2000178660A (ja) | 高品質低SiO2 焼結鉱の製造方法 | |
JP4725230B2 (ja) | 焼結鉱の製造方法 | |
JP4767388B2 (ja) | 高温性状の優れた焼結鉱の製造方法 | |
KR102233326B1 (ko) | 탄재 내장 소결광의 제조 방법 | |
JP6887717B2 (ja) | 焼結鉱製造用の炭材内装造粒粒子およびそれを用いた焼結鉱の製造方法 | |
JP5126580B2 (ja) | 焼結鉱の製造方法 | |
JP7529186B1 (ja) | ペレットの製造方法 | |
JP3952988B2 (ja) | 低SiO2焼結鉱の製造方法 | |
JP2003277838A (ja) | 高炉用焼結原料に用いる高結晶水鉱石、高炉用焼結原料及びその製造方法 | |
JP3709001B2 (ja) | 製鉄用非焼成塊成鉱及びその使用方法 | |
JP4501656B2 (ja) | 焼結鉱の製造方法 | |
JP2001348622A (ja) | 高炉用高品質低SiO2焼結鉱の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 20795324 Country of ref document: EP Kind code of ref document: A1 |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112021018309 Country of ref document: BR |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 112021018309 Country of ref document: BR Kind code of ref document: A2 Effective date: 20210915 |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 20795324 Country of ref document: EP Kind code of ref document: A1 |