WO2020122390A1 - Polymère superabsorbant et son procédé de préparation - Google Patents

Polymère superabsorbant et son procédé de préparation Download PDF

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Publication number
WO2020122390A1
WO2020122390A1 PCT/KR2019/013302 KR2019013302W WO2020122390A1 WO 2020122390 A1 WO2020122390 A1 WO 2020122390A1 KR 2019013302 W KR2019013302 W KR 2019013302W WO 2020122390 A1 WO2020122390 A1 WO 2020122390A1
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Prior art keywords
polymer
surface crosslinking
crosslinking agent
superabsorbent polymer
base resin
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PCT/KR2019/013302
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English (en)
Korean (ko)
Inventor
박보희
김준규
김동현
Original Assignee
주식회사 엘지화학
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Priority claimed from KR1020190124302A external-priority patent/KR102417829B1/ko
Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to US17/270,338 priority Critical patent/US20210322953A1/en
Priority to CN201980053547.9A priority patent/CN112585194B/zh
Priority to JP2020556904A priority patent/JP7191403B2/ja
Priority to EP19896240.9A priority patent/EP3819329A4/fr
Publication of WO2020122390A1 publication Critical patent/WO2020122390A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/02—Making granules by dividing preformed material
    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00—Making preforms
    • B29B11/06—Making preforms by moulding the material
    • B29B11/10—Extrusion moulding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00—Making preforms
    • B29B11/14—Making preforms characterised by structure or composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B13/00—Conditioning or physical treatment of the material to be shaped
    • B29B13/06—Conditioning or physical treatment of the material to be shaped by drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/12—Making granules characterised by structure or composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/071—Preforms or parisons characterised by their configuration, e.g. geometry, dimensions or physical properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00—Indexing scheme relating to blow-moulding
    • B29C2949/07—Preforms or parisons characterised by their configuration
    • B29C2949/0715—Preforms or parisons characterised by their configuration the preform having one end closed

Definitions

  • the present invention relates to a superabsorbent polymer and a method for manufacturing the same, which not only has excellent basic absorption performance, but also exhibits improved pressurized liquid permeability, which can improve the rewet and leakage control properties of sanitary materials such as diapers.
  • Super Absorbent Polymer is a synthetic polymer material that has the ability to absorb about 500 to 1,000 times its own weight, and SAM (Super Absorbency Material), AGM (Absorbent Gel) for each developer Material).
  • SAM Super Absorbency Material
  • AGM Absorbent Gel
  • the superabsorbent polymer as described above began to be put into practical use as a sanitary tool, and now, in addition to sanitary products such as children's paper diapers, soil repair agents for horticulture, civil engineering, construction index materials, nursery sheets, and freshness retention agents in the food distribution field, and It is widely used as a material for poultice.
  • these superabsorbent polymers are widely used in the field of sanitary materials such as diapers and sanitary napkins. For this purpose, it is necessary to show a high absorption capacity for moisture, etc., and excellent pressurization that does not escape moisture absorbed by external pressure. It is necessary to show the absorption performance and the like.
  • the superabsorbent polymer when the superabsorbent polymer is contained in a hygiene material such as a diaper, it is necessary to diffuse urine and the like as wide as possible even in an environment that is pressurized by a user's weight. Through this, it is possible to further improve the absorption performance and the absorption rate of the hygiene material by utilizing the superabsorbent polymer particles contained in the entire area of the hygienic material absorption layer as a whole. In addition, due to the diffusion characteristics under pressure, the rewet characteristics of diapers that suppress urine and the like once absorbed by the superabsorbent polymer can be further improved, and at the same time, the diaper leakage suppression characteristics can be improved. It becomes possible.
  • the present invention is to provide a superabsorbent polymer and a method of manufacturing the same, which not only has excellent basic absorption performance, but also exhibits improved pressure and liquid permeability, which can further improve the rewet characteristics of hygiene materials such as diapers.
  • the present invention is a base resin powder comprising a first crosslinked polymer of a water-soluble ethylenically unsaturated monomer having an acidic group at least partially neutralized;
  • the first crosslinked polymer is a super absorbent polymer comprising a surface crosslinking layer comprising a second crosslinked polymer further crosslinked via a surface crosslinking agent,
  • the surface crosslinking agent provides a superabsorbent polymer comprising a polymer type first surface crosslinking agent having a number average molecular weight of 300 or more and having a plurality of hydroxy groups or epoxy groups.
  • the present invention in the presence of an internal crosslinking agent, crosslinking polymerization of a water-soluble ethylenically unsaturated monomer having an acidic group at least partially neutralized to form a hydrogel polymer comprising a first crosslinked polymer;
  • the surface crosslinking agent has a number average molecular weight of 300 or more and provides a method for producing a super absorbent polymer comprising a polymer type first surface crosslinking agent having a plurality of hydroxy groups or epoxy groups.
