WO2017028781A1 - Compound organic fertilizer and preparation method thereof, soil restoration agent and application thereof, and plant planting method - Google Patents

Compound organic fertilizer and preparation method thereof, soil restoration agent and application thereof, and plant planting method Download PDF

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WO2017028781A1
WO2017028781A1 PCT/CN2016/095617 CN2016095617W WO2017028781A1 WO 2017028781 A1 WO2017028781 A1 WO 2017028781A1 CN 2016095617 W CN2016095617 W CN 2016095617W WO 2017028781 A1 WO2017028781 A1 WO 2017028781A1
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organic fertilizer
weight
soil
oil
soil remediation
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PCT/CN2016/095617
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French (fr)
Chinese (zh)
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宫丽梅
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宫丽梅
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials

Definitions

  • the invention relates to a preparation method of a composite organic fertilizer, a composite organic fertilizer prepared by the method, a soil repairing agent containing the above composite organic fertilizer, and the application of the soil repairing agent in soil remediation, and a plant Planting method.
  • organic fertilizer The earliest used organic fertilizer.
  • the use of organic fertilizer has a long history in China.
  • farmers have a proverb: a crop of flowers, all relying on feces.
  • the most important part of farming is the accumulation of fertilizer.
  • farmers have basically relied on soil and fertilizer to cultivate.
  • organic fertilizers in the market are generally divided into three categories: farmyard manure, green manure and humic acid fertilizer. The characteristics are: many nutrients, low concentration, slow release, but only Make base fertilizer.
  • fertilizer also known as inorganic fertilizer.
  • fertilizer also known as inorganic fertilizer.
  • fertilizer also known as inorganic fertilizer.
  • microbial fertilizer The Ministry of Agriculture began to include microbial fertilizer in the fertilizer registration category in 1996. It is stipulated that microbial fertilizer must be inspected and registered in the Ministry of Agriculture. It is a bacterial fertilizer, a living organism, and a powerful decomposition and reduction by bacteria. Activities play a role. China's microbial fertilizer research has been carried out for more than 10 years, and many experiments have been done, and good results have been achieved.
  • One of the experimental data namely, Ziyunying, shows that the first year after the application of microbial fertilizer, the yield will increase by 60%-100%; the second year will increase the yield by 20%-60%; the third year will increase the yield by 15%-40%; the fourth year will increase the yield. 10%.
  • Microbial fertilizer types can be generally divided into: microbial seed dressing agents, various rhizobial fertilizers; compound microbial fertilizers; among them, compound microbial fertilizers contain bacterial fertilizers (rhizobial fertilizer, nitrogen fixation, phosphorus dissolving, potassium dissolving), actinomycetes ( Antibiotics), fungal fertilizers (mycorrhizal fungi, mold fertilizers, yeast fertilizers) and photosynthetic bacteria fertilizers. It is characterized by initial use, robust crops, and high yields.
  • nitrates after the crops have absorbed nitrogen fertilizer, and further conversion into nitrite.
  • High amounts of nitrite are the main culprit in cancer.
  • microbial compound fertilizer is also called whole fertilizer.
  • the effect of microbial compound fertilizer in the past few years is particularly good, because it is an active alien species, which will destroy or even destroy the original species of the land.
  • the land gradually Not long crops, resulting in the loss of land effectiveness.
  • the object of the present invention is to provide a preparation method of a composite organic fertilizer, a composite organic fertilizer prepared by the method, a soil remediation agent capable of better repairing soil, and application of the soil remediation agent in soil remediation, And a planting method to increase the effectiveness of the soil, increase the yield of the soil, and thereby increase the yield, quality and resistance of crops, vegetables, fruits, and the like.
  • the inventors of the present invention found in the research, a method for preparing a composite organic fertilizer, the method comprising: mixing an organic fertilizer, an aqueous ethanol solution and an oil for more than one hour, the oil being an edible oil, the composite organic fertilizer capable of Significantly increase plant yields.
  • the soil remediation agent containing the composite organic fertilizer and the natural crystal powder can improve the soil efficiency, increase the soil output, and thereby improve the yield, quality and resistance of crops, vegetables, fruits and the like.
  • the present invention provides a method for preparing a composite organic fertilizer, which comprises: mixing an organic fertilizer, an aqueous ethanol solution and an oil for more than 1 hour, the oil being an edible oil.
  • the present invention also provides a composite organic fertilizer prepared by the above method.
  • the present invention provides a soil remediation agent comprising the above composite organic fertilizer and natural crystal powder, wherein the content of the natural crystal powder is 0.01 with respect to 100 parts by weight of the composite organic fertilizer. - 45 parts by weight.
  • the invention also provides the use of the above soil remediation agent in soil remediation.
  • the present invention also provides a method of planting a plant in which the above soil resturant is used or the above composite organic fertilizer is used.
  • the composite organic fertilizer of the invention can significantly increase the yield of the plant, and the soil repairing agent of the invention can provide a perfect and harmonious rhizosphere environment for the plants, especially the plants in the adversity, by coordinating the relationship between water and nutrition. Promote rapid growth of plants, increase crop yield and fruit quality, and enhance plant resistance, such as drought resistance, cold resistance, disease resistance and salt and alkali resistance. Therefore, the soil remediation agent of the present invention is not only suitable for ordinary agricultural land, It is also suitable for a variety of saline-alkali soils, degraded and polluted soil sites, and can improve soil desertification.
  • the soil remediation agent of the present invention can be used for sand control, soil improvement, ecological restoration, agriculture, forestry planting (emphasis on economic crops), urban and rural greening and garden construction, water-saving agriculture, economic forest construction, road and railway roads. Greening, urban and rural organic wastes are harmless and resource-based treatment plays a role.
