WO2020073733A1 - Electrolyzed acidic water generation device and refrigerator - Google Patents

Electrolyzed acidic water generation device and refrigerator Download PDF

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Publication number
WO2020073733A1
WO2020073733A1 PCT/CN2019/100728 CN2019100728W WO2020073733A1 WO 2020073733 A1 WO2020073733 A1 WO 2020073733A1 CN 2019100728 W CN2019100728 W CN 2019100728W WO 2020073733 A1 WO2020073733 A1 WO 2020073733A1
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WIPO (PCT)
Prior art keywords
water
mgcl
nacl
decomposition tank
spray
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PCT/CN2019/100728
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French (fr)
Chinese (zh)
Inventor
王丽燕
刘浩泉
王磊
辛若武
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青岛海尔股份有限公司
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Publication of WO2020073733A1 publication Critical patent/WO2020073733A1/en

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/04—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
    • F25D17/042—Air treating means within refrigerated spaces
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • A23L5/273—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption using adsorption or absorption agents, resins, synthetic polymers, or ion exchangers
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D11/00—Self-contained movable devices, e.g. domestic refrigerators
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/46185—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only anodic or acidic water, e.g. for oxidizing or sterilizing
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/4619—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02—Non-contaminated water, e.g. for industrial water supply
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4618—Supplying or removing reactants or electrolyte
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2317/00—Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass
    • F25D2317/04—Treating air flowing to refrigeration compartments
    • F25D2317/041—Treating air flowing to refrigeration compartments by purification
    • F25D2317/0413—Treating air flowing to refrigeration compartments by purification by humidification

Definitions

  • the invention relates to the technical field of refrigeration equipment, in particular to an electrolyzed acid water generating device and a refrigerator having the same.
  • An object of the present invention is to provide an electrolyzed acid water generating device and a refrigerator having the same.
  • an embodiment of the present invention provides an electrolysis acidic water generation device, including the following modules: a decomposition tank storing NaCl / MgCl 2 electrolyte solution; a membrane is installed in the decomposition tank, and the decomposition tank It is divided into an anode decomposition tank and a cathode decomposition tank.
  • An anode electrode is provided in the anode decomposition tank, and a cathode electrode is provided in the cathode decomposition tank.
  • the anode electrode is connected to the positive electrode of the DC power supply and the cathode electrode is connected to the negative electrode of the DC power supply.
  • the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.1%.
  • the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.2%.
  • the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.3%.
  • the NaCl / MgCl 2 electrolyte solution has a NaCl / MgCl 2 molar concentration of 0.1% to 0.3%.
  • An embodiment of the present invention also provides a refrigerator, which is equipped with the above-mentioned electrolytic acid water generating device, and the refrigerator further includes the following module: a spray device, the spray device is connected to the anode decomposition tank through a pipe, The spray device can spray the electrolytic acidic water in the anode decomposition tank into the storage compartment.
  • a water storage box and a spray water pipe for storing electrolyzed acidic water are connected by a pipe between the water storage box and the spray water pipe; the spray water pipe is provided to the storage compartment The top of the tank can spray electrolyzed acidic water into the storage compartment.
  • the spray device is a pipe provided with a plurality of holes on the lower side, and the holes pass through the inside and outside of the pipe.
  • the spray device further includes: a water guide baffle disposed on the lower side of the spray water pipe, the water guide baffle is provided with an upper side penetrating through the water guide baffle and Holes on the underside.
  • the storage compartment is a changing greenhouse.
  • an embodiment of the present invention provides a refrigerator, which is equipped with an electrolyzed acid water generating device, a spray device, and the spray device is connected to an anode through a pipe for decomposition Tank, the spraying device can spray the electrolytic acidic water in the anode decomposition tank into the storage compartment.
  • the spraying device can spray the electrolyzed acidic water in the electrolyzed acidic water generating device into the storage compartment, the electrolyzed acidic water can not only degrade the pesticide residues, but also can supplement the loss in the storage compartment The water has the effect of keeping fresh.
  • FIG. 1 is a schematic structural diagram of a device for generating electrolyzed acidic water in an embodiment of the present invention
  • FIG. 2 is a schematic structural view of a shower device in an embodiment of the present invention.