  • the base resin powder comprising a first crosslinked polymer of a water-soluble ethylenically unsaturated monomer having at least a partially neutralized acid group
  • the first crosslinked polymer is a super absorbent polymer comprising a surface crosslinking layer comprising a second crosslinked polymer further crosslinked via a surface crosslinking agent,
  • the surface crosslinking agent is provided with a superabsorbent polymer comprising a polymer type first surface crosslinking agent having a number average molecular weight of 300 or more and having a plurality of hydroxy groups or epoxy groups.
  • the superabsorbent polymer of one embodiment is to include a polymer-type first surface crosslinking agent having a number average molecular weight of 300 or more and a crosslinkable functional group in order to form a surface crosslinking layer.
  • the polymer type first surface crosslinking agent contains polymer chains having a molecular weight of a certain level or higher, it is difficult to penetrate deeply into the base resin powder when crosslinking the surface, and most of the crosslinking structure is formed by crosslinking near the surface of the base resin powder. Therefore, the superabsorbent polymer formed in this way can increase the crosslinking density of the surface near the surface without significantly increasing the overall amount of the surface crosslinking agent during the manufacturing process, and further, the high surface-derived crosslinking agent derived from the first surface crosslinking agent near the surface. A higher molecular weight polymer structure can be included.
  • the superabsorbent polymer of one embodiment exhibits a harder surface property in the vicinity of the surface, it may exhibit improved pressure-permeable properties than previously known, and accordingly, it may further improve the hygroscopic material's repellent property or leak-inhibiting property. have.
  • the superabsorbent polymer does not need to use an excessively high content of a surface crosslinking agent in order to realize such a hard surface property, so that the internal crosslinking density can maintain an appropriate level, and as a result, water absorption performance such as water retention capacity It can keep excellent.
  • the superabsorbent polymer of one embodiment can improve the rewetting characteristics of hygiene materials, such as diapers, by exhibiting improved pressure-permeability while maintaining excellent basic absorption performance.
  • the term'superabsorbent polymer' referred to herein refers to a base resin powder comprising a first crosslinked polymer of a water-soluble ethylenically unsaturated monomer having an acidic group at least partially neutralized; And it is formed on the base resin powder, the first crosslinked polymer means a superabsorbent polymer comprising a surface crosslinking layer including a second crosslinked polymer further crosslinked via a surface crosslinking agent.
  • the water-soluble ethylenically unsaturated monomer may be any monomer commonly used in the production of super absorbent polymers.
  • the water-soluble ethylenically unsaturated monomer may be a compound represented by Formula 1 below:
  • R 1 is an alkyl group having 2 to 5 carbon atoms containing an unsaturated bond
  • M 1 is a hydrogen atom, a monovalent or divalent metal, an ammonium group or an organic amine salt.
  • the monomer may be at least one selected from the group consisting of acrylic acid, methacrylic acid, and monovalent metal salts, divalent metal salts, ammonium salts and organic amine salts of these acids.
  • acrylic acid or a salt thereof is used as the water-soluble ethylenically unsaturated monomer, it is advantageous to obtain a super absorbent polymer with improved water absorption.
  • the monomers include maleic anhydride, fumaric acid, crotonic acid, itaconic acid, 2-acryloylethane sulfonic acid, 2-methacryloylethanesulfonic acid, 2-(meth)acryloylpropanesulfonic acid, or 2-( Anionic monomers of meth)acrylamide-2-methyl propane sulfonic acid and salts thereof; (Meth)acrylamide, N-substituted (meth)acrylate, 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, methoxypolyethylene glycol (meth)acrylate or polyethylene glycol ( Nonionic hydrophilic monomers of meth)acrylate; And an amino group-containing unsaturated monomer of (N,N)-dimethylaminoethyl (meth)acrylate or (N,N)-dimethylaminopropyl (meth)acrylamide, and a quaternary product thereof.
  • the water-soluble ethylenically unsaturated monomer has an acidic group, and at least a portion of the acidic group may be neutralized.
  • the monomer may be partially neutralized with an alkali material such as sodium hydroxide, potassium hydroxide or ammonium hydroxide.
  • the neutralization degree of the monomer may be 40 to 95 mol%, or 40 to 80 mol%, or 45 to 75 mol%.
  • the range of the degree of neutralization may vary depending on the final physical properties, but if the degree of neutralization is too high, the neutralized monomer may be precipitated and polymerization may not proceed smoothly. It can exhibit properties such as elastic rubber that are difficult to handle.
  • the'first crosslinked polymer' means that the aforementioned water-soluble ethylenically unsaturated monomer is crosslinked and polymerized in the presence of an internal crosslinking agent, and the'base resin powder' refers to such a first crosslinked polymer. It means a substance containing.
  • the'second crosslinked polymer' means a material in which the first crosslinked polymer is additionally crosslinked through a surface crosslinking agent, and a surface crosslinking layer including the same is formed on the base resin powder.
  • the first crosslinked polymer contained in the base resin powder includes bis(meth)acrylamide having 8 to 12 carbon atoms, poly(meth)acrylate of a polyol having 2 to 10 carbon atoms, and 2 to 10 carbon atoms.
