WO2018012021A1 - Produit cosmétique capillaire - Google Patents

Produit cosmétique capillaire Download PDF

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Publication number
WO2018012021A1
WO2018012021A1 PCT/JP2017/007058 JP2017007058W WO2018012021A1 WO 2018012021 A1 WO2018012021 A1 WO 2018012021A1 JP 2017007058 W JP2017007058 W JP 2017007058W WO 2018012021 A1 WO2018012021 A1 WO 2018012021A1
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WIPO (PCT)
Prior art keywords
acid
extract
hair
oil
component
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PCT/JP2017/007058
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English (en)
Japanese (ja)
Inventor
智史 山川
祐貴 勝間田
透 清水
幸浩 大橋
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日本精化株式会社
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Publication of WO2018012021A1 publication Critical patent/WO2018012021A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair

Definitions

  • the present invention relates to a hair cosmetic containing the following components (A) and (B).
  • B At least one selected from the group consisting of linear and branched saturated and unsaturated fatty acids having 12 to 31 carbon atoms, hydroxy fatty acids having 12 to 31 carbon atoms and polymers thereof.
  • Silicone compounds are widely used in cosmetics because they have low surface tension and excellent lubricity, and give a light touch and smoothness to skin and hair.
  • silicone with a low degree of polymerization is used for the purpose of imparting lightness and smoothness to the hair
  • silicone with a high degree of polymerization is used for the purpose of giving moist feeling and smoothness and protecting the hair.
  • amino-modified silicones modified with amino groups are used.
  • high-polymerization silicones are difficult to handle due to their high viscosity, so products with high-polymerization silicones dissolved in low-polymerization silicones are sold. Thus, it is possible to impart both of the above characteristics of the silicone compound to the hair cosmetic.
  • the silicone compound has build-up properties (accumulation on the hair surface), if the silicone-containing hair cosmetic is repeatedly used, the hair gradually becomes wrinkled or squeaked, and chemical hair treatment (waving, There has been a problem that it is difficult for the drug to penetrate into the hair when performing coloring or the like.
  • Patent Document 2 describes that a polyester having a weight average molecular weight of 30,000 to 1,000,000 containing one or both of dimer acid and dimer diol as a structural unit can be used as an alternative to high-polymerization silicone and amino-modified silicone.
  • the polyester feel equivalent to high-polymerization silicone and amino-modified silicone, gloss improvement effect, hair combing property improvement effect, splitting suppression effect by brushing can be obtained. It is disclosed that there is little build-up property.
  • the polyester can provide a feeling of use and effects equivalent to those of highly polymerized silicone and amino-modified silicone, it is not always satisfactory in terms of imparting a smooth feel like silicone with a low degree of polymerization. .
  • An object of the present invention is to provide a hair cosmetic having a low feeling of use and an effect equivalent to a hair cosmetic containing a silicone compound having a low polymerization degree and a high polymerization degree using a non-silicone compound. is there.
  • the inventors of the present invention have (A) at least one selected from the group consisting of dimer acid and dimer diol as a constituent unit, and have a weight average molecular weight of 30,000 to 1,000,000. At least one selected from the group consisting of polyester, (B) linear and branched saturated and unsaturated fatty acids having 12 to 31 carbon atoms, hydroxy fatty acids having 12 to 31 carbon atoms and polymers thereof.
  • the hair cosmetic composition of the present invention has the same feeling of moistness and smoothness as high-polymerized silicone and amino-modified silicone, the effect of improving gloss, the effect of improving the combing property of hair, and the effect of suppressing the occurrence of split ends by brushing. In addition, it has a smooth use feeling similar to that of low-polymerization silicone. On the other hand, since the hair cosmetic composition of the present invention is composed of only raw materials with low build-up properties, problems that are a concern with silicone compounds are suppressed even when used repeatedly.
  • the polyester containing as a constituent unit at least one selected from the group consisting of the dimer acid and dimer diol of the component (A) used in the present invention is produced using dimer acid and dimer diol described below as raw materials. .
  • Dimer acid is a known dibasic acid obtained by the intermolecular polymerization reaction of unsaturated fatty acids, and its industrial production process is almost standardized in the industry.
  • dimer acid or / and its lower alcohol ester is carbon It is obtained by dimerizing an unsaturated fatty acid having a number of 11 to 22 or a lower alcohol ester thereof with a clay catalyst or the like.
  • the dimer acid obtained industrially is mainly composed of a dibasic acid having about 36 carbon atoms, but contains an arbitrary amount of trimer acid and monomer acid depending on the degree of purification. In general, dimer acid content exceeding 70% by weight and dimer acid content increased to 90% by weight or more by molecular distillation are in circulation.
  • dimer acid that is further hydrogenated to improve oxidation stability that is, a hydrogenated dimer acid is also on the market.