  • FIG. 3 is a schematic structural diagram of a sprinkler pipe in an embodiment of the present invention.
  • An embodiment of the present invention provides a device for generating electrolyzed acidic water. As shown in FIG. 1, it includes the following modules: a decomposition tank storing NaCl / MgCl 2 electrolyte solution;
  • a diaphragm is installed in the decomposition tank, the decomposition tank is divided into an anode decomposition tank 1 and a cathode decomposition tank 2, an anode electrode 11 is provided in the anode decomposition tank 1, and a cathode electrode 21 is provided in the cathode decomposition tank 2.
  • the anode electrode 11 is connected to the positive electrode of the DC power supply 4 and the cathode electrode 21 is connected to the negative electrode of the DC power supply 4.
  • the NaCl / MgCl 2 electrolyte solution is stored in the decomposition tank, and the decomposition tank is divided into an anode decomposition tank 1 and a cathode decomposition tank 2 using a diaphragm, and an electrochemical reaction occurs in both the anode decomposition tank 1 and the cathode decomposition tank 2.
  • Decomposition tank 2 in the cathode generates hydrogen gas and hydropower decomposition reaction occurs on the cathode electrode 21, so that the concentration of hydroxide ions rises, resulting electrolyzed alkaline water; in the anodic dissolution tank 1, an anode electrode 11 exploded NaCl / MgCl 2 electrolysis, Chlorine gas is generated, and chlorine-containing compounds, active oxygen, and hydrogen ions are generated, so that the anode decomposition tank 1 generates electrolytic acid water.
  • the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.1%.
  • the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.2%.
  • the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.3%.
  • the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.1% to 0.3%.
  • Embodiment 2 of the present invention provides a refrigerator equipped with the electrolysis acidic water generating device in Embodiment 1, and the refrigerator further includes the following modules:
  • the spraying device 5 is connected to the anode decomposition tank 1 through a pipe, and the spraying device 5 can spray the electrolytic acidic water in the anode decomposition tank 1 into the storage compartment.
  • the spray device 5 is connected to the electrolyzed acid water generating device through a pipe. If the electrolyzed acid water cannot flow into the spray device 5 along the pipe, a water pump may be provided in the pipe, and the electrolyzed acid water From this generating device, it is pumped into the spray device 5.
  • the spraying device 5 can spray the electrolyzed acidic water in the electrolyzed acidic water generating device into the storage compartment.
  • the electrolyzed acidic water can not only degrade pesticide residues, but also replenish the lost moisture in the storage compartment (for example, in an air-cooled refrigerator, the air circulation will remove part of the water vapor from the storage compartment, which has the effect of keeping fresh.
  • the spray device 5 includes a water storage box 51 and a spray water pipe 52 for storing electrolyzed acidic water, and the water storage box 51 and the spray water pipe 52 are connected by a pipe
  • the spray water pipe 52 is provided at the top of the storage compartment, and can spray electrolytic acidic water to the storage compartment.
  • the electrolyzed acidic water in the water storage box 51 will flow into the spray water pipe 52, and the spray water pipe 52 is provided at the top of the storage compartment, therefore, the water droplets sprayed from the spray water pipe 52 will wet the storage Fruits and vegetables in the compartment, so that the electrolytic acidic water will degrade pesticide residues on the surface of the fruits and vegetables.
  • a water pump may be provided in the pipeline, and the electrolyzed acidic water is pumped from the water storage box 51 to the spray water pipe 52 by the water pump
  • the spraying device 5 is a pipe provided with a plurality of holes 521 on the lower side, and the holes 521 pass through the inside and outside of the pipe.
  • a hole 521 is provided on the lower side of the pipe, so that when the electrolytic acid water flows in the pipe, the electrolytic acid water will flow down along the hole 521, thus achieving the purpose of spraying the storage compartment.
  • the number and size of holes 521 can be adjusted according to actual needs; here, the pipe can be bent and then placed on top of the storage compartment, so that the length of the pipe can be increased.
  • the spray device 5 further includes: a water guide baffle 53 provided on the lower side of the spray water pipe 52, and the water guide baffle 53 is provided with upper and lower sides penetrating the water guide baffle 53 Holes (not shown).