  • Test Example 1 is a rice grown on soil to which a composite organic fertilizer is applied in Test Example 1;
  • Test Example 2 is a rice grown on soil to which inorganic fertilizer is applied in Test Example 1;
  • Figure 3 is a camellia grown on soil applied with a soil repairing agent in Test Example 2;
  • Figure 4 is a camellia grown on soil applied with inorganic fertilizer in Test Example 2;
  • Figure 5 is a eucalyptus tree grown on soil applied with a soil repairing agent in Test Example 3;
  • Figure 6 is a eucalyptus tree grown on soil applied with inorganic fertilizer in Test Example 3;
  • Figure 7 is a radish harvested on soil applied with a soil repairing agent in Test Example 5;
  • Figure 8 is a radish harvested on soil in which the soil remediation agent was not applied in Test Example 5;
  • Figure 9 is a greenhouse strawberry grown on soil applied with a soil repairing agent in Test Example 6;
  • Figure 10 is a greenhouse strawberry grown on soil applied with inorganic fertilizer in Test Example 6;
  • Figure 11 is a pepper grown on soil to which a soil repairing agent is applied in Test Example 7;
  • Figure 12 is a pepper grown on soil to which inorganic fertilizer is applied in Test Example 7;
  • Fig. 13 is a harvest season of millet on desert soil to which soil soiling agent was applied in Test Example 8.
  • the present invention provides a method for preparing a composite organic fertilizer, which comprises: mixing an organic fertilizer, an aqueous ethanol solution, and an oil for more than one hour, the oil being an edible oil.
  • the aqueous ethanol solution is used in an amount of 0.01 to 10 parts by weight, based on 100 parts by weight of the organic fertilizer, and the oil is used in an amount of 0.01 to 20 parts by weight.
  • aqueous ethanol solution may be various aqueous ethanol solutions, preferably, the concentration of ethanol in the aqueous ethanol solution is 20 to 95% by weight, thereby further improving the composite organic fertilizer and the soil remediation agent. Soil remediation and promotion of plant growth.
  • the organic fertilizer can be various organic fertilizers conventional in the art, commercially available or self-made, and generally obtained by fermentation of organic matter, preferably, the organic matter is organic waste.
  • the cost can be further reduced, wherein the organic waste can be a conventional organic waste, for example, various industrial waste organic substances, various food waste organic substances, various agricultural waste organic substances, and the like, and more specifically, the organic waste. It is at least one of cassava residue, bean dregs, waste oil, distiller's grains, and animal waste.
  • a method for preparing an organic fertilizer by fermentation of an organic substance may include: placing an organic matter heap in a fermentation plant for aerobic fermentation, performing initial temperature measurement, and recording at 20 ° C; 48 hours apart After that, the material pile was tumbling once using a tumbling machine, and the real-time temperature was measured after 6 days and recorded at 30 ° C. Next, after 48 hours, the material pile was tumbling once using a tumbling machine, and the temperature was measured every 24 hours. And recorded, when the temperature reached 60 ° C, the raw material pile was tumbled once a day with a tumbling machine, and maintained at a temperature of 60 ° C for 15 days after aerobic fermentation to form an organic fertilizer.
  • the edible oil may be various edible oils, for example, may be vegetable oil and/or animal oil.
  • the edible oil when the edible oil is a mixture of vegetable oil and animal oil, the ratio of the two is not particularly limited.
  • the specific types of the vegetable oil and the animal oil do not cause differences in the properties of the obtained composite organic fertilizer.
  • Types of vegetable oils include, but are not limited to, soybean oil, peanut oil, corn oil, sunflower oil, tea seed oil, rapeseed oil, and mixtures thereof.
  • the contacting is carried out in a closed environment for a contact time of 2 to 10 hours, thereby facilitating the preparation of the composite organic fertilizer.
  • the present invention also provides a composite organic fertilizer prepared by the above method.
  • the composite organic fertilizer of the present invention can promote the growth of plants, thereby contributing to an increase in plant yield.
  • the present invention provides a soil remediation agent comprising the above composite organic fertilizer and natural crystal powder, wherein the content of the natural crystal powder is 100 parts by weight of the composite organic fertilizer. 0.01-45 parts by weight.
  • the content of the natural crystal powder is 0.1-20 parts by weight relative to 100 parts by weight of the composite organic fertilizer, which can further improve the efficiency of the soil, increase the yield of the soil, and further improve the crops and vegetables. Yield, quality and resistance of vegetables, fruits, etc.
  • the content of the natural crystal powder is 0.1 to 2 parts by weight with respect to 100 parts by weight of the composite organic fertilizer; and the natural crystal is relative to 100 parts by weight of the composite organic fertilizer
  • the content of the powder is 2-4 parts by weight; the content of the natural crystal powder is 4-6 parts by weight relative to 100 parts by weight of the composite organic fertilizer; and the 100 parts by weight of the composite organic fertilizer
  • the content of the natural crystal powder is 6-8 parts by weight; the content of the natural crystal powder is 8-10 parts by weight relative to 100 parts by weight of the composite organic fertilizer; and 100 parts by weight of the composite organic fertilizer
  • the content of the natural crystal powder is 10-12 parts by weight; the content of the natural crystal powder is 12-14 parts by weight relative to 100 parts by weight of the compound organic fertilizer; and the composite organic layer is compared with 100 parts by weight Fertilizer, the content of the natural crystal powder is 14-16 parts by weight; the content of the natural crystal powder is 16-18 parts by weight relative to 100 parts by weight of the compound organic fertilizer; and
  • the soil repairing agent according to the present invention wherein the natural crystal powder may be various natural crystal powders, for example, white crystal, amethyst, smoke crystal (tea crystal), ink crystal, citrine, rose crystal (furong stone), Hair crystal and rainbow crystal.
