CN108302889A - Refrigerating device and its container for storing - Google Patents

Refrigerating device and its container for storing Download PDF

Info

Publication number
CN108302889A
CN108302889A CN201711407921.XA CN201711407921A CN108302889A CN 108302889 A CN108302889 A CN 108302889A CN 201711407921 A CN201711407921 A CN 201711407921A CN 108302889 A CN108302889 A CN 108302889A
Authority
CN
China
Prior art keywords
container
storing
anode plate
deoxygenation component
electrolysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711407921.XA
Other languages
Chinese (zh)
Inventor
朱小兵
姜波
王磊
王丽燕
马冰雪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Haier Co Ltd
Original Assignee
Qingdao Haier Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Haier Co Ltd filed Critical Qingdao Haier Co Ltd
Priority to CN201711407921.XA priority Critical patent/CN108302889A/en
Publication of CN108302889A publication Critical patent/CN108302889A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D25/00Charging, supporting, and discharging the articles to be cooled
    • F25D25/02Charging, supporting, and discharging the articles to be cooled by shelves
    • F25D25/024Slidable shelves
    • F25D25/025Drawers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/04Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
    • F25D17/042Air treating means within refrigerated spaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/104Oxygen

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Cold Air Circulating Systems And Constructional Details In Refrigerators (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The present invention provides a kind of refrigerating device and its container for storing.Wherein, container for storing includes electrolysis deoxygenation component.Electrolysis deoxygenation component is used to consume the oxygen in storage space in air, to obtain rich nitrogen oxygen deprivation in the space in favor of the atmosphere of food fresh-keeping.The atmosphere reduces the intensity of the aerobic respiration of food, while ensureing the respiration on basis, prevents food from carrying out anaerobic respiration, to achieve the purpose that food long-period freshness preserving by the content of oxygen in reduction storage space.The present invention refrigerating device include:Container for storing and water storage box.Electrolysis deoxygenation component is set on side of the cylinder towards the water storage box.Since water storage box storage inside has liquid water, neighbouring humidity is larger, and the air of the position can provide sufficient vapor as reactant to anode plate.Therefore, electrolysis deoxygenation component is arranged in face of water storage box, the progress of cell reaction can be promoted, to improve the working efficiency of electrolysis deoxygenation component.