  • the spraying water pipe 52 leads the electrolyzed acidic water to the surface of the water guide partition 53 and sprays the holes on the water guide partition 53 to the surface of the fruits and vegetables, so that the pesticide residue on the surface of the fruits and vegetables can be degraded.
  • the storage room is a variable greenhouse.

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Abstract

Provided is a refrigerator. The refrigerator is mounted with an electrolyzed acidic water generation device and a spraying device, wherein the spraying device is connected to an anode decomposition tank by means of a pipeline, and the spraying device can spray electrolyzed acidic water in the anode decomposition tank into a storage compartment. In the refrigerator, the spraying device can spray the electrolyzed acidic water in the electrolyzed acidic water generation device into the storage compartment, and the electrolyzed acidic water can degrade pesticide residues and provide a supplement to moisture lost in the storage compartment to provide a preservation effect.

Description

电解酸性水的产生装置及冰箱Electrolytic acid water generating device and refrigerator
本申请要求了申请日为2018年10月11日，申请号为201811183741.2，发明名称为“一种电解酸性水的产生装置及具有其的冰箱”的中国专利申请的优先权，其全部内容通过引用结合在本申请中。This application claims the priority of the Chinese patent application with the application date of October 11, 2018, the application number of 201811183741.2, the name of the invention is "an electrolyzed acid water generating device and a refrigerator with it", the entire content of which is cited by reference Incorporated in this application.
技术领域Technical field
本发明涉及制冷设备技术领域，尤其涉及一种电解酸性水的产生装置及具有其的冰箱。The invention relates to the technical field of refrigeration equipment, in particular to an electrolyzed acid water generating device and a refrigerator having the same.
背景技术Background technique
在生活中，为了防止果蔬脱水变质，人们通常都将买回的果蔬放在冰箱中保存，在现有的农业生产过程中，经常使用农药对果蔬进行杀虫处理，这就导致果蔬的外表面上不可避免的存在农药残留，因此，如果冰箱具有降解农药残留的功能，将会极大的方便用户的使用。In life, in order to prevent the dehydration and deterioration of fruits and vegetables, people usually keep the purchased fruits and vegetables in the refrigerator. In the current agricultural production process, pesticides are often used to kill the fruits and vegetables, which results in the outer surface of the fruits and vegetables There is unavoidable pesticide residues on the surface, so if the refrigerator has the function of degrading pesticide residues, it will greatly facilitate the use of users.
因此，设计一种能够对所保存的物品上的农药残留进行降解的冰箱，就成为一个亟待解决的问题。Therefore, designing a refrigerator capable of degrading pesticide residues on stored items has become an urgent problem to be solved.
发明内容Summary of the invention
本发明的目的在于提供一种电解酸性水的产生装置及具有其的冰箱。An object of the present invention is to provide an electrolyzed acid water generating device and a refrigerator having the same.
为了实现上述发明目的之一，本发明一实施方式提供一种电解酸性水的产生装置，包括以下模块：存储有NaCl/MgCl 2电解质溶液的分解槽；所述分解槽中安装有隔膜，分解槽被分割为阳极分解槽和阴极分解槽，在阳极分解槽中设置有阳电极，在阴极分解槽中设置有阴电极，所述阳电极连接到直流电源的正极、阴电极连接到直流电源的负极。 In order to achieve one of the above objects of the invention, an embodiment of the present invention provides an electrolysis acidic water generation device, including the following modules: a decomposition tank storing NaCl / MgCl 2 electrolyte solution; a membrane is installed in the decomposition tank, and the decomposition tank It is divided into an anode decomposition tank and a cathode decomposition tank. An anode electrode is provided in the anode decomposition tank, and a cathode electrode is provided in the cathode decomposition tank. The anode electrode is connected to the positive electrode of the DC power supply and the cathode electrode is connected to the negative electrode of the DC power supply. .
作为本发明一实施方式的进一步改进，所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.1％。 As a further improvement of an embodiment of the present invention, the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.1%.
作为本发明一实施方式的进一步改进，所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.2％。 As a further improvement of an embodiment of the present invention, the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.2%.
