WO2018186567A1 - Method for producing water-permeable block using recycled synthetic resin, and water-permeable block produced by said method - Google Patents

Method for producing water-permeable block using recycled synthetic resin, and water-permeable block produced by said method Download PDF

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Publication number
WO2018186567A1
WO2018186567A1 PCT/KR2018/000815 KR2018000815W WO2018186567A1 WO 2018186567 A1 WO2018186567 A1 WO 2018186567A1 KR 2018000815 W KR2018000815 W KR 2018000815W WO 2018186567 A1 WO2018186567 A1 WO 2018186567A1
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WIPO (PCT)
Prior art keywords
synthetic resin
fine aggregate
permeable block
cooling
water
Prior art date
Application number
PCT/KR2018/000815
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French (fr)
Korean (ko)
Inventor
김태현
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김태현
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Publication of WO2018186567A1 publication Critical patent/WO2018186567A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C5/00Apparatus or methods for producing mixtures of cement with other substances, e.g. slurries, mortars, porous or fibrous compositions
    • B28C5/08Apparatus or methods for producing mixtures of cement with other substances, e.g. slurries, mortars, porous or fibrous compositions using driven mechanical means affecting the mixing
    • B28C5/10Mixing in containers not actuated to effect the mixing
    • B28C5/12Mixing in containers not actuated to effect the mixing with stirrers sweeping through the materials, e.g. with incorporated feeding or discharging means or with oscillating stirrers
    • B28C5/14Mixing in containers not actuated to effect the mixing with stirrers sweeping through the materials, e.g. with incorporated feeding or discharging means or with oscillating stirrers the stirrers having motion about a horizontal or substantially horizontal axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/002Apparatus for washing concrete for decorative purposes or similar surface treatments for exposing the texture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/245Curing concrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B7/00Moulds; Cores; Mandrels
    • B28B7/0097Press moulds; Press-mould and press-ram assemblies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C5/00Apparatus or methods for producing mixtures of cement with other substances, e.g. slurries, mortars, porous or fibrous compositions
    • B28C5/46Arrangements for applying super- or sub-atmospheric pressure during mixing; Arrangements for cooling or heating during mixing, e.g. by introducing vapour
    • B28C5/466Heating, e.g. using steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C7/00Controlling the operation of apparatus for producing mixtures of clay or cement with other substances; Supplying or proportioning the ingredients for mixing clay or cement with other substances; Discharging the mixture
    • B28C7/0007Pretreatment of the ingredients, e.g. by heating, sorting, grading, drying, disintegrating; Preventing generation of dust
    • B28C7/0023Pretreatment of the ingredients, e.g. by heating, sorting, grading, drying, disintegrating; Preventing generation of dust by heating or cooling
    • B28C7/003Heating, e.g. using steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C7/00Controlling the operation of apparatus for producing mixtures of clay or cement with other substances; Supplying or proportioning the ingredients for mixing clay or cement with other substances; Discharging the mixture
    • B28C7/04Supplying or proportioning the ingredients
    • B28C7/0404Proportioning
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/20Waste materials; Refuse organic from macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0051Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof characterised by the pore size, pore shape or kind of porosity
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • E01C11/22Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
    • E01C11/224Surface drainage of streets
    • E01C11/225Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Definitions

  • the present invention relates to a method for producing a water permeable block using recycled synthetic resin, such as a waste container used as a food and beverage container, and a water permeable block produced thereby.
  • sidewalks for people to walk safely.
  • Such sidewalks are manufactured in various forms so that pedestrians can walk more comfortably and safely.
  • cement, asphalt, urethane, etc. are poured directly onto the ground to form sidewalks, or concrete or synthetic resins are used.
  • Formed sidewalk blocks are manufactured by forming the sidewalk blocks flat on the ground to form sidewalks.
  • the bigger problem is that most of the sidewalk blocks are products using cement concrete products, clay products, and waste tires, and these products use pigments produced by chemical methods in the upper layer, and they do not undergo sufficient curing process. As it is released, it causes pollution of river and river water quality.
  • products using eco-friendly resins do not have a product that is directly produced using a molding machine, and the curing time is long, many molds must be used, and after curing for at least 2 to 24 hours in the mold, demolding is performed. Therefore, it is difficult to apply to the actual site because there are many production processes and excessive production costs.
  • the present invention has been made to solve the above-mentioned problems, one object of the present invention is to mix the waste synthetic resin used as an edible container to prepare a permeable block, but to enhance the strength by increasing the resin compounding ratio compared to the existing In addition, by increasing the porosity by lowering the pressing force in the press molding, and by increasing the cooling time of the permeation block, it is possible to prevent burning or melting of the resin to prevent pore blockage and also to prevent harmful gas generation. It is to provide a method for producing a permeable block using.
  • Another object of the present invention to provide a permeable block produced by the above-described manufacturing method.
  • the molten resin and the fine aggregate are added to the mixer at a ratio of 3: 7, and the temperature inside the mixer is heated to be 220 to 290 ° C., and the rotation speed of the mixer is rotated at a speed of 10 to 30 rpm to adjust the fine aggregate and the molten recycled synthetic resin.
  • Mixing step of mixing A molding step of inserting the mixed molten resin and fine aggregate into a mold and molding a permeable block by pressure molding at a pressure of 30 to 40 MPa; And a cooling step of uniformly cooling the surface and the inside of the molded water permeable block for 15 to 20 sec.
  • the mixer used in the mixing step includes a cylindrical mixer barrel and a plurality of stirring blades arranged in a step shape along the longitudinal direction on the inner circumferential surface of the mixer cylinder, each of the stirring blades is a portion of the stirring stirring adjacent It may be arranged to overlap with the wings.
  • water cooling is performed as the cooling tray containing each of the permeation blocks passes through the cooling water tank while being transported by the conveyor, and air is blown by the nozzle through the open upper portion of the cooling tray.
  • the permeation block can be air cooled.
  • a permeation block manufactured by the method for producing a permeation block using the recycled synthetic resin, wherein the permeation block has a hexahedral shape, the regenerated synthetic resin and the fine aggregate constituting the permeation block is 3: 7 It is made by mixing at a ratio, and when formed under pressure at a pressure of 30 to 40 MPa is provided a permeability block comprising a porosity of 20 to 30%.
  • the porosity can be increased by lowering the pressing force in the press molding as compared with the existing, thereby increasing the permeability efficiency.
  • FIG. 1 is a flowchart illustrating a method of manufacturing a pitcher block using recycled synthetic resin according to the present invention.
  • FIG. 2 is a block diagram of a mixer and stirring blade according to the present invention
  • FIG 3 is a view for explaining the cooling process of the water permeable block according to the present invention.
  • Figure 4 is a shape of the pitcher block produced according to the production method of the present invention
  • FIG. 5 is a schematic cross-sectional view showing an embodiment of an air nozzle according to the present invention.
  • FIG. 1 is a flowchart illustrating a method of manufacturing a pitcher block using recycled synthetic resin according to the present invention.
  • the manufacturing method of the water permeable block using the recycled synthetic resin according to the present invention is the aggregate aggregate heating step (S10), fine aggregate thermal insulation step (S20), melting step (S30), mixing step (S40), molding step (S50) And cooling step (S60).
  • the fine aggregate heating step (S10) is a step of inputting the fine aggregate conveyed by the conveyor to the primary heating furnace and heating it to a predetermined temperature.
  • the fine aggregate heating step is to allow the recycled synthetic resin to be melted by the heating temperature of the fine aggregate when the recycled synthetic resin and the fine aggregate to be described in the steps to be described later are mixed.
  • the fine aggregate thermal insulation step (S20) is a step of keeping the heated temperature of the fine aggregate is kept constant by inputting the fine aggregate heated in the above step into the secondary heating furnace.
  • the melting step (S30) is a step of melting the regenerated synthetic resin by the heated temperature of the residual aggregate by inputting the residual aggregate discharged from the secondary heating furnace and the regenerated synthetic resin crushed to a certain size in the melting furnace.
  • the recycled synthetic resin introduced into the melting furnace is subjected to the sorting step (S100), the crushing step (S200) and the washing and drying step (S300).
  • the sorting step (S100) is a step of sorting the PET bottle (PET) used as a container for food and beverage by colorless, color and material
  • the grinding step (S200) is to crush the regenerated synthetic resin selected in the above, but the diameter is 0.5 ⁇ 2.0cm
  • the washing and drying step (S300) is a step of washing, dehydrating and drying the pulverized regenerated synthetic resin.
  • the screening step is to use a colorless of the recycled synthetic resin can be produced a transparent block of the transparent color, if you use a colored block can be produced according to the color of the corresponding color to obtain the desired color without using a dye This makes it possible to manufacture environmentally friendly pitching blocks and contributes to cost reduction.
  • the recycled synthetic resin and the aggregate are added to the mixer at a ratio of 3: 7, and the temperature inside the mixer is heated to be 220 to 290 ° C, and the rotation speed of the mixer is at a speed of 10 to 30 rpm. It is a step of mixing the molten recycled synthetic resin which is rotated to serve as a fine aggregate and a flocculant.
  • the internal temperature of the mixer is lower than 220 °C can not solidify because it is not melted, whereas if higher than 290 °C can be burned due to high heat is preferably limited to the above temperature range.
  • the mixing ratio of the recycled synthetic resin and fine aggregates is an important factor for improving the strength, and as the mixing ratio of the recycled synthetic resins increases with respect to the fine aggregates, the cohesive strength of the fine aggregates increases, but the mixing ratio of the recycled synthetic resins is more than necessary. If it is increased, the ductility is increased to increase the possibility of deformation is preferably determined in the above compounding range.
  • the rotational speed in the above range is good mixing efficiency.
