WO2020015009A1 - 一种不易掉色的活性染料配方 - Google Patents

一种不易掉色的活性染料配方 Download PDF

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WO2020015009A1
WO2020015009A1 PCT/CN2018/097958 CN2018097958W WO2020015009A1 WO 2020015009 A1 WO2020015009 A1 WO 2020015009A1 CN 2018097958 W CN2018097958 W CN 2018097958W WO 2020015009 A1 WO2020015009 A1 WO 2020015009A1
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parts
dye
reactive
easy
agent
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PCT/CN2018/097958
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English (en)
French (fr)
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陈永兵
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启东市新利来制衣有限公司
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5228—Polyalkenyl alcohols, e.g. PVA
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621—Compounds without nitrogen
    • D06P1/627—Sulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65125—Compounds containing ester groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic

Definitions

  • the invention relates to a dye, in particular to a reactive dye formulation which is not easy to fade.
  • Textile dye is a kind of dye used for textile dyeing.
  • the existing anti-dye is usually prepared by artificial proportioning according to different needs.
  • the existing dyeing of fabrics with reactive dyes has poor colorability and color.
  • the durability of the fabric is not high, and it is easy to fade and fade after washing, which results in that the products made of the fabric are discarded due to poor aesthetics, which increases the cost of the user.
  • a non-fading reactive dye formula is composed of the following components: 20-40 parts of tetrafluoromonochloropyrimidine type dye; 50-70 parts of vinyl sulfone type dye; ⁇ -bromoacrylamide type reactive dye 35 -60 parts; leveling agent 10-15 parts; fatty alcohol sodium sulfate 4-8 parts; polyvinyl alcohol 8-13 parts; sodium propionate 6-12 parts; methyl acrylate 8-16 parts; acrylic resin 4-8 5-9 parts of glacial acetic acid; 7-15 parts of inorganic antibacterial agent: 1-4 parts of bright ion antistatic agent; 70-100 parts of deionized water.
  • the inorganic antibacterial agent is one of zinc oxide, copper oxide, ammonium dihydrogen phosphate, and lithium carbonate.
  • the anionic antistatic agent is an alkali metal salt of an alkylsulfonic acid, phosphoric acid or dithiocarbamic acid.
  • the dye formulation is composed of the following components: 40 parts of tetrafluoromonochloropyrimidine type dyes; 60 parts of vinyl sulfone type dyes; 50 parts of ⁇ -bromoacrylamide type reactive dyes; 13 parts of leveling agents; fatty alcohols 6 parts of sodium sulfate; 7 parts of polyvinyl alcohol; 8 parts of sodium propionate; 15 parts of methyl acrylate; 5 parts of acrylic resin; 5 parts of glacial acetic acid; 8 parts of inorganic antibacterial agent: 4 parts of bright ion antistatic agent; deionized water 100 servings.
  • the dye formulation is composed of the following components: 30 parts of tetrafluoromonochloropyrimidine type dyes; 60 parts of vinyl sulfone type dyes; 40 parts of ⁇ -bromoacrylamide type reactive dyes; 12 parts of leveling agents; fatty alcohols 6 parts of sodium sulfate; 10 parts of polyvinyl alcohol; 8 parts of sodium propionate; 10 parts of methyl acrylate; 6 parts of acrylic resin; 7 parts of glacial acetic acid; 11 parts of inorganic antibacterial agent: 3 parts of bright ion antistatic agent; deionized water 90 servings.
  • the present invention discloses a reactive dye formula that is not easy to fade, has high fastness and wet fastness, bright color, excellent performance, and strong applicability. Its hue and performance can adapt to the market and expand the range of fabrics. ;
  • the preparation method is simple, convenient to operate, low in cost, and easy to popularize.
  • Example 1 A reactive dye formulation that is not easy to fade, the dye formulation is composed of the following components: 40 parts of tetrafluoromonochloropyrimidine type dye; 60 parts of vinyl sulfone type dye; 50 parts of ⁇ -bromoacrylamide type reactive dye 13 parts of leveling agent; 6 parts of fatty alcohol sodium sulfate; 7 parts of polyvinyl alcohol; 8 parts of sodium propionate; 15 parts of methyl acrylate; 5 parts of acrylic resin; 5 parts of glacial acetic acid; 8 parts of inorganic antibacterial agent: bright ion 4 parts antistatic agent; 100 parts deionized water.
  • the inorganic antibacterial agent is one of zinc oxide, copper oxide, ammonium dihydrogen phosphate, and lithium carbonate.
  • the anionic antistatic agent is an alkali metal salt of an alkylsulfonic acid, phosphoric acid or dithiocarbamic acid.
  • Example 2 A reactive dye formulation that is not easy to fade, the dye formulation is composed of the following components: 30 parts of tetrafluoromonochloropyrimidine type dye; 60 parts of vinyl sulfone type dye; 40 parts of ⁇ -bromoacrylamide type reactive dye 12 parts of leveling agent; 6 parts of fatty alcohol sodium sulfate; 10 parts of polyvinyl alcohol; 8 parts of sodium propionate; 10 parts of methyl acrylate; 6 parts of acrylic resin; 7 parts of glacial acetic acid; 11 parts of inorganic antibacterial agent: bright ion 3 parts antistatic agent; 90 parts deionized water.
  • the inorganic antibacterial agent is one of zinc oxide, copper oxide, ammonium dihydrogen phosphate, and lithium carbonate.
  • the anionic antistatic agent is an alkali metal salt of an alkylsulfonic acid, phosphoric acid or dithiocarbamic acid.
  • the invention discloses a reactive dye formula that is not easy to fade, has high fastness, wet fastness, bright color, excellent performance, and strong applicability. Its hue and performance can adapt to the market and expand the use range of fabrics.
  • the preparation method is simple , Easy to operate, low cost, easy to promote.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Coloring (AREA)