作为本发明一实施方式的进一步改进，所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.3％。 As a further improvement of an embodiment of the present invention, the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.3%.
作为本发明一实施方式的进一步改进，所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.1％～0.3％。 As a further improvement of an embodiment of the present invention, the NaCl / MgCl 2 electrolyte solution has a NaCl / MgCl 2 molar concentration of 0.1% to 0.3%.
本发明实施例还提供了一种冰箱，所述冰箱安装有上述的电解酸性水的产生装置，该冰 箱还包括以下模块：喷淋装置，所述喷淋装置通过管道连接到阳极分解槽，所述喷淋装置能够将阳极分解槽中的电解酸性水喷淋到存储间室中。An embodiment of the present invention also provides a refrigerator, which is equipped with the above-mentioned electrolytic acid water generating device, and the refrigerator further includes the following module: a spray device, the spray device is connected to the anode decomposition tank through a pipe, The spray device can spray the electrolytic acidic water in the anode decomposition tank into the storage compartment.
作为本发明一实施方式的进一步改进，用于存储电解酸性水的储水盒和喷淋水管，所述储水盒和喷淋水管之间通过管道连接；所述喷淋水管设置与存储间室的顶部、且能够向存储间室喷淋电解酸性水。As a further improvement of an embodiment of the present invention, a water storage box and a spray water pipe for storing electrolyzed acidic water are connected by a pipe between the water storage box and the spray water pipe; the spray water pipe is provided to the storage compartment The top of the tank can spray electrolyzed acidic water into the storage compartment.
作为本发明一实施方式的进一步改进，所述喷淋装置为下侧设置有若干孔洞的管道，所述孔洞贯通管道的内侧和外侧。As a further improvement of an embodiment of the present invention, the spray device is a pipe provided with a plurality of holes on the lower side, and the holes pass through the inside and outside of the pipe.
作为本发明一实施方式的进一步改进，所述喷淋装置还包括：设置于所述喷淋水管下侧的导水隔板，所述导水隔板设置有贯通导水隔板的上侧和下侧的孔洞。As a further improvement of an embodiment of the present invention, the spray device further includes: a water guide baffle disposed on the lower side of the spray water pipe, the water guide baffle is provided with an upper side penetrating through the water guide baffle and Holes on the underside.
作为本发明一实施方式的进一步改进，所述存储间室为变温室。As a further improvement of an embodiment of the present invention, the storage compartment is a changing greenhouse.
相对于现有技术，本发明的技术效果在于：本发明实施例提供一种了冰箱，所述冰箱安装有电解酸性水的产生装置，喷淋装置，所述喷淋装置通过管道连接到阳极分解槽，所述喷淋装置能够将阳极分解槽中的电解酸性水喷淋到存储间室中。在该冰箱中，喷淋装置能够将电解酸性水的产生装置中的电解酸性水喷淋到存储间室中，该起电解酸性水不仅能够降解农药残留，而且也能够补充存储间室中的失掉的水分，起到保鲜的效果。Compared with the prior art, the technical effect of the present invention is that an embodiment of the present invention provides a refrigerator, which is equipped with an electrolyzed acid water generating device, a spray device, and the spray device is connected to an anode through a pipe for decomposition Tank, the spraying device can spray the electrolytic acidic water in the anode decomposition tank into the storage compartment. In this refrigerator, the spraying device can spray the electrolyzed acidic water in the electrolyzed acidic water generating device into the storage compartment, the electrolyzed acidic water can not only degrade the pesticide residues, but also can supplement the loss in the storage compartment The water has the effect of keeping fresh.
附图说明BRIEF DESCRIPTION
图1是本发明实施例中的电解酸性水的产生装置的结构示意图；FIG. 1 is a schematic structural diagram of a device for generating electrolyzed acidic water in an embodiment of the present invention;
图2是本发明实施例中的喷淋装置的结构示意图；2 is a schematic structural view of a shower device in an embodiment of the present invention;
图3是本发明实施例中的喷淋水管的结构示意图。FIG. 3 is a schematic structural diagram of a sprinkler pipe in an embodiment of the present invention.
