WO2017154916A1 - Procédé de production de fil de cuivre plaqué d'aluminium liquide - Google Patents

Procédé de production de fil de cuivre plaqué d'aluminium liquide Download PDF

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Publication number
WO2017154916A1
WO2017154916A1 PCT/JP2017/009037 JP2017009037W WO2017154916A1 WO 2017154916 A1 WO2017154916 A1 WO 2017154916A1 JP 2017009037 W JP2017009037 W JP 2017009037W WO 2017154916 A1 WO2017154916 A1 WO 2017154916A1
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WO
WIPO (PCT)
Prior art keywords
steel wire
molten aluminum
hot
aluminum plating
bath
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PCT/JP2017/009037
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English (en)
Japanese (ja)
Inventor
忠昭 三尾野
鴨志田　真一
服部　保徳
Original Assignee
日新製鋼株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日新製鋼株式会社 filed Critical 日新製鋼株式会社
Priority to CN201780015819.7A priority Critical patent/CN108713069A/zh
Priority to KR1020187027146A priority patent/KR20180123048A/ko
Priority to EP17763256.9A priority patent/EP3428305A4/fr
Priority to US16/083,620 priority patent/US20190136358A1/en
Publication of WO2017154916A1 publication Critical patent/WO2017154916A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36—Elongated material
    • C23C2/38—Wires; Tubes
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003—Apparatus
    • C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/12—Aluminium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/50—Controlling or regulating the coating processes
    • C23C2/52—Controlling or regulating the coating processes with means for measuring or sensing

Definitions

  • the present invention relates to a method for producing a hot-dip aluminized steel wire. More specifically, the present invention is, for example, a molten aluminum plated steel wire manufacturing method that can be suitably used for automobile wire harnesses and a molten aluminum plating steel wire that can be suitably used for the molten aluminum plated steel wire manufacturing method.
  • the present invention relates to a steel wire introduction part control device for aluminum plating.
  • the hot-dip aluminum-plated steel wire is a steel wire that has been subjected to aluminum plating by continuously pulling the steel wire from the hot-dip aluminum plating bath after the steel wire is immersed in the hot-dip aluminum plating bath.
  • the molten aluminum plating bath means a molten aluminum plating solution.
  • the molten Al-plated steel wire is obtained by immersing a material steel wire made of a steel core wire or a material steel wire made of a plated steel wire having a zinc plating layer or a nickel plating layer on the surface of the steel core wire in a molten aluminum plating bath, It is manufactured by a method of continuously pulling it up to the gas phase space (see, for example, paragraph [0024] of Patent Document 1).
  • the present invention has been made in view of the above prior art, and is a molten aluminum plating in which a plating film is formed on the entire surface even when a steel wire is immersed in a molten aluminum plating bath at a high speed of 200 m / min or more.
  • the present invention (1) A method for producing a molten aluminum plated steel wire by immersing a steel wire in a molten aluminum plating bath and then continuously pulling up the steel wire from the molten aluminum plating bath. It consists of a tubular body having a heating device for heating the steel wire before being immersed in the bath and a through-hole for penetrating the steel wire inside, and the longitudinal direction of the tubular body from one end of the tubular body And a bath surface control device having an immersion region for immersing in a molten aluminum plating bath along a heating wire and a heating device in a state where the immersion region of the bath surface control device is immersed in a molten aluminum plating bath, and A method for producing a hot-dip aluminum-plated steel wire, characterized in that the hot-dip aluminum-plated steel wire is immersed in a hot-dip aluminum plating bath in sequence through a bath surface control device; (2) The method for producing a hot-dip aluminum-plated steel wire according to (1) above, wherein the steel wire is
  • the method for manufacturing a hot-dip aluminum plating steel wire and the hot-wire plating steel wire introduction part control device of the present invention even when the steel wire is immersed in a hot-dip aluminum plating bath at a high speed of 200 m / min or more, the entire surface An excellent effect is achieved in that a hot-dip aluminum-plated steel wire having a plating film formed thereon can be efficiently produced.
  • the method for producing a hot-dip aluminum-plated steel wire of the present invention includes hot-dip aluminum-plated steel by continuously pulling the steel wire from the hot-dip aluminum plating bath after the steel wire is immersed in the hot-dip aluminum plating bath.