Description

Refrigerating device and its container for storing
Technical field
The present invention relates to refrigerating field, more particularly to a kind of refrigerating device and its container for storing.
Background technology
Controlled atmosphere technology refers to that the atmosphere (gas componant of enclosure space residing for object is stored by adjusting in general manner Ratio or gas pressure) mode extend the technology of shelf life of food products, basic principle is:In certain enclosure space It is interior, the atmosphere different from normal air constituent is obtained by various regulative modes, to inhibit to cause storage object (usually to eat Material) putrid and deteriorated physiological and biochemical procedure and microorganism activity.Particularly, in this application, the controlled atmosphere discussed will Specifically in the controlled atmosphere technology that gas component ratio is adjusted.
Those skilled in the art know that normal air constituent includes (pressing volume percentage, hereafter together):About 78% Nitrogen, about 21% oxygen, the carbon dioxide of about 0.939% rare gas 0.031% and 0.03% other gases and Impurity is (for example, ozone, nitric oxide, nitrogen dioxide, vapor etc..In controlled atmosphere field, generally use is filled to enclosure space Enter nitrogen-rich gas and obtains the fresh-keeping atmosphere of rich nitrogen oxygen deprivation to reduce the mode of oxygen content.Here, people in the art Member knows that nitrogen-rich gas refers to the gas that nitrogen content is more than nitrogen content in above-mentioned normal air, such as nitrogen therein Content can be 95%~99%, even higher;And it is more than above-mentioned normal that the fresh-keeping atmosphere of rich nitrogen oxygen deprivation, which refers to nitrogen content, Nitrogen content, oxygen content are less than the atmosphere of oxygen content in above-mentioned normal air in air.
Find fruit and vegetable in hypoxemia water although the history of controlled atmosphere technology can trace back to German biologist in 1821 Metabolism can be usually reduced to start.But up to this point, since the equipment of making nitrogen volume for being conventionally used to controlled atmosphere is huge Greatly, with high costs, cause the technology to be substantially also limited to using (the storage capacity one on the professional storage of various large sizes As at least 30 tons or more).It can be said that being likely to controlled atmosphere economically using which kind of gas regulation technology appropriate and related device System compact, mute make it is suitable for family or personal user, are that controlled atmosphere field technology personnel thirst for solving always But the technical barrier for the solution that fails always.
Invention content
In view of the above problems, it is proposed that the present invention overcoming the above problem in order to provide one kind or solves at least partly State the refrigerating device and its container for storing of problem.
It is an object of the invention to provide rich nitrogen oxygen deprivations in favor of the atmosphere of food fresh-keeping.
Another object of the present invention is to improve the working efficiency of electrolysis deoxygenation component.
Another object of the present invention is for the ease of being electrolysed the installation and removal of deoxygenation component.
On the one hand, the present invention provides a kind of container for storing for refrigerating device, including:Box body, the interior limit of box body There are storage space, box body both sides to be wherein provided with opening on one side surely;It is electrolysed deoxygenation component, is removable installed in opening, It is configured to consume the oxygen of controlled atmosphere space interior by cell reaction;Wherein being electrolysed deoxygenation component includes:Anode plate, configuration At electrolysis vapor, hydrogen ion and oxygen are generated;Cathode plate, is configured with hydrogen ion and oxygen reaction generates water;And clamping Proton exchange membrane between cathode plate and anode plate is configured to hydrogen ion transporting cathode plate side by anode plate side; Wherein cathode plate is at least partly exposed to inside storage space facing away from the one side of proton exchange membrane, and anode plate is facing away from proton exchange membrane One side be at least partly exposed to outside storage space.
Optionally, electrolysis deoxygenation component further includes:Wind turbine is set to side of the anode plate facing away from proton exchange membrane, will Vapor outside container for storing is blowed towards anode plate.
Optionally, electrolysis deoxygenation component further includes:Two layers of diffusion layer, is respectively arranged between anode plate and proton exchange membrane And between cathode plate and proton exchange membrane, for conductive and permission water vapor diffusion.
Optionally, the edge of anode plate also has the anode plate terminals for connecting extraneous galvanic anode;Cathode plate Edge also has the cathode plate terminals for connecting extraneous cell cathode.
Optionally, electrolysis deoxygenation component further includes:Accommodating case, for integrating all parts in electrolysis deoxygenation component, Top offers the installing port for being packed into electrolysis deoxygenation component all parts, the bottom surface hollow out of accommodating case, to allow gas logical It crosses.