  • the stirring efficiency is significantly lowered.
  • the stirring efficiency is lowered.
  • the mixer may have a form as in FIG. 2 to increase the stirring efficiency.
  • the mixer 100 has a cylindrical mixer barrel 110 having an inlet 111 and an outlet 112 and a plurality of staircases arranged in the longitudinal direction on the inner circumferential surface of the mixer barrel 110. It may be composed of a plate or streamlined stirring blades 120.
  • each of the stirring blades 120 is preferably a portion, for example, the end of the longitudinal direction is disposed to overlap with the other stirring blades adjacent.
  • the stirring blade 120 of the present application is disposed in a step shape, so that the aggregate and the molten resin are staircases. Since it flows smoothly along the flow efficiency can be doubled, and thus the stirring efficiency can be doubled.
  • the molding step (S50) is a step of forming a permeation block by putting a predetermined amount of the mixed molten resin and the residual aggregate into a mold (mold), and by pressure molding at a pressure of 30 ⁇ 40MPa by a plunger.
  • the important factor is the pressurization pressure, the larger the pressing force, the porosity is lowered because the pores between the molten resin and the fine aggregate becomes dense, while the smaller the pressing force increases the porosity between the molten resin and the fine aggregate, thereby increasing the porosity.
  • the permeation block may be better because the larger the porosity, the larger the porosity, so the larger the porosity, the greater the porosity. Can be guaranteed.
  • Porosity when pressurized to the above pressure is 20 to 30%.
  • the porosity is Vs
  • the cooling step (S60) is a step of evenly cooling the surface and the interior of the molding block is completed for 15 to 20 seconds.
  • the external cooling of the permeation block 1 is performed by water cooling, and the internal cooling of the permeation block 1 is simultaneously performed by air cooling, the inside and outside of the permeation block 1 can be cooled overall.
  • the improvement in cooling efficiency contributes to productivity improvement since the curing time can be significantly reduced compared to the existing curing time of 28 days.
  • the water permeability block 1 of the present invention can increase the cooling efficiency and shorten the cooling time since the porosity is improved compared to the conventional one.
  • Figure 4 is a photograph of the pitcher block produced by the invention described above.
  • the permeable block 1 has a hexahedral shape, and is composed of recycled synthetic resin and fine aggregate at a ratio of 3: 7, and is press-molded at a pressure of 30 to 40 MPa to form a porosity of 20 to Up to 30%.
  • the permeable block 1 according to these conditions can obtain a product that satisfies both strength and permeability efficiency.
  • the air nozzle 510 may be made of a swirl nozzle as shown in FIG.
  • the vortex nozzle is a means for rotating the injected air while increasing the blowing force of the air.
  • a thread forming part 64 having a thread is formed to be fastened to the air supply pipe 500, and the thread forming part 64 is formed.
  • a hollow and conical body portion 65 is formed integrally extending.
  • the body portion 65 has a plurality of air holes 66 which are holes for final injection of air along the spiral direction. It is formed through.
  • the outer surface of the body portion 65 is formed with a spiral air groove inner groove 68 coinciding with the air holes 66 arranged in a spiral direction, the air groove inner groove 68 is an air hole ( 66 to guide the jet direction of the air jetted from the spiral direction to form a vortex.
  • the air injected through the air hole 66 of the vortex nozzle and the spiral air while the inner groove 68 rotates and simultaneously sprays air while forming a vortex, thereby evenly spraying the permeable block 1 while the permeable block (1) The whole is cooled evenly.
  • the anti-fouling coating layer coated with the anti-fouling coating composition may be formed around the stirring vane 120 to effectively achieve the prevention and removal of contaminants.
  • the antifouling coating composition includes hydrogen peroxide and sodium metasilicate in a 1: 0.01 to 1: 2 molar ratio, and the total content of hydrogen peroxide and sodium metasilicate is 1 to 10% by weight based on the total aqueous solution.
  • sodium metasilicate or calcium carbonate may be used as a material for improving the coatability of the antifouling coating layer, but preferably sodium metasilicate may be used.
  • the hydrogen peroxide and sodium metasilicate are preferably 1: 0.01 to 1: 2 as the molar ratio. If the molar ratio is out of the above range, the coating property of the substrate may be reduced or the moisture absorption of the surface may be increased after application, thereby removing the coating film. have.
  • the hydrogen peroxide and sodium metasilicate are preferably 1 to 10% by weight of the total composition aqueous solution, if less than 1% by weight has a problem that the applicability of the substrate is lowered, if it exceeds 10% by weight crystal due to the increase in the coating film thickness Precipitation is likely to occur.
  • the final coating film thickness on the stirring blade 120 is preferably 500 to 2000 kPa, more preferably 1000 to 2000 kPa. If the thickness of the coating film is less than 500 kPa, there is a problem of deterioration in the case of high temperature heat treatment, and if the thickness of the coating film exceeds 2000 kPa, crystal precipitation of the coated surface is liable to occur.
  • the antifouling coating composition may be prepared by adding 0.1 mol of hydrogen peroxide and 0.05 mol of sodium metasilicate to 1000 ml of distilled water, followed by stirring.
  • the cooling bath 400 may be formed of a surface protective coating layer of a surface coating material of a metal material in order to prevent corrosion of the surface from dust, contaminants, and the like.
  • the surface protective coating layer is composed of 2.5% by weight zirconium powder, 60% by weight alumina powder, 30% by weight NH 4 Cl, 2.5% by weight zinc, 2.5% by weight magnesium and 2.5% by weight titanium.
  • the zirconium powder is excellent in corrosion resistance and heat resistance. This zirconium powder is mixed at 2.5% by weight. If the mixing ratio of the zirconium powder is less than 2.5% by weight, the corrosion resistance and the heat resistance are not greatly improved. On the other hand, if the mixing ratio of the zirconium powder exceeds 2.5% by weight, the above-mentioned effect is not improved further while the material cost is greatly increased. Therefore, the titanium is preferably mixed 2.5% by weight.
  • the alumina powder is added for the purpose of sintering, tangling, fusion prevention, etc. when heated to a high temperature.
  • the alumina powder is added in less than 60% by weight, the effect of sintering, tangling and fusion prevention is inferior, and when the alumina powder exceeds 60% by weight, the above-mentioned effect is not further improved, while the material cost is greatly increased. Therefore, it is preferable to add 60 weight% of alumina powders.
  • the NH 4 Cl reacts with zinc and magnesium in a vapor state to serve to activate diffusion and penetration. This NH 4 Cl is added 30% by weight. If NH 4 Cl is added at less than 30% by weight, it does not react properly with the vaporized zinc and magnesium and thus does not activate diffusion and penetration. On the other hand, when NH 4 Cl exceeds 30% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, it is preferable to add 30% by weight of NH 4 Cl.
  • the zinc is formulated to prevent corrosion of metals in water and to be used for electrical applications. This zinc is mixed 2.5% by weight. If the mixing ratio of zinc exceeds 2.5% by weight, it will not properly prevent corrosion of the metal on water. On the other hand, when the mixing ratio of zinc exceeds 2.5% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, the zinc is preferably mixed 2.5% by weight.
  • magnesium Since the pure metal of magnesium has a low structural strength, the magnesium is combined with zinc to increase the hardness, tensile strength and corrosion resistance of the metal. This magnesium is mixed 2.5% by weight. If the mixing ratio of magnesium is less than 2.5% by weight, the hardness, tensile strength and corrosion resistance to salt water of the metal when combined with zinc and the like are not significantly improved. On the other hand, when the mixing ratio of magnesium exceeds 2.5% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, magnesium is preferably mixed at 2.5% by weight.
  • the titanium is a light, hard and corrosion-resistant transition metal element has a silver-white metallic luster, and because of its excellent corrosion resistance and low specific gravity, the weight of the titanium is only 60% compared to steel, so that the weight of the coating material applied to the metal base material is reduced but the gloss is increased. It is formulated to have excellent waterproof and corrosion resistance.
  • This titanium is mixed 2.5% by weight.
  • the mixing ratio of titanium is less than 2.5% by weight, the weight of the coating material applied to the metal base material is not so much reduced, and the glossiness, waterproofness, and corrosion resistance are not greatly improved.
  • the mixing ratio of titanium exceeds 2.5% by weight, the above-mentioned effect is not further improved while the material cost is greatly increased. Therefore, the titanium is preferably mixed 2.5% by weight.
  • the surface coating method of the cooling water tank 400 according to the present invention is as follows.
  • the cooling water tank 400 to which the surface protective coating layer is to be formed and the coating material blended in the above configuration are put together in the closing furnace.
  • Argon gas is injected, and maintained at a temperature of 700 ° C to 800 ° C for 4 to 5 hours while argon gas is injected.
  • the zirconium powder, alumina powder, zinc, magnesium, and titanium in a vapor state are formed inside the closure, and the zirconium powder, alumina powder, zinc, magnesium, and titanium blend penetrate the surface of the base material to provide a surface protective coating layer. Is formed.
  • the internal temperature of the coating material / substrate composite is maintained at 800 ° C. to 900 ° C. for 30 to 40 hours, and the surface protection coating layer for preventing corrosion is formed on the surface of the cooling water tank 400.
  • the surface of the cooling water tank 400 and the outside air is isolated. At this time, in performing the process, the temperature change is rapid because the surface protective coating layer of the surface of the cooling water tank 400 may be peeled off.
  • the surface protective coating layer of the present invention has the following advantages.
  • the surface protective coating layer of the present invention has a very wide range of uses, it can be applied by various methods such as curtain coating, spray painting, dip coating, flooding, and the like.
