WO2020045687A1 - Capsule d'oxygène liquide et dispositif d'injection d'oxygène liquide utilisant celle-ci - Google Patents

Capsule d'oxygène liquide et dispositif d'injection d'oxygène liquide utilisant celle-ci Download PDF

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Publication number
WO2020045687A1
WO2020045687A1 PCT/JP2019/035289 JP2019035289W WO2020045687A1 WO 2020045687 A1 WO2020045687 A1 WO 2020045687A1 JP 2019035289 W JP2019035289 W JP 2019035289W WO 2020045687 A1 WO2020045687 A1 WO 2020045687A1
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WO
WIPO (PCT)
Prior art keywords
capsule
liquid oxygen
lid
oxygen
opening
Prior art date
Application number
PCT/JP2019/035289
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English (en)
Japanese (ja)
Inventor
鍾勉 金
Original Assignee
李 粲淑
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 李 粲淑 filed Critical 李 粲淑
Publication of WO2020045687A1 publication Critical patent/WO2020045687A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00—Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/32—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/72—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for for edible or potable liquids, semiliquids, or plastic or pasty materials

Definitions

  • the present invention relates to a liquid oxygen capsule filled with liquid oxygen for making oxygen-containing water for drinking and an injection device, and in particular, has a sealed and stable structure in which the contents do not leak at room temperature after the liquid oxygen is filled.
  • the present invention relates to a liquid oxygen capsule in which liquid oxygen can be easily injected and ejected by piercing and insertion, in which liquid oxygen is easily sealed, and a liquid oxygen injection device using the same.
  • Oxygen water is water obtained by dissolving oxygen in water, and is drinking water containing oxygen more than water naturally present in the air. Oxygen is a gas that is hardly soluble in water, and requires technical processing such as jetting it vigorously into water to make it contained in drinking water. Further, since the generated oxygen water releases oxygen when left to stand and returns to the original natural water, there has been a demand for a device (apparatus) that can be easily generated as needed.
  • Japanese Patent Application Laid-Open No. 2010-137181 exists as a technique related to such oxygen water.
  • an oxygen injection tube having an oxygen injection member attached to the lower end thereof is inserted into the PET bottle, and the PET bottle is controlled by a pressure control valve.
  • this technology would make it possible to dissolve oxygen into the water in plastic bottles, but the equipment for supplying oxygen would have to be large, making it simple or portable. There was a problem that it was difficult to provide oxygen capsules and instruments for producing water.
  • 2013-158724 discloses a technique relating to an oxygen water generating apparatus capable of generating high-concentration oxygen water.
  • a hydrogen peroxide water mixing device that mixes hydrogen peroxide water into the water in the airtight container
  • a decomposing agent mixing device that mixes the decomposing agent into the water in the airtight container
  • hydrogen peroxide water and the decomposing agent are mixed
  • a pressurizing device for increasing the pressure in an airtight container for storing water and a distribution device for distributing oxygen water discharged from the airtight container by a drainage device, wherein hydrogen peroxide is converted into water and oxygen.
  • oxygen is generated in an airtight container by utilizing decomposition, and the generated oxygen is dissolved in water in the airtight container.
  • the present invention is directed to a liquid oxygen capsule in which liquid oxygen for making oxygen-containing water for beverages is sealed, in order to solve the above-mentioned problem.
  • An injection device is provided.
  • the liquid oxygen capsule according to the present invention is a liquid oxygen capsule in which oxygen to be injected into drinking water is liquefied and sealed, a cylindrical capsule body having an opening at the top, and liquid oxygen to be sealed.
  • a disk-shaped capsule lid inserted into the opening of the capsule body to seal liquid oxygen, and a meat having the same diameter as the capsule lid installed at a position where the capsule lid contacts the capsule body.
  • a thick disk-shaped O-ring wherein the capsule body has a thickened locking portion for inserting and locking the capsule lid, and the capsule provided on the locking portion. And a caulking portion for tightly fixing the lid portion.
  • the capsule lid portion is formed at the center of the upper surface of the disk in order to pierce and pierce a hole for ejecting the enclosed liquid oxygen.
  • Thin cut edge and bottom A cylindrical O-ring fixing cylinder for inserting and fixing an O-ring attached to the O-ring, and the capsule lid in which the O-ring is inserted and installed in the O-ring fixing cylinder, wherein the liquid oxygen is sealed. It is inserted from the opening of the capsule body and locked to the locking part, and the caulking part is pressed against the capsule lid part side and caulked to tightly fix the capsule lid part to seal and form liquid oxygen. is there.
  • the liquid oxygen capsule according to the present invention is a liquid oxygen capsule in which oxygen to be injected into drinking water is liquefied and sealed.
