WO2017111323A1 - Composition destinée au traitement de fibre - Google Patents

Composition destinée au traitement de fibre Download PDF

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Publication number
WO2017111323A1
WO2017111323A1 PCT/KR2016/013558 KR2016013558W WO2017111323A1 WO 2017111323 A1 WO2017111323 A1 WO 2017111323A1 KR 2016013558 W KR2016013558 W KR 2016013558W WO 2017111323 A1 WO2017111323 A1 WO 2017111323A1
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Prior art keywords
fiber
composition
cationic
polyquaternium
soluble polymer
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PCT/KR2016/013558
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English (en)
Korean (ko)
Inventor
김세훈
차경온
조민석
조윤진
Original Assignee
주식회사 엘지생활건강
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Priority claimed from KR1020150182943A external-priority patent/KR102073867B1/ko
Priority claimed from KR1020160030913A external-priority patent/KR102030757B1/ko
Priority claimed from KR1020160030918A external-priority patent/KR20170074148A/ko
Application filed by 주식회사 엘지생활건강 filed Critical 주식회사 엘지생활건강
Publication of WO2017111323A1 publication Critical patent/WO2017111323A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment

Definitions

  • the present invention relates to a composition for treating fibers and a method for producing the same.
  • fiber refers to a thin, long, thread-like structural unit that forms the tissue of a living body in the biological field, and refers to a thin, long and soft object such as cotton or wool.
  • fibers There are dozens of kinds of fibers currently used, classified according to chemical composition, physical and chemical properties, and classified according to age, country and scholar. For example, until artificial fibers came out, they were classified into three types of fibers of vegetable, animal, and mineral, but after artificial fibers were classified into natural fibers and artificial fibers.
  • Natural fiber means that it is produced in the form of fiber in nature and can be directly used as a fiber, and what is obtained from plants such as flax is called vegetable fiber. These fibers are also called cellulose fibers because they are all made of cellulose.
  • the fiber obtained from the animal body is called animal fiber, and because the chemical component is protein, it is also called protein fiber.
  • Fibers can also be made from vegetable proteins, and the properties of artificial protein fibers are closer to those of natural animal fibers than to natural vegetable fibers, whether the compounds that make up the fibers are cellulosic or protein based rather than plant or animal sources. It is determined according to.
  • these fibers need to be washed when contamination occurs due to human use regardless of whether they are vegetable or animal, and each time hand washing or machine washing, tens of thousands of laundry residues are used for fibers, such as clothes or bedding.
  • tens of thousands of laundry residues are used for fibers, such as clothes or bedding.
  • Conventional lint-free techniques include cationic surfactants in the form of quaternary ammonium, polysiloxanes, starch or acrylic polymers, polyvinylpyrrolidone, etc. on clothing or bedding to reduce friction or wear There is a way to suppress. However, such a method may cause yellowing, and a sufficient effect may not be achieved during the washing process.
  • the conventional lint removing technique is a technique of hydrolyzing fibers using enzymes, which is limited in enzymatic activity temperature and selectivity of hydrolysis position. There is no problem that the fiber becomes thin.
  • a technique for coating clothing or bedding has not existed previously, while at the same time dispersing the residue well during the washing process to prevent re-adhesion to clothing or bedding.
  • the problem to be solved by the present invention is to provide a composition for treating fibers, a method for preparing the same, or a method for suppressing the residue of laundry by treating the composition excellent in the laundry residue residue suppression effect.
  • Another problem to be solved by the present invention is to provide a composition for treating fibers excellent in anti-desalting effect, a method for preparing the same, or a method for preventing desalinating of fibers by treating the composition.
  • Another problem to be solved by the present invention is to provide a composition for treating fibers having an excellent dust adsorption preventing effect, a method for preparing the same or a method for preventing dust adsorption on fibers by treating the composition.
