CN214881855U - Ship type chlorine dioxide synergistic disinfectant generation system adopting electrolysis method - Google Patents

Ship type chlorine dioxide synergistic disinfectant generation system adopting electrolysis method Download PDF

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CN214881855U
CN214881855U CN202121080455.0U CN202121080455U CN214881855U CN 214881855 U CN214881855 U CN 214881855U CN 202121080455 U CN202121080455 U CN 202121080455U CN 214881855 U CN214881855 U CN 214881855U
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chlorine dioxide
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刘志永
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Abstract

The application provides a ship type chlorine dioxide synergistic disinfectant generating system by using an electrolytic method, which comprises an anti-rolling base, an electrolytic device, a salt dissolving device, an electric control device and a reaction device; the anti-rolling base comprises an upper plate and a bottom plate fixed on the ground, the two plates are connected through a damping shock absorber, and an anti-rolling device is mounted in the middle of the upper plate; the electrolysis device comprises an electrolysis bath body fixed on an upper layer plate of the anti-rolling base, wherein an anode and a cathode are arranged in the electrolysis bath body, and an ionic membrane is arranged between the anode and the cathode; the electrolytic bath body is provided with a dosing pipe, an anode return pipe and an anode gas collecting pipe; the salt dissolving device is connected with the electrolytic bath body through a dosing pipe and an anode return pipe to form circulation; the reaction device is provided with an air inlet pipe, a water inlet pipe and a disinfectant feeding pipeline, and the air inlet pipe of the reaction device is communicated with an anode gas collecting pipe of the electrolysis device. The generating system can be used in application environments of ships, oil platforms and the like, and the concentration of the produced disinfectant is stable and adjustable.

Description

Ship type chlorine dioxide synergistic disinfectant generation system adopting electrolysis method
Technical Field
The application belongs to the technical field of water body disinfection, and particularly relates to a ship type chlorine dioxide synergistic disinfectant generation system by an electrolytic method.
Background
In order to solve the water environment disinfection problem, ultraviolet disinfection, chlorine tablet throwing or chemical chlorine dioxide generator and the like are generally adopted to disinfect water. The main raw material used by the chemical chlorine dioxide generator is hydrochloric acid, which is greatly limited in use at present. The chlorine dioxide generator by the electrolytic method is a short name of a chlorine dioxide synergistic disinfectant generator by the salt electrolysis method, the raw material of the chlorine dioxide generator is mainly saturated salt water, and the chlorine dioxide multicomponent synergistic disinfectant is generated by electrolyzing the saturated salt water, so that the comprehensive use effect is better. In the existing complete equipment of the chlorine dioxide generator by the electrolytic method, an electrolytic system is generally composed of an electrolytic power supply, an electrolytic bath and a salt dissolving tank.
For special conditions of marine operation environments of marine ships and oil platforms, due to factors such as wind waves, jolts, high humidity and high-concentration salt fog, the complete disinfection equipment has process defects when used, and the disinfection problems of sealed water bins, drinking water and the like in the environments are difficult to solve.
SUMMERY OF THE UTILITY MODEL
In view of this, the application provides a ship type electrolytic chlorine dioxide synergistic disinfectant generating system, which is mainly used in use environments such as ships and oil platforms, and can produce chlorine dioxide synergistic disinfectant with stable concentration in such environments, thereby solving the problem of water body disinfection.
The application provides a ship type chlorine dioxide synergistic disinfectant generating system by electrolysis, which comprises an anti-rolling base, an electrolysis device, a salt dissolving device, an electric control device and a reaction device; the anti-rolling base comprises an upper plate and a bottom plate fixed on the ground, the two plates are connected through a damping shock absorber, and an anti-rolling device is mounted in the middle of the upper plate;
the electrolysis device comprises an electrolysis bath body fixed on an upper layer plate of the anti-rolling base, wherein an anode and a cathode are arranged in the electrolysis bath body, and an ionic membrane for separating electrolysis products of the two electrodes is arranged between the two electrodes; the electrolytic bath body is provided with a dosing pipe, an anode return pipe and an anode gas collecting pipe; the salt dissolving device is connected with the electrolytic bath body through the dosing pipe and the anode return pipe to form circulation and is used for providing dissolved saturated salt water for the electrolytic device and circulating anolyte; the electric control device mainly provides electric energy for the electrolysis device to electrolyze saturated salt water;
the reaction device is provided with an air inlet pipe, a water inlet pipe and a chlorine dioxide synergistic disinfectant dosing pipeline, and the air inlet pipe of the reaction device is communicated with an anode gas collecting pipe of the electrolysis device.