Optionally, one of accommodating case side wall is also set up there are two through-hole, to allow anode plate terminals and cathode Plate terminals stretch out.
Optionally, the edge of installing port is also with a circle towards the flange stretched out outside accommodating case, for by accommodating case It is overlapped at the open edge of box body.
Optionally, flange has at least two spaced notches, to appear anode plate terminals and cathode plate wiring End.
Optionally, multiple claws are provided at the open edge of box body, the lateral surface of accommodating case is correspondingly provided with multiple convex It rises, claw blocks protrusion to realize the installation of accommodating case.
Optionally, container for storing is drawer comprising:Cylinder, it is internal to form storage space;And withdrawing part, it can be pushed away Enter inner barrel or extracted out by inner barrel, to open or close storage space;Wherein electrolysis deoxygenation component is set to cylinder two On the side of one of side.
On the other hand, the present invention also provides a kind of refrigerating devices, including babinet, internal to form refrigerating dress The storage compartment set, storage compartment includes refrigerator room and freezing compartment;Above-mentioned container for storing, container for storing are set to refrigerator Room bottom.
Optionally, above-mentioned refrigerating device further includes:Water storage box, it is indoor to be set to storage, is located at container for storing Side;Electrolysis deoxygenation group is set on side of the box body towards water storage box.
The present invention provides a kind of container for storing for refrigerating device, including:It is electrolysed deoxygenation component.It is electrolysed deoxygenation Component is used to consume the oxygen in storage space in air, to obtain rich nitrogen oxygen deprivation in the space in favor of food fresh-keeping Atmosphere.The atmosphere reduces aerobic the exhaling of food (especially fruits and vegetables) by the content of oxygen in reduction storage space The intensity of suction, while ensureing the respiration on basis, prevent food from carrying out anaerobic respiration, to reach the mesh of food long-period freshness preserving 's.
Further, electrolysis deoxygenation component further includes fan, for blowing vapor to anode plate.Electrolysis in the present invention The reactant of deoxygenation component anode plate is water, and anode plate needs constantly to keep the skin wet so that cell reaction can continue into Row.When being electrolysed deoxygenation component and opening work, battery is powered to cathode plate and anode plate respectively, while wind turbine is opened, wind turbine to While anode plate blows air, the vapor in air is blowed into positive plate together, to provide reactant to anode plate.By Generally relatively low in refrigerating device internal temperature, the storage compartment in refrigerating device has moister gas atmosphere It encloses, includes a large amount of vapor in air.Therefore, storeroom room air can provide enough reactants to anode plate, It is not necessary that water source or water delivery device is separately provided for electrolysis deoxygenation component.
Further, the present invention also provides a kind of refrigerating device, which includes:Container for storing And water storage box.Water storage box is located at the side of the container for storing, and is bonded the side wall of container for storing or certain apart from container for storing Interval setting.Electrolysis deoxygenation component is set on side of the cylinder towards the water storage box, i.e., anode plate is towards the water storage Box.Since water storage box storage inside has liquid water, neighbouring humidity is larger, and the air of the position can provide abundance to anode plate Vapor as reactant.Therefore, electrolysis deoxygenation component is arranged in face of water storage box, the progress of cell reaction can be promoted, To improve the working efficiency of electrolysis deoxygenation component.
According to the following detailed description of specific embodiments of the present invention in conjunction with the accompanying drawings, those skilled in the art will be brighter The above and other objects, advantages and features of the present invention.
Description of the drawings
Some specific embodiments that the invention will be described in detail by way of example and not limitation with reference to the accompanying drawings hereinafter. Identical reference numeral denotes same or similar component or part in attached drawing.It should be appreciated by those skilled in the art that these What attached drawing was not necessarily drawn to scale.In attached drawing:
Fig. 1 is the schematic diagram of container for storing according to an embodiment of the invention;
Fig. 2 is the schematic diagram of the electrolysis deoxygenation component of container for storing according to an embodiment of the invention;
Fig. 3 is the decomposition diagram of the electrolysis deoxygenation component of container for storing according to an embodiment of the invention;
Fig. 4 is the schematic diagram of the accommodating case of the electrolysis deoxygenation component of container for storing according to an embodiment of the invention;