  • the present invention comprises a cationic water-soluble polymer, preferably a fiber for restraining laundry residues containing a cationic water-soluble polymer having a charge density of 0.1 to 25 meq / g
  • a composition for treatment preferably a cationic water-soluble polymer, preferably a fiber for restraining laundry residues containing a cationic water-soluble polymer having a charge density of 0.1 to 25 meq / g.
  • composition for treating fibers according to the present invention may be a composition for treating fibers for inhibiting washing residues, preventing desalination or adsorption of dust.
  • the "fiber treatment composition” may mean a composition treated to benefit the fiber state, such as improvement of fiber state, that is, improvement of fiber state including all natural fibers and / or artificial fibers, and prevention of deterioration. .
  • the present invention is a product containing the fiber treatment composition, for example, textile detergents, fabric softeners, fiber deodorant, fiber fragrance, fiber bleach, fiber treatment agent, fiber pretreatment agent, fiber post-treatment agent, fiber nutrition agent, fiber Essences, fiber styling agents, fiber coloring agents or fiber bleaching agents are provided, preferably fiber softeners or fiber deodorants, and more preferably fiber softeners, but are not limited thereto.
  • the fiber treatment composition for example, textile detergents, fabric softeners, fiber deodorant, fiber fragrance, fiber bleach, fiber treatment agent, fiber pretreatment agent, fiber post-treatment agent, fiber nutrition agent, fiber Essences, fiber styling agents, fiber coloring agents or fiber bleaching agents are provided, preferably fiber softeners or fiber deodorants, and more preferably fiber softeners, but are not limited thereto.
  • the present inventors have solved the residual phenomenon of laundry residues remaining in clothes during or after washing after a long study by using cationic water-soluble polymer, and the composition for fiber treatment which is excellent in preventing desalinating and / or dust adsorption.
  • the cationic polymer may be a polymer having a cationic quaternary ammonium or an amine or an imine group in its structure, and a quaternary ammonium product or dimethyldiallyl in which acrylamide and dimethyldiallylammonium chloride are polymerized.
  • Ammonium alone or polymerized with acrylic acid for example poly-diallyldimethylammonium chloride (polyquaternium-6), acrylamide-diallyldimethylammonium chloride (polyquaternium-7), polyvinylpyrrolidone (PVP ) -Dimethylaminoethyl methacrylate copolymer, polyvinylpyrrolidone (PVP) -dimethylaminoethyl methacrylate (polyquaternium-11), acrylic acid-diallyldimethylammonium chloride (polyquaternium-22), acrylic acid -Diallyldimethylammonium chloride-acrylamide polymer (polyquaternium-39), quaternary polyvinyl alcohol, cationic polyvinyl alcohol, cationic polyvinyl Cool derivatives, polyamines, polyethyleneimines, ethoxylated polyethyleneimines, polyvinylimidazoles, polyquaternium-16 and polyquaternium- copoly
  • the cationic guar derivatives in the present invention may be, for example Guar hydroxypropyl trimonium chloride, or hydroxypropyl guar hydroxyalkyl cationic guar derivatives such as trimonium chloride (e.g., JAGUAR ® C17).
  • the cationic cellulose derivative may be, for example, polyquaternium-10, polyquaternium-67, or a mixture thereof.
