WO2020174303A1 - 半導体装置及び半導体装置の動作方法 - Google Patents
半導体装置及び半導体装置の動作方法 Download PDFInfo
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- WO2020174303A1 WO2020174303A1 PCT/IB2020/051162 IB2020051162W WO2020174303A1 WO 2020174303 A1 WO2020174303 A1 WO 2020174303A1 IB 2020051162 W IB2020051162 W IB 2020051162W WO 2020174303 A1 WO2020174303 A1 WO 2020174303A1
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- Prior art keywords
- transistor
- oxide
- insulator
- conductor
- electrically connected
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Classifications
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- H03F1/02—Modifications of amplifiers to raise the efficiency, e.g. gliding Class A stages, use of an auxiliary oscillation
- H03F1/0205—Modifications of amplifiers to raise the efficiency, e.g. gliding Class A stages, use of an auxiliary oscillation in transistor amplifiers
- H03F1/0211—Modifications of amplifiers to raise the efficiency, e.g. gliding Class A stages, use of an auxiliary oscillation in transistor amplifiers with control of the supply voltage or current
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- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/04—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body
- H01L27/06—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration
- H01L27/0688—Integrated circuits having a three-dimensional layout
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- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/04—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body
- H01L27/06—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration
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- H01L27/04—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body
- H01L27/06—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration
- H01L27/0611—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration integrated circuits having a two-dimensional layout of components without a common active region
- H01L27/0617—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration integrated circuits having a two-dimensional layout of components without a common active region comprising components of the field-effect type
- H01L27/0629—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration integrated circuits having a two-dimensional layout of components without a common active region comprising components of the field-effect type in combination with diodes, or resistors, or capacitors
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- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1203—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI
- H01L27/1207—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI combined with devices in contact with the semiconductor body, i.e. bulk/SOI hybrid circuits
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- H03F1/0205—Modifications of amplifiers to raise the efficiency, e.g. gliding Class A stages, use of an auxiliary oscillation in transistor amplifiers
- H03F1/0261—Modifications of amplifiers to raise the efficiency, e.g. gliding Class A stages, use of an auxiliary oscillation in transistor amplifiers with control of the polarisation voltage or current, e.g. gliding Class A
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- H03F3/45076—Differential amplifiers with semiconductor devices only characterised by the way of implementation of the active amplifying circuit in the differential amplifier
- H03F3/45179—Differential amplifiers with semiconductor devices only characterised by the way of implementation of the active amplifying circuit in the differential amplifier using MOSFET transistors as the active amplifying circuit
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- H03K5/00—Manipulating of pulses not covered by one of the other main groups of this subclass
- H03K5/01—Shaping pulses
- H03K5/08—Shaping pulses by limiting; by thresholding; by slicing, i.e. combined limiting and thresholding
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- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/0203—Particular design considerations for integrated circuits
- H01L27/0248—Particular design considerations for integrated circuits for electrical or thermal protection, e.g. electrostatic discharge [ESD] protection
- H01L27/0251—Particular design considerations for integrated circuits for electrical or thermal protection, e.g. electrostatic discharge [ESD] protection for MOS devices
- H01L27/0266—Particular design considerations for integrated circuits for electrical or thermal protection, e.g. electrostatic discharge [ESD] protection for MOS devices using field effect transistors as protective elements
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- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78645—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with multiple gate
- H01L29/78648—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with multiple gate arranged on opposing sides of the channel
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- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/7869—Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising an oxide semiconductor material, e.g. zinc oxide, copper aluminium oxide, cadmium stannate
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
- H02J7/0029—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries with safety or protection devices or circuits
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- H03F2200/42—Indexing scheme relating to amplifiers the input to the amplifier being made by capacitive coupling means
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- H03F—AMPLIFIERS
- H03F2200/00—Indexing scheme relating to amplifiers
- H03F2200/522—Indexing scheme relating to amplifiers the bias or supply voltage or current of the gate side of a FET amplifier being controlled to be on or off by a switch
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- H03—ELECTRONIC CIRCUITRY
- H03F—AMPLIFIERS
- H03F2203/00—Indexing scheme relating to amplifiers with only discharge tubes or only semiconductor devices as amplifying elements covered by H03F3/00
- H03F2203/45—Indexing scheme relating to differential amplifiers
- H03F2203/45156—At least one capacitor being added at the input of a dif amp
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- H03F—AMPLIFIERS
- H03F2203/00—Indexing scheme relating to amplifiers with only discharge tubes or only semiconductor devices as amplifying elements covered by H03F3/00
- H03F2203/45—Indexing scheme relating to differential amplifiers
- H03F2203/45342—Indexing scheme relating to differential amplifiers the AAC comprising control means on a back gate of the AAC
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- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03F—AMPLIFIERS
- H03F2203/00—Indexing scheme relating to amplifiers with only discharge tubes or only semiconductor devices as amplifying elements covered by H03F3/00
- H03F2203/45—Indexing scheme relating to differential amplifiers
- H03F2203/45544—Indexing scheme relating to differential amplifiers the IC comprising one or more capacitors, e.g. coupling capacitors
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- H—ELECTRICITY
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- H03F—AMPLIFIERS
- H03F2203/00—Indexing scheme relating to amplifiers with only discharge tubes or only semiconductor devices as amplifying elements covered by H03F3/00
- H03F2203/45—Indexing scheme relating to differential amplifiers
- H03F2203/45618—Indexing scheme relating to differential amplifiers the IC comprising only one switch
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- H03F—AMPLIFIERS
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- H03F2203/72—Indexing scheme relating to gated amplifiers, i.e. amplifiers which are rendered operative or inoperative by means of a control signal
- H03F2203/7203—Indexing scheme relating to gated amplifiers, i.e. amplifiers which are rendered operative or inoperative by means of a control signal the gated amplifier being switched on or off by a switch in the bias circuit of the amplifier controlling a bias current in the amplifier
Definitions
- One embodiment of the present invention relates to a semiconductor device and a method for operating the semiconductor device. Further, one embodiment of the present invention relates to a battery control circuit, a battery protection circuit, a power storage device, and an electric device.
- one embodiment of the present invention is not limited to the above technical field.
- the technical field of the invention disclosed in this specification and the like relates to an object, a method, or a manufacturing method.
- one embodiment of the present invention relates to a process, a machine, a manufacture, or a composition (composition of matter). Therefore, more specifically, as technical fields of one embodiment of the present invention disclosed in this specification, a display device, a light-emitting device, a power storage device, an imaging device, a memory device, a driving method thereof, or a manufacturing method thereof, Can be cited as an example.
- Power storage devices also called batteries and secondary batteries
- batteries are used in a wide range of fields, from small electrical devices to automobiles.
- applications using multi-cell battery stacks in which multiple battery cells are connected in series are increasing.
- the power storage device is provided with a circuit for grasping an abnormality during charging/discharging such as overdischarge, overcharge, overcurrent, or short circuit.
- an abnormality during charging/discharging such as overdischarge, overcharge, overcurrent, or short circuit.
- data such as voltage and current is acquired in order to detect abnormalities during charging and discharging.
- control such as charging/discharging stop and cell balancing is performed based on the observed data.
- Patent Document 1 discloses a protection IC that functions as a battery protection circuit.
- a plurality of comparators are provided inside, and the reference voltage and the voltage of the terminal to which the battery is connected are compared to detect an abnormality during charging/discharging. The structure is disclosed.
- Patent Document 2 discloses a comparator using a field effect transistor.
- Patent Document 1 US Patent Application Publication No. 201 1 -267726
- Patent Document 2 Japanese Patent Laid-Open No. 2009-71 653
- An object of one embodiment of the present invention is to provide a novel comparison circuit, a novel amplifier circuit, a novel battery control circuit, a novel battery protection circuit, a power storage device, a semiconductor device, an electric device, and the like.
- one aspect of the present invention ⁇ 0 2020/174303 ? €1/162020/051162 Aspect is a novel configuration of comparison circuit, amplification circuit, battery control circuit, battery protection circuit, power storage device, semiconductor device and semiconductor device that can reduce power consumption. It is an object to provide electric appliances and the like.
- problems of one embodiment of the present invention are not limited to the problems listed above.
- the issues listed above do not preclude the existence of other issues.
- Other issues are the ones not mentioned in this item, which are described in the following description.
- Problems that are not mentioned in this item can be derived from descriptions in the specification, drawings, etc. by those skilled in the art, and can be appropriately extracted from these descriptions.
- one embodiment of the present invention is to solve at least one of the problems listed above and/or other problems.
- One embodiment of the present invention includes a first amplifier circuit, a second amplifier circuit, and a capacitor, the first amplifier circuit has a first output terminal, the second amplifier circuit has an input terminal, It has two output terminals, a first transistor and a second transistor, the first output terminal is electrically connected to the first electrode of the capacitive element, and the second electrode of the capacitive element is connected to the input terminal. Electrically connected, the input terminal of the second amplifier circuit is electrically connected to the gate of the first transistor and one of the source and drain of the second transistor, and the source of the first transistor. One of the drain and the drain is electrically connected to the second output terminal, and the second amplification circuit has a function of amplifying a signal given to the input terminal and giving it to the second output terminal.
- a semiconductor device having a function of applying and holding a potential to an input terminal
- a channel formation region of the second transistor includes a metal oxide containing at least one of indium and gallium.
- one embodiment of the present invention includes a first amplifier circuit, a second amplifier circuit, and a capacitor, the first amplifier circuit has a first output terminal, and the second amplifier circuit has a first output terminal.
- the channel formation region of the second transistor has a metal oxide containing at least one of indium and gallium
- the third electrode is electrically connected to the high-potential wiring
- the fourth electrode is One of a source and a drain of the first transistor is electrically connected to the second output terminal
- the other of the source and the drain of the first transistor is a semiconductor device electrically connected to the low potential wiring. It is a place.
- the first semiconductor element has the third transistor, the third electrode is electrically connected to one of the source and the drain of the third transistor, and the fourth electrode is the third transistor. It is preferably electrically connected to the other of the source and the drain of the transistor.
- the first semiconductor element has a plurality of transistors connected in series
- the third electrode is electrically connected to a source or a drain of a transistor at one end of the plurality of transistors connected in series.
- the fourth electrode is electrically connected to the source or drain of the transistor at the other end of the plurality of transistors connected in series.
- [0 0 1 4] ⁇ 0 2020/174303 ? €1/162020/051162 or one embodiment of the present invention includes a first amplifier circuit, a second amplifier circuit, and a capacitor, and the second amplifier circuit has an input terminal and a second amplifier circuit.
- the first output terminal is electrically connected to the first electrode of the capacitive element
- the second electrode of the capacitive element is an input terminal and the gate of the first transistor.
- One of the source and drain of the first transistor is electrically connected to the second output terminal, the potential V 1 is output from the first output terminal, and the potential V 1 is input to the input terminal. Change the potential output from the first output terminal from the potential V 1 to the potential (1 + 1).
- a method of operating a semiconductor device comprising: a third step in which a signal, which is changed to (2 + 1) and whose potential (2 + 1) is amplified, is output from the second output terminal.
- the second amplifier circuit includes the second transistor, the gate of the first transistor is electrically connected to one of the source and the drain of the second transistor, and the second step is performed in the first step. It is preferable that the second transistor be on and the first transistor be off in the second step and the third step.
- the channel formation region of the second transistor have a metal rogate containing at least one of indium and gallium.
- the first amplifier circuit includes the third transistor and the fourth transistor, and one of the source and the drain of the third transistor is electrically connected to one of the source and the drain of the fourth transistor.
- the other of the source and the drain of the fourth transistor is electrically connected to the first output terminal, and in the third step, the potential of the first output terminal is applied to the gate of the third transistor. It is preferably generated according to the result of comparison between the potential and the potential applied to the gate of the fourth transistor.
- the first amplifier circuit has a fifth transistor and a sixth transistor, and a channel formation region of the sixth transistor has a metal oxide containing at least one of indium and gallium.
- One of the source and the drain of the fifth transistor is electrically connected to the first output terminal, and the one of the source and the drain of the sixth transistor is electrically connected to the gate of the fifth transistor. It is preferable that in the first step, the sixth transistor be on, and in the second step and the third step, the sixth transistor be off.
- a novel comparison circuit a novel amplifier circuit, a novel battery control circuit, a novel battery protection circuit, a power storage device, a semiconductor device, an electric device, and the like can be provided.
- a novel structure of a comparison circuit, an amplifier circuit, a battery control circuit, a battery protection circuit, a power storage device, a semiconductor device, an electrical device, or the like which can reduce power consumption is provided. can do.
- the effects of one embodiment of the present invention are not limited to the effects listed above.
- the effects listed above do not prevent the existence of other effects.
- Other effects are not mentioned in this item, as described in the following description. ⁇ 0 2020/174303 ? €1/16 2020/051162 It is an effect.
- the effects not mentioned in this item can be derived by those skilled in the art from the description in the specification or drawings, and can be appropriately extracted from these descriptions.
- one aspect of the present invention has at least one of the effects listed above and/or other effects. Therefore, one aspect of the present invention may not have the effects listed above in some cases.
- Figure 18 shows an example of the circuit configuration.
- Figure 18 shows an example of the circuit configuration.
- Figure 1 ⁇ 3 is an example of the circuit configuration.
- Figure 28 shows a circuit configuration example.
- Figure 23 shows an example of the circuit configuration.
- Figures 38 and 38 show examples of circuit configurations.
- Figure 4 shows an example of the circuit configuration.
- Figure 5 shows an example of the circuit configuration.
- Figure 68 shows a circuit configuration example.
- Figure 63 shows a circuit configuration example.
- FIG. 7 is a sectional view showing a configuration example of a semiconductor device.
- FIG. 88 is a cross-sectional view showing a structural example of a transistor.
- FIG. 83 is a cross-sectional view showing a structural example of a transistor.
- FIG. 8 is a cross-sectional view showing a structural example of a transistor.
- FIG. 98 is a top view showing a structural example of a transistor.
- Figure 93 is a cross-sectional view showing an example of the structure of a transistor.
- FIG. 9 is a cross-sectional view showing a structural example of a transistor.
- FIG. 108 is a top view showing a structural example of a transistor.
- FIG. 1013 is a cross-sectional view showing a structural example of a transistor.
- FIG. 10 (3 is a sectional view showing a structural example of a transistor.
- Figure 118 is a top view showing an example of the structure of a transistor.
- Figure 113 is a cross-sectional view showing an example of the structure of a transistor.
- FIG. 11 (3 is a cross-sectional view showing a structural example of a transistor.
- Figure 128 is a top view showing a structural example of a transistor.
- Figure 123 is a cross-sectional view showing an example of the structure of a transistor.
- FIG. 12 (3 is a sectional view showing a structural example of a transistor.
- Figure 138 is a top view showing an example of the structure of a transistor.
- Figure 133 is a sectional view showing an example of the structure of a transistor.
- FIG. 13 (3 is a cross-sectional view showing a structural example of a transistor.
- Figure 148 is a top view showing an example of the structure of a transistor.
- Figure 14 13 is a cross-sectional view showing an example of the structure of a transistor.
- FIG. 14 (3 is a cross-sectional view showing a structural example of a transistor.
- FIG. 15 is a cross-sectional view showing a configuration example of a semiconductor device.
- FIG. 16 is a cross-sectional view showing a structural example of a semiconductor device.
- the position, size, range, etc. of each configuration shown in the drawings and the like may not represent the actual position, size, range, etc. for easy understanding of the invention. Therefore, the disclosed invention is not necessarily limited to the position, size, range, or the like disclosed in the drawings and the like.
- the resist mask may be unintentionally diminished due to etching or the like, but it may not be reflected in the figure for ease of understanding.
- top view also referred to as “plan view”
- perspective view some of the constituent elements may be omitted in order to make the drawing easy to understand.
- electrode and “wiring” do not functionally limit these components.
- electrode may be used as part of “wiring” and vice versa.
- electrode and wiring include the case where a plurality of “electrodes” and “wirings” are integrally formed.
- a “terminal” may refer to a wiring or an electrode connected to the wiring, for example.
- part of the “wiring” may be referred to as a “terminal”.
- the terms “upper” and “lower” do not necessarily mean that a component is placed immediately above or below the component and is in direct contact with the component.
- the expression “electrode 8 on insulating layer 8” it is not necessary that the electrode 8 is directly formed on the insulating layer 8 and that another electrode is formed between the insulating layer 8 and the electrode 8. Do not exclude that includes components.
- the functions of the source and drain are switched depending on the operating conditions, such as when transistors with different polarities are used or when the direction of the current changes during circuit operation. Therefore, which is the source or drain is limited. Is difficult. Therefore, in this specification, the terms source and drain can be used interchangeably.
- “electrically connected” includes a case of being directly connected and a case of being connected through “thing having some electric action”.
- the “object having some kind of electric action” is not particularly limited as long as it can transfer an electric signal between the connected objects. Therefore, even if it is expressed as “electrically connect”, there are cases where the actual circuit does not have a physical connection part and only the wiring extends.
- parallel means, for example, that two straight lines are arranged at an angle of not less than 10° and not more than 10°. Say. Therefore, -5. It also includes the case of above 5°.
