WO2020169119A1 - 红反膜系滤光板和其在抗刹车灯眩目方面的应用及滤光器 - Google Patents

红反膜系滤光板和其在抗刹车灯眩目方面的应用及滤光器 Download PDF

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WO2020169119A1
WO2020169119A1 PCT/CN2020/085735 CN2020085735W WO2020169119A1 WO 2020169119 A1 WO2020169119 A1 WO 2020169119A1 CN 2020085735 W CN2020085735 W CN 2020085735W WO 2020169119 A1 WO2020169119 A1 WO 2020169119A1
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film
layer
physical thickness
tio
sio
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PCT/CN2020/085735
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French (fr)
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申屠炜
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申屠炜
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J3/00Antiglare equipment associated with windows or windscreens; Sun visors for vehicles
    • B60J3/02Antiglare equipment associated with windows or windscreens; Sun visors for vehicles adjustable in position
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/26Reflecting filters
    • GPHYSICS
    • G02OPTICS
    • G02CSPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00Optical parts
    • G02C7/10Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses

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  • the invention belongs to the technical field of special film filter plates, and specifically relates to a red reflective film filter plate and its application in anti-glare of brake lights and a filter.
  • the present invention mainly solves the technical problems existing in the above-mentioned prior art, and provides a red reflective film filter plate and its application in anti-glare of brake lights and a filter.
  • a red reflective film filter plate including a transparent substrate, the substrate is PC or PMMA, the PC or PMMA substrate is sequentially provided with a first layer of TiO 2 film, second SiO 2 film, third TiO 2 film, fourth SiO 2 film, fifth TiO 2 film, sixth SiO 2 film, seventh TiO 2 film, eighth SiO 2 Film, ninth TiO 2 film, tenth SiO 2 film, eleventh TiO 2 film, twelfth SiO 2 film, thirteenth SiO 2 film, coating process requirements: light source: white light, substrate : PC or PMMA, angle: 0.0 (deg), incident medium: air, output medium: PC or PMMA, reference: 690.0nm, detector: Ideal.
  • the physical thickness of the first TiO 2 film is 13.79 ⁇ 10% nm
  • the physical thickness of the second SiO 2 film is 180.31 ⁇ 10% nm
  • the physical thickness of the third TiO 2 film is 280.43 ⁇ 10% nm.
  • the physical thickness of the four-layer SiO 2 film is 154.38 ⁇ 10% nm
  • the physical thickness of the fifth layer of TiO 2 film is 212.12 ⁇ 10% nm
  • the physical thickness of the sixth layer of SiO 2 film is 167.33 ⁇ 10% nm
  • the seventh layer The physical thickness of the TiO 2 film is 30.63 ⁇ 10% nm
  • the physical thickness of the eighth layer of SiO 2 film is 183.72 ⁇ 10% nm
  • the physical thickness of the ninth layer of TiO 2 film is 27.42 ⁇ 10% nm
  • the tenth layer of SiO 2 The physical thickness of the film is 162.63 ⁇ 10% nm
  • the physical thickness of the eleventh layer of TiO 2 film is 223.38 ⁇ 10% nm
  • the physical thickness of the twelfth layer of SiO 2 film is 55.33 ⁇ 10% nm
  • the thirteenth layer of SiO 2 The physical thickness of the film is 180.64 ⁇ 10% nm.
  • the substrate is CR-39
  • the CR-39 substrate is provided with a first layer of MgF 2 film, a second layer of TiO 2 film, a third layer of MgF 2 film, a fourth layer of TiO 2 film, and a fifth layer of MgF 2 in sequence.
  • the coating process requirements are: Light source: white light, substrate: CR-39, angle: 0.0 (deg), incident medium: air, output medium: CR-39, reference: 680.0 nm, detector: Ideal, polarization: Ave-, first side: front.
  • the physical thickness of the first MgF 2 film is 123.19 ⁇ 10% nm
  • the physical thickness of the second TiO 2 film is 230.60 ⁇ 10% nm
  • the physical thickness of the third MgF 2 film is 369.57 ⁇ 10% nm.
  • the physical thickness of the four-layer TiO 2 film is 230.60 ⁇ 10% nm
  • the physical thickness of the fifth layer of MgF 2 film is 369.57 ⁇ 10% nm
  • the physical thickness of the sixth layer of TiO 2 film is 230.60 ⁇ 10% nm
  • the seventh layer The physical thickness of the MgF 2 film is 369.57 ⁇ 10% nm
  • the physical thickness of the eighth layer of TiO 2 film is 230.60 ⁇ 10% nm
  • the physical thickness of the ninth layer of MgF 2 film is 369.57 ⁇ 10% nm
  • the tenth layer of TiO 2 The physical thickness of the film is 230.60 ⁇ 10% nm
  • the physical thickness of the eleventh layer of MgF 2 film is 123.19 ⁇ 10% nm.
  • the physical thickness of the first TiO 2 film is 13.79 ⁇ 5% nm
  • the physical thickness of the second SiO 2 film is 180.31 ⁇ 5% nm
  • the physical thickness of the third TiO 2 film is The physical thickness is 280.43 ⁇ 5% nm
  • the physical thickness of the fourth layer of SiO 2 film is 154.38 ⁇ 5% nm
  • the physical thickness of the fifth layer of TiO 2 film is 212.12 ⁇ 5% nm
  • the physical thickness of the sixth layer of SiO 2 film The physical thickness of the seventh layer of TiO 2 film is 30.63 ⁇ 5% nm
  • the physical thickness of the eighth layer of SiO 2 film is 183.72 ⁇ 5% nm
  • the physical thickness of the ninth layer of TiO 2 film is 27.42 ⁇ 5% nm
  • the physical thickness of the tenth layer of SiO 2 film is 162.63 ⁇ 5% nm
  • the physical thickness of the eleventh layer of TiO 2 film is 223.38 ⁇ 5% nm
  • the physical thickness of the first MgF 2 film is 123.19 ⁇ 5% nm
  • the physical thickness of the second TiO 2 film is 230.60 ⁇ 5% nm
  • the physical thickness of the third MgF 2 film is 369.57 ⁇ 5% nm
  • the physical thickness of the fourth layer of TiO 2 film is 230.60 ⁇ 5% nm
  • the physical thickness of the fifth layer of MgF 2 film is 369.57 ⁇ 5% nm
  • the physical thickness of the sixth layer of TiO 2 film is 230.60 ⁇
  • the physical thickness of the seventh layer of MgF 2 film is 369.57 ⁇ 5% nm
  • the physical thickness of the eighth layer of TiO 2 film is 230.60 ⁇ 5% nm
  • the physical thickness of the ninth layer of MgF 2 film is 369.57 ⁇ 5%.