  • the surface protective coating layer of the present invention can be applied with a very thin layer thickness in addition to the principle protection against corrosion and / or scale, thereby improving the electrical conductivity as well as material and cost savings. Even after hot forming, a thin electroconductive primer may be applied on top of the application layer if high electrical conductivity is desired.
  • the coating material may be retained on the surface of the substrate, for example, to increase scratch resistance, to improve corrosion protection, to meet aesthetic appearance, to prevent discoloration, and to be electrically conductive. And can be provided as a primer for conventional downstream processes (eg, dip and electrophoretic dip coating).

Abstract

Disclosed are a method for producing a water-permeable block using recycled synthetic resin, and a water-permeable block produced by the method. The production method comprises: (S10) a fine aggregate heating step for feeding fine aggregate into a primary heating furnace and heating at a set temperature; (S20) a fine aggregate temperature maintenance step for feeding the heated fine aggregate into a secondary heating furnace and maintaining so that the temperature to which the fine aggregate has been heated is maintained as a constant; (S30) a melting step for feeding, into a melting furnace, fine aggregate discharged from the secondary heating furnace and recycled synthetic resin pulverized to a set size, and melting the recycled synthetic resin by means of the temperature of the fine aggregate; (S40) a mixing step for feeding molten resin and fine aggregate into a mixer and mixing the fine aggregate and melted recycled synthetic resin, wherein the mixer is heated so that the temperature therein is 220-290℃, and is rotated at the rotational speed of 10-30rpm; (S50) a molding step for feeding the mixed molten resin and fine aggregate into a mold and molding the water-permeable block by compression-molding at 30-40MPa; and (S60) a cooling step for evenly cooling the surface and interior of the molded water-permeable block for 15-20 seconds.

Description

재생 합성수지를 이용한 투수블록의 제조방법 및 이에 의해 제조된 투수블록Method for producing permeable block using recycled synthetic resin and permeable block produced thereby
본 발명은 재생 합성수지, 예컨대 식음료 용기로 사용되었던 폐용기를 이용하는 투수블록의 제조방법 및 이에 의해 제조된 투수블록에 관한 것이다.The present invention relates to a method for producing a water permeable block using recycled synthetic resin, such as a waste container used as a food and beverage container, and a water permeable block produced thereby.
일반적으로 공원이나 도로에는 사람들이 안전하게 보행할 수 있도록 다양한 형태의 인도가 설치되어 있다. 이러한 인도는 보행자가 더욱 편안하고 안전하게 보행할 수 있도록 여러 가지 형태로 제작되는데, 예컨대 인도를 형성하고자 하는 지면에 시멘트, 아스팔트, 우레탄 등을 직접 타설하여 형성하거나, 또는 콘크리트나 합성수지 등을 이용하여 일정형태의 보도블록들을 제작하고 이 보도블록들을 인도를 형성하고자 하는 지면에 평탄하게 설치하여 형성하고 있다.Generally, parks and roads have various forms of sidewalks for people to walk safely. Such sidewalks are manufactured in various forms so that pedestrians can walk more comfortably and safely. For example, cement, asphalt, urethane, etc. are poured directly onto the ground to form sidewalks, or concrete or synthetic resins are used. Formed sidewalk blocks are manufactured by forming the sidewalk blocks flat on the ground to form sidewalks.
그런데, 시멘트 콘크리트, 아스팔트, 우레탄 등을 지면에 직접 타설하여 인도를 형성할 경우에는 그 표면이 일체로 형성되어 구조적으로 안정되어 있기는 하나, 그 형태 및 색이 단조롭기 때문에 시각적으로 심미감이 현저하게 저하될 뿐만 아니라, 물이 전혀 투수되지 못하여 많은 오수가 발생하게 된다.However, when cement concrete, asphalt, urethane, etc. are directly poured on the ground to form sidewalks, the surface is integrally formed and structurally stable, but the aesthetics are remarkably visual because its shape and color are monotonous. Not only is it lowered, but water is not permeable at all, so that a lot of sewage is generated.
그래서 최근에 설치되는 인도는 대부분 다양한 문양과 색을 가지도록 제작함과 동시에 투수성을 확보할 수 있도록 보도블록들을 이용한 제작이 점차 증가하고 있는 추세이다. 그러나 이 또한 보도블록에 색상을 나타내기 위하여 첨가되는 안료가 햇빛이나 마찰 등에 의하여 그 색이 발하는 백화현상이 빠르게 진행되어 시각적으로 보기 좋지 않은 문제점이 내포되어 있다.Therefore, recently installed India has been gradually increasing the production of a variety of patterns and colors while at the same time using the sidewalk blocks to ensure permeability. However, the whitening phenomenon, in which the pigment is added due to sunlight or friction, is added to express the color of the sidewalk block.
더 큰 문제는 보도블록 대부분이 시멘트 콘크리트 제품, 점토질 제품, 폐타이어를 활용한 제품들로서 이들 제품들은 상층부에 화학적 방법에 의하여 생산된 안료를 사용한 것으로 충분한 양생과정을 거치지 않아 우수에 의하여 화학재료가 그대로 방출되면서 하천 및 강의 수질을 오염시키는 원인이 되고 있다는 점이다.The bigger problem is that most of the sidewalk blocks are products using cement concrete products, clay products, and waste tires, and these products use pigments produced by chemical methods in the upper layer, and they do not undergo sufficient curing process. As it is released, it causes pollution of river and river water quality.
또한, 폐타이어를 활용한 탄성재질의 고무칩 블록의 경우 강도를 확보할 수 없기 때문에 시간이 경과하면 상층부의 탈루현상이 발생되어 블록으로서의 기능이 저하되고 교체 수명이 짧아 국가예산의 과다 지출이라는 문제를 야기하였다.In addition, in the case of elastic tire rubber chip blocks using waste tires, strength cannot be secured, and as time passes, the fugitive phenomenon occurs in the upper layer, which deteriorates the function as a block and shorts the replacement life. Caused.
그리고, 친환경 수지를 활용한 제품들은 성형기를 사용하여 바로 생산하는 제품이 없으며 양생시간이 길어 많은 형틀을 사용하여야 하고, 형틀 내에서 최소 2~24시간 동안 양생한 후 탈형을 하게 된다. 따라서 생산공정이 많고 생산원가가 과도하게 소요되므로 실제 현장에 적용되기 곤란하였다.In addition, products using eco-friendly resins do not have a product that is directly produced using a molding machine, and the curing time is long, many molds must be used, and after curing for at least 2 to 24 hours in the mold, demolding is performed. Therefore, it is difficult to apply to the actual site because there are many production processes and excessive production costs.
본 발명은 상기한 종래의 문제점을 해결하기 위해 안출한 것으로, 본 발명의 일 목적은 식용 용기로 사용되었던 폐합성수지를 투수블록을 제조하는데 혼합하여 사용하되, 수지 배합비를 기존 대비 높힘으로써 강도를 강화하고, 가압 성형시 가압력을 기존 대비 낮춤으로써 공극률을 크게하며, 투수블록의 냉각시간을 늘림으로써 수지가 타거나 녹는 것을 방지하여 공극막힘 현상을 방지함과 아울러 유해가스 발생도 방지할 수 있는 재생 합성수지를 이용한 투수블록의 제조방법을 제공함에 있다.The present invention has been made to solve the above-mentioned problems, one object of the present invention is to mix the waste synthetic resin used as an edible container to prepare a permeable block, but to enhance the strength by increasing the resin compounding ratio compared to the existing In addition, by increasing the porosity by lowering the pressing force in the press molding, and by increasing the cooling time of the permeation block, it is possible to prevent burning or melting of the resin to prevent pore blockage and also to prevent harmful gas generation. It is to provide a method for producing a permeable block using.
또한, 본 발명의 다른 목적은 상기한 제조방법에 의해 제조된 투수블록을 제공함에 있다.In addition, another object of the present invention to provide a permeable block produced by the above-described manufacturing method.
본 발명이 해결하고자 하는 과제는 이상에 언급한 과제들에 제한되지 않으며, 언급되지 않는 또 다른 과제들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.The problem to be solved by the present invention is not limited to the above-mentioned problems, and other problems not mentioned will be clearly understood by those skilled in the art from the following description.
상기한 목적을 달성하기 위한 본 발명의 일 양태에 따르면, 잔골재를 1차 가열로에 투입하여 잔골재를 소정온도로 가열하는 잔골재 가열단계; 상기 가열된 잔골재를 2차 가열로로 투입하여 잔골재의 가열된 온도가 일정하게 유지되도록 보온하는 잔골재 보온단계; 상기 2차 가열로로부터 배출되는 잔골재와 일정크기로 분쇄된 재생 합성수지를 융용로에 투입하여, 잔골재의 온도에 의해 재생 합성수지를 용융시키는 용융단계; 상기 용융수지와 잔골재를 3:7의 비율로 믹서에 투입하되, 믹서 내부의 온도는 220 ~ 290℃가 되도록 가열하고, 믹서의 회전속도는 10 ~ 30rpm의 속도로 회전시켜서 잔골재와 용융된 재생 합성수지를 혼합시키는 혼합단계; 상기 혼합된 용융수지와 잔골재를 몰드에 투입하고, 30 ~ 40MPa의 압력으로 가압 성형하여 투수블록을 성형하는 성형단계; 및 상기 성형된 투수블록의 표면 및 내부를 15 ~ 20sec 동안 고르게 냉각시키는 냉각단계;를 포함하는 재생 합성수지를 이용한 투수블록의 제조방법이 제공된다.According to an aspect of the present invention for achieving the above object, a fine aggregate heating step of heating the fine aggregate to a predetermined temperature by inputting the fine aggregate into the primary heating furnace; A fine aggregate warming step of insulating the heated fine aggregate into a secondary heating furnace to keep the heated temperature of the fine aggregate constant; A melting step of melting the regenerated synthetic resin by the temperature of the fine aggregate by injecting the fine aggregate discharged from the secondary heating furnace and the regenerated synthetic resin crushed to a certain size into a melting furnace; The molten resin and the fine aggregate are added to the mixer at a ratio of 3: 7, and the temperature inside the mixer is heated to be 220 to 290 ° C., and the rotation speed of the mixer is rotated at a speed of 10 to 30 rpm to adjust the fine aggregate and the molten recycled synthetic resin. Mixing step of mixing; A molding step of inserting the mixed molten resin and fine aggregate into a mold and molding a permeable block by pressure molding at a pressure of 30 to 40 MPa; And a cooling step of uniformly cooling the surface and the inside of the molded water permeable block for 15 to 20 sec.