Abstract

本发明涉及一种不易掉色的活性染料配方，所述染料配方由以下组分组成：四氟一氯嘧啶型染料20-40份；乙烯砜型染料50-70份；γ-溴代丙烯酰胺型活性染料35-60份；均染剂10-15份；脂肪醇硫酸钠4-8份；聚乙烯醇8-13份；丙酸钠6-12份；丙烯酸甲酯8-16份；丙烯酸树脂4-8份；冰醋酸5-9份；无机抗菌剂7-15份：明离子抗静电剂1-4份；去离子水70-100份。本发明的优点在于：坚牢度、湿牢度较高，色泽鲜艳、性能优异，适用性强，其色相和性能均能适应市场，扩大面料的使用范围；制备方法简单、操作方便、成本较低、易于推广。

Description

一种不易掉色的活性染料配方 技术领域
本发明涉及一种染料，尤其是一种不易掉色的活性染料配方。
背景技术
纺织染料是用于纺织品染色的一种染剂，现有的防止染料通常是根据不同需求通过人工配比的方式配制而成的，而现有的采用活性染料进行面料染色，其着色性差，色的牢固性不高，经过水洗容易褪色、掉色，导致该面料制成的产品因美观性差被丢弃，增加使用者的成本。
发明内容
一种不易掉色的活性染料配方,所述染料配方由以下组分组成：四氟一氯嘧啶型染料20-40份；乙烯砜型染料50-70份；γ-溴代丙烯酰胺型活性染料35-60份；均染剂10-15份；脂肪醇硫酸钠4-8份；聚乙烯醇8-13份；丙酸钠6-12份；丙烯酸甲酯8-16份；丙烯酸树脂4-8份；冰醋酸5-9份；无机抗菌剂7-15份：明离子抗静电剂1-4份；去离子水70-100份。
优选的，所述的无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵、碳酸锂中的一种。
优选的，所述的阴离子抗静电剂为烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐。
优选的，所述染料配方由以下组分组成：四氟一氯嘧啶型染料40份；乙烯砜型染料60份；γ-溴代丙烯酰胺型活性染料50份；均染剂13份；脂肪醇硫酸钠6份；聚乙烯醇7份；丙酸钠8份；丙烯酸甲酯15份；丙烯酸树脂5份；冰醋酸5份；无机抗菌剂8份：明离子抗静电剂4份；去离子水100份。
优选的，所述染料配方由以下组分组成：四氟一氯嘧啶型染料30份；乙烯砜型染料60份；γ-溴代丙烯酰胺型活性染料40份；均染剂12份；脂肪醇硫酸钠6份；聚乙烯醇10份；丙酸钠8份；丙烯酸甲酯10份；丙烯酸树脂6份；冰醋酸7份；无机抗菌剂11份：明离子抗静电剂3份；去离子水90份。
有益效果：本发明揭示了一种不易掉色的活性染料配方,坚牢度、湿牢度较高，色泽鲜艳、性能优异，适用性强，其色相和性能均能适应市场，扩大面料的使用范围；制备方法简单、操作方便、成本较低、易于推广。
具体实施方式
实例1：一种不易掉色的活性染料配方,所述染料配方由以下组分组成：四氟一氯嘧啶型染料40份；乙烯砜型染料60份；γ-溴代丙烯酰胺型活性染料50份；均染剂13份；脂肪醇硫酸钠6份；聚乙烯醇7份；丙酸钠8份；丙烯酸甲酯15份；丙烯酸树脂5份；冰醋酸5份；无机抗菌剂8份：明离子抗静电剂4份；去离子水100份。
本实例中，所述的无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵、碳酸锂中的一种。
本实例中，所述的阴离子抗静电剂为烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐。