具体实施方式detailed description
以下将结合附图所示的各实施方式对本发明进行详细描述。但这些实施方式并不限制本发明，本领域的普通技术人员根据这些实施方式所做出的结构、方法、或功能上的变换均包含在本发明的保护范围内。The present invention will be described in detail below with reference to the embodiments shown in the drawings. However, these embodiments do not limit the present invention, and structural, method, or functional changes made by those of ordinary skill in the art according to these embodiments are all included in the protection scope of the present invention.
本发明实施例提供了一种电解酸性水的产生装置，如图1所示，包括以下模块：存储有NaCl/MgCl 2电解质溶液的分解槽； An embodiment of the present invention provides a device for generating electrolyzed acidic water. As shown in FIG. 1, it includes the following modules: a decomposition tank storing NaCl / MgCl 2 electrolyte solution;
所述分解槽中安装有隔膜，分解槽被分割为阳极分解槽1和阴极分解槽2，在阳极分解槽1中设置有阳电极11，在阴极分解槽2中设置有阴电极21，所述阳电极11连接到直流电源4的正极、阴电极21连接到直流电源4的负极。A diaphragm is installed in the decomposition tank, the decomposition tank is divided into an anode decomposition tank 1 and a cathode decomposition tank 2, an anode electrode 11 is provided in the anode decomposition tank 1, and a cathode electrode 21 is provided in the cathode decomposition tank 2. The anode electrode 11 is connected to the positive electrode of the DC power supply 4 and the cathode electrode 21 is connected to the negative electrode of the DC power supply 4.
这里，在分解槽中存储有NaCl/MgCl 2电解质溶液，使用隔膜将分解槽分隔为阳极分解槽1和阴极分解槽2，在阳极分解槽1和阴极分解槽2都发生电化学反应。在阴极分解槽2 中，在阴电极21上发生水电解反应并产生氢气，从而氢氧离子浓度上升，得到电解碱性水；在阳极分解槽1中，阳电极11分解NaCl/MgCl 2电解，产生氯气，生成含氯化合物、活性氧和氢离子，从而阳极分解槽1生成电解酸性水。 Here, the NaCl / MgCl 2 electrolyte solution is stored in the decomposition tank, and the decomposition tank is divided into an anode decomposition tank 1 and a cathode decomposition tank 2 using a diaphragm, and an electrochemical reaction occurs in both the anode decomposition tank 1 and the cathode decomposition tank 2. Decomposition tank 2 in the cathode, generates hydrogen gas and hydropower decomposition reaction occurs on the cathode electrode 21, so that the concentration of hydroxide ions rises, resulting electrolyzed alkaline water; in the anodic dissolution tank 1, an anode electrode 11 exploded NaCl / MgCl 2 electrolysis, Chlorine gas is generated, and chlorine-containing compounds, active oxygen, and hydrogen ions are generated, so that the anode decomposition tank 1 generates electrolytic acid water.
优选的，所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.1％。 Preferably, the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.1%.
优选的，所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.2％。 Preferably, the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.2%.
优选的，所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.3％。 Preferably, the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.3%.
优选的，所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.1％～0.3％。 Preferably, the molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.1% to 0.3%.
本发明实施例二提供了一种冰箱，所述冰箱安装有实施例一中的电解酸性水的产生装置，该冰箱还包括以下模块： Embodiment 2 of the present invention provides a refrigerator equipped with the electrolysis acidic water generating device in Embodiment 1, and the refrigerator further includes the following modules:
喷淋装置5，所述喷淋装置5通过管道连接到阳极分解槽1，所述喷淋装置5能够将阳极分解槽1中的电解酸性水喷淋到存储间室中。The spraying device 5 is connected to the anode decomposition tank 1 through a pipe, and the spraying device 5 can spray the electrolytic acidic water in the anode decomposition tank 1 into the storage compartment.
这里，喷淋装置5通过管道连接到电解酸性水的产生装置，如果电解酸性水无法沿着该管道流动到喷淋装置5中，则可以在该管道中设置水泵，由该水泵将电解酸性水从该产生装置中泵到喷淋装置5中。Here, the spray device 5 is connected to the electrolyzed acid water generating device through a pipe. If the electrolyzed acid water cannot flow into the spray device 5 along the pipe, a water pump may be provided in the pipe, and the electrolyzed acid water From this generating device, it is pumped into the spray device 5.