바람직하게, 상기 재생 합성수지는 식음료용 용기로 사용되는 패트병을 무색, 유색 및 재질별로 선별하는 선별단계; 상기 선별된 재생 합성수지를 분쇄하되, 직경이 0.5 ~ 2.0cm가 되도록 분쇄하는 분쇄단계; 및 상기 분쇄된 재생 합성수지를 세척 및 탈수, 건조하는 세정 및 건조단계;를 거쳐 상기 용융로에 투입될 수 있다.Preferably, the regeneration synthetic resin screening step of sorting the plastic bottle used as a container for food and beverage by color, color and material; Pulverizing the selected recycled synthetic resin, but pulverizing the diameter to 0.5 to 2.0 cm; And a washing and drying step of washing and dehydrating and drying the pulverized regenerated synthetic resin, and may be added to the melting furnace.
바람직하게, 상기 혼합단계에서 사용되는 믹서는, 원통형의 믹서통과, 상기 믹서통의 내주면에 길이방향을 따라 계단형으로 배치되는 다수의 교반날개를 포함하되, 상기 각 교반날개는 그 일부분이 인접한 교반날개와 중첩되게 배치될 수 있다.Preferably, the mixer used in the mixing step includes a cylindrical mixer barrel and a plurality of stirring blades arranged in a step shape along the longitudinal direction on the inner circumferential surface of the mixer cylinder, each of the stirring blades is a portion of the stirring stirring adjacent It may be arranged to overlap with the wings.
바람직하게, 상기 냉각단계는, 상기 각 투수블록이 수용된 냉각 트레이가 컨베이어에 의해 이송되면서 냉각수조를 통과함에 따라 수냉이 이루어지고, 이와 함께, 상기 냉각 트레이의 개방된 상부를 통해 노즐에 의해 에어를 분사함으로써 투수블록을 공냉시킬 수 있다.Preferably, in the cooling step, water cooling is performed as the cooling tray containing each of the permeation blocks passes through the cooling water tank while being transported by the conveyor, and air is blown by the nozzle through the open upper portion of the cooling tray. By spraying, the permeation block can be air cooled.
본 발명의 다른 양태에 따르면, 상기 재생 합성수지를 이용한 투수블록의 제조방법에 의해 제조되는 투수블록으로서, 상기 투수블록은 육면체 형상을 가지며, 투수블록을 구성하고 있는 재생 합성수지와 잔골재는 3:7의 비율로 혼합되어 이루어지고, 성형시 30 ~ 40 MPa의 압력으로 가압 성형됨에 따라 공극률이 20~30%인 것을 포함하는 투수블록이 제공된다.According to another aspect of the present invention, a permeation block manufactured by the method for producing a permeation block using the recycled synthetic resin, wherein the permeation block has a hexahedral shape, the regenerated synthetic resin and the fine aggregate constituting the permeation block is 3: 7 It is made by mixing at a ratio, and when formed under pressure at a pressure of 30 to 40 MPa is provided a permeability block comprising a porosity of 20 to 30%.
본 발명의 과제의 해결수단에 따르면, 식용 용기로 사용되었던 폐합성수지를 투수블록을 제조하는데 혼합하여 사용함으로써 친환경적이다.According to the solution of the present invention, it is environmentally friendly by using a mixture of waste synthetic resin used as an edible container to prepare a water permeable block.
또한, 수지 배합비를 기존 대비 높힘으로써 강도가 강화된 투수블록을 제공할 수 있다.In addition, by increasing the resin compounding ratio compared to the existing can provide a permeable block of enhanced strength.
또한, 가압 성형시 가압력을 기존 대비 낮춤으로써 공극률을 크게할 수 있고, 이에 따라 투수효율을 높일 수 있다.In addition, the porosity can be increased by lowering the pressing force in the press molding as compared with the existing, thereby increasing the permeability efficiency.
또한, 투수블록의 냉각시간을 늘림으로써 수지가 타거나 녹는 것을 방지하여 공극막힘 현상을 방지함과 아울러 유해가스 발생도 방지할 수 있어서 작업 환경을 개선할 수 있다.In addition, by increasing the cooling time of the permeation block to prevent burning or melting of the resin to prevent the clogging of the pore and also to prevent the generation of harmful gases can improve the working environment.
도 1은 본 발명에 따른 재생 합성수지를 이용한 투수블록의 제조방법을 설명하기 위한 흐름도1 is a flowchart illustrating a method of manufacturing a pitcher block using recycled synthetic resin according to the present invention.
도 2는 본 발명에 따른 믹서 및 교반날개의 구성도2 is a block diagram of a mixer and stirring blade according to the present invention
도 3은 본 발명에 따른 투수블록의 냉각과정을 설명하기 위한 도면3 is a view for explaining the cooling process of the water permeable block according to the present invention.
도 4는 본 발명의 제조방법에 따라 제조된 투수블록의 형상도Figure 4 is a shape of the pitcher block produced according to the production method of the present invention
도 5는 본 발명에 따른 에어노즐의 일실시예를 보인 개략적 단면도5 is a schematic cross-sectional view showing an embodiment of an air nozzle according to the present invention.
본 발명은 여기서 설명되는 실시예들에 한정되지 않고 다른 형태로 구체화될 수도 있다. 오히려, 여기서 소개되는 실시예들은 개시된 내용이 철저하고 완전해질 수 있도록 그리고 당업자에게 본 발명의 사상이 충분히 전달될 수 있도록 하기 위해 제공되는 것이다. 명세서 전체에 걸쳐서 동일한 참조 번호들은 동일한 구성 요소들을 나타낸다. 한편, 본 명세서에서 사용된 용어는 실시예들을 설명하기 위한 것이며 본 발명을 제한하고자 하는 것은 아니다. 본 명세서에서, 단수형은 문구에서 특별히 언급되지 않는 한 복수형도 포함된다. 명세서에서 사용되는 "포함한다(comprises)" 및/또는 "포함하는(comprising)"은 언급된 구성 요소, 단계, 동작 및/또는 소자가 하나 이상의 다른 구성 요소, 단계, 동작 및/또는 소자의 존재 또는 추가를 배제하지 않는다.The invention is not limited to the embodiments described herein but may be embodied in other forms. Rather, the embodiments introduced herein are provided so that the disclosure may be made thorough and complete, and to fully convey the spirit of the present invention to those skilled in the art. Like reference numerals refer to like elements throughout. Meanwhile, the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. In this specification, the singular forms also include the plural unless specifically stated otherwise in the text. As used herein, "comprises" and / or "comprising" refers to the presence of one or more other components, steps, operations and / or elements in which the stated components, steps, operations and / or elements are known. Or does not exclude additions.
이하, 첨부한 도면을 참조하여 본 발명의 바람직한 실시예를 상세히 설명한다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.
도 1은 본 발명에 따른 재생 합성수지를 이용한 투수블록의 제조방법을 설명하기 위한 흐름도이다.1 is a flowchart illustrating a method of manufacturing a pitcher block using recycled synthetic resin according to the present invention.
도 1에 따르면, 본 발명에 따른 재생 합성수지를 이용한 투수블록의 제조방법은 잔골재 가열단계(S10), 잔골재 보온단계(S20), 용융단계(S30), 혼합단계(S40), 성형단계(S50) 및 냉각단계(S60)을 포함한다.According to Figure 1, the manufacturing method of the water permeable block using the recycled synthetic resin according to the present invention is the aggregate aggregate heating step (S10), fine aggregate thermal insulation step (S20), melting step (S30), mixing step (S40), molding step (S50) And cooling step (S60).
먼저, 잔골재 가열단계(S10)는 컨베이어에 의해 이송되어온 잔골재를 1차 가열로에 투입하고 이를 소정온도로 가열하는 단계이다. 상기 잔골재 가열단계는 후술될 단계에서 설명될 재생 합성수지와 잔골재를 혼합하였을 때 잔골재의 가열온도에 의해 재생 합성수지가 용융되도록 하기 위함이다.First, the fine aggregate heating step (S10) is a step of inputting the fine aggregate conveyed by the conveyor to the primary heating furnace and heating it to a predetermined temperature. The fine aggregate heating step is to allow the recycled synthetic resin to be melted by the heating temperature of the fine aggregate when the recycled synthetic resin and the fine aggregate to be described in the steps to be described later are mixed.
다음, 잔골재 보온단계(S20)는 상기 단계에서 가열된 잔골재를 2차 가열로로 투입하여 잔골재의 가열된 온도가 일정하게 유지되도록 보온하는 단계이다.Next, the fine aggregate thermal insulation step (S20) is a step of keeping the heated temperature of the fine aggregate is kept constant by inputting the fine aggregate heated in the above step into the secondary heating furnace.
다음, 용융단계(S30)는 2차 가열로로부터 배출되는 잔골재와 일정크기로 분쇄된 재생 합성수지를 용융로에 투입하여, 잔골재의 가열된 온도에 의해 재생 합성수지를 용융시키는 단계이다.Next, the melting step (S30) is a step of melting the regenerated synthetic resin by the heated temperature of the residual aggregate by inputting the residual aggregate discharged from the secondary heating furnace and the regenerated synthetic resin crushed to a certain size in the melting furnace.