  • the monomer may be a crosslinked polymerized polymer.
  • the internal crosslinking agent are not particularly limited, but trimethylolpropane tri(meth)acrylate, ethylene glycol di(meth)acrylate, polyethylene glycol di(meth)acrylate, and propylene glycol di(meth)acrylate , Polypropylene glycol di(meth)acrylate, butanediol di(meth)acrylate, butylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, hexanediol di(meth)acrylate , Triethylene glycol di(meth)acrylate, tripropylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, dipentaerythritol pentaacrylate, glycerin tri(meth)acrylate or pentaerythritol tetra Acrylate, and the like, and in addition, various internal crosslinking agents known to be usable for the production of super absorbent poly
  • the A surface crosslinking layer is formed.
  • the first surface crosslinking agent is 300 or more, or 300 to 30000, or a number average molecular weight of 350 to 15000, and a functional group capable of reacting with the carboxyl group, specifically, a polyhydric polymer having a plurality of hydroxyl groups or epoxy groups, all without particular limitations Can be used.
  • a polymer-type crosslinking agent include polyglycidyl ether-based polyols such as polyethylene glycol-based polymers, polypropylene glycol-based polymers, and diglycidyl ethers of polyalkylene glycols. And one or more selected from the group consisting of polymers and polyvinyl alcohol-based polymers.
  • a surface crosslinking agent having a molecular weight or a number average molecular weight not exceeding the above range is used as the first surface crosslinking agent (for example, when two types of surface crosslinking agents having no polymer form are used), pressurization of the superabsorbent polymer
  • the liquid permeability may be poor, and as a result, the hygienic material's reset property or water leakage control property may not be sufficient.
  • the superabsorbent polymer of one embodiment may include a crosslinking structure derived therefrom by using a second surface crosslinking agent having a molecular weight of less than 300 in addition to the polymer type first surface crosslinking agent.
  • the second surface cross-linking agent a single-molecule type surface cross-linking agent that has been used in the manufacture of super absorbent polymers can be used without any limitation.
  • the surface crosslinking agent is ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, 1,2-hexanediol, 1,3-hexanediol, 2- One selected from the group consisting of methyl-1,3-propanediol, 2,5-hexanediol, 2-methyl-1,3-pentanediol, 2-methyl-2,4-pentanediol, tripropylene glycol and glycerol Or more polyols; At least one alkylene carbonate-based compound selected from the group consisting of ethylene carbonate and propylene carbonate; Epoxy compounds such as alkylene glycol diglycidyl ether; Oxazoline compounds
  • the superabsorbent polymer of one embodiment uses a plurality of surface crosslinking agents, in particular, a polymer type first surface crosslinking agent together with a second surface crosslinking agent, without significantly increasing the overall amount/content of the surface crosslinking agent.
  • the crosslinking density in the vicinity can be further increased. Therefore, as the superabsorbent polymer of one embodiment exhibits a harder surface property in the vicinity of the surface, it may exhibit improved pressure-permeable properties than previously known, and accordingly, it may further improve the hygroscopic material's repellent property or leak-inhibiting property. have.
  • the crosslinking structure derived from the first surface crosslinking agent is present in the highest ratio on the outermost surface of the surface crosslinking layer, and the deeper the depth of the surface crosslinking layer, The rate of existence may be lowered.
  • first surface crosslinking agent: second surface crosslinking agent may be included in a weight ratio of 3:1 to 1:3, or 2.5:1 to 1:2.5, or 2:1 to 1:2.
  • the surface of the superabsorbent polymer can be made more firm, and the pressure-permeable liquid of the superabsorbent polymer, the leakage property of the hygiene material, or the leak suppressing property can be further improved, and the absorbent performance of the superabsorbent polymer can also be excellently maintained.
  • the superabsorbent polymer of the above-described embodiment may further use aluminum salts such as aluminum sulfate salts and various other polyvalent metal salts during surface crosslinking for further improvement such as liquid permeability.
  • aluminum salts such as aluminum sulfate salts and various other polyvalent metal salts during surface crosslinking for further improvement such as liquid permeability.
  • Such a polyvalent metal salt may be included on the surface crosslinked layer of the final superabsorbent polymer.
  • the superabsorbent polymer of the above-described embodiment may have a particle diameter of 150 to 850 ⁇ m. More specifically, at least 95% by weight or more of the base resin powder and the superabsorbent polymer including the same may have a particle diameter of 150 to 850 ⁇ m, and may include 50% by weight or more of particles having a particle diameter of 300 to 600 ⁇ m, 150 The fine powder having a particle diameter of less than ⁇ m may be less than 3% by weight.
  • the superabsorbent polymer of the above-described embodiment while maintaining excellent water absorption performance, such as basic water retention capacity, may exhibit improved pressure-permeability.
  • the excellent absorption performance of the super absorbent polymer of one embodiment may be defined by water retention capacity and pressure absorption capacity. More specifically, the superabsorbent polymer may have a centrifugal water retention capacity (CRC) of 30 to 40 g/g for 30 minutes for physiological saline (0.9 wt% sodium chloride aqueous solution). . Such a centrifugal water retention capacity (CRC) range may define an excellent unpressurized absorption performance exhibited by the superabsorbent polymer of one embodiment.
