WO2018194298A3 - 에폭시 아크릴계 중굴절 광학렌즈용 수지 조성물 및 그 제조방법 - Google Patents

에폭시 아크릴계 중굴절 광학렌즈용 수지 조성물 및 그 제조방법 Download PDF

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Publication number
WO2018194298A3
WO2018194298A3 PCT/KR2018/003956 KR2018003956W WO2018194298A3 WO 2018194298 A3 WO2018194298 A3 WO 2018194298A3 KR 2018003956 W KR2018003956 W KR 2018003956W WO 2018194298 A3 WO2018194298 A3 WO 2018194298A3
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WIPO (PCT)
Prior art keywords
optical lens
resin composition
refractive optical
based medium
epoxy acryl
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PCT/KR2018/003956
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English (en)
French (fr)
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WO2018194298A2 (ko
Inventor
장동규
노수균
홍길표
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주식회사 케이오씨솔루션
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Priority to CN201880013795.6A priority Critical patent/CN110337456A/zh
Publication of WO2018194298A2 publication Critical patent/WO2018194298A2/ko
Publication of WO2018194298A3 publication Critical patent/WO2018194298A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00—Producing optical elements, e.g. lenses or prisms
    • B29D11/00009—Production of simple or compound lenses
    • B29D11/00355—Production of simple or compound lenses with a refractive index gradient
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041—Lenses
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B3/00—Simple or compound lenses
    • G02B3/0006—Arrays
    • G02B3/0012—Arrays characterised by the manufacturing method

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Mechanical Engineering (AREA)
  • Ophthalmology & Optometry (AREA)
  • Epoxy Resins (AREA)

Abstract

본 발명은 에폭시 아크릴계 광학렌즈에 관한 것으로, 특히 고상 굴절률 1.53~1.58의 투명성, 아베수, 열안정성, 내광성 및 압축강도가 좋은 에폭시 아크릴계 중굴절 광학렌즈용 수지 조성물 및 그 제조방법에 관한 것이다. 본 발명에서는, 염소 함량이 100~1,700ppm인 비스페놀 A 디글리시딜 에테르와 아크릴산을 반응시켜 얻은 비스페놀 A 에폭시아크릴레이트를 50~70중량%와, 메틸메타크릴레이트 21~45중량%와, 반응성 희석제 1~17중량%를 포함하는, 고상 굴절률 1.53~1.58의 에폭시 아크릴계 중굴절 광학렌즈용 수지 조성물이 제공된다. 본 발명에 따르면, 비스페놀 A 디글리시딜 에테르의 염소 함량을 제어하고 조성물 중에 MMA를 다량 함유시킴으로써 굴절률 1.53~1.58의 중굴절 렌즈에서 압축강도를 향상시키면서 투명성·아베수·열안정성·내광성 또한 좋은 에폭시 아크릴계 중굴절 광학렌즈용 수지 조성물을 얻을 수 있다. 본 발명에 따른 에폭시 아크릴계 중굴절 광학렌즈는 기존의 중굴절 광학렌즈를 대체하여 다양한 분야에서 널리 이용될 수 있다.
PCT/KR2018/003956 2017-04-21 2018-04-04 에폭시 아크릴계 중굴절 광학렌즈용 수지 조성물 및 그 제조방법 WO2018194298A2 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201880013795.6A CN110337456A (zh) 2017-04-21 2018-04-04 用于环氧丙烯酸类中折射光学透镜的树脂组合物及其制备方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020170051781A KR101816722B1 (ko) 2017-04-21 2017-04-21 에폭시 아크릴계 중굴절 광학렌즈용 수지 조성물 및 그 제조방법
KR10-2017-0051781 2017-04-21

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WO2018194298A2 WO2018194298A2 (ko) 2018-10-25
WO2018194298A3 true WO2018194298A3 (ko) 2019-01-10

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KR (1) KR101816722B1 (ko)
CN (1) CN110337456A (ko)
WO (1) WO2018194298A2 (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101816722B1 (ko) * 2017-04-21 2018-01-11 주식회사 케이오씨솔루션 에폭시 아크릴계 중굴절 광학렌즈용 수지 조성물 및 그 제조방법
KR20180128296A (ko) * 2017-05-23 2018-12-03 주식회사 케이오씨솔루션 에폭시 아크릴계 중굴절 광학렌즈용 수지 조성물 및 그 제조방법
CN112430435B (zh) * 2020-11-12 2022-05-24 江苏鹿山新材料有限公司 复合封装胶膜及其制备方法和光伏组件
CN113831441B (zh) * 2021-09-26 2022-06-03 湖北巴乐福化工科技有限公司 一种光学树脂单体的制备方法及其反应系统

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WO2018194298A2 (ko) 2018-10-25
KR101816722B1 (ko) 2018-01-11
CN110337456A (zh) 2019-10-15

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