WO2020173173A1 - 一种环保型地板及其生产方法 - Google Patents

一种环保型地板及其生产方法 Download PDF

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WO2020173173A1
WO2020173173A1 PCT/CN2019/124607 CN2019124607W WO2020173173A1 WO 2020173173 A1 WO2020173173 A1 WO 2020173173A1 CN 2019124607 W CN2019124607 W CN 2019124607W WO 2020173173 A1 WO2020173173 A1 WO 2020173173A1
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parts
powder
substrate
environmentally friendly
sepiolite
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PCT/CN2019/124607
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English (en)
French (fr)
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孙日东
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扬州富铭新材料有限公司
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    • C08K13/04Ingredients characterised by their shape and organic or inorganic ingredients
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    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
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    • C08K3/00Use of inorganic substances as compounding ingredients
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    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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    • C08L23/06Polyethene
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    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
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    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
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    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/18Separately-laid insulating layers; Other additional insulating measures; Floating floors
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    • C08K3/20Oxides; Hydroxides
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    • C08K2003/2296Oxides; Hydroxides of metals of zinc
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    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Definitions

  • the invention relates to the technical field of flooring, in particular to an environmentally friendly flooring and a production method thereof.
  • Wood flooring has undergone more than 20 years of development from 1995 to the present. Its floor decoration effect is warm and natural, strong and durable. According to people's traditional understanding, wood flooring is a kind of ground decoration material, and there seems to be nothing other than texture For consideration and reference, with the improvement of people's quality of life, when people choose floor decoration materials such as floors, in addition to the appearance, the lack of water resistance, crack resistance, durability, and flame retardancy of wooden floors has also become the focus of attention.
  • the current wooden floor has caused a large number of trees to be felled and destroyed the ecological environment, which is not environmentally friendly and has poor flame retardant effect. Therefore, how to design an environmentally friendly floor is particularly important.
  • the purpose of the present invention is to provide an environmentally friendly floor and a production method thereof in order to solve the above-mentioned shortcomings of the prior art.
  • an environmentally friendly floor designed by the present invention includes a substrate and a flame-retardant layer above the substrate, and a waterproof layer below the substrate.
  • the substrate includes raw materials prepared in the following quantities: 30-40 parts of environmentally friendly resin, 15-22 parts of waste phenolic foam, 22-28 parts of poplar wood powder, 8-15 parts of sepiolite, 5-10 parts of perlite, 8-15 parts of ordinary sawdust powder, nano-zinc oxide 4 -9 parts, 8-15 parts of nano silica, 10-18 parts of glass fiber, 8-15 parts of waste paper fiber, 6-12 parts of bamboo charcoal powder, 5-10 parts of talcum powder, 3-7 parts of polyethylene wax, 1-3 parts of silane coupling agent, 1.5-3 parts of antioxidant, 1.5-2.5 parts of heat stabilizer, the flame-retardant layer includes raw materials prepared according to the following parts: 22-28 parts of poplar wood powder, sepiolite 8-15 parts, 8-15 parts of ordinary sawdust powder, 3-5 parts of flame retardant, 5-10 parts of
  • the substrate also includes 5-10 parts of antibacterial agent.
  • the substrate also includes 15-25 parts of carbon fiber.
  • the substrate includes raw materials prepared in the following parts: 35 parts of waste environmentally friendly resin, 20 parts of waste phenolic foam, and poplar wood powder 23 parts, sepiolite 10 parts, perlite 8 parts, ordinary sawdust powder 12 parts, glass fiber 18 parts, nano zinc oxide 5 parts, nano silica 12 parts, glass fiber 15 parts, waste paper fiber 13 parts, bamboo charcoal 10 parts of powder, 8 parts of talc, 5 parts of polyethylene wax, 2 parts of silane coupling agent, 2.5 parts of antioxidant, 2 parts of heat stabilizer, and the flame retardant layer includes raw materials prepared in the following parts: poplar wood 25 parts of powder, 13 parts of sepiolite, 15 parts of ordinary sawdust powder, 18 parts of glass fiber, 4 parts of flame retardant, 8 parts of smoke suppressant and 2 parts of silane coupling agent.
  • the waterproof layer includes the following parts The raw materials: 17 parts of acrylic elastic resin, 6 parts of anti-
  • the substrate also includes 18 parts of carbon fiber.
  • the silane coupling agent is one or more combinations of vinyl triethoxy silane, 3-aminopropyl trimethoxy silane and gamma mercaptopropyl triethoxy silane.
  • the anti-smoke agent is one or more combinations of zinc stearate, molybdenum trioxide, or quicklime powder.
  • the invention also discloses a production method of environment-friendly floor, which specifically includes the following steps:
  • waste environmental protection resin for preheating and fusion, and then add waste phenolic foam, poplar wood powder, ordinary wood dust powder, nano zinc oxide, nano silica, glass fiber, waste paper fiber, bamboo charcoal powder, talcum powder, polyethylene wax , Silane coupling agent, antioxidant, and heat stabilizer are stirred and mixed evenly through a high-speed mixer;
  • step 1 an antibacterial agent is also added.
  • step 1 carbon fiber is also added.
  • the floor of the present invention uses waste environmentally friendly resin and waste phenolic foam as raw materials, and forms a base layer by adding other hard stones to cooperate to ensure that the base layer has good strength, pressure resistance and Flame-retardant, at the same time, the upper part is provided with a flame-retardant layer and the lower part is provided with a waterproof layer, which ultimately achieves flame-retardancy and waterproofness.
  • all raw materials are environmentally friendly and recyclable, ultimately reducing production costs and being environmentally friendly.