  • any dimer acid currently in circulation can be used, but hydrogenated dimer acid is more preferable from the viewpoint of oxidation stability.
  • those derived from animal oils and fats and vegetable oils are distributed among these dimer acids, but those derived from vegetable oils and fats are more preferable.
  • dimer acid for example, PRIPOL 1006, 1009, 1015, 1025 of Croda, etc. are commercially available. These may be used alone or in combination of two or more.
  • the dimer diol is mainly composed of a diol having about 36 carbon atoms in which the dimer acid or / and lower alcohol ester thereof is hydrogenated in the presence of a catalyst and the carboxylic acid portion of the dimer acid is an alcohol.
  • industrially obtained dimer diol may contain other components such as trimer triol, monomer alcohol and ether compound. Products with dimer diol content exceeding about 70% by weight, and those with further dimer diol content exceeding 90% by weight, etc. are in circulation. Either can be used.
  • dimer diol those derived from animal fats and oils and vegetable fats and oils are distributed, but those derived from vegetable fats and oils are more preferable.
  • PRIDO 2033 of Croda etc. can be obtained as a commercial item. These may be used alone or in combination of two or more.
  • the polyester containing one or both of dimer acid and dimer diol used in the present invention as a structural unit is an ester of dimer acid and divalent alcohol other than dimer diol, dimer diol and divalent carboxylic acid other than dimer acid, and And a compound that includes one or more selected from esters of dimer acid and dimer diol.
  • a saturated linear, branched, ring-containing or cyclic divalent alcohol having 2 to 24 carbon atoms is preferable.
  • ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 1,5-pentanediol from the viewpoints of availability and feel of the resulting ester Neopentyl glycol, 2,2-dimethyl-1,3-propanediol, 1,6-hexanediol, hexylene glycol, 3-methyl-1,5-pentanediol, 2,2-diethyl-1,3- Propanediol, 2,2,4-trimethyl-1,5-pentanediol, 1,8-octanediol, 2-butyl-2-ethyl-1,3-propanediol, 2,4-diethyl-1,5- Pentanediol, 1,10-decanediol, 1,4-cyclohexanediol, 1,4-cyclohexyl
  • a saturated linear, branched or ring-containing divalent carboxylic acid having 4 to 24 carbon atoms is preferable.
  • malonic acid succinic acid, glutaric acid, adipic acid, 3-methylpentanedioic acid, azelaic acid, sebacic acid, 2,4-diethylpentanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid , Hexadecanedioic acid, octadecanedioic acid, icosanedioic acid, dimethylicosanedioic acid, docosanedioic acid, cyclohexanedicarboxylic acid, malic acid, tartaric acid and the like.
  • succinic acid glutaric acid, adipic acid, 3-methylpentanedioic acid, azelaic acid, sebacic acid, dodecanedioic acid, tetradecanedioic acid, hexadecanedioic acid are used from the viewpoint of availability and feel of the resulting ester.
  • Octadecanedioic acid, icosanedioic acid, dimethylicosanedioic acid, cyclohexanedicarboxylic acid and the like are preferable. These may be used alone or in combination of two or more.
  • a polyester containing both dimer acid and dimer diol as structural units in terms of exhibiting the effects of the present invention most. Even in such a case, a divalent carboxylic acid other than dimer acid and a divalent alcohol other than dimer diol may be included as a structural unit.
  • dimer dilinoleic acid dimer dilinoleyl is most preferred.
  • the polyester of component (A) in the present invention is a compound whose terminal is alcohol or carboxylic acid.
  • the polyester of the component (A) may be further esterified with a monovalent carboxylic acid or alcohol.
  • the terminal when it is a carboxylic acid, it may be in the form of a neutralized salt.
  • salts include alkali metal salts such as sodium and potassium, alkaline earth metal salts such as calcium and magnesium, metal salts such as aluminum, iron, zinc, copper and cobalt, basic amino acid salts such as lysine and arginine, triethylamine, Examples include organic amine salts such as stearylamine.
  • the polyester of component (A) in the present invention has a weight average molecular weight of 30,000 to 1,000,000, more preferably 70,000 to 500,000.
  • the weight average molecular weight of the component (A) polyester can be adjusted by changing the charging ratio of the divalent carboxylic acid to be reacted and the divalent alcohol.
  • the reaction ratio of the polyester of the component (A) when the terminal is an alcohol, the divalent carboxylic acid is used in an amount of 0.85 to 1.0 mol, more preferably 0, per 1 mol of the divalent alcohol. .95 to 1.0 mole.
  • the amount of divalent alcohol is 0.85 to 1.0 mol, more preferably 0.95 to 1.0 mol, per 1 mol of divalent carboxylic acid.
  • the polyester of component (A) in the present invention has a very high viscosity and does not crystallize, so that it becomes a glassy material having no fluidity at room temperature. Therefore, handling such as subdivision and weighing at room temperature is difficult.