  • the average crystal grain size of the natural crystal powder is 200-2000 mesh, more preferably 200-1000 mesh.
  • the natural crystal powder may have an average particle diameter of 200-250 mesh, 250-300 mesh, 300-350 mesh, 350-400 mesh, 400-450 mesh, 450-500 mesh, 500-550.
  • the natural crystal powder may be commercially available or may be self-made.
  • the natural crystal may be ground into a powder having the above average particle diameter range using a ball mill.
  • the composite organic fertilizer is the composite organic fertilizer prepared as described above, but in order to further improve the efficiency of the soil, increase the yield of the soil, thereby further increasing the yield and quality of the crops, vegetables, fruits, and the like.
  • the composite organic fertilizer contains at least one of nitrogen, phosphorus, potassium, calcium, magnesium and zinc elements, based on the total weight of the composite organic fertilizer, nitrogen, phosphorus,
  • the total content of potassium, calcium, magnesium and zinc elements is from 5 to 20% by weight, and more preferably, the total content of nitrogen, phosphorus, potassium, calcium, magnesium and zinc elements in the composite organic fertilizer is from 5 to 15% by weight.
  • the respective amounts of the elements of nitrogen, phosphorus, potassium, calcium, magnesium and zinc are not particularly limited as long as the total amount is within the above preferred range.
  • the invention also provides the use of the above soil remediation agent in soil remediation.
  • the dosage can be determined according to actual needs, generally, relative In 1 mu of land, the amount of soil remediation agent is 100-400 kg.
  • the use of the soil remediation agent in the present invention can be applied in the soil, or the soil remediation agent and water can be adjusted into a paste, and the trees of the pests and diseases are applied to the lesions, coated with straw, and made into a rainproof brewing. jobs.
  • the soil remediation agent of the present invention can be applied to various soil types, such as saline soil, desertified soil, etc., to improve soil condition, improve soil efficiency, even in saline-alkali soil and desert soil after improvement by soil remediation agent.
  • the growth state of the plants is better than that of the plants on the undegraded soil, thus enhancing the availability of saline soil and desert soil.
  • the present invention also provides a method of planting a plant using the above soil restorative agent or the above composite organic fertilizer.
  • the planting method of the invention can be used for planting various plants, for example, can promote the growth of trees, vegetables, flowers and food crops, and increase various resistances of plants such as disease resistance, drought resistance, mites resistance, sand resistance and salt and alkali resistance. Sex.
  • the soil remediation agent of the present invention can be applied to the soil before planting the plant, or can be applied to the soil during the planting process of the plant, and the application amount and method are as described above.
  • the composite organic fertilizer can also be separately applied to the soil, and the amount of the composite organic fertilizer can be 100-500 jins relative to 1 mu of land, and the application method of the composite organic fertilizer can be a conventional fertilizer application method, for example, It can be applied in the soil.
  • the preparation process of organic fertilizer is as follows: the cassava residue, the bean dregs and the waste oil are put into the fermentation workshop according to the weight ratio of 1:1:1, and the aerobic fermentation is carried out, and the initial temperature measurement is performed, and the temperature is recorded as 20 ° C; after 48 hours, the tumbling is adopted.
  • the machine rolls over the raw material pile once, and measures it after 6 days and records the real-time temperature at 30 ° C. Next, every 48 hours, the material pile is tumbling once using a tumbling machine, and every 24 hours, the temperature is measured and recorded. After the temperature reached 60 ° C, the raw material pile was tumbled once a day with a tumbling machine, and maintained at a temperature of 60 ° C for 15 days after aerobic fermentation to form an organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 0.01 g of an aqueous ethanol solution (concentration of ethanol: 20% by weight) and 0.01 g of soybean oil were mixed and contacted in a closed environment for 2 hours to prepare a composite organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer and 1 g of aqueous ethanol solution (the concentration of ethanol is 25 wt%) was mixed with 1 g of lard and exposed to a closed environment for 2.5 hours to prepare a composite organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 2 g of an aqueous ethanol solution (concentration of ethanol: 30% by weight) and 3 g of edible oil (the ratio of soybean oil to lard are 1:1) are mixed in a closed environment. After contact for 3 hours, a composite organic fertilizer was prepared.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 6 g of an aqueous ethanol solution (concentration of ethanol: 50% by weight) and 11 g of peanut oil were mixed and exposed to a closed environment for 5 hours to prepare a composite organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 7 g of an aqueous ethanol solution (concentration of ethanol: 55 wt%) and 13 g of rapeseed oil were mixed and exposed to a closed environment for 5.5 hours to prepare a composite organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 8 g of an aqueous ethanol solution (concentration of ethanol of 60% by weight) and 15 g of tea seed oil were mixed and contacted in a closed environment for 6 hours to prepare a composite organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 9 g of an aqueous ethanol solution (concentration of ethanol: 65 wt%) and 17 g of lard were mixed and exposed to a 6.5 hour in a closed environment to prepare a composite organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 70% by weight) and 19 g of sunflower oil were mixed and contacted in a closed environment for 7 hours to prepare a composite organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 75% by weight) and 20 g of tallow were mixed and exposed in a closed environment for 7.5 hours to prepare a composite organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 80% by weight) and 20 g of soybean oil were mixed and contacted in a closed environment for 8 hours to prepare a composite organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 85% by weight) and 20 g of soybean oil were mixed and exposed to a closed environment for 9 hours to prepare a composite organic fertilizer.
  • Preparation of Compound Organic Fertilizer 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 90% by weight) and 20 g of soybean oil were mixed and exposed in a closed environment for 9.5 hours to prepare a composite organic fertilizer.
  • Preparation of compound organic fertilizer 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 95% by weight) and 20 g of soybean oil were mixed and contacted in a closed environment for 10 hours to prepare a composite organic fertilizer.