  • Figure 1 is a structural cross-sectional view of an environmentally friendly floor in Example 1;
  • the environmentally friendly floor provided by this embodiment includes a substrate 2 and a flame-retardant layer 1 provided above the substrate 2, and a waterproof layer 3 provided below the substrate 2.
  • the substrate 2 includes the following The number of raw materials: 30-40 parts of waste environmentally friendly resin, 15-22 parts of waste phenolic foam, 22-28 parts of poplar wood powder, 8-15 parts of sepiolite, 5-10 parts of perlite, 8-parts of ordinary sawdust powder 15 parts, 4-9 parts of nano-zinc oxide, 8-15 parts of nano-silica, 10-18 parts of glass fiber, 8-15 parts of waste paper fiber, 6-12 parts of bamboo charcoal powder, 5-10 parts of talcum powder, poly 3-7 parts of ethylene wax, 1-3 parts of silane coupling agent, 1.5-3 parts of antioxidant, 1.5-2.5 parts of heat stabilizer, the flame-retardant layer 1 includes raw materials prepared according to the following parts: poplar wood powder 22-28 parts, sepiolite 8-15 parts, ordinary sawdust powder 8-15 parts, flame retardant 3-5 parts
  • the substrate 2 also includes 5-10 parts of antibacterial agent.
  • the substrate 2 also includes 15-25 parts of carbon fiber.
  • the substrate 2 includes raw materials prepared according to the following parts: waste environmentally friendly resin 35 parts, waste phenolic foam 20 parts, 23 parts of poplar wood powder, 10 parts of sepiolite, 8 parts of perlite, 12 parts of ordinary wood powder, 5 parts of nano zinc oxide, 12 parts of nano silica, 15 parts of glass fiber, 13 parts of waste paper fiber, 10 parts of bamboo charcoal powder, 8 parts of talc powder, 5 parts of polyethylene wax, 2 parts of silane coupling agent, 2.5 parts of antioxidant, and 2 parts of heat stabilizer.
  • the flame-retardant layer 1 includes raw materials prepared in the following parts: 25 parts of poplar wood powder, 13 parts of sepiolite, 15 parts of ordinary sawdust powder, 18 parts of glass fiber, 4 parts of flame retardant, 8 parts of smoke suppressant and 2 parts of silane coupling agent.
  • the waterproof layer 3 includes the following The raw materials for the number of parts: 17 parts of acrylic elastic resin, 6 parts of anti-slip agent.
  • the substrate 2 also includes 18 parts of carbon fiber.
  • the silane coupling agent is one or more combinations of vinyltriethoxysilane, 3-aminopropyltrimethoxysilane and ⁇ -mercaptopropyltriethoxysilane.
  • the anti-smoke agent is one or more combinations of zinc stearate, molybdenum trioxide, or quicklime powder.
  • This embodiment also discloses a production method of environmentally friendly flooring, which specifically includes the following steps:
  • waste environmental protection resin for preheating and fusion, and then add waste phenolic foam, poplar wood powder, ordinary wood dust powder, nano zinc oxide, nano silica, glass fiber, waste paper fiber, bamboo charcoal powder, talcum powder, polyethylene wax , Silane coupling agent, antioxidant, and heat stabilizer are stirred and mixed evenly through a high-speed mixer;
  • step 1 an antibacterial agent is also added.
  • step 1 carbon fiber is also added.
  • the floor of this embodiment uses waste environmentally friendly resin and waste phenolic foam as raw materials.
  • the base layer is formed by adding other hard stones to ensure that the base layer has good strength, compression resistance and flame retardancy.
  • the upper part is provided with a flame retardant layer and the lower part is provided
  • the waterproof layer finally achieves flame retardancy and waterproofness, and all raw materials are environmentally friendly and recyclable, ultimately reducing production costs and being environmentally friendly.
  • the environment-friendly floor provided by this embodiment includes a substrate 2 and a flame-retardant layer 1 provided above the substrate 2, and a waterproof layer 3 provided below the substrate 2, and the substrate 2 includes raw materials prepared in the following parts: 39 parts of waste environmentally friendly resin, 21 parts of waste phenolic foam, 27 parts of poplar wood powder, 14 parts of sepiolite, 9 parts of perlite, 14 parts of ordinary wood powder, 8 parts of nano zinc oxide, 14 parts of nano silica, glass fiber 17 parts, 9 parts of waste paper fiber, 11 parts of bamboo charcoal powder, 9 parts of talc powder, 6 parts of polyethylene wax, 2 parts of silane coupling agent, 2 parts of antioxidant, 2 parts of heat stabilizer, the flame retardant layer 1 Including raw materials prepared according to the following parts: 27 parts of poplar wood powder, 14 parts of sepiolite, 14 parts of ordinary wood powder, 19 parts of glass fiber, 3.8 parts of flame retardant, 9 parts of smoke suppressant and 2.8 parts of silane coupling agent
  • the waterproof layer 3 includes raw materials prepared
  • silane coupling agent is 3-aminopropyltrimethoxysilane and gamma mercaptopropyltriethoxysilane.
  • the smoke suppressant is one or more combinations of molybdenum trioxide and quicklime powder.