  • the polyester of the above component (A) is excellent in compatibility with various oil agents, so it can be uniformly diluted with liquid oil and can be handled in a fluid state even at room temperature. It becomes possible.
  • Specific examples of liquid oils for diluting the component (A) polyester in the present invention include tri (caprylic / capric) glyceryl, neopentyl glycol dicaprate, diglyceryl triisostearate, and pentaerythrityl tetraisostearate.
  • Polyhydric alcohol fatty acid esters that are liquid at room temperature such as oils and fats such as soybean oil and rice bran oil, hydrocarbons that are liquid at room temperature such as hydrogenated polyisobutene, isododecane, and squalane, isopropyl palmitate, diethylhexyl sebacate, and apples
  • Monoalcohol carboxylic esters that are liquid at room temperature such as diisostearyl acid, acylamino acid diesters such as di- (phytosteryl / octyldodecyl) N-lauroyl-L-glutamate, and higher alcohols that are liquid at room temperature such as octyldodecanol Raised It is.
  • the component (A), component (B), component (C) and component (D) of the present invention can be mixed and dissolved in advance to form a premix, and then blended into the hair cosmetic composition of the present invention.
  • the dilution rate with liquid oil is not particularly limited, and may be diluted to such an extent that fluidity is obtained at room temperature.
  • the polyester ratio may be diluted to 0.1 to 99% by weight, preferably about 1 to 90% by weight.
  • the polyester of component (A) in the present invention has the same feel, improved gloss, improved combing properties of hair, and split ends by brushing, as described in high-polymerization silicone and amino-modified silicone.
  • the effect of suppressing the generation of hair can be imparted to hair cosmetics.
  • the amount of component (A) to be blended is not particularly limited, but it is usually 0.001 to 10% by weight, preferably about 0.01 to 2% by weight, in the hair cosmetic composition of the present invention.
  • Component (B) in the present invention is selected from the group consisting of linear and branched saturated and unsaturated fatty acids having 12 to 31 carbon atoms, hydroxy fatty acids having 12 to 31 carbon atoms and polymers thereof. At least one. Specifically, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid, eicosenoic acid, behenic acid, erucic acid, lignoceric acid, isopalmitic acid, isostearic acid , Ricinoleic acid, polyricinoleic acid, hydroxystearic acid, polyhydroxystearic acid, lanolin fatty acid.
  • Polyhydroxystearic acid is preferable, and palmitoleic acid, oleic acid, linoleic acid, linolenic acid, ricinoleic acid, isostearic acid, hydroxystearic acid, lanolin fatty acid, polyricinoleic acid, and polyhydroxystearic acid are more preferable. These may be blended singly or in combination of two or more.
  • the component (B) in the present invention can impart a silicone-like slipperiness with a lower polymerization degree to the hair without impairing the preferable effects of the component (A).
  • the amount of component (B) is not particularly limited, but is usually 0.01 to 10% by weight, preferably about 0.1 to 3% by weight.
  • ceramides in the hair cosmetic composition of the present invention, as component (C), ceramides; sterols and fatty acid esters thereof; fatty acid esters of dextrin, inulin and sucrose; amino acids; protein hydrolysates; hyaluronic acid; You may contain the at least 1 sort (s) of hair repair component selected from the group which consists of a white jellyfish polysaccharide.
  • ceramides sphingosine, phytosphingosine and their long chain fatty acid amides such as ceramide 1, ceramide 2, ceramide 3, ceramide 3B, ceramide 4, ceramide 5, ceramide 6, ceramide 6I, ceramide 6II, etc. Natural sp.
  • Sterols and fatty acid esters thereof include cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, and mixtures thereof, reduced lanolin, lanolin alcohol; ⁇ -sitosterol, campesterol, stigmasterol, brassicasterol, and mixtures thereof.
  • sterol fatty acid esters such as phytosteryl oleate, phytosteryl isostearate, macadamia nut oil fatty acid phytosteryl, and sunflower seed oil fatty acid phytosteryl.
  • fatty acid esters of dextrin, inulin and sucrose include ethylhexanoate dextrin, dextrin palmitate, dextrin myristate, dextrin isostearate; inulin palmitate, inulin stearate; sucrose laurate, sucrose palmitate, sucrose stearate, palm Oil fatty acid sucrose, sucrose dilaurate, sucrose distearate, sucrose trilaurate, sucrose tristearate, sucrose tribethenate, sucrose tetraisostearate, sucrose tetrahydroxystearate, sucrose pentahydroxystearate, sucrose pentaerucate, sucrose hexapalmitate Sucrose hexaisostearate,
  • Amino acids include betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, ⁇ -alanine, threonine, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine Leucine, isoleucine, valine, tryptophan, histidine, taurine, ⁇ -aminobutyric acid, ⁇ -amino- ⁇ -hydroxybutyric acid, carnitine, carnosine, creatine and the like.