  • the composite organic fertilizer was prepared according to the method of Preparation Example 1, except that the amount of the aqueous ethanol solution was 12 g and the amount of the rapeseed oil was 22 g with respect to 100 g of the organic fertilizer, and a composite organic fertilizer was obtained.
  • a composite organic fertilizer was prepared according to the method of Preparation Example 1, except that the concentration of ethanol in the aqueous ethanol solution was 18% by weight to prepare a composite organic fertilizer.
  • a composite organic fertilizer was prepared according to the method of Preparation Example 1, except that the concentration of ethanol in the aqueous ethanol solution was 97% by weight to prepare a composite organic fertilizer.
  • the composite organic fertilizer was prepared according to the method of Preparation Example 1, except that the contact was not carried out in a closed environment, and the contact time was 1.5 hours to prepare a composite organic fertilizer.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • the content of each element in the composite organic fertilizer prepared in Preparation Example 1 was measured by ICP-MS (inductively coupled plasma mass spectrometer), and nitrogen, phosphorus, potassium, calcium,
  • the content of the magnesium element and the zinc element are each 1% by weight, 1% by weight, 1% by weight, 0.5% by weight, 0.5% by weight, and 1% by weight, that is, the total content is 5% by weight;
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • each element in the composite organic fertilizer prepared in Preparation Example 2 was determined by ICP-MS (inductively coupled plasma mass spectrometer), and nitrogen, phosphorus, potassium, calcium and Containing magnesium The amount is 2% by weight, 2% by weight, 2% by weight, 1% by weight, 1% by weight, that is, the total content is 8% by weight;
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • the content of each element in the composite organic fertilizer prepared in Preparation Example 3 was measured by ICP-MS (inductively coupled plasma mass spectrometer), and the nitrogen, phosphorus, calcium and zinc elements in the composite organic fertilizer were measured.
  • the content is each 3% by weight, 3% by weight, 2% by weight, and 2% by weight, that is, the total content is 10% by weight;
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, potassium element, calcium element, magnesium element and zinc element) prepared in Preparation Example 4 was 2% by weight each. , 5% by weight, 2% by weight, 3% by weight, 2% by weight, 1% by weight, that is, 15% by weight total) and the natural crystal powder obtained by the step (2) (average particle diameter of 350 mesh) by weight Mixing with 1:0.06 to prepare a soil remediation agent.
  • the content of the compound organic fertilizer nitrogen element, phosphorus element, potassium element, calcium element, magnesium element and zinc element
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, potassium element, calcium element and magnesium element) prepared in Preparation Example 5 was 4% by weight and 2 parts each. %, 2% by weight, 1% by weight, 1% by weight, that is, the total content is 10% by weight), and the natural crystal powder (average particle diameter of 400 mesh) obtained in the step (2) is mixed at a weight ratio of 1:0.08. Get soil repair agent.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, calcium element and zinc element) prepared in Preparation Example 6 was 5% by weight, 5% by weight, and 3, respectively.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, calcium element, and magnesium element) prepared in Preparation Example 7 was 5% by weight, 5% by weight, and 3, respectively.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the nitrogen compound, phosphorus element and calcium element prepared in Preparation Example 8 was 4% by weight, 4% by weight, and 2% by weight, respectively. That is, the total content of 10% by weight) and the natural crystal powder (average particle diameter of 550 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.14 to prepare a soil repairing agent.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the nitrogen compound, phosphorus element and magnesium element prepared in Preparation Example 9 was 4% by weight, 4% by weight, and 2% by weight, respectively. That is, the total content of 10% by weight) and the natural crystal powder (average particle diameter of 600 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.16 to prepare a soil repairing agent.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the nitrogen compound, the phosphorus element, and the zinc element prepared in Preparation Example 10 was 4% by weight, 4% by weight, and 2% by weight, respectively. That is, the total content is 10
  • the natural crystal powder (average particle diameter of 650 mesh) obtained by the step (2) was mixed at a weight ratio of 1:0.18 to prepare a soil repairing agent.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, potassium element, calcium element, magnesium element and zinc element) prepared in Preparation Example 11 was 5% by weight each. , 5 wt%, 5% by weight, 2 wt%, 2 wt%, 1 wt%, i.e., a total content of 20 wt%) and the natural crystal powder obtained by the step (2) (average particle diameter of 700 mesh) by weight Mixing with 1:0.2 to prepare a soil remediation agent.
  • the compound organic fertilizer nitrogen element, phosphorus element, potassium element, calcium element, magnesium element and zinc element
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, potassium element, calcium element and magnesium element) prepared in Preparation Example 12 was 7 wt% and 5 wt%, respectively. %, 5% by weight, 2% by weight, 1% by weight, that is, a total content of 20% by weight) and the natural crystal powder (average particle diameter of 750 mesh) obtained in the step (2) are mixed at a weight ratio of 1:0.2. Get soil repair agent.
  • the content of the compound organic fertilizer nitrogen element, phosphorus element, potassium element, calcium element and magnesium element
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, calcium element and zinc element) prepared in Preparation Example 13 was 10% by weight, 5% by weight, and 3, respectively.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the composite organic fertilizer (nitrogen element, phosphorus element, potassium element, calcium element, magnesium element and zinc element) prepared in Preparation Example 14 was 5% by weight each. 2% by weight, 2% by weight, 3% by weight, 2% by weight, 1% by weight, that is, 15% by weight total) and the natural crystal powder obtained by the step (2) (average particle diameter of 850 mesh) by weight Mixing with 1:0.2 to prepare a soil remediation agent.