  • This embodiment also discloses a production method of environmentally friendly flooring, which specifically includes the following steps:
  • waste environmental protection resin for preheating and fusion, and then add waste phenolic foam, poplar wood powder, ordinary wood dust powder, nano zinc oxide, nano silica, glass fiber, waste paper fiber, bamboo charcoal powder, talcum powder, polyethylene wax , Silane coupling agent, antioxidant, and heat stabilizer are stirred and mixed evenly through a high-speed mixer;
  • the environment-friendly floor provided by this embodiment includes a substrate 2 and a flame-retardant layer 1 provided above the substrate 2, and a waterproof layer 3 provided below the substrate 2, and the substrate 2 includes raw materials prepared in the following parts: 33 parts of waste environmentally friendly resin, 18 parts of waste phenolic foam, 24 parts of poplar wood powder, 10 parts of sepiolite, 8 parts of perlite, 9 parts of ordinary wood powder, 5 parts of nano zinc oxide, 9 parts of nano silica, glass fiber 11 parts, 9 parts of waste paper fiber, 7 parts of bamboo charcoal powder, 5-10 parts of talc powder, 4 parts of polyethylene wax, 1.5 parts of silane coupling agent, 1.8 parts of antioxidant, 1.8 parts of heat stabilizer, the flame retardant Layer 1 includes raw materials prepared according to the following parts: 23 parts of poplar wood powder, 9 parts of sepiolite, 9 parts of ordinary wood dust powder, 16 parts of glass fiber, 3.5 parts of flame retardant, 6 parts of smoke suppressant and silane coupling agent 1.8 parts, the waterproof layer 3 includes raw materials
  • the substrate 2 also includes 15-25 parts of carbon fiber.
  • the substrate 2 also includes 20 parts of carbon fiber.
  • silane coupling agent is vinyl triethoxy silane.
  • the smoke suppressant is zinc stearate.
  • This embodiment also discloses a production method of environmentally friendly flooring, which specifically includes the following steps:
  • waste environmental protection resin for preheating and fusion, and then add waste phenolic foam, poplar wood powder, ordinary wood dust powder, nano zinc oxide, nano silica, glass fiber, waste paper fiber, bamboo charcoal powder, talcum powder, polyethylene wax , Silane coupling agent, antioxidant, and heat stabilizer are stirred and mixed evenly through a high-speed mixer;
  • step 1 carbon fiber is also added.
  • the environment-friendly floor provided by this embodiment includes a substrate 2 and a flame-retardant layer 1 provided above the substrate 2, and a waterproof layer 3 provided below the substrate 2, and the substrate 2 includes raw materials prepared in the following parts: 30 parts of waste environmentally friendly resin, 15 parts of waste phenolic foam, 22 parts of poplar wood powder, 8 parts of sepiolite, 5 parts of perlite, 8 parts of ordinary wood powder, 4 parts of nano zinc oxide, 8 parts of nano silica, glass fiber 10 parts, 8 parts of waste paper fiber, 6 parts of bamboo charcoal powder, 5 parts of talc powder, 3 parts of polyethylene wax, 1 part of silane coupling agent, 1.5 parts of antioxidant, 1.5 parts of heat stabilizer, the flame retardant layer 1 Including the following raw materials: 22 parts of poplar wood powder, 8 parts of sepiolite, 8 parts of ordinary wood powder, 15 parts of glass fiber, 3 parts of flame retardant, 5 parts of smoke suppressant and 1 part of silane coupling agent
  • the waterproof layer 3 includes raw materials prepared according to the following parts:
  • the substrate 2 also includes 5-10 parts of antibacterial agent. 8 parts of the antibacterial agent.
  • silane coupling agent is among vinyl triethoxy silane, 3-aminopropyl trimethoxy silane and gamma mercaptopropyl triethoxy silane.
  • the smoke suppressant is zinc stearate, molybdenum trioxide and quicklime powder.
  • This embodiment also discloses a production method of environmentally friendly flooring, which specifically includes the following steps:
  • waste environmental protection resin for preheating and fusion, and then add waste phenolic foam, poplar wood powder, ordinary wood dust powder, nano zinc oxide, nano silica, glass fiber, waste paper fiber, bamboo charcoal powder, talcum powder, polyethylene wax , Silane coupling agent, antioxidant, and heat stabilizer are stirred and mixed evenly through a high-speed mixer;
  • step 1 an antibacterial agent is also added.
  • the environment-friendly floor provided by this embodiment includes a substrate 2 and a flame-retardant layer 1 provided above the substrate 2, and a waterproof layer 3 provided below the substrate 2, and the substrate 2 includes raw materials prepared in the following parts: 40 parts of waste environmentally friendly resin, 22 parts of waste phenolic foam, 28 parts of poplar wood powder, 15 parts of sepiolite, 10 parts of perlite, 8-15 parts of ordinary wood powder, 9 parts of nano zinc oxide, 15 parts of nano silica, 18 parts of glass fiber, 15 parts of waste paper fiber, 12 parts of bamboo charcoal powder, 10 parts of talcum powder, 7 parts of polyethylene wax, 3 parts of silane coupling agent, 3 parts of antioxidant, 2.5 parts of heat stabilizer, the flame retardant Layer 1 includes raw materials prepared according to the following parts: 28 parts of poplar wood powder, 15 parts of sepiolite, 15 parts of ordinary sawdust powder, 20 parts of glass fiber, 5 parts of flame retardant, 10 parts of smoke suppressant and silane coupling agent 3 parts, the waterproof layer 3 includes raw materials prepared according
  • the substrate 2 also includes 5-10 parts of antibacterial agent.
  • the substrate 2 also includes 15-25 parts of carbon fiber.
  • the substrate 2 also includes 18 parts of carbon fiber.
  • the silane coupling agent is one or more combinations of vinyl triethoxy silane, 3-aminopropyl trimethoxy silane and gamma mercaptopropyl triethoxy silane.
  • the silane coupling agent is vinyl triethoxy silane and gamma mercaptopropyl triethoxy silane.
  • the anti-smoke agent is one or more combinations of zinc stearate, molybdenum trioxide, or quicklime powder.
  • the smoke suppressant is zinc stearate and quicklime powder.