  • Protein hydrolysates include collagenolytic peptide, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin degrading peptide, conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, Examples include soybean proteolytic peptide, wheat proteolytic peptide, hydrolyzed wheat protein, casein degrading peptide, keratin degrading peptide, hydrolyzing keratin and the like.
  • ceramide 2, ceramide 3, phytosterol, cholesterol, phytosteryl oleate, phytosteryl isostearate, macadamia nut oil fatty acid phytosteryl, and sunflower seed oil fatty acid phytosteryl are preferred from the standpoint of availability and the feel of the resulting hair cosmetic.
  • Component (C) in the present invention has an effect of repairing damaged hair and improving the feel of hair, and is used in combination for the purpose of further exhibiting the excellent effects of components (A) and (B). Can do.
  • the amount of component (C) to be blended is not particularly limited, but is usually 0.001 to 5% by weight, preferably about 0.002 to 2% by weight.
  • these may be blended singly or in combination of two or more.
  • the component (D) in the present invention can be further blended in the hair cosmetic composition of the present invention for the purpose of imparting a silicone-like slipperiness having a low polymerization degree as in the case of the component (B).
  • the amount of component (D) is not particularly limited, but is usually 0.01 to 10% by weight, preferably about 0.1 to 3% by weight.
  • water and additives added to normal cosmetics as necessary such as oil bases, surfactants, alcohols, humectants, polymers, thickeners, gelling agents, oxidation Antiseptics, antiseptics, bactericides, chelating agents, pH adjusters / acids / alkalis, UV absorbers, whitening agents, solvents, exfoliating / dissolving agents, antipruritics, anti-inflammatory agents, antiperspirants, cooling agents, antihistamines, Astringents, stimulants, hair-growth agents / blood circulation promoters, reducing agents / oxidants, polymer powders, hydroxy acids, vitamins and derivatives thereof, saccharides and derivatives thereof, organic acids, enzymes, nucleic acids, Hormones, inorganic powders, fragrances, pigments and the like can be blended.
  • additives added to normal cosmetics as necessary such as oil bases, surfactants, alcohols, humectants, polymers, thickeners, gelling agents, oxidation Antis
  • oily bases examples include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, ceralkyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexa Higher fatty acids such as
  • liquid paraffin mineral oil
  • heavy liquid isoparaffin heavy liquid isoparaffin
  • light liquid isoparaffin ⁇ -olefin oligomer
  • polyisobutene hydrogenated polyisobutene
  • polybutene squalane
  • olive-derived squalane squalene
  • petrolatum solid Type hydrocarbons such as candelilla wax, carnauba wax, rice wax, wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, fisher Tropsch wax, polyethylene wax, waxes such as ethylene / propylene copolymer
  • palm oil, palm oil, palm kernel oil, safflower oil olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut Oil, hazelnut oil, cucumber oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, peppermin
  • Lipid complex Lipid complex; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl parmitate, octyldodecyl palmitate, cetyl octanoate, hexyl decyl octanoate, isotridecyl isononanoate, isononyl isononanoate, isononanoate Isotridecyl acid, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octeodecanoate Ludodecyl, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate
  • humectants and feel improvers examples include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (Ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether, etc.
  • Ethoxydiglycol ethylene glycol monoethyl ether
  • ethylene glycol monobutyl ether diethylene glycol dibutyl
  • (eicosanedioic acid / tetradecanedioic acid) water-soluble esters such as polyglyceryl-10, tetradecanedioic acid polyglyceryl-10, cyclohexanedicarboxylic acid bisethoxydiglycol; sugars such as sorbitol, xylitol, erythritol, mannitol, maltitol Alcohols; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins ( ⁇ -, ⁇ -, ⁇ - Cyclodextrins and modified cyclodextrins such as maltosylation and hydroxyalkylation),
  • the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and a polymer surfactant.
  • an anionic surfactant a nonionic surfactant
  • a cationic surfactant a cationic surfactant
  • an amphoteric surfactant a polymer surfactant.
  • HLB of surfactant It can use from about 1 low thing to about 20 high thing, It is also preferable to combine a low thing and a high thing of HLB.
  • preferable surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth Polyoxyethylene alkyl sulfates such as sodium sulfate and laureth sulfate triethanolamine; cocoyl methyl taurine sodium, cocoyl methyl taurine potassium, lauroyl methyl taurine sodium, myristoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl sarcosine sodium, lauroyl sarcosine triethanol Acyl N-methyl amino acid salts such as amine and sodium methylalanine lauroylglutamate; Cocoyl Glue Acyl amino acid salts such as sodium phosphate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl gluta
  • Glycerin fatty acid partial esters polyglyceryl stearate 2, 3, 4, 5, 6, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate, polyglyceryl decastearate -10, polyglyceryl isostearate 2, 3, 4, 5, 6, 8, 8, diisostearate polyglyceryl-2 (diglyceryl diisostearate), 3, 10, polyglyceryl triisostearate 2.
