WO2019034837A1 - Procédé de formation d'un alliage d'aluminium coulé - Google Patents

Procédé de formation d'un alliage d'aluminium coulé Download PDF

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WO2019034837A1
WO2019034837A1 PCT/GB2018/052186 GB2018052186W WO2019034837A1 WO 2019034837 A1 WO2019034837 A1 WO 2019034837A1 GB 2018052186 W GB2018052186 W GB 2018052186W WO 2019034837 A1 WO2019034837 A1 WO 2019034837A1
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alloy
melt
castings
alloys
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PCT/GB2018/052186
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English (en)
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Ji SHOUXUN
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Brunel University London
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Priority to EP18765965.1A priority Critical patent/EP3669011A1/fr
Priority to US16/638,838 priority patent/US20200190634A1/en
Priority to CN201880052663.4A priority patent/CN111032897A/zh
Publication of WO2019034837A1 publication Critical patent/WO2019034837A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/02—Alloys based on aluminium with silicon as the next major constituent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
    • B22D21/002—Castings of light metals
    • B22D21/007—Castings of light metals with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/026—Alloys based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/02—Alloys based on aluminium with silicon as the next major constituent
    • C22C21/04—Modified aluminium-silicon alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C3/00—Removing material from alloys to produce alloys of different constitution separation of the constituents of alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent

Definitions

  • the present invention generally relates to a method of forming a cast aluminium alloy, and in particular aluminum castings for enhanced mechanical properties in structural applications.
  • the castings When utilized to make shape aluminium alloy castings with gravity casting process, the castings have achieved a 0.2 % offset yield strength of greater than 310 MPa, an ultimate tensile strength of greater than 365 MPa, and an elongation of greater than 10 %. More specifically, the excellent strength and ductility properties are superimposed with the casting characteristics inherent for aluminum cast alloy compositions without containing Cu elements.
  • Aluminum alloys have been successfully used in a wide range of structural applications because of their relatively low density, high strength and elastic modulus, fatigue resistance and ease of fabrication. This is particularly important for the transportation industry because structural weight savings are becoming more critical as fuel consumption and air pollution concerns come to the forefront of technological issues. For example, automotive
  • the multitude of aluminum alloys can be divided into the categories of wrought and cast aluminum alloys. Wrought aluminum alloys are generally processed by the plastic
  • Cast aluminum alloys differ greatly from wrought aluminum alloys as cast aluminium alloys are ultimately used in the geometry of the original mould Therefore; many of the beneficial processing steps used to produce wrought aluminum are not practical for use in castings.
  • the alloy design goals, microstructure, processing steps and strengthening mechanisms are the major aspects for making castings with enhanced mechanical properties.
  • Al-Si systems are one of the most popular materials in casting manufacturing because of their excellent casting performance, high specific strength and toughness, and good fatigue resistance and corrosion resistance, etc.
  • a commonly used high performance aluminum casting alloy is Aluminum Association alloy 356/357 with a nominal composition of 7.0 wt.% Si and 0.3 to 0.45 wt.% Mg and minor amounts of Ti, Mn, Fe, Be, and Cu. Mechanical properties in the highest strength temper are among the highest in the aluminum cast alloy systems.
  • the existing alloys are generally capable of satisfying in many critical load-bearing structures, with the development of automotive, aviation, aerospace and military industry, the tensile strength and elongation of Al-Si alloys of a higher requirement, conventional grades of Al-Si alloys have been unable to meet the needs of a number of automotive and aerospace products. Therefore, development of high strength castings based on new Al-Si alloy is an urgent need. There are numerous efforts to develop new materials and technologies.
  • WO2010003349 discloses a high strength casting aluminium alloy material comprises (in weight %) Cu 2.0-6.0 %, Mn 0.05-1.0 %, Ti 0.01-0.5 %, Cr 0.01-0.2 %, Cd 0.01-0.4 %, Zr 0.01-0.25 %, B 0.005-0.04 %, rare earth 0.05-0.3 %, and balance aluminium and trace impurities.
  • the alloy has reduced cost.
