Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D39/00—Filtering material for liquid or gaseous fluids
  • B01D39/14—Other self-supporting filtering material ; Other filtering material
  • B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
  • B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
  • B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D39/00—Filtering material for liquid or gaseous fluids
  • B01D39/14—Other self-supporting filtering material ; Other filtering material
  • B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D39/00—Filtering material for liquid or gaseous fluids
  • B01D39/14—Other self-supporting filtering material ; Other filtering material
  • B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
  • B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
  • B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
  • B01D39/163—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin sintered or bonded
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D39/00—Filtering material for liquid or gaseous fluids
  • B01D39/14—Other self-supporting filtering material ; Other filtering material
  • B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
  • B01D39/2003—Glass or glassy material
  • B01D39/2017—Glass or glassy material the material being filamentary or fibrous
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/02—Types of fibres, filaments or particles, self-supporting or supported materials
  • B01D2239/025—Types of fibres, filaments or particles, self-supporting or supported materials comprising nanofibres
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
  • B01D2239/0604—Arrangement of the fibres in the filtering material
  • B01D2239/0622—Melt-blown
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
  • B01D2239/065—More than one layer present in the filtering material
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
  • B01D2239/065—More than one layer present in the filtering material
  • B01D2239/0654—Support layers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
  • B01D2239/065—More than one layer present in the filtering material
  • B01D2239/0668—The layers being joined by heat or melt-bonding
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
  • B01D2239/065—More than one layer present in the filtering material
  • B01D2239/0681—The layers being joined by gluing
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/12—Special parameters characterising the filtering material
  • B01D2239/1233—Fibre diameter
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/12—Special parameters characterising the filtering material
  • B01D2239/1258—Permeability
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/12—Special parameters characterising the filtering material
  • B01D2239/1266—Solidity
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/12—Special parameters characterising the filtering material
  • B01D2239/1275—Stiffness