  • a method of manufacturing a wire comprising a heating device for heating a steel wire before immersing the steel wire in a molten aluminum plating bath, and a tubular body having a through-hole for penetrating the steel wire inside,
  • a bath surface control device having an immersion region for immersing in a molten aluminum plating bath from the end of one end of the tubular body along the longitudinal direction of the tubular body, and the immersion region of the bath surface control device is molten aluminum plated
  • the steel wire is sequentially passed through the heating device and the bath surface control device and immersed in the molten aluminum plating bath. That.
  • the method for producing a hot-dip aluminum-plated steel wire of the present invention since the above operation is taken, the entire surface is plated even when the steel wire is immersed in a hot-dip aluminum plating bath at a high speed of 200 m / min or more. A hot-dip aluminized steel wire with a coating formed thereon can be produced efficiently.
  • the steel wire is immersed in the hot-dip aluminum plating bath from the gas phase space.
  • the oxide film generated on the surface of the molten aluminum plating bath is prevented from being introduced into the molten aluminum plating bath while the steel wire is accompanied.
  • the reactivity of a steel wire and a molten aluminum plating bath improves, it can suppress that the location where a plating film is not formed on the surface of a hot-dip aluminum plating steel wire generate
  • the temperature of the steel wire is increased because the heating device used in the steel wire introduction part control device for hot dip aluminum plating of the present invention is passed.
  • the steel wire can be introduced into the molten aluminum plating bath in the state. Therefore, since the reactivity between the steel wire and the hot dip aluminum plating bath is improved, there is a portion where a plating film is not formed on the surface of the hot dip aluminum plated steel wire even when the wire passing speed of the steel wire is increased. Generation
  • production can be suppressed.
  • FIG. 1 is a schematic explanatory view showing one embodiment of a method for producing a hot-dip aluminized steel wire of the present invention.
  • the steel wire 2 is immersed in the hot dip aluminum plating bath 1, the steel wire 2 is continuously pulled up from the hot dip aluminum plating bath 1 to thereby obtain hot dip aluminum plating steel.
  • Line 3 is manufactured.
  • Examples of the steel material constituting the steel wire 2 include stainless steel and carbon steel, but the present invention is not limited to such examples.
  • Stainless steel is an alloy steel containing 10% by mass or more of chromium (Cr).
  • examples of the stainless steel include austenitic steel materials, ferritic steel materials, martensitic steel materials and the like specified in JIS G4309, but the present invention is not limited only to such examples.
  • the stainless steel include stainless steels such as SUS301 and SUS304, which are generally considered to be metastable; austenitic stainless steels such as SUS305, SUS310, and SUS316; SUS405, SUS410L, SUS429, SUS430, SUS434, Ferritic stainless steels such as SUS436, SUS444, and SUS447; martensitic stainless steels such as SUS403, SUS410, SUS416, SUS420, SUS431, and SUS440, as well as chromium-nickel-manganese stainless steel classified in the SUS200 series
  • the present invention is not limited to such examples.
  • Carbon steel is a steel material containing 0.02% by mass or more of carbon (C).
  • Examples of the carbon steel include steel materials specified in the standard of JIS G3506 hard steel wire rod, steel materials specified in the standard of JIS G3505 mild steel wire rod, etc., but the present invention is limited to such examples only. Is not to be done. Specific examples of carbon steel include hard steel and mild steel, but the present invention is not limited to such examples.
  • stainless steel and carbon steel are preferable, and stainless steel is more preferable from the viewpoint of increasing the tensile strength of the hot-dip aluminized steel wire 3.
  • the diameter of the steel wire 2 is not particularly limited, and is preferably adjusted as appropriate according to the application of the hot-dip aluminized steel wire 3.
  • the diameter of the steel wire 2 is usually preferably about 0.05 to 0.5 mm.
  • the steel wire 2 may be degreased before being subjected to hot-dip aluminum plating.
  • the steel wire 2 is degreased by, for example, a method of degreasing the steel wire 2 by immersing the steel wire 2 in an alkaline degreasing solution, washing with water to neutralize the alkali attached to the steel wire 2, and washing again with water. It can be performed by a method in which electrolytic degreasing is performed by energizing the steel wire 2 with the wire 2 immersed in an alkaline degreasing solution.
  • the alkali degreasing solution may contain a surfactant from the viewpoint of improving the degreasing power.
  • a plated coating (not shown) made of aluminum or an aluminum alloy is formed on the surface of the molten aluminum plated steel wire 3.