  • the cationic polymer of the present invention is a diallyldimethylammonium chloride with acrylamide, acrylic acid or homopolymerized poly-diallyldimethylammonium chloride (polyquaternium-6), acrylamide-diallyldimethylammonium chloride (polyquater) Nium-7), polyquaternium-10, polyvinylpyrrolidone (PVP) -dimethylaminoethyl methacrylate (polyquaternium-11), vinylpyrrolidone (VP) and vinylimidazole (QVI) Polymers polyquaternium-16 and polyquaternium-44, acrylic acid-diallyldimethylammonium chloride (polyquaternium-22), polyquaternium-39, polyquaternium-67, polyethyleneimine, ethoxylated polyethyleneimine , Cationic polyvinyl alcohol, cationic starch derivatives and cationic guar derivatives can be any one or a mixture of two or more thereof
  • the cationic polymer of the present invention may be a diallyldimethylammonium chloride with acrylamide, acrylic acid, or a homopolymerized poly-diallyldimethylammonium chloride (polyquaternium-6), acrylamide-diallyldimethylammonium chloride (Polyquaternium-7), polyvinylpyrrolidone (PVP) -dimethylaminoethyl methacrylate (polyquaternium-11), acrylic acid-diallyldimethylammonium chloride (polyquaternium-22), vinylpyrrolidone ( Polyquaternium-16 and polyquaternium-44, polymers of VP) and vinylimidazole (QVI), polyethyleneimine, ethoxylated polyethyleneimine, cationic cellulose derivatives, cationic starch derivatives, cationic guar derivatives, and It may be any one selected from the group consisting of cationic polyvinyl alcohol or mixtures or copolymers of two
  • the cationic water-soluble polymer may have a charge density of about 0.1 to 25 meq / g at pH 7, preferably about 0.5 to 20 meq / g, more preferably about 1 to 10. meq / g. Most preferably about 5 to 8 meq / g.
  • washing residue residue suppression, anti-scattering prevention, or dust adsorption preventing effect which is an object of the present invention, may be low, and in the case of more than about 25 meq / g, there may be a problem that the stains on the fibers are fixed. Can be.
  • the cationic water-soluble polymer may be included in an amount of about 0.1 to 50% by weight, preferably about 0.3 to 30% by weight, and more preferably about 0.5 to 20% by weight, based on the total weight of the composition.
  • the effect of preventing laundry residue residue, preventing desalting or adsorbing dust, which is an object of the present invention may be low, and when it is more than about 50% by weight, it is uneconomical.
  • the fiber treatment composition according to the present invention may include a nonionic surfactant in addition to the cationic polymer.
  • the nonionic surfactants include, but are not limited to, hydrogenated castor oils, polyoxyethylene alkyl ethers, coconut diethanolamides, fatty acid alkanolamines, amine oxides, alkyl polyglucosides, At least one selected from the group consisting of kenyl polyethylene alkyl ether and sugar ether.
  • the nonionic surfactant may be included in an amount of about 0.1 to 80% by weight, preferably about 0.5 to 40% by weight, and more preferably about 1 to 20% by weight, based on the total weight of the composition.
  • Fiber treatment composition according to the present invention may include a weight ratio of the cationic water-soluble polymer and nonionic surfactant 0.1 to 20: 1, preferably 0.5 to 10: 1, more preferably 0.5-5: 1.
  • composition for treating fibers according to the present invention may be for preventing residue of laundry residues, preventing demineralization or preventing adsorption of dust. More specifically, the composition for treating fibers according to the present invention is excellent as can be seen in the following experimental example, laundry residue residue suppression, anti-aliasing or dust adsorption prevention effect that could not be confirmed in the conventional fiber treatment composition.
  • the fiber treatment composition according to the present invention is provided as a fiber treatment composition for inhibiting laundry residue residue, a fiber treatment composition for preventing desalting salt, or a fiber treatment composition for preventing dust adsorption.
  • the laundry debris generally refers to the debris that appears on the laundry during washing, and may include, for example, all of the laundry debris or fiber debris generated from the laundry.
  • the laundry detergent may include a builder added to increase washing power, an insoluble ingredient of the detergent, residues complexed with the detergent, biofilm, zeolite, carbonate, phosphate, sulfate, and the like.
  • the fiber residue generated in the laundry may include all of the fibers of the laundry constituting the laundry.
  • debris from the fibers includes, for example, but not limited to, fiber dust, clothes dust, lint, dirt, dust, airborne dust, pollen, fine dust, animal hair, hair, hair, and the like. do.
  • the fiber dreg particles may have a diameter of about 1 to 50 ⁇ m, but are not limited thereto.
  • the desalting prevention is a term that includes both desalting and desalting of dyes included in laundry.
  • the dust is not limited thereto, but includes all fine particles that may be attached to laundry such as dust and fine dust.
  • the fiber treatment composition according to the invention it is possible to prevent the dust is adsorbed on the laundry surface.