여기서, 상기 용융로로 투입되는 재생 합성수지는 선별단계(S100), 분쇄단계(S200) 및 세정 및 건조단계(S300)를 거치게 된다.Here, the recycled synthetic resin introduced into the melting furnace is subjected to the sorting step (S100), the crushing step (S200) and the washing and drying step (S300).
상기 선별단계(S100)는 식음료용 용기로 사용되던 패트병(PET)을 무색, 유색 및 재질별로 선별하는 단계이고, 분쇄단계(S200)는 상기에서 선별된 재생 합성수지를 분쇄하되 직경이 0.5 ~ 2.0cm가 되도록 분쇄하는 단계이며, 세정 및 건조단계(S300)는 상기 분쇄된 재생 합성수지를 세척 및 탈수, 건조하는 단계이다.The sorting step (S100) is a step of sorting the PET bottle (PET) used as a container for food and beverage by colorless, color and material, and the grinding step (S200) is to crush the regenerated synthetic resin selected in the above, but the diameter is 0.5 ~ 2.0cm It is a step of pulverizing, and the washing and drying step (S300) is a step of washing, dehydrating and drying the pulverized regenerated synthetic resin.
특히, 상기 선별단계는 재생 합성수지 중 무색을 사용하게 되면 투명한 색상의 투수블록을 제조할 수 있고, 유색을 사용하게 되면 그에 맞는 색상의 투수블록을 제조할 수 있어서 염료를 사용하지 않고도 원하는 칼라를 얻을 수 있게 되므로 친환경적인 투수블록의 제작이 가능하고, 원가절감에도 기여된다.In particular, the screening step is to use a colorless of the recycled synthetic resin can be produced a transparent block of the transparent color, if you use a colored block can be produced according to the color of the corresponding color to obtain the desired color without using a dye This makes it possible to manufacture environmentally friendly pitching blocks and contributes to cost reduction.
다음, 혼합단계(S40)는 상기 재생 합성수지와 잔골재를 3:7의 비율로 믹서에 투입하되, 믹서 내부의 온도는 220 ~ 290℃가 되도록 가열하고, 믹서의 회전속도는 10 ~ 30rpm의 속도로 회전시켜서 잔골재와 응집제 역활을 하는 용융된 재생 합성수지를 혼합시키는 단계이다. Next, in the mixing step (S40), the recycled synthetic resin and the aggregate are added to the mixer at a ratio of 3: 7, and the temperature inside the mixer is heated to be 220 to 290 ° C, and the rotation speed of the mixer is at a speed of 10 to 30 rpm. It is a step of mixing the molten recycled synthetic resin which is rotated to serve as a fine aggregate and a flocculant.
여기서, 상기 믹서의 내부온도가 220℃ 보다 낮으면 잘 녹지 않아서 응고 될 수 있고, 반면 290℃ 보다 높으면 고열로 인하여 탈 수 있으므로 위 온도 범위로 한정하는 것이 바람직하다.Here, if the internal temperature of the mixer is lower than 220 ℃ can not solidify because it is not melted, whereas if higher than 290 ℃ can be burned due to high heat is preferably limited to the above temperature range.
또한, 상기 재생 합성수지와 잔골재의 배합비는 강도향상에 중요한 요소로서, 잔골재에 대비 재생 합성수지의 배합비가 증가할 수록 잔골재에 대한 응집력이 강해지기 때문에 강도가 강화될 수 있으나, 재생 합성수지의 배합비가 필요이상 증가하게 되면 오히려 연성이 증가하게 되어 변형의 소지가 크게 되므로 위 배합범위에서 결정되는 것이 바람직하다.In addition, the mixing ratio of the recycled synthetic resin and fine aggregates is an important factor for improving the strength, and as the mixing ratio of the recycled synthetic resins increases with respect to the fine aggregates, the cohesive strength of the fine aggregates increases, but the mixing ratio of the recycled synthetic resins is more than necessary. If it is increased, the ductility is increased to increase the possibility of deformation is preferably determined in the above compounding range.
또한, 믹서의 회전속도의 경우는 위 범위에서의 회전속도가 혼합효율이 좋다. 이 범위보다 느리게 회전하면 교반효율이 현저히 저하되고, 그렇다고 위 범위보다 빠르게 회전하더라도 교반효율이 오히려 떨어지게 되므로 위 범위 내에서 적절히 조절하는 것이 바람직하다.In addition, in the case of the rotational speed of the mixer, the rotational speed in the above range is good mixing efficiency. When the rotation is slower than this range, the stirring efficiency is significantly lowered. However, even if it is rotated faster than the above range, the stirring efficiency is lowered.
상기 믹서는 교반효율을 높이기 위해 도 2에서와 같은 형태를 가질 수 있다. 도시된 바와 같이, 상기 믹서(100)는 입구(111)와 출구(112)를 갖는 원통형의 믹서통(110)과, 상기 믹서통(110)의 내주면에 길이방향을 따라 계단형으로 배치되는 다수의 판형 또는 유선형의 교반날개(120)들로 구성될 수 있다.The mixer may have a form as in FIG. 2 to increase the stirring efficiency. As shown, the mixer 100 has a cylindrical mixer barrel 110 having an inlet 111 and an outlet 112 and a plurality of staircases arranged in the longitudinal direction on the inner circumferential surface of the mixer barrel 110. It may be composed of a plate or streamlined stirring blades 120.
여기서, 상기 각 교반날개(120)는 그 일부분, 예컨대 길이방향의 단부가 인접하는 다른 교반날개와 중첩되게 배치되는 것이 바람직하다. 스크류형의 일반적인 교반날개의 경우는 잔골재 및 용융수지가 한쪽으로 쏠리는 현상이 발생하여 원활한 교반효과를 얻기 어려운 반면, 본원의 교반날개(120)는 계단형으로 배치되는 관계로 잔골재 및 용융수지가 계단을 따라 원활하게 유동되므로 유동효율을 배가시킬 수 있고, 이로 인해 교반효율도 배가시킬 수 있게 된다.Here, each of the stirring blades 120 is preferably a portion, for example, the end of the longitudinal direction is disposed to overlap with the other stirring blades adjacent. In the case of a screw-type general stirring blade, the aggregate aggregate and the melted resin are leaned to one side, and thus, it is difficult to obtain a smooth stirring effect, whereas the stirring blade 120 of the present application is disposed in a step shape, so that the aggregate and the molten resin are staircases. Since it flows smoothly along the flow efficiency can be doubled, and thus the stirring efficiency can be doubled.
다음, 성형단계(S50)는 상기 혼합된 용융수지와 잔골재를 몰드(금형)에 일정량 투입하고, 플런저에 의해 30 ~ 40MPa의 압력으로 가압 성형하여 투수블록을 형성하는 단계이다.Next, the molding step (S50) is a step of forming a permeation block by putting a predetermined amount of the mixed molten resin and the residual aggregate into a mold (mold), and by pressure molding at a pressure of 30 ~ 40MPa by a plunger.
여기서, 중요한 요소는 가압 압력인데, 가압력이 크면 용융수지와 잔골재 사이의 공극이 치밀해 지기 때문에 공극률이 떨어지는 반면, 가압력이 작으면 용융수지와 잔골재 사이의 공극이 커지게 되므로 공극률이 증가하게 된다. 특히, 투수블록은 공극률이 커야만 배수효율이 크기 때문에 공극이 크면 클수록 좋을 수는 있겠으나, 반면 공극률이 크게 되면 강도가 약화되는 반대급부가 발생할 수 있으므로 위 가압범위를 따르게 되면 적절한 공극률과 강도가 보장될 수 있다. 위 압력으로 가압하였을 때의 공극률은 20~30%이 된다.Here, the important factor is the pressurization pressure, the larger the pressing force, the porosity is lowered because the pores between the molten resin and the fine aggregate becomes dense, while the smaller the pressing force increases the porosity between the molten resin and the fine aggregate, thereby increasing the porosity. In particular, the permeation block may be better because the larger the porosity, the larger the porosity, so the larger the porosity, the greater the porosity. Can be guaranteed. Porosity when pressurized to the above pressure is 20 to 30%.
참고로, 상기 공극률이란 잔골재의 부피를 Vs, 공극을 포함한 투수블록 전체의 부피를 V라고 할 때, 공극률 n은, n=(V-Vs)/V×100(%)의 수식에 의해 구해진 수치이다.For reference, the porosity is Vs, and when the volume of the aggregate permeation block including the void is V, the porosity n is a numerical value obtained by the formula of n = (V-Vs) / V × 100 (%). to be.
다음, 냉각단계(S60)는 상기 성형이 완료된 투수블록의 표면 및 내부를 15 ~ 20sec 동안 고르게 냉각시키는 단계이다. Next, the cooling step (S60) is a step of evenly cooling the surface and the interior of the molding block is completed for 15 to 20 seconds.
즉, 상기 냉각단계는 도 3에서와 같이, 각 투수블록(1)이 수용된 냉각 트레이(200)가 컨베이어(300)에 의해 이송되면서 냉각수조(400)를 통과함에 따라 수냉이 이루어지고, 이와 함께 상기 냉각 트레이(200)의 상부에 냉각 트레이의 이동 경로를 따라 설치되는 에어 공급관(500)의 에어노즐(510)을 통해 배출되는 에어를, 상기 냉각 트레이(200)의 개방된 상부를 통해 투수블록(1)으로 분사해 줌으로써 투수블록(1)을 공냉시키는 이중 냉각방식을 취하게 된다.That is, in the cooling step, as shown in FIG. 3, water cooling is performed as the cooling tray 200 in which the permeation block 1 is accommodated passes through the cooling water tank 400 while being transferred by the conveyor 300. Permeation block through the open upper portion of the cooling tray 200, the air discharged through the air nozzle 510 of the air supply pipe 500 is installed along the movement path of the cooling tray on the upper portion of the cooling tray 200 By spraying on (1), a double cooling method of air cooling the permeation block 1 is taken.