  • the plating film made of aluminum or an aluminum alloy is formed on the surface of the hot-dip aluminum-plated steel wire 3 in this way, When bundled with a wire and used in a wire harness, it has excellent adhesion to the aluminum wire, and is excellent in tensile strength and electrical resistance over time.
  • the steel wire 2 is sent out from the sending device 4, continuously passed in the direction of arrow A, and immersed in the molten aluminum plating bath 1 in the plating bath 5.
  • the steel wire 2 is the steel wire 2 which consists of carbon steel
  • the steel wire 2 is preferably degreased between the delivery device 4 and the molten aluminum plating bath 1. Degreasing of the steel wire 2 made of carbon steel can be performed by the same method as the degreasing of the steel wire 2.
  • the molten aluminum plating bath 1 only aluminum may be used, and if necessary, other elements may be contained within a range not impairing the object of the present invention.
  • the other elements include nickel, chromium, zinc, silicon, copper, and iron, but the present invention is not limited to such examples.
  • the mechanical strength of the plating film can be increased, and as a result, the tensile strength of the hot-dip aluminum-plated steel wire 3 can be increased.
  • the formation of an iron-aluminum alloy layer having brittleness between the iron contained in the steel wire 2 and the aluminum contained in the plating film Silicon is preferable from the viewpoint of efficiently plating the steel wire 2 by reducing the melting point and increasing the mechanical strength of the plating film and lowering the melting point of the molten aluminum plating bath 1.
  • the lower limit of the content of the other element in the plating film is 0% by mass, but preferably 0.3% by mass or more, more preferably 0 from the viewpoint of sufficiently expressing the properties of the other element. 0.5% by mass or more, more preferably 1% by mass or more, and preferably 50% by mass or less, more preferably 20% by mass or less, and still more preferably 15% from the viewpoint of suppressing potential difference corrosion due to contact with the aluminum wire. It is below mass%.
  • a steel wire introduction part control device 8 for molten aluminum plating having a heating device 6 and a bath surface control device 7 for heating the steel wire 2. Let the steel wire 2 pass through.
  • the said operation since the said operation is taken, even if it is a case where the steel wire 2 is immersed in the hot dip aluminum plating bath 1 at a high speed of 200 m / min or more, the hot dip galvanized steel in which the plating film is formed on the whole surface
  • the wire 3 can be manufactured efficiently.
  • FIG. 2 is a schematic cross-sectional view showing an embodiment of the heating device 6 used in the steel wire introduction part control device 8 for hot-dip aluminum plating of the present invention shown in FIG.
  • the heating device 6 has a tubular heating device body 6a made of, for example, stainless steel.
  • the interior 6b of the heating device body 6a is hollow in order to pass the steel wire 2 in the direction of arrow B.
  • a branch pipe 6e having a heating gas vent 6c for ventilating the heating gas is disposed on the side surface of the heating device body 6a.
  • Examples of the heating gas vented to the heating device 6 include air, inert gases such as nitrogen gas, argon gas, and helium gas, but the present invention is not limited to such examples. Absent.
  • emitted from the lower end 6d of the heating apparatus 6 is ventilated into the inside from the inlet of the upper end 7a of the bath surface control apparatus 7 arrange
  • an inert gas is preferable. Since the temperature of the heated gas varies depending on conditions such as the type and diameter of the steel wire 2 used, the wire speed, and the flow rate of the heated gas, it cannot be determined unconditionally. It is preferable to adjust so that is heated appropriately.
  • the heating temperature of the steel wire 2 is the same as that when the steel wire 2 is immersed in the molten aluminum plating bath 1 at a wire speed of 200 m / min or more. From the viewpoint of efficient production, it is preferably 60 ° C. or higher, more preferably 80 ° C. or higher, more preferably 150 ° C. or higher, and still more preferably 200 ° C. or higher.
  • the upper limit varies depending on the type of the steel wire 2 and the like. Although it cannot be generally determined, in consideration of energy efficiency, it is usually preferably 1000 ° C. or lower, more preferably 900 ° C. or lower, and further preferably 800 ° C. or lower.
  • the said heating temperature is a temperature when it measures based on the method as described in a following example.
  • the upper limit of the wire speed of the steel wire 2 is not particularly limited, it may be 1000 m / min or less from the viewpoint of efficiently producing the hot-dip aluminum-plated steel wire 3 having a plating film formed on the entire surface. Preferably, it is 800 m / min or less.