Fig. 5 is the enlarged diagram of container for storing opening according to an embodiment of the invention;
Fig. 6 is the decomposition diagram of container for storing according to an embodiment of the invention;
Fig. 7 is the schematic diagram of container for storing and water storage box according to an embodiment of the invention;
Fig. 8 is the schematic internal view of refrigerating device according to an embodiment of the invention.
Specific implementation mode
As shown in Figure 1 and Figure 2, the embodiment of the present invention provides firstly a kind of container for storing for refrigerating device 100, including:Box body 110, electrolysis deoxygenation component 200.Define storage space in box body 110, wherein the one of 110 both sides of box body Face is provided with opening.Electrolysis deoxygenation component 200 is formed in above-mentioned opening, is configured to consume controlled atmosphere sky by cell reaction Between internal oxygen.
In the present embodiment, it is open as rectangular aperture, for installing electrolysis deoxygenation component 200.It is electrolysed deoxygenation component 200 Size and openings of sizes are adapted, so that it can completely enclose opening, prevent from that gas occurs with extraneous inside storage space It exchanges.
As shown in figure 3, electrolysis deoxygenation component 200 includes:Battery, anode plate 220, cathode plate 230 and it is held on cathode plate Proton exchange membrane 210 between 230 and anode plate 220.Battery can be arranged on container for storing, can also be arranged and hold in storing Outside device.Cathode plate 230 is at least partly exposed to inside storage space facing away from the one side of proton exchange membrane 210, and anode plate 220 is carried on the back One side towards proton exchange membrane 210 is at least partly exposed to outside storage space.That is, electrolysis deoxygenation component 200 has At least 3-tier architecture, is followed successively by anode plate 220, proton exchange membrane 210 and cathode plate 230, and anode plate 220 is towards outside storage space Portion, cathode plate 220 is towards inside storage space.Each layer of structure is parallel with plane where opening, and each level product is big It is small identical as openings of sizes.
Preferably, cathode plate 230 and anode plate 220 are carbon electrode plate or platinum electrode plate, generally have platinum coating using surface Carbon electrode.The edge of anode plate 220 and cathode plate 230 is respectively provided with there are one terminals, respectively 221 He of anode plate terminals Cathode plate terminals 231, the anode and cathode for being separately connected battery.Battery provides electronics, while anode to cathode plate 230 Plate 220 provides electronics to galvanic anode.Anode plate 220 is configured to electrolysis vapor, generates proton and oxygen.Proton exchange membrane 210 are configured to proton transporting 230 side of cathode plate by 220 side of anode plate.Cathode plate 230 is configured with proton and oxygen Solid/liquid/gas reactions generate water.Wherein, the chemical equation of anode plate and cathode plate is respectively:
Anode plate:2H2O→O2+4H++4e-
Cathode plate:O2+4H++4e-→2H2O
Specifically, the anode of battery charges to anode plate 220,220 side of anode plate is electrolysed the water outside container for storing 100 Steam, generates hydrogen ion and oxygen, oxygen are expelled to outside storage space, and hydrogen ion enters in proton exchange membrane 210.Battery Cathode charges to cathode plate 230, provides electronics to cathode plate 230,230 side of cathode plate is provided using proton exchange membrane 210 Oxygen reaction inside hydrogen ion and storage space generates water, and the oxygen inside storage space is consumed with this.
Proton exchange membrane 210 includes:Proton conductive polymer, perforated membrane and at least one active constituent.It is at least one Active constituent is dispersed in proton conductive polymer, and proton conductive polymer is inhaled into and is filled in the hole of perforated membrane.Matter Proton exchange 210 act as passing through for hydrogen ion, and the hydrogen ion that the reaction of anode plate 220 generates is transported cathode plate 230, It reacts and uses for cathode plate 230.
Preferably, proton conductive polymer is polystyrolsulfon acid (PSSA) or carboxymethyl cellulose (CMC).Perforated membrane is Polytetrafluoroethylene (PTFE) (PTFE) or fluorinated ethylene propylene (FEP) or polyolefin film or perfluoroethylene-propylene or glass fibre or ceramics Fiber or polymer fiber;Active constituent is the silica gel suitable for electrokinetic flow, and the silica gel concentration of dispersion is no more than proton exchange The 5% of film quality.
In the present embodiment, above-mentioned electrolysis deoxygenation component 200 can further include:Two pieces of elastic plates 240, set respectively It sets in the outside of anode plate 220 and cathode plate 230, for stepping up anode plate 220, proton exchange membrane 210 and cathode plate 230.Electricity It further includes multiple trip bolts, two pieces of elastic plates 240, anode plate 220, proton exchange membrane 210 and cathode plate to solve deoxygenation component 200 230 by the position of proximal edge are both provided with multiple screw holes 201, and each trip bolt sequentially passes through above-mentioned multiple component identical bits The screw hole 201 set, to realize the fixation and clamping of multi-layer part.Two pieces of elastic plates 240 are towards cathode plate 230 and anode plate 220 Side on all have multiple elastic bumps 241, and the position of the elastic bumps 241 on two pieces of elastic plates 240 is corresponding, also Be say each elastic bumps 241 can and another block of plate on an elastic bumps 241 match it is common close squeeze anode plate 220, Cathode plate 230, for further stepping up proton exchange membrane 210.The middle section hollow out of every piece of elastic plate 240, or uniformly open If multiple stomatas, to allow gas to pass through.