  • EP1347066 discloses a high-strength aluminum alloy for casting comprising 3.5 to 4.3 % of Cu, 5.0 to 7.5 % of Si, 0.10 to 0.25 % of Mg, not more than 0.2 % of Fe, 0.0004 to 0.0030 % of P, 0.005 to 0.0030 % of Sr, and the balance comprising Al and unavoidable impurities.
  • a high-strength cast aluminum alloy is also disclosed obtained by: casting a high-strength aluminum alloy for casting comprising 3.5 to 4.3 % of Cu, 5.0 to 7.5 % of Si, 0.10 to 0.25 % of Mg, not more than 0.2 % of Fe, 0.0004 to 0.0030 % of P, 0.005 to 0.030 % of Sr, 0.05 to 0.35 % of Ti, and the balance comprising Al and unavoidable impurities; and subjecting the alloy thus cast to a T6 treatment.
  • WO2015121635 (Brunei University) discloses a high strength cast aluminium alloy for high pressure die casting comprising magnesium silicide 6 to 12 wt.%, magnesium 4 to 10 wt.%, X element from copper (Cu), zinc (Zn), silver (Ag), gold (Au) and Lithium (Li) at 3 to 10 wt.%), manganese 0.1 to 1.2 wt.%>, iron max.
  • EP2865772 discloses an aluminium casting alloy comprising 7-9 % by weight of silicon, 0.6- 1 % by weight of iron, 0.7-1.5 % by weight of copper, 0.05-0.5 % by weight of manganese, 0.1-3 % by weight of zinc, 0.05-0.5 % by weight of magnesium, 0.01-0.15 % by weight of titanium, 0.01-0.1 % by weight of chrome, 0.01-0.1 % by weight of nickel, 0.01-0.1 % by weight of lead and 0.01-0.1 % by weight of tin.
  • WO2004104240 discloses a high-strength, thermally-resistant, ductile, cast aluminium alloy (AlSi7Mg0.25Zr, or AlSi7Mg0.25Hf) and (Al Si6Mg0.25Zr or Al Si6Mg0.25Hf), comprising Si: 6.5 to 7.5 wt.% and 5.5 to 6.5 wt.%, Mg: 0.20 to 0.32 wt.%, Zr: 0.03 to 0.50 wt.% and/or Hf: 0.03 to 1.50 wt.%, Ti: 0 to 0.20 wt.%, Fe: ⁇ 0.20 wt.%, Mn: ⁇ 0.50 wt.%, Cu: ⁇ 0.05 wt.%), Zn: ⁇ 0.07 wt.% and made up to 100 wt.% with Al.
  • the invention relates to the use thereof for workpieces or parts thereof with elevated thermal loading, such as a cylinder head.
  • Al-Si-Mg alloys Despite the property of casting Al-Si-Mg alloys is among the highest and the relatively high amount of Si affords excellent casting characteristics that are paramount to produce complex shapes.
  • the available Al-Si alloys generally offer the ultimate tensile strength (UTS) at a level of 330 MPa, the yield strength at a level of 250 MPa, and the elongation at a level of 5 %.
  • UTS ultimate tensile strength
  • the addition of Cu is not desirable because of the detrimental of corrosion resistance. Therefore, it would be highly desirable to develop castings with yield strength more than 300 MPa and UTS more than 350 MPa with an elongation more than 9 %.
  • the end users for such an alloy are quite extensive and varied, and include electrical rotors, structural members, engine bodies, cylinder heads, gear boxes, air conditioners, business machines, industrial equipment, aerospace housings, gears pumps, bearing houses, engine blocks, nodes for connecting tubular structures, wheels, aircraft fittings, flywheel castings, machine tool parts, gear blocks, general automotive castings, marine structures, pressure tight applications, recreational equipment, connecting rods and numerous other applications.
  • the new Al-Si alloys may stimulate the use of castings in new, innovative design scenarios that were not previously achievable with conventional casting alloys.
  • a method of forming a cast aluminium alloy including the steps of: (i) providing an aluminium alloy including
  • a composition of a casting alloy may be provided with a primary alloying addition of 8.5 to 12.5 wt.% Si, 0.46 to 1.0 wt.% Mg, 0.1 to 0.2 wt.% Ti, 0.05 to 0.25 wt.% Mn, and less than 0.05 wt.%) Sn.