  • the length of the heating device main body 6a shown in FIG. 2 is not particularly limited as long as the length can be adjusted so that the steel wire 2 is heated to a predetermined temperature. About 1 to 5 m. Moreover, since the diameter of the inside 6b of the heating apparatus main body 6a changes with diameters and types, etc. of the steel wire 2 used, it is preferable to adjust suitably according to the diameter, type, etc. of the used steel wire 2.
  • the diameter of the inside 6b of the heating device main body 6a is usually selected as appropriate according to the diameter of the steel wire 2 from a range of about 1.5 to 50 times the diameter of the steel wire 2. For example, when the steel wire 2 having a diameter of 0.2 mm is used, the diameter of the inside 6b of the heating device body 6a is preferably about 0.3 to 10 mm.
  • a branch pipe 6e having a heated gas vent 6c is disposed on the side surface of the heating device body 6a.
  • a heater (not shown) is provided in the branch pipe 6e.
  • the heating gas vented into the branch pipe 6e may be heated by the heater.
  • branch pipes 6e are arranged, but the number of branch pipes 6e is not particularly limited, and the number of branch pipes 6e is only one. Alternatively, it may be about 2-10.
  • a gap D is provided between the lower end 6 d of the heating device 6 and the upper end 7 a of the bath surface control device 7 disposed below the heating device 6.
  • the gap D is preferably 3 mm or more from the viewpoint of efficiently discharging the heated gas from the gap D.
  • An inert gas is used as the heated gas, and the interior of the bath surface control device 7 is not covered with the inert gas.
  • the thickness is preferably 10 mm or less.
  • the gap D is not necessarily provided, and the heating device 6 and the bath surface control device 7 may be configured as separate members, and may be integrated by, for example, screw fitting.
  • an outlet not shown
  • an outlet for discharging the heated gas vented into the heating device 6 is provided in the heating device 6 or You may provide in the side surface of the bath surface control apparatus 7.
  • heating device 6 instead of the heating device 6, for example, an electric heating device, an induction heating device, or the like can be used.
  • FIG. 3 is a schematic cross-sectional view showing an embodiment of the bath surface control device 7 used in the hot-dip aluminum plating steel wire introduction portion control device 8 of the present invention shown in FIG.
  • the bath surface control device 7 is composed of a tubular body 9 having a through hole 9 a for allowing the steel wire 2 to penetrate in the direction of arrow C therein, and a hot-dip aluminum plating bath for the tubular body 9. 1 has an immersion region 9b for immersing the tubular body 9 in the molten aluminum plating bath 1 from the end of one end on the side immersed in 1 to the virtual line P along the longitudinal direction.
  • the total length L of the bath surface control device 7 is the bath liquid of the molten aluminum plating bath 1 or the molten aluminum plating bath 1 from the introduction port 9c for introducing the steel wire 2 when the immersion region 9b is immersed in the molten aluminum plating bath 1.
  • the hot-dip aluminum-plated steel wire 3 in which a plating film is formed on the entire surface, preventing the oxide film formed on the surface of the steel body from entering the through-hole 9a of the tubular body 9, preferably 30 mm
  • it is preferably 500 mm or less, more preferably 300 mm or less, and still more preferably 100 mm or less.
  • the length of the immersion region 9b is preferably from the viewpoint of efficiently producing the hot-dip aluminum-plated steel wire 3 having a plating film formed on the entire surface so as not to be affected by the perturbation of the bath surface of the hot-dip aluminum plating bath 1.
  • the tubular body 9 is reduced, the workability is improved, and the hot-dip aluminum-plated steel wire 3 having a plating film formed on the entire surface is efficiently used. From the viewpoint of producing well, it is preferably 20 mm or less, more preferably 15 mm or less.
  • the length of the portion that is not immersed in the molten aluminum plating bath 1 is the oxidation generated on the surface of the molten aluminum plating bath 1 or the molten aluminum plating bath 1 from the inlet 9 c of the tubular body 9.
  • the thickness is preferably 5 mm or more, more preferably 10 mm or more.
  • the value of the area of the opening / the area in the cross section of the steel wire 2] is a melting in which the steel wire 2 is smoothly introduced into the through hole 9a of the tubular body 9 and a plating film is formed on the entire surface.