  • the physical thickness of the tenth layer of TiO 2 film is 230.60 ⁇ 5% nm
  • the physical thickness of the eleventh layer of MgF 2 film is 230.60
  • the physical thickness of the first TiO 2 film is 13.79 nm
  • the physical thickness of the second SiO 2 film is 180.31 nm
  • the physical thickness of the third TiO 2 film is 280.43 nm
  • the physical thickness of the fourth layer of SiO 2 film is 154.38 nm
  • the physical thickness of the fifth layer of TiO 2 film is 212.12 nm
  • the physical thickness of the sixth layer of SiO 2 film is 167.33 nm
  • the physical thickness of the seventh layer of TiO 2 film is 30.63 nm
  • the eighth layer is the physical thickness of the SiO 2 film is 183.72nm
  • the physical thickness of the TiO 2 thin film of the ninth layer was 27.42nm
  • the physical thickness of the SiO 2 film of the tenth layer is 162.63nm
  • physical eleventh layer TiO 2 thin film The thickness is 223.38 nm
  • the physical thickness of the twelfth layer of SiO 2 film is 55.33 nm
  • the physical thickness of the first MgF 2 film is 123.19 nm
  • the physical thickness of the second TiO 2 film is 230.60 nm
  • the physical thickness of the third MgF 2 film is 369.57 nm
  • the fourth layer The physical thickness of the TiO 2 film is 230.60 nm
  • the physical thickness of the fifth MgF 2 film is 369.57 nm
  • the physical thickness of the sixth TiO 2 film is 230.60 nm
  • the physical thickness of the seventh MgF 2 film is 369.57 nm.
  • the physical thickness of the eight-layer TiO 2 film is 230.60 nm
  • the physical thickness of the ninth MgF 2 film is 369.57 nm
  • the physical thickness of the tenth TiO 2 film is 230.60 nm
  • the physical thickness of the eleventh MgF 2 film is 123.19 nm.
  • the filter is a vehicle-mounted device clamped on the light-shielding plate of a car, wherein the upper edge of the red reflective film filter plate is provided with Bar frame, the middle of the bar frame is provided with a base, the base is provided with a support rod, and the end of the support rod is provided with a clamping hook, and the clamping hook hooks and clamps the light shielding plate of the automobile, thereby clamping the vehicle-mounted device Hold it on the car's visor.
  • the upper end of the support rod is provided with a shaft seat, the upper end of the support rod is provided on the shaft seat via a rotating shaft, and the base of the clamp hook is provided on the shaft seat.
  • the support rod is a telescopic rod.
  • the characteristics of the film material selected in the present invention (1)TiO 2 , a white solid or powdery amphoteric oxide, with a molecular weight of 79.9. When exposed to ultraviolet light, it undergoes a photocatalytic reaction and oxidizes with water adsorbed on the surface to produce hydroxyl radicals (OH ) becomes of CO 2 and H 2 O on their own to eliminate volatile, film-based facilitate surface cleaning - -OOH), with oxygen in the air oxidation-reduction reaction generates superoxide anion (O 2 occurs.
  • SiO 2 colorless and transparent crystal, good chemical stability, good evaporation state, not easy to collapse, according to the requirements of the use of ultraviolet light, infrared light, and visible light.
  • (3)MgF 2 a colorless tetragonal crystalline powder with high purity, can increase the transmittance of the film and avoid collapse points.
  • the present invention needs to be set in front of the field of view of the main driving position and auxiliary driving position, worn on the eyes or clamped on the shading plate, considering that in the event of an accidental impact, the material used for the filter plate substrate needs to be The possibility of injury to the driver and assistant driver is minimized.
  • inorganic mineral glass with the characteristics of fragility and injury is not suitable.
  • PC, PMMA and CR-39 are the most suitable.
  • PC, PMMA, CR-39 three materials are not resistant to high temperature.
  • High temperature evaporation resistance heating or electron beam evaporation source process should not be used when coating.
  • IDA cold coating process is suitable. The coating temperature can still be controlled even under continuous working conditions.
  • the IDA cold plating process also has a series of technical advantages, such as relatively stable wavelength drift, relatively high filling density, less moisture absorption in the infrared band, and film Layer adhesion, friction resistance, mechanical strength and surface finish are all relatively good, film stress is well controlled, and production efficiency is high.
  • the red reflective film filter plate of the present invention adopts the vacuum ion source assisted deposition (IDA) process, preferably the film system combination and film system design are precisely controlled, and selectively reflects and transmits red light in the visible light band from 610nm to 720nm The rate is reduced to about 20%, the human eye feels comfortable, and the ambient light brightness is basically not affected, which is beneficial to driving safety.
  • IDA vacuum ion source assisted deposition
  • the filter of the present invention is worn on the eyes or clamped on the light-shielding plate of the car, and is convenient to use; the upper end of the support rod in the vehicle-mounted device is set on the shaft seat via the rotating shaft, and the red reflective film filter plate can be folded, and stored and stored. It is very convenient to use.
  • the support rod is set as a telescopic rod, and the filter plate can be adjusted up and down to suit different people. Therefore, the invention has the characteristics of simple structure and reasonable design.
  • FIG. 1 is a schematic diagram of the first film system design structure of the red reflective film filter plate of the present invention
  • FIG. 2 is a schematic diagram of the second film system design structure of the red reflective film filter plate of the present invention.
  • Figure 3 is a schematic diagram of a front view of the optical filter of the present invention.
  • FIG. 4 is a schematic diagram of a side view structure of the optical filter of the present invention.
  • FIG. 5 is a schematic diagram of a three-dimensional structure of the optical filter of the present invention.
  • Fig. 6 is a spectrogram of dark glasses for sunglasses in the prior art
  • Fig. 7 is a spectrum diagram of the red reflective film filter plate of the present invention.
