WO2018153132A1 - 纤维素纤维织物湿法转移印花用浸轧液及其配制方法 - Google Patents

纤维素纤维织物湿法转移印花用浸轧液及其配制方法 Download PDF

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WO2018153132A1
WO2018153132A1 PCT/CN2017/113295 CN2017113295W WO2018153132A1 WO 2018153132 A1 WO2018153132 A1 WO 2018153132A1 CN 2017113295 W CN2017113295 W CN 2017113295W WO 2018153132 A1 WO2018153132 A1 WO 2018153132A1
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sodium
transfer printing
cellulose fiber
fiber fabric
wet transfer
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PCT/CN2017/113295
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French (fr)
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黄庄芳容
左凯杰
颜怀成
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黄庄芳容
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/66—Natural or regenerated cellulose using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/628—Compounds containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6491—(Thio)urea or (cyclic) derivatives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing

Definitions

  • the invention belongs to the technical field of textile printing, and particularly relates to a padding liquid for wet transfer printing of cellulose fiber fabric and a preparation method thereof.
  • the transfer printing process of fabrics is divided into dry transfer printing and wet transfer printing.
  • Dry transfer printing is thermal transfer printing, mainly used for transfer printing of polyester fabrics; wet transfer printing is called cold transfer in the past few years, mainly because the technology was applied to the transfer printing of cotton fabrics at the beginning of the research.
  • the cold-stacking process is also called cold transfer in order to distinguish it from thermal transfer and highlight its advantages in energy saving and emission reduction.
  • cold-stacking has the following advantages: 1 saving energy; 2 high dye utilization, bright color; 3 dyes can penetrate into the fiber, the pattern is not easy to white; 4 paste is always wet, easy to wash.
  • some problems in the production process can not be ignored, including: 1 low proofing efficiency, color is not easy to control; 2 fine line pattern is prone to flower type permeation during cold stacking; 3 for thin type Fabrics, due to the directness of the dyes, the amount of dye migration to the inside and the back of the fibers during cold stacking is different, resulting in an increase in chromatic aberration and variation.
  • the prior art can better solve the above problems by using a steaming solid coloring process instead of a cold stack to fix the color, and at the same time, a dye and a immersion liquid suitable for the steaming process.
  • a steaming solid coloring process instead of a cold stack to fix the color
  • a dye and a immersion liquid suitable for the steaming process there is still a problem that the cellulose fiber fabric after the wet transfer printing has a low color yield and a low fastness (only 3-4 grades).
  • the object of the present invention is to provide a padding liquid for wet transfer printing of a cellulose fiber fabric which can improve the color yield and fastness of a fabric after wet transfer printing, and a method for preparing the same.
  • the technical solution for achieving the object of the present invention is: a padding liquid for wet transfer printing of cellulose fiber fabric, which is prepared from the following components by weight: 2% to 5% sodium hydrogencarbonate, 0.1% to 2 % sodium carbonate, 0.5% to 2% sodium m-nitrobenzenesulfonate, 5% to 15% urea, 0.5% to 2% chelating dispersant, 1% to 3% anti-migration agent, 0.5 % to 2% paste and the balance of water.
  • the above chelate dispersant is an anionic surfactant which has a chelate dispersing action on ions such as iron, copper, magnesium and calcium.
  • the above anti-migration agent is an anionic surfactant which prevents the migration of the reactive dye during drying.
  • the above paste is modified starch, guar gum, sodium alginate, long gum or sodium carboxymethylcellulose.
  • the viscosity of the above paste is preferably 400 ⁇ 20 mPa ⁇ s (1%).
  • the preparation method of the above-mentioned cellulose fiber fabric wet transfer printing padding liquid has the following steps:
  • the solution obtained in the step 2 is filtered with a 200 mesh screen to obtain a padding solution.
  • the positive effect of the invention the wet transfer printing of the cellulose fiber fabric by using the padding liquid of the invention not only can make the fabric color saturated and uniform, the color yield is high, the flower pattern has high fineness, and the washing fastness can be Up to level 4 or above.
  • the padding liquid for wet transfer printing of the cellulose fiber fabric of the present embodiment is prepared from the following components by weight: 3% sodium hydrogencarbonate, 0.3% sodium carbonate, 2% m-nitrobenzenesulfonic acid Sodium, 5% urea, 1% chelating dispersant, 1.5% anti-migration agent, 2% paste and 85.2% water.
  • sodium m-nitrobenzenesulfonate is also the anti-staining salt S;
  • the chelate dispersing agent is HEPTOL WZB anionic surfactant of CHT Group of Germany;
  • the anti-migration agent is MIGRASOL SAP anionic surfactant of CHT Group of Germany; paste It is sodium alginate having a viscosity of 400 ⁇ 5 mPa ⁇ s (1%).
  • water, sodium hydrogencarbonate, sodium carbonate, sodium m-nitrobenzenesulfonate, urea, chelating dispersant, anti-migration agent and paste are sequentially used.
  • the solution obtained in the step 2 is filtered with a 200 mesh screen to obtain a padding solution.
  • the impregnation liquids of the respective examples and the respective proportions were used for the wet transfer printing of the cellulose fiber fabric (refer to the Chinese patent document CN106120405A for the specific method), and the relevant properties of the fabric after the wet transfer printing were tested. 3.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)