  • the alloy could further include grain refining additions of Ti, TiB 2 , A1B 2 , B, Be, Zr, Y, V, Nb, singly or in combination with one another in the range of 0.001 to 1.0 wt.%), chemical modifiers such as Na and Sr, singly or in combination with one another in the range of 0.001 to about 0.10 wt.%> and phase refiners such as P in the range of 0.01 to about 0.30 wt.%), and the balance of Al and incidental impurities.
  • An optimised process for melt treatment may include appropriate melting, degassing, and grain refining.
  • Al-10 wt.%> Sr master alloy is added into the melt to the preferred content of no less than 120 ppm and no higher than 200 ppm for the modification and refinement of the eutectic silicon phase.
  • the molten metal is degassed using nitrogen, argon or chlorine or their mixtures injected into the melt by means of a rotary degassing impeller at a speed of at least 150 rpm for at least 10 min.
  • the degassing process includes the introduction of at least one of nitrogen, argon or chlorine or their mixtures into the alloy melt to remove the dissolved hydrogen in the melt to a level of less than 2 mL/100 g. It is preferred that the dissolved hydrogen in the melt can be reduced to a level of less than 0.7 mL/100 g, even preferably to a level of less than 0.2 mL/100 g. Then TiB-containing master alloy is added into the melt as grain refiner.
  • the refining process consists essentially of adding up to 0.3 wt.%> grain refiners into the aluminium alloy melt, which includes the TiB-containing master alloy for refining primary aluminium phase, which is at least one of ⁇ 1-5 ⁇ 1 ⁇ , ⁇ 1-3 ⁇ 1 ⁇ , Al- 1 ⁇ 3 ⁇ , or ⁇ 1-3 ⁇ 3 ⁇ alloys.
  • the alternation method is adding 25% Na 2 SiF 6 + 75% C 2 C1 6 refining agents and with the rotary degassing unit with the use of the best refining effect in an amount of 0.5-0.8 wt.%.
  • the amount of grain refiner can be preferably at a level of up to 0.2 wt.%. After degassing, the top surface of the melt is covered by commercial granular flux, then the melt is held for 10-15 min, thereafter the melt is ready for casting, and the preferred casting temperature is at 700-720 °C.
  • An embodiment may include an optimised process for heat treatment of castings made by the developed aluminium alloys.
  • the heat treatment in accordance with the practice that involves the steps of solution heat treatment at temperatures approaching the solidus temperature of a given alloy; quenching into water or other appropriate media, and ageing at temperatures ranging from ambient to about 300°C.
  • a multiple stages solution process and multiple stages ageing process can be utilized.
  • the solution is conducted at a temperature between 520 °C to 545 °C, preferably between 530 °C to 540 °C, and more preferably between 535 °C to 540 °C.
  • the solution time at the more preferably solution temperature 540 °C is between 2 h to 12 h, preferably between 8 h to 10 h, as indicated in Fig.
  • the ageing is conducted at a temperature between 170 °C to 200 °C, preferably between 170 °C to 190 °C, and more preferably at 170 °C or 190 °C.
  • the ageing time at the more preferably ageing temperature is between 2 h to 8 h, preferably ageing at 170 °C for 7-8 h or ageing at 190 °C for 3-4 h, as indicated in Fig. 2.
  • the optimised heat treatment process for the alloy is solution at 540 °C for 8-10 h, then quenching into water or other appropriate media, after ageing at 170 °C for 7-8 h or ageing at 190 °C for 3-4 h, as indicated in Fig. 3.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably provide enhanced mechanical properties for structural applications comprising (1) alloy optimisation with 8.5 to 12.5 wt.% Si, 0.46 to 1.0 wt.% Mg, 0.1 to 0.2 wt.% Ti, 0.05 to 0.25 wt.% Mn, 0.01 to 0.02 wt.%) Sr, 0.004 to 0.1 wt.%> B and other impurity elements of Cu, Fe, Zn each less than 0.15 wt.%) and the balance of Al and incidental impurities; (2) optimised melt treatment with appropriate melting, degassing and grain refining; (3) appropriate type of grain refiner with optimised amount and method to add into the aluminium melt, and (4) optimised heat treatment process.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably comprises: 8.5 to 10.0 wt.% Si, 0.46 to 0.65 wt.% Mg, 0.1 to 0.15 wt.% Ti, less than 0.15 wt.% Mn, 0.012 to 0.018 wt.%) Sr, 0.004 to 0.04 wt.% B and other impurity elements of Cu, Fe, Zn each less than 0.15 wt.%) and the balance of Al and incidental impurities.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably comprises less than 0.05 wt.% Cu.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably comprises less than 0.12 wt.% Fe.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of an appropriate process for making melt through degassing and grain refining.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of degassing, in which the gas including at least one of nitrogen, argon or chlorine or their mixtures is introduced into the alloy melt to remove the dissolved hydrogen in the melt to a level of less than 2 mL/100 g melt.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of degassing, in which the gas including at least one of nitrogen, argon or chlorine or their mixtures is introduced into the alloy melt to remove the dissolved hydrogen in the melt to a preferred level of less than 0.7 mL/100 g melt.