这里，喷淋装置5能够将电解酸性水的产生装置中的电解酸性水喷淋到存储间室中，该电解酸性水不仅能够降解农药残留，而且也能够补充存储间室中的失掉的水分(例如，在风冷冰箱中，风路循环会从存储间室中带走部分水汽)，起到保鲜的效果。Here, the spraying device 5 can spray the electrolyzed acidic water in the electrolyzed acidic water generating device into the storage compartment. The electrolyzed acidic water can not only degrade pesticide residues, but also replenish the lost moisture in the storage compartment ( For example, in an air-cooled refrigerator, the air circulation will remove part of the water vapor from the storage compartment, which has the effect of keeping fresh.
优选的，如图2所示，所述喷淋装置5包括：用于存储电解酸性水的储水盒51和喷淋水管52，所述储水盒51和喷淋水管52之间通过管道连接；所述喷淋水管52设置与存储间室的顶部、且能够向存储间室喷淋电解酸性水。这里，储水盒51中的电解酸性水会流动到喷淋水管52中，而喷淋水管52设置与存储间室的顶部，因此，喷淋水管52所喷出的水珠，会淋湿存储间室中的果蔬等，从而该电解酸性水会降解果蔬表面上的农药残留。Preferably, as shown in FIG. 2, the spray device 5 includes a water storage box 51 and a spray water pipe 52 for storing electrolyzed acidic water, and the water storage box 51 and the spray water pipe 52 are connected by a pipe The spray water pipe 52 is provided at the top of the storage compartment, and can spray electrolytic acidic water to the storage compartment. Here, the electrolyzed acidic water in the water storage box 51 will flow into the spray water pipe 52, and the spray water pipe 52 is provided at the top of the storage compartment, therefore, the water droplets sprayed from the spray water pipe 52 will wet the storage Fruits and vegetables in the compartment, so that the electrolytic acidic water will degrade pesticide residues on the surface of the fruits and vegetables.
可选的，如果电解酸性水无法沿着该管道流动到喷淋水管52中，则可以在该管道中设置水泵，由该水泵将电解酸性水从该储水盒51中泵到喷淋水管52Optionally, if the electrolyzed acidic water cannot flow along the pipeline into the spray water pipe 52, a water pump may be provided in the pipeline, and the electrolyzed acidic water is pumped from the water storage box 51 to the spray water pipe 52 by the water pump
优选的，如图3所示，所述喷淋装置5为下侧设置有若干孔洞521的管道，所述孔洞521贯通管道的内侧和外侧。这里，该管道的下侧设置有孔洞521，从而当电解酸性水在该管道中流动时，电解酸性水会顺着孔洞521向下流出，从而就达到了喷淋存储间室的目地。可选的，在实际生产中，孔洞521的数量和孔径大小可以根据实际需要来调整；这里，可以将该管道弯曲，然后设置在存储间室的顶部，从而就可以增加该管道的长度。Preferably, as shown in FIG. 3, the spraying device 5 is a pipe provided with a plurality of holes 521 on the lower side, and the holes 521 pass through the inside and outside of the pipe. Here, a hole 521 is provided on the lower side of the pipe, so that when the electrolytic acid water flows in the pipe, the electrolytic acid water will flow down along the hole 521, thus achieving the purpose of spraying the storage compartment. Optionally, in actual production, the number and size of holes 521 can be adjusted according to actual needs; here, the pipe can be bent and then placed on top of the storage compartment, so that the length of the pipe can be increased.
优选的，所述喷淋装置5还包括：设置于所述喷淋水管52下侧的导水隔板53，所述导 水隔板53设置有贯通导水隔板53的上侧和下侧的孔洞(未图示)。喷淋水管52把电解酸性水引到导水隔板53面上，通过导水隔板53上的孔洞喷到果蔬表面，从而能够降解果蔬表面的农药残留。Preferably, the spray device 5 further includes: a water guide baffle 53 provided on the lower side of the spray water pipe 52, and the water guide baffle 53 is provided with upper and lower sides penetrating the water guide baffle 53 Holes (not shown). The spraying water pipe 52 leads the electrolyzed acidic water to the surface of the water guide partition 53 and sprays the holes on the water guide partition 53 to the surface of the fruits and vegetables, so that the pesticide residue on the surface of the fruits and vegetables can be degraded.
