WO2018186568A1 - Water-permeable block production system using recycled synthetic resin - Google Patents

Water-permeable block production system using recycled synthetic resin Download PDF

Info

Publication number
WO2018186568A1
WO2018186568A1 PCT/KR2018/000817 KR2018000817W WO2018186568A1 WO 2018186568 A1 WO2018186568 A1 WO 2018186568A1 KR 2018000817 W KR2018000817 W KR 2018000817W WO 2018186568 A1 WO2018186568 A1 WO 2018186568A1
Authority
WO
WIPO (PCT)
Prior art keywords
cooling
synthetic resin
fine aggregate
water
mixer
Prior art date
Application number
PCT/KR2018/000817
Other languages
French (fr)
Korean (ko)
Inventor
김태현
Original Assignee
김태현
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 김태현 filed Critical 김태현
Priority to CN201880004867.0A priority Critical patent/CN110049852B/en
Publication of WO2018186568A1 publication Critical patent/WO2018186568A1/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/003Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B13/00Conditioning or physical treatment of the material to be shaped
    • B29B13/02Conditioning or physical treatment of the material to be shaped by heating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • B29B17/0412Disintegrating plastics, e.g. by milling to large particles, e.g. beads, granules, flakes, slices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/02Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type
    • B29B7/06Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices
    • B29B7/10Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/80Component parts, details or accessories; Auxiliary operations
    • B29B7/82Heating or cooling
    • B29B7/823Temperature control
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/80Component parts, details or accessories; Auxiliary operations
    • B29B7/88Adding charges, i.e. additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/52Heating or cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/26Scrap or recycled material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0068Permeability to liquids; Adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/10Building elements, e.g. bricks, blocks, tiles, panels, posts, beams
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Definitions