  • This embodiment also discloses a production method of environmentally friendly flooring, which specifically includes the following steps:
  • waste environmental protection resin for preheating and fusion, and then add waste phenolic foam, poplar wood powder, ordinary wood dust powder, nano zinc oxide, nano silica, glass fiber, waste paper fiber, bamboo charcoal powder, talcum powder, polyethylene wax , Silane coupling agent, antioxidant, and heat stabilizer are stirred and mixed evenly through a high-speed mixer;
  • step 1 an antibacterial agent is also added.
  • step 1 carbon fiber is also added.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Dispersion Chemistry (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Floor Finish (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种环保型地板,包括基板、阻燃层、防水层,基板包括:废弃环保树脂30-40份、废弃酚醛泡沫15-22份、杨木粉22-28份、海泡石8-15份、珍珠岩5-10份、普通木屑粉8-15份、纳米氧化锌4-9份、纳米二氧化硅8-15份、玻璃纤维10-18份、废旧纸纤维8-15份、竹炭粉6-12份、滑石粉5-10份、聚乙烯蜡3-7份、硅烷偶联剂1-3份、抗氧剂1.5-3份、热稳定剂1.5-2.5份,阻燃层包括杨木粉、海泡石、普通木屑粉、玻璃纤维、阻燃剂、消烟剂和硅烷偶联剂,防水层包括:丙烯酸系弹性树脂和防滑剂。本发明还公开了该地板的生产方法。本发明降低生产成本。

Description

一种环保型地板及其生产方法 技术领域
本发明涉及一种地板的技术领域,尤其是一种环保型地板及其生产方法。
背景技术
木地板从1995年到现在历经二十多年的发展,其地面装饰效果温馨自然,结实耐用,在人们的传统认识当中,木地板就是一种地面装饰材料,除了材质花色之外,好像没有什么考量参考,随着人们生活品质的提高,人们在选购地板等地面装饰材料时,除了讲求外观,木地板缺乏防水性、抗裂性和耐久性、阻燃性也日益成为关注的焦点。
目前的木质地板造成大量树木砍伐破坏生态环境,不够环保,且阻燃效果差,因此如何设计一款环保的地板显得尤为重要。
发明内容
本发明的目的是为了解决上述现有技术的不足而提供一种环保型地板及其生产方法。
为了实现上述目的,本发明所设计的一种环保型地板,包括基板和设于基板上方的阻燃层,以及设于基板下方的防水层,所述基板包括按照以下份数配备的原料:废弃环保树脂30-40份、废弃酚醛泡沫15-22份、杨木粉22-28份、海泡石8-15份、珍珠岩5-10份、普通木屑粉8-15份、纳米氧化锌4-9份、纳米二氧化硅8-15份、玻璃纤维10-18份、废旧纸纤维8-15份、竹炭粉6-12份、滑石粉5-10份、聚乙烯蜡3-7份、硅烷偶联剂1-3份和抗氧剂1.5-3份、热稳定剂1.5-2.5份,所述阻燃层包括按照以下份数配备的原料:杨木粉22-28份、海泡石8-15份、普通木屑粉8-15份、阻燃剂3-5份、消烟剂5-10份和硅烷偶联剂1-3份,所述防水层包括按照以下份数配备的原料:丙烯酸系弹性树脂15-20份、防滑剂5-8份。
进一步,该基板还包括抗菌剂5-10份。
进一步,该基板还包括碳纤维15-25份。
进一步,包括基板和设于基板上方的阻燃层,以及设于基板下方的防水层,所述基板包括按照以下份数配备的原料:废弃环保树脂35份、废弃酚醛泡沫20份、杨木粉23份、海泡石10份、珍珠岩8份、普通木屑粉12份、玻璃纤维18份、纳米氧化锌5份、纳米二氧化硅12份、玻璃纤维15份、废旧纸纤维13份、竹炭粉10份、滑石粉8份、聚乙烯蜡5份、硅烷偶联剂2份和抗氧剂2.5份、热稳定剂2份,所述阻燃层包括按照以下份数配备的原料:杨木粉25份、海泡石13份、普通木屑粉15份、玻璃纤维18份、阻燃剂4份、消烟剂8份和硅烷偶联剂2份,所述防水层包括按照以下份数配备的原料:丙烯酸系弹性树脂17份、防滑剂6份。