In the embodiment of the application, the top of the anode gas collecting pipe of the electrolytic bath body is provided with a tower structure.
In the embodiment of the application, the electrolytic bath body is also provided with a cathode tower type gas collecting pipe and a sewage draining pipe.
In an embodiment of the present application, the reaction apparatus has a liquid level control device and an aeration device.
In the embodiment of the application, a cooling circulation unit is arranged between the reaction device and the electrolysis device.
In an embodiment of the present application, the reaction device is further provided with a pressure equalization tube.
In the embodiment of the application, the electric control device adopts a closed design and a water cooling mode.
In the embodiment of the application, the salt dissolving device, the electric control device and the electrolysis device form an integrated device.
In order to solve the problem of water body disinfection in environments such as steamships, oil platforms and the like, the application provides a steamship type chlorine dioxide disinfectant generating system by an electrolysis method, which mainly comprises an anti-rolling base, an electrolysis device, a salt dissolving device, an electric control device and a reaction device; the anti-rolling base is composed of a base body part consisting of an upper plate and a bottom plate, and the anti-rolling part comprises a damping shock absorber between the two plates and an anti-rolling device arranged in the middle of the upper plate. The electrolyzer has an ion membrane electrolyzer structure, and the anolyte circulates from the salt dissolving device to the anode. The chlorine dioxide synergistic disinfectant is generated by adopting a saturated saline solution electrolytic mode of an ionic membrane, wherein the fluctuation of the liquid level of the electrolyte is mainly controlled by the anti-rolling base, so that the impact on a polar plate and the ionic membrane in an electrolytic cell body is reduced; the incompletely inhibited shaking is combined with the circulation of the anolyte, so that the stability of the concentration of the anolyte can be fully ensured, and the disinfectant with stable concentration is produced in the environment, thereby fundamentally solving the water body disinfection problem.
Drawings
FIG. 1 is a schematic structural diagram of a ship type electrolytic chlorine dioxide synergistic disinfectant generating system provided by an embodiment of the application;
FIG. 2 is a schematic top view of a ship-type electrolytic chlorine dioxide synergistic disinfectant generating system in an embodiment of the present application;
FIG. 3 is a schematic front view of a ship type electrolytic chlorine dioxide synergistic disinfectant generating system in an embodiment of the present application;
FIG. 4 is a right side view schematic diagram of a ship type electrolytic chlorine dioxide synergistic disinfectant generating system in an embodiment of the present application;
FIG. 5 is a schematic view of the left side of a ship-type electrolytic chlorine dioxide synergistic disinfectant generating system in an embodiment of the present application;
fig. 6 is a schematic diagram of the electrolysis principle of the chlorine dioxide generation system by the electrolysis method in the embodiment of the application.
Detailed Description
The technical solutions in the embodiments of the present application are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present application, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.
The application provides a ship type chlorine dioxide generating system by an electrolytic method, which comprises an anti-rolling base, an electrolysis device, a salt dissolving device, an electric control device and a reaction device; the anti-rolling base comprises an upper plate and a bottom plate fixed on the ground, the two plates are connected through a damping shock absorber, and an anti-rolling device is mounted in the middle of the upper plate;
the electrolysis device comprises an electrolysis bath body fixed on an upper layer plate of the anti-rolling base, wherein an anode and a cathode are arranged in the electrolysis bath body, and an ionic membrane for separating electrolysis products of the two electrodes is arranged between the two electrodes; the electrolytic bath body is provided with a dosing pipe, an anode return pipe and an anode gas collecting pipe; the salt dissolving device is connected with the electrolytic bath body through the dosing pipe and the anode return pipe to form circulation and is used for providing dissolved saturated salt water for the electrolytic device and circulating anolyte; the electric control device mainly provides electric energy for the electrolysis device to electrolyze saturated salt water;
the reaction device is provided with an air inlet pipe, a water inlet pipe and a chlorine dioxide synergistic disinfectant dosing pipeline, and the air inlet pipe of the reaction device is communicated with an anode gas collecting pipe of the electrolysis device.