  • CRC centrifugal water retention capacity
  • the superabsorbent polymer may have a pressure absorption capacity (AUP) of 0.7 psi, measured according to EDANA method WSP 242.3-10, of 15 to 27 g/g, or 20 to 25 g/g.
  • AUP pressure absorption capacity
  • Such a pressure absorbing capacity range may define an excellent absorbing performance under pressure indicated by the superabsorbent polymer of one embodiment.
  • the improved pressure-permeability of the super absorbent polymer can be defined by the properties of GPUP.
  • GPUPs were swelled in physiological saline (0.9 wt% sodium chloride aqueous solution) for 1 hour under the pressure of 0.3 psi of the superabsorbent polymer, and when the physiological saline was flowed into the superabsorbent polymer, 5 drops from the point of dropping. It can be measured at a flow rate for a minute. More specific measurement methods thereof are described in the experimental examples described later.
  • the superabsorbent polymer of one embodiment may have the GPUP of 5 ⁇ 10E-13m 2 or more, or of 5 to 30 ⁇ 10E-13m 2 , or of 7 to 25 ⁇ 10E-13m 2 , thereby exhibiting excellent press-through properties. have.
  • the superabsorbent polymer of the above-described embodiment can improve the resorption properties of the hygiene material and the like, while maintaining improved pressure-permeability than previously known, while maintaining excellent absorbent performance.
  • the superabsorbent polymer that satisfies all the physical properties of the above-described one embodiment, after obtaining a hydrogel polymer by crosslinking polymerization, drying, grinding and classifying it to form a base resin powder, surface crosslinking process in the presence of a specific surface crosslinking agent It can be produced by a manufacturing method comprising a.
  • a method for manufacturing the superabsorbent polymer described above comprises the steps of crosslinking and polymerizing a water-soluble ethylenically unsaturated monomer having an acidic group at least partially neutralized in the presence of an internal crosslinking agent to form a hydrogel polymer comprising a first crosslinked polymer; Drying, grinding and classifying the hydrogel polymer to form a base resin powder; And in the presence of a surface crosslinking agent, heat-treating the base resin powder to crosslink the surface,
  • the surface crosslinking agent may have a number average molecular weight of 300 or more, and may include a polymer type first surface crosslinking agent having a functional group capable of reacting with a carboxyl group, specifically, a plurality of hydroxy groups or epoxy groups.
  • the manufacturing method of another embodiment includes forming a hydrogel polymer by crosslinking polymerization. Specifically, it is a step of forming a hydrogel polymer by thermal polymerization or photopolymerization of a monomer composition comprising a water-soluble ethylenically unsaturated monomer and a polymerization initiator in the presence of an internal crosslinking agent.
  • the water-soluble ethylenically unsaturated monomer contained in the monomer composition is as described above.
  • the monomer composition may include a polymerization initiator generally used in the production of super absorbent polymers.
  • the polymerization initiator may be a thermal polymerization initiator or a photo polymerization initiator depending on the polymerization method.
  • a thermal polymerization initiator may be additionally included.
  • benzoin ether (benzoin ether), dialkyl acetophenone (dialkyl acetophenone), hydroxyl alkyl ketone (hydroxyl alkylketone), phenyl glyoxylate (phenyl glyoxylate), benzyl dimethyl
  • benzoin ether dialkyl acetophenone
  • dialkyl acetophenone dialkyl acetophenone
  • hydroxyl alkyl ketone hydroxyl alkylketone
  • phenyl glyoxylate phenyl glyoxylate
  • benzyl dimethyl One or more compounds selected from the group consisting of Benzyl Dimethyl Ketal, acyl phosphine, and a-aminoketone may be used.
  • acylphosphine a commercially available lucirin TPO, that is, 2,4,6-trimethyl-benzoyl-trimethyl phosphine oxide (2,4,6-trimethyl-benzoyl-trimethyl phosphine oxide) can be used.
  • 2,4,6-trimethyl-benzoyl-trimethyl phosphine oxide 2,4,6-trimethyl-benzoyl-trimethyl phosphine oxide
  • More various photopolymerization initiators are disclosed on page 115 of Reinhold Schwalm's book “UV Coatings: Basics, Recent Developments and New Application (Elsevier 2007)", which can be referred to.
  • thermal polymerization initiator one or more compounds selected from the group consisting of a persulfate-based initiator, an azo-based initiator, hydrogen peroxide, and ascorbic acid may be used.
  • a persulfate-based initiator sodium persulfate (Na 2 S 2 O 8 ), potassium persulfate (K 2 S 2 O 8 ), ammonium persulfate (Ammonium persulfate; (NH 4 ) 2 S 2 O 8 ) and the like.