In the present embodiment, electrolysis deoxygenation component 200 can also include further:Diffusion layer 270, activated carbon sieves With one or more washers 260.Diffusion layer 270 is between anode plate 220 and proton exchange membrane 210 and 230 He of cathode plate Between proton exchange membrane 210, the material of diffusion layer 270 is the titanium net of surface platinum plating, and it acts as convenient for conductive and permission water Steam is spread.Activated carbon sieves is set to side of the anode facing away from proton exchange membrane 210, enters anode plate 220 for purifying Gas.At least one washer 260 can be between above-mentioned multilayered structure, and each washer 260 is the circular thin circle of square, outside It is identical as the size of cathode plate 230, anode plate 220 to enclose size.Each washer 260 is made of elastic material, to buffer adjacent layer Between extruding force.
Being electrolysed deoxygenation component 200 further includes:Wind turbine 250.Above-mentioned wind turbine 250 can be minisize axial-flow wind turbine 250.Wind turbine 250 are set to side of the anode plate 220 facing away from proton exchange membrane 210, and shaft is vertical with anode plate 220, for holding storing Vapor outside device 100 is blowed towards anode.The reactant of 200 anode plate of electrolysis deoxygenation component of the present embodiment steams for water Gas, therefore, anode plate need constantly to keep the skin wet, so that cell reaction can continue to carry out.When electrolysis deoxygenation component 200 When opening work, battery is powered to cathode plate 230 and anode plate 220 respectively, while wind turbine 250 is opened, and wind turbine 250 is to anode plate 220 while blow air, and the vapor in air is blowed positive plate 220 together, to provide reaction to anode plate 220 Object.Since refrigerating device internal temperature is generally relatively low, the storage compartment in refrigerating device has moister gas Body atmosphere includes a large amount of vapor in air.Therefore, storeroom room air can provide enough to anode plate 220 Reactant, it is not necessary that water source or water delivery device is separately provided for electrolysis deoxygenation component 200.
In the present embodiment, the multilayered structures such as above-mentioned cathode plate 230, anode plate 220 and proton exchange membrane 210 are integrated into one In accommodating case 280, in order to integral installation or dismounting electrolysis deoxygenation component 200.Above-mentioned accommodating case 280 can be completely embedded into storing In the box wall of container 100, it can also be partially submerged into.
As shown in figure 4, the X-direction defined in figure is the length direction of accommodating case 280, Y is width direction, and Z is height side To.280 top of accommodating case offers the installing port for being fitted into all parts in electrolysis deoxygenation component 200, which is square Shape, size are adapted with cathode plate 230,220 size of anode plate.280 bottom surface hollow out of accommodating case, to allow gas logical It crosses, in the present embodiment, 280 bottom surface of accommodating case is further fixed on a cross frame 286, and deoxygenation group is electrolysed for support All parts in part 200.
One of accommodating case 280 side wall is also set up there are two through-hole 285, to allow anode plate terminals 221 and the moon Pole plate terminals 231 stretch out.After anode plate terminals 221 or cathode plate terminals 231 stretch out accommodating case 280, then pass through circuit It connects and is connected to the anode and cathode of extraneous battery.
The flange 282 that the edge of installing port is also stretched out with a circle towards the outside of accommodating case 280, for by accommodating case 280 are overlapped at the open edge of box body.When accommodating case 280 is overlapped at the open edge of box body, flange 282 can seal Gap between box body and accommodating case 280 prevents storage space internal gas from leaking.There are flange 282 at least two intervals to be arranged Notch 283, the position face anode plate terminals 221 and cathode plate terminals 231 of two of which notch 283, on appearing State two terminals be convenient for connection, while above-mentioned notch 283 can also dismounting be electrolysed deoxygenation component 200 during, User is facilitated to take accommodating case 280.