Referring to fig. 1, fig. 1 is a schematic structural diagram of a ship-type electrolytic chlorine dioxide synergistic disinfectant generating system provided in the embodiment of the present application. In fig. 1, 1 is a roll reducing base, 101 is a damping spring, and 102 is a roll reducer; 2, an electrolytic tank, 201, 202, a cathode cabin and 203, wherein the electrolytic tank is an electrolytic tank; 3 is a salt dissolving box, and 301 is an inclined clapboard; 4, a power supply cabin, and 401, a water cooler water inlet and outlet; and 5 is a reaction box.
In the embodiment of the application, the basic structure of the ship type electrolytic chlorine dioxide synergistic disinfectant generating system is five parts, comprising: the device comprises an anti-rolling base 1, an electrolytic bath 2, a salt dissolving box 3, a power supply cabin 4 and a reaction box 5.
Wherein, the anti-rolling base 1 is composed of a base body and an anti-rolling part; the base body comprises an upper plate and a bottom plate for fixing on the ground, the two plates are generally arranged in parallel, the middle of the two plates is connected by a plurality of damping springs 101, and the damping springs 101 and the stabilizer 102 arranged in the middle of the upper plate form a stabilizing part. The roll damper 102 plays a major role in reducing the roll, and the damping spring 101, also called a damping spring, is a supplementary part for reducing the roll and plays an auxiliary role. Aiming at the generating system described in the embodiment of the application, the damping spring used as a damping shock absorber is matched in such a way that the effective load of each 6 branches is slightly larger than the weight of the equipment, so that the fluctuation of the electrolyte level in the electrolytic tank 2 on the stabilizing base 1 is controlled to a certain degree.
The electrolysis device in the embodiment of the application is an electrolysis bath 2 which is fixed on an upper plate of a stabilizing base 1 by screws; the inside of the electrolytic tank body consists of an anode cabin 201 and a cathode cabin 202, wherein an anode plate and a cathode are arranged in the anode cabin 201The chamber 202 has a cathode plate, and an ionic membrane is disposed between the cathode and the anode to separate the cathode from the anode and separate the electrolysis products of the two electrodes. The anode compartment 201 is filled with saturated brine and the cathode compartment 202 is filled with water. When the power is switched on and the electrolysis process is carried out, Cl is generated at the anode2Generating NaOH and H at the cathode2(ii) a The ionic membrane is arranged to allow only Na+And H+Smoothly pass through the cathode without chlorine ions Cl-And (4) passing. The system adopts the electrolytic device added with the ionic membrane, can electrolyze saturated salt water, improves the conversion rate of raw materials and reduces the salt consumption.
The ionic membrane in the electrolytic device strictly separates the anode and the cathode in the electrolytic cell body, and Cl generated by the anode2And H generated at the cathode2Absolutely do not mix, and avoid Cl in the electrolyzer2And H2The danger of explosion of the cell due to the occurrence of strong redox reactions.
In the present application, the anode has a high chlorine evolution activity and the cathode has a high hydrogen evolution activity. The cathode and the anode have good electrochemical stability, corrosion resistance and long service life. The electrode is of a conventional plate-shaped structure, and different types of electrodes correspond to different structural sizes of the polar plate; the ionic membrane is not particularly limited in porosity and other parameters.