  • the Al- alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of degassing, in which the gas including at least one of nitrogen, argon or chlorine or their mixtures is introduced into the alloy melt to remove the dissolved hydrogen in the melt to a more preferred level of less than 0.2 mL/100 g melt.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of cleaning the aluminium melt through pumping solid flux into aluminum melt, which can be associated with degassing process.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of cleaning the aluminium melt through pumping chemical gas flux into aluminum melt, which can be associated with degassing process.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of cleaning the aluminium melt through adding 25% Na 2 SiF 6 + 75% C 2 Cl 6 refining agents in an amount of 0.5-0.8 wt.% and with the rotary degassing unit.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of adding up to 0.3 wt.% grain refiners into the aluminium alloy melt, which includes Sr- containing master alloys for modification and refining eutectic silicon phase, and TiB- containing master alloys for refining primary aluminium phase.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of adding up to 0.2 wt.% grain refiners into the aluminium alloy melt, which includes Sr- containing master alloys for modification and refining eutectic silicon phase, and the TiB- containing master alloy for refining primary aluminium phase.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of refining primary aluminium phase by adding TiB-containing master alloys, which is at least one of ⁇ 1-5 ⁇ 1 ⁇ , ⁇ 1-3 ⁇ 1 ⁇ , ⁇ 1-1 ⁇ 3 ⁇ , or ⁇ 1-3 ⁇ 3 ⁇ alloys.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of refining primary aluminium phase by adding TiB-containing master alloys, which are preferred to be ⁇ 13 ⁇ 3 ⁇ , ⁇ 11 ⁇ 3 ⁇ , or other B-rich AlTiB master alloys.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one heat treatment from solution, annealing and ageing.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one solution at a temperature between 520 °C to 545 °C.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one solution at a temperature preferably between 530 °C to 540 °C.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one solution at a temperature more preferably between 535 °C to 540 °C.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one solution for a time between 2 h to 12 h.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one solution for a time preferably between 8 h to 10 h.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one ageing at a temperature between 170 °C to 200 °C.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one ageing at a temperature preferably between 170 °C to 190 °C.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one ageing at the temperature more preferably 170 °C or 190 °C.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one ageing for a time between 2 h to 8 h.
  • the alloy and manufacturing method of Al-Si-Mg castings preferably consists essentially of at least one ageing preferably at 170°C for 7 h to 8 h or 190°C for 3 h to 4h.
  • the alloy and manufacturing method of Al-Si-Mg castings to provide enhanced mechanical properties for structural applications preferably comprises (1) alloy optimisation with 8.5 to 10.0 wt.% Si, 0.46 to 0.65 wt.% Mg, 0.1 to 0.15 wt.% Ti, less than 0.15 wt.% Mn, 0.012 to 0.018 wt.% Sr, 0.004 to 0.04 wt.% B and other impurity elements of Cu, Fe, Zn each less than 0.15 wt.% and the balance of Al and incidental impurities; (2) optimised melt treatment with appropriate melting, modification, degassing and grain refining; (3) appropriate type of grain refiner with optimised amount and method to add into the aluminium melt, and (4) optimised heat treatment process.