이에 따라, 수냉에 의해 투수블록(1)의 외부 냉각이 이루어지고, 공냉에 의해 투수블록(1)의 내부 냉각이 동시에 이루어지게 되므로 투수블록(1)의 내외부를 전반적으로 냉각시킬 수 있게 된다. Accordingly, since the external cooling of the permeation block 1 is performed by water cooling, and the internal cooling of the permeation block 1 is simultaneously performed by air cooling, the inside and outside of the permeation block 1 can be cooled overall.
냉각효율의 향상은 양생시간이 28일 이었던 기존과 비교하였을 때 양생시간을 현저히 줄일 수 있으므로 생산성 향상에 기여된다. 이와 관련하여, 앞서 설명한 바 있듯이 본 발명의 투수블록(1)은 공극률이 기존 대비 향상되었기 때문에 냉각효율을 보다 높일 수 있고, 냉각시간도 단축할 수 있게 된다.The improvement in cooling efficiency contributes to productivity improvement since the curing time can be significantly reduced compared to the existing curing time of 28 days. In this regard, as described above, the water permeability block 1 of the present invention can increase the cooling efficiency and shorten the cooling time since the porosity is improved compared to the conventional one.
한편, 도 4은 상기한 발명에 의해 제조된 투수블록의 사진이다.On the other hand, Figure 4 is a photograph of the pitcher block produced by the invention described above.
이 투수블록(1)은 앞선 제조공정에서 설명하였듯이, 육면체 형상을 가지며, 재생 합성수지와 잔골재가 3:7의 비율로 혼재되어 구성되고, 성형시 30 ~ 40MPa의 압력으로 가압 성형되어 공극률이 20 ~ 30%에 이르게 된다. 이러한 조건을 따르는 투수블록(1)은 강도와 투수효율을 모두 만족하는 제품을 얻을 수 있게 된다.As described in the foregoing manufacturing process, the permeable block 1 has a hexahedral shape, and is composed of recycled synthetic resin and fine aggregate at a ratio of 3: 7, and is press-molded at a pressure of 30 to 40 MPa to form a porosity of 20 to Up to 30%. The permeable block 1 according to these conditions can obtain a product that satisfies both strength and permeability efficiency.
한편, 에어노즐(510)은 도 5에 도시한 바와 같이 소용돌이노즐로 이루어질 수도 있다. 이 소용돌이노즐은, 에어의 분사력을 강하게 하면서도 분사되는 에어를 회전시키는 수단으로서, 그 상단부에는 에어 공급관(500)에 체결되도록 나사산을 갖는 나사산형성부(64)가 형성되고, 이 나사산형성부(64)로부터 그 아래쪽으로는 중공형이고 원추 형상을 갖는 바디부(65)가 일체로 연장 형성되는데, 이 바디부(65)에는 나선방향을 따라 에어가 최종 분사되는 홀인 다수개의 에어홀(66)이 관통 형성된다.On the other hand, the air nozzle 510 may be made of a swirl nozzle as shown in FIG. The vortex nozzle is a means for rotating the injected air while increasing the blowing force of the air. At the upper end thereof, a thread forming part 64 having a thread is formed to be fastened to the air supply pipe 500, and the thread forming part 64 is formed. From the bottom thereof, a hollow and conical body portion 65 is formed integrally extending. The body portion 65 has a plurality of air holes 66 which are holes for final injection of air along the spiral direction. It is formed through.
또한, 상기 바디부(65)의 외면에는 나선방향으로 배열된 상기 에어홀(66)과 일치되는 나선형의 에어이동안내홈(68)이 형성되며, 이 에어이동안내홈(68)은 에어홀(66)로부터 분사되는 에어의 분사방향을 나선방향으로 안내하여 소용돌이를 형성하는 역할을 한다.In addition, the outer surface of the body portion 65 is formed with a spiral air groove inner groove 68 coinciding with the air holes 66 arranged in a spiral direction, the air groove inner groove 68 is an air hole ( 66 to guide the jet direction of the air jetted from the spiral direction to form a vortex.
이에, 상기 소용돌이노즐의 에어홀(66) 및 나선형의 에어이동안내홈(68)을 통해 분사되는 에어가 회전하는 동시에 소용돌이를 형성하면서 에어를 분사함으로써, 투수블록(1)에 골고루 분사되면서 투수블록(1) 전체를 고르게 냉각시키게 된다.Accordingly, the air injected through the air hole 66 of the vortex nozzle and the spiral air while the inner groove 68 rotates and simultaneously sprays air while forming a vortex, thereby evenly spraying the permeable block 1 while the permeable block (1) The whole is cooled evenly.
또한, 교반날개(120)의 둘레에는 오염물질의 부착방지 및 제거를 효과적으로 달성할 수 있도록 오염 방지 도포용 조성물이 도포된 오염방지도포층이 형성될 수 있다. 상기 오염 방지 도포용 조성물은 과산화수소 및 메타규산나트륨이 1:0.01 ~ 1:2 몰비로 포함되어 있고, 과산화수소 및 메타규산나트륨의 총함량은 전체 수용액에 대해 1 ~ 10 중량%이다. 이에 더하여, 상기 오염방지도포층의 도포성을 향상시키는 물질로 메타규산나트륨 또는 탄산칼슘이 이용될 수 있으나 바람직하게는 메타규산나트륨이 이용될 수 있다. 상기 과산화수소 및 메타규산나트륨은 몰비로서 1:0.01 ~ 1:2가 바람직한 바, 몰비가 상기 범위를 벗어나는 경우에는 기재의 도포성이 저하되거나 도포후 표면의 수분흡착이 증가하여 도포막이 제거되는 문제점이 있다.In addition, the anti-fouling coating layer coated with the anti-fouling coating composition may be formed around the stirring vane 120 to effectively achieve the prevention and removal of contaminants. The antifouling coating composition includes hydrogen peroxide and sodium metasilicate in a 1: 0.01 to 1: 2 molar ratio, and the total content of hydrogen peroxide and sodium metasilicate is 1 to 10% by weight based on the total aqueous solution. In addition, sodium metasilicate or calcium carbonate may be used as a material for improving the coatability of the antifouling coating layer, but preferably sodium metasilicate may be used. The hydrogen peroxide and sodium metasilicate are preferably 1: 0.01 to 1: 2 as the molar ratio. If the molar ratio is out of the above range, the coating property of the substrate may be reduced or the moisture absorption of the surface may be increased after application, thereby removing the coating film. have.
상기 과산화수소 및 메타규산나트륨은 전제 조성물 수용액중 1 ~ 10 중량%가 바람직한 바, 1 중량% 미만이면 기재의 도포성이 저하되는 문제점이 있고, 10 중량%를 초과하면 도포막 두께의 증가로 인한 결정석출이 발생하기 쉽다.The hydrogen peroxide and sodium metasilicate are preferably 1 to 10% by weight of the total composition aqueous solution, if less than 1% by weight has a problem that the applicability of the substrate is lowered, if it exceeds 10% by weight crystal due to the increase in the coating film thickness Precipitation is likely to occur.
상기 오염 방지 도포용 조성물을 기재 상에 도포하는 방법으로는 스프레이법에 의해 도포하는 것이 바람직하다. 또한, 상기 교반날개(120) 상의 최종 도포막 두께는 500~2000Å이 바람직하며, 보다 바람직하게는 1000 ~ 2000 Å이다. 상기 도포막의 두께가 500 Å미만이면 고온 열처리의 경우에 열화되는 문제점이 있고, 2000 Å을 초과하면 도포 표면의 결정석출이 발생하기 쉬운 단점이 있다.It is preferable to apply | coat by the spray method as a method of apply | coating the said antifouling coating composition on a base material. In addition, the final coating film thickness on the stirring blade 120 is preferably 500 to 2000 kPa, more preferably 1000 to 2000 kPa. If the thickness of the coating film is less than 500 kPa, there is a problem of deterioration in the case of high temperature heat treatment, and if the thickness of the coating film exceeds 2000 kPa, crystal precipitation of the coated surface is liable to occur.
또한, 오염 방지 도포용 조성물은 과산화수소 0.1 몰 및 메타규산나트륨 0.05 몰을 증류수 1000 ㎖에 첨가한 다음 교반하여 제조될 수 있다.In addition, the antifouling coating composition may be prepared by adding 0.1 mol of hydrogen peroxide and 0.05 mol of sodium metasilicate to 1000 ml of distilled water, followed by stirring.
그리고, 냉각수조(400)는, 먼지, 오염물질 등으로부터 표면의 부식현상을 방지시키기 위해 금속재의 표면 도포재료로 표면보호도포층이 형성될 수 있다. 이 표면보호도포층은 지르코늄 분말 2.5중량%, 알루미나 분말 60중량%, NH4Cl 30중량%, 아연 2.5중량%, 마그네슘 2.5중량%, 티타늄 2.5중량%로 구성된다.In addition, the cooling bath 400 may be formed of a surface protective coating layer of a surface coating material of a metal material in order to prevent corrosion of the surface from dust, contaminants, and the like. The surface protective coating layer is composed of 2.5% by weight zirconium powder, 60% by weight alumina powder, 30% by weight NH 4 Cl, 2.5% by weight zinc, 2.5% by weight magnesium and 2.5% by weight titanium.