The electrolytic bath body in the embodiment of the application is provided with a dosing pipe, an anode return pipe, an anode gas collecting pipe, a water replenishing pipe, a water inlet pipe, an air inlet pipe, a sewage discharge pipe and the like. The electrolytic tank 2 is connected with the salt dissolving tank 3 through a dosing pipe and an anode return pipe, and forms circulation. In the embodiment of the application, the chlorine dioxide synergistic disinfectant generating system comprises a salt dissolving tank 3, wherein salt (NaCl) added in the salt dissolving tank is dissolved to form saturated salt water, the saturated salt water is sent to an electrolytic cell 2 through a drug adding pipe, and electrolyzed light salt water flows back to the salt dissolving tank 3 through an anode return pipe. In addition, the electric control device in the system of the embodiment of the application is arranged in the power supply cabin 4, preferably a full-automatic intelligent electrolysis power supply, and the negative electrode and the positive electrode of the electric control device can be respectively connected with the electrode plate assembly of the electrolysis bath body through copper bars to provide electric energy for the electrolysis device to electrolyze saturated salt water.
In the embodiment of the application, the electrolytic bath 2, the salt dissolving tank 3 and the power supply cabin 4 preferably form an integrated device, which can be called a chlorine dioxide generator; as shown in figure 1, the integrated equipment is of a box-shaped structure, high-quality PVC (polyvinyl chloride) is adopted for welding and forming, and corrosion-resistant UPVC (unplasticized polyvinyl chloride) plates are adopted for manufacturing the box body, so that the corrosion of the box body can be reduced.
The integrated chlorine dioxide generator is divided into an upper layer, a middle layer and a lower layer, wherein the upper layer is a salt dissolving tank 3 and a power supply cabin 4 which are used for storing raw materials and placing an electrolytic power supply, the middle layer is an electrolytic bath 2, the lower layer is a pipeline space for water inlet, a sewage discharge pipe and the like, and a magnetic pump can be arranged between the two layers to provide power for the circulation of electrolyte.
Wherein, the salt dissolving box 3 preferably has an isolated salt feeding and dissolving structure; the raw material salt is dissolved into saturated salt water, the saturated salt water is connected with the electrolytic bath 2 through a pipeline to form circulation, and the inclined partition plate 301 is arranged at the communication position, so that the impact of liquid level fluctuation on the ionic membrane can be reduced.
The circulating part is an electrolyte circulating part and mainly circulates anolyte, the pump provides power, and the electrolyte circulates between the dissolved salt tank and the anode cabin. Because above-mentioned anti-rolling base is the suppression shake not completely, this application combines the circulation of anolyte, fully guarantees the stability of electrolyte concentration, does benefit to the stable of follow-up reaction and goes on.
In the specific embodiment of the application, the electric control device adopts a closed design to resist high-concentration salt fog; and preferably adopt water-cooling form, control electrolysis trough and power heat production through water cooler inlet outlet 401, compare traditional forced air cooling, the preferred power cooling mode of this application is more difficult to lead to the circuit board to corrode. In addition, the electrolytic cell can be controllably cooled, and the flow of cooling water can be controlled (controlled by a valve and adjusted along with the temperature of equipment, so that the electrolytic cell is not overcooled or overheated), thereby meeting the requirements of high-temperature or low-temperature environments.
The generating system of the embodiment of the application comprises a reaction box 5, a chlorine dioxide synergistic disinfectant, a disinfectant and a disinfectant tank, wherein the reaction box is used for reacting to generate chlorine dioxide synergistic disinfectant; the reaction device is of a box-type structure and is formed by welding high-quality PVC. An air inlet pipe, a water inlet pipe and a chlorine dioxide synergistic disinfectant chemical feeding pipeline are arranged in the reaction box 5, and the air inlet pipe of the reaction box 5 is communicated with the anode gas collecting pipe 203 of the electrolytic cell.
Referring to fig. 2-5, schematic diagrams of a ship type electrolytic chlorine dioxide synergistic disinfectant generating system in the embodiment of the application are sequentially viewed from top, front, right and left; the side appearance of which does not show the roll base.
In the preferred embodiment of the present application, the top of the anode gas collector of the electrolytic cell body has a tower structure, such as tower gas collector 203 shown in fig. 1. The tower design is internally provided with the leaf-shaped sheet, so that even if the equipment shakes, the electrolyte in the top of the gas collecting pipe can be reduced layer by layer even if the electrolyte is upwards arranged layer by layer, and finally, only gas but no electrolyte flows out from the gas collecting pipe.
