CN107289722A - A kind of depository dish and the refrigerator with it - Google Patents
A kind of depository dish and the refrigerator with it Download PDFInfo
- Publication number
- CN107289722A CN107289722A CN201710436835.5A CN201710436835A CN107289722A CN 107289722 A CN107289722 A CN 107289722A CN 201710436835 A CN201710436835 A CN 201710436835A CN 107289722 A CN107289722 A CN 107289722A
- Authority
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- China
- Prior art keywords
- depository dish
- oxygen
- reduction apparatus
- housing
- oxygen reduction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/10—Arrangements for mounting in particular locations, e.g. for built-in type, for corner type
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Cold Air Circulating Systems And Constructional Details In Refrigerators (AREA)
Abstract
The present invention provides a kind of depository dish, which is provided with oxygen reduction apparatus, oxygen reduction apparatus includes:Housing, yin, yang electrode, PEM, PEM includes:Proton conductive polymer, perforated membrane and active component;At least part of active component is dispersed in proton conductive polymer, and proton conductive polymer is inhaled into and is filled in the hole of perforated membrane;Depository dish also includes blower fan and oxygen sensor, when first threshold of the oxygen content in depository dish higher than setting, and oxygen sensor feedback information to refrigerator control unit opens oxygen reduction apparatus and the blower fan;When Second Threshold of the oxygen content in depository dish less than setting, oxygen sensor feedback information to refrigerator control unit closes oxygen reduction apparatus and blower fan.Compared with prior art, the depository dish in the present invention realizes the function of extension preserving fruit and vegetable utilizing phase, and it need not add aqueous water in the anode of electrolysis unit, is only that depository dish can be achieved to subtract oxygen function using the vaporous water in refrigerator body.
Description
Technical field
The invention belongs to household electrical appliance technical field, more particularly to a kind of depository dish and the refrigerator with it.
Background technology
The use of electrolytic method deoxygenation is a kind of emerging method, it has safety collar in the controlled atmosphere technology of refrigerator
The advantages of guarantor, low energy consumption, deoxygenation velocity-stabilization.The technical scheme of current comparative maturity is to install electricity on the depository dish in refrigerator
Pole device, and need to supply aqueous water to electrolysis unit, but there are some drawbacks in this technology:
1st, aqueous water needs user to add on time, and Consumer's Experience is not good;
2nd, the aqueous water supplied needs pure water, if water quality is problematic, can produce considerable influence to the life-span of electrolytic film;
3rd, in the anode surface of electrolysis unit " liquid flooding " phenomenon easily occurs for aqueous water, i.e., the confession of anode water is carried out using aqueous water
Give, then cause water in polyelectrolyte membrane(That is PEM)It is mobile and reach cathode layer, hinder hydrogen in cathode layer from
The reaction of son and oxygen, so as to cause the reduction of its performance.
The content of the invention
An object of the present invention is to provide a kind of depository dish with oxygen reduction apparatus for solving above-mentioned technical problem, its
The function of extension preserving fruit and vegetable utilizing phase can be achieved.
The present invention also aims to provide a kind of refrigerator.
One of for achieving the above object, the present invention provides a kind of depository dish, and its at least one box wall is provided with least
One through hole, is removably equipped with oxygen reduction apparatus, the oxygen reduction apparatus includes in the through hole:
Housing;
Yin, yang electrode, in the housing;
PEM, is clamped between the yin, yang electrode, the PEM includes:It is proton conductive polymer, porous
Film and at least one active component;Wherein, at least part of active component is dispersed in the proton conductive polymer, and
The proton conductive polymer is inhaled into and is filled in the hole of the perforated membrane;
The depository dish also includes blower fan and the oxygen sensor for sensing oxygen content in the depository dish, and the oxygen is passed
When the oxygen content that sensor is configured as in the depository dish is higher than the first threshold of setting, the oxygen sensor feedback letter
Breath opens the oxygen reduction apparatus and the blower fan to refrigerator control unit;Set when the oxygen content in the depository dish is less than
During fixed Second Threshold, the oxygen sensor feedback information to refrigerator control unit, by the oxygen reduction apparatus and the blower fan
Close.