  • Example 1 With reference to Figure 1, in the schematic diagram of the first film system design structure of the red reflective film filter plate of the present invention, the transparent substrate is PC or PMMA, and the PC or PMMA substrate is sequentially provided with a first layer of TiO 2 film and a second layer Two-layer SiO 2 film, third TiO 2 film, fourth SiO 2 film, fifth TiO 2 film, sixth SiO 2 film, seventh TiO 2 film, eighth SiO 2 film, ninth Layers of TiO 2 film, tenth layer of SiO 2 film, eleventh layer of TiO 2 film, twelfth layer of SiO 2 film, thirteenth layer of SiO 2 film, coating process requirements: light source: white light, substrate: PC or PMMA , Angle: 0.0 (deg), incident medium: air, output medium: PC or PMMA, reference: 690.0nm, detector: Ideal.
  • light source white light
  • substrate PC or PMMA
  • Angle 0.0 (deg)
  • incident medium air
  • output medium PC or PMMA
  • the physical thickness of the first TiO 2 film is 13.79 ⁇ 10% nm
  • the physical thickness of the second SiO 2 film is 180.31 ⁇ 10% nm
  • the physical thickness of the third TiO 2 film is 280.43 ⁇ 10% nm.
  • the physical thickness of the four-layer SiO 2 film is 154.38 ⁇ 10% nm
  • the physical thickness of the fifth layer of TiO 2 film is 212.12 ⁇ 10% nm
  • the physical thickness of the sixth layer of SiO 2 film is 167.33 ⁇ 10% nm
  • the seventh layer The physical thickness of the TiO 2 film is 30.63 ⁇ 10% nm
  • the physical thickness of the eighth layer of SiO 2 film is 183.72 ⁇ 10% nm
  • the physical thickness of the ninth layer of TiO 2 film is 27.42 ⁇ 10% nm
  • the tenth layer of SiO 2 The physical thickness of the film is 162.63 ⁇ 10% nm
  • the physical thickness of the eleventh layer of TiO 2 film is 223.38 ⁇ 10% nm
  • the physical thickness of the twelfth layer of SiO 2 film is 55.33 ⁇ 10% nm
  • the thirteenth layer of SiO 2 The physical thickness of the film is 180.64 ⁇ 10% nm;
  • the physical thickness of the twelfth layer of SiO 2 film is 55.33 ⁇ 5% nm, and the physical thickness of the thirteenth layer of SiO 2 film is 180.64 ⁇ 5% nm; optimally, on the PC or PMMA substrate, the first layer of TiO 2
  • the physical thickness of the film is 13.79 nm
  • the physical thickness of the second SiO 2 film is 180.31 nm
  • the physical thickness of the third TiO 2 film is 280.43 nm
  • the physical thickness of the fourth SiO 2 film is 154.38 nm.
  • the physical thickness of the TiO 2 film is 212.12 nm, the physical thickness of the sixth SiO 2 film is 167.33 nm, the physical thickness of the seventh TiO 2 film is 30.63 nm, and the physical thickness of the eighth SiO 2 film is 183.72 nm.
  • the physical thickness of the ninth layer of TiO 2 film is 27.42nm, the tenth The physical thickness of the SiO 2 film is 162.63 nm, the physical thickness of the eleventh TiO 2 film is 223.38 nm, the physical thickness of the twelfth SiO 2 film is 55.33 nm, and the physical thickness of the thirteenth SiO 2 film is 180.64nm.
  • the anti-brake light glare filter with the above red reflective film filter plate is goggles.
  • the structure of the goggles is the prior art.
  • the lens of the eyepiece includes the red reflective film filter plate; or referring to Figures 3 to 5, the anti-brake light glare filter with the red reflective film filter plate is a vehicle mounted on the car’s light shield Device, wherein the upper edge of the red reflective film filter plate is provided with a frame, the middle of the frame is provided with a base, and a support rod is provided on the base, and the end of the support rod is provided with a clamping hook, which is hooked and clamped
  • the car’s light-shielding plate is held, whereby the vehicle-mounted device is clamped on the car’s light-shielding plate, the upper end of the support rod is provided with a shaft seat, the upper end of the support rod is arranged on the shaft seat via a rotating shaft, and the clamp
  • the red reflective film filter plate of the present invention adopts the vacuum ion source assisted deposition (IDA) process, preferably the film system combination and film system design are precisely controlled, and selectively reflects and transmits red light in the visible light band from 610nm to 720nm The rate is reduced to about 20%.
  • IDA vacuum ion source assisted deposition
  • the filter of the present invention is worn on the eyes or clamped on the light-shielding plate of the car, and is convenient to use; the upper end of the support rod in the vehicle-mounted device is set on the shaft seat via the rotating shaft, and the red reflective film filter plate can be folded, and stored and stored. It is very convenient to use.
  • the support rod is set as a telescopic rod, and the filter plate can be adjusted up and down to suit different people. Therefore, the invention has the characteristics of simple structure and reasonable design.
  • Example 2 Referring to Figure 2, in the second film system design structure diagram of the red reflective film filter plate of the present invention, the transparent substrate is CR-39, and the CR-39 substrate is sequentially provided with a first layer of MgF 2 film and a second film Two-layer TiO 2 film, third MgF 2 film, fourth TiO 2 film, fifth MgF 2 film, sixth TiO 2 film, seventh MgF 2 film, eighth TiO 2 film, ninth Layer MgF 2 film, tenth layer TiO 2 film, and eleventh layer MgF 2 film.
  • the coating process requirements are: light source: white light, substrate: CR-39, angle: 0.0 (deg), incident medium: air, exit medium: CR-39, reference: 680.0nm, detector: Ideal, polarization: Ave-, first side: front.
  • the physical thickness of the first MgF 2 film is 123.19 ⁇ 10% nm
  • the physical thickness of the second TiO 2 film is 230.60 ⁇ 10% nm
  • the physical thickness of the third MgF 2 film is 369.57 ⁇ 10% nm.