进一步,该基板还包括碳纤维18份。
进一步,所述硅烷偶联剂为乙烯基三乙氧基硅烷、3-氨丙基三甲氧基硅烷和γ巯丙基三乙氧基硅烷中的一种或多种结合。
进一步,所述消烟剂为硬脂酸锌、三氧化钼或生石灰粉中的一种或多种结合。
本发明还公开了一种环保型地板的生产方法,具体包括以下步骤:
1)先制备基板:
①通过获取珍珠岩、海泡石进行研磨处理,备用;
②再获取废弃环保树脂进行预热融合,然后加入废弃酚醛泡沫、杨木粉、普通木屑粉、纳米氧化锌、纳米二氧化硅、玻璃纤维、废旧纸纤维、竹炭粉、滑石粉、聚乙烯蜡、硅烷偶联剂和抗氧剂、热稳定剂通过高速混合机进行搅拌混合均匀;
③然后挤入压膜机构中进行压膜处理构成基板;
2)再制备阻燃层:
①通过获取海泡石进行研磨处理,备用;
②获取杨木粉、普通木屑粉、玻璃纤维和海泡石粉末通过高速混合机进行搅拌混合均匀;
④将阻燃剂、消烟剂和硅烷偶联剂加入杨木粉、普通木屑粉、玻璃纤维和海泡石粉末混合制得的混合物中,升温至80-90摄氏度,以1300-1600转/分钟的速度搅拌混合30-45分钟后,放入真空干燥箱中在80-90摄氏度的条件下,烘干5小时,冷却至室温,然后挤入压膜机构中进行压膜处理构成阻燃层;
3)制备防水层:
①通过获取丙烯酸系弹性树脂进行预热融合,然后加入防滑剂通过高速混合机进行搅拌混合均匀;
②然后挤入压膜机构中进行压膜处理构成防水层;
4)按照顺序将基板、阻燃层和防水层进行叠加,然后进行复合最终构成环保木板。
进一步,在步骤1中还加入抗菌剂。
进一步,在步骤1中还加入碳纤维。
本发明得到的一种环保型地板及其生产方法,本发明地板以废弃环保树脂和废弃酚醛泡沫为原料,通过加入其它硬性石头的配合作用构成基层,保证基层具有良好的强度、抗压性和阻燃性,同时上部设置阻燃层下部设置防水层,最终实现阻燃性以及防水性,同时所有原料环保,可回收,最终降低生产成本,绿色环保。
附图说明
图1是实施例1中一种环保型地板的结构剖视图;
附图标记中:1.阻燃层;2.基板;3.防水层。
具体实施方式
下面结合实施例对发明创造作进一步说明。
实施例1:
如图1所示,本实施例提供的一种环保型地板,包括基板2和设于基板2上方的阻燃层1,以及设于基板2下方的防水层3,所述基板2包括按照以下份数配备的原料:废弃环保树脂30-40份、废弃酚醛泡沫15-22份、杨木粉22-28份、海泡石8-15份、珍珠岩5-10份、普通木屑粉8-15份、纳米氧化锌4-9份、纳米二氧化硅8-15份、玻璃纤维10-18份、废旧纸纤维8-15份、竹炭粉6-12份、滑石粉5-10份、聚乙烯蜡3-7份、硅烷偶联剂1-3份和抗氧剂1.5-3份、热稳定剂1.5-2.5份,所述阻燃层1包括按照以下份数配备的原料:杨木粉22-28份、海泡石8-15份、普通木屑粉8-15份、阻燃剂3-5份、消烟剂5-10份和硅烷偶联剂1-3份,所述防水层3包括按照以下份数配备的原料:丙烯酸系弹性树脂15-20份、防滑剂5-8份。
进一步,该基板2还包括抗菌剂5-10份。
进一步,该基板2还包括碳纤维15-25份。
进一步,包括基板2和设于基板2上方的阻燃层1,以及设于基板2下方的防水层3,所述基板2包括按照以下份数配备的原料:废弃环保树脂35份、废弃酚醛泡沫20份、杨木粉23份、海泡石10份、珍珠岩8份、普通木屑粉12份、纳米氧化锌5份、纳米二氧化硅12份、玻璃纤维15份、废旧纸纤维13份、竹炭粉10份、滑石粉8份、聚乙烯蜡5份、硅烷偶联剂2份和抗氧剂2.5份、热稳定剂2份,所述阻燃层1包括按照以下份数配备的原料:杨木粉25份、海泡石13份、普通木屑粉15份、玻璃纤维18份、阻燃剂4份、消烟剂8份和硅烷偶联剂2份,所述防水层3包括按照以下份数配备的原料:丙烯酸系弹性树脂17份、防滑剂6份。
进一步,该基板2还包括碳纤维18份。
进一步,所述硅烷偶联剂为乙烯基三乙氧基硅烷、3-氨丙基三甲氧基硅烷 和γ巯丙基三乙氧基硅烷中的一种或多种结合。
进一步,所述消烟剂为硬脂酸锌、三氧化钼或生石灰粉中的一种或多种结合。
本实施例还公开了一种环保型地板的生产方法,具体包括以下步骤:
1)先制备基板2:
①通过获取珍珠岩、海泡石进行研磨处理,备用;
②再获取废弃环保树脂进行预热融合,然后加入废弃酚醛泡沫、杨木粉、普通木屑粉、纳米氧化锌、纳米二氧化硅、玻璃纤维、废旧纸纤维、竹炭粉、滑石粉、聚乙烯蜡、硅烷偶联剂和抗氧剂、热稳定剂通过高速混合机进行搅拌混合均匀;
③然后挤入压膜机构中进行压膜处理构成基板2;
2)再制备阻燃层1:
①通过获取海泡石进行研磨处理,备用;
②获取杨木粉、普通木屑粉、玻璃纤维和海泡石粉末通过高速混合机进行搅拌混合均匀;
④将阻燃剂、消烟剂和硅烷偶联剂加入杨木粉、普通木屑粉、玻璃纤维和海泡石粉末混合制得的混合物中,升温至80-90摄氏度,以1300-1600转/分钟的速度搅拌混合30-45分钟后,放入真空干燥箱中在80-90摄氏度的条件下,烘干5小时,冷却至室温,然后挤入压膜机构中进行压膜处理构成阻燃层1;