- vertical and orthogonal refer to, for example, a state in which two straight lines are arranged at an angle of 80° or more and 100° or less. Therefore, 8 5. This includes cases where the temperature is above 95°.
- a voltage often indicates a potential difference between a certain potential and a reference potential (eg, ground potential or source potential). Therefore, the voltage and the potential can be paraphrased in many cases. In this specification and the like, voltage and potential can be paraphrased unless otherwise specified.
- semiconductor even when described as “semiconductor”, for example, when it has sufficiently high conductivity, it has characteristics as “conductor”. Therefore, it is possible to replace the “semiconductor” with the “conductor”. In this case, the boundary between “semiconductor” and “conductor” is ambiguous, and it is difficult to distinguish between them. Therefore, the “semiconductor” and the “conductor” described in this specification may be interchangeable with each other.
- the “on state” of a transistor means a state where the source and the drain of the transistor can be regarded as being electrically short-circuited (also referred to as “conduction state”).
- the “off state” of a transistor is a state in which the source and drain of a transistor can be considered to be electrically cut off (also referred to as “non-conduction state”).
- the “on-state current” may refer to a current flowing between a source and a drain when the transistor is on.
- “off-state current” may refer to a current flowing between a source and a drain when a transistor is off.
- a high-potential signal refers to a power supply potential higher than that of a low-potential signal.
- the low potential signal indicates a power source potential that is lower than the high potential signal.
- the ground potential can be used as a high potential signal or a low potential signal.
- the high potential signal may be referred to as a high power supply potential.
- the low potential signal ⁇ 0 2020/174303 ? €1/16 2020/051162 Sometimes called the place.
- a gate refers to part or all of a gate electrode and a gate wiring.
- the gate wiring is a wiring for electrically connecting the gate electrode of at least one transistor to another electrode or another wiring.
- a source refers to part or all of a source region, a source electrode, and a source wiring.
- the source region is a region of the semiconductor layer whose resistivity is equal to or lower than a certain value.
- the source electrode refers to a portion of the conductive layer which is connected to the source region.
- a source wiring is a wiring for electrically connecting at least one transistor source electrode to another electrode or another wiring.
- drain means part or all of the drain region, the drain electrode, and the drain wiring.
- the drain region refers to a region of the semiconductor layer whose resistivity is equal to or lower than a certain value.
- the drain electrode refers to a conductive layer in a portion connected to the drain region.
- the drain wiring is a wiring for electrically connecting the drain electrode of at least one transistor to another electrode or another wiring.
- the semiconductor device 70 shown in FIG. 1 has an amplifier circuit 11, a capacitor element 61 and an amplifier circuit 71.
- the capacitance value of the capacitive element 61 is, for example, two times or more, or five times or more that of the transistor 81 described later.
- the capacitance value of the capacitor 6 1, for example, less than 1 0 0 F or 1 0? F.
- Terminals 0 11 3 are electrically connected to the amplifier circuit 11.
- Terminal 011 3 is electrically connected to one electrode of capacitive element 61.
- the node N 0 1 is electrically connected to the terminals 011 and 3 and one electrode of the capacitor 61.
- the amplifier circuit 7 1 has terminal IX 2, terminal 011 2, terminal 3 £, terminal XX, terminal and terminal.
- a high-potential signal and a low-potential signal are applied to the terminal XX and the terminal £, respectively.
- the ground potential may be used as the low potential signal.
- the amplifier circuit 71 shown in FIG. 18 has a transistor 81, a transistor 82 and a resistance element 89.
- One of the source and drain of the transistor 81 is electrically connected to the terminal £, and the other is connected to the terminal ⁇ . It is electrically connected to UT 2 and one electrode of the resistance element 89.
- the other electrode of the resistance element 89 is electrically connected to the terminal VDD.
- One of a source and a drain of the transistor 82 is electrically connected to the gate of the transistor 81 and the terminal IN2, and the other is electrically connected to the terminal BIAS1.
- the terminal S ET is electrically connected to the gate of the transistor 82.
- the potential between the terminal VDD and the terminal VS S is divided by the resistance value of the resistance element 89 and the transistor 81, and the potential is output from the terminal OUT 2.
- the gate of the transistor 81 is electrically connected to one of the source and the drain of the transistor 82.
- the signal from the terminal BI AS 1 is applied to the node ND 2 via the transistor 8 2.
- the operating point of the amplification circuit 71 (sometimes called the center point of operation) is set to a suitable potential, and the amplification circuit 7 1
- the gain of can be further increased. Further, the output range of the amplifier circuit 71 can be further widened.
- the off-state current can be extremely reduced.
- an OS transistor an oxide semiconductor in a channel formation region
- a suitable potential can be applied to the node ND 2 and then the node ND 2 can be brought into a floating state. That is, after the potential is applied to the node ND 2, the potential applied to the node ND 2 can be programmed by keeping the potential applied by turning off the transistor 82.
- the potential of ND 2 is maintained. At this time, for example, the node ND 2 holds a suitable operating point of the amplifier circuit 71. Since the signal supply to the terminal B I AS 1 can be stopped after the operating point is kept at the node ND 2, the power consumption of the semiconductor device 70 can be reduced.
- the amplifier circuit 71 can operate at a suitable operating point.
- a potential adjusted according to the characteristics of the amplifier circuit 71 can be supplied from the terminal B I AS 1 and programmed into the node ND 2.
- the potential for programming may be adjusted to the suitable operating point in accordance with the characteristics of the transistor.
- the semiconductor device 70 does not include the capacitive element 61 and the transistor 82.
- the signal from terminal OUTB is applied to the gate of transistor 81, ⁇ 0 2020/174303 ? €1/162020/051162
- the operating point of the path 7 1 is the output potential from the terminal 0 11 3 in the state where the amplifier circuit 11 is initialized. Since the semiconductor device of the embodiment has the capacitive element 61 and the transistor 82, the operating point of the amplification circuit 71 can be set to a desired value.
- the amplifier circuit 71 shown in FIG. 18 is different in that it has a circuit 303 instead of the resistance element 89 shown in FIG.
- the circuit 30 3 includes a transistor 8 3 and a transistor 8 4.
- the circuit 3 03 one of a source and a drain of the transistor 8 3 is used. Is electrically connected to the terminal XX and the other is electrically connected to the terminal 0111 to 2.
- One of the source and the drain of the transistor 8 4 is connected to the gate of the transistor 8 3 and the other is connected to the terminal.
- 0 3 electrically connected to each other.
- the gate of transistor 84 is electrically connected to the terminal.
- the circuit 303 has a function as a current source.
- the transistors included in the amplifier circuits 71 shown in FIGS. 18 and 18 may or may not have a back gate.
- the amplifier circuit 71 shown in FIG. 28 differs from the amplifier circuit 71 in that it has a circuit 301 in place of the circuit 303.
- the circuit 30b has a function as a current source.
- circuit 3013 has two transistors (transistor 8 3 and transistor 8 5) connected in series between terminals 0 and 2 as compared to circuit 3 03. ) Is different.
- the capacitor 8 7 is provided between the terminal 011 2 and the gate of the transistor 8 3
- the capacitor 8 8 is provided between the terminal 011 2 and the gate of the transistor 8 5.
- the circuit is not limited to the example shown in FIG. 23, and the circuit 30b may have three or more transistors between the terminal XX and the terminal XX.
- the voltage between the terminal XX and the terminal XX2 is distributed according to the resistance of each transistor. For example, if the source-drain voltage of transistor 8 3 increases, the current flowing in transistor 8 3 tries to increase, but the gate-source voltage of transistor 8 5 decreases, so the current flowing in transistor 8 5 decreases. Try to lower it. Since one transistor operates in the direction of suppressing the other transistor, the operation of both transistors is stable. The stable operation of the transistor stabilizes the output signal of the amplifier circuit 71. In addition, the gain of the amplifier circuit 71 may be increased.
- the circuit 3 0 13 includes a transistor 8 3, a transistor 8 4, a transistor 8 5, a transistor 8 6, a capacitor element 8 7, and a capacitor element 8 8.
- Terminal 011 2 is a tiger ⁇ 0 2020/174303 ? €1/16 2020/051162 Electrically connected to one of the source and drain of transistor 8 3, and the other of the source and drain of transistor 8 3 is one of the source and drain of transistor 8 5.
- the other of the source and drain of the transistor 85 is electrically connected to the terminal XX.
- One of the source and the drain of the transistor 84 is electrically connected to the gate of the transistor 83, and the other is electrically connected to the terminal: £80.
- One of a source and a drain of the transistor 86 is electrically connected to the gate of the transistor 85, and the other is electrically connected to the terminal 08.
- the terminal ££ is electrically connected to the gate of transistor 84 and the gate of transistor 86.
- One electrode of the capacitor 8 7 is electrically connected to the terminal 011 2 and the other electrode is electrically connected to the gate of the transistor 8 3.
- One electrode of the capacitor element 8 8 is electrically connected to the terminal 0112, and the other electrode is electrically connected to the gate of the transistor 85.
- the gates of transistor 8 3 and transistor 8 5 are turned off by turning off transistors 8 4 and 8 6. Then, the potential is held.
- the transistor 84 and the transistor 86 the signal supply to the terminal V 30 £ and the terminal V 08 £ can be stopped, and power consumption can be reduced.
- the transistor included in the amplifier circuit 71 may have a back gate.
- the threshold voltage of the transistor can be controlled by applying a potential to the back gate of the transistor.
- Backgate of transistor 82 Electrically connected to.
- the back gate of transistor 81 is electrically connected to terminal £.
- the transistor included in the circuit 30013 may have a back gate.
- the transistor 85 for example, one of the source and the drain is electrically connected to the terminal XX and the other is electrically connected to the back gate of the transistor 85.
- a back gate is electrically connected to the terminal 011-2.
- An 11-channel transistor as a transistor included in the amplifier circuit of one embodiment of the present invention Any of channel type transistors may be used. As shown in FIGS. 18, 18, 28 and 28, 11 channel type transistors may be used as the main transistors of the amplification circuit 71. Good. In the semiconductor device of one embodiment of the present invention, an 11-channel transistor is used as a main transistor included in the amplifier circuit, and an amplifier circuit having high gain and wide output can be realized.
- the transistor whose gate is connected to the terminal £ £ is turned on at time 1 and turned off at time 2.
- a signal is applied to the gate of the transistor 82 from the terminal P and the transistor 82 is turned on. Therefore, a signal is supplied from the terminal 8 I8 1 to the node N02 through the transistor 82, and the potential of the node N02 becomes the potential V 2. Also, a signal is output from terminals 011 to 8, and the potential of the node N01 becomes the potential V 1.
- a signal is applied to the gate of the transistor 82 from the terminal P and the transistor 82 is turned off.
- the off-state current is extremely low, so the node N02 is in a floating state.
- the potential of the node N01 is constant, the potential of the node N02 is also kept substantially constant.
- the potential of the node N02 changes by an amount corresponding to the change of the potential of the node N01 due to capacitive coupling with the capacitive element 61.
- the amplifier circuit 71 can be operated with the potential V 2 as the operating point.
- a suitable signal may be given from the terminal 3 I 8 1 so that the potential V 2 becomes a suitable value.
- the potential 2 may be adjusted, for example, so that the operating region of the transistor 81 is suitable.
- the transistor 81 may be operated in the saturation region, for example.
- the potential V 2 is preferably an intermediate potential between the potential applied to the terminal VOO and the potential applied to the terminal V.
- the gain of the amplifier circuit 71 can be further increased. Further, the output range of the amplifier circuit 71 can be further widened.
- the amplifier circuit 11 shown in FIG. 38 has a function as a comparison circuit.
- terminal I NP are electrically connected.
- the first input signal is applied to the terminal I NN4, the second input signal is applied to the terminal I NP, and the output signal is output from the terminal 011-3.
- the transistor used for the amplifier circuit 11 may or may not be provided with a back gate.
- the amplifier circuit 11 includes a transistor 31, a transistor 32, a transistor 34, a transistor 45, a circuit 300 and a circuit 30 ⁇ 1.
- the amplifier circuit 11 is electrically connected to a terminal XX, a terminal, a terminal 3818, a terminal VSH, a terminal 3 and a terminal 0.
- Circuit 300, and ⁇ 02020/174303 ?1/162020/051162 and the circuit 30 ⁇ 1 have a function as a current source.
- the gate of the transistor 31 is electrically connected to the terminal I NN4, and the gate of the transistor 32 is electrically connected to the terminal I NP.
- One of a source and a drain of transistor 34 is electrically connected to terminal £, and the other is electrically connected to node N05.
- Node N05 is electrically connected to one of a source and a drain of transistor 31 and one of a source and a drain of transistor 32.
- the other of the source and the drain of transistor 31 is electrically connected to node N03, and the other of the source and the drain of transistor 32 is electrically connected to terminal 011-8.
- a terminal may be connected to the node N03 and the terminal may function as an output terminal.
- One of the source and the drain of the transistor 45 is electrically connected to the gate of the transistor 34, and the other is electrically connected to the terminal 8.
- Terminal 011 is electrically connected to node N03.
- the terminals 011 may be in a floating state, for example.
- FIG. 33 when a plurality of stages of amplifier circuits 11 are connected, they may be connected to the next stage amplifier circuits 11 1.
- FIG. 33 shows an example in which a plurality of stages of amplifier circuits 11 are connected.
- the amplifier circuits 11 may be connected, for example, in 5 stages or more and 20 stages or less, or in 7 stages or more and 14 stages or less.
- the terminals 011 and 3 functioning as the output terminals of the amplifier circuit 11 are electrically connected to the input terminals of the amplifier circuit 11 of the next stage.
- it is electrically connected to the terminals I NP and I NN4 as the input terminals of the amplifier circuit 11 in the next stage.
- the terminal 011, 3 may be connected to one of the terminals I NP and I NN4, and the terminal 011, 3 may be connected to the other.
- the amplifier circuit 11 shown in FIG. 4 has a capacitive element 41 and a capacitive element 42.
- One electrode of the capacitor 41 and one electrode of the capacitor 42 are electrically connected to the gate of the transistor 34.
- the other electrode of the capacitor 41 is electrically connected to the node N03, and the other electrode of the capacitor 42 is electrically connected to the terminal 0111-8.
- Node N04 is electrically connected to the gate of transistor 34.
- the node N04 is brought into a floating state by applying a potential at which the transistor 45 is turned off, for example, a low potential signal to the terminal H.
- Capacitance element 41 and capacitance element 42 are electrically connected to node N04, and the effect of suppressing the variation of node N04 due to the variation of characteristics of transistor 31 and transistor 32 and stabilizing the operating point of amplification circuit 11 Equipped with. ⁇ 02020/174303 ? €1/162020/051162
- the transistor 45 By using a ⁇ transistor as the transistor 45, after the potential is applied to the gate of the transistor 34, the transistor 45 is turned off and the potential is held. It is possible to stop the signal supply to the terminal VSH and reduce the power consumption.
- the transistor included in the amplifier circuit 11 may have a back gate.
- the back gate is electrically connected to the terminal £.
- the transistor 45, the transistor 46, and the transistor 47, for example, the back gate is electrically connected to the terminal: 80.
- the threshold values of the transistors 31 and 32 can be negatively shifted.
- shifting the threshold of the transistor by a minus it becomes possible to detect a lower level input signal.
- Node N05 is electrically connected to terminal £ via transistor 34.
- One of the source and the drain of the transistor 34 is electrically connected to the terminal £, and the other is electrically connected to the node N05.
- a transistor 46 and a capacitive element 48 are connected to the back gate of the transistor 31, and a signal from the terminal N4 V 3 is given via the transistor 46.
- the gates of transistor 46 and transistor 4 7 have terminals The Ding is electrically connected.
- One of the source and the drain of the transistor 46 is electrically connected to the terminal 3, and the other is electrically connected to the back gate of the transistor 31 and one electrode of the capacitor element 48.
- the other electrode of the capacitive element 48 is electrically connected to the node N05.
- a transistor 47 and a capacitive element 49 are connected to the back gate of the transistor 32, and a signal from the terminal 8 is given via the transistor 47.
- One of a source and a drain of the transistor 47 is electrically connected to the terminal 3, and the other is electrically connected to a back gate of the transistor 32 and one electrode of the capacitor 49.
- the other electrode of the capacitive element 49 is electrically connected to the node N05.
- the transistors 46 and 47 are turned off, whereby the back gate potential of the transistor 31 is held by the capacitor 48 and the back gate of the transistor 32 is held.
- the potential of the gate is held by the capacitor 49.
- FIG. 5 shows an example of the amplifier circuit 11.
- the amplifier circuit 11 shown in FIG. And the transistor 36 between the transistor 31, is that it has a transistor 37 between the circuit 30 ⁇ 1 and the transistor 32 differs from the amplifier circuit 1 1 shown in FIG. [0102]
- one of the source and the drain of the transistor 31 is electrically connected to the node N D5, and the other is electrically connected to one of the source and the drain of the transistor 36.
- the other of the source and drain of transistor 36 is electrically connected to circuit 30c.
- One of the source and the drain of the transistor 32 is electrically connected to the node ND5, and the other is electrically connected to one of the source and the drain of the transistor 37.
- the other source and drain of transistor 37 are electrically connected to circuit 30d.