  • it is preferably 3 or more, and preferably from 4000 or less, more preferably from the viewpoint of efficiently producing the molten aluminum-plated steel wire 3 having a plating film formed on the entire surface. Is 3000 or less, more preferably 2000 or less, and still more preferably 1000 or less.
  • the shape of the opening of the through-hole 9a of the tubular body 9 may be circular, elliptical, or polygonal, such as a square or a rectangle. It is not limited. Further, the clearance (clearance) between the opening of the through hole 9a of the tubular body 9 and the steel wire 2 is from the viewpoint of avoiding the sliding of the inner wall of the through hole 9a of the tubular body 9 and the steel wire 2. Preferably it is 10 micrometers or more, More preferably, it is 20 micrometers or more, More preferably, it is 50 micrometers or more, More preferably, it is 100 micrometers or more.
  • the opening part of the through-hole 9a which the tubular body 9 has is shown in FIG. 3, and the opening part 9d in the inlet 9c for introducing the steel wire 2 into the end of the tubular body 9, and the said tubular body 9 It is the opening 9f in the discharge port 9e for discharging the steel wire 2 to the other end.
  • the area and shape of the opening 9d and the opening 9f may be the same or different, but the steel wire 2 is smoothly passed through the through hole 9a of the tubular body 9, and the tubular body 9 From the viewpoint of efficiently producing a hot-dip aluminum-plated steel wire 3 in which a plating film is formed on the entire surface, avoiding sliding between the inner wall of the through-hole 9a and the steel wire 2, as shown in FIG.
  • the area and shape of the opening 9d and the opening 9f are preferably the same.
  • the steel wire 2 is introduced from the introduction port 9c of the tubular body 9 constituting the bath surface control device 7 shown in FIG. 3, is discharged from the discharge port 9e, and is immersed in the molten aluminum plating bath 1.
  • the steel wire 2 immersed in the molten aluminum plating bath 1 is pulled upward from the bath surface 10 of the molten aluminum plating bath 1, thereby forming a plating film 17 of the molten aluminum plating bath 1 on the surface of the steel wire 2.
  • a hot-dip aluminum-plated steel wire 3 is obtained.
  • the steel wire 2 when the steel wire 2 is pulled up from the molten aluminum plating bath 1 in the direction of arrow E, the steel wire 2 is formed at the boundary between the steel wire 2 and the bath surface 10 of the molten aluminum plating bath 1. It is preferable to bring the stabilizing member 11 into contact.
  • FIG. 4 shows a boundary portion between the steel wire 2 and the bath surface 10 of the molten aluminum plating bath 1 when the steel wire 2 is pulled up from the molten aluminum plating bath 1 in the method for producing a molten aluminum plated steel wire of the present invention. It is a schematic explanatory drawing.
  • Examples of the stabilizing member 11 include a stainless steel square bar having a heat-resistant cloth material 11a wound around the surface thereof.
  • Examples of the heat resistant cloth member 11a wound around the stabilizing member 11 include woven fabrics and nonwoven fabrics containing heat resistant fibers such as ceramic fibers, carbon fibers, aramid fibers, and imide fibers.
  • the heat-resistant cloth material 11a wound around the stabilizing member 11 is a surface on which aluminum is not adhered in the heat-resistant cloth material 11a from the viewpoint of suppressing the adhesion of aluminum lump to the surface of the hot-dip aluminized steel wire 3 ( It is preferable to bring the new surface) into contact with the steel wire 2.
  • the stabilizing member 11 is preferably brought into contact with both the bath surface 10 of the molten aluminum plating bath 1 and the steel wire 2 simultaneously.
  • the stabilizing member 11 is simultaneously brought into contact with both the bath surface 10 of the molten aluminum plating bath 1 and the steel wire 2, pulsation of the bath surface 10 of the molten aluminum plating bath 1 is suppressed, and the steel wire is suppressed.
  • the steel wire 2 is pulled up while being in contact with the stabilizing member 11, it is possible to suppress the fine vibration of the steel wire 2, and to uniformly form the plating film 17 of the molten aluminum plating bath 1 on the surface of the steel wire 2. Can do.
  • the stabilization member 11 is used in order to apply tension to the steel wire 2 as necessary. May be pressed lightly against the steel wire 2.
  • a nozzle 12 for spraying an inert gas toward the boundary between the steel wire 2 and the bath surface 10 of the molten aluminum plating bath 1 is provided. Further, in the embodiment shown in FIG. 4, the tip 12 a of the nozzle 12 is disposed so that an inert gas can be blown onto the boundary portion between the steel wire 2 and the bath surface 10 of the molten aluminum plating bath 1.