  • the physical thickness of the four-layer TiO 2 film is 230.60 ⁇ 10% nm
  • the physical thickness of the fifth layer of MgF 2 film is 369.57 ⁇ 10% nm
  • the physical thickness of the sixth layer of TiO 2 film is 230.60 ⁇ 10% nm
  • the seventh layer The physical thickness of the MgF 2 film is 369.57 ⁇ 10% nm
  • the physical thickness of the eighth layer of TiO 2 film is 230.60 ⁇ 10% nm
  • the physical thickness of the ninth layer of MgF 2 film is 369.57 ⁇ 10% nm
  • the tenth layer of TiO 2 The physical thickness of the film is 230.60 ⁇ 10% nm
  • the physical thickness of the eleventh layer of MgF 2 film is 123.19 ⁇ 10% nm; preferably, on the CR-39 substrate, the physical thickness of the first MgF 2 film is 123.19 ⁇ 5% nm
  • the physical thickness of the second layer of TiO 2 film
  • the physical thickness of the eleven-layer MgF 2 film is 123.19 ⁇ 5% nm; optimally, on the CR-39 substrate, the physical thickness of the first MgF 2 film is 123.19 nm, and the physical thickness of the second TiO 2 film
  • the physical thickness of the third MgF 2 film is 369.57 nm
  • the physical thickness of the fourth TiO 2 film is 230.60 nm
  • the physical thickness of the fifth MgF 2 film is 369.57 nm
  • the physical thickness of the sixth TiO 2 film is 369.57 nm.
  • the physical thickness is 230.60nm
  • the physical thickness of the seventh layer of MgF 2 film is 369.57nm
  • the physical thickness of the eighth layer of TiO 2 film is 230.60nm
  • the physical thickness of the ninth layer of MgF 2 film is 369.57nm
  • the tenth layer of TiO 2 The physical thickness of the film is 230.60 nm
  • the physical thickness of the eleventh MgF 2 film is 123.19 nm.
  • the rest refer to Example 1.

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Abstract

一种红反膜系滤光板(26),滤光板(26)的基板(1)为PC或PMMA,基板(1)上设有若干层TiO 2镀膜和SiO 2镀膜,或者滤光板(26)的基板(1)为CR‑39,基板(1)上设有若干层MgF 2镀膜和TiO 2镀膜,采用真空离子源辅助沉积(IDA)工艺,膜系组合及膜系设计精准控制,选择性地将可见光波段中610nm~720nm的红光反射并使其透过率降低到20%左右,人眼感觉舒适,基本不影响环境光亮度,利于行车安全。

Description

红反膜系滤光板和其在抗刹车灯眩目方面的应用及滤光器 技术领域
本发明属于专用膜系滤光板的技术领域,具体是涉及一种红反膜系滤光板和其在抗刹车灯眩目方面的应用及滤光器。
背景技术
根据公安部最新发布的信息,仅全国家庭小型客车保有量已达到1.87亿辆,全国机动车驾驶人达4.07亿人。随着我国经济的快速发展,汽车的保有量与日俱增,车辆尾部的刹车灯目前已经普遍采用亮度高、寿命长的LED光源。刹车灯一般安装于车辆尾部两侧,采用穿透力较强的红色光源,用于警示后车司机,告知前车已经采取制动措施,防止后车追尾。进入夜间,环境光变暗,由于LED光源亮度太高,导致刹车灯极其眩目,某些车型急刹时还会出现爆闪,其亮度甚至不亚于远光灯,灯厂设计目的自然是为了对后车起到更强的警示作用,然而从环保和医学角度上来说,刹车灯眩目现象所带来的问题是一种彩光污染,这种眩目的红色强光对后车司机的眼健康会产生不利影响,对经常开夜车的职业司机更有可能会造成视觉神经系统不同程度的损伤,对此国内外的科学杂志均有相关报道。然而如何解决刹车灯眩目给驾驶人员带来健康甚至安全隐患问题,目前尚未发现具有针对性的解决方案或实例。现有技术中,有一种称作防眩滤光器的产品,其滤光板是一片黄色有机玻璃,从光学原理上无法解释其对红光具有抑制作用,而实测结果也证实其对抑制红光没有作用。此外,有部分司机在不堪忍受刹车灯眩目时会佩戴白天使用的墨镜作为权宜之计,但无疑这是一种绝不可取的危险行为,因为墨镜使用的暗色镜片系为降低白昼强光照射设计,其在可见光波段范围的透过率呈水平下降,参看图6,实际通过暗色镜片观察,红色强光虽也受到抑制,但本已不足的夜间环境光变得严重不足,安全风险大幅提高。新技术新材料所带来的新问题,给本领域技术人员提供了新课题,亟需解决。