- a potential is applied to the gates of the transistor 36 and the transistor 37 from the terminal VC AS D.
- Transistor 36 and transistor 37 may have a back gate.
- the back gate of the transistor 36 is electrically connected to one of the source and the drain, for example.
- the back gate of the transistor 36 may be connected to, for example, a terminal that gives a desired potential, and specifically, may be connected to terminals such as the terminal VSS and the terminal VBG.
- the back gate of the transistor 37 is electrically connected to one of the source and the drain, for example.
- the back gate of the transistor 37 may be connected to, for example, a terminal that gives a desired potential, and specifically, may be connected to terminals such as the terminal VS S and the terminal V BG.
- FIG. 5 shows an example in which the amplifier circuit 11 does not have the capacitor element 41 and the capacitor element 42
- the amplifier circuit 11 shown in FIG. 5 may have the capacitor element 41 and the capacitor element 42. ..
- the transistors 34, 45, 46 and 47 do not have back gates, but they may have back gates.
- the voltage between the terminal OUT and the node ND 5 is distributed according to the respective transistor resistances. For example, when the source-drain voltage of the transistor 36 increases, the current flowing in the transistor 36 is increased, but the gate-source voltage of the transistor 36 decreases, and therefore the current flowing in the transistor 31 decreases. Since one transistor operates in the direction of suppressing the other transistor, the operation of both transistors is stable. The stable operation of the transistor stabilizes the output signal of the amplifier circuit 11. In addition, the gain of the amplifier circuit 11 may be increased in some cases. Similarly, if the above description is applied to the transistor 36 instead of the transistor 36 and the transistor 32 instead of the transistor 31, one of the transistors 31 and 32 operates in the direction of suppressing the other transistor. It can be said that the operation of the transistor is stable.
- the transistor 46 and the transistor 47 have a function of holding the potential applied from the terminal VBG.
- a high potential signal is applied from the terminal S ET to turn on the transistors 46 and 47, a potential from the terminal VBG is applied to the transistor 31 and the transistor 32, and then a low potential signal is applied from the terminal S ET.
- the potential from VBG can be held.
- OS Transistor has extremely low off current. Therefore, the transistor By using a resistor, the potential applied from the terminal VBG can be held for a long time, preferably 1 minute or more, more preferably 1 hour or more, and further preferably 10 hours or more.
- a high-potential signal is applied to the terminal S ET and the transistors connected to each terminal are turned on.
- the potential V 2 is applied to the node ND 2 from the terminal B I AS 1 through the transistor 82.
- the circuit 30a, the circuit 30b, the circuit 30c, the circuit 30d, etc. can function as a current source.
- a high potential signal is applied to the terminal VSH to turn on the transistor 45.
- this signal is applied to the gate of the transistor 34 via the transistor 45, and the transistor 34 can function as a current source.
- Transistor 34 is preferably operated in the saturation region, for example.
- Input approximately the same potential to pin I NM and pin I NP. It is preferable that the potential difference is within the range of 20 mV. Alternatively, the potential difference is preferably within 10 mV. It is preferable that the potential difference is within 5 mV.
- a low-potential signal is applied to pin SET and pin VSH.
- Transistor 82 is turned off and terminal IN 2 is in a floating state. Further, the transistors 84 and 86 are turned off, and the gate potential of the transistor 83 and the gate potential of the transistor 85 are in a floating state.
- the two signals to be compared are input to terminals I NM and I NP.
- the potential at time t 2 is continuously held and the value of the terminal I NP is changed.
- the potential of the node ND 1 connected to the terminal OUT B changes.
- the potential of the terminal IN is low
- the potential of the node ND 1 is high
- the potential of the terminal I NP is high
- the potential of the node ND 1 is low. Since the node ND 2 is in a floating state, the potential of the node ND 2 fluctuates by an amount equivalent to the fluctuation of the potential of the node ND 1 due to capacitive coupling.
- the amplifier circuit of one embodiment of the present invention is applied to a comparison circuit (also referred to as a comparator), and a memory element is connected to one input terminal of the comparison circuit.
- a comparison circuit also referred to as a comparator
- a memory element is connected to one input terminal of the comparison circuit.
- amplifier circuit 80 The configuration in which the amplifier circuit 11 shown in FIGS. 18, 13 and 28 is connected to the capacitor element 61 and the amplifier circuit 71 is hereinafter referred to as an amplifier circuit 80.
- the amplifier circuit 80 functions as a comparison circuit having two terminals, that is, the terminal INP and the terminal INM that function as input terminals, and the terminal 011-2 that functions as the output terminal.
- a signal is output from pin 0112 according to the comparison result of the signals input to pin I NP and pin I NM. It is preferable that one of the terminal I NP and the terminal I NN4 functions as a non-inverting input terminal and the other functions as an inverting input terminal.
- FIG. 68 shows an example in which the base signal is applied to terminal I NN4.
- the reference signal is preferably held in the storage element.
- the connection with the signal supply circuit can be disconnected after the reference signal is given from the signal supply circuit.
- the power supply can be cut off in the whole or a part of the signal supply circuit.
- the memory element As the memory element, the structure of the memory element 114 shown in FIG. 68 can be used.
- the memory element 1 1 1 4 shown in FIG. 6 8 has a capacitor 1 1 6 and a transistor 1 6 2.
- One of the source and the drain of the transistor 1 6 2 is electrically connected to the terminal I NN4, and the other (terminal in FIG. 6) receives the reference signal.
- One electrode of the capacitive element 1 61 is electrically connected to the terminal I NN4, and the other is supplied with the second reference signal, for example.
- the second reference signal a ground potential, a low potential signal, a high potential signal, a positive or negative potential of the secondary battery, a value obtained by resistance division between the positive and negative potentials of the secondary battery, and the like are used. Good.
- transistor 162 It is preferable to use a O transistor as the transistor 162. Note that although the transistor 162 has a back gate in FIG. 68, it may have a structure without it.
- the transistor 1 6 2 is turned on, a signal is applied to the terminal, and a potential corresponding to the signal is applied to the terminal I NN4 via the transistor 1 6. After that, the transistor 1 6 2 is turned off. By using a transistor as the transistor 1 62, the off current of the transistor 1 6 2 can be made extremely low. Therefore the terminal.
- FIG. 63 shows an example in which the semiconductor device of one embodiment of the present invention is applied to a power storage system.
- the power storage system 100 includes a semiconductor device 70 and a secondary battery 1 21.
- the positive electrode of the secondary battery 1 21 is electrically connected to the terminal IX of the amplifier circuit 80.
- the terminal I NN4 holds, for example, the upper limit or the lower limit of the voltage range in the range preferable as the positive electrode.
- a storage device such as a secondary battery, a capacitor, or the like can be used as the secondary battery 1 21.
- a lithium ion secondary battery can be used as the secondary battery 1 21.
- Element 8 is one or more elements selected from Group 1 elements and Group 2 elements.
- an alkali metal such as lithium, sodium, potassium, etc.
- a group 2 element for example, calcium, beryllium, magnesium, etc.
- the element is one or more selected from cobalt, nickel, manganese, iron, and vanadium. Examples include 0 0 0 2 and lithium iron phosphate Otsu 1 F 6 0 4 .
- the signal from terminal 011 2 is inverted when the potential at terminal IN P exceeds the potential at terminal I NN4.
- the signal inversion means that a high potential signal changes to a low potential signal and a low potential signal changes to a high potential signal, for example.
- the secondary battery 1 21 is controlled according to the given signal.
- the transistor has an oxide semiconductor in the channel formation region.
- the oxide semiconductor it is preferable to use a metal oxide containing at least indium or zinc.
- a metal oxide containing indium and zinc In particular, it is preferable to use a metal oxide containing indium and zinc.
- gallium, yttrium, tin, and the like are contained. Further, one or more selected from boron, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten, and magnesium, may be contained.
- the metal oxide is indium, Consider the case of an I 11 — N 4 — 11 oxide with zinc and zinc.
- the element N4 is aluminum, gallium, yttrium, or tin.
- Other elements applicable to IV! include boron, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten, and Madanesium. However, in some cases, it may be possible to combine a plurality of the aforementioned elements.
- the semiconductor device illustrated in FIG. 7 includes a transistor 300, a transistor 500, and a capacitor 600.
- Figure 88 is a cross-sectional view of the transistor 500 in the channel length direction.
- FIG. 8C is a cross-sectional view of the transistor 300 in the channel width direction, and
- FIG. 8C is a cross-sectional view of the transistor 300 in the channel width direction.
- the transistor 500 is a transistor (OS transistor) including a metal oxide in a channel formation region.
- the transistor 500 has a feature of extremely low off-state current.
- the semiconductor device described in this embodiment includes a transistor 300, a transistor 500, and a capacitor 600 as illustrated in FIG.
- the transistor 500 is provided above the transistor 300
- the capacitor 600 is provided above the transistor 300 and the transistor 500, [0134]
- the transistor 300 is provided over the substrate 31 1 and includes a conductor 316, an insulator 315, a semiconductor region 3 1 3 which is part of the substrate 31 1, and a low resistance region 314 a which functions as a source region or a drain region. , And a low resistance region 314 b.
- the transistor 300 As shown in FIG. 8C, the upper surface and the side surface in the channel width direction of the semiconductor region 31 3 are covered with the conductor 3 16 via the insulator 3 15. As described above, by making the transistor 300 a F in type, the effective channel width is increased, so that the on-state characteristics of the transistor 300 can be improved. Moreover, since the contribution of the electric field of the gate electrode can be increased, the off characteristics of the transistor 300 can be improved.
- the transistor 300 may be either a p-channel type or an n-channel type.
- a semiconductor region such as a silicon-based semiconductor may be contained in a region where a channel of the semiconductor region 313 is formed, a region in the vicinity thereof, a low-resistance region 314 a to be a source region, a drain region, a low-resistance region 314 b, or the like.
- a semiconductor region such as a silicon-based semiconductor may be contained in a region where a channel of the semiconductor region 313 is formed, a region in the vicinity thereof, a low-resistance region 314 a to be a source region, a drain region, a low-resistance region 314 b, or the like.
- single crystal silicon is included.
- a material containing Ge (germanium), SiGe (silicon germanium), GaAs (gallium arsenide), Gaa1As (galluium aluminum arsenide), or the like may be used. It is also possible to employ a structure in which the effective mass is controlled by applying stress to the crystal la
- the transistor 300 may be a HEMT (H i g h E l e c t r o n Mo b i l i t y Tr a n s i s t o r) V,.
- the low-resistance region 314 a and the low-resistance region 314 b are the semiconductor material applied to the semiconductor region 313, an element that imparts n-type conductivity such as arsenic and phosphorus, or a p-type element such as boron. Contains an element that imparts the conductivity of.
- the conductor 316 that functions as a gate electrode is a semiconductor material such as silicon containing an element imparting n-type conductivity such as arsenic or phosphorus, or an element imparting p-type conductivity such as boron, or a metal.
- a conductive material such as a material, an alloy material, or a metal oxide material can be used.
- the work function is determined by the material of the conductor, so changing the material of the conductor ⁇ 02020/174303 It is possible to adjust the V 1; 11 of the capacitor (: 17132020 /051162). Specifically, it is preferable to use a material such as titanium nitride or tantalum nitride for the conductor. It is preferable to use a metal material such as tungsten or aluminum as a laminate for the conductor in order to achieve both the filling property and the embedding property, and it is particularly preferable to use tungsten in terms of heat resistance.
- transistor 300 illustrated in FIG. 7 is an example, and the structure is not limited thereto, and an appropriate transistor may be used depending on a circuit configuration or a driving method.
- An insulator 320, an insulator 322, an insulator 324, and an insulator 326 are sequentially stacked to cover the transistor 300.
- Examples of insulator 320, insulator 322, insulator 324, and insulator 326 include silicon oxide, silicon oxynitride, silicon nitride oxide, silicon nitride, aluminum oxide, aluminum oxynitride, aluminum nitride oxide, and nitride nitride. Aluminum or the like may be used.
- the insulator 322 may have a function as a flattening film for flattening a step caused by the transistor 300 or the like provided below the insulator.
- the upper surface of the insulator 322 may be flattened by a flattening treatment using a chemical mechanical polishing (0?) method or the like to improve flatness.
- the insulator 324 it is preferable to use a film having a barrier property such that hydrogen and impurities do not diffuse from the substrate 311 or the transistor 300 to a region where the transistor 500 is provided.
- a film having a barrier property against hydrogen for example, silicon nitride formed by the XX method can be used.
- silicon nitride formed by the XX method when hydrogen is diffused into a semiconductor element including an oxide semiconductor, such as the transistor 500, characteristics of the semiconductor element may be deteriorated in some cases. Therefore, it is preferable to use a film which suppresses diffusion of hydrogen between the transistor 500 and the transistor 300.
- the film that suppresses the diffusion of hydrogen is a film that has a small amount of released hydrogen.
- the desorption amount of hydrogen can be analyzed using, for example, the temperature programmed desorption gas analysis (exact analysis) method.
- the desorption amount of hydrogen in Insulator 324 was calculated as follows: when the surface temperature of the film is in the range of 50° ⁇ to 500° ⁇ , the desorption amount converted to hydrogen atoms is the area of Insulator 324. It is 10 X 10 15 3 1: 01X18 / or less, preferably 5 10 15 3 1: 01X18 / or less in terms of per hit.
- the insulator 326 preferably has a lower dielectric constant than the insulator 324.
- the dielectric constant of the insulator 326 is preferably less than 4, and more preferably less than 3.
- the relative permittivity of the insulator 326 is preferably 0.7 times or less, and more preferably 0.6 times or less, that of the insulator 324.
- Insulator 320, insulator 322, insulator 324, and insulator 326 have capacitive element 600, ⁇ 0 2020/174303 A conductor (: 17132020/051162 or a conductor 3 28 connected to the transistor 500, conductor 3300, etc. is embedded.
- Conductor 3 2 8 and conductor 3 3 30 has a function as a plug or a wiring, and an electric conductor having a function as a plug or a wiring may have a plurality of structures collectively given the same reference numeral. In this case, the wiring and the plug connected to the wiring may be integrated, that is, some of the conductors may function as wiring, and some of the conductors may function as plugs. ..
- each plug and wiring As the material of each plug and wiring (conductor 32 8 and conductor 3 30 etc.), a conductive material such as metal material, alloy material, metal nitride material, or metal oxide material is used. It can be used as a layer or a laminate. It is preferable to use a high melting point material such as tungsten or molybdenum, which has both heat resistance and conductivity, and it is preferable to use tungsten. Alternatively, it is preferably formed of a low resistance conductive material such as aluminum or copper. Wiring resistance can be reduced by using a low-resistance conductive material.
- a wiring layer may be provided on the insulator 326 and the conductor 330.
- an insulator 350, an insulator 352, and an insulator 354 are sequentially stacked.
- a conductor 3 5 6 is formed on the insulator 3 50, the insulator 3 52, and the insulator 3 5 4.
- the conductor 356 has a function as a plug connected to the transistor 300 or a wiring. Note that the conductor 3 56 can be provided using a material similar to that of the conductor 3 28 and the conductor 3 30.
- the insulator 350 it is preferable to use an insulator having a barrier property against hydrogen, like the insulator 324.
- the conductor 356 preferably contains a conductor having a barrier property against hydrogen.
- a conductor having a barrier property against hydrogen is formed in the opening of the insulator 350 having a barrier property against hydrogen.
- tantalum nitride or the like is preferably used as the conductor having a barrier property against hydrogen.
- tantalum nitride or the like is preferably used as the conductor having a barrier property against hydrogen.
- tantalum nitride and tungsten having high conductivity diffusion of hydrogen from the transistor 300 can be suppressed while maintaining conductivity as a wiring.
- the tantalum nitride layer having a barrier property against hydrogen is in contact with the insulator 350 having a barrier property against hydrogen.
- a wiring layer may be provided on the insulator 354 and the conductor 356.
- the insulator 360, the insulator 362, and the insulator 364 are sequentially stacked.
- a conductor 3666 is formed on the insulator 360, the insulator 362, and the insulator 364.
- the conductor 366 has a function as a plug or a wiring. Note that the conductor 3 66 can be provided using a material similar to that of the conductor 3 28 and the conductor 3 30.
- the insulator 360 is an insulator having a barrier property against hydrogen, like the insulator 324. ⁇ 0 2020/174303 It is preferable to use (: 17132020/051162.
- the conductor 366 preferably contains a conductor having a barrier property against hydrogen. Particularly, it has a barrier property against hydrogen.
- a conductor having a barrier property against hydrogen is formed in the opening of the insulator 360. With this structure, the transistor 300 and the transistor 500 can be separated by a barrier layer. The diffusion of hydrogen from the transistor 300 to the transistor 500 can be suppressed.
- a wiring layer may be provided on the insulator 364 and the conductor 3666.
- an insulator 370, an insulator 372, and an insulator 374 are sequentially stacked and provided. Further, a conductor 3 7 6 is formed on each of the insulator 370, the insulator 372, and the insulator 374.
- the conductor 376 has a function as a plug or a wiring. Note that the conductor 376 can be provided using a material similar to that of the conductor 3 28 and the conductor 3 30.
