WO2017094625A1 - Cosmétique capillaire - Google Patents

Cosmétique capillaire Download PDF

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Publication number
WO2017094625A1
WO2017094625A1 PCT/JP2016/085039 JP2016085039W WO2017094625A1 WO 2017094625 A1 WO2017094625 A1 WO 2017094625A1 JP 2016085039 W JP2016085039 W JP 2016085039W WO 2017094625 A1 WO2017094625 A1 WO 2017094625A1
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Prior art keywords
hair
acid
group
mass
component
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PCT/JP2016/085039
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English (en)
Japanese (ja)
Inventor
晶子 松藤
健介 青柳
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花王株式会社
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Priority to SG11201804615SA priority Critical patent/SG11201804615SA/en
Publication of WO2017094625A1 publication Critical patent/WO2017094625A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to a hair cosmetic that is washed off after being applied to hair.
  • Patent Documents 1 and 2 disclose a hair conditioner that is excellent in touch and that contains a cationic surfactant, a higher alcohol, an oil and fat, silicone, and the like.
  • Patent Document 2 discloses a hair conditioning composition in which volatile silicone M3T (methyltrimethicone), a nonvolatile silicone derivative and a cationic surfactant are combined.
  • Patent Document 3 discloses an optically transparent hair treatment agent containing a hydrophobic silicone compound and a hydrophilic silicone compound, as well as various active agents and polymers.
  • Patent Document 1 JP-A-6-172131 (Patent Document 2) JP-A-2006-265205 (Patent Document 3) JP-T 2008-520614
  • the present invention provides a hair cosmetic containing components (A) to (D) and water, which is used after being applied to hair and washed away.
  • the present invention also provides a hair treatment method in which the above-described hair cosmetic is applied to the hair and washed away with water.
  • hair damage caused by hair sets using heat such as hair irons and hair dryers which has become a habit mainly among young women, has become serious. It is known that hair damage is accompanied by the loss of 18-MEA (18-methyleicosanoic acid), which is a fatty acid covering the hair surface, and causes increased surface friction as the hair surface becomes hydrophilic. Damaged and hydrophilized hair not only loses its smoothness but also becomes difficult to dry after shampooing, and it takes a long time to dry with a dryer or the like, which is a physical burden. In addition, wet damaged hair tends to get entangled, and the catches that occur during drying of the dryer add to the accumulation of further damage and the psychological burden on the consumer.
  • 18-MEA 18-methyleicosanoic acid
  • the present invention makes it easy to disperse each piece of wet hair, regardless of the type of cationic surfactant contained, by washing it after applying it to the hair after shampooing.
  • the present invention relates to a hair cosmetic that can be dried over time and has excellent smoothness during rinsing.
  • “Hair dispersal” is important as a factor to increase the drying speed of hair after washing. That is, when the hair is dispersed, the contact area with the towel increases when the towel is dried, and moisture of the hair is absorbed quickly by the towel, and when the dryer is dried (even during natural drying), the contact area with the air is increased. Will increase and the moisture of the hair will evaporate quickly.
  • the present inventors have used an amino-polyether co-modified silicone having a specific structure and a volatile silicone in combination to produce an adhesive component on the hair. It has been found that the amount of adsorption is reduced and the bulky adhesive component hardly adheres to the hair. As a result, the present inventors have found that the adhesiveness of each hair can be weakened, wet hair after treatment becomes extremely easy to disperse, and the drying speed can be dramatically improved without tangling.
  • Component (A) Cationic surfactant
  • cationic surfactant of component (A) include (i) alkyltrimethylammonium salt, (ii) alkoxyalkyltrimethylammonium salt, (iii) dialkyldimethylammonium salt, (iv) alkyldimethylamine and salts thereof, ( v) alkoxyalkyldimethylamine and its salt, (vi) alkylamidoalkyldimethylamine and its salt, and the like.
  • alkyltrimethylammonium salt examples include those represented by the following general formula (1).
  • R 1 represents an alkyl group having 12 to 22 carbon atoms
  • X ⁇ represents a halide ion such as a chloride ion or a bromide ion; a methosulphate ion, an ethosulphate ion, a methosphosphate ion, an ethosphosphate ion. , Methocarbonate ions and the like.