  • the present invention relates to a permeation block manufacturing system using a waste container used as a recycled synthetic resin, for example, a food and beverage container, and more particularly, to produce a permeation block having a high porosity and a high porosity, and to prevent pore clogging and harmful gases.
  • the present invention relates to a permeable block manufacturing system using recycled synthetic resin that provides an environment-friendly working environment due to a low generation amount.
  • the conventionally developed permeation method is mainly a method using a permeation block, and forms a permeation block using natural aggregate or recycled aggregate and cement mixture.
  • the main object of the present invention is to mix the waste synthetic resin used as an edible container to prepare a water permeable block, but to enhance the strength by increasing the resin compounding ratio, Permeability block by reducing pressing force to increase porosity and increase cooling time of permeation block to prevent burning or melting of resin to prevent pore blockage and to prevent harmful gas generation To provide a manufacturing system.
  • a transfer conveyor for transporting the fine aggregate discharged from the hopper is stored fine aggregate;
  • a secondary heating furnace configured to be in communication with an outlet of the primary heating furnace to insulate the residual aggregate in a heating state provided from the primary heating furnace to maintain a constant temperature thereof;
  • a pressure molding machine for press-molding the mixture of the molten resin and the fine aggregate provided from the mixer at a pressure of 30 to 40 MPa;
  • a permeable block manufacturing system using a recycled synthetic resin comprising a; and a cooler for dual
  • the mixer comprises a cylindrical mixer barrel; It includes a plurality of stirring blades arranged in a step shape along the longitudinal direction on the inner circumferential surface of the mixer barrel, each of the stirring blades may be disposed so that a portion thereof overlaps with the adjacent stirring blades.
  • the cooler the cooling tray for receiving each water permeation block discharged from the pressure molding machine;
  • a horizontal cooling water tank configured to immerse the cooling tray in the cooling water and to cool the water while being installed under the cooling tray containing the water permeable block;
  • a transport conveyor for transporting the cooling tray along the longitudinal direction of the cooling water tank;
  • An air supply pipe installed above the cooling tray along a moving direction of the cooling tray;
  • an air nozzle disposed at predetermined intervals on the air supply pipe to inject air in the air supply pipe toward the permeation block to cool the permeation block.
  • the porosity can be increased by lowering the pressing force in the press molding as compared with the existing, thereby increasing the permeability efficiency.
  • FIG. 1 is a block diagram of a pitcher block manufacturing system using a recycled synthetic resin according to the present invention
  • FIG. 2 is a block diagram of a mixer which is one configuration of a system according to the present invention.
  • FIG. 3 is a configuration diagram of a cooler that is one configuration of another system according to the present invention.
  • FIG. 4 is a flow chart for explaining a method of manufacturing a pitcher block using a pitcher block manufacturing system using a recycled synthetic resin according to the present invention.
  • FIG. 5 is a shape diagram of a pitcher block manufactured according to the system of the present invention.
  • Figure 6 is a schematic cross-sectional view showing an embodiment of an air nozzle according to the present invention.
  • FIG. 1 is a block diagram of a pitcher block manufacturing system using a recycled synthetic resin according to the present invention.
  • the permeation block manufacturing system using the recycled synthetic resin according to the present invention the transfer conveyor 100, the primary heating furnace 200, the secondary heating furnace 300, the melting furnace 400, the mixer 500 , A press molding machine 600 and a cooler 700.
  • the transfer conveyor 100 serves to transfer the fine aggregate discharged from the hopper 10 in which the fine aggregate is stored to the primary heating furnace 200.
  • the primary furnace 200 is rotatably supported by the frame, and serves to heat the aggregate aggregate transported through the transfer conveyor 100 to a predetermined temperature, the primary furnace 200 is a recycled synthetic resin When the fine aggregate is mixed with the fine aggregate, the fine aggregate is preheated in order to melt the regenerated synthetic resin by the heating temperature of the fine aggregate.
  • the secondary heating furnace 300 is insulated in communication with the outlet of the primary heating furnace 200 to keep the heated aggregate provided from the primary heating furnace 200 to maintain its temperature constant. Role. At this time, the secondary heating furnace 300 has an installation structure in which the outlet is installed obliquely downwardly inclined from the inlet so that the fine aggregate in the secondary heating furnace can be naturally discharged toward the outlet.
  • the melting furnace 400 is installed at the outlet side of the secondary heating furnace 300, and the heated aggregate provided from the secondary heating furnace 300 and the pulverized recycled synthetic resin are introduced together to be heated by the heated aggregate. It plays a role to make recycled synthetic resin melt.
  • the diameter of the recycled synthetic resin introduced into the melting furnace 400 is suitable for 0.5 ⁇ 2.0cm.
  • the recycled synthetic resin is introduced into the melting furnace 400 through the process of sorting, pulverizing, washing and drying.
  • the sorting is a process for sorting the PET bottles (PET) used as food and beverage containers by colorless, colored, and materials, and the grinding is to grind the recycled synthetic resin selected from the above to be 0.5 to 2.0cm in diameter.
  • Washing and drying are operations for washing, dehydrating and drying the pulverized recycled synthetic resin.
  • using colorless of the selected recycled synthetic resin can produce a transparent color permeable block, if using a color can be prepared a permeable block of the color corresponding to it so that the desired color can be obtained without using a dye Therefore, it is possible to manufacture environmentally friendly pitching block, and contribute to cost reduction.
  • the mixer 500 serves to stir and mix the molten resin and the fine aggregate provided from the melting furnace 400, as shown in FIG. 2, and a cylindrical mixer cylinder 510 having an inlet 511 and an outlet 512. ), And a plurality of plate-shaped or streamlined stir blades 520 disposed on the inner circumferential surface of the mixer barrel 510 along the longitudinal direction.
  • each of the stirring blades 520 is preferably disposed so that a portion thereof, for example, an end portion in the longitudinal direction overlaps with another adjacent stirring blade (o).
  • the stirring blade 520 of the present invention is disposed in a stepped shape, so that the aggregate and the melted resin are The smooth flow along the stairs can double the flow efficiency, thereby doubling the stirring efficiency.
  • the recycled synthetic resin and the aggregate aggregate is added to the mixer 500 at a ratio of 3: 7, the temperature inside the mixer is heated to 220 ⁇ 290 °C, the speed of the mixer at a speed of 10 ⁇ 30rpm It is preferable to rotate.
  • the internal temperature of the mixer 500 When the internal temperature of the mixer 500 is lower than 220 ° C., the internal temperature of the mixer 500 may not solidify, and if the internal temperature of the mixer 500 is higher than 290 ° C., the internal temperature of the mixer 500 may be burned due to high heat.
  • the mixing ratio of the recycled synthetic resin and fine aggregates is an important factor for improving the strength, and as the mixing ratio of the recycled synthetic resins increases with respect to the fine aggregates, the cohesive strength of the fine aggregates increases, but the mixing ratio of the recycled synthetic resins is more than necessary If it is increased, the ductility is increased to increase the possibility of deformation is preferably determined in the above compounding range.
  • the rotational speed in the above range is good mixing efficiency.
  • the stirring efficiency is significantly lowered.
  • the stirring efficiency is lowered.
  • the mixer 500 is provided with first and second burners 530 and 540 for heating the inside of the mixer at both end portions thereof, and a heating wire 550 is provided on the wall surface of the mixer barrel 510 so that the mixer 500 is provided with first and second burners.
  • the burner will heat up the inside of the mixer.
  • the reason why the burner and the heating wire are combined is that it is difficult to evenly heat the burner alone, so even heating is possible by reinforcing the heating wire, and supplementing the heating wire can save electric energy rather than installing several burners. to be.
  • the pressure molding machine 600 is a pressure molding of the mixture of the molten resin and the fine aggregate provided from the mixer 500 at a pressure of 30 ⁇ 40MPa by the plunger 610.
  • the important factor is the pressurization pressure, the larger the pressing force, the porosity is lowered because the pores between the molten resin and the fine aggregate becomes dense, while the smaller the pressing force increases the porosity between the molten resin and the fine aggregate, thereby increasing the porosity.
  • the permeation block may be better because the larger the porosity, the larger the porosity, so the larger the porosity, the greater the porosity. Can be guaranteed.
  • Porosity when pressurized to the above pressure is 20 to 30%.
  • the cooler 700 is dual cooling for 15 to 20 sec by water and air cooling while conveying the water permeable block 1 formed by the pressure molding machine 600, as shown in FIG. 3, in the pressure molding machine 600
  • Cooling tray 710 for accommodating each of the discharged water permeation block (1), and horizontal cooling water for cooling the water by immersing the cooling tray in the cooling water while being installed in the lower portion of the cooling tray 710 containing the water permeable block (1)
  • the air supply pipe 740 and a plurality of air nozzles 750 which are arranged at regular intervals on the air supply pipe to inject air in the air supply pipe toward the permeation block to cool the permeation block.
  • the external cooling of the permeation block 1 is performed by water cooling, and the internal cooling of the permeation block 1 is simultaneously performed by air cooling, thereby allowing the inside and outside of the permeation block 1 to be cooled down evenly.
  • the improvement in cooling efficiency contributes to productivity improvement since the curing time can be significantly reduced compared to the existing curing time of 28 days.
  • the water permeability block 1 of the present invention can increase the cooling efficiency and shorten the cooling time since the porosity is improved compared to the conventional one.
  • Residual aggregate heating step (S10) which is a first step, is a step of inputting the residual aggregate transferred by the transfer conveyor 100 to the primary heating furnace 200 and heating it to a predetermined temperature.
  • Residual aggregate warming step (S20) is a step of keeping the heated temperature of the aggregate remains constant by inputting the residual aggregate heated in the first step into the secondary heating furnace (300).
  • Melting step (S30) of the third step is a step of melting the regenerated synthetic resin by the heated temperature of the residual aggregate by inputting the fine aggregate discharged from the secondary heating furnace 300 and the recycled synthetic resin crushed to a predetermined size into the melting furnace 400 to be.
  • the recycled synthetic resin introduced into the melting furnace 400 is subjected to the sorting step (S100), the crushing step (S200) and the washing and drying step (S300).
  • Mixing step (S40), which is the fourth step, is added to the mixer in the ratio of the recycled synthetic resin and the fine aggregate 3: 7, the temperature inside the mixer 500 is heated to 220 ⁇ 290 °C, the mixer 500 Rotational speed is a step of mixing the molten recycled synthetic resin serving as a coagulant and the aggregate by rotating at a speed of 10 ⁇ 30rpm.
  • Step 5 is a step of forming a permeable block by putting a predetermined amount of the mixed molten resin and fine aggregate into the pressure molding machine 600, by pressing the pressure of 30 ⁇ 40MPa by the plunger 610. .
  • the cooling step (S60), which is a sixth step, is a step of evenly cooling the surface and the inside of the permeation block 1 on which the molding is completed for 15 to 20 seconds.
  • the cooling tray 710 containing each of the permeation blocks 1 passes through the cooling water tank 720 while being transported by the conveyor 730, and thus water cooling is performed. Air is injected by the nozzle 750 through the open upper portion of the cooling tray 710 to take two cooling methods in parallel to air-cool the water permeable block 1.
  • the external cooling of the permeation block 1 is performed by water cooling, and the internal cooling of the permeation block 1 is simultaneously performed by air cooling, the inside and outside of the permeation block 1 can be cooled overall.
  • the air nozzle 750 may be made of a swirl nozzle as shown in FIG.
  • the vortex nozzle is a means for rotating the injected air while increasing the blowing force of the air.
  • a thread forming part 64 having a thread is formed to be fastened to the air supply pipe 740, and the thread forming part 64 is formed.
  • a hollow and conical body portion 65 is formed integrally extending.
  • the body portion 65 has a plurality of air holes 66 which are holes for final injection of air along the spiral direction. It is formed through.
  • the outer surface of the body portion 65 is formed with a spiral air groove inner groove 68 coinciding with the air holes 66 arranged in a spiral direction, the air groove inner groove 68 is an air hole ( 66 to guide the jet direction of the air jetted from the spiral direction to form a vortex.
  • the air injected through the air hole 66 of the vortex nozzle and the spiral air while the inner groove 68 rotates and simultaneously sprays air while forming a vortex, thereby evenly spraying the permeable block 1 while the permeable block (1) The whole is cooled evenly.
  • the anti-fouling coating layer coated with the anti-fouling coating composition may be formed around the stirring vane 120 to effectively achieve the prevention and removal of contaminants.
  • the antifouling coating composition includes hydrogen peroxide and sodium metasilicate in a 1: 0.01 to 1: 2 molar ratio, and the total content of hydrogen peroxide and sodium metasilicate is 1 to 10% by weight based on the total aqueous solution.
  • sodium metasilicate or calcium carbonate may be used as a material for improving the coatability of the antifouling coating layer, but preferably sodium metasilicate may be used.
  • the hydrogen peroxide and sodium metasilicate are preferably 1: 0.01 to 1: 2 as the molar ratio. If the molar ratio is out of the above range, the coating property of the substrate may be reduced or the moisture absorption of the surface may be increased after application, thereby removing the coating film. have.
  • the hydrogen peroxide and sodium metasilicate are preferably 1 to 10% by weight of the total composition aqueous solution, if less than 1% by weight has a problem that the applicability of the substrate is lowered, if it exceeds 10% by weight crystal due to the increase in the coating film thickness Precipitation is likely to occur.
  • the final coating film thickness on the stirring blade 120 is preferably 500 to 2000 kPa, more preferably 1000 to 2000 kPa. If the thickness of the coating film is less than 500 kPa, there is a problem of deterioration in the case of high temperature heat treatment, and if the thickness of the coating film exceeds 2000 kPa, crystal precipitation of the coated surface is liable to occur.
  • the antifouling coating composition may be prepared by adding 0.1 mol of hydrogen peroxide and 0.05 mol of sodium metasilicate to 1000 ml of distilled water, followed by stirring.
  • the cooling water tank 720 may be formed of a surface protective coating layer of a surface coating material of a metal material to prevent corrosion of the surface from dust, contaminants, and the like.
  • the surface protective coating layer is composed of 2.5% by weight zirconium powder, 60% by weight alumina powder, 30% by weight NH 4 Cl, 2.5% by weight zinc, 2.5% by weight magnesium and 2.5% by weight titanium.
  • the zirconium powder is excellent in corrosion resistance and heat resistance. This zirconium powder is mixed at 2.5% by weight. If the mixing ratio of the zirconium powder is less than 2.5% by weight, the corrosion resistance and the heat resistance are not greatly improved. On the other hand, if the mixing ratio of the zirconium powder exceeds 2.5% by weight, the above-mentioned effect is not improved further while the material cost is greatly increased. Therefore, the titanium is preferably mixed 2.5% by weight.
  • the alumina powder is added for the purpose of sintering, tangling, fusion prevention, etc. when heated to a high temperature.
  • the alumina powder is added in less than 60% by weight, the effect of sintering, tangling and fusion prevention is inferior, and when the alumina powder exceeds 60% by weight, the above-mentioned effect is not further improved, while the material cost is greatly increased. Therefore, it is preferable to add 60 weight% of alumina powders.
  • the NH 4 Cl reacts with zinc and magnesium in a vapor state to serve to activate diffusion and penetration. This NH 4 Cl is added 30% by weight. If NH 4 Cl is added at less than 30% by weight, it does not react properly with the vaporized zinc and magnesium and thus does not activate diffusion and penetration. On the other hand, when NH 4 Cl exceeds 30% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, it is preferable to add 30% by weight of NH 4 Cl.
  • the zinc is formulated to prevent corrosion of metals in water and to be used for electrical applications. This zinc is mixed 2.5% by weight. If the mixing ratio of zinc exceeds 2.5% by weight, it will not properly prevent corrosion of the metal on water. On the other hand, when the mixing ratio of zinc exceeds 2.5% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, the zinc is preferably mixed 2.5% by weight.
  • magnesium Since the pure metal of magnesium has a low structural strength, the magnesium is combined with zinc to increase the hardness, tensile strength and corrosion resistance of the metal. This magnesium is mixed 2.5% by weight. If the mixing ratio of magnesium is less than 2.5% by weight, the hardness, tensile strength and corrosion resistance to salt water of the metal when combined with zinc and the like are not significantly improved. On the other hand, when the mixing ratio of magnesium exceeds 2.5% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, magnesium is preferably mixed at 2.5% by weight.
  • the titanium is a light, hard and corrosion-resistant transition metal element has a silver-white metallic luster, and because of its excellent corrosion resistance and low specific gravity, the weight of the titanium is only 60% compared to steel, so that the weight of the coating material applied to the metal base material is reduced but the gloss is increased. It is formulated to have excellent waterproof and corrosion resistance.
  • This titanium is mixed 2.5% by weight.
  • the mixing ratio of titanium is less than 2.5% by weight, the weight of the coating material applied to the metal base material is not so much reduced, and the glossiness, waterproofness, and corrosion resistance are not greatly improved.
  • the mixing ratio of titanium exceeds 2.5% by weight, the above-mentioned effect is not further improved while the material cost is greatly increased. Therefore, the titanium is preferably mixed 2.5% by weight.
  • the surface coating method of the cooling water tank 720 according to the present invention is as follows.
  • the cooling water tank 720 and the coating material blended in the above-mentioned structure to be formed with the surface protective coating layer are put together in the closing furnace.
  • Argon gas is injected, and maintained at a temperature of 700 ° C to 800 ° C for 4 to 5 hours while argon gas is injected.
  • zirconium powder, alumina powder, zinc, magnesium, and titanium in a vapor state are formed inside of a closed state, and zirconium powder, alumina powder, zinc, magnesium, and titanium blend penetrate the surface of the base material to provide a surface protective coating layer. Is formed.
  • the internal temperature is closed to maintain the temperature of the coating material / substrate composite at 800 ° C. to 900 ° C. for 30 to 40 hours.
  • a surface protection coating layer for preventing corrosion is formed on the surface of the cooling water tank 720. The surface of the cooling water tank 720 and the outside air is isolated. At this time, the sudden temperature change in performing the above process causes the surface protective coating layer on the surface of the cooling water tank 720 to be peeled off, thereby changing the temperature at a rate of 60 ° C / hr.
  • the surface protective coating layer of the present invention has the following advantages.
  • the surface protective coating layer of the present invention has a very wide range of uses, it can be applied by various methods such as curtain coating, spray painting, dip coating, flooding, and the like.
  • the surface protective coating layer of the present invention can be applied with a very thin layer thickness in addition to the principle protection against corrosion and / or scale, thereby improving the electrical conductivity as well as material and cost savings. Even after hot forming, a thin electroconductive primer may be applied on top of the application layer if high electrical conductivity is desired.
  • the coating material may be retained on the surface of the substrate, for example, to increase scratch resistance, to improve corrosion protection, to meet aesthetic appearance, to prevent discoloration, and to be electrically conductive. And can be provided as a primer for conventional downstream processes (eg, dip and electrophoretic dip coating).

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Road Paving Structures (AREA)

Abstract

Disclosed is a water-permeable block production system using recycled synthetic resin. The disclosed water-permeable block production system using recycled synthetic resin comprises: a primary heating furnace (200) for heating fine aggregate, transported on a moving conveyor (100), to a set temperature; a secondary heating furnace (300), structured so as to be in communication with an outlet of the primary heating furnace (200), for keeping the heated fine aggregate provided by the primary heating furnace (200) at the constant heated temperature; a melting furnace (400) into which heated fine aggregate, provided from the secondary heating furnace (300), and recycled synthetic resin, pulverized to 0.5-2.0 cm in diameter, are inserted together, and which melts the recycled synthetic resin by the heated state of the fine aggregate; a mixer (500) for agitating and mixing the molten resin and fine aggregate provided by the melting furnace (400), the interior temperature of the mixer being 220-290 ℃ and rotational speed for same being 10-30 rpm; a compression molding press (600) for compression-molding, at 30-40 MPa, the mixture of molten resin and fine aggregate provided by the mixer (500); and a cooler (700) for double-cooling, via water and air for 15-20 seconds, the water-permeable block (1) molded by the compression molding press (600) while transporting the former.