  • a disk-shaped capsule lid that is inserted into the portion to seal liquid oxygen, and a disk-shaped O-ring having the same diameter as the capsule lid installed at the top of the capsule lid.
  • the capsule body has a locking portion in which a position for inserting and locking the capsule lid portion is formed thick, and a caulking portion for tightly fixing the capsule lid portion provided above the locking portion,
  • the capsule lid has a thin, thin cutout formed in the center of the upper surface of the disk to pierce and pierce a hole for ejecting the enclosed liquid oxygen.
  • the capsule lid is made of liquid acid Is inserted through the opening of the capsule body in which the capsule is sealed, and is locked by the locking portion.
  • the caulking portion is pressed toward the capsule lid portion. Then, the capsule lid is tightly fixed via the O-ring, and liquid oxygen is sealed.
  • the capsule body and the capsule lid are made of aluminum, and the O-ring is made of a resin material.
  • the liquid oxygen injecting apparatus for forcibly injecting oxygen into drinking water sealed in a plastic bottle includes the liquid oxygen capsule and the liquid oxygen capsule housed and mounted therein.
  • Oxygen injection means having a structure screwed or fixed to the opening of the plastic bottle for evaporating the liquid oxygen filled in the liquid oxygen capsule and spouting and introducing the liquid oxygen into the plastic bottle, wherein the oxygen injection means is A base for screwing or adhering to the opening of the liquid oxygen capsule for sealing and fixing, and a storage lid for screwing the liquid oxygen capsule therein so as to be pressed against the base for sealing and fixing.
  • the base is provided with a thin tube that communicates the opening of the plastic bottle with the storage lid, and the thin tube has a sharp tip with a tip on the storage lid side.
  • the liquid oxygen capsule stored in the part is pierced by abutting and piercing the cutout portion of the liquid oxygen capsule, liquid oxygen is spouted into the plastic bottle, and the vaporized oxygen in the drinking water is forcibly injected. is there.
  • the liquid oxygen injecting device may be configured such that the base is screwed or fixed to the opening of the plastic bottle in which the drinking water is sealed and hermetically fixed, and the storage lid portion storing the liquid oxygen capsule is provided with a sharp-edged sword.
  • the thin tube is screwed to the base so as not to pierce the liquid oxygen capsule, and when the opening of the PET bottle is directed downward, the storage lid is further screwed so as to be further pushed into the base.
  • the tubule with a sharp tip pierces the liquid oxygen capsule and penetrates through the cutout to vaporize and eject the liquid oxygen in the liquid oxygen capsule into drinking water sealed in a plastic bottle. It is a configuration to be melted.
  • the present invention Since the present invention has the configuration as described in detail above, it has the following effects. 1. Since the thick O-ring is inserted between the capsule lid and the capsule body, it is possible to prevent the liquid oxygen sealed in the capsule from evaporating and leaking to the outside. In addition, since the caulking portion is provided in the capsule body, it is possible to reliably cover the container after the liquid oxygen is sealed, and it is possible to prevent leakage of the content of liquid oxygen. In addition, since the cutout portion is provided in the capsule lid portion, the liquid oxygen of the contents can be easily ejected and discharged to the outside when the capsule is used by piercing and inserting. 2.
  • the thick O-ring is inserted into the upper portion of the capsule lid and swaged, it is possible to effectively prevent leakage of the liquid oxygen sealed in the capsule to the outside. 3. Since the capsule body and the capsule lid are made of aluminum, it is possible to construct a lightweight and durable capsule. Further, since the O-ring is made of a resin material, it is possible to reliably prevent the leakage of the contents. 4. Since the liquid oxygen capsule is stored in the storage lid, it is possible to form a sealed state by tightening the storage lid, and it is possible to inject the oxygen in the liquid oxygen capsule into the PET bottle without waste. Become.
  • the storage lid is configured to be closed with the opening of the plastic bottle facing downward, the oxygen injected from the liquid oxygen capsule can be easily dissolved in the drinking water in the plastic bottle.
  • FIG. 1 is an exploded side sectional view of the liquid oxygen capsule
  • FIG. 2 is a side sectional view of the liquid oxygen injection device
  • FIG. 3 is a diagram illustrating an example of use of the liquid oxygen injection device.
  • the liquid oxygen capsule 100 according to the present invention includes a capsule body 110, a capsule lid 120, and an O-ring 130, and is liquefied at a low temperature, which is the content in the capsule body 110.
  • the capsule main body 110 is a main body of the liquid oxygen capsule 100 for enclosing the liquid oxygen 10 therein. As shown in FIG. 1, the capsule body 110 has a cylindrical shape having an opening 112 at the top. In the present embodiment, the capsule body 110 is formed of a cylindrical member having a uniform diameter, but is not limited to this, and may be appropriately selected and configured, such as a sphere or a prism.
