WO2018001008A1 - 一种聚酯织物的纳米有机硅防水防污整理方法 - Google Patents

一种聚酯织物的纳米有机硅防水防污整理方法 Download PDF

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WO2018001008A1
WO2018001008A1 PCT/CN2017/085751 CN2017085751W WO2018001008A1 WO 2018001008 A1 WO2018001008 A1 WO 2018001008A1 CN 2017085751 W CN2017085751 W CN 2017085751W WO 2018001008 A1 WO2018001008 A1 WO 2018001008A1
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finishing
agent
polyester fabric
minutes
dirt
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PCT/CN2017/085751
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French (fr)
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何勇
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江苏田园新材料股份有限公司
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025—Corona discharge or low temperature plasma
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01—Stain or soil resistance

Definitions

  • the invention relates to a nano silicone waterproof antifouling finishing method for polyester fabric.
  • Silicone polymers have low surface tension and good weatherability, electrical insulation properties and biocompatibility.
  • the silicone polymer is prepared in an aqueous form, which can greatly reduce the emission of organic volatiles (VOC), not only for water.
  • the coating has the advantages of the silicone material, and can be used as an auxiliary agent to effectively eliminate many of the drawbacks of other water-based paint films.
  • Silicone has a quartz-like reticulated chemical structure, which has good film forming properties, gas permeability and excellent weather resistance. It provides protection for the purpose of protecting the substrate by imparting hydrophobicity and crosslinking curing to the porous substrate. In life, there are often liquids such as coffee and water that are accidentally spilled onto the clothes. These liquids can cause stains on the clothes and are difficult to clean. Therefore, a new waterproof and antifouling method is needed.
  • the object of the present invention is to provide a nano-silicone waterproof antifouling finishing method for a polyester fabric, and the fabric finished by the method has the ability to reduce stains, and the specific finishing steps are as follows:
  • the waterproof antifouling finishing agent is composed of the following mass percentage components:
  • the speed of the coating machine driving roller is controlled at 40-50 m/min, and the coating amount is 5-8 g/m 2 ;
  • polyester fabric coated with the finishing agent is heated at 120-150 ° C for 3 minutes, and solidified to complete the finishing of the polyester fabric.
  • the polyester fabric is first subjected to low-temperature plasma treatment, the gas is argon gas, the treatment power is 250-300 W, the pressure is 50-60 Pa, and the time is 10-15 minutes.
  • the lye is a 1-5 mol/L sodium hydroxide solution at a temperature of 25 to 30 °C.
  • the titanium dioxide has a particle diameter of 15 to 35 nm and a specific surface area of 150 to 180 m 2 /g.
  • the leveling agent is an acrylic resin.
  • the polyester fabric finished by the above steps has an environmentally-friendly permanent anti-fouling and waterproof function. If there are coffee, water and other sputum sticking to the fabric, as long as it is wiped with water, it can be clean and fresh, and the problem that the fabric is easy to be dirty and difficult to clean is changed.
  • the polyester fabric was subjected to low-temperature plasma treatment, and the gas was argon gas, the treatment power was 250 W, the pressure was 50 Pa, and the time was 15 minutes.
  • the polyester fabric was immersed in sodium hydroxide lye for 15 minutes, washed, and dried.
  • concentration of sodium hydroxide in the alkali solution was 1 mol/L, and the temperature of the alkali solution was 25 °C.
  • the mass percentage of each component is: vinyl silicone oil 65%, hydrogen silicone oil 14%, silane coupling agent 1%, methanol 6%, acrylic resin 4%, titanium dioxide 3%, xylene 4%, Span 20#3%, the above materials were stirred evenly at room temperature.
  • the waterproof antifouling finishing agent is coated on the polyester fabric, the speed of the coating machine driving roller is controlled at 50 m/min, the coating amount is 6 g/m 2 , and the polyester fabric coated with the finishing agent is 140-150 ° C Heating for 3 minutes, curing, finishing the finishing of the polyester fabric.
  • the titanium dioxide has a particle diameter of 15 to 20 nm and a specific surface area of 170 to 180 m 2 /g.
  • the polyester fabric was subjected to low-temperature plasma treatment, and the gas was argon gas, the treatment power was 300 W, the pressure was 60 Pa, and the time was 10 minutes.
  • the polyester fabric was immersed in sodium hydroxide lye for 25 minutes, washed, and dried.
  • concentration of sodium hydroxide in the alkali solution was 3 mol/L, and the temperature of the alkali solution was 30 °C.
  • each component is: vinyl silicone oil 60%, hydrogen silicone oil 20%, silane coupling agent 2%, methanol 6%, acrylic resin 5%, titanium dioxide 2%, xylene 3%, Span 20#2%, the above materials were stirred evenly at room temperature.
  • the waterproof antifouling finishing agent is coated on the polyester fabric, the speed of the coating machine driving roller is controlled at 40 m/min, the coating amount is 5 g/m 2 , and the polyester fabric coated with the finishing agent is at 120-130 ° C Heating for 3 minutes, curing, finishing the finishing of the polyester fabric.
  • the titanium dioxide has a particle diameter of 30 to 35 nm and a specific surface area of 150 to 160 m 2 /g.
  • the polyester fabric was subjected to low-temperature plasma treatment, and the gas was argon gas, the treatment power was 300 W, the pressure was 55 Pa, and the time was 12 minutes.
  • the polyester fabric was immersed in sodium hydroxide lye for 25 minutes, washed, and dried.
  • concentration of sodium hydroxide in the alkali solution was 5 mol/L, and the temperature of the alkali solution was 28 °C.
  • the mass percentage of each component is: vinyl silicone oil 63%, hydrogen silicone oil 18%, silane coupling agent 1.5%, methanol 5%, acrylic resin 4%, titanium dioxide 4%, xylene 2.5%, Span 20#2%, the above materials are stirred evenly at room temperature.
  • the waterproof antifouling finishing agent is coated on the polyester fabric, the speed of the coating machine driving roller is controlled at 45 m/min, the coating amount is 8 g/m 2 , and the polyester fabric coated with the finishing agent is at 130-140 ° C Heating for 3 minutes, curing, finishing the finishing of the polyester fabric.
  • the titanium dioxide has a particle diameter of 20 to 30 nm and a specific surface area of 160 to 170 m 2 /g.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