As a further improvement on the present invention, the blower fan is arranged on the outside of the depository dish, and subtracts oxygen dress with described
Put and be correspondingly arranged.
As a further improvement on the present invention, when first threshold of the oxygen content in the depository dish higher than setting,
The air quantity of the blower fan is in 6-7CFM, and the deaerating effect of the oxygen reduction apparatus is best.
As a further improvement on the present invention, the proton conductive polymer is polystyrolsulfon acid(PSSA)Or carboxylic first
Base cellulose (CMC).
As a further improvement on the present invention, the material of the perforated membrane is polytetrafluoroethylene (PTFE) (PTFE) or ethylene fluoride
Propylene (FEP) or polyolefin film or perfluoroethylene-propylene or glass fibre or ceramic fibre or polymer fiber, the work
The material of sexual element is the silica gel suitable for electrokinetic flow.
As a further improvement on the present invention, the housing includes the first housing and the second housing, when first housing
After the second shell combination, an accommodation space, the yin, yang electrode are formed between first housing and second housing
It is located at the PEM in the accommodation space.
As a further improvement on the present invention, the oxygen reduction apparatus also include extremely electric body, gas expanding layer, the first packing ring and
Second packing ring, the extremely electric body is located between the anode and the PEM, and the gas expanding layer is located at described the moon
Between pole and the PEM, first packing ring is located between first housing and the anode, second pad
Circle is located between the negative electrode and second housing.
As a further improvement on the present invention, the oxygen reduction apparatus also includes the sealing ring positioned at second hull outside.
As a further improvement on the present invention, it is described to subtract oxygen dress when the oxygen reduction apparatus is assemblied on the depository dish
The box wall of the half insertion depository dish is put, or is embedded in the box wall of the depository dish entirely.
To realize above-mentioned another goal of the invention, the present invention provides a kind of refrigerator, including depository dish as described above.
The beneficial effects of the invention are as follows:A kind of realized with the oxygen reduction apparatus that refrigerator depository dish matches is provided and extends fruits and vegetables guarantor
The function of fresh phase, it need not add aqueous water in the anode of electrolysis unit, only can be real using the vaporous water in refrigerator body
Show depository dish subtracts oxygen function.
Brief description of the drawings
Fig. 1 is the structural representation of depository dish in the embodiment of the invention;
Fig. 2 is the explosive view of the oxygen reduction apparatus of the embodiment of the invention.
Embodiment
Below with reference to each embodiment shown in the drawings, the present invention will be described in detail.But these embodiments are not
The limitation present invention, structure that one of ordinary skill in the art is made according to these embodiments, method or change functionally
Change and be all contained in protection scope of the present invention.
Join the embodiment of the refrigerator depository dish shown in Fig. 1.The depository dish 10, at least the one of depository dish 10
Individual wall is provided with least one through hole(Non- label), oxygen reduction apparatus 11 is removably equipped with through-holes.In addition, depository dish
Also include blower fan(It is not shown)With the oxygen sensor 12 for sensing oxygen content in depository dish 10.
Join shown in Fig. 2, oxygen reduction apparatus 11 mainly includes housing, negative electrode 113, positive electrode 114 and PEM 115,
Wherein, PEM 115 is clamped between negative electrode 113 and positive electrode 114, and housing includes the first housing 111 and second again
Housing 112, after the first housing 111 and the combination of the second housing 112, one is formed between the first housing 111 and the second housing 112
Accommodation space(Non- label), negative electrode 113, the clamping PEM 115 of positive electrode 114 are located in the accommodation space.
Preferably, negative electrode 113 and positive electrode 114 are carbon electrode or platinum electrode, the general carbon for using surface to have platinum coating
Electrode;The material of PEM 115 is proton conductive polymer, and PEM 115 includes:It is proton conductive polymer, many
Pore membrane and at least one active component;Wherein, at least part of active component is dispersed in the proton conductive polymer,
And the proton conductive polymer is inhaled into and is filled in the hole of the perforated membrane.PEM 115 act as hydrogen supply
Ion is passed through so that the product of anode reaction is changed into the reactant of cathode reaction.