  • the composition for fiber treatment is not limited to the treatment aspect (treatment time, components used together, formulation, etc.) as long as it does not inhibit the washing residue residue suppression, anti-aliasing or dust adsorption effect.
  • the fiber treatment composition according to the present invention may be treated separately, sequentially or simultaneously with a conventional detergent, may be treated separately, sequentially or simultaneously with a fabric softener after normal washing, and with a conventional detergent or fiber It may be included and processed together in the softening agent.
  • composition for treating fibers according to the present invention is excellent in its original characteristics, for example, its softness, reverberation, and antistatic effect, in addition to the effects of washing residue residue prevention, anti-aliasing or dust adsorption. It is as confirming in the Example of this invention.
  • composition for treating fibers according to the present invention may be formulated into a liquid, spray, gel, paste, powder, sheet, film, pellet, granule or pastille, and the like, and preferably formulated into a liquid or spray. have.
  • the present invention provides a method for producing a composition for treating fibers for inhibiting washing residues, preventing desalinating salts or preventing adsorption of dust, including adding a cationic water-soluble polymer.
  • the method may further include adding a nonionic surfactant.
  • Preparation of the fiber treatment composition may be prepared through a method generally practiced in the art.
  • the present invention is a method for treating the fiber to suppress the residue of laundry residues, a method for treating the fiber to prevent fiber leaving salt, or the composition to the fiber to prevent dust adsorption on the fiber Provide a way to.
  • composition for treating a fiber according to the present invention exhibits excellent properties of preventing washing residues, preventing desalting or adsorbing dust.
  • Figure 1 shows the results of pollen adsorption prevention test.
  • Figure 2 shows the results of the pollen adsorption prevention confirmation of the spray formulation.
  • the present inventors produced a composition for treating fibers with a composition as shown in Tables 1 and 2 below.
  • Comparative Example 1 used TEA Ester Quaternary (TEA Ester quat, INCI Name: dehydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%) as a general fabric softener composition.
  • Comparative Example 2 is a fiber treating composition having a detergent residue removal function including citric acid.
  • Comparative Example 3 is a general fiber deodorant composition
  • Comparative Examples 4 and 5 are a composition of the deodorizing, antistatic and anti-wrinkle spray products
  • TEA Ester quat and silicone are commonly used as an antistatic agent
  • silicone is an emulsion amino modified silicone.
  • Deodorants include green tea, extracts containing polyphenols such as persimmon leaves, cyclic dextrins, and the like, and green tea extract was used here.
  • the cationic water soluble high molecular compound used in the Example is as follows.
  • Cationic PVA is GOHSENX TM K from NIPPON GOHSEI
  • Amphoteric modified Starch is Polyquart® Ecoclean from BASF
  • Polyethyleneimine is BACA's ethoxylated Polyethyleneimine (HPSF)
  • Cationic ampholytic acrylate polymer is Lubrizol's Merquat TM 295 (INCI Name: Poly Quarterium-22)
  • Poly-DADMAC INCI Name: Polyquaternium-6
  • Poly-DADMAC-acrylamide INCI Name: Polyquaternium-7) are Lubrizol.
  • the trade names are Merquat TM 100 Polymer, Merquat.
  • Each raw material is converted on a 5% active basis, for example, in the case of Comparative Example 1 is 5.56% by weight of the total composition content.
  • non-ionic surfactant low foaming Hydrogenated Castor Oil (HCO) was used, and polyoxyethylene alkyl ether, coconut diethanolamide, fatty acid alkanolamine, amine oxide, alkyl which can solubilize common flavors or oils. Both polyglucosides can be used.
  • HCO Hydrogenated Castor Oil
  • the present inventors comply with the test method in EL306 (fiber softener) of the environmental label certification standard of the Korea Environmental Industry and Technology Institute as the laundry test conditions, the sample usage was 0.67ml / L.
  • Weight corrections for each laundry garment were excluded to ensure objective residuals.
  • the laundry garments used were 100% black cotton tees, black cotton / polyester blend tees (66% / 34%) and black blends.
