WO2018006730A1 - 一种氨基酸蔬果净 - Google Patents

一种氨基酸蔬果净 Download PDF

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WO2018006730A1
WO2018006730A1 PCT/CN2017/090457 CN2017090457W WO2018006730A1 WO 2018006730 A1 WO2018006730 A1 WO 2018006730A1 CN 2017090457 W CN2017090457 W CN 2017090457W WO 2018006730 A1 WO2018006730 A1 WO 2018006730A1
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amino acid
vegetable
surfactant
fruit
net
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PCT/CN2017/090457
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French (fr)
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张健
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张健
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

Definitions

  • the invention relates to a vegetable and fruit net, and more particularly to an amino acid vegetable and fruit net with an amino acid surfactant as the only clean component, which is safe and environmentally friendly, and belongs to the field of consumer goods for daily use.
  • the fruits and vegetables are a blended product, which can be used for washing fruits and vegetables. In recent years, it has developed very rapidly in the country and is an indispensable washing product for the catering industry and the family. At present, the fruits and vegetables on the market have strong detergency, concentrated type and strong bactericidal power.
  • the active ingredients of vegetable and fruit detergents are mainly surfactants.
  • Traditional vegetable and fruit detergents mainly use chemical synthetic surfactants, such as sodium dodecylbenzenesulfonate LAS, sodium lauryl sulfate AS, sodium lauryl sulfate. AES, sodium secondary alkylsulfonate SAS, etc. are used as raw materials. However, most of them are not easily degraded or degraded, causing pollution to the environment.
  • the main object of the present invention is to provide an amino acid vegetable and fruit net which is safe and environmentally friendly with an amino acid surfactant as the sole cleansing ingredient.
  • the technical solution adopted by the present invention comprises: an amino acid vegetable and fruit net comprising an amino acid surfactant; the amino acid surfactant is a main active ingredient; and the weight ratio of the amino acid surfactant is 0.1-25 %;
  • the amino acid vegetable and fruit net also contains water, a moisturizing agent and a preservative, and the weight percentages thereof are respectively:
  • the humectant is 0.5-5%
  • Preservative is 0.1-1%
  • the pH of the amino acid vegetable is in the range of 6-8.
  • the weight ratio of the amino acid surfactant is 5-20%.
  • the weight ratio of the amino acid surfactant is 10-15%.
  • the amino acid surfactant is mainly alanine type surfactant, and the alanine type surfactant accounts for more than 60% by weight of the total surfactant, wherein the alanine type surfactant accounts for the total.
  • the weight percentage of the surfactant is preferably 70% or more.
  • the alanine type surfactant comprises at least one of sodium N-lauroyl-L-alaninate and sodium cocamidopropionate in a concentration of 98% or more.
  • the present invention has at least the following advantages:
  • the amino acid vegetable and fruit net of the invention adopts amino acid surfactant as the main active ingredient, instead of the traditional vegetable and fruit net surfactants, such as LAS, AS, AES, SAS, and does not contain fluorescent whitening agent, and is free of chemistry.
  • the invention adopts biodegradable natural amino acid surfactant, non-toxic, non-corrosive, non-polluting, no residue; dedicated to cleaning fruits and vegetables, Efficient and rapid removal of herbicides, insecticides, fungicides, dirt, fruit waxes, oily substances and other undesirable substances on the surface to ensure food safety.
  • Figure 1 is the first page of the ingredient inspection report of the amino acid vegetable and fruit net according to the present invention.
  • Figure 3 is a third page of the component inspection report of the amino acid vegetable and fruit net according to the present invention.
  • Figure 4 is a fourth page of the composition test report of the amino acid vegetable and fruit net of the present invention.
  • Figure 5 is the first page of the performance test report 1 of the amino acid vegetable and fruit net according to the present invention.
  • Figure 6 is a second page of the performance test report 1 of the amino acid vegetable and fruit net according to the present invention.
  • Figure 7 is a third page of the performance test report 1 of the amino acid vegetable and fruit net according to the present invention.
  • Figure 8 is a fourth page of the performance test report 1 of the amino acid vegetable and fruit net of the present invention.
  • Figure 9 is the first page of the performance test report 2 of the amino acid vegetable and fruit net according to the present invention.
  • Figure 10 is a second page of the performance test report 2 of the amino acid vegetable and fruit net according to the present invention.
  • Figure 11 is a third page of the performance test report 2 of the amino acid vegetable and fruit net according to the present invention.
  • Fig. 12 is a fourth page of the performance test report 2 of the amino acid vegetable and fruit net according to the present invention.
  • the amino acid vegetable and fruit net of the invention comprises an amino acid surfactant; the amino acid surfactant is used as a main active ingredient; the amino acid surfactant is mainly alanine type surfactant, and the alanine type surface active agent Agent as a percentage of total surfactant
  • the ratio is more than 60%, wherein the alanine type surfactant is more preferably 70% by weight or more based on the total surfactant; the alanine type surfactant contains at least 98% or more of N-lauroyl group.
  • the amino acid vegetable and fruit net also contains water, sodium hydroxide, carcass, glycerin, and flavor; the amino acid and fruit have a net pH range of 6-8.
  • the weight percentages of the components of the amino acid fruits and vegetables are shown in Table 1 and Table 2. A total of 10 examples are listed.
  • Amino acids are familiar to us. They are one of the many biologically active molecules that build biological organisms, or the basic materials for building human cells and repairing human tissues.
  • Amino acids are the basic unit of protein, which is one of the most important active molecules in the body, including enzymes that catalyze metabolism.
  • the amino acid surfactant in the amino acid vegetable and fruit net produced by the invention contains at least one of N-lauroyl-L-alanine sodium salt and cocoamido alanine sodium salt at a concentration of 98% or more, instead of The traditional fruit and vegetable net surfactants, such as LAS, AS, AES, SAS-based surfactants. Tested: Alanine-type surfactant produced by using alanine surfactant in a weight ratio of less than 60% of total surfactant, alanine type having a foam richness ratio of 60% or more by weight of total surfactant The amino acid fruits and vegetables produced by the surfactant are low in net, relatively stable in stability, and have poor detergency.
  • the basic raw material for preparing the vegetable and fruit net is also included.
  • Tables 1 and 2 refers to parts by weight, and the total weight fraction of the amino acid fruits and vegetables in Examples 1 to 10 is 100.
  • the core of the invention is to use amino acid surfactant as the main surface active ingredient to be added to the fruit and vegetable net and to verify its non-toxic, non-corrosive, non-polluting, residue-free and high-efficiency and quick-cleaning ability in the fruit and vegetable net.
  • the present invention has at least the following advantages:
  • the amino acid and vegetable fruit net of the invention adopts amino acid surfactant as the main active ingredient, instead of the traditional vegetable and fruit net surfactants, such as LAS, AS, AES, SAS; eliminating chemical damage and human body damage and environment Contaminated, non-irritating, non-allergic, kitchen efficient and clean, clean ingredients using biodegradable natural amino acid surfactant, non-toxic, non-corrosive, non-polluting, no residue; can quickly and effectively remove oil stains on the surface of kitchen utensils To ensure food safety.
  • the traditional vegetable and fruit net surfactants such as LAS, AS, AES, SAS