优选的，所述存储间室为变温室。Preferably, the storage room is a variable greenhouse.
应当理解，虽然本说明书按照实施方式加以描述，但并非每个实施方式仅包含一个独立的技术方案，说明书的这种叙述方式仅仅是为清楚起见，本领域技术人员应当将说明书作为一个整体，各实施方式中的技术方案也可以经适当组合，形成本领域技术人员可以理解的其他实施方式。It should be understood that although this specification is described in terms of embodiments, not every embodiment only contains an independent technical solution. This description of the specification is for clarity only, and those skilled in the art should treat the specification as a whole, each The technical solutions in the embodiments may also be combined appropriately to form other embodiments that can be understood by those skilled in the art.
上文所列出的一系列的详细说明仅仅是针对本发明的可行性实施方式的具体说明，它们并非用以限制本发明的保护范围，凡未脱离本发明技艺精神所作的等效实施方式或变更均应包含在本发明的保护范围之内。The series of detailed descriptions listed above are only specific descriptions of feasible embodiments of the present invention, they are not intended to limit the scope of protection of the present invention, and equivalent embodiments or technical equivalents made without departing from the technical spirit of the present invention Changes should be included in the protection scope of the present invention.

Claims (10)

  1. 一种电解酸性水的产生装置，其特征在于，包括以下模块：An electrolysis acidic water generating device, characterized in that it includes the following modules:
    存储有NaCl/MgCl 2电解质溶液的分解槽； Decomposition tank with NaCl / MgCl 2 electrolyte solution stored;
    所述分解槽中安装有隔膜，分解槽被分割为阳极分解槽和阴极分解槽，在阳极分解槽中设置有阳电极，在阴极分解槽中设置有阴电极，所述阳电极连接到直流电源的正极、阴电极连接到直流电源的负极。A diaphragm is installed in the decomposition tank, the decomposition tank is divided into an anode decomposition tank and a cathode decomposition tank, an anode electrode is provided in the anode decomposition tank, a cathode electrode is provided in the cathode decomposition tank, and the anode electrode is connected to a DC power supply The positive electrode and negative electrode are connected to the negative electrode of the DC power supply.
  2. 根据权利要求1所述的电解酸性水的产生装置，其特征在于：The electrolysis acidic water generating device according to claim 1, characterized in that:
    所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.1％。 The molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.1%.
  3. 根据权利要求1所述的电解酸性水的产生装置，其特征在于：The electrolysis acidic water generating device according to claim 1, characterized in that:
    所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.2％。 The molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.2%.
  4. 根据权利要求1所述的电解酸性水的产生装置，其特征在于：The electrolysis acidic water generating device according to claim 1, characterized in that:
    所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.3％。 The molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.3%.
  5. 根据权利要求1所述的电解酸性水的产生装置，其特征在于：The electrolysis acidic water generating device according to claim 1, characterized in that:
    所述NaCl/MgCl 2电解质溶液中NaCl/MgCl 2的摩尔浓度为0.1％～0.3％。 The molar concentration of NaCl / MgCl 2 in the NaCl / MgCl 2 electrolyte solution is 0.1% to 0.3%.
  6. 一种冰箱，所述冰箱安装有权利要求1所述的电解酸性水的产生装置，其特征在于，还包括以下模块：A refrigerator equipped with the electrolysis acidic water generating device according to claim 1, further comprising the following modules:
    喷淋装置，所述喷淋装置通过管道连接到阳极分解槽，所述喷淋装置能够将阳极分解槽中的电解酸性水喷淋到存储间室中。A spraying device connected to the anode decomposition tank through a pipe, and the spraying device can spray the electrolytic acid water in the anode decomposition tank into the storage compartment.