  • the distance (shortest distance) from the steel wire 2 to the tip 12a of the nozzle 12, the temperature of the inert gas discharged from the tip 12a of the nozzle 12, the inner diameter of the tip 12a of the nozzle 12, and the discharge from the nozzle 12 By appropriately controlling the volume flow rate of the inert gas to be produced, the hot-dip galvanized steel wire 3 having a uniform outer diameter and almost no aluminum lump adhering to the surface can be efficiently produced.
  • the distance from the steel wire 2 to the tip 12a of the nozzle 12 is preferably 1 mm or more from the viewpoint of avoiding contact with the steel wire 2 and efficiently producing the hot-dip aluminized steel wire 3. From the viewpoint of obtaining a molten aluminum-plated steel wire 3 having a uniform diameter and almost no aluminum lump adhering to the surface, it is preferably 50 mm or less, more preferably 40 mm or less, still more preferably 30 mm or less, and even more preferably 10 mm or less. .
  • the inner diameter of the tip 12a of the nozzle 12 can be adjusted by spraying an inert gas discharged from the tip 12a of the nozzle 12 onto the boundary portion between the steel wire 2 and the bath surface 10 of the molten aluminum plating bath 1 by hot-dip aluminum plating.
  • an inert gas discharged from the tip 12a of the nozzle 12 onto the boundary portion between the steel wire 2 and the bath surface 10 of the molten aluminum plating bath 1 by hot-dip aluminum plating.
  • it is 15 mm or less, More preferably, it is 10 mm or less, More preferably, it is 5 mm or less.
  • the inert gas can be supplied to the nozzle 12 via the pipe 14 from the inert gas supply device 13 shown in FIG.
  • a flow rate control device such as a valve may be provided in the inert gas supply device 13 or the pipe 14.
  • the inert gas means a gas that is inert with respect to molten aluminum.
  • the inert gas include nitrogen gas, argon gas, helium gas, and the like, but the present invention is not limited to such examples.
  • nitrogen gas is preferred.
  • the inert gas may contain, for example, oxygen gas, carbon dioxide gas, or the like within a range that does not impair the object of the present invention.
  • the volume flow rate of the inert gas discharged from the tip 12a of the nozzle 12 is preferably 2 L from the viewpoint of obtaining a molten aluminized steel wire 3 having a uniform outer diameter and almost no aluminum lump adhering to the surface.
  • it is preferably 200 L / min or less, more preferably 150 L / min or less, and still more preferably 100 L / min or less.
  • the temperature of the inert gas discharged from the tip 12a of the nozzle 12 is preferably 200 ° C. or more, more preferably from the viewpoint of obtaining a molten aluminized steel wire 3 having a uniform outer diameter and almost no aluminum lump attached to the surface. Is not less than 300 ° C., more preferably not less than 400 ° C., and if it is too high, the thermal efficiency is lowered, so that it is preferably 800 ° C. or less, more preferably 780 ° C. or less, and even more preferably 750 ° C. or less.
  • the temperature of the inert gas discharged from the tip 12a of the nozzle 12 is, for example, a sheath thermoelectric having a diameter of 1.6 mm in the inert gas at a distance of 2 mm from the tip 12a of the nozzle 12. It is a value when measured by inserting a thermocouple for temperature measurement such as a pair.
  • the line speed at the time of pulling up the molten aluminum plated steel wire 3 from the bath surface 10 of the molten aluminum plating bath 1 is not particularly limited, and the surface of the molten aluminum plated steel wire 3 can be adjusted by appropriately adjusting the line speed. Since the average thickness of the hot-dip plated coating 17 can be adjusted, it is preferable that the thickness is appropriately adjusted according to the average thickness of the plated coating 17.
  • the hot dip galvanized steel wire 3 even when the passage speed of the hot dip galvanized steel wire 3 is as high as 200 m / min or more, the hot dip aluminum having a uniform outer diameter and the plating film 17 formed on the entire surface. A plated steel wire 3 can be obtained. Therefore, the manufacturing method of the hot dip galvanized steel wire of the present invention can efficiently manufacture the hot dip aluminum plated steel wire 3 having the plating film 17 formed on the entire surface. Excellent productivity.
  • the cooling device 15 may be disposed above the nozzle 12.