Definitions

• Fluid streams particularly air and gas streams, often carry particulate material therein.
• the removal of some or all of the particulate material from the fluid stream is needed.
• air intake streams to the cabins of motorized vehicles, air in computer disk drives, HVAC air, clean room ventilation air, air to engines for vehicles or power generation equipment, gas streams directed to gas turbines, and air streams to various combustion furnaces often include particulate material therein.
• cabin air filters it is desirable to remove the particulate matter for comfort of the passengers and/or for aesthetics.
• particulate material because particulate can cause substantial damage to the internal workings of the various mechanisms involved.
• production gases or off-gases from industrial processes or engines may contain particulate material therein. Before such gases are discharged to the atmosphere, it is typically desirable to obtain a substantial removal of particulate material from those streams.
• the present disclosure provides filter media and filter elements, particularly for gas (e.g., air) filtration applications.
• gas e.g., air
• a gas filter medium e.g., air filter medium
• a surface loading filter layer including fine fibers having an average diameter of less than 1 micron e.g., air filter medium
• the layers are configured and arranged for placement in a gas stream with the surface loading filter layer being the most upstream layer. That is, the layers are positioned relative to each other such that the surface loading filter layer is positioned as the first layer encountered by the gas (e.g., air) stream being filtered (i.e., the fine fiber filter layer is the most upstream layer).
• filter media of the present disclosure are pulse cleanable.
• a gas filter element e.g., air filter element
• a housing and a filter medium as described herein.
• a method of filtering gas e.g., air
• the method including directing the gas through a filter medium or filter element as described herein.
• the depth loading filter layer includes a high-efficiency glass-containing filter layer, a melt-blown filter layer, or a combination thereof.
• a high- efficiency glass-containing filter layer may include glass fibers and multi-component binder fibers.
• a high-efficiency melt-blown filter layer may include fibers having an average diameter of 0.5 micron to 10 microns.
• high-efficiency for a composite filter medium (which may or may not be corrugated) and/or filter element (which is typically corrugated and pleated) of the present disclosure displays an efficiency of at least F9 per EN779:2012.
• a “high- efficiency” filter element (which is typically corrugated and pleated) of the present disclosure displays an efficiency of at least E10, or at least El 1, or at least E12 per EN1822:2009.
• nylon-6 made from a cyclic lactam—also known as episilon-aminocaproic acid
• nylon copolymers are also contemplated.
• the melt-blown filter layer includes a continuously gradient structure of larger fibers and more open structure at a first major surface and smaller fibers and less open structure at a second major surface. In certain embodiments of this
• a typical coating weight is at least 0.5 wt-% and often no more than 3 wt-%.
• suitable material for the support layer include spunbond, wet-laid, carded, or melt-blown nonwoven.
• Suitable fibers can be cellulosic fiber, glass fibers, metal fibers, or synthetic polymeric fibers or the combination. Fibers can be in the form of wovens or nonwovens. Plastic or metal screen-like materials both extruded and hole punched, are other examples of filter substrates.
• synthetic nonwovens include polyester nonwovens, nylon nonwovens, polyolefin (e.g., polypropylene) nonwovens, polycarbonate nonwovens, or blended or multicomponent nonwovens thereof.
• Sheet-like substrates are typical examples of filter substrates.
• suitable substrates include polyester or bicomponent polyester fibers (as described herein for the glass-containing filter layer) or polypropylene/polyethylene terephthalate, or polyethylene/ polyethylene terephthalate bicomponent fibers in a spunbond.
• the filter media of the present disclosure can then be manufactured into filter elements (i.e., filtration elements), including, e.g., flat-panel filters, cartridge filters, or other filtration components (e.g., cylindrical or conical).
• filter elements i.e., filtration elements
• flat-panel filters e.g., flat-panel filters, cartridge filters, or other filtration components (e.g., cylindrical or conical).
• filtration elements e.g., flat-panel filters, cartridge filters, or other filtration components
• filter elements e.g., cylindrical or conical
• the filter media can be corrugated. Exemplary corrugations are at a depth of 0.020 to 0.035 inch (0.5 mm to 0.9 mm). Corrugated filter media can then typically be pleated to form a pleat pack, then placed and sealed into a housing, as is known in the art.
• Filter elements of the present disclosure can be used in industrial filtration such as in dust collectors, and in commercial and residential HVAC systems.
• FIGS. 4-14 depict various embodiments of filter elements of the present disclosure that are usable in gas turbine air intake systems or industrial air cleaners.
• a pleated panel element 200 is shown in perspective view.
• the panel element 200 includes a media pack 202 of pleated media 204.
• the pleated media 204 can include a filter medium described herein.
• the media pack 202 is held within a frame 206, with the examples shown being a rectangular frame 206.
• the frame 206 typically will include a gasket (not shown) for permitting the element 200 to be sealed against a tube sheet in the intake system.
• the upstream side of the pleated media 204 with the surface loading filter layer is shown at 205 on the same side as the incoming gas (e.g., air) shown at arrow 207.
• the cleaned gas (e.g., air) is shown at arrow 208, and emerges from the media 204 from a downstream side of the media.
• FIG. 10 depicts two of the cylindrical elements 240 axially aligned, such that they are stacked end to end.
• cylindrical element 240 is axially aligned with a partially conical element 250.