  • Polyoxyethylene methyl glucoside fatty acid ester Polyoxyethylene alkyl ether fatty acid ester; Polyoxyethylene animal and vegetable fats and oils such as polyoxyethylene sorbitol beeswax; Isostearyl glyceryl ether, chimyl alcohol, seraalkyl alcohol, batyl Alkyl glyceryl ethers such as alcohols; polyhydric alcohol alkyl ethers; polyoxyethylene alkyl amines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponins and sophorolipids; polyoxyethylene fatty acids Amides; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), la Phosphoric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide M
  • Fatty acid amide alkyl-N, N-dimethylamino acid betaines include imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkylsulfobetaines such as alkyldimethyltaurine; sulfate-type betaines such as alkyldimethylaminoethanol sulfate; alkyldimethylamino Phosphate betaines such as ethanol phosphates; sphingophospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, sphingomyelin, lysolecithin, water Phospholipids such as raw-added soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid, and hydroxylated lecithin; silicone-based amphoteric surfactants; Preferable examples include polyvinyl alcohol,
  • Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, far selelain, karaya gum, troarooi, cara gum, tragacanth gum, pectin, pectic acid and sodium Salt such as salt, salt such as alginic acid and sodium salt, mannan; starch such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salt, xanthan gum, pullulan, gellan gum, chitin , Chitosan, agar, gypsophila extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypro Cellulose, carboxymethylcellulose and its sodium salts, methylhydroxypropylcellulose,
  • Solvents and propellants include ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol and other lower alcohols; propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol and other glycols Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether Glycol ether esters such as diacetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; glycol esters such as dieth
  • Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or derivatives thereof; erythorbic acid and derivatives thereof; Preferred are sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride As mentioned.
  • Preferred examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like.
  • Preferred examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.
  • Antibacterial agents or antiseptics include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane 1,2-alkanediols such as diols; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); salicylic acid; sodium benzoate; isothiazolinone derivatives such as methyl chloroisothiazolinone and methylisothiazolinone; Dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, chloride Sar
  • chelating agents include edetate (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; Phosphonic acid and its sodium salt; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine Gluconic acid, ascorbic acid, succinic acid, and tartaric acid are preferable.
  • edetate ethylenediaminetetraacetate
  • HEDTA3Na EDTA3Na
  • EDTA4Na hydroxyethylethylenediaminetriacetate
  • pentetate diethylenetriaminepent
  • pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylated Sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate are preferable.
  • powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (for example, zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium oxide, fine particles and super Titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultraf
  • Inorganic salts include sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum sulfate / potassium sulfate (alum), aluminum sulfate / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na and 3Na phosphates, phosphoric acid Potassium, calcium phosphates and magnesium phosphates are preferred.
  • sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt
  • potassium chloride aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chlor
  • ultraviolet absorbers examples include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoic acid ethyl ester.
  • Benzoic acid ultraviolet absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; Anthranilic acid ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; Salicylic acid And salicylic acid systems such as sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate External line absorbent: octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropy
  • Benzophenone series External line absorber 3- (4′-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2′-hydroxy-5- 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole; 2- (2′-hydroxy-5′-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 5- (3 , 3-dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octyl triazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 1- 3,4-dimethoxyphenyl)
  • hydantoin derivatives phenylbenzimidazolazosulfonic acid, terephthalylidene dicamphor Preferred are sulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and derivatives thereof, oryzanol and derivatives thereof.
  • Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; ⁇ , Vitamin E such as ⁇ , ⁇ , and ⁇ -tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt, Ascorbic acid fatty acid esters
  • Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract A plant extract such as a koji leaf extract is preferable.
  • Plant growth and tinctures such as assembly extract, red pepper tincture, ginger tincture, ginger extract, cantalis tincture; capsaicin, nonyl acid valenylamide, gingeron, ictamol, tannic acid Borneol, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, ⁇ -oryzanol, cephalanthin, vitamin E and derivatives such as tocopherol / nicotinic acid tocopherol, ⁇ -oryzanol, nicotinic acid and nicotinamide / benzyl nicotinate Derivatives such as ester, inositol hexanicotinate, nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, Preferable examples include flavonol derivatives,
  • Preferred hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like.
  • Other remedies such as anti-wrinkle agents, anti-aging agents, squeeze agents, cooling sensations, warming sensation agents, wound healing promoters, irritation relievers, analgesics, cell activators include retinols, retinoic acids, retinoin Acid tocopheryl; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, ⁇ - or such as hydroxycapric acid, long chain ⁇ -hydroxy fatty acid, long chain ⁇ -hydroxy fatty acid cholesteryl ⁇ -hydroxy acids and derivatives thereof; ⁇ -aminobutyric acid, ⁇ -amino- ⁇ -hydroxybutyric acid; carnitine; carnosine; creatine; ceramides, sphingosines; caffeine, x
  • Antioxidant / active oxygen scavengers include catechins; flavones such as quercetin; isoflavones; gallic acid and ester sugar derivatives; polyphenols such as tannin, sesamin, protoanthocyanidin, chlorogenic acid, apple polyphenol; rutin and glycosides, etc.