  • the molten aluminum plated steel wire 3 can be cooled by spraying, for example, gas, liquid mist or the like onto the molten aluminum plated steel wire 3.
  • the hot dip galvanized steel wire 3 manufactured as described above can be collected by, for example, a winding device 16 as shown in FIG.
  • the average thickness of the hot dip coating 17 existing on the surface of the hot dip galvanized steel wire 3 suppresses exposure of the base steel wire 2 to the outside during stranded wire processing, caulking, etc., and has a unit outer diameter. From the viewpoint of increasing the mechanical strength, it is preferably about 2 to 20 ⁇ m, and more preferably about 4 to 15 ⁇ m.
  • the hot-dip galvanized steel wire 3 obtained above may be subjected to wire drawing using a die or the like so that the hot-dip galvanized steel wire 3 has a desired outer diameter. .
  • the hot-dip aluminum-plated steel wire obtained by the method for producing hot-dip aluminum-plated steel wire of the present invention can be suitably used for, for example, an automobile wire harness.
  • the hot-dip aluminized steel wire was manufactured in accordance with the embodiment shown in FIG.
  • a steel wire having a diameter shown in each table and made of a steel type shown in each table was used as the steel wire.
  • 37A described in the column of steel types in Table 2 and Table 3 means a steel wire made of hard steel containing 0.37% by mass of carbon.
  • the steel wire was degreased by dipping in a sodium orthosilicate degreasing solution containing a surfactant before dipping in the molten aluminum plating bath.
  • the steel wire was heated to the heating temperature shown in each table by passing it through the heating device before passing it through the bath surface control device.
  • the heating device the heating device main body has an inner diameter of about 10 mm, the number of branch pipes is eight, and a cantal wire heater (not shown) wound in a coil shape is built in each branch pipe.
  • a device was used. By supplying the introduced gas shown in each table to each branch pipe, the heated introduced gas was sent into the heating apparatus main body to preheat the steel wire.
  • the heating temperature was measured by preparing a steel wire connected to a thermocouple and passing the thermocouple together with the steel wire through a heating device.
  • a bath surface control device a stainless steel block or plate material is assembled, and as shown in FIG. 3, the total length L is 100 mm, and the opening 9d in the introduction port 9c and the opening in the discharge port 9e of the through hole 9a.
  • the bath surface control device 7 having the same shape, size and area of the part 9f was used.
  • the shape, size, area of the opening of the through-hole 9a of the bath surface control device 7 and the value of the ratio of the area to the area of the cross section of the steel wire (indicated as “area ratio value” in each table) Shown in each table.
  • the immersion area 9b from the lower end of the bath surface control device 7 to 10 mm is immersed in a molten aluminum plating bath so that the steel wire passed through the bath surface control device 7 is subsequently immersed in the molten aluminum plating bath. .
  • a molten aluminum plating bath As a molten aluminum plating bath, a molten aluminum plating bath (a molten aluminum plating bath containing 8% by mass of silicon: indicated as “8% Si” in the “kind” column of each table) is used. Then, the steel wire was immersed in the molten aluminum plating bath at the wire speed (wire speed of the steel wire) shown in each table, and then pulled up from the plating bath.
  • a nozzle with an inner diameter of 3 mm is arranged so that the tip of the nozzle is located 2 mm away from the steel wire, and an inert gas (nitrogen gas) adjusted to a temperature of 600 ° C. from the tip of the nozzle is provided. It sprayed on the boundary part of the steel wire and the bath surface of a molten aluminum plating bath with the volume flow rate of 10 L / min.
  • FIG. 5 is a schematic explanatory view showing one embodiment of a method for measuring the average thickness of the plated film of the hot-dip aluminum-plated steel wire obtained in each example and each comparative example.
  • wire-type steel wire diameter measuring device 18 As shown in FIG. 5, as the wire-type steel wire diameter measuring device 18, a pair of pulleys 18c and 18d arranged in the vertical direction, and a central portion between the pulley 18c and the pulley 18d are arranged in the horizontal direction.
  • a pair of light-emitting portions 18a and light-receiving portions 18b are opposed to each other, and adjacent light-emitting portions 18a and light-receiving portions 18b are disposed at an angle of 90 ° as shown in FIG.
  • the outer diameter of the hot-dip aluminum-plated steel wire 3 was measured with a wire-type steel wire diameter measuring device 18 at intervals of about 1.4 mm in the length direction of the aluminum-plated steel wire 3. In addition, the number of measurement points of the outer diameter was about 71,000 points.