一种聚酯织物的纳米有机硅防水防污整理方法，具体整理步骤如下：(1)、将聚酯织物在碱液中浸泡15-25分钟后，清洗，干燥；(2)、制备防水防污整理剂，防水防污整理剂由。以下质量百分比的组分组成：乙烯基硅油60-65％，含氢硅油10-20％，硅烷偶联剂1-2％，甲醇5-8％，流平剂1-5％，钛白粉1-5％，二甲苯3-5％，司盘20#1-3％；上述物质在室温下搅拌均匀；将上述防水防污整理剂涂覆在经过步骤(1)处理过的聚酯织物上，涂层机传动辊车速控制在40-50m/min，涂层量在5-8g/m2；(3)、将涂覆过整理剂的聚酯织物在120-150℃下加热3分钟，固化，完成聚酯织物的整理。

Description

一种聚酯织物的纳米有机硅防水防污整理方法 技术领域
本发明涉及一种聚酯织物的纳米有机硅防水防污整理方法。
背景技术
有机硅聚合物具有低的表面张力及良好的耐候性、电绝缘性能和生物相容性，将有机硅聚合物制备成水性形式，可大大降低有机挥发物(VOC)的排放，不仅可作水性涂料兼具有机硅材料的优点，而且可作助剂有效消除其它水性涂料漆膜的很多弊病。硅树脂具有类似石英的网状化学结构，具有很好的成膜性、透气性和优异的耐候性，通过赋予多孔基材憎水性和交联固化增强基材来达到保护目的,在人们的日常生活中，经常会有咖啡、水等液体不小心泼洒到衣物上，这些液体会对衣物造成污渍，难于清洗,因此需要一种新的防水防污整理方法。
发明内容
本发明的目的是提供一种聚酯织物的纳米有机硅防水防污整理方法，采用该方法所整理的织物具有降低污渍的能力，具体整理步骤如下：
(1)、将聚酯织物在碱液中浸泡15-25分钟后，清洗，干燥；
(2)、制备防水防污整理剂，防水防污整理剂由以下质量百分比的组分组成：
乙烯基硅油60-65％，含氢硅油10-20％，硅烷偶联剂1-2％，甲醇5-8％，流平剂1-5％，钛白粉1-5％，二甲苯3-5％，司盘20#1-3％；上述物质在室温下搅拌均匀；
将上述防水防污整理剂涂覆在经过步骤(1)处理过的聚酯织物上，涂层机传动辊车速控制在40-50m/min，涂层量在5-8g/m2；
(3)、将涂覆过整理剂的聚酯织物在120-150℃下加热3分钟，固化，完成聚酯织物的整理。
进一步，在步骤(1)前，聚酯织物首先进行低温等离子体处理，气体为氩气、处理功率为250-300W、压强50-60Pa、时间10-15分钟。
进一步，碱液为1-5mol/L的氢氧化钠溶液，温度为25-30℃。
进一步，钛白粉的粒径为15-35nm，比表面积为150-180m2/g。
进一步，流平剂采用丙烯酸树脂。
采用上述步骤整理过的聚酯织物，具有环保永久性防污防水功能。如有咖啡、水等赃物粘到织物上，只要用清水擦拭就可干净如新，一改以往织物容易脏、不易清洁的问题。
具体实施方式
实施例1
首先将聚酯织物进行低温等离子体处理，气体为氩气、处理功率为250W、压强50Pa、时间15分钟。
然后将聚酯织物在氢氧化钠碱液中浸泡15分钟后，清洗，干燥，碱液中氢氧化钠的浓度为1mol/L，碱液温度为25℃。
配制防水防污整理剂，各组分的质量百分比为：乙烯基硅油65％，含氢硅油14％，硅烷偶联剂1％，甲醇6％，丙烯酸树脂4％，钛白粉3％，二甲苯4％，司盘20#3％，上述物质在室温下搅拌均匀。
将防水防污整理剂涂覆在聚酯织物上，涂层机传动辊车速控制在50m/min，涂层量在6g/m2；涂覆过整理剂的聚酯织物在140-150℃下加热3分钟，固化，完成聚酯织物的整理。
钛白粉的粒径为15-20nm，比表面积为170-180m2/g。
实施例2
首先将聚酯织物进行低温等离子体处理，气体为氩气、处理功率为300W、压强60Pa、时间10分钟。
然后将聚酯织物在氢氧化钠碱液中浸泡25分钟后，清洗，干燥，碱液中氢氧化钠的浓度为3mol/L，碱液温度为30℃。