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)

Abstract

一种蔬果洗涤剂，以重量计，其包含氨基酸表面活性剂0.1-25%，水75-90%，保湿剂 0.5-5%，防腐剂 0.1-1%，所述洗涤剂的pH范围在6-8之间。所述洗涤剂能清除蔬果表面的污垢。

Description

一种氨基酸蔬果净 技术领域
本发明涉及一种蔬果净，更具体地说，涉及一种以氨基酸表面活性剂为唯一清洁成份、安全且环保的氨基酸蔬果净，属于日用消费品领域。
背景技术
蔬果净属于调配型产品，可以用于洗涤水果、蔬菜，近年来在国内发展十分迅速，是饮食业和家庭不可少的洗涤品。目前市面上的蔬果净，有去污力超强的、有浓缩型的及强杀菌力的。蔬果洗涤剂的有效成分主要是表面活性剂，传统蔬果洗涤剂主要以化学合成表面活性剂，如十二烷基苯磺酸钠LAS、十二烷基硫酸钠AS、月桂醇聚醚硫酸酯钠AES、仲烷基磺酸钠SAS等为原料。但它们大多不易降解或无法降解，对环境造成污染。随着人们环保意识的逐步增强，蔬果洗涤剂未来的发展方向将是以环保绿色型为主流。除了有强去污力、对人体无害、杀菌消毒、温和高泡的功能外，还应容易降解、不污染环境。因此，开发环保型蔬果洗涤剂是时代的迫切需求。
为此，我们研发了一种以氨基酸表面活性剂为唯一清洁成份、安全且环保的氨基酸蔬果净。
发明内容
本发明的主要目的在于提供一种以氨基酸表面活性剂为唯一清洁成份、安全且环保的氨基酸蔬果净。
为实现前述发明目的，本发明采用的技术方案包括：一种氨基酸蔬果净，包含氨基酸表面活性剂；所述氨基酸表面活性剂为主要活性成份；所述氨基酸表面活性剂的重量比为0.1-25％；
所述氨基酸蔬果净还含有水、保湿剂、防腐剂，其重量百分比分别为：
水为75-90％；
保湿剂为0.5-5％；
防腐剂为0.1-1％；
所述氨基酸蔬果净的pH范围在6-8之间。
优选的，所述氨基酸表面活性剂的重量比为5-20％。
优选的，所述氨基酸表面活性剂的重量比为10-15％。
优选的，所述氨基酸表面活性剂以丙氨酸型表面活性剂为主，丙氨酸型表面活性剂占总表面活性剂的重量百分比为60％以上，其中丙氨酸型表面活性剂占总表面活性剂的重量百分比为70％以上更好。
优选的，所述丙氨酸型表面活性剂至少包含浓度为98％以上的N-月桂酰-L-丙氨酸钠和椰油酰氨基丙酸钠中的一种。
与现有技术相比，本发明至少具有如下优点：
本发明所述的氨基酸蔬果净，采用氨基酸表面活性剂为主要活性成份，代替了传统的蔬果净用表面活性剂，如LAS、AS、AES、SAS，且不含荧光增白剂、免去化学洗涤剂残留对人体的伤害和环境的污染、无刺激、无过敏、本发明采用了具有生物降解性的天然氨基酸表面活性剂，无毒、无腐蚀、无污染、无残留；专用于清洗蔬果、高效快速清除其表面上的除草剂、杀虫剂、杀菌剂、污垢、果蜡、油性物质以及其他不良物质，保障食用安全。
附图说明
图1是本发明所述的氨基酸蔬果净的成分检验报告的第一页；
图2是本发明所述的氨基酸蔬果净的成分检验报告的第二页；
图3是本发明所述的氨基酸蔬果净的成分检验报告的第三页；
图4是本发明所述的氨基酸蔬果净的成分检验报告的第四页；
图5是本发明所述的氨基酸蔬果净的性能检验报告1的第一页；
图6是本发明所述的氨基酸蔬果净的性能检验报告1的第二页；
图7是本发明所述的氨基酸蔬果净的性能检验报告1的第三页；
图8是本发明所述的氨基酸蔬果净的性能检验报告1的第四页；
图9是本发明所述的氨基酸蔬果净的性能检验报告2的第一页；