发明内容
本发明主要是解决上述现有技术所存在的技术问题,提供了一种红反膜系滤光板和其在抗刹车灯眩目方面的应用及滤光器。
本发明的上述技术问题主要是通过下述技术方案得以解决的:一种红反膜系滤光板,包括透明基板,所述基板为PC或PMMA,PC或PMMA基板上依次设有第一层TiO 2薄膜、第二层SiO 2薄膜、第三层TiO 2薄膜、第四层SiO 2薄膜、第五层TiO 2薄膜、第六层SiO 2薄膜、第七层TiO 2薄膜、第八层SiO 2薄膜、第九层TiO 2薄膜、第十层SiO 2薄膜、第十一层TiO 2薄膜、第十二层SiO 2薄膜、第十三层SiO 2薄膜,镀膜工艺要求为,光源:白光,基底:PC或PMMA,角度:0.0(deg),入射介质:空气,出射介质:PC或PMMA,参考:690.0nm,探测器:Ideal。其中第一层TiO 2薄膜的物理厚度为13.79±10%nm,第二层SiO 2薄膜的物理厚度为180.31±10%nm,第三层TiO 2薄膜的物理厚度为280.43±10%nm,第四层SiO 2薄膜的物理厚度为154.38±10%nm,第五层TiO 2薄膜的物理厚度为212.12±10%nm,第六层SiO 2薄膜的物理厚度为167.33±10%nm,第七层TiO 2薄膜的物理厚度为30.63±10%nm,第 八层SiO 2薄膜的物理厚度为183.72±10%nm,第九层TiO 2薄膜的物理厚度为27.42±10%nm,第十层SiO 2薄膜的物理厚度为162.63±10%nm,第十一层TiO 2薄膜的物理厚度为223.38±10%nm,第十二层SiO 2薄膜的物理厚度为55.33±10%nm,第十三层SiO 2薄膜的物理厚度为180.64±10%nm。
或者所述基板为CR-39,CR-39基板上依次设有第一层MgF 2薄膜、第二层TiO 2薄膜、第三层MgF 2薄膜、第四层TiO 2薄膜、第五层MgF 2薄膜、第六层TiO 2薄膜、第七层MgF 2薄膜、第八层TiO 2薄膜、第九层MgF 2薄膜、第十层TiO 2薄膜、第十一层MgF 2薄膜,镀膜工艺要求为,光源:白光,基底:CR-39,角度:0.0(deg),入射介质:空气,出射介质:CR-39,参考:680.0nm,探测器:Ideal,偏振:Ave-,第一面:front。其中第一层MgF 2薄膜的物理厚度为123.19±10%nm,第二层TiO 2薄膜的物理厚度为230.60±10%nm,第三层MgF 2薄膜的物理厚度为369.57±10%nm,第四层TiO 2薄膜的物理厚度为230.60±10%nm,第五层MgF 2薄膜的物理厚度为369.57±10%nm,第六层TiO 2薄膜的物理厚度为230.60±10%nm,第七层MgF 2薄膜的物理厚度为369.57±10%nm,第八层TiO 2薄膜的物理厚度为230.60±10%nm,第九层MgF 2薄膜的物理厚度为369.57±10%nm,第十层TiO 2薄膜的物理厚度为230.60±10%nm,第十一层MgF 2薄膜的物理厚度为123.19±10%nm。
作为优选,所述PC或PMMA基板上,第一层TiO 2薄膜的物理厚度为13.79±5%nm,第二层SiO 2薄膜的物理厚度为180.31±5%nm,第三层TiO 2薄膜的物理厚度为280.43±5%nm,第四层SiO 2薄膜的物理厚度为154.38±5%nm,第五层TiO 2薄膜的物理厚度为212.12±5%nm,第六层SiO 2薄膜的物理厚度为167.33±5%nm,第七层TiO 2薄膜的物理厚度为30.63±5%nm,第八层SiO 2薄膜的物理厚度为183.72±5%nm,第九层TiO 2薄膜的物理厚度为27.42±5%nm,第十层SiO 2薄膜的物理厚度为162.63±5%nm,第十一层TiO 2薄膜的物理厚度为223.38±5%nm,第十二层SiO 2薄膜的物理厚度为55.33±5%nm,第十三层SiO 2薄膜的物理厚度为180.64±5%nm;
所述CR-39基板上,第一层MgF 2薄膜的物理厚度为123.19±5%nm,第二层TiO 2薄膜的物理厚度为230.60±5%nm,第三层MgF 2薄膜的物理厚度为369.57±5%nm,第四层TiO 2薄膜的物理厚度为230.60±5%nm,第五层MgF 2薄膜的物理厚度为369.57±5%nm,第六层TiO 2薄膜的物理厚度为230.60±5%nm,第七层MgF 2薄膜的物理厚度为369.57±5%nm,第八层TiO 2薄膜的物理厚度为230.60±5%nm,第九层MgF 2薄膜的物理厚度为369.57±5%nm,第十层TiO 2薄膜的物理厚度为230.60±5%nm,第十一层MgF 2薄膜的物理厚度为123.19±5%nm。
作为优选,所述PC或PMMA基板上,第一层TiO 2薄膜的物理厚度为13.79nm,第二层SiO 2薄膜的物理厚度为180.31nm,第三层TiO 2薄膜的物理厚度为280.43nm,第四层SiO 2薄膜的物理厚度为154.38nm,第五层TiO 2薄膜的物理厚度为212.12nm,第六层SiO 2薄膜的物理厚度为167.33nm,第七层TiO 2薄膜的物理厚度为30.63nm,第八层SiO 2薄膜的物理厚度为183.72nm,第九层TiO 2薄膜的物理厚度为27.42nm,第十层SiO 2薄膜的物理厚度为162.63nm,第十一层TiO 2薄膜的物理厚度为223.38nm,第十二层SiO 2薄膜的物理厚 度为55.33nm,第十三层SiO 2薄膜的物理厚度为180.64nm;
所述CR-39基板上,第一层MgF 2薄膜的物理厚度为123.19nm,第二层TiO 2薄膜的物理厚度为230.60nm,第三层MgF 2薄膜的物理厚度为369.57nm,第四层TiO 2薄膜的物理厚度为230.60nm,第五层MgF 2薄膜的物理厚度为369.57nm,第六层TiO 2薄膜的物理厚度为230.60nm,第七层MgF 2薄膜的物理厚度为369.57nm,第八层TiO 2薄膜的物理厚度为230.60nm,第九层MgF 2薄膜的物理厚度为369.57nm,第十层TiO 2薄膜的物理厚度为230.60nm,第十一层MgF 2薄膜的物理厚度为123.19nm。