3)制备防水层3:
①通过获取丙烯酸系弹性树脂进行预热融合,然后加入防滑剂通过高速混合机进行搅拌混合均匀;
②然后挤入压膜机构中进行压膜处理构成防水层3;
4)按照顺序将基板2、阻燃层1和防水层3进行叠加,然后进行复合最 终构成环保木板。
进一步,在步骤1中还加入抗菌剂。
进一步,在步骤1中还加入碳纤维。
本实施例的地板以废弃环保树脂和废弃酚醛泡沫为原料,通过加入其它硬性石头的配合作用构成基层,保证基层具有良好的强度、抗压性和阻燃性,同时上部设置阻燃层下部设置防水层,最终实现阻燃性以及防水性,同时所有原料环保,可回收,最终降低生产成本,绿色环保。
实施例2:
本实施例提供的一种环保型地板,包括基板2和设于基板2上方的阻燃层1,以及设于基板2下方的防水层3,所述基板2包括按照以下份数配备的原料:废弃环保树脂39份、废弃酚醛泡沫21份、杨木粉27份、海泡石14份、珍珠岩9份、普通木屑粉14份、纳米氧化锌8份、纳米二氧化硅14份、玻璃纤维17份、废旧纸纤维9份、竹炭粉11份、滑石粉9份、聚乙烯蜡6份、硅烷偶联剂2份和抗氧剂2份、热稳定剂2份,所述阻燃层1包括按照以下份数配备的原料:杨木粉27份、海泡石14份、普通木屑粉14份、玻璃纤维19份、阻燃剂3.8份、消烟剂9份和硅烷偶联剂2.8份,所述防水层3包括按照以下份数配备的原料:丙烯酸系弹性树脂19份、防滑剂7份。
进一步,所述硅烷偶联剂为3-氨丙基三甲氧基硅烷和γ巯丙基三乙氧基硅烷。
进一步,所述消烟剂为三氧化钼和生石灰粉中的一种或多种结合。
本实施例还公开了一种环保型地板的生产方法,具体包括以下步骤:
1)先制备基板2:
①通过获取珍珠岩、海泡石进行研磨处理,备用;
②再获取废弃环保树脂进行预热融合,然后加入废弃酚醛泡沫、杨木粉、普通木屑粉、纳米氧化锌、纳米二氧化硅、玻璃纤维、废旧纸纤维、竹 炭粉、滑石粉、聚乙烯蜡、硅烷偶联剂和抗氧剂、热稳定剂通过高速混合机进行搅拌混合均匀;
③然后挤入压膜机构中进行压膜处理构成基板2;
2)再制备阻燃层1:
①通过获取海泡石进行研磨处理,备用;
②获取杨木粉、普通木屑粉、玻璃纤维和海泡石粉末通过高速混合机进行搅拌混合均匀;
④将阻燃剂、消烟剂和硅烷偶联剂加入杨木粉、普通木屑粉、玻璃纤维和海泡石粉末混合制得的混合物中,升温至83摄氏度,以13505转/分钟的速度搅拌混合38分钟后,放入真空干燥箱中在83摄氏度的条件下,烘干5小时,冷却至室温,然后挤入压膜机构中进行压膜处理构成阻燃层1;
3)制备防水层3:
①通过获取丙烯酸系弹性树脂进行预热融合,然后加入防滑剂通过高速混合机进行搅拌混合均匀;
②然后挤入压膜机构中进行压膜处理构成防水层3;
4)按照顺序将基板2、阻燃层1和防水层3进行叠加,然后进行复合最终构成环保木板。
实施例3:
本实施例提供的一种环保型地板,包括基板2和设于基板2上方的阻燃层1,以及设于基板2下方的防水层3,所述基板2包括按照以下份数配备的原料:废弃环保树脂33份、废弃酚醛泡沫18份、杨木粉24份、海泡石10份、珍珠岩8份、普通木屑粉9份、纳米氧化锌5份、纳米二氧化硅9份、玻璃纤维11份、废旧纸纤维9份、竹炭粉7份、滑石粉5-10份、聚乙烯蜡4份、硅烷偶联剂1.5份和抗氧剂1.8份、热稳定剂1.8份,所述阻燃层1包括按照以下份数配备的原料:杨木粉23份、海泡石9份、普通木屑粉9份、玻 璃纤维16份、阻燃剂3.5份、消烟剂6份和硅烷偶联剂1.8份,所述防水层3包括按照以下份数配备的原料:丙烯酸系弹性树脂16份、防滑剂6份。
进一步,该基板2还包括碳纤维15-25份。
进一步,该基板2还包括碳纤维20份。
进一步,所述硅烷偶联剂为乙烯基三乙氧基硅烷。
进一步,所述消烟剂为硬脂酸锌。
本实施例还公开了一种环保型地板的生产方法,具体包括以下步骤:
1)先制备基板2:
①通过获取珍珠岩、海泡石进行研磨处理,备用;
②再获取废弃环保树脂进行预热融合,然后加入废弃酚醛泡沫、杨木粉、普通木屑粉、纳米氧化锌、纳米二氧化硅、玻璃纤维、废旧纸纤维、竹炭粉、滑石粉、聚乙烯蜡、硅烷偶联剂和抗氧剂、热稳定剂通过高速混合机进行搅拌混合均匀;
③然后挤入压膜机构中进行压膜处理构成基板2;
2)再制备阻燃层1:
①通过获取海泡石进行研磨处理,备用;
②获取杨木粉、普通木屑粉、玻璃纤维和海泡石粉末通过高速混合机进行搅拌混合均匀;
④将阻燃剂、消烟剂和硅烷偶联剂加入杨木粉、普通木屑粉、玻璃纤维和海泡石粉末混合制得的混合物中,升温至82摄氏度,以1400转/分钟的速度搅拌混合35分钟后,放入真空干燥箱中在82摄氏度的条件下,烘干5小时,冷却至室温,然后挤入压膜机构中进行压膜处理构成阻燃层1;
3)制备防水层3:
①通过获取丙烯酸系弹性树脂进行预热融合,然后加入防滑剂通过高速混合机进行搅拌混合均匀;