As shown in figure 5, being provided with multiple claws 113 at the open edge of box body 110, the lateral surface of accommodating case 280 is corresponding Multiple raised 284 are provided with, claw 113 blocks protrusion 284 to realize the installation of accommodating case 280.In the present embodiment, accommodating case The outer surface of 280 each side wall be respectively provided with there are two protrusion 284, length or width side of two protrusions 284 along accommodating case 280 It is arranged to interval, and two protrusions 284 are on the sustained height position of accommodating case 280.On each edge that box body 110 is open Two claws 113 are correspondingly arranged, two claws 113 horizontally outward stretch out, and end is for blocking 280 side wall of accommodating case Protrusion 284, to fix accommodating case 280.
To electrolysis deoxygenation component 200 assemble when, first by cathode plate 230, anode plate 220, proton exchange membrane 210, The components such as washer 260, elastic plate 240, diffusion layer 270 are arranged according to aforementioned location relationship, and form multilayered structure, then again The multilayered structure is integrally placed into inside accommodating case 280.The height side of the layer orientation and accommodating case 280 of the multilayered structure To consistent.In the present embodiment, the multilayered structure in accommodating case 280 is followed successively by from top to bottom:Wind turbine 250, elastic plate 240, pad Circle 260, anode plate 220, washer 260, diffusion layer 270, proton exchange membrane 210, diffusion layer 270, washer 260, cathode plate 230, Washer 260 and elastic plate 240.When installation is electrolysed deoxygenation component 200, by the whole insertion of assembled electrolysis deoxygenation component 200 In the opening of box body, when the flange of accommodating case 280 contradicts the edge of opening, multiple claws 113 just block 280 side of accommodating case Protrusion 284 on wall, to which accommodating case 280 is fixed, installation is complete for electrolysis deoxygenation component 200.If user does not need storing appearance The deoxygenation function of device, then by the whole taking-up of accommodating case 280.
The container for storing 100 of the present embodiment includes:It is electrolysed deoxygenation component 200.Electrolysis deoxygenation component 200 is for consuming storing Oxygen in space in air, to obtain rich nitrogen oxygen deprivation in the space in favor of the atmosphere of food fresh-keeping.The gas Atmosphere is reduced the intensity of the aerobic respiration of food (especially fruits and vegetables), is protected simultaneously by the content of oxygen in reduction storage space The respiration for demonstrate,proving basis prevents food from carrying out anaerobic respiration, to achieve the purpose that food long-period freshness preserving.
The embodiment of the present invention additionally provides a kind of refrigerating device, including:Babinet, above-mentioned container for storing 100 and water storage Box 300.Box house forms the storage compartment of refrigerating device.Container for storing 100 and water storage box 300 may be contained within storeroom Chamber interior.
In the present embodiment, refrigerating device can be refrigerator, be in the present embodiment wind cooling refrigerator, in wind cooling refrigerator Freezed to storage compartment using air flow circuit in portion.The storage compartment of the refrigerator includes:Refrigerator room and positioned at refrigeration Freezing compartment below compartment.Container for storing 100 can be drawer, and as shown in Figure 6, Figure 7, the drawer is by cylinder 111 and pull Portion 112 forms, and electrolysis deoxygenation component 200 is set on the top surface of cylinder 111.The drawer is removable installed in the refrigeration of refrigerator The bottom of compartment is provided with multipair fin in the inside both sides of refrigerator room liner 410, wherein one positioned at refrigerator room bottom It is used to limit the installation site of drawer to fin.Water storage box 300 is located at the side of container for storing, i.e. water storage box 300 can be arranged In the left or right side of container for storing.Also, water storage box 300 is bonded container for storing or is arranged apart from container for storing certain intervals (interval is usually no more than 5cm), water storage box 300 are connected by pipeline with the ice maker built in refrigerator.Inside water storage box 300 Storing liquid water provides ice making raw material to ice maker.Ice maker manufactures ice cube using liquid water, to be supplied to user to make With.
Electrolysis deoxygenation component 200 is set on side of the cylinder 111 towards water storage box 300, i.e., anode plate 220 is towards the storage Water box 300.Since 300 storage inside of water storage box has liquid water, neighbouring humidity is larger, and the air of the position can be to anode plate 220 provide sufficient vapor as reactant.Therefore, electrolysis deoxygenation component 200 is arranged in face of water storage box 300, can promotees Into the progress of cell reaction, to improve the working efficiency of electrolysis deoxygenation component 200.
So far, although those skilled in the art will appreciate that present invention has been shown and described in detail herein multiple shows Example property embodiment still without departing from the spirit and scope of the present invention, still can according to the present disclosure directly Determine or derive many other variations or modifications consistent with the principles of the invention.Therefore, the scope of the present invention is understood that and recognizes It is set to and covers other all these variations or modifications.