一种上述红反膜系滤光板在抗刹车灯眩目方面的应用。
一种具有上述红反膜系滤光板的抗刹车灯眩目滤光器,所述滤光器为护目镜,护目镜的镜片包括所述的红反膜系滤光板。
一种具有上述红反膜系滤光板的抗刹车灯眩目滤光器,所述滤光器为夹持在汽车的遮光板上的车载装置,其中红反膜系滤光板的上边缘设有条框,条框的中部设有基座,基座上设有支杆,支杆的端部设有夹勾,夹勾勾置并夹持汽车的遮光板,籍此将所述车载装置夹持在汽车的遮光板上。
作为优选,所述支杆的上端设有轴座,支杆的上端经由转轴设置在轴座上,所述夹勾的基部设置在轴座上。
作为优选,所述支杆为伸缩杆。
本发明所选膜系材料的特点:⑴TiO 2,白色固体或粉末状两性氧化物,分子量为79.9,受紫外光照射时经光催化反应,与表面吸附的水氧化产生氢氧自由基团(OH-OOH),与空气中氧发生氧化还原反应产生超氧离子(O 2 -)变成CO 2和H 2O自行挥发消除,有利于膜系表面清洁。⑵SiO 2,无色透明晶体,化学稳定性好,蒸发状态好,不易出现崩点,按使用要求分紫外光、红外光、可见光用几种。⑶MgF 2,无色四方晶体粉末,纯度高,可提高膜系透过率,避免出现崩点。
本发明在实际使用时需要设置在主驾位和副驾位的视场前方,佩戴在眼部或者夹持在遮光板上,考虑到在意外撞击情况下,滤光板基板所使用的材料需对主驾位和副驾位人员致伤的可能性降到最低,显然具有易碎裂致伤特性的无机矿物质玻璃不宜采用,而从材料的轻便、柔韧、透光性等方面综合考虑,选择PC、PMMA、CR-39是最为合适的。PC、PMMA、CR-39三种材料都非耐高温,镀膜时不宜采用高温蒸发的电阻加热或电子束蒸发源工艺,适宜采用IDA冷镀工艺,即便在连续工作状态下,镀膜温度仍可控制在80℃以内,符合滤光板所选基板材料的低温要求,同时IDA冷镀工艺还具有一系列技术优势,比如波长漂移相对较为稳定,填充密度相对较高,红外波段水气吸收较少,膜层结合力、耐摩擦性、机械强度及表面光洁度都比较好,膜应力控制良好,生产效率较高。
本发明的红反膜系滤光板采用真空离子源辅助沉积(IDA)工艺,优选膜系组合及膜系设计精准控制,选择性地将可见光波段中610nm~720nm的红光反射并使其透过率降低到20%左右,人眼感觉舒适,基本不影响环境光亮度,利于行车安全。
本发明的滤光器佩戴在眼部或者夹持在汽车的遮光板上,使用方便;车载装置中支杆 的上端经由转轴设置在轴座上,可以翻折红反膜系滤光板,收纳和使用都很方便,支杆设置为伸缩杆,可以上下调整滤光板,以适应不同人群。因此本发明具有结构简单、设计合理等特点。
附图说明
图1是本发明红反膜系滤光板的第一种膜系设计结构示意图;
图2是本发明红反膜系滤光板的第二种膜系设计结构示意图;
图3是本发明滤光器的一种主视结构示意图;
图4是本发明滤光器的一种侧视结构示意图;
图5是本发明滤光器的一种立体结构示意图;
图6是现有技术中墨镜暗色镜片的一种光谱图;
图7是本发明红反膜系滤光板的一种光谱图。
图中,1-基板,2-第一层TiO 2薄膜,3-第二层SiO 2薄膜,4-第三层TiO 2薄膜,5-第四层SiO 2薄膜,6-第五层TiO 2薄膜,7-第六层SiO 2薄膜,8-第七层TiO 2薄膜,9-第八层SiO 2薄膜,10-第九层TiO 2薄膜,11-第十层SiO 2薄膜,12-第十一层TiO 2薄膜,13-第十二层SiO 2薄膜,14-第十三层SiO 2薄膜,15-第一层MgF 2薄膜,16-第二层TiO 2薄膜,17-第三层MgF 2薄膜,18-第四层TiO 2薄膜,19-第五层MgF 2薄膜,20-第六层TiO 2薄膜,21-第七层MgF 2薄膜,22-第八层TiO 2薄膜,23-第九层MgF 2薄膜,24-第十层TiO 2薄膜,25-第十一层MgF 2薄膜,26-红反膜系滤光板,27-条框,28-基座,29-支杆,30-轴座,31-转轴,32-夹勾,33-遮光板。
具体实施方式
下面通过实施例,并结合附图,对本发明的技术方案作进一步具体的说明。
实施例1:参看图1,本发明红反膜系滤光板的第一种膜系设计结构示意图中,透明基板为PC或PMMA,PC或PMMA基板上依次设有第一层TiO 2薄膜、第二层SiO 2薄膜、第三层TiO 2薄膜、第四层SiO 2薄膜、第五层TiO 2薄膜、第六层SiO 2薄膜、第七层TiO 2薄膜、第八层SiO 2薄膜、第九层TiO 2薄膜、第十层SiO 2薄膜、第十一层TiO 2薄膜、第十二层SiO 2薄膜、第十三层SiO 2薄膜,镀膜工艺要求为,光源:白光,基底:PC或PMMA,角度:0.0(deg),入射介质:空气,出射介质:PC或PMMA,参考:690.0nm,探测器:Ideal。其中第一层TiO 2薄膜的物理厚度为13.79±10%nm,第二层SiO 2薄膜的物理厚度为180.31±10%nm,第三层TiO 2薄膜的物理厚度为280.43±10%nm,第四层SiO 2薄膜的物理厚度为154.38±10%nm,第五层TiO 2薄膜的物理厚度为212.12±10%nm,第六层SiO 2薄膜的物理厚度为167.33±10%nm,第七层TiO 2薄膜的物理厚度为30.63±10%nm,第八层SiO 2薄膜的物理厚度为183.72±10%nm,第九层TiO 2薄膜的物理厚度为27.42±10%nm,第十层SiO 2薄膜的物理厚度为162.63±10%nm,第十一层TiO 2薄膜的物理厚度为223.38±10%nm,第十二层SiO 2薄膜的物理厚度为55.33±10%nm,第十三层SiO 2薄膜的物理厚度为180.64±10%nm;优选地,所述PC或PMMA基板上,第一层TiO 2薄膜的物理厚度为13.79±5%nm,第二层SiO 2薄膜的物理厚度为180.31±5%nm,第三层TiO 2薄膜的物理厚度为280.43± 5%nm,第四层SiO 2薄膜的物理厚度为154.38±5%nm,第五层TiO 2薄膜的物理厚度为212.12±5%nm,第六层SiO 2薄膜的物理厚度为167.33±5%nm,第七层TiO 2薄膜的物理厚度为30.63±5%nm,第八层SiO 