Description

재생 합성수지를 이용한 투수블록 제조시스템Permeable Block Manufacturing System Using Recycled Synthetic Resin
본 발명은 재생 합성수지, 예컨대 식음료 용기로 사용되었던 폐용기를 이용하는 투수블록 제조시스템에 관한 것으로, 더 상세하게는 강도가 강화됨과 아울러 공극률이 큰 투수블록을 제조할 수 있고, 공극막힘 현상 및 유해가스 발생량이 적어서 친환경적 작업환경을 제공하는 재생 합성수지를 이용한 투수블록 제조시스템에 관한 것이다.The present invention relates to a permeation block manufacturing system using a waste container used as a recycled synthetic resin, for example, a food and beverage container, and more particularly, to produce a permeation block having a high porosity and a high porosity, and to prevent pore clogging and harmful gases. The present invention relates to a permeable block manufacturing system using recycled synthetic resin that provides an environment-friendly working environment due to a low generation amount.
현대의 도시는 급속한 도시화로 인해 자연적인 배수면적이 현저하게 감소하고 있다.In modern cities, due to the rapid urbanization, the natural drainage area is markedly reduced.
이는, 우수로 인한 표층수가 지속적으로 유출되는 현상을 유발하고 있다.This causes the surface water to be continuously discharged due to rainwater.
특히, 인구가 밀접한 지역에서는 이미 95%에 달하는 우수가 표층수로 전환되어 배수 시스템이 한계에 도달한 실정이다.In particular, 95% of the stormwater has already been converted to surface water in close-populated areas, and the drainage system has reached its limit.
또한, 지구 온난화를 포함한 이상 기후의 영향으로 강수의 형태도 상당한 변화를 가져오고 있으며, 그 방향 또한 집중 폭우의 형태로 증가되고 있고, 강수량은 일정 기간에 집중되는 특징을 나타내고 있으므로, 많은 강수량에도 불구하고 물 부족으로 인한 장기적인 경제적, 사회적 비용의 증가가 예상되고 있다.In addition, due to the effects of abnormal climate, including global warming, the shape of precipitation has also changed considerably, and the direction is also increasing in the form of heavy rains, and precipitation is concentrated in a certain period of time. And long-term economic and social costs are expected to increase due to water shortages.
이와 같은 상황으로 인하여, 선진국에서는 1990년대 초반부터 도로의 하부 구조를 지속적으로 개량하여 표층수로 배수되는 우수를 임시 저장 공간에 저장하고 지반으로 자연 배수되도록 하여 배수 부하를 줄이고, 환경적인 측면에서 바람직할 수 있는 시공방법을 도입, 실용화한 상태이다.Due to this situation, developed countries have been continuously improving the infrastructure of roads since the early 1990s, saving rainwater drained to surface water in temporary storage spaces and allowing natural drainage to the ground to reduce drainage load, which is desirable from an environmental point of view. The construction method which could be introduced was put into practical use.
하지만, 우리나라는 위와 같은 사회적 필요성과 국내의 현실에도 불구하고 국내 실정에 적합한 시공방법이 개발되지 못한 실정이다.However, in spite of the social necessity and domestic reality, the construction method suitable for domestic situation has not been developed in Korea.
또한, 돌발성 집중호우의 발생율 증가에 따른 침수 피해의 위험 가중으로 선진국에서는 지속적으로 우수의 저류시설 설치를 확대하고 있다.In addition, due to the increased risk of flooding due to the increased incidence of sudden torrential rains, developed countries continue to expand the installation of storm water storage facilities.
국내에서도 이러한 차원에서 도로의 생태 면적율 증가를 위해서 투수포장의 개발을 확대하고 있는 시점이며, 그에 따른 연구와 다양한 시공방법을 고안하여 적용하고 있다.In Korea, it is time to expand the development of permeable pavement in order to increase the ecological area ratio of roads. Therefore, research and various construction methods are devised and applied.
그러나, 종래에 개발된 투수방법은 주로 투수블록을 이용한 방법으로서, 천연골재 또는 재생골재 및 시멘트 혼합물을 사용하여 투수블록을 형성한다.However, the conventionally developed permeation method is mainly a method using a permeation block, and forms a permeation block using natural aggregate or recycled aggregate and cement mixture.
이는 투수블록 내의 공극이 작으므로 시간이 경과할 수록 도로 표면의 우수를 지표면 아래로 배출시키는 기능이 저감된다는 문제점이 있다.This is because the air gap in the permeation block is small, there is a problem that the function of discharging the rain on the surface of the road down the surface as time passes.
또한, 이로 인하여 투수블록의 강도 및 탄성이 저하될 우려가 있고, 도로 표면 오염물의 증가, 보행환경 악화, 투수블록 주변 구조물의 동상발생 등의 문제가 있다.In addition, there is a risk that the strength and elasticity of the permeable block is lowered, there is a problem such as increase of road surface contaminants, deterioration of walking environment, frostbite generation of structures surrounding the permeable block.
더불어, 종래의 투수블록을 제조하기 위해 사용하는 천연골재 또는 재생골재로 인하여 환경적 측면에서도 바람직하지 않다.In addition, due to the natural aggregate or recycled aggregate used to manufacture the conventional permeable block is not preferable in terms of environment.
이러한 문제를 근본적으로 해결하기 않고, 표층의 보도블록만 투수로 교체할 경우, 장기적으로 투수 지수의 지속적인 감소로 인해 그 기능을 상실하게 될 것이다.If you do not solve this problem fundamentally and replace only the surface sidewalk block with a pitcher, it will lose its function in the long run due to the continuous decrease in the index.
본 발명은 상기한 종래의 문제점을 해결하기 위해 안출한 것으로, 본 발명의 주요 목적은 식용 용기로 사용되었던 폐합성수지를 투수블록을 제조하는데 혼합하여 사용하되, 수지 배합비를 높힘으로써 강도를 강화하고, 가압 성형시 가압력을 낮춤으로써 공극률을 크게하며, 투수블록의 냉각시간을 늘림으로써 수지가 타거나 녹는 것을 방지하여 공극막힘 현상을 방지함과 아울러 유해가스 발생도 방지할 수 있는 재생 합성수지를 이용한 투수블록 제조시스템을 제공함에 있다.The present invention has been made to solve the above-mentioned problems, the main object of the present invention is to mix the waste synthetic resin used as an edible container to prepare a water permeable block, but to enhance the strength by increasing the resin compounding ratio, Permeability block by reducing pressing force to increase porosity and increase cooling time of permeation block to prevent burning or melting of resin to prevent pore blockage and to prevent harmful gas generation To provide a manufacturing system.
상기 목적을 달성하기 위한 본 발명에 따르면, 잔골재가 저장된 호퍼로 부터 배출되는 잔골재를 이송하는 이송 컨베이어; 상기 이송 컨베이어를 통해 이송되어 온 잔골재를 소정온도로 가열하는 1차 가열로; 상기 1차 가열로의 출구와 연통되게 구성되어, 상기 1차 가열로로부터 제공되는 가열 상태의 잔골재가 그 온도를 일정하게 유지할 수 있도록 보온하는 2차 가열로; 상기 2차 가열로부터 제공되는 가열 상태의 잔골재와 직경이 0.5 ~ 2.0cm로 분쇄된 재생 합성수지가 함께 투입되어, 가열상태의 잔골재에 의해 재생 합성수지를 용융시키는 용융로; 상기 용융로로부터 제공되는 용융수지와 잔골재를 교반하여 혼합하되, 내부 온도가 220 ~ 290℃이고, 회전속도는 10 ~ 30rpm인 믹서; 상기 믹서로부터 제공되는 용융수지와 잔골재의 혼합물을 30 ~ 40MPa의 압력으로 가압 성형하는 가압 성형기; 및 상기 가압 성형기에 의해 성형된 투수블록을 이송시키면서 수냉 및 공냉에 의해 15 ~ 20sec 동안 이중 냉각하는 냉각기;를 포함하는 재생 합성수지를 이용한 투수블록 제조시스템이 제공된다.According to the present invention for achieving the above object, a transfer conveyor for transporting the fine aggregate discharged from the hopper is stored fine aggregate; A primary heating furnace for heating the fine aggregate transferred through the transfer conveyor to a predetermined temperature; A secondary heating furnace configured to be in communication with an outlet of the primary heating furnace to insulate the residual aggregate in a heating state provided from the primary heating furnace to maintain a constant temperature thereof; A molten furnace in which the heated aggregate provided from the secondary heating and the recycled synthetic resin pulverized to a diameter of 0.5 to 2.0 cm are added together to melt the recycled synthetic resin by the heated aggregate; Mixing by mixing the molten resin and the fine aggregate provided from the melting furnace, the internal temperature is 220 ~ 290 ℃, the rotation speed is 10 ~ 30rpm mixer; A pressure molding machine for press-molding the mixture of the molten resin and the fine aggregate provided from the mixer at a pressure of 30 to 40 MPa; There is provided a permeable block manufacturing system using a recycled synthetic resin comprising a; and a cooler for dual cooling by water cooling and air cooling for 15 to 20 seconds while transferring the permeable block formed by the pressure molding machine.
바람직하게, 상기 믹서는, 원통형의 믹서통; 상기 믹서통의 내주면에 길이방향을 따라 계단형으로 배치되는 다수의 교반날개를 포함하되, 상기 각 교반날개는 그 일부분이 인접한 교반날개와 중첩되게 배치될 수 있다.Preferably, the mixer comprises a cylindrical mixer barrel; It includes a plurality of stirring blades arranged in a step shape along the longitudinal direction on the inner circumferential surface of the mixer barrel, each of the stirring blades may be disposed so that a portion thereof overlaps with the adjacent stirring blades.
바람직하게, 상기 냉각기는, 상기 가압 성형기에서 배출되는 각 투수블록을 수용하는 냉각 트레이; 상기 투수블록이 수용된 냉각 트레이의 하부에 설치된 채 냉각 트레이를 냉각수에 침수시켜 수냉시키기 위한 횡장형의 냉각수조; 상기 냉각 트레이를 냉각수조의 길이방향을 따라 이송시켜주는 이송 컨베이어; 상기 냉각 트레이의 상부에 냉각 트레이의 이동방향을 따라 설치되는 에어 공급관; 및 상기 에어 공급관 상에 일정 간격으로 배치된 채 에어 공급관 내의 에어를 상기 투수블록을 향해 분사하여 투수블록을 공냉시켜주는 에어노즐;을 포함할 수 있다.Preferably, the cooler, the cooling tray for receiving each water permeation block discharged from the pressure molding machine; A horizontal cooling water tank configured to immerse the cooling tray in the cooling water and to cool the water while being installed under the cooling tray containing the water permeable block; A transport conveyor for transporting the cooling tray along the longitudinal direction of the cooling water tank; An air supply pipe installed above the cooling tray along a moving direction of the cooling tray; And an air nozzle disposed at predetermined intervals on the air supply pipe to inject air in the air supply pipe toward the permeation block to cool the permeation block.
본 발명의 과제의 해결수단에 따르면, 식용 용기로 사용되었던 폐합성수지를 투수블록을 제조하는데 혼합하여 사용함으로써 친환경적이다.According to the solution of the present invention, it is environmentally friendly by using a mixture of waste synthetic resin used as an edible container to prepare a water permeable block.
또한, 수지 배합비를 기존 대비 높힘으로써 강도가 강화된 투수블록을 제공할 수 있다.In addition, by increasing the resin compounding ratio compared to the existing can provide a permeable block of enhanced strength.
또한, 가압 성형시 가압력을 기존 대비 낮춤으로써 공극률을 크게할 수 있고, 이에 따라 투수효율을 높일 수 있다.In addition, the porosity can be increased by lowering the pressing force in the press molding as compared with the existing, thereby increasing the permeability efficiency.
또한, 투수블록의 냉각시간을 늘림으로써 수지가 타거나 녹는 것을 방지하여 공극막힘 현상을 방지함과 아울러 유해가스 발생도 방지할 수 있어서 작업 환경을 개선할 수 있다.In addition, by increasing the cooling time of the permeation block to prevent burning or melting of the resin to prevent the clogging of the pore and also to prevent the generation of harmful gases can improve the working environment.
도 1은 본 발명에 따른 재생 합성수지를 이용한 투수블록 제조시스템의 구성도1 is a block diagram of a pitcher block manufacturing system using a recycled synthetic resin according to the present invention
도 2는 본 발명에 따른 시스템의 일 구성인 믹서의 구성도2 is a block diagram of a mixer which is one configuration of a system according to the present invention;
도 3은 본 발명에 다른 시스템의 일 구성인 냉각기의 구성도3 is a configuration diagram of a cooler that is one configuration of another system according to the present invention;
도 4는 본 발명에 따른 재생 합성수지를 이용한 투수블록 제조시스템을 이용한 투수블록 제조방법을 설명하기 위한 흐름도4 is a flow chart for explaining a method of manufacturing a pitcher block using a pitcher block manufacturing system using a recycled synthetic resin according to the present invention.
도 5는 본 발명의 시스템에 따라 제조되는 투수블록의 형상도5 is a shape diagram of a pitcher block manufactured according to the system of the present invention;
도 6은 본 발명에 따른 에어노즐의 일실시예를 보인 개략적 단면도Figure 6 is a schematic cross-sectional view showing an embodiment of an air nozzle according to the present invention