  • the polymerization initiator may be added in a concentration of 0.001 to 1% by weight relative to the monomer composition. That is, when the concentration of the polymerization initiator is too low, the polymerization rate may be slow, and residual monomers in the final product may be extracted in large quantities, which is not preferable. On the contrary, when the concentration of the polymerization initiator is too high, the polymer chain forming the network is shortened, so the content of the water-soluble component is increased and the pressure absorption capacity is lowered.
  • the monomer composition includes a crosslinking agent ("internal crosslinking agent”) for improving the physical properties of the resin by polymerization of the water-soluble ethylenically unsaturated monomer.
  • the crosslinking agent is for internally crosslinking the hydrogel polymer, and can be used separately from the “surface crosslinking agent” described later.
  • the internal crosslinking agent already described above for example, bis(meth)acrylamide having 8 to 12 carbons, poly(meth)acrylate of polyol having 2 to 10 carbons or 2 to 10 carbons
  • Poly(meth)allyl ethers of polyols can be used, and as a result, a hydrogel polymer with appropriate internal crosslinking can be obtained.
  • the type of the internal crosslinking agent has already been described above, additional description thereof will be omitted.
  • the internal cross-linking agent may be a content of 0.4 parts by weight to 2 parts by weight, or 0.4 to 1.8 parts by weight with respect to 100 parts by weight of the monomer composition including the internal cross-linking agent and the monomer.
  • the internal crosslinking degree of the hydrogel polymer and the base resin powder is adjusted, so that the absorption performance and liquid permeability of the super absorbent polymer can be optimized.
  • the content of the internal crosslinking agent is too large, the basic absorption performance of the super absorbent polymer may be deteriorated.
  • the monomer composition may further include additives such as a thickener, a plasticizer, a storage stabilizer, and an antioxidant, if necessary.
  • additives such as a thickener, a plasticizer, a storage stabilizer, and an antioxidant, if necessary.
  • the monomer composition may be prepared in the form of a solution in which raw materials such as the above-described monomer, polymerization initiator, and internal crosslinking agent are dissolved in a solvent.
  • the solvent includes water, ethanol, ethylene glycol, diethylene glycol, triethylene glycol, 1,4-butanediol, propylene glycol, ethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate , Methyl ethyl ketone, acetone, methyl amyl ketone, cyclohexanone, cyclopentanone, diethylene glycol monomethyl ether, diethylene glycol ethyl ether, toluene, xylene, butyrolactone, carbitol, methyl cellosolve acetate, N,N-dimethylacetamide, or mixtures thereof.
  • the formation of a hydrogel polymer through polymerization of the monomer composition may be performed by a conventional polymerization method, and the process is not particularly limited.
  • the polymerization method is largely divided into thermal polymerization and photo polymerization according to the type of polymerization energy source.
  • the thermal polymerization is performed, the polymerization method may be performed in a reactor having a stirring axis such as a kneader, and photo polymerization In the case of proceeding, it may proceed in a reactor equipped with a movable conveyor belt.
  • a hydrogel polymer may be obtained by introducing the monomer composition into a reactor such as a kneader equipped with a stirring shaft, and supplying hot air to it or heating the reactor to thermally polymerize it.
  • a reactor such as a kneader equipped with a stirring shaft
  • the hydrogel polymer discharged to the reactor outlet may be obtained as particles of several millimeters to several centimeters.
  • the hydrogel polymer obtained can be obtained in various forms depending on the concentration and injection speed of the monomer composition to be injected, and a hydrogel polymer having a particle diameter of 2 to 50 mm (average weight) can be usually obtained.
  • a hydrogel polymer in the form of a sheet may be obtained.
  • the thickness of the sheet may vary depending on the concentration and the injection rate of the monomer composition to be injected. In order to ensure the production speed and the like while allowing the entire sheet to be evenly polymerized, it is usually adjusted to a thickness of 0.5 to 10 cm. desirable.
  • the normal water content of the hydrogel polymer obtained in this way may be 40 to 80% by weight.
  • water content refers to a content of moisture occupied with respect to the total weight of the hydrogel polymer, which means the weight of the hydrogel polymer minus the dry polymer weight. Specifically, it is defined as a calculated value by measuring the weight loss due to evaporation of water in the polymer during the drying process by raising the temperature of the polymer through infrared heating. At this time, the drying condition is a method of raising the temperature from room temperature to 180°C and then maintaining it at 180°C. The total drying time is set to 20 minutes including 5 minutes of the temperature rise step to measure the water content.
  • a step of drying the obtained hydrogel polymer is performed. If necessary, in order to increase the efficiency of the drying step, the step of co-grinding the hydrogel polymer before drying may be further performed.