• the partially conical element 250 is a tubular element having a media pack 252 that can include a filter medium of the present disclosure.
• the element has an upstream side 254 and a downstream side 256.
• the conical element 250 has a first end 258 having a diameter that matches the diameter of the cylindrical element 240.
• the conical element 250 includes a second end 260 having a diameter that is larger than the diameter of the first end 258, thus forming the partial cone.
• FIG. 12 depicts two partially conical elements 270, 280 arranged axially, and engaged end to end.
• Each of the elements 270 includes a media pack 272, 282 forming a tube that can include a filter medium of the present disclosure.
• the media packs 272, 282 each have an upstream side 274, 284 and a downstream side 276, 286.
• FIG. 14 is another embodiment of a filter element 290 having media pack 292 that can include a filter medium of the present disclosure.
• the media pack 292 is pleated and forms a tubular shape.
• the tubular shape is an oval shape, and in one example embodiment, a ratio of the short axis compared to the long axis of the oval is about 0.7-0.9.
• the media 292 includes an upstream side 294 and a downstream side 296.
• FIG. 15 is another embodiment of a filter element, in the form of an ovate structure, that can include a filter medium of the present disclosure.
• the filter element includes filter media 310 having end caps 320 located on each of the first end 312 and the second end 314 of the filter media 310.
• the end cap 320 on first end 312 of the filter media 310 may have an opening that allows access to the interior volume of filter cartridge.
• the end cap 320 on the opposite end of the filter media 310 may be closed so that it prevents access to the interior volume of the filter cartridge and so that gas (e.g., air) entering the interior volume of the filter cartridge through the end cap 320 on the first end 312 of the filter media 310 must exit through the filter media in the filter element.
• gas e.g., air
• Embodiment 1 is a gas filter medium comprising: a surface loading filter layer comprising fine fibers having an average diameter of less than 1 micron; a depth loading filter layer; and a support layer; wherein the layers are configured and arranged for placement in a gas stream with the surface loading filter layer being the most upstream layer.
• Embodiment 3 is the filter medium of embodiment 1 or 2 wherein the depth loading filter layer is positioned between the surface loading layer and the support layer.
• Embodiment 4 is the filter medium of any one of embodiments 1 through 3 wherein the fine fibers have an average diameter of up to 0.5 micron.
• Embodiment 5 is the filter medium of embodiment 4 wherein the fine fibers have an average diameter of up to 0.3 micron.
• Embodiment 6 is the filter medium of any one of embodiments 1 through 5 wherein the fine fibers have an average diameter of at least 0.01 micron.
• Embodiment 7 is the filter medium of embodiment 6 wherein the fine fibers have an average diameter of at least 0.1 micron.
• Embodiment 8 is the filter medium of any one of embodiments 1 through 7 wherein the fine fibers comprise nylon, polyvinylidene fluoride, polyurethane, or combinations thereof.
• Embodiment 9 is the filter medium of any one of embodiments 1 through 8 wherein the surface loading filter layer has a LEFS filtration efficiency of at least 30%.
• Embodiment 10 is the filter medium of embodiment 9 wherein the surface loading filter layer has a LEFS filtration efficiency of at least 70%.
• Embodiment 11 is the filter medium of embodiment 10 wherein the surface loading filter layer has a LEFS filtration efficiency of at least 80%.
• Embodiment 12 is the filter medium of any one of embodiments 1 through 11 wherein the surface loading filter layer has a LEFS filtration efficiency of up to 99%.
• Embodiment 13 is the filter medium of embodiment 12 wherein the surface loading filter layer has a LEFS filtration efficiency of up to 95%.
• Embodiment 14 is the filter medium of embodiment 13 wherein the surface loading filter layer has a LEFS filtration efficiency of up to 90%.
• Embodiment 15 is the filter medium of any one of embodiments 1 through 14 wherein the depth loading filter layer comprises a high-efficiency glass-containing filter layer, a high-efficiency melt-blown filter layer, or a combination thereof.
• Embodiment 16 is the filter medium of embodiment 15 wherein the depth loading filter layer comprises a high-efficiency glass-containing filter layer comprising glass fibers and multi-component binder fibers.
• Embodiment 17 is the filter medium of embodiment 16 wherein the high-efficiency glass-containing layer comprises up to 10 wt-% of a binder resin, based on the total weight of the glass-containing layer.
• Embodiment 18 is the filter medium of embodiment 16 or 17 wherein the multi- component binder fibers of the high-efficiency glass-containing filter layer comprise bicomponent fibers having a low melting point polyester sheath and a higher melting point polyester core.
• Embodiment 19 is the filter medium of any one of embodiments 16 through 18 wherein the high-efficiency glass-containing filter layer further comprises polyester fibers distinct from the multi-component binder fibers.
• Embodiment 20 is the filter medium of embodiment 19 wherein the polyester fibers distinct from the multi-component binder fibers have an average diameter of 10 microns to 14 microns.
• Embodiment 21 is the filter medium of any one of embodiments 16 through 20 wherein the high-efficiency glass-containing filter layer comprises glass fibers having an average diameter of 0.4 micron to 0.5 micron.
• Embodiment 22 is the filter medium of embodiment 15 wherein the depth loading filter layer comprises a high-efficiency melt-blown filter layer.
• Embodiment 23 is the filter medium of embodiment 22 wherein the high-efficiency melt-blown filter layer comprises melt-blown fibers comprising polypropylene, polybutylene terephthalate, or combinations thereof.
• Embodiment 24 is the filter medium of embodiment 22 or 23 wherein the high- efficiency melt-blown filter layer comprises melt-blown fibers having an average diameter of 0.5 micron to 10 microns.