  • Fig. 1 is a graph showing micro hardness of the alloy versus solution time at a solution temperature of 540 °C
  • Fig. 2 is a graph showing micro hardness of the alloy versus ageing time at an ageing temperature of 170 °C after solution at 540 °C for 8 hours;
  • Fig. 3 is a graph showing yield strength of the alloy versus ageing time at an ageing temperature of 170 °C after solution at 540 °C for 6-14 hours.
  • an alloy system in accordance with the principles of the present invention is a modification of the Aluminum Association's alloy system 3XX.
  • This modified alloy system generally comprises of Si in the range of 8.5 to 12.5 wt.% and Mg in the range of 0.3 to 0.7 wt.%), with one or more of Ti less than 0.2 wt.%, Mn less than 0.1 wt.%, Zn less than 0.1 wt.%, Sn less than 0.05 wt.%.
  • the alloy could further include grain refining additions of Ti, TiB2, A1B2, B, Be, Zr, Y, V, Nb, singly or in combination with one another in the range of 0.001 to 1.0 wt.%, chemical modifiers such as Na and Sr, singly or in combination with one another in the range of 0.001 to about 0.20 wt.% and phase refiners such as P in the range of 0.01 to about 0.30 wt.%, and the balance of Al and incidental impurities.
  • an alloy system in accordance with the principles of the present invention is a modification of the Aluminum Association's alloy system 3XX.
  • This modified alloy system preferably comprises of 8.5 to 10.0 wt.% Si, 0.46 to 0.65 wt.% Mg, 0.1 to 0.15 wt.% Ti, less than 0.15 wt.% Mn, Sn less than 0.05 wt.%, and Zn less than 0.1 wt.%.
  • the alloy further include grain refining additions of Ti, TiB2, A1B2, B, Be, Zr, Y, V, Nb, singly or in combination with one another in the range of 0.001 to 0.5 wt.%, most preferably grain refining additions of 0.1 to 0.5 wt.% ⁇ 13 ⁇ 3 ⁇ master alloy comprising TiB2 and A1B2, chemical modifiers such as Na and Sr, singly or in combination with one another in the range of 0.001 to about 0.10 wt.% and phase refiners such as P in the range of 0.01 to about 0.20 wt.%), and the balance of Al and incidental impurities.
  • chemical modifiers such as Na and Sr
  • phase refiners such as P in the range of 0.01 to about 0.20 wt.%
  • the silicon can be used to improve the performance of the alloy casting, improve mobility and reduce hot cracking tendency, reduce shrinkage, improve air tightness.
  • Magnesium's role is to improve its strength and toughness; cast, in addition to a small amount of magnesium dissolved in the a-Al substrate body, mainly exists in the larger size of the Mg2Si phase, therefore, cast magnesium alloy on the mechanical properties of the obvious.
  • the role of magnesium in the alloy is achieved by heat treatment; solution treatment, magnesium dissolved a matrix of precipitated Mg2Si during aging, the alloy strengthening.
  • the castings will be cast using the conventional method of pouring the molten alloy mixture into a permanent, sand or investment type mold or alternatively cast using advanced techniques such as high pressure die casting or squeeze casting to produce a near net shape cast parts.
  • Prior to casting it is essential to have a proper degassing and grain refining.
  • the casting Al-Si alloys of the present invention may be resistance furnace smelting, alloying elements above the middle of its way and aluminium alloy added to the molten aluminium; with 25% Na 2 SiF 6 + 75% C 2 Cl 6 refining agents and with the rotary degassing unit with the use of the best refining effect in amount of 0.5-0.8 % (mass percentage).
  • the casting is subjected to an appropriate heat treatment in accordance with the practice that involves the steps of solution heat treatment at temperatures approaching the solidus temperature of a given alloy; quenching into water or other appropriate media, and ageing at temperatures ranging from ambient to about 300 °C.
  • an appropriate heat treatment in accordance with the practice that involves the steps of solution heat treatment at temperatures approaching the solidus temperature of a given alloy; quenching into water or other appropriate media, and ageing at temperatures ranging from ambient to about 300 °C.
  • a multiple stages solution process and multiple stages ageing process can be utilized.
  • it includes primary ageing at a low temperature (e.g., less than about 190 °C, preferably less than 160 °C) for an short period of time (e.g.
  • alloys which embody the present invention, have been shown to have yield strengths (0.2% offset) in excess of 300 MPa and elongation in excess of 10 %.