  • cetyltrimethylammonium chloride stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, behenyltrimethylammonium methosulfate and the like.
  • alkoxyalkyltrimethylammonium salt examples include those represented by the following general formula (2).
  • R 2 O—R 3 —N + (CH 3 ) 3 X ⁇ (2)
  • R 3 represents an ethylene group or a propylene group optionally substituted by a hydroxy group
  • X ⁇ represents a halogen such as a chloride ion or a bromide ion.
  • Compound ion; methosulphate ion, ethosulphate ion, methosphosphate ion, ethosphosphate ion, methcarbonate ion, etc.
  • Specific examples include stearoxypropyltrimethylammonium chloride, stearoxyethyltrimethylammonium chloride, stearoxyhydroxypropyltrimethylammonium chloride, and the like.
  • dialkyldimethylammonium salt examples include those represented by the following general formula (3).
  • R 4 independently represents an alkyl group having 12 to 22 carbon atoms or a benzyl group, and X ⁇ represents a halide ion such as a chloride ion or a bromide ion; a methosulphate ion, an ethosulphate ion, or a methophos ion.
  • ions include fate ions, ethophosphate ions, methocarbonate ions, and the like.
  • Specific examples include distearyl dimethyl ammonium chloride.
  • alkyldimethylamine and its salt Alkyldimethylamine reacts with an acid to form a quaternary ammonium salt, which becomes a surfactant. Therefore, alkyldimethylamine and its salt are defined here as a cationic surfactant. Moreover, the content is converted by the mass of alkyldimethylamine. Examples of alkyldimethylamine and salts thereof include those represented by the following general formula (4) and salts thereof. R 5 —N (CH 3 ) 2 (4) [Wherein R 5 represents an alkyl group having 12 to 22 carbon atoms. ]
  • Examples of the salt include salts with organic acids or inorganic acids.
  • Examples of the organic acid include monocarboxylic acids such as acetic acid and propionic acid; dicarboxylic acids such as malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, and phthalic acid; polycarboxylic acids such as polyglutamic acid; Examples thereof include hydroxycarboxylic acids such as glycolic acid, lactic acid, hydroxyacrylic acid, glyceric acid, malic acid, tartaric acid and citric acid; acidic amino acids such as glutamic acid and aspartic acid.
  • Examples of the inorganic acid include hydrochloric acid, sulfuric acid, phosphoric acid and the like.
  • organic acids are preferable, dicarboxylic acids, hydroxycarboxylic acids, and acidic amino acids are preferable.
  • dicarboxylic acids maleic acid and succinic acid are more preferable.
  • hydroxycarboxylic acid glycolic acid, lactic acid, and malic acid are more preferable.
  • acidic amino acid glutamic acid is more preferable.
  • alkyldimethylamine and salts thereof include N, N-dimethylbehenylamine, N, N-dimethylstearylamine, and organic acid salts thereof.
  • N, N-dimethylbehenylamine lactate, N, N-dimethylstearylamine glycolate and the like are preferred.
  • alkoxyalkyldimethylamine and salts thereof Alkoxyalkyldimethylamine reacts with an acid to form a quaternary ammonium salt, which becomes a surfactant. Accordingly, alkoxyalkyldimethylamine and its salts are defined herein as cationic surfactants. Moreover, the content is converted with the mass of alkoxyalkyl dimethylamine. Examples of the alkoxyalkyldimethylamine and salts thereof include those represented by the following general formula (5) and salts thereof. R 6 —O—R 7 —N (CH 3 ) 2 (5) [Wherein R 6 represents an alkyl group having 12 to 22 carbon atoms, and R 7 represents an ethylene group or a propylene group. ]
  • Examples of the salt include salts with organic acids or inorganic acids.
  • Examples of the organic acid include monocarboxylic acids such as acetic acid and propionic acid; dicarboxylic acids such as malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, and phthalic acid; polycarboxylic acids such as polyglutamic acid; Examples thereof include hydroxycarboxylic acids such as glycolic acid, lactic acid, hydroxyacrylic acid, glyceric acid, malic acid, tartaric acid and citric acid; acidic amino acids such as glutamic acid and aspartic acid.
  • Examples of the inorganic acid include hydrochloric acid, sulfuric acid, phosphoric acid and the like.