Abstract

本发明公开了一种纤维素纤维织物湿法转移印花用浸轧液及其配制方法，该浸轧液由下述重量百分比的组分配制而成：2%～5%的碳酸氢钠、0.1%～2%的碳酸钠、0.5%～2%的间硝基苯磺酸钠、5%～15%的尿素、0.5%～2%的螯合分散剂、1%～3%的防泳移剂、0.5%～2%糊料以及余量的水。该浸轧液的配制方法如下：先将碳酸氢钠和碳酸钠加入到水中并搅拌溶解；然后加入间硝基苯磺酸钠并搅拌溶解；接着加入尿素并搅拌溶解；再接着依次加入螯合分散剂和防泳移剂并搅拌溶解；最后缓慢加入糊料并缓慢搅拌至溶解；再过滤即得。采用本发明的浸轧液进行湿法转移印花不仅能够使得织物颜色饱和丰满，得色率高，而且水洗牢度可达4级以上。

Description

纤维素纤维织物湿法转移印花用浸轧液及其配制方法 技术领域
本发明属于纺织品印花技术领域，具体涉及一种纤维素纤维织物湿法转移印花用浸轧液及其配制方法。
背景技术
织物的转移印花工艺分为干法转移印花和湿法转移印花两种。干法转移印花即热转印，主要用于涤纶织物的转移印花；湿法转移印花前几年被称为冷转印，主要因为该项技术在研究初期是针对棉织物的转移印花，且采用冷堆固色工艺，为了与热转印相区别，且凸显其在节能减排方面的优势，故也称为冷转印。
采用冷堆固色固然有如下的优点：①节约能源；②染料利用率高，得色鲜艳；③染料可向纤维内部渗透，花型不易露白；④糊料始终处于润湿状态，易于水洗。但是该工艺在生产过程中存在的一些问题，也不容忽视，主要包括：①打样效率低，颜色不易把控；②精细线条花型在冷堆过程中易出现花型的渗化；③针对薄型织物，由于染料的直接性不同，冷堆过程中染料迁移到纤维内部及反面的量不同，从而导致色差及匹差增大。
现有技术通过采用蒸化固色工艺替代冷堆固色，同时配合适合蒸化工艺的染料和浸轧液，能够较好的解决上述问题。但是仍然存在湿法转移印花后的纤维素纤维织物得色率低、牢度不高(只有3-4级)的问题。
发明内容
本发明的目的在于针对现有技术的不足，提供一种能够提高湿法转移印花后织物得色率和牢度的纤维素纤维织物湿法转移印花用浸轧液及其配制方法。
实现本发明目的的技术方案是：一种纤维素纤维织物湿法转移印花用浸轧液，由下述重量百分比的组分配制而成：2％～5％的碳酸氢钠、0.1％～2％的碳酸钠、0.5％～2％的间硝基苯磺酸钠、5％～15％的尿素、0.5％～2％的螯合分散剂、1％～3％的防泳移剂、0.5％～2％糊料以及余量的水。
上述螯合分散剂为对铁、铜、镁、钙等离子有螯合分散作用的阴离子表面活性剂。
上述防泳移剂为对活性染料烘干时泳移有防止作用的阴离子表面活性剂。
上述糊料为改性淀粉、瓜儿豆胶、海藻酸钠、龙胶或者羧甲基纤维素钠。
上述糊料的粘度优选为400±20mPa·s(1％)。