  • the liquid oxygen 10 sealed in the capsule body 110 is liquefied oxygen.
  • Liquid oxygen has a boiling point of -183 [deg.] C, and when vaporized, its volume becomes about 800 times.
  • the liquid oxygen capsule 100 is completely sealed and sealed so as not to be vaporized.
  • the vaporized oxygen may be gradually discharged. is there.
  • the capsule lid part 120 is a disk-shaped member serving as a lid that seals the capsule main body 110. As shown in FIG. 1, the capsule lid part 120 is inserted into the opening 112 of the capsule main body 110 to remove the liquid oxygen 10 in the capsule main body 110. It is a member for sealing.
  • the capsule lid 120 is formed in a circular shape having the same diameter as the opening 112 having a circular cross section in order to reliably seal the opening 112 of the capsule body 110.
  • the O-ring 130 is a sealing material for improving the airtightness of the liquid oxygen capsule 100 to prevent the leakage of the liquid oxygen 10 in the capsule body 110.
  • the O-ring 130 is formed in a disk shape having the same diameter as the capsule lid 112 and has a position where the capsule lid 120 and the capsule main body 110 are in contact with each other, that is, between the capsule main body 110 and the capsule lid 120. It is a configuration installed in.
  • the capsule body 110 further includes a locking portion 114 and a caulking portion 116.
  • the locking portion 114 is formed as a stopper by forming the locking position to be thick in order to lock the capsule lid portion 120 at a fixed position after inserting the capsule lid portion 120 into the capsule main body 110. Thereby, the capsule lid 120 can be locked and fixed at a fixed position in the capsule main body 110.
  • the entire lower part of the locking portion 114 of the capsule body 110 is made thick.
  • the caulking part 116 is for tightly fixing the capsule lid part 120 to the capsule main body 110, and is provided above the locking part 114 as shown in FIG.
  • the caulking portion 116 is an upper portion of the capsule main body 110 and has a cylindrical shape.
  • the caulking portion 116 is caulked from the periphery toward the inside of the opening 112 so that the capsule lid portion 120 is tightly fixed. is there. With this configuration, the airtightness of the liquid oxygen capsule 100 can be easily ensured.
  • the capsule lid part 120 includes a cutout part 122 and an O-ring fixing cylinder 124.
  • the cutout portion 122 is provided for piercing a hole for ejecting the liquid oxygen 10 sealed in the liquid oxygen capsule 100 from the outside, and as shown in FIG.
  • the capsule lid 120 is made of a thin member formed at the center of the upper surface of the disk.
  • a cutout portion 122 is formed by a circular thin member at the center of the upper surface of the disk of the capsule lid portion 120.
  • the O-ring fixing cylinder 124 is a member for fixing the O-ring 130 installed between the capsule body 110 and the capsule lid 120, and is attached below the capsule lid 120 as shown in FIG. Is a cylindrical member into which the O-ring 130 is inserted and fixed.
  • the O-ring 130 has a disk shape, and has a circular hole at the center.
  • the O-ring 130 is fixed below the capsule lid 120 by inserting the O-ring fixing cylinder 124 into the hole.
  • the liquid oxygen capsule 100 first, the liquid oxygen 10 is injected into the capsule body 110 at an extremely low temperature.
  • the capsule lid 120 is inserted through the opening 112 of the capsule body 110 in which the liquid oxygen 10 is sealed.
  • the capsule lid part 120 is locked by the locking part 114 as described above.
  • the liquid oxygen capsule 100 in which the liquid oxygen 10 is sealed and formed by tightly fixing the capsule lid 120 is formed.
  • the capsule body 110 and the capsule lid 120 are made of an aluminum material.
  • the O-ring 130 is made of a resin material. With this configuration, it is possible to configure a lightweight and durable capsule, and it is possible to reliably prevent leakage of contents.
  • the O-ring 130 is made of silicon, but is not limited to this, and can be appropriately selected and used.
  • a configuration in which a disk-shaped O-ring 130 is installed on the top of a disk-shaped capsule lid that is inserted into the opening of the capsule body and seals liquid oxygen. It is possible.
  • the capsule lid 120 is inserted from the opening 112 of the capsule main body 110 in which the liquid oxygen 10 is sealed and locked by the locking portion 114, and a thin cutout portion 122 having a circular shape is formed above the capsule lid 120.
  • the O-ring 130 is installed so that the O is exposed.
  • the caulking part 116 is pressed toward the capsule lid part 120 and caulked.
  • the capsule lid 120 can be tightly fixed to the capsule body 110 via the O-ring.
  • the liquid oxygen injection device 300 for injecting oxygen by the liquid oxygen capsule 100 will be described.
  • the liquid oxygen injecting device 300 is a device for forcibly injecting and dissolving oxygen into the drinking water 30 sealed in the plastic bottle 20, and as shown in FIG. And oxygen injection means 200 for impingement.
  • the oxygen injecting means 200 is a means for injecting the liquid oxygen 10 sealed in the liquid oxygen capsule 100 into a PET bottle in a vaporized state.