  • Three types of fabric (acrylic / rayon / polyester / span, 47% / 28% / 19% / 6%) were used.
  • the present inventors were evaluated according to the ASTM D5548 method for the anti-desalting experiment, the desalting fabric used was Direct Blue 90, Blue 1 desalting cloth (TESTFABRICS, USA), Bleached cotton print cloth (undyed) (TESTFABRICS, USA) was used. Color change was measured using a Spectrophotometer (SA 4000, NIPPON DENSHOKU), the measurement results are shown in Table 4 (sample usage: 0.67 ml / L).
  • the present inventors proceeded with the sample usage of 0.67ml / L according to the test method in EL306 for the yellowing experiment, and additionally bleached cotton print cloth (undyed) (TESTFABRICS, USA) for each two sheets to observe the color change.
  • the rinse was performed once by input. After drying for 12 hours in a constant temperature and humidity room, it was treated for 48 hours in a daylight fastness tester (Fadeometer). Color change was measured by using a spectrophotometer (SA 4000, NIPPON DENSHOKU) ⁇ b value. The larger the ⁇ b value, the more yellowish.
  • the present inventors put 0.2g of pine pollen in a polyethylene bag (20L) and shake it up and down 30 times (once per second) to confirm the effect of preventing pollen adsorption of the composition according to the present invention 6cm ⁇ 6cm black fabric 5 sheets of (polyester / wool, 50% / 50%) are shaken up and down 30 times (once / second) and taken out immediately, and then the pine powder attached to the fiber surface is visually evaluated and magnified 200 times with a microscope. Counted and averaged. The experiment was conducted in a constant temperature and humidity room [20 ° C, 40% relative humidity (RH)].
  • the fabric was ethanol to remove the contamination and organic matter on the surface, and then dried in a constant temperature and humidity room (20 °C, 40% RH).
  • the evaluation was conducted according to the EL3016 test method, and the laundry detergent was LG Household & Health Tech's powder detergent (0.84g / L), and the amount of each sample was 0.67ml / L at the last rinse.
  • test tools such as pine powder and envelopes were also stored in a constant temperature and humidity room for more than 12 hours.
  • Detergent was treated only as a control group, and the evaluation was visually performed by 10 panelists and averaged based on the 5-point scale method.
  • the inventors put 0.2g of pine pollen in a polyethylene bag (20L) and shake it up and down 30 times (1 time / 1 second) to confirm the effect of preventing pollen adsorption of the composition according to the present invention 6cm ⁇ 6cm black 5 pieces of fabric (polyester / wool, 50% / 50%) are shaken up and down 30 times (once / second), and taken out immediately, and the pine powder attached to the fiber surface is visually evaluated and 200 times under a microscope. The average was calculated by enlarging the number by enlarging. The experiment was conducted in a constant temperature and humidity room [20 ° C, 40% relative humidity (RH)].
  • the fabric was ethanol to remove the contamination and organic matter on the surface, and then dried in a constant temperature and humidity room (20 °C, 40% RH). After spraying 1 g of each composition, the composition was dried in a constant temperature and humidity room for at least 12 hours, and experimental tools such as pine powder and envelopes were also stored in a constant temperature and humidity room. Control means untreated fabric.
  • the present inventors selected 30 hairs of similar length and thickness for black pet fabrics (acrylic / rayon / polyester / span, 47% / 28% / 19% / 6%) and then subjected to a washing machine rinsing cycle once, and then measuring the number of remaining hairs, and performing the method three times to average the number of hairs remaining before and after the fabric.
  • the sample amount was 0.67 ml / L.
  • the inventors have measured the flexibility and antistatic power of the compositions according to the invention.
  • -Judgment is equal to 0 compared to only detergent and nothing at the time of the last rinse, 1 for good compared to detergent, 2 for superior to detergent, -1 for slightly inferior to detergent, -2 for inferior to detergent It evaluated by the point.