Claims (11)

1. a kind of container for storing for refrigerating device, including:
Box body defines storage space in the box body, and the box body both sides are wherein provided with opening on one side;
It is electrolysed deoxygenation component, the opening is removable installed in, is configured to consume the controlled atmosphere by cell reaction The oxygen of space interior;The wherein described electrolysis deoxygenation component includes:
Anode plate is configured to electrolysis vapor, generates hydrogen ion and oxygen;
Cathode plate, is configured with hydrogen ion and oxygen reaction generates water;With
The proton exchange membrane being held between the cathode plate and anode plate is configured to transport hydrogen ion by the anode plate side It is defeated to arrive the cathode plate side;Wherein
The cathode plate is at least partly exposed to facing away from the one side of the proton exchange membrane inside the storage space, the anode The one side of backboard towards the proton exchange membrane is at least partly exposed to outside the storage space.
2. container for storing according to claim 1, wherein the electrolysis deoxygenation component further includes:
Wind turbine is set to side of the anode plate facing away from the proton exchange membrane, and the water outside the container for storing is steamed Gas is blowed towards the anode plate.
3. container for storing according to claim 1, wherein the electrolysis deoxygenation component further includes:
Two layers of diffusion layer, is respectively arranged between the anode plate and the proton exchange membrane and the cathode plate and the matter Between proton exchange, for conductive and permission water vapor diffusion.
4. container for storing according to claim 1, wherein
The edge of the anode plate also has the anode plate terminals for connecting extraneous galvanic anode;
The edge of the cathode plate also has the cathode plate terminals for connecting extraneous cell cathode.
5. container for storing according to any one of claim 1 to 4, wherein the electrolysis deoxygenation component further includes:
Accommodating case, for integrating all parts in the electrolysis deoxygenation component, top is offered for being packed into the electrolysis The installing port of deoxygenation component all parts, the bottom surface hollow out of the accommodating case, to allow gas to pass through.
6. container for storing according to claim 5, wherein
One of accommodating case side wall is also set up there are two through-hole, to allow anode plate terminals and cathode plate terminals It stretches out.
7. container for storing according to claim 6, wherein
The edge of the installing port is also with a circle towards the flange stretched out outside the accommodating case, for by the accommodating case It is overlapped at the open edge of the box body.
8. container for storing according to claim 7, wherein
Multiple claws are provided at the open edge of the box body, the lateral surface of the accommodating case is correspondingly provided with multiple protrusions, The claw blocks the protrusion to realize the installation of the accommodating case.
9. container for storing according to claim 8, wherein
The container for storing is drawer comprising:
Cylinder, it is internal to form storage space;With
Withdrawing part can be pushed into the inner barrel or be extracted out by the inner barrel, to open or close the storage space; Wherein
The electrolysis deoxygenation component is set on the side of one of the cylinder both sides.
10. a kind of refrigerating device, including
Babinet, the internal storage compartment for forming the refrigerating device, the storage compartment includes refrigerator room and freezing Compartment;
Container for storing as claimed in any one of claims 1-9 wherein, the container for storing are set to the refrigerator room bottom.
11. refrigerating device according to claim 10, further includes:
Water storage box, be set to it is described storage it is indoor, be located at the container for storing side;
The electrolysis deoxygenation group is set on side of the box body towards the water storage box.
CN201711407921.XA 2017-12-22 2017-12-22 Refrigerating device and its container for storing Pending CN108302889A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711407921.XA CN108302889A (en) 2017-12-22 2017-12-22 Refrigerating device and its container for storing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711407921.XA CN108302889A (en) 2017-12-22 2017-12-22 Refrigerating device and its container for storing

