CN109405399A - A kind of generation device of electrolyzed acidic water and refrigerator with it - Google Patents

A kind of generation device of electrolyzed acidic water and refrigerator with it Download PDF

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Publication number
CN109405399A
CN109405399A CN201811183741.2A CN201811183741A CN109405399A CN 109405399 A CN109405399 A CN 109405399A CN 201811183741 A CN201811183741 A CN 201811183741A CN 109405399 A CN109405399 A CN 109405399A
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CN
China
Prior art keywords
mgcl2
nacl
spray
water
generation device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811183741.2A
Other languages
Chinese (zh)
Inventor
王丽燕
刘浩泉
王磊
辛若武
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Haier Co Ltd
Original Assignee
Qingdao Haier Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Haier Co Ltd filed Critical Qingdao Haier Co Ltd
Priority to CN201811183741.2A priority Critical patent/CN109405399A/en
Publication of CN109405399A publication Critical patent/CN109405399A/en
Priority to PCT/CN2019/100728 priority patent/WO2020073733A1/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/04Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
    • F25D17/042Air treating means within refrigerated spaces
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • A23L5/273Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption using adsorption or absorption agents, resins, synthetic polymers, or ion exchangers
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D11/00Self-contained movable devices, e.g. domestic refrigerators
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/46185Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only anodic or acidic water, e.g. for oxidizing or sterilizing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/4619Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4618Supplying or removing reactants or electrolyte
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2317/00Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass
    • F25D2317/04Treating air flowing to refrigeration compartments
    • F25D2317/041Treating air flowing to refrigeration compartments by purification
    • F25D2317/0413Treating air flowing to refrigeration compartments by purification by humidification

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Food Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The present invention provides refrigerator a kind of, the refrigerator is equipped with the generation device of electrolyzed acidic water, spray equipment, the spray equipment are connected to anodic decomposition slot by pipeline, and the spray equipment can be by the electrolytic acid water spray in anodic decomposition slot into storage compartment.In the refrigerator, spray equipment can be by the electrolytic acid water spray in the generation device of electrolyzed acidic water into storage compartment, this rise electrolyzed acidic water can not only degrading pesticide residues, and can supplement storage compartment in the moisture lost, play fresh-keeping effect.