  • the alloys listed in Table 1 Four alloys of the compositions listed in Table 1 were cast into a permanent mold.
  • the alloys also include an A356 and an A357 type cast aluminum alloys.
  • the castings were made by weighting different elements with an appropriate ratio and melting them in a 12 kg clay- graphite crucible in an electric resistance furnace. When the melt was fully homogenised, it was subjected to degassing, during which Ar was blown into the melt by a commercial rotatory degasser adjusted at 350 rpm for 4 min. It should be mentioned that Al-lOSr alloy was added at 0.01-0.02 wt.% Sr before degassing. TiB-containing refiner was added at 720 °C with 0.005 wt.% of B and before pouring.
  • melt was poured into the boron nitride painted steel mould, designed based on ASTM B108 standard, to produce dog- bone shape tensile specimens.
  • molten metal was poured into the steel mold which was already heated up to 400-460 °C.
  • composition analysis was carried out using the Foundry-Master Pro which is a high- performing optical emission spectrometer (OES). Each of the four castings was solution heat treated at 540 °C for 8 hours, immediately quenched into ambient temperature water upon removal from the furnace and allowed to stabilize for several days. Ageing was optimized for each alloy by taking Vickers hardness measurements in accordance with the American Society for Testing and Materials (ASTM) standard E92-82 at selected time intervals for a wide range of temperatures. The optimized ageing process is ageing at 170 °C for 8 hours or ageing at 190°C for 4 hours. The mechanical properties were further measured in accordance with ASTM B557 standard using an Instron 5500 Universal Electromechanical Testing Systems equipped with Bluehill software and a ⁇ 50 kN load cell.
  • ASTM B557 Standard using an Instron 5500 Universal Electromechanical Testing Systems equipped with Bluehill software and a ⁇ 50 kN load cell.
  • the developed alloys labelled as GCOl and GC02 display higher strengths and elongations over the commercially available A356 and A357 alloys. This is especially surprising given that the A357 alloy is by far the highest strength alloy in the Al- Si-Mg cast alloy system. Moreover, the Mg content is higher in the A357 alloy, in which Mg content is 0.5-0.7 wt.%. Since published yield strength values (source: Metals Handbook Desk Edition. American Society for metals, H.E. Boyer and T.L. Gall, eds., 1985, pp.
  • the alloys listed in Table 3 Four alloys of the compositions listed in Table 3 were cast into a sand mold.
  • the alloys also include an A356 and an A357 type cast aluminum alloys.
  • the castings were made by weighting different elements with an appropriate ratio and melting them in a 12 kg clay- graphite crucible in an electric resistance furnace. When the melt was fully homogenised, it was subjected to degassing, during which Ar was blown into the melt by a commercial rotatory degasser adjusted at 350 rpm for 4 min. It should be mentioned that Al-lOSr alloy was added at 0.01-0.02 wt.% Sr before degassing. TiB-containing refiner was added at 720 °C with 0.005 wt.% of B and before pouring.
  • melt was poured into the British standard sand mould, to produce dog-bone shape tensile specimens.
  • molten metal was poured into the sand mold which was at room temperature.
  • Chemical composition analysis was carried out using the Foundry-Master Pro which is a high-performing optical emission spectrometer (OES).
  • Each of the four castings was solution heat treated at 540 °C for 8 hours, immediately quenched into ambient temperature water upon removal from the furnace and allowed to stabilize for several days.
  • Ageing was optimized for each alloy by taking Vickers hardness measurements in accordance with the American Society for Testing and Materials (ASTM) standard E92-82 at selected time intervals for a wide range of temperatures. The optimized ageing process is at 170 °C for 8 hours or at 190°C for 4 hours.
  • the mechanical properties were further measured in accordance with ASTM B557 standard using an Instron 5500 Universal Electromechanical Testing Systems equipped with Bluehill software and a ⁇ 50 kN load cell. All the tensile tests were performed at ambient temperature ( ⁇ 25 °C). The gauge length of the extensometer was 50 mm and the ramp rate for extension was 1 mm/min.