본 발명은 여기서 설명되는 실시예들에 한정되지 않고 다른 형태로 구체화될 수도 있다. 오히려, 여기서 소개되는 실시예들은 개시된 내용이 철저하고 완전해질 수 있도록 그리고 당업자에게 본 발명의 사상이 충분히 전달될 수 있도록 하기 위해 제공되는 것이다. 명세서 전체에 걸쳐서 동일한 참조 번호들은 동일한 구성 요소들을 나타낸다. 한편, 본 명세서에서 사용된 용어는 실시예들을 설명하기 위한 것이며 본 발명을 제한하고자 하는 것은 아니다. 본 명세서에서, 단수형은 문구에서 특별히 언급되지 않는 한 복수형도 포함된다. 명세서에서 사용되는 "포함한다(comprises)" 및/또는 "포함하는(comprising)"은 언급된 구성 요소, 단계, 동작 및/또는 소자가 하나 이상의 다른 구성 요소, 단계, 동작 및/또는 소자의 존재 또는 추가를 배제하지 않는다.The invention is not limited to the embodiments described herein but may be embodied in other forms. Rather, the embodiments introduced herein are provided so that the disclosure may be made thorough and complete, and to fully convey the spirit of the present invention to those skilled in the art. Like reference numerals refer to like elements throughout. Meanwhile, the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. In this specification, the singular forms also include the plural unless specifically stated otherwise in the text. As used herein, "comprises" and / or "comprising" refers to the presence of one or more other components, steps, operations and / or elements in which the stated components, steps, operations and / or elements are known. Or does not exclude additions.
이하, 첨부한 도면을 참조하여 본 발명의 바람직한 실시예를 상세히 설명한다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.
도 1은 본 발명에 따른 재생 합성수지를 이용한 투수블록 제조시스템의 구성도이다.1 is a block diagram of a pitcher block manufacturing system using a recycled synthetic resin according to the present invention.
도 1에 따르면, 본 발명에 따른 재생 합성수지를 이용한 투수블록 제조시스템은, 이송 컨베이어(100), 1차 가열로(200), 2차 가열로(300), 용융로(400), 믹서(500), 가압 성형기(600) 및 냉각기(700)를 포함한다.According to Figure 1, the permeation block manufacturing system using the recycled synthetic resin according to the present invention, the transfer conveyor 100, the primary heating furnace 200, the secondary heating furnace 300, the melting furnace 400, the mixer 500 , A press molding machine 600 and a cooler 700.
이송 컨베이어(100)는 잔골재가 저장된 호퍼(10)로부터 배출되는 잔골재를 상기 1차 가열로(200)로 이송시켜주는 역할을 한다.The transfer conveyor 100 serves to transfer the fine aggregate discharged from the hopper 10 in which the fine aggregate is stored to the primary heating furnace 200.
1차 가열로(200)는 프레임에 회전가능하게 지지된 채, 상기 이송 컨베이어(100)를 통해 이송되어온 잔골재를 소정온도로 가열하는 역할을 하는 것으로, 이 1차 가열로(200)는 재생 합성수지와 잔골재를 혼합하였을 때 잔골재의 가열온도에 의해 재생 합성수지가 용융되도록 하기 위하여 잔골재를 미리 가열해 주는 것이다.The primary furnace 200 is rotatably supported by the frame, and serves to heat the aggregate aggregate transported through the transfer conveyor 100 to a predetermined temperature, the primary furnace 200 is a recycled synthetic resin When the fine aggregate is mixed with the fine aggregate, the fine aggregate is preheated in order to melt the regenerated synthetic resin by the heating temperature of the fine aggregate.
2차 가열로(300)는 상기 1차 가열로(200)의 출구와 연통되게 연결된 채, 상기 1차 가열로(200)로부터 제공되는 가열 상태의 잔골재가 그 온도를 일정하게 유지할 수 있도록 보온해 주는 역할을 한다. 이때, 상기 2차 가열로(300)는 그 출구가 입구로부터 비스듬하게 하향 경사지게 설치되어 2차 가열로 내의 잔골재가 자연스럽게 출구를 향해 배출될 수 있는 설치구조를 갖는다.The secondary heating furnace 300 is insulated in communication with the outlet of the primary heating furnace 200 to keep the heated aggregate provided from the primary heating furnace 200 to maintain its temperature constant. Role. At this time, the secondary heating furnace 300 has an installation structure in which the outlet is installed obliquely downwardly inclined from the inlet so that the fine aggregate in the secondary heating furnace can be naturally discharged toward the outlet.
용융로(400)는 상기 2차 가열로(300)의 출구측에 설치된 채, 상기 2차 가열로(300)로부터 제공되는 가열 상태의 잔골재와 분쇄된 재생 합성수지가 함께 투입되어 가열 상태의 잔골재에 의해 재생 합성수지가 용융되게 하는 역할을 한다. 여기서, 상기 용융로(400)로 투입되는 재생 합성수지의 직경은 0.5 ~ 2.0cm가 적당하다. The melting furnace 400 is installed at the outlet side of the secondary heating furnace 300, and the heated aggregate provided from the secondary heating furnace 300 and the pulverized recycled synthetic resin are introduced together to be heated by the heated aggregate. It plays a role to make recycled synthetic resin melt. Here, the diameter of the recycled synthetic resin introduced into the melting furnace 400 is suitable for 0.5 ~ 2.0cm.
한편, 상기 재생 합성수지는 선별, 분쇄 및 세정·건조과정을 거처서 상기 용융로(400)로 투입된다.On the other hand, the recycled synthetic resin is introduced into the melting furnace 400 through the process of sorting, pulverizing, washing and drying.
참고로, 상기 선별은 식음료용 용기로 사용되던 패트병(PET)을 무색, 유색 및 재질별로 선별하는 작업이고, 분쇄는 상기에서 선별된 재생 합성수지를 분쇄하되 직경이 0.5 ~ 2.0cm가 되도록 분쇄하는 작업이며, 세정 및 건조는 상기 분쇄된 재생 합성수지를 세척 및 탈수, 건조하는 작업니다.For reference, the sorting is a process for sorting the PET bottles (PET) used as food and beverage containers by colorless, colored, and materials, and the grinding is to grind the recycled synthetic resin selected from the above to be 0.5 to 2.0cm in diameter. Washing and drying are operations for washing, dehydrating and drying the pulverized recycled synthetic resin.
여기서, 선별된 재생 합성수지 중 무색을 사용하게 되면 투명한 색상의 투수블록을 제조할 수 있고, 유색을 사용하게 되면 그에 맞는 색상의 투수블록을 제조할 수 있어서 염료를 사용하지 않고도 원하는 칼라를 얻을 수 있게 되므로 친환경적인 투수블록의 제작이 가능하고, 원가절감에도 기여된다.Here, using colorless of the selected recycled synthetic resin can produce a transparent color permeable block, if using a color can be prepared a permeable block of the color corresponding to it so that the desired color can be obtained without using a dye Therefore, it is possible to manufacture environmentally friendly pitching block, and contribute to cost reduction.
믹서(500)는 도 2에서와 같이, 상기 용융로(400)로부터 제공되는 용융수지와 잔골재를 교반하여 혼합하는 역할을 하는 것으로, 입구(511)와 출구(512)를 갖는 원통형의 믹서통(510)과, 상기 믹서통(510)의 내주면에 길이방향을 따라 계단형으로 배치되는 다수의 판형 또는 유선형의 교반날개(520)들로 구성될 수 있다.The mixer 500 serves to stir and mix the molten resin and the fine aggregate provided from the melting furnace 400, as shown in FIG. 2, and a cylindrical mixer cylinder 510 having an inlet 511 and an outlet 512. ), And a plurality of plate-shaped or streamlined stir blades 520 disposed on the inner circumferential surface of the mixer barrel 510 along the longitudinal direction.
여기서, 상기 각 교반날개(520)는 그 일부분, 예컨대 길이방향의 단부가 인접하는 다른 교반날개와 중첩되게(overlap:o) 배치되는 것이 바람직하다. 스크류형의 일반적인 교반날개의 경우는 잔골재 및 용융수지가 한쪽으로 쏠리는 현상이 발생하여 원활한 교반효과를 얻기 어려운 반면, 본 발명의 교반날개(520)는 계단형으로 배치되는 관계로 잔골재 및 용융수지가 계단을 따라 원활하게 유동되므로 유동효율을 배가시킬 수 있고, 이로 인해 교반효율도 배가시킬 수 있게 된다.Here, each of the stirring blades 520 is preferably disposed so that a portion thereof, for example, an end portion in the longitudinal direction overlaps with another adjacent stirring blade (o). In the case of a screw-type stirring blade in general, the aggregate aggregate and the melted resin are caused to lean to one side, so that it is difficult to obtain a smooth stirring effect, while the stirring blade 520 of the present invention is disposed in a stepped shape, so that the aggregate and the melted resin are The smooth flow along the stairs can double the flow efficiency, thereby doubling the stirring efficiency.
그리고, 상기 믹서(500)에 투입되는 상기 재생 합성수지와 잔골재는 3:7의 비율로 투입되되, 믹서 내부의 온도는 220 ~ 290℃가 되도록 가열하고, 믹서의 회전속도는 10 ~ 30rpm의 속도로 회전시키는 것이 바람직하다.And, the recycled synthetic resin and the aggregate aggregate is added to the mixer 500 at a ratio of 3: 7, the temperature inside the mixer is heated to 220 ~ 290 ℃, the speed of the mixer at a speed of 10 ~ 30rpm It is preferable to rotate.
상기에서 믹서(500)의 내부온도가 220℃ 보다 낮으면 잘 녹지 않아서 응고 될 수 있고, 반면 290℃ 보다 높으면 고열로 인하여 탈 수 있으므로 위 온도 범위로 한정하는 것이 바람직하다.When the internal temperature of the mixer 500 is lower than 220 ° C., the internal temperature of the mixer 500 may not solidify, and if the internal temperature of the mixer 500 is higher than 290 ° C., the internal temperature of the mixer 500 may be burned due to high heat.
또한, 상기 재생 합성수지와 잔골재의 배합비는 강도향상에 중요한 요소로서, 잔골재에 대비 재생 합성수지의 배합비가 증가할 수록 잔골재에 대한 응집력이 강해지기 때문에 강도가 강화될 수 있으나, 재생 합성수지의 배합비가 필요이상 증가하게 되면 오히려 연성이 증가하게 되어 변형의 소지가 크게 되므로 위 배합범위에서 결정되는 것이 바람직하다.In addition, the mixing ratio of the recycled synthetic resin and fine aggregates is an important factor for improving the strength, and as the mixing ratio of the recycled synthetic resins increases with respect to the fine aggregates, the cohesive strength of the fine aggregates increases, but the mixing ratio of the recycled synthetic resins is more than necessary If it is increased, the ductility is increased to increase the possibility of deformation is preferably determined in the above compounding range.
또한, 상기 믹서(500)의 회전속도의 경우는 위 범위에서의 회전속도가 혼합효율이 좋다. 이 범위보다 느리게 회전하면 교반효율이 현저히 저하되고, 그렇다고 위 범위보다 빠르게 회전하더라도 교반효율이 오히려 떨어지게 되므로 위 범위 내에서 적절히 조절하는 것이 바람직하다.In addition, in the case of the rotational speed of the mixer 500, the rotational speed in the above range is good mixing efficiency. When the rotation is slower than this range, the stirring efficiency is significantly lowered. However, even if it is rotated faster than the above range, the stirring efficiency is lowered.
그리고, 상기 믹서(500)는 그 양쪽 말단부에 믹서 내부를 가열하기 위한 제1, 2 버너(530,540)가 설치되고, 믹서통(510)의 벽면에는 열선(550)이 설치되어 있어서 제1, 2 버너와 함께 믹서의 내부를 가열하게 된다. 이렇게 버너와 열선을 조합한 이유는 버너 만으로는 고른 가열이 어렵기 때문에 열선을 보강함으로써 고른 가열이 가능하고, 또한 버너를 여러 대 설치하는 것 보다는 열선을 보완 설치하는 것이 전기 에너지를 절약할 수 있기 때문이다.The mixer 500 is provided with first and second burners 530 and 540 for heating the inside of the mixer at both end portions thereof, and a heating wire 550 is provided on the wall surface of the mixer barrel 510 so that the mixer 500 is provided with first and second burners. The burner will heat up the inside of the mixer. The reason why the burner and the heating wire are combined is that it is difficult to evenly heat the burner alone, so even heating is possible by reinforcing the heating wire, and supplementing the heating wire can save electric energy rather than installing several burners. to be.
가압 성형기(600)는 상기 믹서(500)로부터 제공되는 용융수지와 잔골재의 혼합물을 플런저(610)에 의해 30 ~ 40MPa의 압력으로 가압 성형하는 것이다.The pressure molding machine 600 is a pressure molding of the mixture of the molten resin and the fine aggregate provided from the mixer 500 at a pressure of 30 ~ 40MPa by the plunger 610.
여기서, 중요한 요소는 가압 압력인데, 가압력이 크면 용융수지와 잔골재 사이의 공극이 치밀해 지기 때문에 공극률이 떨어지는 반면, 가압력이 작으면 용융수지와 잔골재 사이의 공극이 커지게 되므로 공극률이 증가하게 된다. 특히, 투수블록은 공극률이 커야만 배수효율이 크기 때문에 공극이 크면 클수록 좋을 수는 있겠으나, 반면 공극률이 크게 되면 강도가 약화되는 반대급부가 발생할 수 있으므로 위 가압범위를 따르게 되면 적절한 공극률과 강도가 보장될 수 있다. 위 압력으로 가압하였을 때의 공극률은 20~30%이 된다.Here, the important factor is the pressurization pressure, the larger the pressing force, the porosity is lowered because the pores between the molten resin and the fine aggregate becomes dense, while the smaller the pressing force increases the porosity between the molten resin and the fine aggregate, thereby increasing the porosity. In particular, the permeation block may be better because the larger the porosity, the larger the porosity, so the larger the porosity, the greater the porosity. Can be guaranteed. Porosity when pressurized to the above pressure is 20 to 30%.