• Embodiment 25 is the filter medium of embodiment 24 wherein the high-efficiency melt-blown filter layer comprises melt-blown fibers having an average diameter of 0.5 micron to 4 microns.
• Embodiment 26 is the filter medium of embodiment 25 wherein the high-efficiency melt-blown filter layer comprises melt-blown fibers having an average diameter of 1 micron to 3 microns.
• Embodiment 27 is the filter medium of embodiment 25 wherein the high-efficiency melt-blown filter layer comprises melt-blown fibers having an average diameter of 2 microns to 3 microns.
• Embodiment 28 is the filter medium of any one of embodiments 1 through 27 wherein the depth loading filter layer displays a DEHS filtration efficiency of at least 55%.
• Embodiment 29 is the filter medium of embodiment 28 wherein the depth loading filter layer displays a DEHS filtration efficiency of at least 70%.
• Embodiment 30 is the filter medium of any one of embodiments 1 through 29 wherein the depth loading filter layer displays a DEHS filtration efficiency of up to 99.997%).
• Embodiment 31 is the filter medium of embodiment 30 wherein the depth loading filter layer displays a DEHS filtration efficiency of up to 99.97%).
• Embodiment 32 is the filter medium of embodiment 31 wherein the depth loading filter layer displays a DEHS filtration efficiency of up to 99.5%.
• Embodiment 33 is the filter medium of any one of embodiments 1 through 32 wherein the depth loading filter layer has a basis weight of up to 150 g/m 2 .
• Embodiment 39 is the filter medium of any one of embodiments 1 through 38 wherein the support layer comprises wet-laid fibers.
• Embodiment 40 is the filter medium of embodiment 39 wherein the wet-laid fibers comprise cellulose, polyester, or combinations thereof.
• Embodiment 43 is the filter medium of any one of embodiments 1 through 42 further comprising a scrim layer disposed between the surface loading filter layer and the depth loading filter layer.
• Embodiment 44 is the filter medium of any one of embodiments 1 through 43 having a thickness of at least 10 mils (0.25 mm).
• Embodiment 46 is the filter medium of embodiment 45 having a thickness of up to 30 mils (0.76 mm).
• Embodiment 47 is the filter medium of any one of embodiments 1 through 46 wherein the layers are adhered together with adhesive, binder fibers, thermal bonding, ultrasonic bonding, self-adhesion, or combinations thereof.
• Embodiment 48 is the filter medium of any one of embodiments 1 through 47 which displays an efficiency of at least F9 per EN779:2012.
• Embodiment 49 is the filter medium of embodiment 48 which displays an efficiency of at least 80%, or greater than 80%, per the DEHS efficiency test at the most penetrating particle size.
• Embodiment 50 is the filter medium of any one of embodiments 1 through 49 which is an air filter medium.
• Embodiment 51 is a gas filter element comprising a housing and a gas filter medium of any one of embodiments 1 through 50.
• Embodiment 52 is the gas filter element of embodiment 51 which displays an efficiency of at least F9 per EN779:2012.
• Embodiment 53 is the gas filter element of embodiment 52 which displays an efficiency of at least E10 per EN1822:2009.
• Embodiment 55 is the gas filter element of embodiment 54 which displays an efficiency of at least E12 per EN1822:2009.
• Embodiment 56 is the gas filter element of any one of embodiments 51 through 55 which is a flat panel, cylindrical, or conical.
• Embodiment 57 is the gas filter element of any one of embodiments 51 through 56 which is pleated.
• Embodiment 58 is a method of filtering a gas (e.g., air), the method comprising directing the gas through a filter element of any one of embodiments 51 through 57.
• a gas e.g., air
• Embodiment 59 is a method of filtering a gas, the method comprising directing the gas through a filter medium of any one of embodiments 1 through 55.
• a TSI 8130 bench is used to load a 100cm 2 sample of filtration media with NaCl salt particles (0.33 ⁇ mass median diameter) at a concentration of 20 mg/m 3 .
• the flowrate in the bench was chosen to represent real world conditions. The other settings for the bench are to be run to the manufacturer's standards.
• the media is loaded anywhere from 4 inches to 10 inches H 2 0 (1000-2500 Pa) of dP before the end of the test, depending on the requestors needs. Every minute the bench measures the amount of salt loaded, salt passed, and dP across the media. This data is recorded by the bench. Before and after the completion of the test the sample is weighed, the difference in the weight is the salt loaded, and this value is used to calibrate the photometer.
• Dust feed rate 2.0 g/m 3 ;
• the flat sheet media was pleated at 2 inches (5.1 cm) pleat depth and built into a 26 inch (66 cm) conical and cylindrical filter pair.
• the conical elements had 280 pleats per element while the cylindrical elements had 230 pleats.
• the elements were built such that the nano-fiber layer was facing upstream.
• Laminated filter media were prepared using the following technique.
• a 50 gsm wet- laid filter material that includes a mixture of glass and bicomponent PET fibers was prepared similar to that of Example 6 in U.S. Pat. No. 7,314,497 (with the modification that it consists of 40% B08 micro glass fibers from Lauscha Fiber International (Lauscha, Germany) and 60% TJ04BN bicomponent PET fibers from Teijin (Osaka, Japan)).
• a 116 gsm wet-laid media consisting of 90% cellulose and 10% polyester blend support material was purchased from H&V of East Walpole, MA. The sheet properties are in Table 3.
• Laminated filter media were prepared using the following technique.
• a 50 gsm laid filter material that includes a mixture of glass and bicomponent fibers was prepared similar to that of Example 6 in U.S. Pat. No. 7,314,497 (with the modification that it consists of 50% B04 micro glass fibers from Lauscha Fiber International (Lauscha, Germany) and 50% bicomponent PET fibers (TJ04BN) from Teijin (Osaka, Japan)).
• a 116 gsm corrugated cellulose support material was purchased from H&V of East Walpole, MA. The sheet properties are in Table 9.