  • the mechanical properties of the four castings after solution and ageing treatment are listed in Table 4. TABLE 3
  • the commercially available A356 alloy displays a yield strength of 230 MPa and an UTS of 280 MPa with 0.35 wt.% Mg
  • the commercially available A357 alloy shows a yield strength of 275 MPa and an UTS of 300 MPa with 0.5 wt.% Mg
  • the developed alloys labelled SCOl and SC02 with 0.5 wt.% Mg display a remarkable increase of strength over the commercially available A356 and A357 alloys, with a yield strength above 295 MPa and an UTS above 325MPa. This is especially surprising given that the A357 alloy is by far the highest strength alloy in the Al-Si-Mg cast alloy system.
  • the Mg content is higher in the A357 alloy, in which Mg content is 0.5-0.7 wt.%, and the A357 alloy achieves higher strength over the A356 alloy at higher Mg content with significant decrease of elongation to be below 3 %, while the developed alloys achieve higher strength over the A356 alloy without obvious decrease of elongation.
  • the developed compositions are very potent in overcoming this large property disparity that is observed with slightly different Mg levels. If the Mg content were adjusted to the 0.60 weight percent level or above, it is likely that the strength of the developed alloys would be even greater.

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  • Continuous Casting (AREA)

Abstract

La présente invention concerne des pièces coulées d'Al-Si-Mg permettant d'obtenir des propriétés mécaniques améliorées pour des applications structurales comprenant (1) une optimisation d'alliage contenant de 8,5 à 12,5 % en poids de Si, de 0,46 à 1,0 % en poids de Mg, de 0,1 à 0,2 % en poids de Ti, de 0,05 à 0,25 % en poids de Mn, de 0,01 à 0,02 % en poids de Sr, de 0,004 à 0,1 % en poids de B et d'autres éléments d'impuretés de Cu, de Fe, de Zn, chacun inférieur à 0,15 % en poids, et le reste d'Al ; (2) un traitement à l'état fondu optimisé comprenant une fusion, une modification, un dégazage et un raffinage de grain appropriés ; (3) un type approprié de raffineur de grains à quantité optimisée et un procédé d'ajout dans le bain d'aluminium, et (4) un processus de traitement thermique optimisé. Lorsqu'elles sont utilisées pour fabriquer des pièces coulées en alliage d'aluminium profilé par mise en œuvre d'un procédé de coulée par gravité, les pièces coulées présentent une limite d'élasticité conventionnelle à 0,2 % supérieure à 310 MPa, une résistance à la traction supérieure à 365 MPa et un allongement supérieur à 10 %.
PCT/GB2018/052186 2017-08-14 2018-07-31 Procédé de formation d'un alliage d'aluminium coulé WO2019034837A1 (fr)

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US16/638,838 US20200190634A1 (en) 2017-08-14 2018-07-31 Method of forming a cast aluminium alloy
CN201880052663.4A CN111032897A (zh) 2017-08-14 2018-07-31 形成铸造铝合金的方法

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GBGB1713005.5A GB201713005D0 (en) 2017-08-14 2017-08-14 The alloy and manufacturing method of Al-Si-Mg castings for improved mechanical performance

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109943754A (zh) * 2019-03-28 2019-06-28 帅翼驰新材料集团有限公司 一种铸造铝合金的制备方法
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EP4234737A1 (fr) * 2022-02-25 2023-08-30 Nio Technology (Anhui) Co., Ltd Alliage d'aluminium et pièce de composant préparée à partir de celui-ci
DE102023105216A1 (de) 2023-01-05 2024-07-11 GM Global Technology Operations LLC Aluminiumräder und Verfahren zum Giessen von Aluminiumrädern unter Verwendung eines hohen Aluminiumschrottgehalts