  • the content of the composite organic fertilizer nitrogen element, phosphorus element, potassium element, calcium element, magnesium element and zinc element
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, calcium element and zinc element) prepared in Preparation Example 15 was 5% by weight, 5% by weight, and 2, respectively.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, calcium element and magnesium element) prepared in Preparation Example 16 was 5% by weight, 5% by weight, and 2, respectively.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the nitrogen compound, the phosphorus element, and the calcium element prepared in Preparation Example 17 was 4% by weight, 2% by weight, and 4% by weight, respectively. That is, the total content of 10% by weight) and the natural crystal powder (average particle diameter of 1000 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.2 to prepare a soil repairing agent.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1, except that the content of the nitrogen compound, phosphorus element and magnesium element prepared in Preparation Example 18 was 4% by weight, 2% by weight, and 4% by weight, respectively. That is, the total content of 10% by weight) and the natural crystal powder (average particle diameter of 1500 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.2 to prepare a soil repairing agent.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1 except that the natural crystal powder had an average particle diameter of 150 mesh to prepare a soil remediation agent.
  • This example is intended to illustrate the soil restorative agent of the present invention.
  • a soil remediation agent was prepared in the same manner as in Example 1 except that the weight ratio of the composite organic fertilizer to the natural crystal powder was 1:0.3.
  • the agricultural land is divided into two parts.
  • the two parts are planted separately.
  • 200 kg of compound organic fertilizer prepared in Example 1 is applied per acre, and the other part is applied with the same amount of inorganic fertilizer, and the two parts are experimentally used.
  • the other management measures of rice were the same.
  • the results of applying compound organic fertilizer are shown in Figure 1.
  • the results of applying inorganic fertilizer are shown in Figure 2.
  • the agricultural land planted with Camellia is divided into two parts. On one part of the soil, 100 kg of the soil remediation agent prepared in Example 1 is applied per acre, and the other part is applied with the same amount of inorganic fertilizer, and the two parts of the experimental land are used in the mountain tea. The other management measures were the same. After 21 days of experimentation, the growth status of two rice fields in the rice field was recorded. The results of applying the soil remediation agent are shown in Fig. 3. The results of applying inorganic fertilizer are shown in Fig. 4.
  • the normal agricultural land planted with eucalyptus is divided into two parts.
  • the eucalyptus trees in the two parts are of the same age and healthy in growth state.
  • 200 kg of soil remediation agent prepared in Example 1 is applied per acre.
  • no soil remediation agent was applied, and the same amount of inorganic fertilizer was applied.
  • the other management measures of the eucalyptus in the two parts of the experiment were the same.
  • the growth status of the two eucalyptus trees was recorded, and the results of applying the repair agent were recorded. See Figure 5, the results of no application of repair agent are shown in Figure 6.
  • the degraded agricultural soil was divided into 21 experimental fields, and 200 kg of the soil remediation agent prepared in Examples 1-20 and 200 kg of the composite organic fertilizer prepared in Preparation Example 1 were applied to each test field to degenerate.
  • Agricultural soil The soil is modified, and then the edible chrysanthemum is planted on the modified soil and the unmodified soil (without applying the soil remediation agent, or applying the composite organic fertilizer of the preparation example, and applying the same amount of commercially available inorganic fertilizer).
  • the fresh chrysanthemum was collected by PONY to determine the content of selenium in the petals of fresh chrysanthemum. The results are shown in Table 1.
  • the rice to which the composite organic fertilizer of the present invention is applied is thicker and the root system is more developed than the seedling of the rice to which the inorganic fertilizer is applied.
  • the rice to which the composite organic fertilizer of the present invention is applied has higher yield, lower heavy metal content, and the heavy metal residue of rice is as low as almost zero. Therefore, the rice planted by the composite organic fertilizer of the present invention is compounded by the national green standard.
  • the camellia to which the soil remediation agent of the present invention is applied grows faster, the leaves are more full, and the yield is higher than that of the application of the inorganic fertilizer, especially the yield before the clearing can be increased by three times.
  • the radish harvested on the soil after application of the soil remediation agent has a larger head, wherein the larger radish has a body length of 46 cm, a diameter of 15 cm, a weight of 5.2 kg, and the harvested radish tastes extremely Ok, returning to the natural taste, the yield is also high.
  • the composite organic fertilizer of the invention can significantly increase the yield of the plant, and the soil repairing agent of the invention can provide a perfect and harmonious rhizosphere environment for the plants, especially the plants in the adversity, by coordinating the relationship between water and nutrition. Promote rapid growth of plants, increase crop yield and fruit quality, and enhance plant resistance, such as drought resistance, cold resistance, disease resistance and salt and alkali resistance. Therefore, the soil remediation agent of the present invention is not only suitable for ordinary agricultural land, It is also suitable for a variety of saline-alkali soils, degraded and polluted soil sites, and can improve soil desertification.
  • the soil remediation agent of the present invention can be used for sand control, soil improvement, ecological restoration, agriculture, forestry planting (emphasis on economic crops), urban and rural greening and garden construction, water-saving agriculture, economic forest construction, road and railway roads. Greening, urban and rural organic wastes are harmless and resource-based treatment plays a role.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
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  • General Life Sciences & Earth Sciences (AREA)
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Abstract

A compound organic fertilizer and preparation method thereof, a soil restoration agent and application thereof, and a plant planting method. The preparation method of preparing the compound organic fertilizer comprises: mixing an organic fertilizer, an ethanol aqueous solution, and an oil, and leaving the mixture to stand for longer than one hour, wherein the oil is a cooking oil. The soil restoration agent comprises the compound organic fertilizer and natural crystal powder, wherein content of the natural crystal powder is 0.01 to 45 parts in weight for every 100 parts in weight of the compound organic fertilizer. The soil restoration agent can facilitate fast growth of plants, increase production and quality of fruits, and enhance plant tolerance such as drought tolerance, cold tolerance, disease resistance, and salt and alkaline tolerance, and is applicable to not only normal farmlands but also various saline and alkali lands, degraded and polluted lands, reducing land desertification.