  • organic acids are preferable, dicarboxylic acids, hydroxycarboxylic acids, and acidic amino acids are preferable.
  • dicarboxylic acids maleic acid and succinic acid are more preferable.
  • hydroxycarboxylic acid glycolic acid, lactic acid, and malic acid are more preferable.
  • acidic amino acid glutamic acid is more preferable.
  • alkoxyalkyldimethylamines and salts thereof include N, N-dimethyl-3-hexadecyloxypropylamine, N, N-dimethyl-3-octadecyloxypropylamine and organic acid salts thereof, N N, N-dimethyl-3-hexadecyloxypropylamine lactate and N, N-dimethyl-3-octadecyloxypropylamine glycolate are preferred.
  • alkylamidoalkyldimethylamine and its salt Alkylamidoalkyldimethylamine reacts with an acid to form a quaternary ammonium salt to become a surfactant. Therefore, herein, alkylamidoalkyldimethylamine and salts thereof are defined as cationic surfactants. Moreover, the content is converted with the mass of alkylamide alkyl dimethylamine. Examples of the alkylamidoalkyldimethylamine and salts thereof include those represented by the following general formula (6) and salts thereof.
  • R 8 CONH— (CH 2 ) m —N (CH 3 ) 2 (6) [Wherein R 8 represents an alkyl group having 12 to 22 carbon atoms, and m represents a number of 2 to 4. ]
  • R 8 is preferably an alkyl group having 14 to 22 carbon atoms, and preferably an alkyl group having 16 to 20 carbon atoms, from the viewpoint of smoothness during rinsing and difficulty in entanglement during drying of the dryer. Those are more preferred.
  • the salt include salts with organic acids or inorganic acids.
  • Examples of the organic acid include monocarboxylic acids such as acetic acid and propionic acid; dicarboxylic acids such as malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, and phthalic acid; polycarboxylic acids such as polyglutamic acid; Examples thereof include hydroxycarboxylic acids such as glycolic acid, lactic acid, hydroxyacrylic acid, glyceric acid, malic acid, tartaric acid and citric acid; acidic amino acids such as glutamic acid and aspartic acid.
  • Examples of the inorganic acid include hydrochloric acid, sulfuric acid, phosphoric acid and the like.
  • organic acids are preferable, dicarboxylic acids, hydroxycarboxylic acids, and acidic amino acids are preferable.
  • dicarboxylic acids maleic acid and succinic acid are more preferable.
  • hydroxycarboxylic acid glycolic acid, lactic acid, and malic acid are more preferable.
  • acidic amino acid glutamic acid is more preferable.
  • alkylamidoalkyldimethylamine and salts thereof include N- (3- (dimethylamino) propyl) docosanamide and salts thereof, and N- (3- (dimethylamino) propyl) stearamide and salts thereof.
  • alkyltrimethylammonium salt (i) alkyltrimethylammonium salt, (ii) alkoxyalkyltrimethylammonium salt, (v) alkoxyalkyldimethylamine and salt thereof, (vi) alkylamidoalkyldimethylamine and salt thereof are preferable, and dried.
  • alkoxyalkyldimethylamine and its salt (v) alkoxyalkyldimethylamine and its salt, and (vi) alkylamidoalkyldimethylamine and its salt are preferable.
  • N, N-dimethyl-3-hexadecyloxypropylamine and its salts are considered from the viewpoints of smoothness during rinsing, ease of hair bundling, difficulty in entanglement during dryer drying, and speed of drying.
  • N, N-dimethyl-3-octadecyloxypropylamine and its salt, N- (3- (dimethylamino) propyl) docosanamide and its salt, N- (3- (dimethylamino) propyl) stearamide and its salt are preferable .
  • Component (A) cationic surfactant can be used alone or in combination of two or more.
  • the content of the component (A) in the hair cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and still more preferably 0.75% from the viewpoint of smoothness when using a conditioner and appropriate quick drying performance. It is preferably 10% by mass or less, more preferably 8% by mass or less, still more preferably 6% by mass or less, still more preferably 4% by mass or less, and further preferably 3% by mass or less.