  • the average value of the outer diameter of the hot-dip aluminized steel wire measured above is obtained, and the diameter of the steel wire before forming the plating film (the diameter of the steel wire shown in each table below) is subtracted from the average value. Then, the average value of the plating film was determined by dividing the obtained value by 2. The results are shown in each table.
  • Non-plating rate is less than 1% (pass) 4: Non-plating rate is 1% or more and less than 5% (pass) 3: Non-plating rate is 5% or more and less than 30% (pass) 2: Non-plating rate is 30% or more and less than 60% (failed) 1: Non-plating rate is 60% or more (failed)
  • FIG. 6 shows the appearance of plating of the hot-dip aluminum-plated steel wires obtained in Examples 2, 7 and Comparative Examples 1 and 2.
  • the white arrow in the figure is a location (non-plated location) where the plating film observed on the surface of the hot-dip aluminized steel wire was not formed. From the results shown in FIG. 6, it can be seen that according to the above-described example, a hot-dip aluminum-plated steel wire having a plating film formed on the entire surface can be efficiently produced.
  • the heating gas for preheating the steel wire before immersing the steel wire in the hot-dip aluminum plating bath is nitrogen. It can be seen that a hot dip aluminized steel wire having a plating film formed on the entire surface can be efficiently produced using not only gas but also air.
  • the hot-dip aluminized steel wire obtained by the production method of the present invention can be suitably used for, for example, an automobile wire harness.

Abstract

Cette invention concerne un procédé de production d'un fil de cuivre plaqué d'aluminium liquide, le procédé de production étant caractérisé par l'utilisation d'un dispositif de chauffage (6) destiné à chauffer un fil de cuivre (2) avant l'immersion du fil de cuivre (2) dans un bain de placage d'aluminium liquide (1), et d'un dispositif de commande de surface de bain (7) qui comprend un corps de forme tubulaire (9) qui présente un trou traversant (9a) pour l'acheminement du fil de cuivre (2) à travers celui-ci, et comprend une région d'immersion (9b) qui doit être immergée dans le bain de placage d'aluminium liquide (1) d'une partie d'extrémité d'une première extrémité du corps de forme tubulaire (9) dans le sens de la longueur du corps de forme tubulaire (9). Ledit procédé de production est en outre caractérisé en ce que le fil de cuivre (2) est acheminé, dans cet ordre, à travers le dispositif de chauffage (6) et le dispositif de commande de surface de bain (7) et immergé dans le bain de placage d'aluminium liquide (1) tandis que la région d'immersion (9b) du dispositif de commande de surface de bain (7) est immergée dans le bain de placage d'aluminium liquide (1).
PCT/JP2017/009037 2016-03-11 2017-03-07 Procédé de production de fil de cuivre plaqué d'aluminium liquide WO2017154916A1 (fr)

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CN201780015819.7A CN108713069A (zh) 2016-03-11 2017-03-07 热浸镀铝钢线的制造方法
KR1020187027146A KR20180123048A (ko) 2016-03-11 2017-03-07 용융 알루미늄 도금 강선의 제조 방법
EP17763256.9A EP3428305A4 (fr) 2016-03-11 2017-03-07 Procédé de production de fil de cuivre plaqué d'aluminium liquide
US16/083,620 US20190136358A1 (en) 2016-03-11 2017-03-07 Method for producing hot-dip aluminum-coated steel wire

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JP2749694B2 (ja) * 1990-03-09 1998-05-13 古河電気工業株式会社 銅線への容融めっき方法
JPH04276051A (ja) * 1991-03-04 1992-10-01 Kawasaki Steel Corp 溶融金属めっき方法
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CN203569171U (zh) * 2013-11-25 2014-04-30 安吉汉洲竹制品有限公司 一种锌鼻子密封系统
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JPH11209861A (ja) * 1998-01-23 1999-08-03 Hitachi Cable Ltd 溶融めっき方法およびその装置
JP2015193877A (ja) * 2014-03-31 2015-11-05 日新製鋼株式会社 伸線加工性に優れた溶融めっき鋼線およびその製造方法並びに製造装置

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CN108713069A (zh) 2018-10-26
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JP2017166069A (ja) 2017-09-21
TW201802264A (zh) 2018-01-16
EP3428305A1 (fr) 2019-01-16

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