实例2：一种不易掉色的活性染料配方,所述染料配方由以下组分组成：四氟一氯嘧啶型染料30份；乙烯砜型染料60份；γ-溴代丙烯酰胺型活性染料40份；均染剂12份；脂肪醇硫酸钠6份；聚乙烯醇10份；丙酸钠8份；丙烯酸甲酯10份；丙烯酸树脂6份；冰醋酸7份；无机抗菌剂11份：明离子抗静电剂3份；去离子水90份。
本实例中，所述的无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵、碳酸锂中的一种。
本实例中，所述的阴离子抗静电剂为烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐。
本发明揭示了一种不易掉色的活性染料配方坚牢度、湿牢度较高，色泽鲜艳、性能优异，适用性强，其色相和性能均能适应市场，扩大面料的使用范围；制备方法简单、操作方便、成本较低、易于推广。
以上所述仅是本发明的优选方式，应当指出，对于本领域普通技术人员来说，在不新型面料配方脱离本发明创造构思的前提下，还可以做出若干相似的变形和改进，这些也应视为本发明新型面料配方的保护范围之内。

Claims (5)

  1. 一种不易掉色的活性染料配方,其特征在于，所述染料配方由以下组分组成：四氟一氯嘧啶型染料20-40份；乙烯砜型染料50-70份；γ-溴代丙烯酰胺型活性染料35-60份；均染剂10-15份；脂肪醇硫酸钠4-8份；聚乙烯醇8-13份；丙酸钠6-12份；丙烯酸甲酯8-16份；丙烯酸树脂4-8份；冰醋酸5-9份；无机抗菌剂7-15份：明离子抗静电剂1-4份；去离子水70-100份。
  2. 根据权利要求1所述一种不易掉色的活性染料配方，其特征在于：所述的无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵、碳酸锂中的一种。
  3. 根据权利要求1所述的一种不易掉色的活性染料配方，其特征在于:所述的阴离子抗静电剂为烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐。
  4. 根据权利要求1所述的一种不易掉色的活性染料配方，其特征在于:一种不易掉色的活性染料配方,所述染料配方由以下组分组成：四氟一氯嘧啶型染料40份；乙烯砜型染料60份；γ-溴代丙烯酰胺型活性染料50份；均染剂13份；脂肪醇硫酸钠6份；聚乙烯醇7份；丙酸钠8份；丙烯酸甲酯15份；丙烯酸树脂5份；冰醋酸5份；无机抗菌剂8份：明离子抗静电剂4份；去离子水100份。
  5. 根据权利要求1所述的一种不易掉色的活性染料配方，其特征在于:所述染料配方由以下组分组成：四氟一氯嘧啶型染料30份；乙烯砜型染料60份；γ-溴代丙烯酰胺型活性染料40份；均染剂12份；脂肪醇硫酸钠6份；聚乙烯醇10份；丙酸钠8份；丙烯酸甲酯10份；丙烯酸树脂6份；冰醋酸7份；无机抗菌剂11份：明离子抗静电剂3份；去离子水90份。
PCT/CN2018/097958 2018-07-20 2018-08-01 一种不易掉色的活性染料配方 WO2020015009A1 (zh)

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CN108193515A (zh) * 2018-01-30 2018-06-22 江苏华艺服饰有限公司 一种吊染染料配方
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