냉각기(700)는 도 3에서와 같이, 상기 가압 성형기(600)에 의해 성형된 투수블록(1)을 이송시키면서 수냉 및 공냉에 의해 15 ~ 20sec 동안 이중 냉각하는 것으로, 상기 가압 성형기(600)에서 배출되는 각 투수블록(1)을 수용하는 냉각 트레이(710)와, 상기 투수블록(1)이 수용된 냉각 트레이(710)의 하부에 설치된 채 냉각 트레이를 냉각수에 침수시켜 수냉시키기 위한 횡장형의 냉각수조(720)와, 상기 냉각 트레이(710)를 냉각수조(720)의 길이방향을 따라 이송시켜주는 이송 컨베이어(730)와, 상기 냉각 트레이(710)의 상부에 냉각 트레이의 이동방향을 따라 설치되는 에어 공급관(740)과, 상기 에어 공급관 상에 일정 간격으로 배치된 채 에어 공급관 내의 에어를 상기 투수블록을 향해 분사하여 투수블록을 공냉시켜주는 다수의 에어노즐(750)로 구성된다.The cooler 700 is dual cooling for 15 to 20 sec by water and air cooling while conveying the water permeable block 1 formed by the pressure molding machine 600, as shown in FIG. 3, in the pressure molding machine 600 Cooling tray 710 for accommodating each of the discharged water permeation block (1), and horizontal cooling water for cooling the water by immersing the cooling tray in the cooling water while being installed in the lower portion of the cooling tray 710 containing the water permeable block (1) A tank 720, a transfer conveyor 730 for transferring the cooling tray 710 along the longitudinal direction of the cooling water tank 720, and installed along the moving direction of the cooling tray on the cooling tray 710. The air supply pipe 740 and a plurality of air nozzles 750 which are arranged at regular intervals on the air supply pipe to inject air in the air supply pipe toward the permeation block to cool the permeation block.
이에 따라, 수냉에 의해 투수블록(1)의 외부 냉각이 이루어지고, 공냉에 의해 투수블록(1)의 내부 냉각이 동시에 이루어지게 되므로 투수블록(1)의 내외부를 전반적으로 고르게 냉각시킬 수 있게 된다.Accordingly, the external cooling of the permeation block 1 is performed by water cooling, and the internal cooling of the permeation block 1 is simultaneously performed by air cooling, thereby allowing the inside and outside of the permeation block 1 to be cooled down evenly. .
냉각효율의 향상은 양생시간이 28일 이었던 기존과 비교하였을 때 양생시간을 현저히 줄일 수 있으므로 생산성 향상에 기여된다. 이와 관련하여, 앞서 설명한 바 있듯이 본 발명의 투수블록(1)은 공극률이 기존 대비 향상되었기 때문에 냉각효율을 보다 높일 수 있고, 냉각시간도 단축할 수 있게 된다.The improvement in cooling efficiency contributes to productivity improvement since the curing time can be significantly reduced compared to the existing curing time of 28 days. In this regard, as described above, the water permeability block 1 of the present invention can increase the cooling efficiency and shorten the cooling time since the porosity is improved compared to the conventional one.
참고로, 상기한 시스템에 의한 재생 합성수지를 이용한 투수블록 제조방법을 간략히 설명하면 아래와 같다(도 4참조).For reference, a brief description of a method for manufacturing a permeable block using recycled synthetic resin according to the above system is as follows (see FIG. 4).
1 단계인 잔골재 가열단계(S10)는, 상기 이송 컨베이어(100)에 의해 이송되어온 잔골재를 상기 1차 가열로(200)에 투입하고 이를 소정온도로 가열하는 단계이다.Residual aggregate heating step (S10), which is a first step, is a step of inputting the residual aggregate transferred by the transfer conveyor 100 to the primary heating furnace 200 and heating it to a predetermined temperature.
2 단계인 잔골재 보온단계(S20)는 1 단계에서 가열된 잔골재를 상기 2차 가열로(300)로 투입하여 잔골재의 가열된 온도가 일정하게 유지되도록 보온하는 단계이다.Residual aggregate warming step (S20) is a step of keeping the heated temperature of the aggregate remains constant by inputting the residual aggregate heated in the first step into the secondary heating furnace (300).
3 단계인 용융단계(S30)는 2차 가열로(300)로부터 배출되는 잔골재와 일정크기로 분쇄된 재생 합성수지를 용융로(400)에 투입하여, 잔골재의 가열된 온도에 의해 재생 합성수지를 용융시키는 단계이다.Melting step (S30) of the third step is a step of melting the regenerated synthetic resin by the heated temperature of the residual aggregate by inputting the fine aggregate discharged from the secondary heating furnace 300 and the recycled synthetic resin crushed to a predetermined size into the melting furnace 400 to be.
여기서, 앞서 설명한 바 있듯이, 상기 용융로(400)로 투입되는 재생 합성수지는 선별단계(S100), 분쇄단계(S200) 및 세정 및 건조단계(S300)를 거치게 된다.Here, as described above, the recycled synthetic resin introduced into the melting furnace 400 is subjected to the sorting step (S100), the crushing step (S200) and the washing and drying step (S300).
4 단계인, 혼합단계(S40)는 상기 재생 합성수지와 잔골재를 3:7의 비율로 믹서에 투입하되, 상기 믹서(500) 내부의 온도는 220 ~ 290℃가 되도록 가열하고, 믹서(500)의 회전속도는 10 ~ 30rpm의 속도로 회전시켜서 잔골재와 응집제 역활을 하는 용융된 재생 합성수지를 혼합시키는 단계이다. Mixing step (S40), which is the fourth step, is added to the mixer in the ratio of the recycled synthetic resin and the fine aggregate 3: 7, the temperature inside the mixer 500 is heated to 220 ~ 290 ℃, the mixer 500 Rotational speed is a step of mixing the molten recycled synthetic resin serving as a coagulant and the aggregate by rotating at a speed of 10 ~ 30rpm.
5 단계인, 성형단계(S50)는 상기 혼합된 용융수지와 잔골재를 가압 성형기(600)에 일정량 투입하고, 플런저(610)에 의해 30 ~ 40MPa의 압력으로 가압 성형하여 투수블록을 형성하는 단계이다.Step 5, forming step (S50) is a step of forming a permeable block by putting a predetermined amount of the mixed molten resin and fine aggregate into the pressure molding machine 600, by pressing the pressure of 30 ~ 40MPa by the plunger 610. .
6 단계인, 냉각단계(S60)는 상기 성형이 완료된 투수블록(1)의 표면 및 내부를 15 ~ 20sec 동안 고르게 냉각시키는 단계이다. The cooling step (S60), which is a sixth step, is a step of evenly cooling the surface and the inside of the permeation block 1 on which the molding is completed for 15 to 20 seconds.
즉, 상기 냉각단계는 도 3에서와 같이, 각 투수블록(1)이 수용된 냉각 트레이(710)가 컨베이어(730)에 의해 이송되면서 냉각수조(720)를 통과함에 따라 수냉이 이루어지고, 이와 함께 상기 냉각 트레이(710)의 개방된 상부를 통해 노즐(750)에 의해 에어를 분사함으로써 투수블록(1)을 공냉시키는 2가지 냉각방식을 병행하여 취하게 된다.That is, in the cooling step, as shown in FIG. 3, the cooling tray 710 containing each of the permeation blocks 1 passes through the cooling water tank 720 while being transported by the conveyor 730, and thus water cooling is performed. Air is injected by the nozzle 750 through the open upper portion of the cooling tray 710 to take two cooling methods in parallel to air-cool the water permeable block 1.
이에 따라, 수냉에 의해 투수블록(1)의 외부 냉각이 이루어지고, 공냉에 의해 투수블록(1)의 내부 냉각이 동시에 이루어지게 되므로 투수블록(1)의 내외부를 전반적으로 냉각시킬 수 있게 된다. Accordingly, since the external cooling of the permeation block 1 is performed by water cooling, and the internal cooling of the permeation block 1 is simultaneously performed by air cooling, the inside and outside of the permeation block 1 can be cooled overall.
한편, 에어노즐(750)은 도 6에 도시한 바와 같이 소용돌이노즐로 이루어질 수도 있다. 이 소용돌이노즐은, 에어의 분사력을 강하게 하면서도 분사되는 에어를 회전시키는 수단으로서, 그 상단부에는 에어 공급관(740)에 체결되도록 나사산을 갖는 나사산형성부(64)가 형성되고, 이 나사산형성부(64)로부터 그 아래쪽으로는 중공형이고 원추 형상을 갖는 바디부(65)가 일체로 연장 형성되는데, 이 바디부(65)에는 나선방향을 따라 에어가 최종 분사되는 홀인 다수개의 에어홀(66)이 관통 형성된다.On the other hand, the air nozzle 750 may be made of a swirl nozzle as shown in FIG. The vortex nozzle is a means for rotating the injected air while increasing the blowing force of the air. At the upper end thereof, a thread forming part 64 having a thread is formed to be fastened to the air supply pipe 740, and the thread forming part 64 is formed. From the bottom thereof, a hollow and conical body portion 65 is formed integrally extending. The body portion 65 has a plurality of air holes 66 which are holes for final injection of air along the spiral direction. It is formed through.
또한, 상기 바디부(65)의 외면에는 나선방향으로 배열된 상기 에어홀(66)과 일치되는 나선형의 에어이동안내홈(68)이 형성되며, 이 에어이동안내홈(68)은 에어홀(66)로부터 분사되는 에어의 분사방향을 나선방향으로 안내하여 소용돌이를 형성하는 역할을 한다.In addition, the outer surface of the body portion 65 is formed with a spiral air groove inner groove 68 coinciding with the air holes 66 arranged in a spiral direction, the air groove inner groove 68 is an air hole ( 66 to guide the jet direction of the air jetted from the spiral direction to form a vortex.
이에, 상기 소용돌이노즐의 에어홀(66) 및 나선형의 에어이동안내홈(68)을 통해 분사되는 에어가 회전하는 동시에 소용돌이를 형성하면서 에어를 분사함으로써, 투수블록(1)에 골고루 분사되면서 투수블록(1) 전체를 고르게 냉각시키게 된다.Accordingly, the air injected through the air hole 66 of the vortex nozzle and the spiral air while the inner groove 68 rotates and simultaneously sprays air while forming a vortex, thereby evenly spraying the permeable block 1 while the permeable block (1) The whole is cooled evenly.
또한, 교반날개(120)의 둘레에는 오염물질의 부착방지 및 제거를 효과적으로 달성할 수 있도록 오염 방지 도포용 조성물이 도포된 오염방지도포층이 형성될 수 있다. 상기 오염 방지 도포용 조성물은 과산화수소 및 메타규산나트륨이 1:0.01 ~ 1:2 몰비로 포함되어 있고, 과산화수소 및 메타규산나트륨의 총함량은 전체 수용액에 대해 1 ~ 10 중량%이다. 이에 더하여, 상기 오염방지도포층의 도포성을 향상시키는 물질로 메타규산나트륨 또는 탄산칼슘이 이용될 수 있으나 바람직하게는 메타규산나트륨이 이용될 수 있다. 상기 과산화수소 및 메타규산나트륨은 몰비로서 1:0.01 ~ 1:2가 바람직한 바, 몰비가 상기 범위를 벗어나는 경우에는 기재의 도포성이 저하되거나 도포후 표면의 수분흡착이 증가하여 도포막이 제거되는 문제점이 있다.In addition, the anti-fouling coating layer coated with the anti-fouling coating composition may be formed around the stirring vane 120 to effectively achieve the prevention and removal of contaminants. The antifouling coating composition includes hydrogen peroxide and sodium metasilicate in a 1: 0.01 to 1: 2 molar ratio, and the total content of hydrogen peroxide and sodium metasilicate is 1 to 10% by weight based on the total aqueous solution. In addition, sodium metasilicate or calcium carbonate may be used as a material for improving the coatability of the antifouling coating layer, but preferably sodium metasilicate may be used. The hydrogen peroxide and sodium metasilicate are preferably 1: 0.01 to 1: 2 as the molar ratio. If the molar ratio is out of the above range, the coating property of the substrate may be reduced or the moisture absorption of the surface may be increased after application, thereby removing the coating film. have.
상기 과산화수소 및 메타규산나트륨은 전제 조성물 수용액중 1 ~ 10 중량%가 바람직한 바, 1 중량% 미만이면 기재의 도포성이 저하되는 문제점이 있고, 10 중량%를 초과하면 도포막 두께의 증가로 인한 결정석출이 발생하기 쉽다.The hydrogen peroxide and sodium metasilicate are preferably 1 to 10% by weight of the total composition aqueous solution, if less than 1% by weight has a problem that the applicability of the substrate is lowered, if it exceeds 10% by weight crystal due to the increase in the coating film thickness Precipitation is likely to occur.
상기 오염 방지 도포용 조성물을 기재 상에 도포하는 방법으로는 스프레이법에 의해 도포하는 것이 바람직하다. 또한, 상기 교반날개(120) 상의 최종 도포막 두께는 500~2000Å이 바람직하며, 보다 바람직하게는 1000 ~ 2000 Å이다. 상기 도포막의 두께가 500 Å미만이면 고온 열처리의 경우에 열화되는 문제점이 있고, 2000 Å을 초과하면 도포 표면의 결정석출이 발생하기 쉬운 단점이 있다.It is preferable to apply | coat by the spray method as a method of apply | coating the said antifouling coating composition on a base material. In addition, the final coating film thickness on the stirring blade 120 is preferably 500 to 2000 kPa, more preferably 1000 to 2000 kPa. If the thickness of the coating film is less than 500 kPa, there is a problem of deterioration in the case of high temperature heat treatment, and if the thickness of the coating film exceeds 2000 kPa, crystal precipitation of the coated surface is liable to occur.