- the insulator 370 it is preferable to use an insulator having a barrier property against hydrogen similarly to the insulator 324.
- the conductor 376 preferably contains a conductor having a barrier property against hydrogen.
- a conductor having a barrier property against hydrogen is formed in the opening of the insulator 370 having a barrier property against hydrogen.
- a wiring layer may be provided on the insulator 374 and the conductor 376.
- an insulator 380, an insulator 382, and an insulator 384 are sequentially stacked and provided.
- a conductor 3 86 is formed on the insulator 380, the insulator 382, and the insulator 384.
- the conductor 386 has a function as a plug or a wiring. Note that the conductor 3 86 can be provided using a material similar to that of the conductor 3 28 and the conductor 3 30.
- the insulator 380 like the insulator 324, it is preferable to use an insulator having a barrier property against hydrogen.
- the conductor 386 preferably contains a conductor having a barrier property against hydrogen.
- a conductor having a barrier property against hydrogen is formed in the opening of the insulator 380 having a barrier property against hydrogen.
- the wiring layer containing the conductor 3 56, the wiring layer containing the conductor 3 6 6, the wiring layer containing the conductor 3 76, and the wiring layer containing the conductor 3 86 were described.
- the semiconductor device according to the present embodiment is not limited to this.
- the wiring layer similar to the wiring layer including the conductor 3 56 may be three layers or less, or the wiring layer similar to the wiring layer including the conductor 356 may be five layers or more.
- An insulator 510, an insulator 512, an insulator 514, and an insulator 516 are laminated in this order on the insulator 384. It is preferable to use a substance having a barrier property against oxygen or hydrogen for any one of the insulator 510, the insulator 512, the insulator 514, and the insulator 516. ⁇ 0 2020/174303 ⁇ (: 17132020/051162
- the insulator 510 and the insulator 514 hydrogen and impurities do not diffuse from the substrate 311 or a region where the transistor 300 is provided to the region where the transistor 500 is provided, for example. It is preferable to use a film having such a barrier property. Therefore, the same material as the insulator 3 24 can be used.
- silicon nitride formed by the XX method can be used as an example of a film having a barrier property against hydrogen.
- silicon nitride formed by the XX method when hydrogen is diffused into a semiconductor element including an oxide semiconductor, such as the transistor 500, the characteristics of the semiconductor element might be deteriorated in some cases. Therefore, it is preferable to use a film which suppresses diffusion of hydrogen between the transistor 500 and the transistor 300.
- the film that suppresses the diffusion of hydrogen is a film that has a small amount of desorbed hydrogen.
- the film having a barrier property against hydrogen for example, it is preferable to use a metal oxide such as aluminum oxide, hafnium oxide, or tantalum oxide for the insulator 510 and the insulator 514.
- a metal oxide such as aluminum oxide, hafnium oxide, or tantalum oxide for the insulator 510 and the insulator 514.
- aluminum oxide has a high blocking effect that does not allow the film to permeate both oxygen and impurities such as hydrogen and moisture that cause fluctuations in the electrical characteristics of the transistor. Therefore, aluminum oxide can prevent impurities such as hydrogen and moisture from entering the transistor 500 during and after the manufacturing process of the transistor. In addition, release of oxygen from the oxide included in the transistor 500 can be suppressed. Therefore, it is suitable for use as a protective film for the transistor 500.
- insulator 5 12 and the insulator 5 16 a material similar to that of the insulator 3 20 can be used. Further, by using a material having a relatively low dielectric constant as the interlayer film, the parasitic capacitance generated between the wirings can be reduced.
- a silicon oxide film, a silicon oxynitride film, or the like can be used as the insulator 5 12 and the insulator 5 16.
- the insulator 510, the insulator 512, the insulator 514, and the insulator 516 include a conductor 518 and a conductor (conductor 50) which forms the transistor 5100. 3) etc. are embedded.
- the conductor 518 has a function as a plug connected to the capacitor 600 or the transistor 300, or a wiring.
- the conductor 5 18 can be provided using a material similar to that of the conductor 3 28 and the conductor 3 30.
- the insulator 5 10 and the conductor 5 18 in a region in contact with the insulator 5 14 are preferably conductors having a barrier property against oxygen, hydrogen, and water.
- the transistor 300 and the transistor 500 can be separated by a layer having a barrier property against oxygen, hydrogen, and water, and diffusion of hydrogen from the transistor 300 to the transistor 500 can be performed. Can be suppressed.
- a transistor 500 is provided above the insulator 516.
- the transistor 500 is arranged so as to be embedded in the insulator 5 1 4 and the insulator 5 16.
- Compound 5 3 0 13 and the conductor 5 4 2 3 and the conductor 5 4 3 which are placed on the oxide 5 3 0 13 and are separated from each other.
- FIG. 8 eight as shown in FIG. 8 3, the oxide 5 3 0 3, oxide 5 3 0 1 3, the conductor 5 4 2 3 and conductor 5 4 2 1 3, insulator 5 It is preferred that an insulator 544 is disposed between 80. Further, as shown in FIG. 8 eight, 8 8, the conductor 5 6 0, the conductors 5 6 0 3 disposed inside the insulator 5 5 0, implanted inside of the conductor 5 6 0 3 It is preferable to have the conductors 560 1 3 provided so that Further, as shown in FIGS. 88 and 88, it is preferable that the insulator 580, the conductor 560, and the insulator 574 be arranged over the insulator 550.
- the oxide 5303, the oxide 5313, and the oxide 530 may be collectively referred to as the oxide 530.
- the conductor 5 4 2 3 and the conductor 5 4 2 13 may be collectively referred to as a conductor 5 4 2.
- the transistor 500 a structure in which three layers of an oxide 5303, an oxide 5313, and an oxide 5300 are stacked in and around a region where a channel is formed is shown.
- the present invention is not limited to this.
- the above-described laminated structure may be provided.
- the conductor 560 is shown as a two-layer laminated structure, but the present invention is not limited to this.
- the conductor 560 may have a single-layer structure or a stacked structure of three or more layers.
- the transistor 500 illustrated in FIGS. 7, 88, and 83 is an example, and the structure is not limited thereto, and an appropriate transistor may be used depending on a circuit configuration or a driving method.
- the conductor 560 functions as a gate electrode of the transistor, and the conductor 5 4 23 and the conductor 5 4 213 function as a source electrode or a drain electrode, respectively.
- the conductor 5
- the conductor 60 is formed so as to be embedded in the opening of the insulator 580 and the region sandwiched between the conductor 5423 and the conductor 542b.
- the arrangement of the conductor 5600, the conductor 5432 and the conductor 5421 is selected in a self-aligned manner with respect to the openings in the insulator 58. That is, in the transistor 500, the gate electrode can be arranged in a self-aligned manner between the source electrode and the drain electrode. Therefore, the conductor 560 can be formed without providing a positioning margin, so that the area occupied by the transistor 550 can be reduced. As a result, miniaturization and high integration of semiconductor devices can be achieved. it can.
- the conductor 560 is formed in a region between the conductor 542a and the conductor 542b in a self-aligned manner, the conductor 560 overlaps with the conductor 542a or the conductor 542b. It has no area. Thereby, the parasitic capacitance formed between the conductor 560 and the conductor 542a and the conductor 542b can be reduced. Therefore, the switching speed of the transistor 500 can be improved and high frequency characteristics can be provided.
- the conductor 560 may function as a first gate (also referred to as a top gate) electrode.
- the conductor 503 may function as a second gate (also referred to as a bottom gate) electrode.
- V th of the transistor 500 can be controlled by changing the potential applied to the conductor 503 independently of the potential applied to the conductor 560 and without changing the potential.
- V th of the transistor 500 can be made higher than 0 V and off-state current can be reduced. Therefore, applying a negative potential to the conductor 503 can reduce the drain current when the potential applied to the conductor 560 is 0 V, as compared to the case where no potential is applied, [0 1 77]
- the conductor 503 is arranged so as to overlap with the oxide 530 and the conductor 560.
- the electric field generated from the conductor 560 is connected to the electric field generated from the conductor 503 to form a channel formation region in the oxide 530.
- a structure of a transistor which electrically surrounds a channel formation region by an electric field of the first gate electrode and the second gate electrode is referred to as a surro un dedchanne 1 (S— cha n el) structure. ..
- the side surface and the periphery of the oxide 530 which is in contact with the conductor 542 a and the conductor 542 b functioning as a source electrode and a drain electrode are the same as in the channel formation region. It has the characteristic of being a mold. Further, the side surface and the periphery of the oxide 530 which are in contact with the conductor 542a and the conductor 542b are in contact with the insulator 544, and thus can be I-type like the channel formation region. In this specification and the like, type I can be treated as the same as high-purity intrinsic, which will be described later.
- the S—cha n n e 1 structure disclosed in this specification and the like is different from the F in type structure and the planar type structure.
- the S— c h a n e e 1 structure it is possible to increase the resistance to the short channel effect, in other words, to make the transistor in which the short channel effect hardly occurs.
- the conductor 50 3 has the same structure as the conductor 5 18, and the conductor 503 a is formed in contact with the inner walls of the openings of the insulator 5 14 and the insulator 5 16 and the conductor 503 a is further formed inside.
- a body 503b is formed.
- the insulator 520, the insulator 522, the insulator 524, and the insulator 550 have a function as a gate insulating film.
- the insulator 524 which is in contact with the oxide 530, an insulator containing more oxygen than oxygen which satisfies the stoichiometric composition is preferably used. That is, the insulator 524 has an excess oxygen region formed therein. Preferably. By providing such an insulator containing excess oxygen in contact with the oxide 530, oxygen vacancies in the oxide 530 can be reduced and the reliability of the transistor 500 can be improved.
- an oxide material in which part of oxygen is released by heating is preferably used.
- An oxide desorbs oxygen by heating, TDS (Th e rma l De sorption S pectroscopy) under the analytical, the amount of released oxygen converted into oxygen atoms is 1. 0 X 1 0 18 at oms / cm 3 or more, preferably 1. 0 X 10 19 at om s / cm 3 or more, is preferably in al 2. 0 X 10 19 at oms / cm 3 or more, or 3.1 ⁇ X 1 0 20 at oms / cm
- the oxide film is 3 or more.
- the surface temperature of the film during the TDS analysis is preferably 100°C or higher and 700°C or lower, or 100°C or higher and 400°C or lower.
- the insulator 522 preferably has a function of suppressing diffusion of oxygen (eg, oxygen atoms, oxygen molecules, and the like) (oxygen is difficult to permeate).
- oxygen eg, oxygen atoms, oxygen molecules, and the like
- the insulator 522 has a function of suppressing diffusion of oxygen and impurities, oxygen included in the oxide 530 does not diffuse to the insulator 520 side, which is preferable.
- the conductor 503 can be prevented from reacting with the oxygen contained in the insulator 524 and the oxide 530.
- the insulator 522 may be, for example, aluminum oxide, hafnium oxide, tantalum oxide, zirconium oxide, lead zirconate titanate (PZT), strontium titanate (S r T i 0 3 ) or (B a, S r) T i. It is preferable to use an insulator containing a so-called high-k material such as Os (BST) in a single layer or a laminated layer. As transistors become finer and more highly integrated, thinning of the gate insulating film may cause problems such as leakage current. By using a hig h-k material for the insulator that functions as a gate insulating film, it is possible to reduce the gate potential during transistor operation while maintaining the physical film thickness.
- a so-called high-k material such as Os (BST)
- an insulator including an oxide of one or both of aluminum and hafnium which is an insulating material having a function of suppressing diffusion of impurities, oxygen, and the like (oxygen does not easily penetrate) is preferably used.
- the insulator containing one or both oxides of aluminum and hafnium it is preferable to use aluminum oxide, hafnium oxide, an oxide containing aluminum and hafnium (hafnium aluminate), or the like.
- the insulator 522 is formed using such a material, the insulator 522 suppresses release of oxygen from the oxide 530 and entry of impurities such as hydrogen from the periphery of the transistor 500 into the oxide 530. Function as a layer.
- aluminum oxide, bismuth oxide, germanium oxide, niobium oxide, silicon oxide, titanium oxide, tungsten oxide, yttrium oxide, or zirconium oxide may be added to these insulators.
- these insulators may be nitrided. Silicon oxide, silicon oxynitride, or silicon nitride may be stacked over the above insulator and used.
- the insulator 520 is preferably thermally stable.
- silicon oxide and oxide Silicon nitride is preferable because it is thermally stable.
- an insulator made of a high-k material with silicon oxide or silicon oxynitride, an insulator 520 having a laminated structure which is thermally stable and has a high relative dielectric constant can be obtained.
- the insulator 520, the insulator 522, and the insulator 524 may have a stacked structure of two or more layers. In that case, it is not limited to a laminated structure made of the same material, and may be a laminated structure made of different materials.
- the oxide 530 including a channel formation region is preferably a metal oxide functioning as an oxide semiconductor.
- an In-M-Zn oxide the element M is aluminum, gallium, yttrium, copper, vanadium, beryllium, boron, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium). , Neodymium, hafnium, tantalum, tungsten, magnesium, or the like), or a metal oxide).
- an In-Ga oxide or an In-Zn oxide may be used as the oxide 530.
- a metal oxide having a low carrier concentration is preferably used for the transistor 500.
- the concentration of impurities in the metal oxide may be lowered and the defect density may be lowered.
- low impurity concentration and low defect density are referred to as high purity intrinsic or substantially high purity intrinsic.
- the impurities in the metal oxide include, for example, hydrogen, nitrogen, alkali metals, alkaline earth metals, iron, nickel, silicon and the like.
- hydrogen contained in a metal oxide reacts with oxygen bonded to a metal atom to be water, which may cause oxygen vacancies in the metal oxide. If the channel formation region in the metal oxide contains oxygen vacancies, the transistor might have normally-on characteristics. Further, a defect in which hydrogen is contained in an oxygen vacancy may function as a donor and an electron which is a carrier may be generated. In addition, a part of hydrogen may combine with oxygen that bonds with a metal atom to generate an electron which is a carrier. Therefore, a transistor including a metal oxide containing a large amount of hydrogen is likely to be a normally-on extraordinary student.
- a defect in which hydrogen is contained in an oxygen vacancy can function as a metal oxide donor.
- the carrier concentration may be used for evaluation instead of the donor concentration. Therefore, in this specification and the like, a carrier concentration which is assumed to be a state where an electric field is not applied is sometimes used as a parameter of a metal oxide, instead of a donor concentration. That is, the “carrier concentration” described in this specification and the like may be referred to as the “donor concentration” in some cases.
- the hydrogen concentration obtained by secondary ion mass spectrometry is less than 1 X 10 20 at om s/cm 3 , preferably l X 1 0 19 at oms / cm less than 3, more preferably Less than 5 X 10 18 at om s / cm 3, further preferably that be less than 1 X 1 0 18 at oms / cm 3.
- the carrier concentration of the metal oxide of the channel formation region is preferably from 1 X 1 ⁇ 18 cm one 3, less than 1 X 1 0 17 cm one 3 there is laid more preferred, and even more preferably less than 1 X 10 16 cm one 3, and more preferably less than 1 X 1 0 13 cm one 3, to be less than 1 X 10 12 cm one 3 More preferable.
- the lower limit of the carrier concentration of the metal oxide of the channel forming region is not particularly limited, for example, be a 1 X 10- 9 cm- 3.
- the oxygen in the oxide 530 diffuses to the conductor 542 when the conductor 542 (the conductor 542a and the conductor 542b) is in contact with the oxide 530.
- the conductor 542 may be oxidized. It is highly probable that the conductivity of the conductor 542 will decrease due to the oxidation of the conductor 542. Note that diffusion of oxygen in the oxide 530 to the conductor 542 can be restated as absorption of oxygen in the oxide 530 by the conductor 542.
- oxygen in the oxide 530 diffuses into the conductor 542 (conductor 542 a and conductor 542 b), so that the oxygen between the conductor 542 a and the oxide 530 b, and between the conductor 542 b and the conductor 542 b.
- a different layer may be formed between the oxide and 530 b. Since the different layer contains more oxygen than the conductor 542, it is presumed that the different layer has an insulating property.
- the three-layer structure including the conductor 542, the different layer, and the oxide 53 Ob can be regarded as a three-layer structure including a metal, an insulator, and a semiconductor, and MI S (Me ta 1— I nsulator—Semiconductor) structure or a diode junction structure mainly composed of MIS structure.
- the different layer is not limited to being formed between the conductor 542 and the oxide 530 b, and for example, when the different layer is formed between the conductor 542 and the oxide 530 c. , May be formed between the conductor 542 and the oxide 530 b and between the conductor 542 and the oxide 530 c.
- the metal oxide functioning as a channel formation region in the oxide 530 it is preferable to use a metal oxide having a bandgap of 2 eV or more, preferably 2.5 eV or more. As described above, the off-state current of the transistor can be reduced by using the large band gap layer metal oxide.
- the oxide 530 has the oxide 530 a below the oxide 530 b, and thus can suppress diffusion of impurities from the structure formed below the oxide 530 a into the oxide 530 b. it can. Further, by having the oxide 530 c on the oxide 530 b, diffusion of impurities into the oxide 530 b from a structure formed above the oxide 530 c can be suppressed.