Preferably, proton conductive polymer is polystyrolsulfon acid(PSSA)Or carboxymethyl cellulose (CMC);It is porous
Film is polytetrafluoroethylene (PTFE) (PTFE) or PEP (FEP) or polyolefin film or perfluoroethylene-propylene or glass fibers
Dimension or ceramic fibre or polymer fiber;Active ingredient is the silica gel suitable for electrokinetic flow, and scattered silica gel concentration is no more than
The 5% of proton conductive film quality.
Further, oxygen reduction apparatus 11 also includes extremely electric body 116, gas expanding layer the 117, first packing ring 119 and the second pad
Circle 120, extremely electric body 116 is located between anode 114 and PEM 115, and the material of extremely electric body 116 is the titanium of surface platinum plating
Net, it is conductive and through gas that it, which is acted on,;Gas expanding layer 117 is located between negative electrode 113 and PEM 115, and gas expands
The material for spreading layer 117 is carbon paper or carbon cloth, and its effect is the diffusion for vapor.First packing ring position 119 is in the first housing
Between 111 and anode 114, second packing ring 120 is located between the housing 112 of negative electrode 113 and second.
When oxygen reduction apparatus 11 is assemblied on depository dish 10, oxygen reduction apparatus 11 half is embedded in the box wall of depository dish 10, or complete embedding
Enter the box wall of depository dish 10, after oxygen reduction apparatus 11 is installed, the first housing 111 is towards the outside of depository dish 10, the second housing
112 towards the inside of depository dish 10.Preferably, oxygen reduction apparatus 11 also includes the sealing ring 118 for being located at the outside of the second housing 112,
To close the gap in oxygen reduction apparatus 11 and the box wall of depository dish 10 between through hole.
Depository dish 10 also includes being arranged on the blower fan 13 in the outside of depository dish 10 and for sensing oxygen in the depository dish 10
The oxygen sensor 12 of content, blower fan 13 is correspondingly arranged with oxygen reduction apparatus 11, and oxygen sensor 12 is configured as depository dish 10
When interior oxygen content is higher than the first threshold set, the feedback information of oxygen sensor 12 to refrigerator control unit(It is not shown),
Oxygen reduction apparatus 11 and blower fan 13 are opened;When Second Threshold of the oxygen content in depository dish 10 less than setting, oxygen sensor
The feedback information of device 12 closes oxygen reduction apparatus 11 and blower fan 13 to refrigerator control unit.
Preferably, the numerical value of first threshold is more than the numerical value of Second Threshold.
When first threshold of the oxygen content in depository dish 10 higher than setting, the feedback information of oxygen sensor 12 to refrigerator
Control unit, oxygen reduction apparatus 11 and blower fan 13 are opened simultaneously, i.e., blower fan 13 starts to rotate, and oxygen reduction apparatus 11 is powered, and starts electricity
The vaporous water in refrigerator body is solved, in the anode of oxygen reduction apparatus 11:Vaporous water is electrolyzed to produce hydrogen ion and oxygen, anode generation
Hydrogen ion reaches the negative electrode of oxygen reduction apparatus 11 through PEM 115, in negative electrode:Hydrogen ion and oxygen in depository dish 10 are anti-
Water should be generated.Simultaneously, during the cell reaction of oxygen reduction apparatus 11 occurs, blower fan 13 is also being rotated, to oxygen reduction apparatus
11 provide air quantity, and the wind that the water generated in negative electrode is provided by blower fan 13 is constantly dried up so that the chemistry of the chemical reaction of negative electrode
Balance, so as to constantly consume the oxygen of depository dish 10, reaches the effect of deoxygenation towards the direction movement of generation water.Preferably,
Air quantity is in 6-7CFM, and preferably, in the present embodiment, the optimal value of air quantity is 6.5CFM to the deaerating effect of oxygen reduction apparatus.This
What invention to be solved is that in cell reaction, while performance and life-span is ensured, electrolysis deoxygenation is carried out without using aqueous water.