②然后挤入压膜机构中进行压膜处理构成防水层3;
4)按照顺序将基板2、阻燃层1和防水层3进行叠加,然后进行复合最终构成环保木板。
进一步,在步骤1中还加入碳纤维。
实施例4:
本实施例提供的一种环保型地板,包括基板2和设于基板2上方的阻燃层1,以及设于基板2下方的防水层3,所述基板2包括按照以下份数配备的原料:废弃环保树脂30份、废弃酚醛泡沫15份、杨木粉22份、海泡石8份、珍珠岩5份、普通木屑粉8份、纳米氧化锌4份、纳米二氧化硅8份、玻璃纤维10份、废旧纸纤维8份、竹炭粉6份、滑石粉5份、聚乙烯蜡3份、硅烷偶联剂1份和抗氧剂1.5份、热稳定剂1.5份,所述阻燃层1包括按照以下份数配备的原料:杨木粉22份、海泡石8份、普通木屑粉8份、玻璃纤维15份、阻燃剂3份、消烟剂5份和硅烷偶联剂1份,所述防水层3包括按照以下份数配备的原料:丙烯酸系弹性树脂15份、防滑剂5份。
进一步,该基板2还包括抗菌剂5-10份。所述抗菌剂8份。
进一步,所述硅烷偶联剂为乙烯基三乙氧基硅烷、3-氨丙基三甲氧基硅烷和γ巯丙基三乙氧基硅烷中。
进一步,所述消烟剂为硬脂酸锌、三氧化钼和生石灰粉。
本实施例还公开了一种环保型地板的生产方法,具体包括以下步骤:
1)先制备基板2:
①通过获取珍珠岩、海泡石进行研磨处理,备用;
②再获取废弃环保树脂进行预热融合,然后加入废弃酚醛泡沫、杨木粉、普通木屑粉、纳米氧化锌、纳米二氧化硅、玻璃纤维、废旧纸纤维、竹炭粉、滑石粉、聚乙烯蜡、硅烷偶联剂和抗氧剂、热稳定剂通过高速混合机进行搅拌混合均匀;
③然后挤入压膜机构中进行压膜处理构成基板2;
2)再制备阻燃层1:
①通过获取海泡石进行研磨处理,备用;
②获取杨木粉、普通木屑粉、玻璃纤维和海泡石粉末通过高速混合机进行搅拌混合均匀;
④将阻燃剂、消烟剂和硅烷偶联剂加入杨木粉、普通木屑粉、玻璃纤维和海泡石粉末混合制得的混合物中,升温至80摄氏度,以1300转/分钟的速度搅拌混合30分钟后,放入真空干燥箱中在80摄氏度的条件下,烘干5小时,冷却至室温,然后挤入压膜机构中进行压膜处理构成阻燃层1;
3)制备防水层3:
①通过获取丙烯酸系弹性树脂进行预热融合,然后加入防滑剂通过高速混合机进行搅拌混合均匀;
②然后挤入压膜机构中进行压膜处理构成防水层3;
4)按照顺序将基板2、阻燃层1和防水层3进行叠加,然后进行复合最终构成环保木板。
进一步,在步骤1中还加入抗菌剂。
实施例5:
本实施例提供的一种环保型地板,包括基板2和设于基板2上方的阻燃层1,以及设于基板2下方的防水层3,所述基板2包括按照以下份数配备的原料:废弃环保树脂40份、废弃酚醛泡沫22份、杨木粉28份、海泡石15份、珍珠岩10份、普通木屑粉8-15份、纳米氧化锌9份、纳米二氧化硅15份、玻璃纤维18份、废旧纸纤维15份、竹炭粉12份、滑石粉10份、聚乙烯蜡7份、硅烷偶联剂3份和抗氧剂3份、热稳定剂2.5份,所述阻燃层1包括按照以下份数配备的原料:杨木粉28份、海泡石15份、普通木屑粉15份、玻璃纤维20份、阻燃剂5份、消烟剂10份和硅烷偶联剂3份,所述防 水层3包括按照以下份数配备的原料:丙烯酸系弹性树脂20份、防滑剂8份。
进一步,该基板2还包括抗菌剂5-10份。
进一步,该基板2还包括碳纤维15-25份。
进一步,该基板2还包括碳纤维18份。
进一步,所述硅烷偶联剂为乙烯基三乙氧基硅烷、3-氨丙基三甲氧基硅烷和γ巯丙基三乙氧基硅烷中的一种或多种结合。在本实施例中所述硅烷偶联剂为乙烯基三乙氧基硅烷和γ巯丙基三乙氧基硅烷。
进一步,所述消烟剂为硬脂酸锌、三氧化钼或生石灰粉中的一种或多种结合。在本实施例中所述消烟剂为硬脂酸锌和生石灰粉。
本实施例还公开了一种环保型地板的生产方法,具体包括以下步骤:
1)先制备基板2:
①通过获取珍珠岩、海泡石进行研磨处理,备用;
②再获取废弃环保树脂进行预热融合,然后加入废弃酚醛泡沫、杨木粉、普通木屑粉、纳米氧化锌、纳米二氧化硅、玻璃纤维、废旧纸纤维、竹炭粉、滑石粉、聚乙烯蜡、硅烷偶联剂和抗氧剂、热稳定剂通过高速混合机进行搅拌混合均匀;
③然后挤入压膜机构中进行压膜处理构成基板2;
2)再制备阻燃层1:
①通过获取海泡石进行研磨处理,备用;
②获取杨木粉、普通木屑粉、玻璃纤维和海泡石粉末通过高速混合机进行搅拌混合均匀;
④将阻燃剂、消烟剂和硅烷偶联剂加入杨木粉、普通木屑粉、玻璃纤维和海泡石粉末混合制得的混合物中,升温至90摄氏度,以1600转/分钟的速度搅拌混合45分钟后,放入真空干燥箱中在90摄氏度的条件下,烘干5小时,冷却至室温,然后挤入压膜机构中进行压膜处理构成阻燃层1;
3)制备防水层3:
①通过获取丙烯酸系弹性树脂进行预热融合,然后加入防滑剂通过高速混合机进行搅拌混合均匀;
②然后挤入压膜机构中进行压膜处理构成防水层3;
4)按照顺序将基板2、阻燃层1和防水层3进行叠加,然后进行复合最终构成环保木板。
进一步,在步骤1中还加入抗菌剂。