2薄膜的物理厚度为183.72±5%nm,第九层TiO 2薄膜的物理厚度为27.42±5%nm,第十层SiO 2薄膜的物理厚度为162.63±5%nm,第十一层TiO 2薄膜的物理厚度为223.38±5%nm,第十二层SiO 2薄膜的物理厚度为55.33±5%nm,第十三层SiO 2薄膜的物理厚度为180.64±5%nm;最佳地,所述PC或PMMA基板上,第一层TiO 2薄膜的物理厚度为13.79nm,第二层SiO 2薄膜的物理厚度为180.31nm,第三层TiO 2薄膜的物理厚度为280.43nm,第四层SiO 2薄膜的物理厚度为154.38nm,第五层TiO 2薄膜的物理厚度为212.12nm,第六层SiO 2薄膜的物理厚度为167.33nm,第七层TiO 2薄膜的物理厚度为30.63nm,第八层SiO 2薄膜的物理厚度为183.72nm,第九层TiO 2薄膜的物理厚度为27.42nm,第十层SiO 2薄膜的物理厚度为162.63nm,第十一层TiO 2薄膜的物理厚度为223.38nm,第十二层SiO 2薄膜的物理厚度为55.33nm,第十三层SiO 2薄膜的物理厚度为180.64nm。
一种上述红反膜系滤光板在抗刹车灯眩目方面的应用,具有上述红反膜系滤光板的抗刹车灯眩目滤光器为护目镜,护目镜的结构为现有技术,护目镜的镜片包括所述的红反膜系滤光板;或者参看图3-图5,具有上述红反膜系滤光板的抗刹车灯眩目滤光器为夹持在汽车的遮光板上的车载装置,其中红反膜系滤光板的上边缘设有条框,条框的中部设有基座,基座上设有支杆,支杆的端部设有夹勾,夹勾勾置并夹持汽车的遮光板,籍此将所述车载装置夹持在汽车的遮光板上,所述支杆的上端设有轴座,支杆的上端经由转轴设置在轴座上,所述夹勾设置在轴座上,所述支杆为伸缩杆。
本发明的红反膜系滤光板采用真空离子源辅助沉积(IDA)工艺,优选膜系组合及膜系设计精准控制,选择性地将可见光波段中610nm~720nm的红光反射并使其透过率降低到20%左右,参看图7,人眼感觉舒适,基本不影响环境光亮度,利于行车安全。
本发明的滤光器佩戴在眼部或者夹持在汽车的遮光板上,使用方便;车载装置中支杆的上端经由转轴设置在轴座上,可以翻折红反膜系滤光板,收纳和使用都很方便,支杆设置为伸缩杆,可以上下调整滤光板,以适应不同人群。因此本发明具有结构简单、设计合理等特点。
实施例2:参看图2,本发明红反膜系滤光板的第二种膜系设计结构示意图中,透明基板为CR-39,CR-39基板上依次设有第一层MgF 2薄膜、第二层TiO 2薄膜、第三层MgF 2薄膜、第四层TiO 2薄膜、第五层MgF 2薄膜、第六层TiO 2薄膜、第七层MgF 2薄膜、第八层TiO 2薄膜、第九层MgF 2薄膜、第十层TiO 2薄膜、第十一层MgF 2薄膜,镀膜工艺要求为,光源:白光,基底:CR-39,角度:0.0(deg),入射介质:空气,出射介质:CR-39,参考:680.0nm,探测器:Ideal,偏振:Ave-,第一面:front。其中第一层MgF 2薄膜的物理厚度为123.19±10%nm,第二层TiO 2薄膜的物理厚度为230.60±10%nm,第三层MgF 2薄膜的物理厚度为369.57±10%nm,第四层TiO 2薄膜的物理厚度为230.60±10%nm,第五层MgF 2薄膜的物理厚度为369.57±10%nm,第六层TiO 2薄膜的物理厚度为230.60±10%nm,第七层MgF 2薄膜的物理厚度为369.57±10%nm,第八层TiO 2薄膜的物理厚度为230.60±10%nm, 第九层MgF 2薄膜的物理厚度为369.57±10%nm,第十层TiO 2薄膜的物理厚度为230.60±10%nm,第十一层MgF 2薄膜的物理厚度为123.19±10%nm;优选地,所述CR-39基板上,第一层MgF 2薄膜的物理厚度为123.19±5%nm,第二层TiO 2薄膜的物理厚度为230.60±5%nm,第三层MgF 2薄膜的物理厚度为369.57±5%nm,第四层TiO 2薄膜的物理厚度为230.60±5%nm,第五层MgF 2薄膜的物理厚度为369.57±5%nm,第六层TiO 2薄膜的物理厚度为230.60±5%nm,第七层MgF 2薄膜的物理厚度为369.57±5%nm,第八层TiO 2薄膜的物理厚度为230.60±5%nm,第九层MgF 2薄膜的物理厚度为369.57±5%nm,第十层TiO 2薄膜的物理厚度为230.60±5%nm,第十一层MgF 2薄膜的物理厚度为123.19±5%nm;最佳地,所述CR-39基板上,第一层MgF 2薄膜的物理厚度为123.19nm,第二层TiO 2薄膜的物理厚度为230.60nm,第三层MgF 2薄膜的物理厚度为369.57nm,第四层TiO 2薄膜的物理厚度为230.60nm,第五层MgF 2薄膜的物理厚度为369.57nm,第六层TiO 2薄膜的物理厚度为230.60nm,第七层MgF 2薄膜的物理厚度为369.57nm,第八层TiO 2薄膜的物理厚度为230.60nm,第九层MgF 2薄膜的物理厚度为369.57nm,第十层TiO 2薄膜的物理厚度为230.60nm,第十一层MgF 2薄膜的物理厚度为123.19nm。其余参考实施例1。
最后,应当指出,以上实施例仅是本发明较有代表性的例子。显然,本发明不限于上述实施例,还可以有许多变形。凡是依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰,均应认为属于本发明的保护范围。

Claims (8)