图10是本发明所述的氨基酸蔬果净的性能检验报告2的第二页；
图11是本发明所述的氨基酸蔬果净的性能检验报告2的第三页；
图12是本发明所述的氨基酸蔬果净的性能检验报告2的第四页。
具体实施方式
下面通过具体实施例对本发明作进一步的详细说明。
本发明所述的氨基酸蔬果净，包含氨基酸表面活性剂；所述氨基酸表面活性剂作为主要活性成份；所述的氨基酸表面活性剂以丙氨酸型表面活性剂为主，丙氨酸型表面活性剂占总表面活性剂的重量百分 比为60％以上，其中丙氨酸型表面活性剂占总表面活性剂的重量百分比为70％以上更好；所述丙氨酸型表面活性剂至少包含浓度为98％以上的N-月桂酰-L-丙氨酸钠和椰油酰氨基丙酸钠中的一种。
所述氨基酸蔬果净还含有水、片碱氢氧化钠、卡松、甘油、香精；所述氨基酸蔬果净的ph值范围在6-8之间。
所述氨基酸蔬果净的组分的重量百分比见表一、表二，共列举了10个实施例。
鉴于现有技术中的不足，本案发明人经长期研究和大量实践，得以提出本发明的技术方案。如下将对该技术方案、其实施过程及原理等作进一步的解释说明。
氨基酸我们都很熟悉，它是构建生物机体的众多生物活性分子之一，还是构建人体细胞、修复人体组织的基础材料。
氨基酸是构成蛋白质的基本单位，蛋白质它是生物体内最重要的活性分子之一，包括催化代谢的酶。
氨基酸的作用有很多，它能够将我们人体内有毒物质排出体外，有效的减轻辐射、污染对人体所造成的伤害。排除机体在剧烈的运动以后体内的代谢产物，从而具有促进精神、机体、肌肉等多方面的快速恢复，因此对提高机体机能有很好的帮助。
本发明所生产的氨基酸蔬果净中的氨基酸表面活性剂至少含有浓度为98％以上的N-月桂酰-L-丙氨酸钠盐和椰油酰胺基丙氨酸钠盐中的一种，代替了传统的蔬果净表面活性剂，如LAS、AS、AES、SAS为主的表面活性剂。经过试验：采用重量比为总表面活性剂的60％以下的丙氨酸型表面活性剂所生产的氨基酸蔬果净，泡沫丰富度比重量比为总表面活性剂的60％以上的丙氨酸型表面活性剂所生产的氨基酸蔬果净低，稳定性也相对较差，去污能力较差。
本发明所述的氨基酸蔬果净中，除所述氨基酸表面活性剂成分外，还包括配制蔬果净的基本原料。
表一、表二中所涉及的数据是指重量份数，实施例1至实施例10中氨基酸蔬果净的总重量份数均为100。
表一
Figure PCTCN2017090457-appb-000001
Figure PCTCN2017090457-appb-000002
表二
Figure PCTCN2017090457-appb-000003
本发明的核心在于采用氨基酸表面活性剂作为主要表面活性成分添加到蔬果净中并验证其在蔬果净中的无毒、无腐蚀、无污染、无残留和高效快速清除污能力，详见附图1-4所示的成分检验报告、附图5-8所示的性能检验报告1和附图9-12所示的性能检验报告2。
与现有技术相比，本发明至少具有如下优点：
本发明所述的氨基酸蔬果净采用氨基酸表面活性剂为主要活性成份，代替了传统的蔬果净用表面活性剂，如LAS、AS、AES、SAS；免去化学洗涤剂残留对人体的伤害和环境的污染、无刺激、无过敏、厨房高效清洁型、清洁成分采用了具有生物降解性的天然氨基酸表面活性剂，无毒、无腐蚀、无污染、无残留；能高效快速清除厨房餐具表面的油污，保障食用安全。
上述实施例只为说明本发明的技术构思及特点，其目的在于让熟悉此项技术的人士能够了解本发明的内容并加以实施，并不能以此限制本发明的保护范围，凡根据本发明精神实质所作的等效变化或修饰，都应涵盖在本发明的保护范围内。