上述纤维素纤维织物湿法转移印花用浸轧液的配制方法，具有以下步骤：
①按照配方依次称取水、碳酸氢钠、碳酸钠、间硝基苯磺酸钠、尿素、螯合分散剂、防泳移剂以及糊料待用；
②先将碳酸氢钠和碳酸钠依次加入到水中，边加边搅拌至完全溶解；然后加入间硝基苯磺酸钠，边加边搅拌至完全溶解；接着加入尿素，边加边搅拌至完全溶解；再接着依次加入螯合分散剂和防泳移剂，边加边搅拌至完全溶解；最后缓慢加入糊料，边加边快速搅拌至完全溶解；
③用200目滤网过滤步骤②得到的溶液，即得浸轧液。
本发明具有的积极效果：采用本发明的浸轧液进行纤维素纤维织物湿法转移印花，不仅能够使得织物颜色饱和丰满、均匀，得色率高，花型精细度高，而且水洗牢度可达4级以上。
具体实施方式
(实施例1)
本实施例的纤维素纤维织物湿法转移印花用浸轧液由下述重量百分比的组分配制而成：3％的碳酸氢钠、0.3％的碳酸钠、2％的间硝基苯磺酸钠、5％的尿素、1％的螯合分散剂、1.5％的防泳移剂、2％的糊料以及水85.2％。
其中，间硝基苯磺酸钠也即防染盐S；螯合分散剂为德国CHT集团的HEPTOL WZB阴离子表面活性剂；防泳移剂为德国CHT集团的MIGRASOL SAP阴离子表面活性剂；糊料为海藻酸钠，其粘度为400±5mPa·s(1％)。
本实施例的纤维素纤维织物湿法转移印花用浸轧液的配制方法具有以下步骤：
①按照配方依次称取水、碳酸氢钠、碳酸钠、间硝基苯磺酸钠、尿素、螯合分散剂、防泳移剂以及糊料待用。
②先将碳酸氢钠和碳酸钠依次加入到水中，高速搅拌机调至1400r/min，边加边搅拌约10min，使其完全溶解；然后加入间硝基苯磺酸钠，同样的转速下边加边搅拌约5min，使其完全溶解；接着加入尿素，同样的转速下边加边搅拌约5min，使其完全溶解；再接着依次加入螯合分散剂和防泳移剂，同样的转速下边加边搅拌约5min，使其完全溶解；最后缓慢加入糊料，将高速搅拌机转速调整为2800r/min，边加边快速搅拌约30min，使其完全溶解。
③用200目滤网过滤步骤②得到的溶液，即得浸轧液。
(实施例2～实施例5)
各实施例的浸轧液与实施例1的不同之处见表1。
表1
Figure PCTCN2017113295-appb-000001
(对比例1～对比例5)
各对比例的浸轧液与实施例1的不同之处见表2。
表2
Figure PCTCN2017113295-appb-000002
(应用例)
将各实施例和各对比例的浸轧液用于纤维素纤维织物的湿法转移印花(具体方法参考中国专利文献CN106120405A)，检测湿法转移印花后织物的相关性能，结果见表 3。
表3
Figure PCTCN2017113295-appb-000003

Claims (5)