상기 지르코늄 분말은, 내식성, 내열성이 뛰어나다. 이러한 지르코늄 분말은 2.5중량% 혼합된다. 지르코늄 분말의 혼합 비율이 2.5중량% 미만이면, 내식성, 내열성이 크게 개선되지 않는다. 반면에, 지르코늄 분말의 혼합 비율이 2.5중량%를 초과하면 상술한 효과는 더 개선되지 않는 반면에 재료비는 크게 증가된다. 따라서 티타늄은 2.5중량% 혼합되는 것이 바람직하다.The zirconium powder is excellent in corrosion resistance and heat resistance. This zirconium powder is mixed at 2.5% by weight. If the mixing ratio of the zirconium powder is less than 2.5% by weight, the corrosion resistance and the heat resistance are not greatly improved. On the other hand, if the mixing ratio of the zirconium powder exceeds 2.5% by weight, the above-mentioned effect is not improved further while the material cost is greatly increased. Therefore, the titanium is preferably mixed 2.5% by weight.
상기 알루미나 분말은 고온으로 가열될 때 소결, 엉킴, 융착 방지 등의 목적으로 첨가된다. 이러한 알루미나 분말이 60중량% 미만으로 첨가되면, 소결, 엉킴, 융착 방지의 효과가 떨어지며, 알루미나 분말이 60중량%를 초과하면 상술한 효과는 더 개선되지 않는 반면에, 재료비가 크게 증가된다. 따라서, 알루미나 분말은 60중량%를 첨가하는 것이 바람직하다.The alumina powder is added for the purpose of sintering, tangling, fusion prevention, etc. when heated to a high temperature. When the alumina powder is added in less than 60% by weight, the effect of sintering, tangling and fusion prevention is inferior, and when the alumina powder exceeds 60% by weight, the above-mentioned effect is not further improved, while the material cost is greatly increased. Therefore, it is preferable to add 60 weight% of alumina powders.
상기 NH4Cl은 증기 상태의 아연, 마그네슘과 반응하여 확산 및 침투를 활성화시키는 역할을 한다. 이러한 NH4Cl은 30중량% 첨가된다. NH4Cl이 30중량% 미만으로 첨가되면, 증기 상태의 아연, 마그네슘과 반응이 제대로 이루어지지 않으며 이에 따라 확산 및 침투를 활성화시키지 못한다. 반면에, NH4Cl이 30중량% 초과하면 상술한 효과는 더 개선되지 않는 반면에, 재료비가 크게 증가된다. 따라서 NH4Cl은 30중량%를 첨가하는 것이 바람직하다.The NH 4 Cl reacts with zinc and magnesium in a vapor state to serve to activate diffusion and penetration. This NH 4 Cl is added 30% by weight. If NH 4 Cl is added at less than 30% by weight, it does not react properly with the vaporized zinc and magnesium and thus does not activate diffusion and penetration. On the other hand, when NH 4 Cl exceeds 30% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, it is preferable to add 30% by weight of NH 4 Cl.
상기 아연은 물에 닿는 금속의 부식을 방지하는 것과 전기 방식용으로 사용되도록 배합된다. 이러한 아연은 2.5중량%가 혼합된다. 아연의 혼합비율이 2.5중량%를 초과하면 물에 닿는 금속의 부식을 제대로 방지시키지 못하게 된다. 반면에 아연의 혼합비율이 2.5중량%를 초과하면 상술한 효과는 더 개선되지 않는 반면에 재료비가 크게 증가된다. 따라서 아연은 2.5중량% 혼합되는 것이 바람직하다.The zinc is formulated to prevent corrosion of metals in water and to be used for electrical applications. This zinc is mixed 2.5% by weight. If the mixing ratio of zinc exceeds 2.5% by weight, it will not properly prevent corrosion of the metal on water. On the other hand, when the mixing ratio of zinc exceeds 2.5% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, the zinc is preferably mixed 2.5% by weight.
상기 마그네슘의 순수한 금속은 구조강도가 낮으므로 상기 아연 등과 함께 조합하여 금속의 경도, 인장강도 및 염수에 대한 내식성을 높이는 용도로 배합된다. 이러한 마그네슘은 2.5중량% 혼합된다. 마그네슘의 혼합 비율이 2.5중량% 미만이면, 아연 등과 함께 조합될 시 금속의 경도, 인장강도 및 염수에 대한 내식성이 크게 개선되지 않는다. 반면에 마그네슘의 혼합 비율이 2.5중량%를 초과하면 상술한 효과는 더 개선되지 않는 반면에 재료비가 크게 증가된다. 따라서 마그네슘는 2.5중량% 혼합되는 것이 바람직하다.Since the pure metal of magnesium has a low structural strength, the magnesium is combined with zinc to increase the hardness, tensile strength and corrosion resistance of the metal. This magnesium is mixed 2.5% by weight. If the mixing ratio of magnesium is less than 2.5% by weight, the hardness, tensile strength and corrosion resistance to salt water of the metal when combined with zinc and the like are not significantly improved. On the other hand, when the mixing ratio of magnesium exceeds 2.5% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, magnesium is preferably mixed at 2.5% by weight.
상기 티타늄은 가볍고 단단하고 내부식성이 있는 전이 금속 원소로 은백색의 금속광택이 있는바, 뛰어난 내식성과 비중이 낮아 강철 대비 무게는 60% 밖에 되지 않으므로 금속모재에 도포되는 도포재의 중량은 줄이되 광택을 높이고 뛰어난 방수성 및 내식성을 갖도록 배합된다.The titanium is a light, hard and corrosion-resistant transition metal element has a silver-white metallic luster, and because of its excellent corrosion resistance and low specific gravity, the weight of the titanium is only 60% compared to steel, so that the weight of the coating material applied to the metal base material is reduced but the gloss is increased. It is formulated to have excellent waterproof and corrosion resistance.
이러한 티타늄은 2.5중량% 혼합된다. 티타늄의 혼합 비율이 2.5중량% 미만이면, 금속모재에 도포되는 도포재의 중량이 그다지 경감되지 않고, 광택성, 방수성, 내식성이 크게 개선되지 않는다. 반면에, 티타늄의 혼합 비율이 2.5중량%를 초과하면 상술한 효과는 더 개선되지 않는 반면에 재료비는 크게 증가된다. 따라서 티타늄은 2.5중량% 혼합되는 것이 바람직하다.This titanium is mixed 2.5% by weight. When the mixing ratio of titanium is less than 2.5% by weight, the weight of the coating material applied to the metal base material is not so much reduced, and the glossiness, waterproofness, and corrosion resistance are not greatly improved. On the other hand, if the mixing ratio of titanium exceeds 2.5% by weight, the above-mentioned effect is not further improved while the material cost is greatly increased. Therefore, the titanium is preferably mixed 2.5% by weight.
본 발명에 따른 냉각수조(400)의 표면 도포방법은 다음과 같다.The surface coating method of the cooling water tank 400 according to the present invention is as follows.
표면보호도포층이 형성되어야 할 냉각수조(400)와 상기 구성으로 배합된 도포재료를 폐쇄로 내에 함께 투입시키고 폐쇄로 내부에는 냉각수조(400)의 산화를 방지하기 위하여 2 L/min의 비율로 아르곤 가스를 주입시킨다, 아르곤 가스가 주입된 상태에서 700℃ 내지 800℃의 온도로 4 ~ 5 시간 동안 유지한다.In order to prevent the oxidation of the cooling water tank 400, the cooling water tank 400 to which the surface protective coating layer is to be formed and the coating material blended in the above configuration are put together in the closing furnace. Argon gas is injected, and maintained at a temperature of 700 ° C to 800 ° C for 4 to 5 hours while argon gas is injected.
상기 단계를 수행하여 증기 상태의 지르코늄 분말, 알루미나 분말, 아연, 마그네슘 및 티타늄이 폐쇄로 내부에 형성되고, 지르코늄 분말, 알루미나 분말, 아연, 마그네슘 및 티타늄 배합물은 모재의 표면에 침투하여 표면보호도포층이 형성된다.By performing the above steps, the zirconium powder, alumina powder, zinc, magnesium, and titanium in a vapor state are formed inside the closure, and the zirconium powder, alumina powder, zinc, magnesium, and titanium blend penetrate the surface of the base material to provide a surface protective coating layer. Is formed.
표면보호도포층이 형성된 후 폐쇄로 내부의 온도를 도포 물질/기재 복합물이 800℃~900℃로 하여 30 ~ 40시간을 유지하면 냉각수조(400)의 표면에는 부식 방지용 표면보호도포층이 형성되어 냉각수조(400)의 표면과 외기를 격리시키게 된다. 이때 상기 공정을 수행함에 있어 급격한 온도 변화는 냉각수조(400) 표면의 표면보호도포층이 박리될 수 있으므로 60℃/hr의 비율로 온도 변화를 시킨다.After the surface protective coating layer is formed, the internal temperature of the coating material / substrate composite is maintained at 800 ° C. to 900 ° C. for 30 to 40 hours, and the surface protection coating layer for preventing corrosion is formed on the surface of the cooling water tank 400. The surface of the cooling water tank 400 and the outside air is isolated. At this time, in performing the process, the temperature change is rapid because the surface protective coating layer of the surface of the cooling water tank 400 may be peeled off.
본 발명의 표면보호도포층은 다음과 같은 장점이 있다. The surface protective coating layer of the present invention has the following advantages.
본 발명의 표면보호도포층은 매우 넓은 범위의 용도를 가지므로 커튼 도포, 스프레이 페인팅, 딥 도포, 플루딩(flooding) 등과 같은 여러 가지 방법에 의해 도포될 수 있다.Since the surface protective coating layer of the present invention has a very wide range of uses, it can be applied by various methods such as curtain coating, spray painting, dip coating, flooding, and the like.