또한, 오염 방지 도포용 조성물은 과산화수소 0.1 몰 및 메타규산나트륨 0.05 몰을 증류수 1000 ㎖에 첨가한 다음 교반하여 제조될 수 있다.In addition, the antifouling coating composition may be prepared by adding 0.1 mol of hydrogen peroxide and 0.05 mol of sodium metasilicate to 1000 ml of distilled water, followed by stirring.
그리고, 냉각수조(720)는, 먼지, 오염물질 등으로부터 표면의 부식현상을 방지시키기 위해 금속재의 표면 도포재료로 표면보호도포층이 형성될 수 있다. 이 표면보호도포층은 지르코늄 분말 2.5중량%, 알루미나 분말 60중량%, NH4Cl 30중량%, 아연 2.5중량%, 마그네슘 2.5중량%, 티타늄 2.5중량%로 구성된다.In addition, the cooling water tank 720 may be formed of a surface protective coating layer of a surface coating material of a metal material to prevent corrosion of the surface from dust, contaminants, and the like. The surface protective coating layer is composed of 2.5% by weight zirconium powder, 60% by weight alumina powder, 30% by weight NH 4 Cl, 2.5% by weight zinc, 2.5% by weight magnesium and 2.5% by weight titanium.
상기 지르코늄 분말은, 내식성, 내열성이 뛰어나다. 이러한 지르코늄 분말은 2.5중량% 혼합된다. 지르코늄 분말의 혼합 비율이 2.5중량% 미만이면, 내식성, 내열성이 크게 개선되지 않는다. 반면에, 지르코늄 분말의 혼합 비율이 2.5중량%를 초과하면 상술한 효과는 더 개선되지 않는 반면에 재료비는 크게 증가된다. 따라서 티타늄은 2.5중량% 혼합되는 것이 바람직하다.The zirconium powder is excellent in corrosion resistance and heat resistance. This zirconium powder is mixed at 2.5% by weight. If the mixing ratio of the zirconium powder is less than 2.5% by weight, the corrosion resistance and the heat resistance are not greatly improved. On the other hand, if the mixing ratio of the zirconium powder exceeds 2.5% by weight, the above-mentioned effect is not improved further while the material cost is greatly increased. Therefore, the titanium is preferably mixed 2.5% by weight.
상기 알루미나 분말은 고온으로 가열될 때 소결, 엉킴, 융착 방지 등의 목적으로 첨가된다. 이러한 알루미나 분말이 60중량% 미만으로 첨가되면, 소결, 엉킴, 융착 방지의 효과가 떨어지며, 알루미나 분말이 60중량%를 초과하면 상술한 효과는 더 개선되지 않는 반면에, 재료비가 크게 증가된다. 따라서, 알루미나 분말은 60중량%를 첨가하는 것이 바람직하다.The alumina powder is added for the purpose of sintering, tangling, fusion prevention, etc. when heated to a high temperature. When the alumina powder is added in less than 60% by weight, the effect of sintering, tangling and fusion prevention is inferior, and when the alumina powder exceeds 60% by weight, the above-mentioned effect is not further improved, while the material cost is greatly increased. Therefore, it is preferable to add 60 weight% of alumina powders.
상기 NH4Cl은 증기 상태의 아연, 마그네슘과 반응하여 확산 및 침투를 활성화시키는 역할을 한다. 이러한 NH4Cl은 30중량% 첨가된다. NH4Cl이 30중량% 미만으로 첨가되면, 증기 상태의 아연, 마그네슘과 반응이 제대로 이루어지지 않으며 이에 따라 확산 및 침투를 활성화시키지 못한다. 반면에, NH4Cl이 30중량% 초과하면 상술한 효과는 더 개선되지 않는 반면에, 재료비가 크게 증가된다. 따라서 NH4Cl은 30중량%를 첨가하는 것이 바람직하다.The NH 4 Cl reacts with zinc and magnesium in a vapor state to serve to activate diffusion and penetration. This NH 4 Cl is added 30% by weight. If NH 4 Cl is added at less than 30% by weight, it does not react properly with the vaporized zinc and magnesium and thus does not activate diffusion and penetration. On the other hand, when NH 4 Cl exceeds 30% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, it is preferable to add 30% by weight of NH 4 Cl.
상기 아연은 물에 닿는 금속의 부식을 방지하는 것과 전기 방식용으로 사용되도록 배합된다. 이러한 아연은 2.5중량%가 혼합된다. 아연의 혼합비율이 2.5중량%를 초과하면 물에 닿는 금속의 부식을 제대로 방지시키지 못하게 된다. 반면에 아연의 혼합비율이 2.5중량%를 초과하면 상술한 효과는 더 개선되지 않는 반면에 재료비가 크게 증가된다. 따라서 아연은 2.5중량% 혼합되는 것이 바람직하다.The zinc is formulated to prevent corrosion of metals in water and to be used for electrical applications. This zinc is mixed 2.5% by weight. If the mixing ratio of zinc exceeds 2.5% by weight, it will not properly prevent corrosion of the metal on water. On the other hand, when the mixing ratio of zinc exceeds 2.5% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, the zinc is preferably mixed 2.5% by weight.
상기 마그네슘의 순수한 금속은 구조강도가 낮으므로 상기 아연 등과 함께 조합하여 금속의 경도, 인장강도 및 염수에 대한 내식성을 높이는 용도로 배합된다. 이러한 마그네슘은 2.5중량% 혼합된다. 마그네슘의 혼합 비율이 2.5중량% 미만이면, 아연 등과 함께 조합될 시 금속의 경도, 인장강도 및 염수에 대한 내식성이 크게 개선되지 않는다. 반면에 마그네슘의 혼합 비율이 2.5중량%를 초과하면 상술한 효과는 더 개선되지 않는 반면에 재료비가 크게 증가된다. 따라서 마그네슘는 2.5중량% 혼합되는 것이 바람직하다.Since the pure metal of magnesium has a low structural strength, the magnesium is combined with zinc to increase the hardness, tensile strength and corrosion resistance of the metal. This magnesium is mixed 2.5% by weight. If the mixing ratio of magnesium is less than 2.5% by weight, the hardness, tensile strength and corrosion resistance to salt water of the metal when combined with zinc and the like are not significantly improved. On the other hand, when the mixing ratio of magnesium exceeds 2.5% by weight, the above-mentioned effect is not improved further, while the material cost is greatly increased. Therefore, magnesium is preferably mixed at 2.5% by weight.
상기 티타늄은 가볍고 단단하고 내부식성이 있는 전이 금속 원소로 은백색의 금속광택이 있는바, 뛰어난 내식성과 비중이 낮아 강철 대비 무게는 60% 밖에 되지 않으므로 금속모재에 도포되는 도포재의 중량은 줄이되 광택을 높이고 뛰어난 방수성 및 내식성을 갖도록 배합된다.The titanium is a light, hard and corrosion-resistant transition metal element has a silver-white metallic luster, and because of its excellent corrosion resistance and low specific gravity, the weight of the titanium is only 60% compared to steel, so that the weight of the coating material applied to the metal base material is reduced but the gloss is increased. It is formulated to have excellent waterproof and corrosion resistance.
이러한 티타늄은 2.5중량% 혼합된다. 티타늄의 혼합 비율이 2.5중량% 미만이면, 금속모재에 도포되는 도포재의 중량이 그다지 경감되지 않고, 광택성, 방수성, 내식성이 크게 개선되지 않는다. 반면에, 티타늄의 혼합 비율이 2.5중량%를 초과하면 상술한 효과는 더 개선되지 않는 반면에 재료비는 크게 증가된다. 따라서 티타늄은 2.5중량% 혼합되는 것이 바람직하다.This titanium is mixed 2.5% by weight. When the mixing ratio of titanium is less than 2.5% by weight, the weight of the coating material applied to the metal base material is not so much reduced, and the glossiness, waterproofness, and corrosion resistance are not greatly improved. On the other hand, if the mixing ratio of titanium exceeds 2.5% by weight, the above-mentioned effect is not further improved while the material cost is greatly increased. Therefore, the titanium is preferably mixed 2.5% by weight.
본 발명에 따른 냉각수조(720)의 표면 도포방법은 다음과 같다.The surface coating method of the cooling water tank 720 according to the present invention is as follows.
표면보호도포층이 형성되어야 할 냉각수조(720)와 상기 구성으로 배합된 도포재료를 폐쇄로 내에 함께 투입시키고 폐쇄로 내부에는 냉각수조(720)의 산화를 방지하기 위하여 2 L/min의 비율로 아르곤 가스를 주입시킨다, 아르곤 가스가 주입된 상태에서 700℃ 내지 800℃의 온도로 4 ~ 5 시간 동안 유지한다.In order to prevent the oxidation of the cooling water tank 720, the cooling water tank 720 and the coating material blended in the above-mentioned structure to be formed with the surface protective coating layer are put together in the closing furnace. Argon gas is injected, and maintained at a temperature of 700 ° C to 800 ° C for 4 to 5 hours while argon gas is injected.
상기 단계를 수행하여 증기 상태의 지르코늄 분말, 알루미나 분말, 아연, 마그네슘 및 티타늄이 폐쇄로 내부에 형성되고, 지르코늄 분말, 알루미나 분말, 아연, 마그네슘 및 티타늄 배합물은 모재의 표면에 침투하여 표면보호도포층이 형성된다.By performing the above steps, zirconium powder, alumina powder, zinc, magnesium, and titanium in a vapor state are formed inside of a closed state, and zirconium powder, alumina powder, zinc, magnesium, and titanium blend penetrate the surface of the base material to provide a surface protective coating layer. Is formed.
표면보호도포층이 형성된 후 폐쇄로 내부의 온도를 도포 물질/기재 복합물이 800℃~900℃로 하여 30 ~ 40시간을 유지하면 냉각수조(720)의 표면에는 부식 방지용 표면보호도포층이 형성되어 냉각수조(720)의 표면과 외기를 격리시키게 된다. 이때 상기 공정을 수행함에 있어 급격한 온도 변화는 냉각수조(720) 표면의 표면보호도포층이 박리될 수 있으므로 60℃/hr의 비율로 온도 변화를 시킨다.After the surface protective coating layer is formed, the internal temperature is closed to maintain the temperature of the coating material / substrate composite at 800 ° C. to 900 ° C. for 30 to 40 hours. A surface protection coating layer for preventing corrosion is formed on the surface of the cooling water tank 720. The surface of the cooling water tank 720 and the outside air is isolated. At this time, the sudden temperature change in performing the above process causes the surface protective coating layer on the surface of the cooling water tank 720 to be peeled off, thereby changing the temperature at a rate of 60 ° C / hr.
본 발명의 표면보호도포층은 다음과 같은 장점이 있다. The surface protective coating layer of the present invention has the following advantages.
본 발명의 표면보호도포층은 매우 넓은 범위의 용도를 가지므로 커튼 도포, 스프레이 페인팅, 딥 도포, 플루딩(flooding) 등과 같은 여러 가지 방법에 의해 도포될 수 있다.Since the surface protective coating layer of the present invention has a very wide range of uses, it can be applied by various methods such as curtain coating, spray painting, dip coating, flooding, and the like.
본 발명의 표면보호도포층은 부식 및/또는 스케일에 대한 원칙적인 보호 기능에 추가하여 도포가 매우 얇은 층두께로 도포될 수 있어 전기전도성을 개선하는 것은 물론 물질 및 비용 절감이 가능하다. 열간 성형 과정 이후에도 높은 전기전도성이 바람직하다면 얇은 전기전도성 프라이머가 도포층의 상부에 도포될 수 있다.The surface protective coating layer of the present invention can be applied with a very thin layer thickness in addition to the principle protection against corrosion and / or scale, thereby improving the electrical conductivity as well as material and cost savings. Even after hot forming, a thin electroconductive primer may be applied on top of the application layer if high electrical conductivity is desired.
성형 과정 또는 열간 성형 과정 이후, 도포 물질은 기재의 표면상에 유지될 수 있으며, 예를 들어, 긁힘 내성을 증가시키며, 부식 보호를 개선하고, 미적 외관을 충족시키며, 변색을 방지하고, 전기전도성을 변화시키며 종래 다운스트림 공정(예, 침린 및 전기이동 딥 도포)용 프라이머로 제공될 수 있다.After the forming process or the hot forming process, the coating material may be retained on the surface of the substrate, for example, to increase scratch resistance, to improve corrosion protection, to meet aesthetic appearance, to prevent discoloration, and to be electrically conductive. And can be provided as a primer for conventional downstream processes (eg, dip and electrophoretic dip coating).
이러한 본 발명의 냉각수조(720)에 지르코늄 분말, 알루미나 분말, NH4Cl, 아연, 마그네슘, 티타늄으로 이루어진 표면보호도포층이 도포되므로 먼지, 오염물질 등으로부터 냉각수조(720)의 표면의 부식현상을 방지시킬 수 있다.Since a surface protective coating layer made of zirconium powder, alumina powder, NH 4 Cl, zinc, magnesium, and titanium is applied to the cooling water tank 720 of the present invention, corrosion of the surface of the cooling water tank 720 from dust, contaminants, etc. Can be prevented.
이상 본 발명을 구체적인 실시예를 통하여 상세히 설명하였으나, 이는 본 발명을 구체적으로 설명하기 위한 것으로, 본 발명은 이에 한정되지 않으며, 본 발명의 기술적 사상 내에서 당 분야의 통상을 지식을 가진 자에 의해 그 변형이나 개량이 가능함이 명백하다.Although the present invention has been described in detail through specific examples, this is for explaining the present invention in detail, and the present invention is not limited thereto, and a person having ordinary skill in the art within the technical idea of the present invention. It is obvious that modifications and improvements are possible.
본 발명의 단순한 변형 내지 변경은 모두 본 발명의 범주에 속하는 것으로 본 발명의 구체적인 보호 범위는 첨부된 특허청구범위에 의해 명확해질 것이다.Simple modifications and variations of the present invention are all within the scope of the present invention, and the specific scope of protection of the present invention will be apparent from the appended claims.