  • the used grinder is not limited in configuration, but specifically, a vertical cutter (Vertical pulverizer), a turbo cutter (Turbo cutter), a turbo grinder (Turbo grinder), a rotary cutting mill (Rotary cutter mill), cutting Cutter mill, disc mill, shred crusher, crusher, chopper, and disc cutter
  • a vertical cutter Very pulverizer
  • turbo cutter Turbo cutter
  • Turbo grinder turbo grinder
  • rotary cutting mill Rotary cutting mill
  • cutting Cutter mill disc mill
  • shred crusher crusher
  • chopper chopper
  • disc cutter rotary cutting mill
  • the coarse crushing step may be pulverized so that the particle diameter of the hydrogel polymer is 2 to 10 mm. Grinding to a particle diameter of less than 2 mm is not technically easy due to the high water content of the hydrogel polymer, and there may also be a phenomenon of agglomeration between the crushed particles. On the other hand, when the particle diameter is crushed to more than 10 mm, the effect of increasing the efficiency of the subsequent drying step may be insignificant.
  • the drying temperature of the drying step may be 150 to 250 °C.
  • the drying temperature is less than 150°C, the drying time is too long and there is a fear that the physical properties of the final superabsorbent polymer may be deteriorated.
  • the drying temperature exceeds 250°C, only the polymer surface is dried excessively, and a subsequent grinding process is performed. In the fine powder may be generated, there is a fear that the physical properties of the superabsorbent polymer to be formed finally decreases. Therefore, preferably, the drying may be performed at a temperature of 150 to 200 °C, more preferably at a temperature of 170 to 195 °C.
  • process efficiency may be considered, and may be performed for 20 to 90 minutes, but is not limited thereto.
  • the drying method of the drying step is also commonly used as a drying process of the hydrogel polymer, it can be selected and used without limitation of its configuration. Specifically, the drying step may be performed by a method such as hot air supply, infrared irradiation, microwave irradiation, or ultraviolet irradiation.
  • the moisture content of the polymer after the drying step may be about 0.1 to about 10% by weight.
  • the polymer powder obtained after the grinding step may have a particle size of 150 to 850 ⁇ m.
  • the pulverizer used for pulverizing to such a particle size is specifically, a pin mill, a hammer mill, a screw mill, a roll mill, a disc mill or a jog. It is possible to use a mill (jog mill), but is not limited to the above example.
  • a separate process of classifying the polymer powder obtained after crushing according to the particle size may be performed.
  • a polymer having a particle diameter of 150 to 850 ⁇ m is classified, and only a polymer powder having such a particle diameter can be commercialized through a surface crosslinking reaction step.
  • the classified base resin powder has a particle diameter of 150 to 850 ⁇ m, and may include 50 wt% or more of particles having a particle diameter of 300 to 600 ⁇ m.
  • the base resin powder may be surface-crosslinked while heat-treating to form superabsorbent resin particles.
  • the surface crosslinking is to induce a crosslinking reaction on the surface of the base resin powder in the presence of a surface crosslinking agent, and a surface crosslinking layer may be formed on the surface of the base resin powder through such surface crosslinking.
  • a polymer type first surface crosslinking agent having a number average molecular weight of 300 or more is used, and a second surface crosslinking agent having no polymer form can be used together.
  • a polymer type first surface crosslinking agent having a number average molecular weight of 300 or more is used, and a second surface crosslinking agent having no polymer form can be used together.
  • the content of the surface crosslinking agent may be appropriately adjusted according to the specific type of crosslinking agent or reaction conditions, and preferably, the first and second surface crosslinking agents each have a base resin powder of 100 weight. With respect to parts, it may be used in an amount of 0.1 to 2.0 parts by weight, or 0.3 to 1.5 parts by weight, or 0.5 to 1.0.
  • the content of the surface crosslinking agent is too low, surface modification may not be properly performed, and physical properties of the final resin may be deteriorated.
  • the content of the polymer type first surface crosslinking agent is low, the pressure-permeable property of the super absorbent polymer may not be sufficient.
  • the basic absorption performance of the resin may be lowered due to excessive surface crosslinking reaction, which is undesirable.
  • the surface crosslinking agent is added to the base resin powder in the state of a surface crosslinking liquid containing the same, but there is no particular limitation on the structure of the method for adding the surface crosslinking liquid.
  • the surface crosslinking solution and the base resin powder are mixed in a reaction tank, or the surface resin crosslinking solution is sprayed onto the base resin powder, and the base resin powder and the surface crosslinking solution are continuously supplied to the mixer to be mixed and mixed. Method, etc. can be used.
  • the surface crosslinking solution may further include water and/or a hydrophilic organic solvent as a medium.
  • water and/or a hydrophilic organic solvent as a medium.
  • the surface crosslinking agent and the like can be evenly dispersed on the base resin powder.
  • the content of the water and the hydrophilic organic solvent induces even dissolution/dispersion of the surface crosslinking agent and prevents agglomeration of the base resin powder, and at the same time, optimizes the surface penetration depth of the surface crosslinking agent and 100 parts by weight of the base resin powder It can be applied by adjusting the addition ratio to.
  • the base resin powder to which the surface crosslinking solution is added may be heat-treated at a temperature of 140°C to 250°C, or 140°C to 220°C, or 170°C to 210°C for at least 30 minutes. More specifically, the surface crosslinking may be performed by performing the heat treatment for 30 to 80 minutes, or 40 to 70 minutes at the maximum reaction temperature, using the above-mentioned temperature as the maximum reaction temperature, and thereby proceed to the surface crosslinking reaction.