  • Preferred examples include capsaicin, vanillin and the like and derivatives; insect repellents such as diethyltoluamide; and complexes of physiologically active substances and cyclodextrins.
  • antipruritic agents include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor and the like.
  • exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like.
  • antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, and zinc paraphenol sulfonate.
  • Examples of the refreshing agent include menthol and methyl salicylate.
  • the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid.
  • enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, and the like.
  • Preferred nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and adenosine triphosphate disodium.
  • Orange No. 204 Yellow No. 205, Yellow No. 401, Blue No. 404, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205
  • Organic pigments such as zirconium, barium or aluminum lake such as yellow No. 4, yellow No. 5, yellow No. 202, yellow No. 203, green No. 3 and blue No.
  • anthraquinones such as astaxanthin and alizarin
  • Natural pigments and dyes such as naphthoquinones such as cumin, cochineal, shikonin, bixin, flavones, betacyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, Oxidative dye intermediates and couplers such as m-, or p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and their salts; indoline, etc.
  • An auto-oxidizing dye such as m
  • preferable water examples include normal water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionic water, and cluster water.
  • cosmetic ingredient standards cosmetic ingredient-specific formulation standards, Japan Cosmetic Industry Association ingredient name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), Quasi-drug ingredient standards, Japanese Pharmacopoeia, Pharmaceutical Additives Ingredients listed in standards, official food additives, etc., and Japanese and foreign patent publications and patent publications (including publications and republications) in which the international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the ingredients described, in known combinations, blending ratios and blending amounts.
  • the hair cosmetic composition of the present invention preferably does not contain silicones.
  • the accumulation property (build-up property) of silicones on the hair surface is suppressed, and even if hair cosmetics are used repeatedly, The occurrence of squeaks is further suppressed, and the chemicals are more likely to penetrate into the hair when performing chemical hair treatment (waving, coloring, etc.).
  • the upper limit of the content is preferably 0.1% by weight, more preferably 0.05% by weight, and further 0.01% by weight. preferable.
  • the hair cosmetics in the present invention include oil shampoo, cream shampoo, conditioning shampoo, dandruff shampoo, hair color shampoo, rinse-in shampoo, etc .; rinse, treatment, leave-on treatment, hair essence, hair pack, hair oil, hair Foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, set lotion, color lotion, hair liquid, pomade, tic, hair cream, hair blow, split hair coat, hair oil, permanent wave agent, oxidative hair dye , Hair bleach, hair color pre-treatment, hair color after-treatment, perm pre-treatment, perm after-treatment, hair Cure, can be exemplified hair tonic or the like.
  • emulsified cosmetics such as oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type, etc.
  • a weight average molecular weight means the numerical value by polystyrene conversion measured by gel permeation chromatography (GPC). In this invention, it is the value measured with the following apparatuses and conditions.
  • Analysis device GPC-8020 (manufactured by Tosoh Corporation) Column: TSK-GEL G3000HHR (7.8 ⁇ 300 mm, manufactured by Tosoh Corporation) TSK-GEL G2000HHR (7.8 ⁇ 300mm, manufactured by Tosoh Corporation) TSK-GEL GMHHR-M (7.8 ⁇ 300mm, manufactured by Tosoh Corporation) Detector: RI detector RI-8020 (manufactured by Tosoh Corporation) Solvent: Tetrahydrofuran Measurement temperature: 40 ° C Flow rate: 1.0 mL / min
  • Synthesis Examples 2 to 5 Production of Polyester An esterification reaction was carried out in the same manner as in Synthesis Example 1 except that the ratio of hydrogenated dimer acid to dimer diol was changed to the ratio shown in Table 1 to obtain the target polyester.
  • Synthesis Example 6 Production of polyester As hydrogenated dimer acid, PRIPOL 1025 was used instead of PRIPOL 1006, and the ratio of dimer acid and dimer diol was changed from 1.0: 1.0 to 0.95: 1.0. An esterification reaction was carried out in the same manner as in Synthesis Example 1 to obtain the target polyester.
  • ⁇ Hair feel evaluation method> A healthy black-haired human hair was bleached once with a commercially available two-component oxidized bleaching agent to produce a hair bundle (25 cm ⁇ 5 g) of damaged hair.
  • the hair bundle was washed with 3% aqueous laureth sulfate solution, 0.5 g of each hair cosmetic was applied, left for 2 minutes, rinsed for 30 seconds under running water, and dried with a dryer.
  • the touch was evaluated by five professional panelists.