Claims (3)

  1. 잔골재가 저장된 호퍼로 부터 배출되는 잔골재를 이송하는 이송 컨베이어(100);A transfer conveyor 100 for transferring the fine aggregate discharged from the hopper in which the fine aggregate is stored;
    상기 이송 컨베이어(100)를 통해 이송되어 온 잔골재를 소정온도로 가열하는 1차 가열로(200);A primary heating furnace (200) for heating the fine aggregate conveyed through the transfer conveyor (100) to a predetermined temperature;
    상기 1차 가열로(200)의 출구와 연통되게 구성되어, 상기 1차 가열로(200)로부터 제공되는 가열 상태의 잔골재가 그 온도를 일정하게 유지할 수 있도록 보온하는 2차 가열로(300);A secondary heating furnace 300 configured to communicate with an outlet of the primary heating furnace 200 to insulate the residual aggregate in a heating state provided from the primary heating furnace 200 to maintain a constant temperature thereof;
    상기 2차 가열로(300)부터 제공되는 가열 상태의 잔골재와 직경이 0.5 ~ 2.0cm로 분쇄된 재생 합성수지가 함께 투입되어, 가열상태의 잔골재에 의해 재생 합성수지를 용융시키는 용융로(400);A melting furnace 400 for melting the regenerated synthetic resin by adding the regenerated synthetic resin pulverized to a diameter of 0.5 to 2.0 cm and the heated aggregate provided from the secondary heating furnace 300 by heating;
    상기 용융로(400)로부터 제공되는 용융수지와 잔골재를 교반하여 혼합하되, 내부 온도가 220 ~ 290℃이고, 회전속도는 10 ~ 30rpm인 믹서(500);Mixing by mixing the molten resin and the fine aggregate provided from the melting furnace 400, the internal temperature is 220 ~ 290 ℃, the rotation speed is 10 ~ 30rpm mixer 500;
    상기 믹서(500)로부터 제공되는 용융수지와 잔골재의 혼합물을 30 ~ 40MPa의 압력으로 가압 성형하는 가압 성형기(600); 및A pressure molding machine 600 for press-molding the mixture of the molten resin and the fine aggregate provided from the mixer 500 at a pressure of 30 to 40 MPa; And
    상기 가압 성형기(600)에 의해 성형된 투수블록(1)을 이송시키면서 수냉 및 공냉에 의해 15 ~ 20sec 동안 이중 냉각하는 냉각기(700);를 포함하는 재생 합성수지를 이용한 투수블록의 제조시스템.And a cooler (700) for dual cooling by water and air cooling for 15 to 20 sec while transferring the permeable block (1) formed by the pressure molding machine (600).
  2. 청구항 1에 있어서,The method according to claim 1,
    상기 믹서(500)는, The mixer 500,
    원통형의 믹서통(510);Cylindrical mixer barrel 510;
    상기 믹서통(510)의 내주면에 길이방향을 따라 계단형으로 배치되는 다수의 교반날개(120)를 포함하되, 상기 각 교반날개(120)는 그 일부분이 인접한 교반날개와 중첩되게 배치되는 것을 특징으로 하는 재생 합성수지를 이용한 투수블록의 제조시스템.Including a plurality of stirring blades 120 which are arranged in the longitudinal direction on the inner circumferential surface of the mixer barrel 510, each of the stirring blades 120 is a portion of which is disposed to overlap with the adjacent stirring blades A system for producing a permeable block using recycled synthetic resin.
  3. 청구항 1에 있어서,The method according to claim 1,
    상기 냉각기(700)는,The cooler 700,
    상기 가압 성형기(600)에서 배출되는 각 투수블록(1)을 수용하는 냉각 트레이(710);A cooling tray 710 for receiving each water permeation block 1 discharged from the pressure molding machine 600;
    상기 투수블록(1)이 수용된 냉각 트레이(710)의 하부에 설치된 채 냉각 트레이를 냉각수에 침수시켜 수냉시키기 위한 횡장형의 냉각수조(720);A horizontal cooling water tank 720 installed in the lower portion of the cooling tray 710 in which the water permeation block 1 is accommodated so as to immerse the cooling tray in the cooling water to cool the water;
    상기 냉각 트레이(710)를 냉각수조(720)의 길이방향을 따라 이송시켜주는 이송 컨베이어(730);A transfer conveyor 730 for transferring the cooling tray 710 along the longitudinal direction of the cooling water tank 720;
    상기 냉각 트레이(710)의 상부에 냉각 트레이의 이동방향을 따라 설치되는 에어 공급관(740); 및An air supply pipe 740 installed on the cooling tray 710 along the moving direction of the cooling tray; And
    상기 에어 공급관(740) 상에 일정 간격으로 배치된 채 에어 공급관 내의 에어를 상기 투수블록(1)을 향해 분사하여 투수블록을 공냉시켜주는 에어노즐(750);을 포함하는 것을 특징으로 하는 재생 합성수지를 이용한 투수블록의 제조시스템.Regenerated synthetic resin comprising a; air nozzle 750 for air cooling the permeation block by injecting the air in the air supply pipe toward the permeation block (1) while being arranged at a predetermined interval on the air supply pipe (740) Pitching block manufacturing system using.
PCT/KR2018/000817 2017-04-03 2018-01-17 Water-permeable block production system using recycled synthetic resin WO2018186568A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201880004867.0A CN110049852B (en) 2017-04-03 2018-01-17 Permeable block manufacturing system using regenerated synthetic resin