Description

A kind of generation device of electrolyzed acidic water and refrigerator with it
Technical field
The present invention relates to the generation device of technical field of refrigeration equipment more particularly to a kind of electrolyzed acidic water and with its Refrigerator.
Background technique
In life, fruits and vegetables ' dehydration is rotten in order to prevent, and the fruits and vegetables bought back usually are placed in refrigerator and save by people, In existing agricultural production process, desinsection processing is carried out to fruits and vegetables commonly using pesticide, this is resulted on the outer surface of fruits and vegetables not Evitable there are pesticide residues, therefore, if refrigerator has the function of degrading pesticide residues, it will greatly facilitate user's It uses.
Therefore, a kind of refrigerator that can be degraded to the pesticide residue on the article saved is designed, just becomes one Urgent problem to be solved.
Summary of the invention
The purpose of the present invention is to provide a kind of generation device of electrolyzed acidic water and with its refrigerator.
One of in order to achieve the above-mentioned object of the invention, an embodiment of the present invention provides a kind of generation dress of electrolyzed acidic water It sets, comprises the following modules: being stored with the decomposer of NaCl/MgCl2 electrolyte solution;Diaphragm is installed in the decomposer, point Solution slot is divided into anodic decomposition slot and cathodic decomposition slot, positive electrode is provided in anodic decomposition slot, in cathodic decomposition slot It is provided with negative electrode, the positive electrode is connected to the anode of DC power supply, negative electrode is connected to the cathode of DC power supply.
As the further improvement of an embodiment of the present invention, NaCl/MgCl2 in the NaCl/MgCl2 electrolyte solution Molar concentration be 0.1%.
As the further improvement of an embodiment of the present invention, NaCl/MgCl2 in the NaCl/MgCl2 electrolyte solution Molar concentration be 0.2%.
As the further improvement of an embodiment of the present invention, NaCl/MgCl2 in the NaCl/MgCl2 electrolyte solution Molar concentration be 0.3%.
As the further improvement of an embodiment of the present invention, NaCl/MgCl2 in the NaCl/MgCl2 electrolyte solution Molar concentration be 0.1%~0.3%.
The embodiment of the invention also provides a kind of refrigerator, the refrigerator is equipped with the generation dress of above-mentioned electrolyzed acidic water Set, which further includes with lower module: spray equipment, the spray equipment are connected to anodic decomposition slot, the spray by pipeline Shower device can be by the electrolytic acid water spray in anodic decomposition slot into storage compartment.
As the further improvement of an embodiment of the present invention, for storing the water storage case and shower water of electrolyzed acidic water Pipe is connected between the water storage case and spray waterpipe by pipeline;Top and energy of the spray waterpipe setting with storage compartment It is enough to spray electrolyzed acidic water to storage compartment.
As the further improvement of an embodiment of the present invention, the spray equipment is the pipe that downside is provided with several holes Road, the inner side and outer side of described hole straight through tube.
As the further improvement of an embodiment of the present invention, the spray equipment further include: be set to the shower water Water guide partition on the downside of pipe, the water guide partition are provided with the hole of the upper side and lower side of perforation water guide partition.
As the further improvement of an embodiment of the present invention, the storage compartment is temperature-changing chamber.
Compared with the existing technology, the technical effects of the invention are that: the embodiment of the present invention provides refrigerator a kind of, the ice Case is equipped with the generation device of electrolyzed acidic water, spray equipment, and the spray equipment is connected to anodic decomposition slot, institute by pipeline Stating spray equipment can be by the electrolytic acid water spray in anodic decomposition slot into storage compartment.In the refrigerator, spray equipment Can be by the electrolytic acid water spray in the generation device of electrolyzed acidic water into storage compartment, this plays electrolyzed acidic water can not only Enough degrading pesticide residues, and the moisture lost in storage compartment can be supplemented, play fresh-keeping effect.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the generation device of the electrolyzed acidic water in the embodiment of the present invention;
Fig. 2 is the structural schematic diagram of the spray equipment in the embodiment of the present invention;
Fig. 3 is the structural schematic diagram of the spray waterpipe in the embodiment of the present invention.
Specific embodiment
Hereinafter, the present invention will be described in detail with reference to various embodiments shown in the accompanying drawings.But these embodiments are not The limitation present invention, structure that those skilled in the art are made according to these embodiments, method or change functionally It changes and is included within the scope of protection of the present invention.
The embodiment of the invention provides a kind of generation devices of electrolyzed acidic water, as shown in Figure 1, comprising the following modules: depositing Contain the decomposer of NaCl/MgCl2 electrolyte solution;
Diaphragm is installed, decomposer is divided into anodic decomposition slot 1 and cathodic decomposition slot 2, in anode in the decomposer It is provided with positive electrode 11 in decomposer 1, negative electrode 21 is provided in cathodic decomposition slot 2, the positive electrode 11 is connected to direct current The anode of power supply 4, negative electrode 21 are connected to the cathode of DC power supply 4.
Here, it is stored with NaCl/MgCl2 electrolyte solution in decomposer, decomposer is divided into anode using diaphragm In anodic decomposition slot 1 and cathodic decomposition slot 2 electrochemical reaction all occurs for decomposer 1 and cathodic decomposition slot 2.In cathodic decomposition slot 2 In, water electrolysis reaction occurs in negative electrode 21 and generates hydrogen, so that hydroxide ion concentration rises, obtains electrolysis alkaline water; In anodic decomposition slot 1, positive electrode 11 decomposes NaCl/MgCl2 electrolysis, generates chlorine, generates chlorine-containing compound, active oxygen and hydrogen Ion, so that anodic decomposition slot 1 generates electrolyzed acidic water.
Preferably, the molar concentration of NaCl/MgCl2 is 0.1% in the NaCl/MgCl2 electrolyte solution.
Preferably, the molar concentration of NaCl/MgCl2 is 0.2% in the NaCl/MgCl2 electrolyte solution.
Preferably, the molar concentration of NaCl/MgCl2 is 0.3% in the NaCl/MgCl2 electrolyte solution.
Preferably, the molar concentration of NaCl/MgCl2 is 0.1%~0.3% in the NaCl/MgCl2 electrolyte solution.
Second embodiment of the present invention provides a kind of refrigerator, the refrigerator is equipped with the production of the electrolyzed acidic water in embodiment one Generating apparatus, the refrigerator further include with lower module:
Spray equipment 5, the spray equipment 5 are connected to anodic decomposition slot 1 by pipeline, and the spray equipment 5 can incite somebody to action Electrolytic acid water spray in anodic decomposition slot 1 is into storage compartment.
Here, spray equipment 5 is connected to the generation device of electrolyzed acidic water by pipeline, if electrolyzed acidic water can not edge The pipeline flow in spray equipment 5, then water pump can be set in the pipeline, by the water pump by electrolyzed acidic water from the production Pump is into spray equipment 5 in generating apparatus.
Here, spray equipment 5 can be by the electrolytic acid water spray in the generation device of electrolyzed acidic water to storage compartment In, the electrolyzed acidic water can not only degrading pesticide residues, and can supplement storage compartment in the moisture (example lost Such as, in wind cooling refrigerator, wind path circulation can take away part steam from storage compartment), play fresh-keeping effect.
Preferably, as shown in Fig. 2, the spray equipment 5 includes: the water storage case 51 and spray for storing electrolyzed acidic water Water pipe 52 is connected between the water storage case 51 and spray waterpipe 52 by pipeline;The setting of spray waterpipe 52 and storage compartment Top and can to storage compartment spray electrolyzed acidic water.Here, the electrolyzed acidic water in water storage case 51 can flow to spray In water pipe 52, and the top of the setting of spray waterpipe 52 and storage compartment, therefore, the droplet that spray waterpipe 52 is sprayed can drench Store the fruits and vegetables etc. in compartment, the pesticide residue on fruit and vegetable surfaces so that the electrolyzed acidic water can degrade.
It optionally, can be in the pipeline if electrolyzed acidic water can not be flow in spray waterpipe 52 along the pipeline Middle setting water pump is pumped electrolyzed acidic water from the water storage case 51 to spray waterpipe 52 by the water pump
Preferably, as shown in figure 3, the spray equipment 5 is the pipeline that downside is provided with several holes 521, described hole The inner side and outer side of 521 straight through tube.Here, hole 521 is arranged in the downside of the pipeline, thus when electrolyzed acidic water is in the pipe When flowing in road, electrolyzed acidic water can be flowed downward out along hole 521, thus with just having reached the mesh of spray storage compartment.It can Choosing, in actual production, the quantity and pore size of hole 521 can adjust according to actual needs;Here it is possible to should Then the top of storage compartment is arranged in, to can increase the length of the pipeline in pipe bending.
Preferably, the spray equipment 5 further include: it is set to the water guide partition 53 of 52 downside of spray waterpipe, it is described Water guide partition 53 is provided with the hole (not shown) of the upper side and lower side of perforation water guide partition 53.Spray waterpipe 52 is electrolytic acid Water is guided on 53 face of water guide partition, fruit and vegetable surfaces is sprayed by the hole on water guide partition 53, so as to fruit and vegetable surfaces of degrading Pesticide residue.
Preferably, the storage compartment is temperature-changing chamber.
It should be appreciated that although this specification is described in terms of embodiments, but not each embodiment only includes one A independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should will say As a whole, the technical solution in each embodiment may also be suitably combined to form those skilled in the art can for bright book With the other embodiments of understanding.
The series of detailed descriptions listed above only for feasible embodiment of the invention specifically Protection scope bright, that they are not intended to limit the invention, it is all without departing from equivalent implementations made by technical spirit of the present invention Or change should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of generation device of electrolyzed acidic water, which is characterized in that comprise the following modules:
It is stored with the decomposer of NaCl/MgCl2 electrolyte solution;
Diaphragm is installed, decomposer is divided into anodic decomposition slot and cathodic decomposition slot, in anodic decomposition slot in the decomposer In be provided with positive electrode, negative electrode is provided in cathodic decomposition slot, the positive electrode is connected to the anode of DC power supply, negative electricity Pole is connected to the cathode of DC power supply.
2. generation device according to claim 1, it is characterised in that:
The molar concentration of NaCl/MgCl2 is 0.1% in the NaCl/MgCl2 electrolyte solution.
3. generation device according to claim 1, it is characterised in that:
The molar concentration of NaCl/MgCl2 is 0.2% in the NaCl/MgCl2 electrolyte solution.
4. generation device according to claim 1, it is characterised in that:
The molar concentration of NaCl/MgCl2 is 0.3% in the NaCl/MgCl2 electrolyte solution.
5. generation device according to claim 1, it is characterised in that:
The molar concentration of NaCl/MgCl2 is 0.1%~0.3% in the NaCl/MgCl2 electrolyte solution.
6. a kind of refrigerator, the refrigerator is equipped with the generation device of the described in any item electrolyzed acidic waters of claim 1-5, special Sign is, further includes with lower module:
Spray equipment, the spray equipment are connected to anodic decomposition slot by pipeline, and the spray equipment can be by anodic decomposition Electrolytic acid water spray in slot is into storage compartment.
7. refrigerator according to claim 6, which is characterized in that the spray equipment includes:
For storing the water storage case and spray waterpipe of electrolyzed acidic water, connected between the water storage case and spray waterpipe by pipeline It connects;
The spray waterpipe is arranged and stores the top of compartment and can spray electrolyzed acidic water to storage compartment.
8. refrigerator according to claim 6, it is characterised in that:
The spray equipment is the pipeline that downside is provided with several holes, the inner side and outer side of described hole straight through tube.
9. refrigerator according to claim 7, which is characterized in that the spray equipment further include:
The water guide partition being set on the downside of the spray waterpipe, the water guide partition are provided with the upside of perforation water guide partition under The hole of side.
10. refrigerator according to claim 6, it is characterised in that:
The storage compartment is temperature-changing chamber.
CN201811183741.2A 2018-10-11 2018-10-11 A kind of generation device of electrolyzed acidic water and refrigerator with it Pending CN109405399A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201811183741.2A CN109405399A (en) 2018-10-11 2018-10-11 A kind of generation device of electrolyzed acidic water and refrigerator with it
PCT/CN2019/100728 WO2020073733A1 (en) 2018-10-11 2019-08-15 Electrolyzed acidic water generation device and refrigerator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811183741.2A CN109405399A (en) 2018-10-11 2018-10-11 A kind of generation device of electrolyzed acidic water and refrigerator with it

Publications (1)

Publication Number Publication Date
CN109405399A true CN109405399A (en) 2019-03-01

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WO (1) WO2020073733A1 (en)

Cited By (1)

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Application publication date: 20190301