  • the evaluation points were the following 5 stages, and the hair cosmetics of Comparative Example 1 were compared with other hair cosmetics with 3 points. The results are shown as the average value of 5 panelists. 5 points: very good, 4 points: good, 3 points: same, 2 points: not good, 1 point: not good
  • the hair cosmetics of the present invention (Examples 1 to 8) have the same feeling of use as compared with the hair cosmetics containing silicone (Comparative Examples 5 and 6). there were. Moreover, in the hair cosmetics which mix
  • Example 9 Hair Treatment A treatment having the following formulation was prepared. This treatment was a treatment capable of improving hair damage without giving silicone and giving a moist feeling, smoothness, a smooth feeling and a long-lasting feeling.
  • Example 10 Hair Treatment A treatment having the following formulation was prepared. This treatment can improve hair damage and give a moist feeling and a smooth feeling like silicone. Further, after washing with shampoo, no residual feeling on the hair was felt.
  • Example 11 Hair Treatment A treatment having the following formulation was prepared. This treatment can improve hair damage and give a moist feeling and a smooth feeling like silicone. Further, after washing with shampoo, no residual feeling on the hair was felt.
  • Component Blending amount (% by weight) --------------------------------------------------------------------------------------------------------------------------------------------------- Part A Polyester of Synthesis Example 1 0.2 Linolenic acid 0.5 Lanolin fatty acid 0.5 Macadamia nut fatty acid phytosteryl 0.2 (Plandool-MAS: Nippon Seika) Dineopentanoic acid methylpentanediol 1.0 (Neosolu-MP: Nippon Seika) Ceramide 2 0.001 Ceramide 6 0.001 Part B stearoxypropyltrimonium chloride 1.0 Cetrimonium chloride 0.3 Dialkyl (C12-18) dimonium chloride 0.3 Ste
  • Example 12 Hair Treatment A treatment having the following formulation was prepared. This treatment can improve hair damage and give a moist feeling and a smooth feeling like silicone. Further, after washing with shampoo, no residual feeling on the hair was felt.
  • Example 13 Hair Treatment A treatment having the following formulation was prepared. This treatment can improve hair damage and give a moist feeling and a smooth feeling like silicone. Further, after washing with shampoo, no residual feeling on the hair was felt.
  • Example 14 Treatment A treatment having the following formulation was prepared. This treatment can improve hair damage and give a moist feeling and a smooth feeling like silicone. Further, after washing with shampoo, no residual feeling on the hair was felt.
  • Example 15 Treatment A treatment having the following formulation was prepared. This treatment can improve hair damage and give a moist feeling and a smooth feeling like silicone. Further, after washing with shampoo, no residual feeling on the hair was felt.
  • Example 16 Shampoo A hair shampoo having the following formulation was prepared. This shampoo was excellent in foaming and was able to give a feeling of use that was moisturized and smooth without using silicone.
  • Example 17 Dandruff Shampoo A dandruff shampoo having the following formulation was prepared. This shampoo was a shampoo capable of suppressing dandruff, imparting a moist feeling and gloss to hair without using silicone, and imparting a smooth finger passage. Component Blending amount (% by weight) --------------------------------------------------------------------- Part A Polyester of Synthesis Example 4 0.05 Ricinoleic acid 0.1 Lauroylmethylalanine Na (30%) 13.0 Cocamidopropyl betaine (30%) 20.0 Cocoa glutamic acid TEA (30%) 5.0 Cocamide DEA 1.0 Glycerin 1.0 Glyceryl caprylate 0.4 Glyceryl undecylenate 0.1 Isostearoyl hydrolyzed collagen 0.5 (Eicosanedioic acid / Tetradecanedioic acid) Polyglyceryl-10 1.0 (Neosolu-AquaS: Nippon Seika) Distearate glycol 1.5 Part B
  • Cocamidomethyl MEA 1.0 Distearate glycol 0.5 Palm oil fatty acid PEG-7 glyceryl 0.3 Ascorbyl dipalmitate 0.2 Lauric acid PEG-2
  • Example 22 Shampoo A hair shampoo having the following formulation was prepared. This shampoo was excellent in foaming and was able to give a feeling of use that was moisturized and smooth without using silicone.
  • Example 23 Shampoo A hair shampoo having the following formulation was prepared. This shampoo was excellent in foaming and was able to give a feeling of use that was moisturized and smooth without using silicone.
  • part E part D was heated to about 80 ° C. and dissolved. While stirring D part to E part, it was gradually added and mixed uniformly, and then rapidly cooled (part F). C part was added to F part which became about 40 ° C. to make it uniform.
  • Example 25 Hair Wax A hair wax having the following formulation was prepared. This hair wax was not sticky, had a smooth feeling of use, had good adhesion to hair, and was excellent in setability.