In addition, the distance between the electrolyte level and the top plate of the electrolytic cell is optimally controlled, and is reduced from about 10cm to less than 5cm, which can be about 1cm, so that the storage volume of the sterilizing gas is reduced (the gas can be compressed, and the larger the storage volume is, the smaller the possibility of active precipitation is). The electrolytic bath body is also provided with a cathode tower type gas collecting pipe and a sewage draining pipe; the cathode tower type gas collecting pipe is communicated with the outside and used for high-altitude exhaust. The tower-type gas collecting pipes of the anode cabin and the cathode cabin can be correspondingly arranged, and the gas collecting towers are generally 3-4 layers, so that the problem of incomplete gas-liquid separation caused by water surface fluctuation can be well restrained.
In the embodiment of the application, the reaction box 5 is also provided with a liquid level controller and an aeration facility (for active aeration) in addition to a liquid and gas inlet and outlet pipeline in the box body, and is also preferably provided with a pressure balance pipe, and the bottom of the box body is provided with a circulating pump; chlorine dioxide and chlorine gas generated by electrolysis react with water in the box to generate chlorine dioxide synergistic disinfectant. In the embodiment of the application, a cooling circulation unit is arranged between the reaction device and the electrolysis device, so that disinfectant cooling circulation can be performed, the circulation part is powered by a magnetic pump at the bottom of a disinfectant reaction box, and the disinfectant circulates from the reaction box, a power supply water cooler, a polar plate cooler and the reaction box and carries out heat in the electrolysis bath and a power supply.
Fig. 6 is a schematic diagram of the electrolysis principle of the chlorine dioxide generation system by the electrolysis method in the embodiment of the application, and the main process comprises the following steps: the salt dissolving device dissolves salt and provides saturated NaCl water solution to the electrolysis deviceCarrying out electrolysis, wherein Cl is generated at the anode in the electrolysis process2Generating NaOH and H at the cathode2(ii) a The electrolytic diaphragm between the anode and the cathode in the electrolytic bath body is an ionic membrane, and only Na is allowed+And H+Smoothly pass through the cathode without passing through chloride ions; in the reaction device, chlorine dioxide, chlorine gas and other synergistic disinfectant gas generated by electrolysis react with water to generate chlorine dioxide synergistic disinfectant.
In the examples of the present application, the reaction equation relating to the electrodes of the device is as follows:
and (3) anode reaction:
Figure BDA0003074349160000061
Figure BDA0003074349160000062
Figure BDA0003074349160000063
Figure BDA0003074349160000064
Figure BDA0003074349160000065
Figure BDA0003074349160000066
Figure BDA0003074349160000071
and (3) cathode reaction:
Figure BDA0003074349160000072
specifically, the installation and connection method of each device in the embodiment of the present application includes:
(1) connecting a water inlet pipe of the reaction box with normal-pressure tap water, and connecting a water outlet of a circulating pump of the reaction box with the inlet of power supply cooling water;
(2) connecting the outlet water of the power supply cooling water with the inlet water of the electrolytic bath cooling water;
(3) connecting the cooling water outlet of the electrolytic bath with a water return pipe of the reaction tank;
(4) connecting an anode tower type gas collecting pipe with a reaction box gas inlet pipe;
(5) connecting the pressure balance pipe of the reaction box with an anode inlet pipe and then leading the reaction box to the outside;
(6) leading the cathode tower type gas collecting pipe to the outside;
(7) leading the cathode cabin blow-off pipe to a sewer or connecting the cathode cabin blow-off pipe with blow-off treatment equipment;
(8) connecting a reaction box dosing pipeline with a pipeline of a water body to be disinfected;
(9) and connecting the liquid level control part of the system with a corresponding interface of the power distribution cabinet.
To sum up, the ship type electrolytic chlorine dioxide synergistic disinfectant generating system provided by the application comprises: the device comprises an anti-rolling base, an electrolysis device, a salt dissolving device, an electric control device and a reaction device; the anti-rolling base is composed of a base body part consisting of an upper plate and a bottom plate, and the anti-rolling part comprises a damping shock absorber between the two plates and an anti-rolling device arranged in the middle of the upper plate. The electrolyzer has an ion membrane electrolyzer structure, and the anolyte circulates from the salt dissolving device to the anode. The ship type chlorine dioxide synergistic disinfectant generating system adopting the electrolytic method can produce chlorine dioxide synergistic disinfectant with stable concentration in the use environments of ships, oil platforms and the like, fundamentally solves the production problem of disinfectant on the ships and the oil platforms, overcomes a plurality of adverse factors such as electrolyte fluctuation and high-concentration salt fog, and is a new equipment system with excellent performance at present.