  • the oxygen injecting means 200 has a structure in which the liquid oxygen capsule 100 is stored and mounted inside, and has a structure capable of being screwed or fixed to the opening 22 of the plastic bottle. This is a configuration in which the gas is ejected and vaporized by piercing and insertion, and the oxygen injection means 200 is introduced into the screwed or fixed PET bottle.
  • the oxygen injection means 200 includes a base 210 and a storage lid 220 as shown in FIG.
  • the base 210 is a member for connecting and fixing the oxygen injection means 200 to the plastic bottle 20, and is hermetically fixed by screwing or fixing to the opening 22 of the plastic bottle 20.
  • the base 210 has a plastic bottle connection opening 212, the portion is configured to have the same diameter as the opening 22 of the plastic bottle 20, and a thread that can be screwed is screwed.
  • the present invention is not limited to this, and a structure in which the base 210 is fixed to the opening 22 of the plastic bottle 20 is also possible.
  • the storage lid 220 is a member for storing the liquid oxygen capsule 100 therein and joining and sealing it with the base 210.
  • the storage lid 220 is provided with a base connection opening 222 in which a screw thread is threaded, and a screwable screw thread provided in the base 210 on the opposite side of the plastic bottle connection opening 212 is provided.
  • the base connection opening 222 is screwed into the engraved storage lid connection opening 214 such that the base connection opening 222 is press-fitted and hermetically sealed.
  • the storage lid 220 and the base 210 can be configured to be detachably connected.
  • the liquid oxygen capsule 100 can be replaced, and the liquid oxygen injection device 300 can be used continuously many times.
  • the base 210 has a configuration provided with a thin tube 230 for communicating the opening 22 of the plastic bottle 20 with the storage lid 220.
  • the oxygen injection means 200 in a state where the base 210 and the storage lid 220 are screwed and fixed by the thin tube 230 is screwed and fixed to the opening 22 of the plastic bottle 20, the internal space of the plastic bottle 20 and the storage lid are fixed.
  • the internal space of the section 220 is in communication with which the contents (vaporized liquid oxygen) can be moved. As shown in FIG.
  • the tip of the thin tube 230 on the side of the storage lid 220 has a sharp-tipped shape.
  • the cutting opening 122 of the liquid oxygen capsule 100 stored in the storage lid 220 is When the tip on the side of the storage lid 220 contacts, the cutout 122 is pierced (broken), and a fine hole is inserted and bored.
  • the vaporized liquid oxygen 10 spouted from the pores of the cutout portion 122 can be spouted and introduced into the plastic bottle 20 through the thin tube 230 without leaking to the outside. By vigorously forcing the injection, oxygen water can be easily generated.
  • the storage lid 220 may have a configuration in which a ventilation hole (not shown) is formed in an upper portion or a side surface. With this configuration, a small amount of oxygen can be released from the ventilation pores. Therefore, when oxygen is introduced into the drinking water 30 in the PET bottle 20, when oxygen is excessively supplied or the like, It is possible to prevent possible rupture of the PET bottle 20.
  • a method of using the liquid oxygen injection device 300 will be described. In the liquid oxygen injection device 300, the base 210 and the storage lid 220 are first removed, and the base 210 is screwed into the opening 22 of the plastic bottle 20 in which the drinking water 30 is sealed, and hermetically fixed.
  • the storage lid 220 is moved to the base 210 to such an extent that the thin tube 230 of the sharpened tip blade provided in the base 210 does not pierce the liquid oxygen capsule 100. Screw together.
  • a structure in which the storage lid 220 storing the liquid oxygen capsule 100 and the base 210 are connected (a state in which the liquid oxygen capsule 100 has not yet been punctured) is screwed or fixed to the PET bottle 20 in advance. May be configured and distributed as drinking water.
  • the PET bottle 20 is turned over so that the opening 22 is directed downward, and the storage lid 220 is further screwed into the base 210 so as to be pushed in, and hermetically sealed.
  • the thin tube 230 having a sharp tip pierces the liquid oxygen capsule 100 and penetrates the liquid oxygen capsule 100, and the thin tube 230 penetrates through the cutout portion 122 to make a hole in the cutout portion 122.
  • the liquid oxygen 10 in the liquid oxygen capsule 100 is jetted and vaporized, and is jetted vigorously into the plastic bottle 20 through the thin tube 230. Since the PET bottle 20 is turned upside down with the opening 22, the drinking water 30 inside moves to the opening 22 side. Therefore, the vaporized oxygen from below the drinking water 30 forms bubbles upward and vigorously passes therethrough. At this time, oxygen is dissolved in the drinking water 30.
  • the liquid oxygen 10 in the liquid oxygen capsule 100 can be vaporized and jetted and melted into the drinking water 30 sealed in the plastic bottle 20, and the liquid oxygen 10 is jetted from the liquid oxygen capsule 100. Oxygen can be dissolved into the drinking water 30 in the plastic bottle 20 without leaking.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Packages (AREA)
  • Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)