  • Example 26 Hair Wax A hair wax having the following formulation was prepared. This hair wax was sticky to the touch and had good adhesion to the hair and excellent setability. Further, the hair was given a harsh feeling and was able to suppress undulation and entanglement both when wet and when dry.
  • Example 27 Mousse A mousse having the following formulation was prepared. This mousse suppressed hair damage, was not sticky, and had excellent hairstyle retention.
  • part E was heated to about 80 ° C. to make it uniform. While stirring D part to E part, it was gradually added and mixed uniformly, and then rapidly cooled (part F). C part was added to F part which became about 40 ° C. to make it uniform.
  • Example 30 Hair Oil A hair oil having the following formulation was prepared. This hair oil was glossy, non-sticky and imparted a smooth feeling when applied to hair. Component Blending amount (% by weight) --------------------------------- Polyester of Synthesis Example 1 3.0 Oleic acid 0.8 Elcalactone DES (Nippon Seika) 2.0 Neosolute-MP (Nippon Seika) 10.0 Neosolute-EHS (Nippon Seika) 10.0 Neosolute-MCT (Nippon Seika) 20.0 PPG-3 caprylyl ether 2.0 Tocopherol 0.1 Propylparaben 0.05 Carnauba wax 0.1 Isododecane in a total amount of 100 ----------------------------------- (Preparation method) All ingredients were dissolved by heating and mixed.

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Abstract

L'invention fournit un produit cosmétique capillaire qui consiste en un composé sans silicone, et qui permet de conférer une sensation lisse et une sensation de fraîcheur similaires à celles d'un composé silicone. Plus précisément, l'invention concerne un produit cosmétique capillaire qui comprend les composants (A) et (B) suivants. (A) : polyester de masse moléculaire moyenne en poids comprise entre 30000 et 1000000, qui contient en tant qu'unité structurale au moins un élément choisi dans un groupe constitué d'un acide dimérisé et d'un dimère diol. (B) : au moins un élément choisi dans un groupe constitué d'un acide gras saturé et insaturé à chaîne droite et à chaîne ramifiée de 12 à 31 atomes de carbone, et d'un acide gras hydroxylé de 12 à 31 atomes de carbone ainsi que d'un polymère de celui-ci.
PCT/JP2017/007058 2016-07-13 2017-02-24 Produit cosmétique capillaire WO2018012021A1 (fr)

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WO2020160904A1 (fr) * 2019-02-04 2020-08-13 Symrise Ag Agents actifs pour soins de la peau et des cheveux avec des propriétés de modification physico-chimique
WO2020160905A1 (fr) * 2019-02-04 2020-08-13 Symrise Ag Activité antimicrobienne d'esters d'acides gras et combinaisons de ceux-ci
WO2020160741A1 (fr) * 2019-02-04 2020-08-13 Symrise Ag Esters d'acides gras en tant qu'agents anti-malassezia
WO2022145430A1 (fr) * 2020-12-28 2022-07-07 花王株式会社 Composition d'émulsion

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JP7158865B2 (ja) * 2018-02-21 2022-10-24 花王株式会社 化粧料
WO2020095425A1 (fr) * 2018-11-09 2020-05-14 日本精化株式会社 Produit cosmétique
JP7361368B2 (ja) * 2019-09-02 2023-10-16 株式会社アリミノ 毛髪洗浄剤、毛髪化粧料セット、シャンプー・トリートメント処理方法、および酸・熱トリートメント処理方法

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JP2007045776A (ja) * 2005-08-11 2007-02-22 Nippon Fine Chem Co Ltd 保湿剤及びこれを含有する化粧料及び皮膚外用剤
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JP2019196318A (ja) * 2018-05-08 2019-11-14 株式会社ヤクルト本社 高内相ｗ／ｏ型乳化組成物及び化粧料
JP7094139B2 (ja) 2018-05-08 2022-07-01 株式会社ヤクルト本社 高内相ｗ／ｏ型乳化組成物及び化粧料
WO2020160904A1 (fr) * 2019-02-04 2020-08-13 Symrise Ag Agents actifs pour soins de la peau et des cheveux avec des propriétés de modification physico-chimique
WO2020160905A1 (fr) * 2019-02-04 2020-08-13 Symrise Ag Activité antimicrobienne d'esters d'acides gras et combinaisons de ceux-ci
WO2020160741A1 (fr) * 2019-02-04 2020-08-13 Symrise Ag Esters d'acides gras en tant qu'agents anti-malassezia
WO2020160743A1 (fr) * 2019-02-04 2020-08-13 Symrise Ag Agents actifs pour soins de la peau et des cheveux avec des propriétés de modification physico-chimique
CN113507917A (zh) * 2019-02-04 2021-10-15 西姆莱斯有限公司 具有物理化学修饰特性的皮肤和头发护理用活性剂
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WO2022145430A1 (fr) * 2020-12-28 2022-07-07 花王株式会社 Composition d'émulsion

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