The technical advantages of the embodiments of the present application further include:
firstly, a corrosion-resistant PVC plate is welded and formed, and is non-toxic and harmless;
secondly, the disinfectant can be normally produced when a ship body shakes due to the adoption of the anti-rolling design;
thirdly, the power supply adopts a closed and water-cooled design, so that high-concentration salt spray corrosion is avoided;
fourthly, the tower type gas collecting pipe is designed to collect only the gas;
fifthly, the micro-positive pressure automatic hydrogen discharge has no hidden danger of groove explosion;
sixthly, the concentration of the disinfectant is adjustable within 1-500ppm, and the stability of the residual chlorine in the treated water body can be kept.
The foregoing is only a preferred embodiment of the present application, and it should be noted that various modifications of the embodiments can be implemented by those skilled in the art without departing from the technical principle of the present application, and these modifications should be considered as the scope of the present application.

Claims (8)

1. A ship type chlorine dioxide synergistic disinfectant generating system adopting an electrolytic method is characterized by comprising an anti-rolling base, an electrolytic device, a salt dissolving device, an electric control device and a reaction device; the anti-rolling base comprises an upper plate and a bottom plate fixed on the ground, the two plates are connected through a damping shock absorber, and an anti-rolling device is mounted in the middle of the upper plate;
the electrolysis device comprises an electrolysis bath body fixed on an upper layer plate of the anti-rolling base, wherein an anode and a cathode are arranged in the electrolysis bath body, and an ionic membrane for separating electrolysis products of the two electrodes is arranged between the two electrodes; the electrolytic bath body is provided with a dosing pipe, an anode return pipe and an anode gas collecting pipe; the salt dissolving device is connected with the electrolytic bath body through the dosing pipe and the anode return pipe to form circulation and is used for providing dissolved saturated salt water for the electrolytic device and circulating anolyte; the electric control device mainly provides electric energy for the electrolysis device to electrolyze saturated salt water;
the reaction device is provided with an air inlet pipe, a water inlet pipe and a chlorine dioxide synergistic disinfectant dosing pipeline, and the air inlet pipe of the reaction device is communicated with an anode gas collecting pipe of the electrolysis device.
2. The ship type electrolytic chlorine dioxide synergistic disinfectant generating system as claimed in claim 1, wherein the top of the anode gas collecting pipe of the electrolytic tank body is provided with a tower structure.
3. The ship type electrolytic chlorine dioxide synergistic disinfectant generating system as claimed in claim 2, wherein said electrolytic cell body is further provided with a cathode tower type gas collecting pipe and a sewage draining pipe.
4. A ship type electrolytic chlorine dioxide synergistic disinfectant generating system according to any of claims 1 to 3, wherein said reaction unit has a liquid level control means and an aeration means.
5. A ship-type electrolytic chlorine dioxide synergistic disinfectant generating system as claimed in claim 4, wherein a cooling circulation unit is provided between said reaction unit and said electrolysis unit.
6. A ship type electrolytic chlorine dioxide synergistic disinfectant generating system according to any of claims 1-3, wherein said reaction means is further provided with a pressure equalization tube.
7. A ship-type electrolytic chlorine dioxide synergistic disinfectant generating system according to any of the claims 1-3, characterized in that said electric control means is of a closed design and water-cooled form.
8. A ship type electrolytic chlorine dioxide synergistic disinfectant generating system according to any one of claims 1 to 3, wherein said salt dissolving means, electric control means and electrolysis means constitute an integrated device.
CN202121080455.0U 2021-05-19 2021-05-19 Ship type chlorine dioxide synergistic disinfectant generation system adopting electrolysis method Expired - Fee Related CN214881855U (en)

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