- the oxide 530 preferably has a stacked structure including a plurality of oxide layers in which the atomic ratio of each metal atom is different.
- the source of element M in the constituent elements ⁇ 0 2020/174303 ??1/162020/051162
- the ratio of the number of atoms is larger than the ratio of the number of atoms of the element N4 in the constituent elements in the metal oxide used for the oxide 5300b.
- the atomic number ratio of the element to 11 is larger than the atomic number ratio of the element N4 to the I11 of the metal oxide used for the oxide 5303. Is preferred.
- the atomic ratio of 11 to the element is higher than the atomic ratio of I11 to the element in the metal oxide used for the oxide 5303. Is preferred.
- the oxide 5300 a metal oxide which can be used for the oxide 5303 or the oxide 5313 can be used.
- the energy at the bottom of the conduction band of the oxide 5303 and the oxide 5300 is preferably higher than the energy at the bottom of the conduction band of the oxide 5300b.
- the electron affinity of the oxide 5300 & and the oxide 5300 is smaller than the electron affinity of the oxide 5300 b.
- the energy and potential at the lower end of the conduction band change gently.
- the oxide 5 3 0 3 the energy level of the conduction band minimum in oxide 5 3 0 1 3, and oxide 5 3 0 junction ⁇ refers continuously varying or continuous bonding result also be able to.
- the oxide 5303 and the oxide 5303, and the oxide 5300b and the oxide 5300 have a common element other than oxygen (as the main component). , It is possible to form a mixed layer with low defect density.
- oxide Oxides 530 and Oxides 530 As 1 11-0 Oxide, 0 It is preferable to use an oxide or gallium oxide.
- the main path of carriers is the oxide 530b.
- the defect density at the interface between the oxide 5303 and the oxide 5301 and at the interface between the oxide 5303 and the oxide 5300 is reduced. can do. Therefore, the influence of interface scattering on the carrier conduction is reduced, and the transistor 500 can obtain a high on-state current.
- a conductor 5 4 2 (conductor 5 4 2 3 and conductor 5 4 2 13) which functions as a source electrode and a drain electrode is provided over the oxide 5 3 0 13.
- Conductors 5 42 include aluminum, chromium, copper, silver, gold, platinum, tantalum, nickel, titanium, molybdenum, tungsten, hafnium, vanadium, niobium, manganese, magnesium, zirconium, beryllium, indium, ruthenium, It is preferable to use a metal element selected from iridium, strontium, and lanthanum, an alloy containing the above metal element as a component, an alloy in which the above metal elements are combined, or the like.
- tantalum nitride titanium nitride, tungsten, nitride containing titanium and aluminum, nitride containing tantalum and aluminum, ruthenium oxide, ruthenium nitride, oxide containing strontium and ruthenium, oxide containing lanthanum and nickel, etc. Is preferably used.
- tantalum nitride titanium nitride, nitride containing titanium and aluminum, nitride containing tantalum and aluminum, ruthenium oxide, ruthenium nitride, oxide containing strontium and ruthenium, oxide containing lanthanum and nickel, ⁇ 02020/174303 It is preferable because it is a conductive material that does not easily oxidize or that maintains conductivity even if it absorbs oxygen.
- regions 54 3 are formed as low resistance regions at the interface of the oxide 530 with the conductor 542 and its vicinity. There are cases. At this time, the region 543 3 functions as one of the source region and the drain region, and the region 543 b functions as the other of the source region and the drain region. In addition, a channel formation region is formed in a region between the region 5433 and the region 543b.
- the oxygen concentration in the region 543 may be reduced in some cases.
- a metal compound layer containing a metal contained in the conductor 542 and a component of the oxide 530 may be formed in the region 543. In such a case, the carrier concentration in the region 543 increases, and the region 543 becomes a low resistance region.
- the insulator 544 is provided so as to cover the conductor 542 and suppresses oxidation of the conductor 542. In that case, the insulator 544 may be provided so as to cover a side surface of the oxide 530 and be in contact with the insulator 524.
- a metal oxide containing one or more selected from hafnium, aluminum, gallium, yttrium, zirconium, tungsten, titanium, tantalum, nickel, germanium, or magnesium is used. be able to.
- an insulator containing one or both of aluminum and hafnium which is an insulator, aluminum oxide, hafnium oxide, an oxide containing aluminum and hafnium
- hafnium aluminate has higher heat resistance than hafnium oxide film. Therefore, crystallization is less likely to occur in a heat treatment in a later step, which is preferable.
- the insulator 544 is not an essential component if the conductor 542 is a material having oxidation resistance or if the conductivity does not significantly decrease even when oxygen is absorbed. It may be appropriately designed according to the desired transistor characteristics.
- the insulator 550 functions as a gate insulating film.
- the insulator 550 is preferably arranged in contact with the inside (top surface and side surface) of the oxide 530.
- the insulator 550 is preferably formed using an insulator in which oxygen is released by heating.
- the desorption amount of oxygen in terms of oxygen atoms is 1.0 1 0 18 3 1; ⁇ 1118/. 111 3 or more, preferably 1.0 1 0 19 3 1; ⁇ 1118/. 111 3 or more, more preferably 2.0 1 0 19 3 1; ⁇ 1118/.
- It is an oxide film having a thickness of 1x1 3 or more, or 3.01 0 2 ⁇ 3 1; ⁇ 1118 or more.
- the surface temperature of the film during the above-mentioned analysis is preferably in the range of 100°° or more and 700°° or less.
- silicon oxide containing excess oxygen, silicon oxynitride, silicon nitride oxide, silicon nitride, silicon oxide doped with fluorine, silicon oxide doped with carbon, silicon oxide doped with carbon and nitrogen, and voids are formed.
- the silicon oxide which it has can be used.
- silicon oxide and silicon oxynitride are preferable because they are stable to heat. ⁇ 0 2020/174303 ? €1/16 2020/051162
- An insulator from which oxygen is released by heating is provided as the insulator 550 in contact with the top surface of the oxide 530, so that the insulator 550 is converted into the oxide 530. Through, it is possible to effectively supply oxygen to the channel formation region of the oxide 5313. Further, similarly to the insulator 524, it is preferable that the concentration of impurities such as water or hydrogen in the insulator 550 is reduced.
- the film thickness of the insulator 550 is preferably 1 11 111 or more and 2 0 11 1x1 or less.
- a metal oxide may be provided between the insulator 550 and the conductor 560 in order to efficiently supply excess oxygen included in the insulator 550 to the oxide 530. ..
- the metal oxide preferably suppresses oxygen diffusion from the insulator 550 to the conductor 560.
- diffusion of excess oxygen from the insulator 550 to the conductor 560 is suppressed. That is, it is possible to suppress a decrease in the excess oxygen amount supplied to the oxide 5300.
- oxidation of the conductor 560 due to excess oxygen can be suppressed.
- a material that can be used for the insulator 544 may be used.
- the conductor 560 functioning as the first gate electrode is shown as a two-layer structure in FIGS. 8A and 8B, it may have a single-layer structure or a stacked structure of three or more layers. ..
- Conductors 5 6 0 3 is a hydrogen atom, a hydrogen molecule, a water molecule, a nitrogen atom, a nitrogen molecule, nitric oxide molecule (N 2 0, N 0, N 0 2 , etc.), inhibits the diffusion of impurities such as copper atoms It is preferable to use a conductive material having a function. Alternatively, it is preferable to use a conductive material having a function of suppressing diffusion of oxygen (eg, at least one of an oxygen atom and an oxygen molecule). Since the conductor 560 3 has a function of suppressing diffusion of oxygen, oxygen contained in the insulator 550 can prevent the conductor 560 13 from being oxidized and decreasing in conductivity. You can As a conductive material having a function of suppressing diffusion of oxygen, for example, tantalum, tantalum nitride, ruthenium, ruthenium oxide, or the like is preferably used.
- the conductor 56013 it is preferable to use a conductive material containing tungsten, copper, or aluminum as its main component. Since the conductor 560 13 also functions as a wiring, it is preferable to use a conductor having high conductivity. For example, a conductive material containing tungsten, copper, or aluminum as its main component can be used.
- the conductor 560 13 may have a laminated structure, for example, a laminated structure of titanium or titanium nitride and the above conductive material.
- the insulator 5800 is provided on the conductor 542 via the insulator 544.
- the insulator 580 preferably has an excess oxygen region.
- silicon oxide, silicon oxynitride, silicon nitride oxide, silicon nitride, silicon oxide added with fluorine, silicon oxide added with carbon, silicon oxide added with carbon and nitrogen, vacancy It is preferable to have a silicon oxide having a resin, a resin, or the like.
- silicon oxide and silicon oxynitride are preferable because they are thermally stable.
- silicon oxide and silicon oxide having pores are preferable because they can easily form an excess oxygen region in a later step.
- Insulator 580 preferably has an excess oxygen region. Insulator 580 from which oxygen is released by heating is contacted with oxide 530 Oxygen in the insulator 580 can be efficiently supplied to the oxide 53013 through the oxide 530 by providing the water in the insulator 580. Alternatively, the concentration of impurities such as hydrogen is preferably reduced.
- the opening of the insulator 5800 is formed so as to overlap with a region between the conductor 5 4 2 3 and the conductor 5 4 2 13.
- the conductor 560 is formed so as to be embedded in the opening of the insulator 580 and the region between the conductor 5423 and the conductor 542b.
- the conductor 560 can have a shape with a high aspect ratio.
- the conductor 560 is provided so as to be embedded in the opening of the insulator 580, even if the conductor 560 is formed in a shape having a high aspect ratio, the conductor 560 is not formed during the process. Can be formed without collapsing 0.
- the insulator 574 is preferably provided in contact with the top surface of the insulator 580, the top surface of the conductor 560, and the top surface of the insulator 550.
- an excess oxygen region can be provided in the insulator 550 and the insulator 580. Thereby, oxygen can be supplied into the oxide 530 from the excess oxygen region.
- aluminum oxide has a high barrier property and can suppress the diffusion of hydrogen and nitrogen even if it is a thin film of 0.511111 or more and 3.011111 or less. Therefore, the aluminum oxide film formed by a sputtering method can have a function as a barrier film against impurities such as hydrogen as well as an oxygen supply source.
- the insulator 581 which functions as an interlayer film over the insulator 574.
- the insulator 5 81 preferably has a reduced concentration of impurities such as water or hydrogen in the film.
- the conductors 5 4 0 3 and 5 4 0 13 are arranged in the openings formed in the insulator 5 81, the insulator 5 74, the insulator 5 8 0, and the insulator 5 4 4.
- the conductor 5403 and the conductor 5403 are provided to face each other with the conductor 560 interposed therebetween.
- the conductor 5403 and the conductor 5413 have the same configurations as the conductor 546 and the conductor 548 described later.
- An insulator 5 82 is provided on the insulator 5 81.
- the insulator 5 82 it is preferable to use a substance having a property of being resistant to oxygen and hydrogen. Therefore, insulator 5 82 is similar to insulator 5 14 ⁇ 0 2020/174303 A material (: 17132020/051162) can be used.
- a metal oxide such as aluminum oxide, hafnium oxide, or tantalum oxide for the insulator 582.
- aluminum oxide has a high blocking effect that does not allow the film to permeate both oxygen and impurities such as hydrogen and moisture that cause fluctuations in the electrical characteristics of the transistor. Therefore, aluminum oxide can prevent impurities such as hydrogen and moisture from entering the transistor 500 during and after the manufacturing process of the transistor. In addition, release of oxygen from the oxide included in the transistor 500 can be suppressed. Therefore, it is suitable for use as a protective film for the transistor 500.
- an insulator 586 is provided on the insulator 582.
- a material similar to that of the insulator 320 can be used.
- a material having a relatively low dielectric constant as the interlayer film it is possible to reduce the parasitic capacitance generated between the wirings.
- a silicon oxide film, a silicon oxynitride film, or the like can be used as the insulator 586.
- the conductor 546 and the conductor 548 have a function of a plug connected to the capacitor 600, the transistor 500, or the transistor 300, or a wiring.
- the conductor 5 46 and the conductor 5 48 can be provided using a material similar to that of the conductor 3 28 and the conductor 3 30.
- the capacitor 600 is provided above the transistor 500.
- the capacitor 600 has a conductor 610, a conductor 620, and an insulator 630.
- the conductor 6 12 may be provided over the conductor 5 46 and the conductor 5 48.
- the conductor 6 12 has a function as a plug connected to the transistor 500 or a wiring.
- the conductor 610 has a function as an electrode of the capacitor element 600. Note that the conductor 6 12 and the conductor 6 10 can be formed at the same time.
- the conductor 6 12 and the conductor 6 10 include a metal film containing an element selected from molybdenum, titanium, tantalum, tungsten, aluminum, copper, chromium, neodymium, and scandium, or the above-mentioned elements as components.
- a metal nitride film (tantalum nitride film, titanium nitride film, molybdenum nitride film, tungsten nitride film) or the like can be used.
- indium tin oxide indium oxide containing tungsten oxide, indium zinc oxide containing tungsten oxide, indium oxide containing titanium oxide, indium tin oxide containing titanium oxide, indium zinc oxide, silicon oxide
- a conductive material such as added indium tin oxide can also be applied.
- the conductor 6 12 and the conductor 6 10 are illustrated as a single-layer structure in FIG. 7, the structure is not limited to this structure. ⁇ 0 2020/174303 ??1/16 2020/051162 However, a laminated structure of two or more layers may be used. For example, a conductor having a barrier property and a conductor having high adhesion to the conductor having high conductivity may be formed between the conductor having barrier property and the conductor having high conductivity.
- the conductor 620 is provided so as to overlap with the conductor 610 through the insulator 630.
- the conductor 620 can be formed using a conductive material such as a metal material, an alloy material, or a metal oxide material. It is preferable to use a high melting point material such as tungsten or molybdenum, which has both heat resistance and conductivity, and it is particularly preferable to use tungsten.
- a low resistance metal material such as 0 11 (copper) or 8 1 (aluminum) may be used.
- An insulator 650 is provided on the conductor 620 and the insulator 630.
- the insulator 650 can be provided using a material similar to that of the insulator 320. Further, the insulator 650 may function as a flattening film that covers the uneven shape below the insulator.
- a transistor including an oxide semiconductor variation in electric characteristics can be suppressed and reliability can be improved.
- a transistor including an oxide semiconductor with high on-state current can be provided.
- a transistor including an oxide semiconductor with low off-state current can be provided.
- a semiconductor device with reduced power consumption can be provided.
- miniaturization or high integration can be achieved.
- transistor 500 of the semiconductor device described in this embodiment is not limited to the above structure.
- structural examples that can be used for the transistor 500 will be described.
- FIG. 98 is a cross-sectional view of the portion indicated by dashed line Otsu 1-Otsu 2 in FIG.
- FIG. 9C is a cross-sectional view of the portion indicated by alternate long and short dash line 12 in FIG. In the top view of Fig. 98, some elements are omitted for clarity.
- the transistor 5108 and the insulator 511, insulator 512, insulator 5114, insulator 5116, and insulator 511 that function as an interlayer film are isolated. It shows body 580, insulator 582, and insulator 584.
- a conductor 5 4 6 (conductor 5 4 6 3 and conductor 5 4 6 13) which is electrically connected to the transistor 510 and functions as a contact plug, and a conductor 5 0 which functions as a wiring. 3 and are shown.
- the transistor 5108 includes a conductor 5600 (conductor 5603 and conductor 561013) which functions as a first gate electrode and a conductor 5600 which functions as a second gate electrode.
- 0 5 (conductor 5 0 5 3 and conductor 5 0 5 13), an insulator 5 50 functioning as a first gate insulating film, and a second gate insulating film ⁇ 0 2020/174303 ? €1/16 2020/051162 Insulator 5 2 1, Insulator 5 2 2 and Insulator 5 2 4 and oxide 5 30 with the region where channel is formed 5 30 ( Oxide 530 3, Oxide 530 13 and Oxide 530 ⁇ :), conductor 5 4 2 & that functions as one of the source or drain, and the other source or drain A conductor 5 4 2 13 and an insulator 5 7 4.
- the oxide 5350, the insulator 5500, and the conductor 5600 are converted into the insulator 5800. It is placed in the opening provided through the insulator 574.
- the oxide 5300, the insulator 550, and the conductor 5600 are the conductor 542, and It is placed between the conductor 5 4 2 b.
- the insulator 5 11 and the insulator 5 12 function as an interlayer film.
- silicon oxide, silicon oxynitride, silicon nitride oxide, aluminum oxide, hafnium oxide, tantalum oxide, zirconium oxide, lead zirconate titanate (chome), strontium titanate (3! chome 10 3 ) Or (8 3, !7) D 10 3 (6 £ X) etc. can be used as a single layer or a laminated layer.
- aluminum oxide, bismuth oxide, germanium oxide, niobium oxide, silicon oxide, titanium oxide, tungsten oxide, yttrium oxide, or zirconium oxide may be added to these insulators.
- these insulators may be nitrided. Silicon oxide, silicon oxynitride, or silicon nitride may be stacked on the above insulator.