  7. 根据权利要求6所述的冰箱，其特征在于，所述喷淋装置包括：The refrigerator according to claim 6, wherein the spraying device comprises:
    用于存储电解酸性水的储水盒和喷淋水管，所述储水盒和喷淋水管之间通过管道连接；A water storage box and a spray water pipe for storing electrolyzed acidic water, and the water storage box and the spray water pipe are connected by a pipeline;
    所述喷淋水管设置与存储间室的顶部、且能够向存储间室喷淋电解酸性水。The spray water pipe is provided at the top of the storage compartment and can spray electrolytic acid water to the storage compartment.
  8. 根据权利要求6所述的冰箱，其特征在于：The refrigerator according to claim 6, wherein:
    所述喷淋装置为下侧设置有若干孔洞的管道，所述孔洞贯通管道的内侧和外侧。The spray device is a pipe provided with a plurality of holes on the lower side, and the holes pass through the inside and the outside of the pipe.
  9. 根据权利要求7所述的冰箱，其特征在于，所述喷淋装置还包括：The refrigerator according to claim 7, wherein the spraying device further comprises:
    设置于所述喷淋水管下侧的导水隔板，所述导水隔板设置有贯通导水隔板的上侧和下侧的孔洞。A water guide baffle provided on the lower side of the spray water pipe, and the water guide baffle is provided with holes penetrating the upper and lower sides of the water guide baffle.
  10. 根据权利要求6所述的冰箱，其特征在于：The refrigerator according to claim 6, wherein:
    所述存储间室为变温室。The storage room is a variable greenhouse.
PCT/CN2019/100728 2018-10-11 2019-08-15 Electrolyzed acidic water generation device and refrigerator WO2020073733A1 (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005337648A (en) * 2004-05-31 2005-12-08 Hitachi Home & Life Solutions Inc Refrigerator
CN102688664A (en) * 2011-03-24 2012-09-26 株式会社东芝 Electrolysis device and refrigerator
CN103423945A (en) * 2013-09-05 2013-12-04 合肥美的电冰箱有限公司 Refrigerator
CN104336167A (en) * 2013-07-29 2015-02-11 苏州三星电子有限公司 Refrigerator and sterilization assembly thereof
CN105091467A (en) * 2014-05-15 2015-11-25 苏州三星电子有限公司 Sterilizing device for refrigerator
KR20180053183A (en) * 2016-11-11 2018-05-21 동명대학교산학협력단 System for producing electrolytic water ice slurry
CN108522944A (en) * 2018-01-11 2018-09-14 青岛海尔股份有限公司 A kind of refrigerator sterilization moisturizing device and method
CN109405399A (en) * 2018-10-11 2019-03-01 青岛海尔股份有限公司 A kind of generation device of electrolyzed acidic water and refrigerator with it

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100756662B1 (en) * 2006-03-10 2007-09-07 영일산업기술 주식회사 Instantaneous sterilizing water generating apparatus
JP2015016408A (en) * 2013-07-10 2015-01-29 モレックス インコーポレイテドＭｏｌｅｘ Ｉｎｃｏｒｐｏｒａｔｅｄ Acidic electrolyzed water, manufacturing method therefor, and cleanser and disinfectant containing said acidic electrolyzed water

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005337648A (en) * 2004-05-31 2005-12-08 Hitachi Home & Life Solutions Inc Refrigerator
CN102688664A (en) * 2011-03-24 2012-09-26 株式会社东芝 Electrolysis device and refrigerator
CN104336167A (en) * 2013-07-29 2015-02-11 苏州三星电子有限公司 Refrigerator and sterilization assembly thereof
CN103423945A (en) * 2013-09-05 2013-12-04 合肥美的电冰箱有限公司 Refrigerator
CN105091467A (en) * 2014-05-15 2015-11-25 苏州三星电子有限公司 Sterilizing device for refrigerator
KR20180053183A (en) * 2016-11-11 2018-05-21 동명대학교산학협력단 System for producing electrolytic water ice slurry
CN108522944A (en) * 2018-01-11 2018-09-14 青岛海尔股份有限公司 A kind of refrigerator sterilization moisturizing device and method
CN109405399A (en) * 2018-10-11 2019-03-01 青岛海尔股份有限公司 A kind of generation device of electrolyzed acidic water and refrigerator with it

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