  1. 一种纤维素纤维织物湿法转移印花用浸轧液，其特征在于由下述重量百分比的组分配制而成：2％～5％的碳酸氢钠、0.1％～2％的碳酸钠、0.5％～2％的间硝基苯磺酸钠、5％～15％的尿素、0.5％～2％的螯合分散剂、1％～3％的防泳移剂、0.5％～2％糊料以及余量的水。
  2. 根据权利要求1所述的纤维素纤维织物湿法转移印花用浸轧液，其特征在于：所述螯合分散剂为对铁、铜、镁、钙离子有螯合分散作用的阴离子表面活性剂。
  3. 根据权利要求1所述的纤维素纤维织物湿法转移印花用浸轧液，其特征在于：上述防泳移剂为对活性染料烘干时泳移有防止作用的阴离子表面活性剂。
  4. 根据权利要求1所述的纤维素纤维织物湿法转移印花用浸轧液，其特征在于：上述糊料为改性淀粉、瓜儿豆胶、海藻酸钠、龙胶或者羧甲基纤维素钠。
  5. 根据权利要求1至4之一所述的纤维素纤维织物湿法转移印花用浸轧液的配制方法，具有以下步骤：
    ①按照配方依次称取水、碳酸氢钠、碳酸钠、间硝基苯磺酸钠、尿素、螯合分散剂、防泳移剂以及糊料待用；
    ②先将碳酸氢钠和碳酸钠依次加入到水中，边加边搅拌至完全溶解；然后加入间硝基苯磺酸钠，边加边搅拌至完全溶解；接着加入尿素，边加边搅拌至完全溶解；再接着依次加入螯合分散剂和防泳移剂，边加边搅拌至完全溶解；最后缓慢加入糊料，边加边快速搅拌至完全溶解；
    ③用200目滤网过滤步骤②得到的溶液，即得浸轧液。
PCT/CN2017/113295 2017-02-24 2017-11-28 纤维素纤维织物湿法转移印花用浸轧液及其配制方法 WO2018153132A1 (zh)

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CN106868895A (zh) * 2017-02-24 2017-06-20 常州旭荣针织印染有限公司 纤维素纤维织物湿法转移印花用浸轧液及其配制方法
CN110055775A (zh) * 2019-05-07 2019-07-26 东丽酒伊织染（南通）有限公司 一种细旦高密涤纶面料的冷转移印花工艺
CN113073481B (zh) * 2021-03-26 2022-07-15 常州旭荣针织印染有限公司 一种提高棉针织物中ci活性蓝19固色率的方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101046060A (zh) * 2007-04-19 2007-10-03 四川大学 棉织物分散染料转移印花用表面改性剂及其预处理方法
CN102505525A (zh) * 2011-10-13 2012-06-20 上海长胜纺织制品有限公司 冷转移数码喷墨印花前处理液及其使用方法
CN106012594A (zh) * 2016-06-24 2016-10-12 常州旭荣针织印染有限公司 牛奶蛋白纤维/棉纤维交织织物湿法转移印花方法
CN106120405A (zh) * 2016-07-26 2016-11-16 常州旭荣针织印染有限公司 涤纶纤维/棉纤维交织织物湿法转移印花方法
CN106868895A (zh) * 2017-02-24 2017-06-20 常州旭荣针织印染有限公司 纤维素纤维织物湿法转移印花用浸轧液及其配制方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101046060A (zh) * 2007-04-19 2007-10-03 四川大学 棉织物分散染料转移印花用表面改性剂及其预处理方法
CN102505525A (zh) * 2011-10-13 2012-06-20 上海长胜纺织制品有限公司 冷转移数码喷墨印花前处理液及其使用方法
CN106012594A (zh) * 2016-06-24 2016-10-12 常州旭荣针织印染有限公司 牛奶蛋白纤维/棉纤维交织织物湿法转移印花方法
CN106120405A (zh) * 2016-07-26 2016-11-16 常州旭荣针织印染有限公司 涤纶纤维/棉纤维交织织物湿法转移印花方法
CN106868895A (zh) * 2017-02-24 2017-06-20 常州旭荣针织印染有限公司 纤维素纤维织物湿法转移印花用浸轧液及其配制方法

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