- the insulator 511 preferably functions as a barrier film which suppresses impurities such as water or hydrogen from entering the transistor 5108 from the substrate side. Therefore, the insulator 511 is preferably made of an insulating material having a function of suppressing diffusion of impurities such as hydrogen atoms, hydrogen molecules, water molecules, and copper atoms (the above impurities are difficult to permeate). Alternatively, it is preferable to use an insulating material having a function of suppressing diffusion of oxygen (for example, at least one of an oxygen atom and an oxygen molecule) (the above oxygen is difficult to permeate). Further, for example, aluminum oxide or silicon nitride may be used as the insulator 5 11. With this configuration, impurities such as hydrogen and water can be suppressed from diffusing from the substrate side of the insulator 511 to the transistor 510 side.
- the insulator 5 12 preferably has a lower dielectric constant than the insulator 5 11.
- the parasitic capacitance generated between the wirings can be reduced.
- the conductor 5 03 is formed so as to be embedded in the insulator 5 12.
- the height of the upper surface of the conductor 5 03 and the height of the upper surface of the insulator 5 12 can be made approximately the same.
- the conductor 503 is shown as having a single layer structure, the present invention is not limited to this.
- the conductor 503 may have a multilayer film structure of two or more layers.
- the conductor 560 may function as a first gate (also referred to as a top gate) electrode.
- the conductor 505 is a second gate (also referred to as a bottom gate). It may function as an electrode.
- the threshold voltage of the transistor 5 10 A can be controlled by changing the potential applied to the conductor 505 independently of the potential applied to the conductor 560.
- the threshold voltage of the transistor 51 OA can be made higher than 0 V and the off-state current can be reduced. Therefore, applying a negative potential to the conductor 505 can reduce the drain current when the potential applied to the conductor 560 is OV, as compared to the case where no potential is applied.
- the conductor 505 and the conductor 560 in an overlapping manner, when a potential is applied to the conductor 560 and the conductor 505, the electric field generated from the conductor 560 and the conductor 505 The generated electric field can be connected to cover a channel formation region formed in the oxide 530.
- the channel formation region can be electrically surrounded by the electric field of the conductor 560 having a function as the first gate electrode and the electric field of the conductor 505 having a function as the second gate electrode. That is, as with the transistor 500 described above, s ur r o un d e d c h a nn e l
- the insulator 514 and the insulator 516 function as an interlayer film similarly to the insulator 511 or the insulator 511.
- the insulator 514 preferably functions as a barrier film which suppresses impurities such as water or hydrogen from entering the transistor 510A from the substrate side. With such a structure, diffusion of impurities such as hydrogen and water from the substrate side of the insulator 514 to the transistor 510 A side can be suppressed.
- the insulator 516 preferably has a lower dielectric constant than the insulator 514. By using a material having a low dielectric constant as the interlayer film, it is possible to reduce the parasitic capacitance generated between the wirings.
- the conductor 505 functioning as a second gate is in contact with the inner walls of the openings of the insulator 514 and the insulator 516 to form the conductor 505a, and further, the conductor 505b is formed inside.
- the heights of the top surfaces of the conductors 505a and 505b and the top surfaces of the insulators 5 16 can be made approximately the same.
- the transistor 510 A has a structure in which the conductor 505 a and the conductor 505 b are stacked; however, the present invention is not limited to this.
- the conductor 505 may have a single-layer structure or a stacked structure including three or more layers.
- the conductor 505a is preferably a conductive material having a function of suppressing diffusion of impurities such as hydrogen atoms, hydrogen molecules, water molecules, and copper atoms (the above impurities are less likely to pass through). Or oxygen
- a conductive material having a function of suppressing diffusion of for example, at least one of oxygen atom, oxygen molecule, etc.
- the function of suppressing diffusion of impurities or oxygen is a function of suppressing diffusion of any one or all of the above impurities and oxygen.
- the conductor 505a since the conductor 505a has a function of suppressing diffusion of oxygen, it is possible to prevent the conductor 505b from being oxidized and being reduced in conductivity.
- the conductor 5 05 13 is mainly composed of tungsten, copper, or aluminum. It is preferable to use a highly conductive material. In that case, the conductor 503 does not necessarily have to be provided.
- the conductor 5053 is illustrated as a single layer, it may have a stacked structure. For example, a stack of titanium or titanium nitride and the above conductive material may be used.
- the insulator 5 2 1, the insulator 5 2 2, and the insulator 5 2 4 have a function as a second gate insulating film.
- the insulator 52 2 preferably has a barrier property.
- the insulator 5 22 2 having a barrier function functions as a layer which suppresses entry of impurities such as hydrogen from the peripheral portion of the transistor 5 10 8 into the transistor 5 10 8.
- Insulators 52 2 are, for example, aluminum oxide, hafnium oxide, oxides containing aluminum and hafnium (hafnium aluminate), tantalum oxide, zirconium oxide, lead zirconate titanate (chome), strontium titanate (31 2 It is preferable to use an insulator containing a so-called 11 1 ⁇ 11 — material such as ⁇ D 10 3 ) or (8 3, !...) D 10 3 (6 £ X) in a single layer or a laminated layer. As transistors become finer and more highly integrated, thinner gate insulating films may cause problems such as leakage current. By using 11 1 ⁇ 11 — material for the insulator that functions as the gate insulating film, it is possible to reduce the gate potential during transistor operation while maintaining the physical film thickness.
- the insulator 5 21 is preferably thermally stable.
- silicon oxide and silicon oxynitride are preferable because they are thermally stable.
- an insulator made of a material of 11 1 ⁇ 11 with silicon oxide or silicon oxynitride, it is possible to obtain an insulator 5 2 1 having a laminated structure which is thermally stable and has a high relative dielectric constant.
- the second gate insulating film has a three-layer stacked structure in FIGS. 98, 93, and 90, it may have a single-layer structure or a stacked structure of two or more layers.
- the laminated structure is not limited to the same material, and may be a laminated structure made of different materials.
- the oxide 5300 having a region functioning as a channel formation region includes oxide 5300&, oxide 5303 on oxide 5303, and oxide on oxide 5300b. 5 30. And,. By having the oxide 5300 & under the oxide 5310, it suppresses the diffusion of impurities from the structure formed below the oxide 5300 & into the oxide 5310. be able to. Further, by having the oxide 5300 on the oxide 5301, the diffusion of impurities from the structure formed above the oxide 5300 to the oxide 5301. Can be suppressed.
- the oxide 530 an oxide semiconductor which is one of the above-described metal oxides can be used.
- the oxide 5300 is preferably provided in the opening provided in the insulator 580 with the insulator 574 interposed therebetween.
- the insulator 574 has a barrier property, diffusion of impurities from the insulator 580 into the oxide 530 can be suppressed. ⁇ 0 2020/174303 ? €1/16 2020/051162
- One of the conductor 5 4 2 3 and the conductor 5 4 2 13 functions as a source electrode and the other functions as a drain electrode.
- Conductors 5 4 2 3 and conductors 5 4 2 13 are metals such as aluminum, titanium, chromium, nickel, copper, yttrium, zirconium, molybdenum, silver, tantalum, or tungsten, or their main components. Can be used.
- a metal nitride film such as tantalum nitride is preferable because it has a barrier property against hydrogen or oxygen and has high oxidation resistance.
- a stacked structure of two or more layers may be used.
- a tantalum nitride film and a tungsten film may be stacked.
- a titanium film and an aluminum film may be laminated.
- a two-layer structure in which an aluminum film is laminated on a tungsten film a two-layer structure in which a copper film is laminated on a copper-magnesium aluminum alloy film, a two-layer structure in which a copper film is laminated on a titanium film, and a tantasten film is formed.
- a two-layer structure in which copper films are laminated may be used.
- a titanium film or a titanium nitride film and a three-layer structure in which an aluminum film or a copper film is stacked on the titanium film or the titanium nitride film and a titanium film or a titanium nitride film is further formed thereon There is a three-layer structure in which a film or a molybdenum nitride film, an aluminum film or a copper film are stacked over the molybdenum film or the molybdenum nitride film, and a molybdenum film or a molybdenum nitride film is formed thereover.
- a transparent conductive material containing indium oxide, tin oxide, or zinc oxide may be used.
- a barrier layer may be provided on the conductor 5 42.
- the barrier layer it is preferable to use a substance that has a barrier property with respect to oxygen or hydrogen. With this structure, it is possible to suppress oxidation of the conductor 5 4 2 when forming the insulator 5 74.
- a metal oxide can be used for the barrier layer.
- an insulating film having a barrier property against oxygen or hydrogen such as aluminum oxide, hafnium oxide, or gallium oxide.
- silicon nitride formed by the XX method may be used.
- the conductor 5 42 By having a barrier layer, it is possible to widen the range of selection of materials for the conductor 5 42.
- a material such as tungsten or aluminum which has low oxidation resistance and high conductivity can be used.
- a conductor which can be easily formed or processed can be used.
- the insulator 550 functions as a first gate insulating film.
- the insulator 550 is preferably provided in the opening provided in the insulator 580 with the oxide 530 and the insulator 574 interposed therebetween.
- the insulator 550 may have a stacked-layer structure like the second gate insulating film.
- the insulator that functions as a gate insulating film is made of 11 1 ⁇ 11—material and thermally stable. By using a layered structure with other materials, it is possible to reduce the gate potential during transistor operation while maintaining the physical film thickness. Further, it is possible to obtain a laminated structure that is thermally stable and has a high relative dielectric constant.
- the conductor 560 functioning as the first gate electrode has a conductor 560a and a conductor 560b over the conductor 560a.
- the conductor 560a is preferably formed using a conductive material having a function of suppressing diffusion of impurities such as hydrogen atoms, hydrogen molecules, water molecules, and copper atoms.
- a conductive material having a function of suppressing diffusion of oxygen eg, at least one of an oxygen atom and an oxygen molecule.
- the conductor 560a has a function of suppressing diffusion of oxygen, the material selectivity of the conductor 560b can be improved. That is, by having the conductor 560 a, oxidation of the conductor 560 b can be suppressed and a decrease in conductivity can be prevented.
- a conductive material having a function of suppressing diffusion of oxygen for example, tantalum, tantalum nitride, ruthenium, ruthenium oxide, or the like is preferably used.
- the conductor 560a an oxide semiconductor which can be used as the oxide 530 can be used. In that case, by forming a film of the conductor 560b by a sputtering method, the electric resistance value of the conductor 560a can be reduced to form a conductor. This can be called an OC (OxideConductor) electrode.
- the conductor 56 O b it is preferable to use a conductive material containing tungsten, copper, or aluminum as a main component. Since the conductor 560 functions as a wiring, it is preferable to use a conductor having high conductivity. For example, a conductive material containing tungsten, copper, or aluminum as a main component can be used. Further, the conductor 560b may have a laminated structure, for example, a laminate of titanium or titanium nitride and the above conductive material.
- An insulator 574 is placed between the insulator 580 and the transistor 510A.
- an insulating material having a function of suppressing diffusion of impurities such as water or hydrogen and oxygen is preferable.
- impurities such as water or hydrogen and oxygen
- metal oxides such as magnesium oxide, gallium oxide, germanium oxide, yttrium oxide, zirconium oxide, lanthanum oxide, neodymium oxide or tantalum oxide, silicon nitride oxide or silicon nitride can be used. it can.
- impurities such as water and hydrogen included in the insulator 580 can be suppressed from diffusing into the oxide 530b through the oxide 530c and the insulator 550.
- the insulator 580, the insulator 582, and the insulator 584 function as an interlayer film.
- the insulator 582 preferably functions as a barrier insulating film which suppresses impurities such as water or hydrogen from entering the transistor 510A from the outside. ⁇ 0 2020/174303 ? €1/16 2020/051162
- the insulator 580 and the insulator 584 preferably have a lower dielectric constant than that of the insulator 582, like the insulator 516.
- the parasitic capacitance generated between the wirings can be reduced.
- the transistor 510 is electrically connected to another structure through a plug or wiring such as an insulator 580, an insulator 582, and a conductor 546 embedded in the insulator 584. You may connect to each other.
- a conductive material such as a metal material, an alloy material, a metal nitride material, or a metal oxide material is formed in a single layer or a laminated layer.
- a high melting point material such as tungsten or molybdenum, which has both heat resistance and conductivity.
- a low resistance conductive material such as aluminum or copper. The wiring resistance can be lowered by using a low resistance conductive material.
- the conductor 546 by using a stacked structure of tungsten nitride or the like, which has a barrier property against hydrogen and oxygen, and tungsten, which has high conductivity, It is possible to suppress the diffusion of impurities from the outside while keeping it.
- a semiconductor device including a transistor including an oxide semiconductor with high on-state current can be provided.
- a semiconductor device including a transistor including an oxide semiconductor with low off-state current can be provided.
- FIG. 108 is a top view of the transistor 5108. Is a cross-sectional view of the portion indicated by dashed-dotted line Otsu 1-Otsu 2 in Fig. 108.
- Fig. 100 is a cross-sectional view of the portion indicated by dashed-dotted line 1-2 in Fig. 108. In the top view of FIG. 108, some elements are omitted for clarity.
- the transistor 5108 is a modification of the transistor 5108. Therefore, in order to prevent repetition of description, points different from the transistor 510 will be mainly described.
- Transistor 5 108 is composed of conductor 5 4 2 (conductor 5 4 2 3 and conductor 5 4 2 13), oxide 5 3 0 ⁇ , insulator 5 5 0, and conductor 5 6 0. , Have an overlapping region. With such a structure, a transistor with high on-state current can be provided. In addition, a transistor with high controllability can be provided.
- the conductor 560 functioning as the first gate electrode includes the conductor 56033 and the conductor 560 over the conductor 56033.
- a conductive material having a function of suppressing diffusion of impurities such as hydrogen atoms, hydrogen molecules, water molecules, and copper atoms as in the case of the conductor 550&3.
- a conductive material having a function of suppressing diffusion of oxygen for example, at least one of oxygen atom, oxygen molecule, etc.).
- the conductor 560 3 has a function of suppressing diffusion of oxygen, the material selectivity of the conductor 560 b can be improved. In other words, by having the conductor 5603, the oxidation of the conductor 56013 can be suppressed and a decrease in conductivity can be prevented.
- the insulator 574 is preferably provided so as to cover the top surface and the side surface of the conductor 560, the side surface of the insulator 550, and the side surface of the oxide 530.
- the insulator 574 may be formed using an impurity such as water or hydrogen, or an insulating material having a function of suppressing diffusion of oxygen.
- an impurity such as water or hydrogen
- an insulating material having a function of suppressing diffusion of oxygen For example, it is preferable to use aluminum oxide or hafnium oxide.
- magnesium oxide, gallium oxide, germanium oxide, yttrium oxide, zirconium oxide, lanthanum oxide, metal oxide such as neodymium oxide or tantalum oxide, silicon nitride oxide, or silicon nitride can be used. ..
- oxidation of the conductor 5600 can be suppressed. Further, with the insulator 574, diffusion of impurities such as water and hydrogen included in the insulator 580 to the transistor 518 can be suppressed.
- an insulator 5 7 6 having a barrier property may be arranged between the conductor 5 4 6 and the insulator 5 80. ..
- an insulator 576 By providing the insulator 576, it is possible to prevent the oxide of the insulator 5880 from reacting with the conductor 546 and oxidizing the conductor 546.
- the range of selection of the material of the conductor used for the plug or the wiring can be widened.
- a semiconductor device with low power consumption can be provided by using a metal material with high conductivity while having a property of absorbing oxygen for the conductor 546.
- a material such as tungsten or aluminum that has low oxidation resistance and high conductivity can be used.
- a conductor which can be easily formed or processed can be used.
- FIG. 11 18 is a top view of the transistor 5 10 (3.
- Figure 18 is a cross-sectional view of the portion indicated by dashed-dotted line Otsu 1-Otsu 2 in Fig. 118.
- Fig. 110 is a cross-sectional view of the portion indicated by alternate long and short-dotted line 1-2 in Fig. 118. In the top view of Fig. 118, some elements are omitted for clarity.
- the transistor 510 is a modification of the transistor 510. Therefore, in order to prevent repetition of description, points different from the transistor 510 will be mainly described.
- Transistor 5 10 (3 in Figure 1 1 8, Figure 1 1 8 and Figure 1 1 (3 has conductor 5 4 7 3 placed between conductor 5 4 2 3 and oxide 5 3 0 13).
- Conductor 5 4 7 13 is placed between conductor 5 4 2 b and oxide 5 3 0 13 ⁇ 02020/174303 ? €1/162020/051162 It is located.
- the conductor 5423 (conductor 54213) extends over the top surface of the conductor 5473 (conductor 54713) and the side surface on the conductor 560 side and has a region in contact with the top surface of the oxide 530.
- the conductor 547 a conductor that can be used for the conductor 542 may be used.
- the film thickness of the conductor 547 is preferably at least larger than that of the conductor 542.
- the conductor 542 can be closer to the conductor 560 than the transistor 510.
- the end of the conductor 5423 and the end of the conductor 54213 can overlap with the end of the conductor 560.
- the substantial channel length of the transistor 5100 can be shortened, and the on-state current and frequency characteristics can be reduced. Can be improved.
- the conductor 5473 (conductor 54713) is preferably provided so as to overlap with the conductor 5423 (conductor 54213).