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1347066A2 (fr) 1999-10-21 2003-09-24 Kabushiki Kaisha Daiki Aluminium Kogyosho Alliage d'aluminium à haute résistance mécanique pour moulage sous pression et alliage d'aluminium ainsi fondu
WO2004104240A2 (fr) 2003-05-24 2004-12-02 Daimlerchrysler Ag Alliages d'aluminium coules durs, a haute rigidite et resistants a chaud
US20050167012A1 (en) * 2004-01-09 2005-08-04 Lin Jen C. Al-Si-Mn-Mg alloy for forming automotive structural parts by casting and T5 heat treatment
WO2010003349A1 (fr) 2008-07-09 2010-01-14 贵州铝厂 Matière d'alliage d'aluminium de fonderie à haute résistance
EP2865772A1 (fr) 2013-10-23 2015-04-29 Befesa Aluminio, S.L. Alliage de fonderie d'aluminium
WO2015121635A1 (fr) 2014-02-11 2015-08-20 Brunel University Alliage d'aluminium coulé à haute résistance pour coulée sous haute pression

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6921512B2 (en) * 2003-06-24 2005-07-26 General Motors Corporation Aluminum alloy for engine blocks
CN1266297C (zh) * 2003-11-20 2006-07-26 上海交通大学 原位自生TiC/Al复合材料超细晶粒细化剂制备工艺
CN103842534A (zh) * 2011-09-19 2014-06-04 美铝有限责任公司 改良的包含钒的铝铸造合金
US9771635B2 (en) * 2012-07-10 2017-09-26 GM Global Technology Operations LLC Cast aluminum alloy for structural components
CN105441737A (zh) * 2015-12-01 2016-03-30 上海交通大学 高强、高耐腐蚀铸造铝合金及其重力铸造制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1347066A2 (fr) 1999-10-21 2003-09-24 Kabushiki Kaisha Daiki Aluminium Kogyosho Alliage d'aluminium à haute résistance mécanique pour moulage sous pression et alliage d'aluminium ainsi fondu
WO2004104240A2 (fr) 2003-05-24 2004-12-02 Daimlerchrysler Ag Alliages d'aluminium coules durs, a haute rigidite et resistants a chaud
US20050167012A1 (en) * 2004-01-09 2005-08-04 Lin Jen C. Al-Si-Mn-Mg alloy for forming automotive structural parts by casting and T5 heat treatment
WO2010003349A1 (fr) 2008-07-09 2010-01-14 贵州铝厂 Matière d'alliage d'aluminium de fonderie à haute résistance
EP2865772A1 (fr) 2013-10-23 2015-04-29 Befesa Aluminio, S.L. Alliage de fonderie d'aluminium
WO2015121635A1 (fr) 2014-02-11 2015-08-20 Brunel University Alliage d'aluminium coulé à haute résistance pour coulée sous haute pression

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DONG XIXI ET AL: "Enhancement of mechanical properties in high silicon gravity cast AlSi9Mg alloy refined by Al3Ti3B master alloy", MATERIALS SCIENCE AND ENGINEERING: A, ELSEVIER, AMSTERDAM, NL, vol. 700, 3 June 2017 (2017-06-03), pages 291 - 300, XP085116212, ISSN: 0921-5093, DOI: 10.1016/J.MSEA.2017.06.005 *
H.E. BOYER AND T.L. GALL,: "Metals Handbook Desk", 1985, AMERICAN SOCIETY FOR METALS, pages: 6.48 - 6.62
YUCEL BIROL ED - BATTEZZATI LIVIO ET AL: "AlBmaster alloy to grain refine AlSi10Mg and AlSi12Cu aluminium foundry alloys", JOURNAL OF ALLOYS AND COMPOUNDS, ELSEVIER SEQUOIA, LAUSANNE, CH, vol. 513, 3 October 2011 (2011-10-03), pages 150 - 153, XP028393615, ISSN: 0925-8388, [retrieved on 20111017], DOI: 10.1016/J.JALLCOM.2011.10.010 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109943754A (zh) * 2019-03-28 2019-06-28 帅翼驰新材料集团有限公司 一种铸造铝合金的制备方法
CN111809083A (zh) * 2019-04-12 2020-10-23 通用汽车环球科技运作有限责任公司 简化半固态铸造工艺的铝合金组合物和半固态铸造方法
EP4234737A1 (fr) * 2022-02-25 2023-08-30 Nio Technology (Anhui) Co., Ltd Alliage d'aluminium et pièce de composant préparée à partir de celui-ci
DE102023105216A1 (de) 2023-01-05 2024-07-11 GM Global Technology Operations LLC Aluminiumräder und Verfahren zum Giessen von Aluminiumrädern unter Verwendung eines hohen Aluminiumschrottgehalts

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