The present invention also provides a kind of refrigerator(It is not shown), the refrigerator by using the depository dish introduced in the respective embodiments described above,
Depository dish in the respective embodiments described above can be obtained to have the advantage that, also, due to the other structures or work(to the refrigerator
Improvement can be not made, therefore the other structures at this to the refrigerator are also repeated no more.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.Any reference in claim should not be considered as to the claim involved by limitation.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It may be appreciated other embodiment.
Claims (10)
1. a kind of depository dish, its at least one box wall is provided with least one through hole, removably it is equipped with the through hole
Oxygen reduction apparatus, it is characterised in that the oxygen reduction apparatus includes:
Housing;
Yin, yang electrode, in the housing;
PEM, is clamped between the yin, yang electrode, the PEM includes:It is proton conductive polymer, porous
Film and at least one active component;Wherein, at least part of active component is dispersed in the proton conductive polymer, and
The proton conductive polymer is inhaled into and is filled in the hole of the perforated membrane;
The depository dish also includes blower fan and the oxygen sensor for sensing oxygen content in the depository dish, and the oxygen is passed
When the oxygen content that sensor is configured as in the depository dish is higher than the first threshold of setting, the oxygen sensor feedback letter
Breath opens the oxygen reduction apparatus and the blower fan to refrigerator control unit;Set when the oxygen content in the depository dish is less than
During fixed Second Threshold, the oxygen sensor feedback information to refrigerator control unit, by the oxygen reduction apparatus and the blower fan
Close.
2. depository dish according to claim 1, it is characterised in that the blower fan is arranged on the outside of the depository dish, and
It is correspondingly arranged with the oxygen reduction apparatus.
3. depository dish according to claim 2, it is characterised in that when the oxygen content in the depository dish is higher than setting
During first threshold, the air quantity of the blower fan is in 6-7CFM, and the deaerating effect of the oxygen reduction apparatus is best.
4. depository dish according to claim 1, it is characterised in that the proton conductive polymer is polystyrolsulfon acid
(PSSA)Or carboxymethyl cellulose (CMC).
5. depository dish according to claim 1, it is characterised in that the material of the perforated membrane is polytetrafluoroethylene (PTFE)
Or PEP (FEP) or polyolefin film or perfluoroethylene-propylene or glass fibre or ceramic fibre or poly- (PTFE)
Compound fiber, the material of the active ingredient is the silica gel suitable for electrokinetic flow.
6. depository dish according to claim 1, it is characterised in that the housing includes the first housing and the second housing, when
After first housing and the second shell combination, an accommodation space is formed between first housing and second housing,
The yin, yang electrode and the PEM are located in the accommodation space.
7. depository dish according to claim 6, it is characterised in that the oxygen reduction apparatus also includes extremely electric body, gas expanding
Layer, the first packing ring and second packing ring, the extremely electric body are located between the anode and the PEM, the gas expanding
Layer is located between the negative electrode and the PEM, first packing ring be located at first housing and the anode it
Between, the second packing ring is located between the negative electrode and second housing.
8. depository dish according to claim 7, it is characterised in that the oxygen reduction apparatus also includes being located at second housing
The sealing ring in outside.
9. depository dish according to claim 1, it is characterised in that when the oxygen reduction apparatus is assemblied on the depository dish
When, the box wall of the embedded depository dish of the oxygen reduction apparatus half, or the box wall of the depository dish is embedded in entirely.
10. a kind of refrigerator, it is characterised in that the refrigerator includes any described depository dish in claim 1 ~ 9.
Priority Applications (1)
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CN201710436835.5A CN107289722A (en) | 2017-06-12 | 2017-06-12 | A kind of depository dish and the refrigerator with it |
Applications Claiming Priority (1)
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CN201710436835.5A CN107289722A (en) | 2017-06-12 | 2017-06-12 | A kind of depository dish and the refrigerator with it |
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CN107289722A true CN107289722A (en) | 2017-10-24 |
Family
ID=60096170
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CN201710436835.5A Pending CN107289722A (en) | 2017-06-12 | 2017-06-12 | A kind of depository dish and the refrigerator with it |
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