Description

一种复合有机肥及其制备方法和土壤修复剂及其应用和一种植物的种植方法Composite organic fertilizer, preparation method thereof, soil repairing agent and application thereof and planting method of plant 技术领域Technical field
本发明涉及一种复合有机肥的制备方法,以及该方法制备的复合有机肥,一种含有上述复合有机肥的土壤修复剂,以及该土壤修复剂在土壤修复中的应用,和一种植物的种植方法。The invention relates to a preparation method of a composite organic fertilizer, a composite organic fertilizer prepared by the method, a soil repairing agent containing the above composite organic fertilizer, and the application of the soil repairing agent in soil remediation, and a plant Planting method.
背景技术Background technique
目前,我国农业用地大面积地退化、板结和重金属化,土壤的退化、板结和重金属化是肥料使用跌更演变的结果。At present, China's agricultural land is extensively degraded, compacted and heavily metallized. Soil degradation, compaction and heavy metallization are the result of a more evolutionary use of fertilizer.
最早使用的是有机肥。有机肥的使用在我国有着较为悠久的历史,农民有句谚语:庄稼一支花,全靠粪当家。农耕最重要的一环就是积肥。数千年来,农民基本上靠土杂肥耕种,现在市场有机肥一般分为农家肥、绿肥和腐殖酸肥三类,其特点为:养分种类多,浓度低,释放慢,但只能做基底肥。The earliest used organic fertilizer. The use of organic fertilizer has a long history in China. Farmers have a proverb: a crop of flowers, all relying on feces. The most important part of farming is the accumulation of fertilizer. For thousands of years, farmers have basically relied on soil and fertilizer to cultivate. Nowadays, organic fertilizers in the market are generally divided into three categories: farmyard manure, green manure and humic acid fertilizer. The characteristics are: many nutrients, low concentration, slow release, but only Make base fertilizer.
其次是化肥(也叫无机肥料)。第二次世界大战结束后,为了适应世界人口的迅速增长,增施化肥成为农业增产的有力措施。我国是1963年开始大规模使用的,化肥一般根据其有效成分划分为氮肥、磷肥、钾肥、复合肥、复混肥和微量元素肥几大类。其特点为:浓度高,释放快。Followed by fertilizer (also known as inorganic fertilizer). After the end of the Second World War, in order to adapt to the rapid growth of the world population, the application of chemical fertilizers has become a powerful measure to increase agricultural production. China began to use it on a large scale in 1963. Fertilizers are generally classified into nitrogen fertilizers, phosphate fertilizers, potash fertilizers, compound fertilizers, compound fertilizers and trace element fertilizers according to their active ingredients. Its characteristics are: high concentration and fast release.
再者是微生物肥,农业部于1996年开始将微生物肥纳入肥料登记范畴,规定微生物肥必须在农业部进行检查登记,它是细菌肥料,是活的生物体,是通过细菌强大的分解、还原活动发挥作用的。我国的微生物肥研究了10多年,做过很多实验,取得了不错的成果。其中一种叫紫云英的实验数据显示,施用微生物肥后第一年增产60%—100%;第二年增产20%—60%;第三年增产15%—40%;第四年增产10%。微生物肥种类一般可分为:微生物拌种剂,各类根瘤菌肥;复合微生物肥;其中,复合微生物肥含有细菌肥(根瘤菌肥、固氮、解磷、解钾肥)、放线菌肥(抗生肥料)、真菌类肥(菌根真菌、霉菌肥料、酵母肥料)和光合细菌肥等。其特点为初期使用,作物健壮;可达高产。In addition, it is microbial fertilizer. The Ministry of Agriculture began to include microbial fertilizer in the fertilizer registration category in 1996. It is stipulated that microbial fertilizer must be inspected and registered in the Ministry of Agriculture. It is a bacterial fertilizer, a living organism, and a powerful decomposition and reduction by bacteria. Activities play a role. China's microbial fertilizer research has been carried out for more than 10 years, and many experiments have been done, and good results have been achieved. One of the experimental data, namely, Ziyunying, shows that the first year after the application of microbial fertilizer, the yield will increase by 60%-100%; the second year will increase the yield by 20%-60%; the third year will increase the yield by 15%-40%; the fourth year will increase the yield. 10%. Microbial fertilizer types can be generally divided into: microbial seed dressing agents, various rhizobial fertilizers; compound microbial fertilizers; among them, compound microbial fertilizers contain bacterial fertilizers (rhizobial fertilizer, nitrogen fixation, phosphorus dissolving, potassium dissolving), actinomycetes ( Antibiotics), fungal fertilizers (mycorrhizal fungi, mold fertilizers, yeast fertilizers) and photosynthetic bacteria fertilizers. It is characterized by initial use, robust crops, and high yields.