- the conductor 5473 (conductor 54713) functions as a stopper and the oxide 53013 is over-etched in the etching for forming the opening for filling the conductor 5463 (conductor 54613). Can be prevented.
- the transistor 510 may have a structure in which the insulator 545 is placed in contact with the insulator 544.
- the insulator 544 includes It is preferable to function as a barrier insulating film which suppresses impurities such as water or hydrogen and excess oxygen from entering the transistor 5100 from the insulator 580.
- the insulator 545 the insulator 544 is preferably used.
- a nitride insulator such as aluminum nitride, aluminum titanium nitride, titanium nitride, silicon nitride, or silicon nitride oxide may be used as the insulator 544.
- the transistor 510 shown in FIGS. 98, 98, and 108 is provided with a single-layer structure of the conductor 505).
- an insulating film to be the insulator 516 is formed on the patterned conductor 505, and the upper part of the insulating film is exposed until the upper surface of the conductor 505 is exposed. It may be removed by using a method or the like. Here, it is preferable to improve the flatness of the upper surface of the conductor 505.
- the average surface roughness (scale 3) of the top surface of the conductor 505 may be set to 1 111x1 or less, preferably 0.5111x1 or less, and more preferably 0.31111x1 or less. Accordingly, the flatness of the insulating layer formed over the conductor 505 can be improved and the crystallinity of the oxide 53013 and the oxide 530 can be improved.
- FIG. 128 is a top view of the transistor 510.
- FIG. 28 is a cross-sectional view of the portion indicated by dashed-dotted line Otsu 1-Otsu 2.
- Fig. 120 is a cross-sectional view of the portion indicated by dashed-dotted line 1 12 in Fig. 12-8. In the top view of FIG. 1, some elements are omitted for clarity.
- the transistor 5100 is a modification of the above transistor. Therefore, in order to prevent repeated explanation, The differences from the above transistor will be mainly described.
- the conductor 503 is not provided and the conductor 505 functioning as the second gate is also functioned as a wiring.
- the insulator 550 is provided over the oxide 530 c, and the metal oxide 552 is provided over the insulator 550.
- the conductor 560 is provided over the metal oxide 552, and the insulator 570 is provided over the conductor 560.
- an insulator 571 is provided over the insulator 570.
- the metal oxide 552 preferably has a function of suppressing oxygen diffusion.
- the metal oxide 552 which suppresses diffusion of oxygen between the insulator 550 and the conductor 560, diffusion of oxygen into the conductor 560 is suppressed. That is, a decrease in the amount of oxygen supplied to the oxide 530 can be suppressed. In addition, oxidation of the conductor 560 due to oxygen can be suppressed.
- the metal oxide 552 may have a function as a part of the first gate.
- an oxide semiconductor which can be used as the oxide 530 can be used as the metal oxide 552.
- the electric resistance value of the metal oxide 552 can be reduced to form a conductive layer. This can be called an OC (OxideConductor) electrode.
- the metal oxide 552 may have a function as part of the gate insulating film. Therefore, when silicon oxide, silicon oxynitride, or the like is used for the insulator 550, the metal oxide 552 is preferably a metal oxide which is a high-k material with a high relative dielectric constant. With this laminated structure, a laminated structure that is stable to heat and has a high relative dielectric constant can be obtained. Therefore, it is possible to reduce the gate potential applied during transistor operation while maintaining the physical film thickness. In addition, the equivalent oxide thickness (EOT) of the insulating layer that functions as the gate insulating film can be reduced.
- EOT equivalent oxide thickness
- the metal oxide 552 is shown as a single layer, but it may have a laminated structure of two or more layers.
- a metal oxide functioning as part of the gate electrode and a metal oxide functioning as part of the gate insulating film may be stacked.
- the on-state current of the transistor 510D can be improved without weakening the influence of the electric field from the conductor 560.
- the physical thickness of the insulator 550 and the metal oxide 552 keeps the distance between the conductor 560 and the oxide 530, so that the conductivity can be improved. Leakage current between the body 560 and the oxide 530 can be suppressed. Therefore, by providing a laminated structure of the insulator 550 and the metal oxide 552, the physical distance between the conductor 560 and the oxide 530 and the electric field applied from the conductor 560 to the oxide 530 can be obtained. The strength can be easily adjusted appropriately.
- the metal oxide 552 can be used as the metal oxide 552 by lowering the resistance of an oxide semiconductor that can be used for the oxide 530.
- an oxide semiconductor that can be used for the oxide 530.
- hafnium oxide an oxide containing aluminum and hafnium (hafnium aluminum oxide), which is an insulating layer containing one or both oxides of aluminum and hafnium.
- hafnium aluminate has higher heat resistance than a hafnium oxide film. Therefore, it is preferable that it is difficult to crystallize in the heat treatment in the subsequent step.
- the metal oxide 5522 is not an essential component. It may be appropriately designed according to the desired transistor characteristics.
- an insulating material having a function of suppressing permeation of impurities such as water or hydrogen and oxygen is preferably used.
- impurities such as water or hydrogen from above the insulator 570 from mixing into the oxide 530 through the conductor 560 and the insulator 550.
- the insulator 5 71 functions as a hard mask.
- the side surface of the conductor 5600 is substantially vertical when the conductor 5600 is applied, specifically, the angle formed between the side surface of the conductor 5600 and the substrate surface.
- the insulator 571 may also serve as a barrier layer by using an insulating material having a function of suppressing permeation of impurities such as water or hydrogen and oxygen. In that case, the insulator 570 need not be provided.
- insulator 571 As a hard mask, insulator 570, conductor 5600, metal oxide 552, insulator 5500, and part of oxide 5300 are selectively used. By removing, these side surfaces can be made to substantially coincide with each other, and a part of the surface of the oxide 5313 can be exposed.
- the transistor 5100 has a region 5313 and a region 5 ⁇ in a part of the exposed surface of the oxide 5313.
- One of the region 5 3 1 & or the region 5 3 1 b functions as a source region and the other functions as a drain region.
- Regions 5 3 1 & and regions 5 3 1 13 are formed on the exposed oxide 5 3 0 13 surface using, for example, an ion implantation method, an ion doping method, a plasma immersion ion implantation method, or a plasma treatment. It can be realized by introducing an impurity element such as phosphorus or boron. In this Embodiment and the like, the “impurity element” means an element other than the main component element.
- the region 5313 and the region 5313 can be formed in a self-aligned manner. Therefore, the region 5 3 1 & and/or the region 5 3 1 13 and the conductor 5600 do not overlap with each other, so that parasitic capacitance can be reduced. In addition, no offset region is formed between the channel forming region and the source/drain region (region 5313 or region 5313). By forming regions 5 3 1 3 and regions 5 3 1 13 in a self-aligned manner, it is possible to increase the on-current, reduce the threshold voltage, and improve the operating frequency.
- an offset region may be provided between the channel formation region and the source/drain region in order to further reduce the off-state current.
- the offset region is a region having a high electric resistivity and is a region in which the above-mentioned impurity element is not introduced.
- the offset region can be formed by introducing the above-mentioned impurity element after forming the insulator 575.
- the insulator 5 7 5 also functions as a master, like the insulator 5 7 1. Therefore, an impurity element is not introduced into a region of the oxide 5301 which overlaps with the insulator 575, so that the electric resistivity of the region can be kept high.
- an insulator 5750 is provided on the side surface of the insulator 570, the conductor 560, the metal oxide 552, the insulator 550, and the oxide 530.
- the insulator 575 is preferably an insulator having a low relative dielectric constant.
- the insulator 575 when silicon oxide, silicon oxynitride, silicon nitride oxide, or silicon oxide having holes is used for the insulator 575, an excess oxygen region can be easily formed in the insulator 575 in a later step. preferable. Further, silicon oxide and silicon oxynitride are preferable because they are thermally stable. Further, the insulator 575 preferably has a function of diffusing oxygen.
- the transistor 5100 has the insulator 575 and the insulator 574 over the oxide 5300.
- the insulator 574 is preferably formed by a sputtering method. By using the sputtering method, an insulator containing few impurities such as water or hydrogen can be formed. For example, aluminum oxide is preferably used as the insulator 574.
- an oxide film formed by a sputtering method may extract hydrogen from a structure to be formed. Therefore, the insulator 5 7 4 can absorb hydrogen and water from the oxide 5 30 and the insulator 5 75, so that the hydrogen concentration in the oxide 5 30 and the insulator 5 7 5 can be reduced. ..
- Figure 138 is a top view of the transistor 510 £.
- Fig. 138 is a cross-sectional view of the part indicated by dashed line Otsu 1-Otsu 2 in Fig. 138.
- Fig. 13 (3 is a cross-sectional view of the portion indicated by alternate long and short dash line 1-2 in Fig. 13-8. In the top view, some elements are omitted for clarity.
- Transistor 51 0 E is a modification of the above transistor. Therefore, in order to prevent the description from being repeated, differences from the above transistor will be mainly described.
- the conductor 542 is not provided and a region 531 a and a region 531 b are provided in a part of the exposed surface of the oxide 530 b.
- One of the region 53 1 a and the region 531 b functions as a source region, and the other functions as a drain region.
- the insulator 573 is provided between the oxide 530 b and the insulator 574.
- Regions 53 1 regions 531 a and 531 b shown in FIGS. 13A, 13 B, and 13 C are regions in which the following elements are added to the oxide 530 b.
- the region 531 can be formed by using a dummy gate, for example.
- a dummy gate may be provided over the oxide 530b, the dummy gate may be used as a mask, and an element that reduces the resistance of the oxide 530b may be added. That is, the element is added to a region where the oxide 530 does not overlap with the dummy gate, so that the region 531 is formed.
- the method of adding the element is as follows: an ion implantation method in which an ionized raw material gas is added by mass separation, an ion doping method in which an ionized raw material gas is added without mass separation, and a plasma immersion ion implantation method. The method etc. can be used.
- the concentration of the element may be measured by secondary ion mass spectrometry (SIMS: Second a r y Ion Ma s s Spec t r ome t r y) or the like.
- boron and phosphorus are preferable because amorphous silicon or low temperature polysilicon production line equipment can be used. Existing equipment can be converted, and capital investment can be suppressed.
- an insulating film to be the insulator 573 and an insulating film to be the insulator 574 may be formed over the oxide 530b and the dummy gate.
- the insulating film to be the insulator 580 can be subjected to CMP (Chemical Mechanical Polishing) treatment. A part of the insulating film to be the insulator 580 is removed to expose the dummy gate. Then, when removing the dummy gate, a part of the insulator 573 which is in contact with the dummy gate may be removed.
- CMP Chemical Mechanical Polishing
- Insulator 5 7 4 and insulator 5 7 3 are exposed on the side surface of the opening provided in insulator 5 80, and the bottom of the opening Partly exposes a region 531 provided in the oxide 5300b.
- an oxide film to be the oxide 530, an insulating film to be the insulator 550, and a conductive film to be the conductor 560 are sequentially formed in the opening, and then the insulator 580 By removing the oxide film that becomes oxide 530, the insulating film that becomes insulator 550, and part of the conductive film that becomes conductor 560
- the transistor shown in Fig. 1 3 3 and Fig. 1 3 can be formed.
- the insulator 573 and the insulator 574 are not essential components. It may be appropriately designed depending on the desired transistor characteristics.
- the transistors shown in Fig. 13 8, Fig. 13 8, and Fig. 13 can be used for existing devices, and further, since the conductor 5 42 is not provided, the cost can be reduced. ..
- Figure 144 is a top view of the transistor 510F.
- Figure 148 is a cross-sectional view of the part indicated by dashed-dotted line Otsu 1-Otsu 2 in Fig. 148.
- FIG. 140 is a cross-sectional view of the portion indicated by alternate long and short dash line 1-2 in FIG. In the top view of Fig. 148, some elements are omitted for clarity.
- the transistor 510F is a modification of the transistor 510. Therefore, in order to prevent the description from being repeated, differences from the above transistor will be mainly described.
- a part of the insulator 574 is provided in an opening provided in the insulator 580 and is provided so as to cover a side surface of the conductor 560.
- an opening is formed by removing part of the insulator 580 and the insulator 574.
- an insulator 576 having a barrier property may be arranged between the conductor 5 4 6 and the insulator 5 8 0. ..
- an insulator 576 having a barrier property (insulators 5 7 6 3 and insulators 5 7 6 13) may be arranged between the conductor 5 4 6 and the insulator 5 8 0. ..
- an oxide semiconductor when used as the oxide 530, it preferably has a stacked structure of a plurality of oxide layers in which the atomic ratio of each metal atom is different.
- the atomic number ratio of the element N4 in the constituent elements is It is preferably larger than the atomic ratio of the element N4.
- the atomic ratio of the element N4 to I 11 is calculated as follows: It is preferably larger than the ratio.
- the atomic ratio of I 11 to the element was calculated from the atomic ratio of I 11 to the element N4 of the metal oxide used for the oxide 5303. It is preferably large.
- the oxide 5300 a metal oxide that can be used for the oxide 5303 or the oxide 5313 can be used.
- Oxide 5303, Oxide 53013, and Oxide 530 Preferably has crystallinity, and it is particularly preferable to use ⁇ 88 ⁇ 108.
- Oxide having crystallinity such as ⁇ 88 ⁇ 10 has few impurities and defects (such as oxygen deficiency) and has a highly crystalline and dense structure. Therefore, extraction of oxygen from the oxide 5313 by the source electrode or the drain electrode can be suppressed. This makes it possible to reduce the extraction of oxygen from the oxide 531013 even when heat treatment is performed, and therefore, the tungsten transistor 510F is resistant to high temperatures in the manufacturing process (so-called thermal budget). It is stable.
- the oxide 5300 may be a single layer of the oxide 5300b.
- the oxide 5300 is a stack of the oxide 5303, the oxide 5313, and the oxide 5300, the oxide 5303 and the oxide 5300 are laminated.
- the energy at the bottom of the conduction band of the oxide is preferably higher than the energy at the bottom of the conduction band of the oxide 531013.
- the electron affinity of the oxide 5303 and the oxide 5300 is smaller than the electron affinity of the oxide 5300b.
- oxide 5300 It is preferable to use a metal oxide that can be used as the oxide 5300.
- the atomic ratio of the element N4 in the constituent elements is the atom number of the element N4 in the constituent elements in the metal oxide used for the oxide 5310. It is preferably larger than the number ratio. Further, in the metal oxide used for the oxide 5300, the atomic ratio of the element N4 to I 11 is larger than the atomic ratio of the element N4 to I 11 in the metal oxide used for the oxide 5310. Is preferred. In addition, in the metal oxide used for the oxide 5301, the atomic ratio of I 11 to the element N4 is oxide 5300. It is preferable that the ratio of the number of atoms of I 11 to the element in the metal oxide used for is larger than that of I 11.
- the energy and potential at the lower end of the conduction band change gently.
- the oxide 5 3 0 3 the energy level of the conduction band minimum in oxide 5 3 0 1 3, and oxide 5 3 0 junction ⁇ refers continuously varying or continuous bonding result also be able to.
- the oxide 5303 and the oxide 5303, and the oxide 5300b and the oxide 5300 have a common element other than oxygen (as the main component). , It is possible to form a mixed layer with low defect density.
- oxide As oxide 5303 and oxide 5300, 1 11-0 Oxide, 0 An oxide, gallium oxide, or the like may be used.
- the oxide 5300 may have a laminated structure.
- a stacked structure with gallium oxide over 311 oxide can be used.
- a laminated structure of 1 11 — 0 3 — 11 oxide and I 11 -free oxide is referred to as oxide 5 30. You may use as.
- oxide 11 5: 1 :3 [atomic ratio] or its vicinity composition, or 10: 1 :3 [atomic ratio] or its vicinity metal oxide, or I 11 — 11 oxide You can use it.
- oxide 530 a metal oxide that can be used for the oxide 5303 or the oxide 53013 may be used.
- the composition in the vicinity includes the range of ⁇ 30% of the desired atomic number ratio.
- the oxide 5300 may have a laminated structure of two or more layers.
- the oxide 530 is used.
- a metal oxide having a composition of 1 11 :03 :211 5 :1 :3 [ratio of atomic numbers] or its vicinity, or a composition of 10:1:3 [atomic ratio] or its vicinity
- Oxide 5 303, Oxide 530 With the above structure, the defect level densities at the interface between the oxide 5303 and the oxide 530 b and the interface between the oxide 5 30 b and the oxide 5300 can be lowered. Therefore, the influence of interface scattering on carrier conduction is reduced, and the transistor 510F can have high on-state current and high frequency characteristics.
- the constituent elements of the oxide 5300 are also included. However, it is expected to suppress the diffusion to the insulator 550 side. More specifically, oxide 530.
- a metal oxide which functions as an oxide semiconductor is preferably used.
- a metal oxide having a band gap of 26 V or higher, preferably 2.56 V or higher as a metal oxide serving as a channel formation region of the oxide 530.
- the off-state current of the transistor can be reduced by using the metal oxide having a wide band gap.
- a semiconductor device with low power consumption can be provided by using such a transistor.
- FIG. 15 shows an example in which the conductor 692 is provided on the insulator 650 in the semiconductor device shown in FIG.
- the conductor 692 is formed so as to cover one surface of the semiconductor device.
- the conductor 692 may have an opening.