配制防水防污整理剂，各组分的质量百分比为：乙烯基硅油60％，含氢硅油20％，硅烷偶联剂2％，甲醇6％，丙烯酸树脂5％，钛白粉2％，二甲苯3％，司盘20#2％，上述物质在室温下搅拌均匀。
将防水防污整理剂涂覆在聚酯织物上，涂层机传动辊车速控制在40m/min，涂层量在5g/m2；涂覆过整理剂的聚酯织物在120-130℃下加热3分钟，固化，完成聚酯织物的整理。
钛白粉的粒径为30-35nm，比表面积为150-160m2/g。
实施例3
首先将聚酯织物进行低温等离子体处理，气体为氩气、处理功率为300W、压强55Pa、时间12分钟。
然后将聚酯织物在氢氧化钠碱液中浸泡25分钟后，清洗，干燥，碱液中氢氧化钠的浓度为5mol/L，碱液温度为28℃。
配制防水防污整理剂，各组分的质量百分比为：乙烯基硅油63％，含氢硅油18％，硅烷偶联剂1.5％，甲醇5％，丙烯酸树脂4％，钛白粉4％，二甲苯2.5％，司盘20#2％，上述物质在室温下搅拌均匀。
将防水防污整理剂涂覆在聚酯织物上，涂层机传动辊车速控制在45m/min，涂层量在8g/m2；涂覆过整理剂的聚酯织物在130-140℃下加热3分钟，固化，完成聚酯织物的整理。
钛白粉的粒径为20-30nm，比表面积为160-170m2/g。

Claims (5)

  1. 一种聚酯织物的纳米有机硅防水防污整理方法，其特征在于，具体整理步骤如下：
    (1)、将聚酯织物在碱液中浸泡15-25分钟后，清洗，干燥；
    (2)、制备防水防污整理剂，防水防污整理剂由以下质量百分比的组分组成：
    乙烯基硅油60-65％，含氢硅油10-20％，硅烷偶联剂1-2％，甲醇5-8％，流平剂1-5％，钛白粉1-5％，二甲苯3-5％，司盘20#1-3％；上述物质在室温下搅拌均匀；
    将上述防水防污整理剂涂覆在经过步骤(1)处理过的聚酯织物上，涂层机传动辊车速控制在40-50m/min，涂层量在5-8g/m2；
    (3)、将涂覆过整理剂的聚酯织物在120-150℃下加热3分钟，固化，完成聚酯织物的整理。
  2. 根据权利要求1所述的整理方法，其特征在于，在步骤(1)前，聚酯织物首先进行低温等离子体处理，气体为氩气、处理功率为250-300W、压强50-60Pa、时间10-15分钟。
  3. 根据权利要求1所述的整理方法，其特征在于，碱液为1-5mol/L的氢氧化钠溶液，温度为25-30℃。
  4. 根据权利要求1所述的整理方法，其特征在于，钛白粉的粒径为15-35nm，比表面积为150-180m2/g。
  5. 根据权利要求1所述的整理方法，其特征在于，流平剂采用丙烯酸树脂。
PCT/CN2017/085751 2016-06-27 2017-05-24 一种聚酯织物的纳米有机硅防水防污整理方法 WO2018001008A1 (zh)

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CN201610476726.1 2016-06-27

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CN112522944A (zh) * 2020-12-08 2021-03-19 绵阳佳联印染有限责任公司 一种洗后晾干型防水面料制作工艺及面料
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CN116288768B (zh) * 2023-04-13 2023-09-19 湖南康宝源科技实业有限公司 一种远红外负离子抗菌防螨保健多功能纤维及制备与应用

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