Landscapes

• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Life Sciences & Earth Sciences (AREA)
• Geology (AREA)
• Filtering Materials (AREA)
• Nonwoven Fabrics (AREA)
• Glass Compositions (AREA)
• Solid-Sorbent Or Filter-Aiding Compositions (AREA)
• Filtering Of Dispersed Particles In Gases (AREA)

Priority Applications (18)

Applications Claiming Priority (4)

Related Child Applications (2)

Publications (1)

Family

ID=58745369

Family Applications (1)

Country Status (13)

Cited By (8)

Families Citing this family (14)

Citations (20)

Family Cites Families (37)

• 2017
  • 2017-05-05 US US16/301,163 patent/US11161070B2/en active Active
  • 2017-05-05 EP EP17724980.2A patent/EP3454967B1/en active Active
  • 2017-05-05 AU AU2017262577A patent/AU2017262577B2/en active Active
  • 2017-05-05 RU RU2018141964A patent/RU2737910C2/ru active
  • 2017-05-05 CA CA3023824A patent/CA3023824C/en active Active
  • 2017-05-05 WO PCT/US2017/031222 patent/WO2017196653A1/en not_active Ceased
  • 2017-05-05 CN CN201780028739.5A patent/CN109562311B/zh active Active
  • 2017-05-05 KR KR1020237044387A patent/KR20240005169A/ko active Pending
  • 2017-05-05 KR KR1020187035531A patent/KR102618766B1/ko active Active
  • 2017-05-05 CN CN202110716746.2A patent/CN113577910A/zh active Pending
  • 2017-05-05 JP JP2018559694A patent/JP7313152B2/ja active Active
  • 2017-05-05 EP EP21162684.1A patent/EP3854469A1/en active Pending
  • 2017-05-05 MX MX2018013755A patent/MX2018013755A/es unknown
  • 2017-05-05 BR BR112018073436-5A patent/BR112018073436B1/pt active IP Right Grant
• 2018
  • 2018-11-09 MX MX2022013881A patent/MX2022013881A/es unknown
  • 2018-11-13 SA SA518400427A patent/SA518400427B1/ar unknown
  • 2018-12-06 ZA ZA2018/08230A patent/ZA201808230B/en unknown
• 2021
  • 2021-10-12 US US17/499,746 patent/US11845027B2/en active Active
• 2022
  • 2022-09-21 JP JP2022150470A patent/JP7591013B2/ja active Active
• 2023
  • 2023-11-06 US US18/502,885 patent/US12233367B2/en active Active
• 2025
  • 2025-01-14 US US19/020,703 patent/US20250153079A1/en active Pending

Patent Citations (23)

Also Published As

Similar Documents

Legal Events