  • the heating means for the surface crosslinking reaction is not particularly limited.
  • the heating medium may be supplied or a heat source may be directly supplied to heat.
  • heated fluid such as steam, hot air, and hot oil may be used, but the present invention is not limited thereto
  • the temperature of the supplied heat medium means the means of the heat medium, the rate of temperature increase and the target temperature of temperature increase. It can be appropriately selected in consideration.
  • the heat source supplied directly may include a heating method through electricity and a gas, but is not limited to the above-described example.
  • the superabsorbent polymer obtained according to the above-described manufacturing method has excellent absorption performance such as water retention capacity and liquid permeability, and can widely diffuse urine absorbed in the hygiene material, it greatly improves the recyclability characteristics of the hygiene material, etc. I can do it.
  • the superabsorbent polymer according to the present invention while maintaining excellent basic absorbent performance and the like, exhibits improved pressurized liquid permeability, and the like, so that urine absorbed by the hygiene material can diffuse rapidly and widely along the surface of the superabsorbent polymer particles. have.
  • the superabsorbent polymer of the present invention can improve the rewet characteristics and the water leakage suppression characteristics of hygiene materials.
  • a monomer composition was prepared by adding 0.008 parts by weight of trimethylbenzoyl)-phosphine oxide and 0.22 parts by weight of polyethylene glycol diacrylate as an internal crosslinking agent.
  • the internal temperature of the monomer composition is maintained at 80°C, and UV light is flowed at a flow rate of 243 kg/hr on a polymerization belt of a continuous belt polymerization reactor in which a UV irradiation device having an intensity of 10 mW is installed as a mercury UV lamp light source 1 Irradiation was performed for a minute, and then the polymerization reaction was performed in a light-free state for 2 minutes.
  • the hydrogel type polymerization sheet was first cut using a shredder type cutter and then coarsely pulverized through a meat chopper. Thereafter, after drying through a hot air dryer at a temperature of 180° C. for 30 minutes, it was pulverized using a rotary mixer and classified into 150 ⁇ m to 850 ⁇ m to prepare a base resin powder.
  • the prepared base resin powder is mixed at a particle size ratio of 10/70/19/1, and 200 parts by weight is prepared.
  • the surface crosslinking solution is 5.4 parts by weight of water, 100 parts by weight of the base resin powder, 0.6 parts by weight of ethylene carbonate, 0.5 parts by weight of a polymer surface crosslinking agent of polyethylene glycol diglycidyl ether having a number average molecular weight of 500, 0.2 parts by weight of propylene glycol, After 0.4 parts by weight of aluminum sulfate 18 hydrate was evenly mixed, the mixture was heated to a temperature of 180° C. and heat-treated for 50 minutes or more to undergo a surface crosslinking reaction. After the surface treatment was completed, a superabsorbent polymer having a particle diameter of 850 ⁇ m or less was obtained using a sheave.
  • Example 2 As the polymer type surface crosslinking agent, a superabsorbent polymer of Example 2 was obtained in the same manner as in Example 1, except that polyethylene glycol diglycidyl ether having a number average molecular weight of 380 was used.
  • Example 3 As the polymer type surface crosslinking agent, a superabsorbent polymer of Example 3 was obtained in the same manner as in Example 1, except that polyvinyl alcohol having a number average molecular weight of 10,000 was used.
  • the superabsorbent polymer of Example 4 was obtained in the same manner as in Example 1, except that the ethylene carbonate was not used and the content of the polymer surface crosslinking agent was changed to 1.1 parts by weight.
  • the superabsorbent polymer of Comparative Example 1 was obtained in the same manner as in Example 1, except that the polymer type surface crosslinking agent was not used.
  • the superabsorbent polymer of Comparative Example 2 was obtained in the same manner as in Example 1, except that the polymer type surface crosslinking agent was not used and the content of ethylene carbonate was changed to 1.1 parts by weight.
  • the superabsorbent polymer of Comparative Example 3 was obtained in the same manner as in Example 1, except that ethylene glycol diglycidyl ether having a molecular weight of about 174 was used instead of the polymer type surface crosslinking agent.
  • the superabsorbent polymer of Comparative Example 4 was obtained in the same manner as in Example 1, except that glycerol triglycidyl ether having a molecular weight of 260 was used instead of the polymer surface crosslinking agent.
  • the particle diameters of the base resin powder and the super absorbent polymer used in Examples and Comparative Examples were measured according to the European Disposables and Nonwovens Association (EDANA) standard EDANA WSP 220.3 method.
  • EDANA European Disposables and Nonwovens Association
  • CRC centrifugal water retention capacity by the unloaded absorption ratio was measured according to the EDANA WSP 241.3 standard of the European Disposables and Nonwovens Association (EDANA).