  • Antistatic evaluation was performed using a rotary static tester (model: EC-3DN, INTEC.CO., LTD). It was measured according to the charging test method (KS K 0555: 2010 B method of friction band voltage measurement) of fabrics and knitted fabrics, and an attached back cloth (cotton friction cloth) for dye fastness test of KS K 0905 was used.
  • the present inventors prepared a powder type detergent, a liquid type detergent, a sheet type detergent with a formulation as shown in Table 8 below, including the composition for treating fibers according to the present invention.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

La présente invention concerne une composition destinée à un traitement de fibre et un procédé pour la produire et, plus précisément, une composition destinée à un traitement de fibre, comprenant un polymère cationique soluble dans l'eau. La composition de traitement de fibre selon la présente invention présente d'excellentes propriétés de suppression d'un résidu de blanchissage, de prévention du transfert de colorant et de décoloration, ou de prévention de l'adsorption de poussière.
PCT/KR2016/013558 2015-12-21 2016-11-23 Composition destinée au traitement de fibre WO2017111323A1 (fr)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
KR10-2015-0182943 2015-12-21
KR1020150182943A KR102073867B1 (ko) 2015-12-21 2015-12-21 섬유 처리용 조성물
KR10-2016-0030918 2016-03-15
KR10-2016-0030913 2016-03-15
KR1020160030913A KR102030757B1 (ko) 2016-03-15 2016-03-15 섬유 처리용 조성물
KR1020160030918A KR20170074148A (ko) 2016-03-15 2016-03-15 섬유 처리용 조성물

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WO2017111323A1 true WO2017111323A1 (fr) 2017-06-29

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Cited By (5)

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KR20190056053A (ko) * 2017-11-16 2019-05-24 주식회사 엘지생활건강 누적 흡착 방지 컨디셔닝 폴리머 및 이를 포함하는 조성물
KR20190124192A (ko) * 2017-11-16 2019-11-04 주식회사 엘지생활건강 누적 흡착 방지 컨디셔닝 폴리머 및 이를 포함하는 조성물
CN110964605A (zh) * 2019-12-05 2020-04-07 广州立白企业集团有限公司 一种柔软型液体洗涤剂组合物
CN111876272A (zh) * 2020-07-28 2020-11-03 上海时宜品牌管理有限公司 一种洗衣液
KR20210070263A (ko) * 2019-10-28 2021-06-14 주식회사 엘지생활건강 누적 흡착 방지 컨디셔닝 폴리머 및 이를 포함하는 조성물

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KR20190056053A (ko) * 2017-11-16 2019-05-24 주식회사 엘지생활건강 누적 흡착 방지 컨디셔닝 폴리머 및 이를 포함하는 조성물
KR102040114B1 (ko) * 2017-11-16 2019-11-04 주식회사 엘지생활건강 누적 흡착 방지 컨디셔닝 폴리머 및 이를 포함하는 조성물
KR20190124192A (ko) * 2017-11-16 2019-11-04 주식회사 엘지생활건강 누적 흡착 방지 컨디셔닝 폴리머 및 이를 포함하는 조성물
KR102263749B1 (ko) * 2017-11-16 2021-06-10 주식회사 엘지생활건강 누적 흡착 방지 컨디셔닝 폴리머 및 이를 포함하는 조성물
KR20210070263A (ko) * 2019-10-28 2021-06-14 주식회사 엘지생활건강 누적 흡착 방지 컨디셔닝 폴리머 및 이를 포함하는 조성물
KR102314140B1 (ko) * 2019-10-28 2021-10-18 주식회사 엘지생활건강 누적 흡착 방지 컨디셔닝 폴리머 및 이를 포함하는 조성물
CN110964605A (zh) * 2019-12-05 2020-04-07 广州立白企业集团有限公司 一种柔软型液体洗涤剂组合物
CN110964605B (zh) * 2019-12-05 2022-06-28 广州立白企业集团有限公司 一种柔软型液体洗涤剂组合物
CN111876272A (zh) * 2020-07-28 2020-11-03 上海时宜品牌管理有限公司 一种洗衣液

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