  • Component (B) Higher alcohol
  • the higher alcohol of component (B) may be linear and branched, or saturated and unsaturated aliphatic alcohols, and the carbon number thereof is preferably 10 or more, more preferably 14 or more, and still more preferably 16 In addition, it is preferably 22 or less, more preferably 20 or less, and still more preferably 18 or less.
  • Specific examples include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, hexyl decanol, isostearyl alcohol, oleyl alcohol, 2-octyldodecanol and the like. Of these, stearyl alcohol, cetyl alcohol, and myristyl alcohol are preferred. These higher alcohols can be used alone or in combination of two or more.
  • the content of the component (B) in the hair cosmetic composition of the present invention is preferably 1% by mass or more, more preferably 2% by mass or more, and further preferably 3% from the viewpoint of smoothness from application to rinsing and after drying. From the viewpoint of quick drying performance, stickiness control after drying, and adjustment to an easy-to-use viscosity, it is preferably 10% by mass or less, more preferably 8% by mass or less, and even more preferably 7% by mass or less. More preferably, it is 6 mass% or less.
  • Component (C) Silicone having polyoxyalkylene side chain and aminoalkyl side chain
  • Examples of the silicone having a polyoxyalkylene side chain and an aminoalkyl side chain as component (C) include those represented by the following general formula (7).
  • R 9 represents a divalent hydrocarbon group having 1 to 6 carbon atoms
  • R 10 represents a substituent having an amino group or an ammonium group represented by —R 11 Z.
  • R 11 represents a divalent hydrocarbon group having 1 to 6 carbon atoms
  • Z represents —NR 12 2 , —NR 12 (CH 2 ) c NR 12 2
  • —NR 12 (CH 2 ) c NR 12 represents a monovalent group selected from the group consisting of C ⁇ O (R 13 )
  • R 12 represents a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms
  • R 13 represents a hydrocarbon having 1 to 4 carbon atoms.
  • C represents an integer of 2 to 6
  • R 14 represents a hydrocarbon group having 1 to 4 carbon atoms or a trimethylsilyl group.
  • R 9 is a divalent hydrocarbon group having 2 to 4 carbon atoms
  • R 10 is —R 11 —NH 2
  • R 11 is a divalent hydrocarbon group having 2 to 4 carbon atoms
  • R 12 and It is preferable that each R 14 is independently a methyl group or an ethyl group.
  • the viscosity at 25 ° C. of component (C), a single one hair wet very loose and easy to improve the finger combability, yet from the viewpoint of the excellent in smoothness during rinsing preferably 4000 mm 2 / s or less, more preferably 3000 mm 2 / s or less, further preferably 2000 mm 2 / s or less, more preferably 1000 mm 2 / s or less, more preferably 800 mm 2 / s or less, and preferably 100 mm 2 / s or more. More preferably, it is 200 mm 2 / s or more.
  • the viscosity at 25 ° C was measured using a capillary viscometer, and the time for a certain volume of liquid to flow through the capillary of the viscometer at 25 ° C and 1013.25 hPa was measured. Is calculated using The capillary viscometer is generally of a type such as Ubbelohde or Canon-Fenske.
  • Viscosity (mm 2 / s) Outflow time (seconds) x Viscometer constant
  • component (C) examples include ABIL SOFT AF100 (Evonik Industry Co., Ltd .: viscosity 400 mm 2 / s), X-22-3939A (Shin-Etsu Chemical Co., Ltd .: viscosity 2,800 mm 2 / s), Silsense A21 (Lubrisol) (Manufactured by company: viscosity 250 mm 2 / s).
  • the silicone having a polyoxyalkylene side chain and an aminoalkyl side chain can be used alone or in combination of two or more.
  • the content of the component (C) in the hair cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1%, from the viewpoint of easily spreading wet hair, preventing tangling, and drying the hair in a short time. % By mass or more, more preferably 0.2% by mass or more, more preferably 0.3% by mass or more.
  • the viscosity is preferably 5% by mass or less, more preferably 4% by mass or less, still more preferably 3% by mass or less, and further preferably 2.5% by mass or less.
  • Component (D): Volatile silicone As the volatile silicone of component (D), one or more selected from the group consisting of linear and cyclic silicone oils having a boiling point of 260 ° C. or lower under 1013.25 hPa can be used. Further, from the viewpoint of stability during storage, the boiling point under 1013.25 hPa is preferably 35 ° C. or higher.