- a conductor electrically connected to a conductor below the insulator 650 may be provided in the opening.
- a metal can be used as the conductor 692.
- As the conductor 692 for example, titanium, titanium nitride, titanium oxide or the like can be used.
- the conductor 692 has a function of blocking or weakening an electromagnetic wave from the outside as compared with the semiconductor device. Further, the conductor 692 has a function of diffusing and releasing static electricity or preventing localization of charges. By providing the conductor 692, the operation of the semiconductor device can be further stabilized.
- FIG. 16 shows an example in which an insulator 693 is provided between an insulator 650 and a conductor 692.
- the insulator 693 for example, a structure body in which a fibrous body is impregnated with an organic resin can be used.
- glass fibers may be used as the fibrous body.
- a brominated epoxy resin may be used as the organic resin.
- the oxide 5 30 it is preferable to use a metal oxide which functions as an oxide semiconductor.
- the metal oxide applicable to the oxide 530 according to the present invention will be described below.
- the metal oxide preferably contains at least indium or zinc. In particular, it is preferable to contain indium and zinc. In addition to these, it is preferable that gallium, yttrium, tin, etc. are contained. Further, one or more selected from boron, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten, magnesium and the like may be contained.
- the metal oxide is an In-M-Zn oxide containing indium, the element M, and zinc is considered.
- the element M is aluminum, gallium, yttrium, or tin.
- Other applicable elements for M are boron, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten, and Madanesium.
- metal oxides containing nitrogen may be collectively referred to as metal oxides (meta x i d e ). Further, the nitrogen-containing metal oxide may be referred to as a metal oxynitride (meta x yn i t r i d e ).
- Oxide semiconductors are classified into single crystal oxide semiconductors and other non-single crystal oxide semiconductors.
- non-single-crystal oxide semiconductors include CAAC-OS, polycrystalline oxide semiconductors, Examples include nc-OS (nanocrystalline oxides semiconductor), pseudo-amorphous oxide semiconductors (a-like OS: amorphous ikeoxide semiconductor), and amorphous roxide semiconductors.
- the CAAC-OS has a c-axis-oriented structure, and a plurality of nanocrystals are connected in the ab plane direction, resulting in a strained crystal structure.
- strain refers to a portion where the orientation of the lattice arrangement changes between a region where the lattice arrangements are aligned and another region where the lattice arrangements are aligned in the region where multiple nanocrystals are connected. ..
- nanocrystals are basically hexagonal, they are not limited to regular hexagons and may be non-regular hexagons.
- the strain may have a lattice arrangement such as a pentagon and a heptagon. Note that CAAC
- the CAAC-OS is formed by stacking a layer containing indium and oxygen (hereinafter referred to as an In layer) and a layer containing element M, zinc, and oxygen (hereinafter referred to as a (M, Zn) layer). It tends to have a layered crystal structure (also referred to as a layered structure). Note that indium and the element M can be replaced with each other, and when the element M of the (M, Zn) layer is replaced with indium, it can be expressed as an (In, M, Zn) layer. Further, when the indium of the I n layer is replaced with the element M, it can be expressed as an (I n, M) layer.
- C AAC-OS is a highly crystalline metal oxide.
- CAAC-OS since it is difficult to confirm a clear grain boundary, it can be said that the decrease in electron mobility due to the grain boundary does not easily occur.
- the crystallinity of metal oxides may decrease due to the inclusion of impurities and the formation of defects.
- — OS can be said to be a metal oxide with few impurities and defects (such as oxygen deficiency). Therefore, the metal oxide having CAAC-OS has stable physical properties. Therefore, metal oxides with CAAC-OS are highly heat resistant and highly reliable.
- n c-OS has a periodic atomic arrangement in a minute region (for example, a region of 1 nm or more and 10 nm or less, particularly a region of 1 nm or more and 3 nm or less).
- a minute region for example, a region of 1 nm or more and 10 nm or less, particularly a region of 1 nm or more and 3 nm or less.
- n c-OS there is no regularity in crystal orientation between different nanocrystals. Therefore, no orientation is seen in the entire film. Therefore, n c-OS may be indistinguishable from a -1 i ke OS or amorphous oxide semiconductor depending on the analysis method.
- I GZO In—Ga—Zn oxide
- I GZO In—Ga—Zn oxide
- a large crystal here, a crystal of several mm or a few cm.
- 3-11 1 ⁇ 60 is a metal oxide having a structure between 110- and an amorphous oxide semiconductor.
- ⁇ has a void or a low density region. That is, ⁇ has low crystallinity compared to 110- ⁇ and 88081.
- Oxide semiconductors have various structures and have different characteristics.
- the oxide semiconductor of the embodiment of the present invention may have two or more kinds of amorphous oxide semiconductors, polycrystalline oxide semiconductors, and 3-1.
- the above defect level may include a trap level.
- the charge trapped in the trap level of the metal oxide takes a long time to disappear and may behave as if it were a fixed charge. Therefore, a transistor including a metal oxide with a high trap level density in a channel formation region may have unstable electrical characteristics.
- the crystallinity of the channel formation region may be low, and the crystallinity of the oxide provided in contact with the channel formation region may be low. .. If the crystallinity of the channel formation region is low, the stability or reliability of the transistor tends to deteriorate. Further, when the crystallinity of the oxide provided in contact with the channel formation region is low, an interface position is formed, which might deteriorate the stability or reliability of the transistor.
- Impurities include hydrogen, nitrogen, alkali metals, alkaline earth metals, iron, nickel and silicon.
- the concentration of the above impurities obtained by elemental analysis using is less than or equal to 1.0 & 10 111 111.
- the concentration ratio of the above impurities to the element in the channel formation region of the oxide semiconductor and in the vicinity thereof is less than 0. 10, preferably 0. It should be less than .05.
- the concentration may be a concentration in the same region as the region where the concentration of the impurity is calculated, or may be a concentration in the oxide semiconductor. ⁇ 0 2020/174303 ? €1/16 2020/051162
- a metal oxide having a reduced impurity concentration has low defects and potential densities, so traps and potential densities may be low.
- V 0 H functions as a donor and an electron that is a carrier may be generated.
- a part of hydrogen may be bonded to oxygen which is bonded to a metal atom to generate an electron which is a carrier.
- a transistor including an oxide semiconductor which contains a large amount of hydrogen is likely to have normally-on characteristics. Further, hydrogen in an oxide semiconductor easily moves due to stress such as heat or an electric field; therefore, when a large amount of hydrogen is contained in the oxide semiconductor, reliability of the transistor might be deteriorated.
- V 0 H in the metal oxide be reduced as much as possible to make highly purified intrinsic or substantially highly purified intrinsic.
- impurities such as moisture and hydrogen in the oxide semiconductor are removed (sometimes referred to as dehydration or dehydrogenation treatment.) Then, it is important to supply oxygen to the oxide semiconductor to fill oxygen vacancies (sometimes referred to as oxygenation treatment).
- ⁇ By using an oxide semiconductor in which impurities such as «is sufficiently reduced in the channel formation region of the transistor, stable electric characteristics can be given.
- an oxide semiconductor having a low carrier concentration is preferably used for the transistor.
- the concentration of impurities in the oxide semiconductor may be lowered and the defects and the density of the defects may be lowered.
- low impurity concentration and low defect density are referred to as high purity intrinsic or substantially high purity intrinsic.
- impurities in the oxide semiconductor include hydrogen, nitrogen, alkali metals, alkaline earth metals, iron, nickel, silicon, and the like.
- hydrogen contained in an oxide semiconductor reacts with oxygen bonded to a metal atom to be water, which might cause oxygen deficiency in the oxide semiconductor.
- the transistor When the channel formation region in the oxide semiconductor contains oxygen vacancies, the transistor might have normally-on characteristics. Further, a defect in which hydrogen is contained in an oxygen vacancy may function as a donor and an electron which is a carrier may be generated. In addition, part of hydrogen may be bonded to oxygen which is bonded to a metal atom to generate an electron which is a carrier. Thus, a transistor including an oxide semiconductor that contains many hydrogen is likely to be normally ON JP 1 'production.
- a defect ( ⁇ : «) in which hydrogen is included in oxygen vacancies can function as a donor of an oxide semiconductor.
- the carrier concentration is sometimes used instead of the donor concentration. Therefore, in this specification and the like, a carrier concentration which is assumed to be a state where an electric field is not applied is sometimes used as a parameter of an oxide semiconductor, instead of a donor concentration. That is, the “carrier concentration” described in this specification and the like can be called the “donor concentration” in some cases.
- the hydrogen concentration obtained by secondary ion mass spectrometry should be less than l X 1 0 2 0 at om s/cm 3 , preferably l X 1 0 19 at oms / cm less than 3, more preferably less than 5 X 10 18 at om s / cm 3, more preferably less than 1 X 1 0 18 at om s / cm 3.
- the carrier concentration of the oxide semiconductor in the channel forming region 1 X 10 18 preferably cm at one 3 or less, more preferably less than l X 10 17 cm one 3, l X 10 16 cm one 3 It is more preferably less than 1, more preferably less than l X 10 13 cm -3 , and even more preferably less than l X 10 12 cm -3 .
- the lower limit of the carrier concentration in the oxide semiconductor in the channel forming region it is not particularly limited, for example, be a 1 X 10- 9 cm 3.
- a semiconductor device with favorable reliability can be provided. Further, according to one embodiment of the present invention, a semiconductor device having favorable electric characteristics can be provided. Further, according to one embodiment of the present invention, a semiconductor device with high on-state current can be provided. Further, according to one embodiment of the present invention, a semiconductor device which can be miniaturized or highly integrated can be provided. Another object of one embodiment of the present invention is to provide a semiconductor device with low power consumption.
- Semiconductor materials that can be used for the oxide 530 are not limited to the above metal oxides.
- a semiconductor material having a band gap (a semiconductor material that is not a zero-gap semiconductor) may be used.
- a semiconductor containing a single element such as silicon, a compound semiconductor such as gallium arsenide, or a layered substance (also referred to as an atomic layer substance or a two-dimensional material) that functions as a semiconductor as a semiconductor material.
- a layered substance that functions as a semiconductor as a semiconductor material it is preferable to use a layered substance that functions as a semiconductor as a semiconductor material.
- the layered substance is a general term for a group of materials having a layered crystal structure.
- the layered crystal structure is a structure in which layers formed by covalent bonds or ionic bonds are laminated via a bond weaker than covalent bonds or ionic bonds, such as van der Waalska.
- the layered material has a high electric conductivity in the unit layer, that is, a high two-dimensional electric conductivity.
- Layered materials include graphene, silicene, and chalcogenides.
- Chalcogenides are compounds containing chalcogen.
- Chalcogen is a general term for elements belonging to Group 16 and includes oxygen, sulfur, selenium, tellurium, polonium, and livermolium.
- Examples of chalcogenides include transition metal chalcogenides and group 13 chalcogenides.
- a transition metal chalcogenide functioning as a semiconductor is preferably used.
- Specific examples of transition metal chalcogenides applicable as oxide 530 include molybdenum sulfide. ⁇ 02020/174303 ? €1/162020/051162 Den (typically 1 ⁇ 3 2 ), molybdenum selenide (typically 1 ⁇ £ 62 ), molybdenum tellurium (typically N4 0 62 ), tungsten sulfide (typically £ 2 ), tungsten selenide (typically £ 62 ), tungsten tellurium (typically Ding 62 ), hafnium sulfide (typically H ££ 2 ), Examples thereof include hafnium selenide (typically H £ 62 ), zirconium sulfide (typically ZrS 2 ), zirconium selenide (typically £ 62 ), and the like.
- Capacitance element 49: Capacitance element, 61: Capacitance element, 70: Semiconductor device, 71: Amplification circuit, 80: Amplification circuit, 81: Transistor, 82: Transistor, 83: Transistor, 84: Transistor, 85: Transistor, 86: Transistor, 87: Capacitance element, 88: Capacitance element, 89: Resistance element, 100: Storage system, 1 14: Storage element, 121: Secondary battery, 161: Capacitance element, 162: Transistor, 300: Transistor, 311: substrate, 313: semiconductor region, 314 3 : low resistance region,
- 3141 3 Low resistance area, 315: Insulator, 316: Conductor, 320: Insulator, 322: Insulator, 3
- 5401 3 Conductor, 542: Conductor, 542 3 : Conductor, 5421 3 : Conductor, 543: Area, 54
- Insulator Insulator, 576 3 : Insulator, 5761 3 : Insulator, 580: Insulator, 581: Insulator, 582: Insulator, 584: Insulator, 586: Insulator, 600: Capacitance element, 610: Conductive Body, 612: conductor, 620: conductor, 630: insulator, 650: insulator, 692: conductor, 693: insulator
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- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
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- Nonlinear Science (AREA)
- Thin Film Transistor (AREA)
Abstract
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KR1020217028315A KR20210129089A (ko) | 2019-02-26 | 2020-02-13 | 반도체 장치 및 반도체 장치의 동작 방법 |
JP2021501134A JP7546544B2 (ja) | 2019-02-26 | 2020-02-13 | 半導体装置 |
CN202080013870.6A CN113424445A (zh) | 2019-02-26 | 2020-02-13 | 半导体装置及半导体装置的工作方法 |
US17/425,348 US11916065B2 (en) | 2019-02-26 | 2020-02-13 | Semiconductor device and method for operating semiconductor device |
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US (1) | US11916065B2 (ja) |
JP (1) | JP7546544B2 (ja) |
KR (1) | KR20210129089A (ja) |
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JP7554673B2 (ja) * | 2018-12-20 | 2024-09-20 | 株式会社半導体エネルギー研究所 | 半導体装置 |
US11799430B2 (en) | 2019-08-23 | 2023-10-24 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device and method for operating semiconductor device |
Citations (3)
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JPH05175752A (ja) * | 1991-09-06 | 1993-07-13 | Fuji Xerox Co Ltd | 差動型電圧比較器 |
JP2004312555A (ja) * | 2003-04-09 | 2004-11-04 | Sony Corp | コンパレータ、差動増幅器、2段増幅器及びアナログ/ディジタル変換器 |
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DE10303427A1 (de) | 2002-02-06 | 2003-10-16 | Nec Corp Tokio Tokyo | Verstärker-Schaltung, Treiber-Schaltung für ein Anzeigegerät , tragbares Telefon und tragbares elektronisches Gerät |
JP4214787B2 (ja) | 2002-02-06 | 2009-01-28 | 日本電気株式会社 | 増幅回路及びその制御方法 |
JP2009071653A (ja) | 2007-09-14 | 2009-04-02 | Yamaha Corp | コンパレータ |
KR101726724B1 (ko) | 2009-01-14 | 2017-04-13 | 미쓰미덴기가부시기가이샤 | 보호감시 회로, 전지팩, 2차전지 감시 회로, 및 보호 회로 |
JP5175752B2 (ja) | 2009-01-22 | 2013-04-03 | 株式会社東芝 | 医用画像処理装置 |
KR20190093705A (ko) * | 2009-11-27 | 2019-08-09 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 반도체 장치 및 반도체 장치의 제작방법 |
EP2538479B1 (en) | 2010-12-13 | 2015-09-02 | Panasonic Corporation | Power generation system and operating method therefor |
US10749338B2 (en) * | 2018-02-22 | 2020-08-18 | Infineon Technologies Ag | ESD power clamp with negative gate voltage |
JP6951293B2 (ja) * | 2018-05-29 | 2021-10-20 | 株式会社東芝 | 半導体装置 |
US11531362B2 (en) * | 2018-08-10 | 2022-12-20 | Semiconductor Energy Laboratory Co., Ltd. | Amplifier circuit, latch circuit, and sensing device |
US20210384751A1 (en) | 2018-10-25 | 2021-12-09 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device and method for operating power storage device |
US11714138B2 (en) | 2018-11-22 | 2023-08-01 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device, power storage device, and electronic device |
KR20210093934A (ko) | 2018-11-22 | 2021-07-28 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 이차 전지의 이상 검출 장치 및 반도체 장치 |
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- 2020-02-13 CN CN202080013870.6A patent/CN113424445A/zh active Pending
- 2020-02-13 US US17/425,348 patent/US11916065B2/en active Active
- 2020-02-13 KR KR1020217028315A patent/KR20210129089A/ko unknown
- 2020-02-13 WO PCT/IB2020/051162 patent/WO2020174303A1/ja active Application Filing
Patent Citations (3)
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JPH05122028A (ja) * | 1991-09-06 | 1993-05-18 | Fuji Xerox Co Ltd | 差動型電圧比較器 |
JPH05175752A (ja) * | 1991-09-06 | 1993-07-13 | Fuji Xerox Co Ltd | 差動型電圧比較器 |
JP2004312555A (ja) * | 2003-04-09 | 2004-11-04 | Sony Corp | コンパレータ、差動増幅器、2段増幅器及びアナログ/ディジタル変換器 |
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US20220102340A1 (en) | 2022-03-31 |
KR20210129089A (ko) | 2021-10-27 |
CN113424445A (zh) | 2021-09-21 |
JP7546544B2 (ja) | 2024-09-06 |
JPWO2020174303A1 (ja) | 2020-09-03 |
US11916065B2 (en) | 2024-02-27 |
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