然而,上述三种肥料的长期施用对土壤退化、板结和重金属化产生了重大影响。首先,近年来,由于人们在对动物养殖的饲料中,使用了各种饲料添加剂,各种抗生素, 造成了动物粪便的不安全。而大田作物均以有机肥作基底肥。其结果则造成了土壤的严重污染和退化,给人们的健康带来了威胁。其次,由于化肥养分单一,使用后,造成土壤各类养分比例失调;农田生态环境遭到破坏;土壤理化性状严重恶化。化肥对农产品的污染最引人注目的是蔬菜和水果,主要表现为:在作物吸收了氮肥后形成硝酸盐,进一步转化成亚硝酸盐,高量的亚硝酸盐是导致癌症的罪魁祸首。此外,随着农业工作者们近年来对土壤超量使用化肥,其结果则造成了土壤的严重污染、板结和退化。第三,微生物复合肥又称全肥,前几年用微生物复合肥效果特别好,因为它是活性外来物种,会把土地原有物种破坏甚至消灭,然而,三至五年以后,土地渐渐就不长作物了,造成了土地效力的渐失。However, the long-term application of the above three fertilizers has a major impact on soil degradation, compaction and heavy metallization. First of all, in recent years, people have used various feed additives and various antibiotics in the feed for animal breeding. Caused the insecurity of animal droppings. The field crops use organic fertilizer as the base fertilizer. As a result, the soil is seriously polluted and degraded, posing a threat to people's health. Secondly, due to the single nutrient nutrient, after use, the soil nutrient ratio is imbalanced; the farmland ecological environment is destroyed; the soil physical and chemical properties are seriously deteriorated. The most striking effects of chemical fertilizers on agricultural products are vegetables and fruits. The main manifestations are: the formation of nitrates after the crops have absorbed nitrogen fertilizer, and further conversion into nitrite. High amounts of nitrite are the main culprit in cancer. In addition, as agricultural workers over-exploit fertilizers in the soil in recent years, the result is severe soil contamination, compaction and degradation. Third, microbial compound fertilizer is also called whole fertilizer. The effect of microbial compound fertilizer in the past few years is particularly good, because it is an active alien species, which will destroy or even destroy the original species of the land. However, after three to five years, the land gradually Not long crops, resulting in the loss of land effectiveness.
因此,面对我国农业用地大面积的性能退化、板结化、重金属化等现状,急需一种能够修复现有退化土壤的修复剂。Therefore, in the face of the large-scale performance degradation, slab formation and heavy metallization of agricultural land in China, there is an urgent need for a repairing agent capable of repairing existing degraded soil.
发明内容Summary of the invention
本发明的目的是为了提供一种复合有机肥的制备方法,及该方法制备的复合有机肥,一种能够较好地修复土壤的土壤修复剂,以及该土壤修复剂在土壤修复中的应用,和一种植物的种植方法,以提高土壤的效力,增加土壤的产出,进而提高作物、蔬菜、水果等的产量、品质和抗性等。The object of the present invention is to provide a preparation method of a composite organic fertilizer, a composite organic fertilizer prepared by the method, a soil remediation agent capable of better repairing soil, and application of the soil remediation agent in soil remediation, And a planting method to increase the effectiveness of the soil, increase the yield of the soil, and thereby increase the yield, quality and resistance of crops, vegetables, fruits, and the like.
本发明的发明人在研究中发现,一种复合有机肥的制备方法,该方法包括:将有机肥、乙醇水溶液和油混合,接触1小时以上,所述油为食用油,该复合有机肥能够显著提高植物的产量。另外,含有该复合有机肥和天然水晶粉的土壤修复剂,能够提高土壤的效力,增加土壤的产出,进而提高作物、蔬菜、水果等的产量、品质和抗性。The inventors of the present invention found in the research, a method for preparing a composite organic fertilizer, the method comprising: mixing an organic fertilizer, an aqueous ethanol solution and an oil for more than one hour, the oil being an edible oil, the composite organic fertilizer capable of Significantly increase plant yields. In addition, the soil remediation agent containing the composite organic fertilizer and the natural crystal powder can improve the soil efficiency, increase the soil output, and thereby improve the yield, quality and resistance of crops, vegetables, fruits and the like.
因此,为了实现上述目的,一方面,本发明提供了一种复合有机肥的制备方法,该方法包括:将有机肥、乙醇水溶液和油混合,接触1小时以上,所述油为食用油。Therefore, in order to achieve the above object, in one aspect, the present invention provides a method for preparing a composite organic fertilizer, which comprises: mixing an organic fertilizer, an aqueous ethanol solution and an oil for more than 1 hour, the oil being an edible oil.
第二方面,本发明还提供了上述方法制得的复合有机肥。In a second aspect, the present invention also provides a composite organic fertilizer prepared by the above method.
第三方面,本发明还提供了一种土壤修复剂,该土壤修复剂含有上述复合有机肥和天然水晶粉,相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为0.01-45重量份。In a third aspect, the present invention provides a soil remediation agent comprising the above composite organic fertilizer and natural crystal powder, wherein the content of the natural crystal powder is 0.01 with respect to 100 parts by weight of the composite organic fertilizer. - 45 parts by weight.
第四方面,本发明还提供了上述土壤修复剂在土壤修复中的应用。In a fourth aspect, the invention also provides the use of the above soil remediation agent in soil remediation.
第五方面,本发明还提供了一种植物的种植方法,该方法中使用上述的土壤修复剂或者使用上述的复合有机肥。 In a fifth aspect, the present invention also provides a method of planting a plant in which the above soil resturant is used or the above composite organic fertilizer is used.
本发明的复合有机肥能够显著提高植物的产量,并且本发明的土壤修复剂可以通过协调水分和营养的关系,能够为植物特别是逆境中的植物提供一个完善的、和谐的根际环境,可以促进植物的快速生长,提高作物的产量和果实品质,增强植物的抗性,例如抗旱、抗寒、抗病和耐盐碱性,因此,本发明的土壤修复剂不仅适用于普通的农业用地,还适用于各种盐碱地、退化和污染的土壤用地,以及可以改善土壤的沙漠化。总之,本发明的土壤修复剂可以在防沙治沙、土壤改良、生态恢复、农业、林业种植(偏重于经济作物)、城乡绿化和园林建设、节水农业、经济林建设、公路和铁路路域绿化、城乡有机废弃物无害化和资源化处理等方面发挥作用。The composite organic fertilizer of the invention can significantly increase the yield of the plant, and the soil repairing agent of the invention can provide a perfect and harmonious rhizosphere environment for the plants, especially the plants in the adversity, by coordinating the relationship between water and nutrition. Promote rapid growth of plants, increase crop yield and fruit quality, and enhance plant resistance, such as drought resistance, cold resistance, disease resistance and salt and alkali resistance. Therefore, the soil remediation agent of the present invention is not only suitable for ordinary agricultural land, It is also suitable for a variety of saline-alkali soils, degraded and polluted soil sites, and can improve soil desertification. In summary, the soil remediation agent of the present invention can be used for sand control, soil improvement, ecological restoration, agriculture, forestry planting (emphasis on economic crops), urban and rural greening and garden construction, water-saving agriculture, economic forest construction, road and railway roads. Greening, urban and rural organic wastes are harmless and resource-based treatment plays a role.