  • chain volatile silicone examples include chain silicones represented by the following formula (8) or the following general formula (9), and examples of the cyclic volatile silicone include those represented by the following general formula (10). And cyclic silicone.
  • methyltrimethicone represented by the formula (8) is preferable from the viewpoint of making each wet hair very easy to disperse, improving finger passage, and excellent smoothness during rinsing. .
  • the volatile silicone of component (D) can be used alone or in combination of two or more.
  • the content of the component (D) in the hair cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1%, from the viewpoint of making it easy to disperse wet hair, preventing tangling, and drying the hair in a short time. It is preferably 10% by mass or less, more preferably 0.5% by mass or more, and from the viewpoint of ease of hair dispersion, speed of drying, suppression of squeezing during rinsing, and suppression of stickiness after drying. More preferably, it is 8 mass% or less, More preferably, it is 6 mass% or less, More preferably, it is 4 mass% or less, More preferably, it is 3 mass% or less, More preferably, it is 2 mass% or less.
  • the mass ratio (C) / (D) of component (C) to component (D) allows the conditioning component to be evenly adsorbed to the entire hair surface and weakens the adhesiveness of each hair. From the viewpoint of making the later wet hair very easy to disperse and dramatically improving the drying speed without entanglement, it is preferably 0.01 or more, more preferably 0.05 or more, further preferably 0.08 or more, more preferably 0.1 or more, still more preferably. Is 0.2 or more, preferably 5 or less, more preferably 4 or less, still more preferably 3 or less, still more preferably 2 or less, still more preferably 1 or less, still more preferably 0.8 or less.
  • the hair cosmetic composition of the present invention contains water as a medium. Water is the remaining amount of components (A) to (D) and other components.
  • the hair cosmetic of the present invention may further contain other components generally used in hair cosmetics depending on the purpose.
  • Antidandruff agent pH adjuster; vitamin agent; bactericidal agent; anti-inflammatory agent; antiseptic agent; chelating agent; moisturizer such as panthenol; colorant such as dye and pigment; Polar solvent extract, protein obtained from shells or pearls having a pearl layer or hydrolyzate thereof, protein obtained from silk or hydrolyzate thereof, protein-containing extract obtained from legume seeds, ginseng extract, Extracts such as rice germ extract, hibamata extract, camellia extract, aloe extract, moon peach leaf extract, chlorella extract; pearl powder such as mica titanium; refreshing agent such as menthol: fragrance; pigment; UV absorption Agents; antioxidants; and other components described in ENCYCLOPEDIA OF SHAMPOO INGREDIENTS (MICELLE PRESS).
  • the pH of the hair cosmetic composition of the present invention is preferably 2.0 or more, more preferably 2.5 or more, and preferably 7.5 or less, more preferably 6.5 or less, and further preferably 5.5 or less.
  • the pH of the hair cosmetic refers to a value at 25 ° C. when diluted 20 times by weight with water.
  • the hair cosmetic composition of the present invention is used after being applied to the hair and washed away, and examples thereof include those used in the bathroom such as hair rinse, hair conditioner, hair treatment, hair pack and the like.
  • the hair cosmetic composition of the present invention is applied to the hair and then washed away with water. Thereby, it is excellent in the smoothness at the time of a rinse, and makes it easy to disperse each wet hair one by one, it is good to pass through a finger without entanglement, and hair can be dried in a short time.
  • a hair cosmetic comprising components (A) to (D) and water, which is used after being applied to hair and washed away.
  • Component (A) is preferably alkyltrimethylammonium salt, alkoxyalkyltrimethylammonium salt, dialkyldimethylammonium salt, alkyldimethylamine and its salt, alkoxyalkyldimethylamine and its salt, and alkylamidoalkyldimethylamine and its Hair cosmetic according to ⁇ 1>, which is one or more compounds selected from the group consisting of salts.
  • the content of component (A) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 0.75% by mass or more, and preferably 10% by mass or less, more preferably 8% by mass.
  • the hair cosmetic composition according to ⁇ 1> or ⁇ 2> which is not more than mass%, more preferably not more than 6 mass%, still more preferably not more than 4 mass%, still more preferably not more than 3 mass%.