进一步,在步骤1中还加入碳纤维。
将实施例1-5制得的环保地板与现有技术的复合地板进行性能测试,最终结果如下,见表1:
Figure PCTCN2019124607-appb-000001
以上显示和描述了本发明的基本原理和主要特征和本发明的优点,对于本领域技术人员而言,显然本发明不限于上述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是上述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、 修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。

Claims (10)

  1. 一种环保型地板,其特征在于,包括基板(2)和设于基板(2)上方的阻燃层(1),以及设于基板(2)下方的防水层(3),所述基板(2)包括按照以下份数配备的原料:废弃环保树脂30-40份、废弃酚醛泡沫15-22份、杨木粉22-28份、海泡石8-15份、珍珠岩5-10份、普通木屑粉8-15份、纳米氧化锌4-9份、纳米二氧化硅8-15份、玻璃纤维10-18份、废旧纸纤维8-15份、竹炭粉6-12份、滑石粉5-10份、聚乙烯蜡3-7份、硅烷偶联剂1-3份和抗氧剂1.5-3份、热稳定剂1.5-2.5份,所述阻燃层(1)包括按照以下份数配备的原料:杨木粉22-28份、海泡石8-15份、普通木屑粉8-15份、阻燃剂3-5份、消烟剂5-10份和硅烷偶联剂1-3份,所述防水层(3)包括按照以下份数配备的原料:丙烯酸系弹性树脂15-20份、防滑剂5-8份。
  2. 根据权利要求1所述的一种环保型地板,其特征在于,该基板(2)还包括抗菌剂5-10份。
  3. 根据权利要求1或2所述的一种环保型地板,其特征在于,该基板(2)还包括碳纤维15-25份。
  4. 根据权利要求1或2所述的一种环保型地板,其特征在于,包括基板(2)和设于基板(2)上方的阻燃层(1),以及设于基板(2)下方的防水层(3),所述基板(2)包括按照以下份数配备的原料:废弃环保树脂35份、废弃酚醛泡沫20份、杨木粉23份、海泡石10份、珍珠岩8份、普通木屑粉12份、纳米氧化锌5份、纳米二氧化硅12份、玻璃纤维15份、废旧纸纤维13份、竹炭粉10份、滑石粉8份、聚乙烯蜡5份、硅烷偶联剂2份和抗氧剂2.5份、热稳定剂2份,所述阻燃层(1)包括按照以下份数配备的原料:杨木粉25份、海泡石13份、普通木屑粉15份、玻璃纤维18份、阻燃剂4份、消烟剂8份和硅烷偶联剂2份,所述防水层(3)包括按照以下份数配备的原料:丙烯酸系弹性树脂17份、防滑剂6份。
  5. 根据权利要求3所述的一种环保型地板,其特征在于,该基板(2) 还包括碳纤维18份。
  6. 根据权利要求1或2所述的一种环保型地板,其特征在于,所述硅烷偶联剂为乙烯基三乙氧基硅烷、3-氨丙基三甲氧基硅烷和γ巯丙基三乙氧基硅烷中的一种或多种结合。
  7. 根据权利要求1或2所述的一种环保型地板,其特征在于,所述消烟剂为硬脂酸锌、三氧化钼或生石灰粉中的一种或多种结合。
  8. 一种环保型地板的生产方法,其特征在于具体包括以下步骤:
    1)先制备基板(2):
    ①通过获取珍珠岩、海泡石进行研磨处理,备用;
    ②再获取废弃环保树脂进行预热融合,然后加入废弃酚醛泡沫、杨木粉、普通木屑粉、纳米氧化锌、纳米二氧化硅、玻璃纤维、废旧纸纤维、竹炭粉、滑石粉、聚乙烯蜡、硅烷偶联剂和抗氧剂、热稳定剂通过高速混合机进行搅拌混合均匀;
    ③然后挤入压膜机构中进行压膜处理构成基板(2);
    2)再制备阻燃层(1):
    ①通过获取海泡石进行研磨处理,备用;
    ②获取杨木粉、普通木屑粉、玻璃纤维和海泡石粉末通过高速混合机进行搅拌混合均匀;
    ④将阻燃剂、消烟剂和硅烷偶联剂加入杨木粉、普通木屑粉、玻璃纤维和海泡石粉末混合制得的混合物中,升温至80-90摄氏度,以1300-1600转/分钟的速度搅拌混合30-45分钟后,放入真空干燥箱中在80-90摄氏度的条件下,烘干5小时,冷却至室温,然后挤入压膜机构中进行压膜处理构成阻燃层(1);
    3)制备防水层(3):
    ①通过获取丙烯酸系弹性树脂进行预热融合,然后加入防滑剂通过高速 混合机进行搅拌混合均匀;
    ②然后挤入压膜机构中进行压膜处理构成防水层(3);
    4)按照顺序将基板(2)、阻燃层(1)和防水层(3)进行叠加,然后进行复合最终构成环保木板。
  9. 根据权利要求8所述的一种环保型地板的生产方法,其特征在于:在步骤1中还加入抗菌剂。
  10. 根据权利要求8所述的一种环保型地板的生产方法,其特征在于:在步骤1中还加入碳纤维。
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