Claims (5)

  1. 一种氨基酸蔬果净，其特征在于，包含氨基酸表面活性剂；所述氨基酸表面活性剂为主要活性成份；所述氨基酸表面活性剂的重量比为0.1-25％；
    所述氨基酸蔬果净还含有水、保湿剂、防腐剂，其重量百分比分别为：
    水为75-90％；
    保湿剂为0.5-5％；
    防腐剂为0.1-1％；
    所述氨基酸蔬果净的pH范围在6-8之间。
  2. 根据权利要求1所述的氨基酸蔬果净，其特征在于，所述氨基酸表面活性剂的重量比为5-20％。
  3. 根据权利要求2所述的氨基酸蔬果净，其特征在于，所述氨基酸表面活性剂的重量比为10-15％。
  4. 根据权利要求1或2或3所述的氨基酸蔬果净，其特征在于，所述氨基酸表面活性剂以丙氨酸型表面活性剂为主，丙氨酸型表面活性剂占总表面活性剂的重量百分比为60％以上，其中丙氨酸型表面活性剂占总表面活性剂的重量百分比为70％以上更好。
  5. 根据权利要求4所述的氨基酸蔬果净，其特征在于，所述丙氨酸型表面活性剂至少包含浓度为98％以上的N-月桂酰-L-丙氨酸钠和椰油酰氨基丙酸钠中的一种。
PCT/CN2017/090457 2016-07-08 2017-06-28 一种氨基酸蔬果净 WO2018006730A1 (zh)

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