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2017-0042889 2017-04-03
KR1020170042889A KR101814332B1 (en) 2017-04-03 2017-04-03 Water-permeable block manufacturing system using recycled synthetic resin

Publications (1)

Publication Number Publication Date
WO2018186568A1 true WO2018186568A1 (en) 2018-10-11

Family

ID=61070870

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2018/000817 WO2018186568A1 (en) 2017-04-03 2018-01-17 Water-permeable block production system using recycled synthetic resin

Country Status (3)

Country Link
KR (1) KR101814332B1 (en)
CN (1) CN110049852B (en)
WO (1) WO2018186568A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102101803B1 (en) 2018-10-24 2020-04-17 (주)천년기업 Auto forming apparatus for manufacturing water-permeable block using recycled material
KR102228813B1 (en) * 2019-03-27 2021-03-17 한국친환경에너지기술(주) method for manufacturing water permeable block

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR950008413B1 (en) * 1991-03-22 1995-07-28 가부시끼가이샤 신가와 Input method and apparatus of wire-bonding equipment
JP2001096143A (en) * 1999-09-29 2001-04-10 Lion Corp Rotation type cylindrical granulator and method for producing granule using the same
JP2002061102A (en) * 2000-08-23 2002-02-28 Mitsubishi Heavy Ind Ltd Recyclable water permeable ceramic pavement material and manufacturing method therefor
US20050175410A1 (en) * 2004-02-06 2005-08-11 Kang Sung S. Permeable and elastic pavement blocks
KR101598356B1 (en) * 2014-12-31 2016-02-29 한덕환 The manufacturing system of polymer blocks

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2640839B2 (en) * 1988-08-29 1997-08-13 日本重化学工業株式会社 Water-permeable, wear-resistant high-strength pavement composition
JPH03169901A (en) * 1989-11-27 1991-07-23 Mitsubishi Materials Corp Water-permeable pavement block and manufacturing method therefor
JP3443161B2 (en) * 1994-04-08 2003-09-02 共和運送株式会社 Method and apparatus for manufacturing composite material for pavement
JPH11181707A (en) * 1997-12-20 1999-07-06 Yuji Kono Pavement method using water-permeable resin pavement material, and manufacture of block
JP2000170113A (en) * 1998-12-03 2000-06-20 Toray Ind Inc Sand for sanded artificial lawn, structural body for sanded artificial lawn, and athletic field
CN1569432A (en) * 2004-04-29 2005-01-26 陈建成 Method for producing grass planting brick and water permeable brick using reclaimed waste plastic
KR101329555B1 (en) * 2012-06-05 2013-11-14 주식회사 코레스 Extrusion molding apparatus and control method thereof
CN204196039U (en) * 2014-09-15 2015-03-11 中天联合节能建设发展(天津)股份有限公司 A kind of polystyrene foam plate recycle device
CN104441327A (en) * 2014-12-08 2015-03-25 孙亚西 Method and equipment for producing environment-friendly rubber plate with infinite length by taking rubber powder as raw material
CN205112253U (en) * 2015-09-29 2016-03-30 惠州茂业科技有限公司 Plastic packaging bottle one shot forming device
CN105330246A (en) * 2015-10-29 2016-02-17 合肥正拓装饰材料有限公司 Composite water permeable brick having anti-bacterial effect

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR950008413B1 (en) * 1991-03-22 1995-07-28 가부시끼가이샤 신가와 Input method and apparatus of wire-bonding equipment
JP2001096143A (en) * 1999-09-29 2001-04-10 Lion Corp Rotation type cylindrical granulator and method for producing granule using the same
JP2002061102A (en) * 2000-08-23 2002-02-28 Mitsubishi Heavy Ind Ltd Recyclable water permeable ceramic pavement material and manufacturing method therefor
US20050175410A1 (en) * 2004-02-06 2005-08-11 Kang Sung S. Permeable and elastic pavement blocks
KR101598356B1 (en) * 2014-12-31 2016-02-29 한덕환 The manufacturing system of polymer blocks

Also Published As

Publication number Publication date
CN110049852A (en) 2019-07-23
CN110049852B (en) 2021-06-04
KR101814332B1 (en) 2018-01-30

Similar Documents

Publication Publication Date Title
WO2018186568A1 (en) Water-permeable block production system using recycled synthetic resin
WO2018186567A1 (en) Method for producing water-permeable block using recycled synthetic resin, and water-permeable block produced by said method
CN105500800A (en) High temperature resistance self-adhesion 3D (Three Dimensional) multi-color waterproof roll and preparation method thereof
CN105442725B (en) A kind of energy-saving prevention fire type external wall construction
CN106747619A (en) Sintered coal gangue expanded perlite water-permeable brick and preparation method thereof
CN104609887A (en) Integral sintering process and equipment for pure microcrystal and microcrystal mixed foamed composite plate
CN207211469U (en) A kind of ZCP pitched roofs energy-saving system structure
CN106747058A (en) Double-layer baking-free permeable brick with silicon manganese alloy slag as aggregate and preparation method thereof
CN102619316A (en) Foam concrete heat-insulation and decorative integrated plate for exterior wall of building
CN103039300A (en) Sunlight greenhouse
CN106045472B (en) A kind of preparation method of composite material ecological ceramic water-permeable brick
CN105924106A (en) Cement-based permeable crystallization type waterproof inorganic paint
CN104844261A (en) Haydite-reinforced heat-insulation aerated building block
CN104652739A (en) Heat preservation decoration plate and manufacturing method thereof
CN108359317A (en) A kind of non-bituminous chromatic spray painting rapid hardening water-repellent paint
CN101608055A (en) A kind of imitated ceramic plastic material
CN106630957A (en) Preparation method of painted-surface heat-preservation sintered brick
CN103669736B (en) Colorful flexible roof tile and preparation method thereof
CN202596098U (en) Wall surface structure and brick material structure
CN1325411C (en) Multicolor glass sand for building decoration
CN104909807A (en) High-waterproof non-leakage ceramsite enhanced aerated building block
CN109868913A (en) A kind of building waterproof system
CN104453109B (en) A kind of waterproof and heat-insulating roof and its construction technology
CN201447784U (en) Intelligent temperature-controlled fireproofing energy-saving wall
CN109912317A (en) Line style aerograph decorative effect glaze and preparation method thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18780402

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 18780402

Country of ref document: EP

Kind code of ref document: A1