Publications (1)

Publication Number Publication Date
CN108302889A true CN108302889A (en) 2018-07-20

Family

ID=62870763

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711407921.XA Pending CN108302889A (en) 2017-12-22 2017-12-22 Refrigerating device and its container for storing

Country Status (1)

Country Link
CN (1) CN108302889A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019105310A1 (en) * 2017-11-30 2019-06-06 青岛海尔股份有限公司 Refrigerating and freezing apparatus and storage container thereof
WO2019105307A1 (en) * 2017-11-30 2019-06-06 青岛海尔股份有限公司 Refrigerating and freezing device and storage container thereof
CN111912158A (en) * 2020-07-23 2020-11-10 珠海格力电器股份有限公司 Electrolysis device, control method and low-temperature storage equipment
WO2022242196A1 (en) * 2021-05-20 2022-11-24 青岛海尔电冰箱有限公司 Refrigerator

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1532495A (en) * 2003-03-25 2004-09-29 株式会社东芝 Refrigerator
CN101388463A (en) * 2008-10-23 2009-03-18 上海交通大学 Membrane electrode for proton exchange membrane water electrolysis battery and preparation thereof
CN103808106A (en) * 2012-11-12 2014-05-21 株式会社东芝 Food preservation device
CN107289722A (en) * 2017-06-12 2017-10-24 青岛海尔股份有限公司 A kind of depository dish and the refrigerator with it

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1532495A (en) * 2003-03-25 2004-09-29 株式会社东芝 Refrigerator
CN101388463A (en) * 2008-10-23 2009-03-18 上海交通大学 Membrane electrode for proton exchange membrane water electrolysis battery and preparation thereof
CN103808106A (en) * 2012-11-12 2014-05-21 株式会社东芝 Food preservation device
CN107289722A (en) * 2017-06-12 2017-10-24 青岛海尔股份有限公司 A kind of depository dish and the refrigerator with it

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019105310A1 (en) * 2017-11-30 2019-06-06 青岛海尔股份有限公司 Refrigerating and freezing apparatus and storage container thereof
WO2019105307A1 (en) * 2017-11-30 2019-06-06 青岛海尔股份有限公司 Refrigerating and freezing device and storage container thereof
CN111912158A (en) * 2020-07-23 2020-11-10 珠海格力电器股份有限公司 Electrolysis device, control method and low-temperature storage equipment
WO2022242196A1 (en) * 2021-05-20 2022-11-24 青岛海尔电冰箱有限公司 Refrigerator

Similar Documents

Publication Publication Date Title
CN109855377A (en) Refrigerating device and its container for storing
CN109855378A (en) Refrigerating device and its container for storing
CN108168181A (en) Refrigerator
CN108332479A (en) Refrigerator
CN108332480A (en) Refrigerating device and its container for storing
CN108302889A (en) Refrigerating device and its container for storing
CN108278823A (en) Refrigerator
CN108514066B (en) Refrigerating and freezing device
CN109855376B (en) Refrigerating and freezing device and deoxygenation control method thereof
CN109855348B (en) Refrigerating and freezing device
WO2021083433A1 (en) Refrigerator
CN108302861A (en) Refrigerator
CN109850386A (en) Refrigerating device and its container for storing
CN215295494U (en) Refrigerator with a door
CN109845944A (en) Refrigerating device and its container for storing
CN109855340A (en) Refrigerating device and its container for storing
CN211695579U (en) Refrigeration storage device
CN112747549B (en) Storage device for refrigerator and refrigerator with storage device
CN109855375A (en) Refrigerating device and its remove oxygen control method
CN109855349B (en) Refrigerating and freezing device
CN216409493U (en) Refrigerating and freezing device and storage device thereof
JP2014037958A (en) Oxygen reduction device
CN112747524A (en) Refrigerator with a door
CN109855341A (en) Refrigerating device and its container for storing
CN214469527U (en) Refrigerator with a door

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180720

RJ01 Rejection of invention patent application after publication