  1. 一种红反膜系滤光板,包括透明基板,其特征在于所述基板为PC或PMMA,PC或PMMA基板上依次设有第一层TiO 2薄膜、第二层SiO 2薄膜、第三层TiO 2薄膜、第四层SiO 2薄膜、第五层TiO 2薄膜、第六层SiO 2薄膜、第七层TiO 2薄膜、第八层SiO 2薄膜、第九层TiO 2薄膜、第十层SiO 2薄膜、第十一层TiO 2薄膜、第十二层SiO 2薄膜、第十三层SiO 2薄膜,其中第一层TiO 2薄膜的物理厚度为13.79±10%nm,第二层SiO 2薄膜的物理厚度为180.31±10%nm,第三层TiO 2薄膜的物理厚度为280.43±10%nm,第四层SiO 2薄膜的物理厚度为154.38±10%nm,第五层TiO 2薄膜的物理厚度为212.12±10%nm,第六层SiO 2薄膜的物理厚度为167.33±10%nm,第七层TiO 2薄膜的物理厚度为30.63±10%nm,第八层SiO 2薄膜的物理厚度为183.72±10%nm,第九层TiO 2薄膜的物理厚度为27.42±10%nm,第十层SiO 2薄膜的物理厚度为162.63±10%nm,第十一层TiO 2薄膜的物理厚度为223.38±10%nm,第十二层SiO 2薄膜的物理厚度为55.33±10%nm,第十三层SiO 2薄膜的物理厚度为180.64±10%nm;或者所述基板为CR-39,CR-39基板上依次设有第一层MgF 2薄膜、第二层TiO 2薄膜、第三层MgF 2薄膜、第四层TiO 2薄膜、第五层MgF 2薄膜、第六层TiO 2薄膜、第七层MgF 2薄膜、第八层TiO 2薄膜、第九层MgF 2薄膜、第十层TiO 2薄膜、第十一层MgF 2薄膜,其中第一层MgF 2薄膜的物理厚度为123.19±10%nm,第二层TiO 2薄膜的物理厚度为230.60±10%nm,第三层MgF 2薄膜的物理厚度为369.57±10%nm,第四层TiO 2薄膜的物理厚度为230.60±10%nm,第五层MgF 2薄膜的物理厚度为369.57±10%nm,第六层TiO 2薄膜的物理厚度为230.60±10%nm,第七层MgF 2薄膜的物理厚度为369.57±10%nm,第八层TiO 2薄膜的物理厚度为230.60±10%nm,第九层MgF 2薄膜的物理厚度为369.57±10%nm,第十层TiO 2薄膜的物理厚度为230.60±10%nm,第十一层MgF 2薄膜的物理厚度为123.19±10%nm。
  2. 根据权利要求1所述的一种红反膜系滤光板,其特征在于所述PC或PMMA基板上,第一层TiO 2薄膜的物理厚度为13.79±5%nm,第二层SiO 2薄膜的物理厚度为180.31±5%nm,第三层TiO 2薄膜的物理厚度为280.43±5%nm,第四层SiO 2薄膜的物理厚度为154.38±5%nm,第五层TiO 2薄膜的物理厚度为212.12±5%nm,第六层SiO 2薄膜的物理厚度为167.33±5%nm,第七层TiO 2薄膜的物理厚度为30.63±5%nm,第八层SiO 2薄膜的物理厚度为183.72±5%nm,第九层TiO 2薄膜的物理厚度为27.42±5%nm,第十层SiO 2薄膜的物理厚度为162.63±5%nm,第十一层TiO 2薄膜的物理厚度为223.38±5%nm,第十二层SiO 2薄膜的物理厚度为55.33±5%nm,第十三层SiO 2薄膜的物理厚度为180.64±5%nm;所述CR-39基板上,第一层MgF 2薄膜的物理厚度为123.19±5%nm,第二层TiO 2薄膜的物理厚度为230.60±5%nm,第三层MgF 2薄膜的物理厚度为369.57±5%nm,第四层TiO 2薄膜的物理厚度为230.60±5%nm,第五层MgF 2薄膜的物理厚度为369.57±5%nm,第六层TiO 2薄膜的物理厚度为230.60±5%nm,第七层MgF 2薄膜的物理厚度为369.57±5%nm,第八层TiO 2薄膜的物理厚度为230.60±5%nm,第九层MgF 2薄膜的物理厚度为369.57±5%nm,第十层TiO 2薄膜的物理厚度为230.60±5%nm,第十一层MgF 2薄膜的物理厚度为123.19±5%nm。
  3. 根据权利要求1所述的一种红反膜系滤光板,其特征在于所述PC或PMMA基板上, 第一层TiO 2薄膜的物理厚度为13.79nm,第二层SiO 2薄膜的物理厚度为180.31nm,第三层TiO 2薄膜的物理厚度为280.43nm,第四层SiO 2薄膜的物理厚度为154.38nm,第五层TiO 2薄膜的物理厚度为212.12nm,第六层SiO 2薄膜的物理厚度为167.33nm,第七层TiO 2薄膜的物理厚度为30.63nm,第八层SiO 2薄膜的物理厚度为183.72nm,第九层TiO 2薄膜的物理厚度为27.42nm,第十层SiO 2薄膜的物理厚度为162.63nm,第十一层TiO 2薄膜的物理厚度为223.38nm,第十二层SiO 2薄膜的物理厚度为55.33nm,第十三层SiO 2薄膜的物理厚度为180.64nm;所述CR-39基板上,第一层MgF 2薄膜的物理厚度为123.19nm,第二层TiO 2薄膜的物理厚度为230.60nm,第三层MgF 2薄膜的物理厚度为369.57nm,第四层TiO 2薄膜的物理厚度为230.60nm,第五层MgF 2薄膜的物理厚度为369.57nm,第六层TiO 2薄膜的物理厚度为230.60nm,第七层MgF 2薄膜的物理厚度为369.57nm,第八层TiO 2薄膜的物理厚度为230.60nm,第九层MgF 2薄膜的物理厚度为369.57nm,第十层TiO 2薄膜的物理厚度为230.60nm,第十一层MgF 2薄膜的物理厚度为123.19nm。
  4. 一种权利要求1或2或3所述红反膜系滤光板在抗刹车灯眩目方面的应用。
  5. 一种具有权利要求1或2或3所述红反膜系滤光板的抗刹车灯眩目滤光器,其特征在于所述滤光器为护目镜,护目镜的镜片包括所述的红反膜系滤光板。
  6. 一种具有权利要求1或2或3所述红反膜系滤光板的抗刹车灯眩目滤光器,其特征在于所述滤光器为夹持在汽车的遮光板上的车载装置,其中红反膜系滤光板的上边缘设有条框,条框的中部设有基座,基座上设有支杆,支杆的端部设有夹勾,夹勾勾置并夹持汽车的遮光板,籍此将所述车载装置夹持在汽车的遮光板上。
  7. 根据权利要求6所述的抗刹车灯眩目滤光器,其特征在于所述支杆的上端设有轴座,支杆的上端经由转轴设置在轴座上,所述夹勾的基部设置在轴座上。
  8. 根据权利要求6或7所述的抗刹车灯眩目滤光器,其特征在于所述支杆为伸缩杆。
PCT/CN2020/085735 2019-02-18 2020-04-20 红反膜系滤光板和其在抗刹车灯眩目方面的应用及滤光器 WO2020169119A1 (zh)

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