본 발명의 표면보호도포층은 부식 및/또는 스케일에 대한 원칙적인 보호 기능에 추가하여 도포가 매우 얇은 층두께로 도포될 수 있어 전기전도성을 개선하는 것은 물론 물질 및 비용 절감이 가능하다. 열간 성형 과정 이후에도 높은 전기전도성이 바람직하다면 얇은 전기전도성 프라이머가 도포층의 상부에 도포될 수 있다.The surface protective coating layer of the present invention can be applied with a very thin layer thickness in addition to the principle protection against corrosion and / or scale, thereby improving the electrical conductivity as well as material and cost savings. Even after hot forming, a thin electroconductive primer may be applied on top of the application layer if high electrical conductivity is desired.
성형 과정 또는 열간 성형 과정 이후, 도포 물질은 기재의 표면상에 유지될 수 있으며, 예를 들어, 긁힘 내성을 증가시키며, 부식 보호를 개선하고, 미적 외관을 충족시키며, 변색을 방지하고, 전기전도성을 변화시키며 종래 다운스트림 공정(예, 침린 및 전기이동 딥 도포)용 프라이머로 제공될 수 있다.After the forming process or the hot forming process, the coating material may be retained on the surface of the substrate, for example, to increase scratch resistance, to improve corrosion protection, to meet aesthetic appearance, to prevent discoloration, and to be electrically conductive. And can be provided as a primer for conventional downstream processes (eg, dip and electrophoretic dip coating).
이러한 본 발명의 냉각수조(400)에 지르코늄 분말, 알루미나 분말, NH4Cl, 아연, 마그네슘, 티타늄으로 이루어진 표면보호도포층이 도포되므로 먼지, 오염물질 등으로부터 냉각수조(400)의 표면의 부식현상을 방지시킬 수 있다.Since a surface protective coating layer made of zirconium powder, alumina powder, NH 4 Cl, zinc, magnesium, and titanium is applied to the cooling water tank 400 of the present invention, corrosion of the surface of the cooling water tank 400 from dust, contaminants, etc. Can be prevented.
이상 본 발명을 구체적인 실시예를 통하여 상세히 설명하였으나, 이는 본 발명을 구체적으로 설명하기 위한 것으로, 본 발명은 이에 한정되지 않으며, 본 발명의 기술적 사상 내에서 당 분야의 통상을 지식을 가진 자에 의해 그 변형이나 개량이 가능함이 명백하다.Although the present invention has been described in detail through specific examples, this is for explaining the present invention in detail, and the present invention is not limited thereto, and a person having ordinary skill in the art within the technical idea of the present invention. It is obvious that modifications and improvements are possible.
본 발명의 단순한 변형 내지 변경은 모두 본 발명의 범주에 속하는 것으로 본 발명의 구체적인 보호 범위는 첨부된 특허청구범위에 의해 명확해질 것이다.Simple modifications and variations of the present invention are all within the scope of the present invention, and the specific scope of protection of the present invention will be apparent from the appended claims.

Claims (5)

  1. 잔골재를 1차 가열로에 투입하여 잔골재를 소정온도로 가열하는 잔골재 가열단계(S10);Residual aggregate heating step (S10) for inputting the fine aggregate into the primary heating furnace to heat the fine aggregate to a predetermined temperature;
    상기 가열된 잔골재를 2차 가열로로 투입하여 잔골재의 가열된 온도가 일정하게 유지되도록 보온하는 잔골재 보온단계(S20);Residual aggregate warming step (S20) to insulate the heated fine aggregate into a secondary heating furnace to keep the heated temperature of the fine aggregate constant;
    상기 2차 가열로로부터 배출되는 잔골재와 일정크기로 분쇄된 재생 합성수지를 융용로에 투입하여, 잔골재의 온도에 의해 재생 합성수지를 용융시키는 용융단계(S30);A melting step (S30) of melting the regenerated synthetic resin by the temperature of the fine aggregate by inputting the fine aggregate discharged from the secondary heating furnace and the regenerated synthetic resin pulverized to a predetermined size into the melting furnace;
    상기 용융수지와 잔골재를 믹서에 투입하되, 믹서 내부의 온도는 220 ~ 290℃가 되도록 가열하고, 믹서의 회전속도는 10 ~ 30rpm의 속도로 회전시켜서 잔골재와 용융된 재생 합성수지를 혼합시키는 혼합단계(S40);Mixing the molten resin and the fine aggregate into the mixer, the temperature inside the mixer is heated to 220 ~ 290 ℃, and the rotation speed of the mixer is rotated at a speed of 10 ~ 30rpm to mix the fine aggregate and the molten recycled synthetic resin ( S40);
    상기 혼합된 용융수지와 잔골재를 몰드에 투입하고, 30 ~ 40MPa의 압력으로 가압 성형하여 투수블록을 성형하는 성형단계(S50); 및A molding step of inserting the mixed molten resin and the remaining aggregate into a mold and molding a permeable block by pressure molding at a pressure of 30 to 40 MPa; And
    상기 성형된 투수블록의 표면 및 내부를 15 ~ 20sec 동안 고르게 냉각시키는 냉각단계(S60);Cooling step (S60) to evenly cool the surface and the inside of the molded water permeable block for 15 ~ 20sec;
    를 포함하는 재생 합성수지를 이용한 투수블록의 제조방법.Method for producing a pitcher block using a recycled synthetic resin comprising a.
  2. 청구항 1에 있어서,The method according to claim 1,
    상기 재생 합성수지는 식음료용 용기로 사용되는 패트병을 무색, 유색 및 재질별로 선별하는 선별단계(S100);The regeneration synthetic resin screening step of selecting the plastic bottle used as a container for food and beverage by colorless, colored and materials (S100);
    상기 선별된 재생 합성수지를 분쇄하되, 직경이 0.5 ~ 2.0cm가 되도록 분쇄하는 분쇄단계(S200); 및Grinding the selected recycled synthetic resin, the grinding step of grinding to a diameter of 0.5 ~ 2.0cm (S200); And
    상기 분쇄된 재생 합성수지를 세척 및 탈수, 건조하는 세정 및 건조단계(S300);를 거쳐 상기 용융로에 투입되는 것을 특징으로 하는 재생 합성수지를 이용한 투수블록의 제조방법.Washing and dehydration of the pulverized regenerated synthetic resin, drying and washing step (S300); through the manufacturing method of the water permeable block using the regenerated synthetic resin, characterized in that the input to the melting furnace.
  3. 청구항 1에 있어서,The method according to claim 1,
    상기 혼합단계에서 사용되는 믹서(100)는, 원통형의 믹서통(110)과, 상기 믹서통(110)의 내주면에 길이방향을 따라 계단형으로 배치되는 다수의 교반날개(120)를 포함하되, 상기 각 교반날개(120)는 그 일부분이 인접한 교반날개와 중첩되게 배치되는 것을 특징으로 하는 재생 합성수지를 이용한 투수블록의 제조방법.The mixer 100 used in the mixing step includes a cylindrical mixer cylinder 110 and a plurality of stirring blades 120 arranged in a step shape along the longitudinal direction on the inner circumferential surface of the mixer cylinder 110, Each of the stirring blades 120 is a part of the manufacturing method of the pitcher block using the regenerated synthetic resin, characterized in that the overlap is disposed overlapping with the stirring blades.
  4. 청구항 1에 있어서,The method according to claim 1,
    상기 냉각단계(S60)는, 상기 각 투수블록(1)이 수용된 냉각 트레이(200)가 컨베이어(300)에 의해 이송되면서 냉각수조(400)를 통과함에 따라 수냉이 이루어지고, 이와 함께, 상기 냉각 트레이(200)의 개방된 상부를 통해 에어노즐(510)에 의해 에어를 분사함으로써 투수블록(1)을 공냉시키는 것을 특징으로 하는 재생 합성수지를 이용한 투수블록의 제조방법.In the cooling step (S60), water cooling is performed as the cooling trays 200 in which the permeation blocks 1 are accommodated pass through the cooling water tank 400 while being transported by the conveyor 300, and together with the cooling, Method for producing a water permeable block using a recycled synthetic resin, characterized in that for cooling the water permeable block (1) by injecting air by the air nozzle (510) through the open upper portion of the tray (200).
  5. 청구항 1 내지 4항 중, 어느 한 항에 있어서,The method according to any one of claims 1 to 4,
    상기 재생 합성수지를 이용한 투수블록의 제조방법에 의해 제조되는 투수블록으로서, 상기 투수블록은 육면체 형상을 가지며, 투수블록을 구성하고 있는 재생 합성수지와 잔골재는 3:7의 비율로 혼합되어 이루어지고, 성형시 30 ~ 40 MPa의 압력으로 가압 성형됨에 따라 공극률이 20~30%인 것을 포함하는 투수블록.A permeable block manufactured by the method for producing a permeable block using the recycled synthetic resin, wherein the permeable block has a hexahedral shape, and the recycled synthetic resin and the fine aggregate constituting the permeable block are mixed at a ratio of 3: 7, and formed Permeable block comprising a porosity of 20 to 30% as it is pressure-molded at a pressure of 30 to 40 MPa.
PCT/KR2018/000815 2017-04-03 2018-01-17 Method for producing water-permeable block using recycled synthetic resin, and water-permeable block produced by said method WO2018186567A1 (en)

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KR101772847B1 (en) * 2017-04-03 2017-08-30 김태현 A method of manufacturing a water permeable block using a regenerated synthetic resin and a water permeable block
KR102177602B1 (en) * 2019-08-30 2020-11-11 에코블럭 주식회사 Recycling assembly type temporary pavement block
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