  • the superabsorbent polymer W 0 g, about 0.2 g was uniformly placed in a nonwoven fabric bag and sealed, and then immersed in physiological saline of 0.9 wt% sodium chloride aqueous solution at room temperature. After 30 minutes, the envelope was centrifuged and drained at 250G for 3 minutes, and then the mass W 2 (g) of the envelope was measured. In addition, after performing the same operation without using a super absorbent polymer, the mass W 1 (g) at that time was measured. Using each mass thus obtained, CRC (g/g) was calculated according to the following Equation 1 to check water retention capacity.
  • AUP Absorbency under Pressure
  • a 400 mesh wire mesh made of stainless steel was mounted on a cylindrical bottom of a plastic having an inner diameter of 60 mm.
  • the resin W 0 (g, 0.90 g) obtained in Examples and Comparative Examples was uniformly spread on a wire mesh under a temperature of 23 ⁇ 2° C. and a relative humidity of 45%, and a load of 4.83 kPa (0.7 psi) was uniformly applied thereon.
  • the piston which can be imparted more, has a slightly smaller outer diameter than 60 mm, has no gaps with the inner wall of the cylinder, and prevents vertical movement. At this time, the weight W 3 (g) of the device was measured.
  • a 150 mm diameter petri dish was placed inside a 125 mm diameter glass filter with a thickness of 5 mm, and the physiological saline composed of 0.90% by weight sodium chloride was brought to the same level as the top surface of the glass filter.
  • the measuring device was mounted on a glass filter, and the liquid was absorbed for 1 hour under a load. After 1 hour, the measuring device was lifted, and the weight W 4 (g) was measured.
  • AUP (g/g) was calculated according to the following Equation 2 to check the absorbency under pressure.
  • a 400 mesh wire mesh made of stainless steel was mounted on a cylindrical bottom of a plastic cylinder having an inner diameter of 60 mm.
  • a piston capable of uniformly adding a load of 2.1 kPa (0.3 psi) was slightly smaller than the outer diameter of 60 mm, installed without a gap with the inner wall of the cylinder, and the vertical movement was not disturbed and the height was measured (t0).
  • a super absorbent polymer (approximately 1.8 ⁇ 0.05 g) was uniformly applied to the cylinder, and after raising the piston, a glass filter with a diameter of 90 mm and a thickness of 5 mm was placed inside a petri dish having a diameter of 200 mm.
  • the filter was put about 5 mm high from the top surface and absorbed/swelled in a super absorbent polymer for 1 hour under load. Thereafter, a physiological saline solution consisting of 0.9% by weight sodium chloride was flowed and the weight of the physiological saline solution passed for 5 minutes was measured after the first drop passed through the swollen superabsorbent resin gel (F g ). After passing the saline for 5 minutes, the height (t1) of the measuring device was measured. From these measurement results, GPUP was calculated according to the following equations 3 and 4:
  • F g saline weight through the gel per hour (g/s)
  • A cylinder area, 28.27 cm 2

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  • Chemical & Material Sciences (AREA)
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  • Engineering & Computer Science (AREA)
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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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Abstract

La présente invention concerne : un polymère superabsorbant qui possède non seulement d'excellentes performances d'absorption de base, mais présente également une perméabilité améliorée sous pression de telle sorte que des propriétés de réhumidification et des propriétés de suppression de fuite pour des produits sanitaires tels qu'une couche, etc. peuvent être améliorées par celle-ci; et un procédé de préparation associé. Le polymère superabsorbant comprend : une poudre de résine de base contenant un premier polymère réticulé d'un monomère éthyléniquement insaturé soluble dans l'eau comprenant des groupes acides au moins partiellement neutralisés; et une couche réticulée en surface formée sur la poudre de résine de base et contenant un second polymère réticulé, le premier polymère réticulé étant en outre réticulé par médiation d'un agent de réticulation de surface, l'agent de réticulation de surface comprenant un premier agent de réticulation de surface de type polymère qui a un poids moléculaire moyen en nombre de 300 ou plus et porte une pluralité de groupes hydroxyle ou de groupes époxy.
PCT/KR2019/013302 2018-12-12 2019-10-10 Polymère superabsorbant et son procédé de préparation WO2020122390A1 (fr)

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US17/270,338 US20210322953A1 (en) 2018-12-12 2019-10-10 Superabsorbent Polymer Composition And Method For Preparing The Same
CN201980053547.9A CN112585194B (zh) 2018-12-12 2019-10-10 超吸收性聚合物组合物及用于制备其的方法
JP2020556904A JP7191403B2 (ja) 2018-12-12 2019-10-10 高吸水性樹脂およびその製造方法
EP19896240.9A EP3819329A4 (fr) 2018-12-12 2019-10-10 Polymère superabsorbant et son procédé de préparation

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EP0937736A2 (fr) 1998-02-24 1999-08-25 Nippon Shokubai Co., Ltd. Réticulation d'un agent absorbant l'eau
WO2014021388A1 (fr) 2012-08-01 2014-02-06 株式会社日本触媒 Absorbant d'eau utilisant une résine en poudre absorbant l'eau à base d'un (sel d')acide polyacrylique et procédé de fabrication d'un absorbant d'eau
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