  • Component (B) is preferably 10 or more carbon atoms, more preferably 14 or more carbon atoms, still more preferably 16 or more carbon atoms, and preferably 22 or less carbon atoms, more preferably 20 or less carbon atoms,
  • the content of component (B) is preferably 1% by mass or more, more preferably 2% by mass or more, still more preferably 3% by mass or more, and preferably 10% by mass or less, more preferably 8% by mass.
  • ⁇ 6> The hair cosmetic according to any one of ⁇ 1> to ⁇ 5>, wherein the component (C) is preferably represented by the following general formula (7).
  • R 9 represents a divalent hydrocarbon group having 1 to 6 carbon atoms
  • R 10 represents a substituent having an amino group or an ammonium group represented by —R 11 Z.
  • R 11 represents a divalent hydrocarbon group having 1 to 6 carbon atoms
  • Z represents —NR 12 2 , —NR 12 (CH 2 ) c NR 12 2
  • —NR 12 (CH 2 ) c NR 12 represents a monovalent group selected from the group consisting of C ⁇ O (R 13 )
  • R 12 represents a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms
  • R 13 represents a hydrocarbon having 1 to 4 carbon atoms.
  • C represents an integer of 2 to 6
  • R 14 represents a hydrocarbon group having 1 to 4 carbon atoms or a trimethylsilyl group.
  • the viscosity of component (C) at 25 ° C. is preferably 4000 mm 2 / s or less, more preferably 3000 mm 2 / s or less, still more preferably 2000 mm 2 / s or less, more preferably 1000 mm 2 / s or less,
  • the content of component (C) is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.2% by mass or more, further preferably 0.3% by mass or more, and preferably 5%.
  • Component (D) is preferably one or more selected from the group consisting of linear and cyclic silicone oils having a boiling point of 260 ° C. or lower under 1013.25 hPa ⁇ 1> to ⁇ 8>
  • the hair cosmetic composition according to any one of the above.
  • Component (D) preferably comprises a chain silicone represented by formula (8), a chain silicone represented by formula (9), and a cyclic silicone represented by formula (10) Hair cosmetic according to ⁇ 9>, which is one or more volatile silicones selected from the group.
  • the content of component (D) is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.5% by mass or more, and preferably 10% by mass or less, more preferably 8% by mass.
  • ⁇ 1> to ⁇ 10> which is not more than mass%, more preferably not more than 6 mass%, still more preferably not more than 4 mass%, still more preferably not more than 3 mass%, still more preferably not more than 2 mass%.
  • the mass ratio (C) / (D) of the component (C) to the component (D) is preferably 0.01 or more, more preferably 0.05 or more, still more preferably 0.08 or more, still more preferably 0.1 or more, and still more preferably. It is 0.2 or more, preferably 5 or less, more preferably 4 or less, further preferably 3 or less, further preferably 2 or less, still more preferably 1 or less, and further preferably 0.8 or less.
  • ⁇ 1> to ⁇ 11> The hair cosmetic composition according to any one of the above.
  • the pH at 25 ° C. when diluted 20 times by mass with water is preferably 2.0 or more, more preferably 2.5 or more, preferably 7.5 or less, more preferably 6.5 or less, and even more preferably 5.5 or less.
  • ⁇ 14> A hair treatment method in which the hair cosmetic composition according to any one of ⁇ 1> to ⁇ 13> is applied to hair and washed away with water.

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Abstract

L'invention concerne un cosmétique capillaire qui contient les composants (A) à (D) et de l'eau, et est utilisé en étant appliqué sur les cheveux puis rincé. (A) est un tensioactif cationique, (B) un alcool supérieur, (C) un silicone possédant une chaîne latérale polyoxyalkylène et une chaîne latérale aminoalkyle, et (D) un silicone volatile.
PCT/JP2016/085039 2015-12-02 2016-11-25 Cosmétique capillaire WO2017094625A1 (fr)

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SG11201804615SA SG11201804615SA (en) 2015-12-02 2016-11-25 Hair cosmetic

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JP2015-235684 2015-12-02
JP2015235684 2015-12-02

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WO2017094625A1 true WO2017094625A1 (fr) 2017-06-08

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WO2020008812A1 (fr) * 2018-07-02 2020-01-09 花王株式会社 Produit cosmétique capillaire
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