Abstract

La présente invention concerne : une capsule d'oxygène liquide qui est constituée d'une structure étanche stable à partir de laquelle une fuite d'oxygène liquide ne se produit pas une fois l'oxygène liquide scellé à l'intérieur de celle-ci et qui permet d'évacuer de l'oxygène par perçage ; et un dispositif d'injection de capsule d'oxygène liquide utilisant celle-ci. La capsule d'oxygène liquide est composée : d'un corps de capsule cylindrique ayant une ouverture dans sa section supérieure ; d'oxygène liquide ; d'un couvercle de capsule pour sceller l'oxygène liquide ; et d'un joint torique ayant une forme de disque épais ayant le même diamètre que le couvercle de capsule. Le corps de capsule est composé d'une partie de verrouillage pour insérer et verrouiller le couvercle de capsule, et d'une partie de sertissage pour coller et fixer le couvercle de capsule. Le couvercle de capsule est composé d'une ouverture découpée formée au centre d'une surface supérieure de disque, et d'un cylindre de fixation de joint torique cylindrique ajusté de manière descendante. Le couvercle de capsule, avec le joint torique inséré et placé dans le cylindre de fixation de joint torique, est inséré à partir de l'ouverture dans le corps de capsule dans lequel de l'oxygène liquide est scellé, puis est verrouillé à la partie de verrouillage, et la partie de sertissage est pressée contre le couvercle de capsule et sertit ce dernier, ce qui permet de coller et de fixer le couvercle de capsule.
PCT/JP2019/035289 2018-08-31 2019-09-02 Capsule d'oxygène liquide et dispositif d'injection d'oxygène liquide utilisant celle-ci WO2020045687A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2018-163808 2018-08-31
JP2018163808A JP7181735B2 (ja) 2018-08-31 2018-08-31 液体酸素カプセルおよびこれを用いた液体酸素注入装置

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WO2020045687A1 true WO2020045687A1 (fr) 2020-03-05

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10505313A (ja) * 1994-08-24 1998-05-26 ポリスター・パッケージング・インコーポレイテッド 内方に折り曲げた巻締めを備える容器及びクロージュア
JP2008161904A (ja) * 2006-12-27 2008-07-17 Toyota Motor Corp 管状部材、ならびにその製造方法及び製造装置
KR20130070083A (ko) * 2011-12-19 2013-06-27 곽상용 용기용 산소주입장치
KR101713246B1 (ko) * 2016-07-15 2017-03-09 노예우 산소 혼합 음료용기

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10505313A (ja) * 1994-08-24 1998-05-26 ポリスター・パッケージング・インコーポレイテッド 内方に折り曲げた巻締めを備える容器及びクロージュア
JP2008161904A (ja) * 2006-12-27 2008-07-17 Toyota Motor Corp 管状部材、ならびにその製造方法及び製造装置
KR20130070083A (ko) * 2011-12-19 2013-06-27 곽상용 용기용 산소주입장치
KR101713246B1 (ko) * 2016-07-15 2017-03-09 노예우 산소 혼합 음료용기

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JP2020033096A (ja) 2020-03-05

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