本发明的其它特征和优点将在随后的具体实施方式部分予以详细说明。Other features and advantages of the invention will be described in detail in the detailed description which follows.
附图说明DRAWINGS
图1是测试例1中施用复合有机肥的土壤上生长的水稻;1 is a rice grown on soil to which a composite organic fertilizer is applied in Test Example 1;
图2是测试例1中施用无机肥的土壤上生长的水稻;2 is a rice grown on soil to which inorganic fertilizer is applied in Test Example 1;
图3是测试例2中施用土壤修复剂的土壤上生长的山茶;Figure 3 is a camellia grown on soil applied with a soil repairing agent in Test Example 2;
图4是测试例2中施用无机肥的土壤上生长的山茶;Figure 4 is a camellia grown on soil applied with inorganic fertilizer in Test Example 2;
图5是测试例3中施用土壤修复剂的土壤上生长的桉树;Figure 5 is a eucalyptus tree grown on soil applied with a soil repairing agent in Test Example 3;
图6是测试例3中施用无机肥的土壤上生长的桉树;Figure 6 is a eucalyptus tree grown on soil applied with inorganic fertilizer in Test Example 3;
图7是测试例5中施用土壤修复剂的土壤上收获的萝卜;Figure 7 is a radish harvested on soil applied with a soil repairing agent in Test Example 5;
图8是测试例5中未施用土壤修复剂的土壤上收获的萝卜;Figure 8 is a radish harvested on soil in which the soil remediation agent was not applied in Test Example 5;
图9是测试例6中施用土壤修复剂的土壤上生长的大棚草莓;Figure 9 is a greenhouse strawberry grown on soil applied with a soil repairing agent in Test Example 6;
图10是测试例6中施用无机肥的土壤上生长的大棚草莓;Figure 10 is a greenhouse strawberry grown on soil applied with inorganic fertilizer in Test Example 6;
图11是测试例7中施用土壤修复剂的土壤上生长的胡椒;Figure 11 is a pepper grown on soil to which a soil repairing agent is applied in Test Example 7;
图12是测试例7中施用无机肥的土壤上生长的胡椒;Figure 12 is a pepper grown on soil to which inorganic fertilizer is applied in Test Example 7;
图13是测试例8中施用土壤修复剂的沙漠土壤上收获季的谷子。Fig. 13 is a harvest season of millet on desert soil to which soil soiling agent was applied in Test Example 8.
具体实施方式detailed description
以下对本发明的具体实施方式进行详细说明。应当理解的是,此处所描述的具体实施方式仅用于说明和解释本发明,并不用于限制本发明。Specific embodiments of the present invention will be described in detail below. It is to be understood that the specific embodiments described herein are merely illustrative and not restrictive.
一方面,本发明提供了一种复合有机肥的制备方法,该方法包括:将有机肥、乙醇水溶液和油混合,接触1小时以上,所述油为食用油。 In one aspect, the present invention provides a method for preparing a composite organic fertilizer, which comprises: mixing an organic fertilizer, an aqueous ethanol solution, and an oil for more than one hour, the oil being an edible oil.
优选地,相对于100重量份的所述有机肥,所述乙醇水溶液的用量为0.01-10重量份,所述油的用量为0.01-20重量份。Preferably, the aqueous ethanol solution is used in an amount of 0.01 to 10 parts by weight, based on 100 parts by weight of the organic fertilizer, and the oil is used in an amount of 0.01 to 20 parts by weight.
根据本发明所述的制备方法,其中,乙醇水溶液可以为各种乙醇水溶液,优选地,所述乙醇水溶液中乙醇的浓度为20-95重量%,从而能够进一步提高复合有机肥和土壤修复剂对土壤的修复作用,以及对植物生长的促进作用等。The preparation method according to the present invention, wherein the aqueous ethanol solution may be various aqueous ethanol solutions, preferably, the concentration of ethanol in the aqueous ethanol solution is 20 to 95% by weight, thereby further improving the composite organic fertilizer and the soil remediation agent. Soil remediation and promotion of plant growth.
根据本发明所述的制备方法,其中,有机肥可以为本领域常规的各种有机肥,可以商购也可以自制,其一般由有机质经发酵制得,优选地,所述有机质为有机废弃物,能够进一步节省成本,其中,有机废弃物可以为常规的有机废物物,例如可以为各种工业垃圾有机质、各种食品垃圾有机质、各种农业垃圾有机质等,更具体地,所述有机废弃物为木薯渣、豆渣、地沟油、酒糟、和动物粪便中的至少一种。The preparation method according to the present invention, wherein the organic fertilizer can be various organic fertilizers conventional in the art, commercially available or self-made, and generally obtained by fermentation of organic matter, preferably, the organic matter is organic waste. Further, the cost can be further reduced, wherein the organic waste can be a conventional organic waste, for example, various industrial waste organic substances, various food waste organic substances, various agricultural waste organic substances, and the like, and more specifically, the organic waste. It is at least one of cassava residue, bean dregs, waste oil, distiller's grains, and animal waste.
本发明中,由有机质经发酵制得有机肥的方法为本领域技术人员公知,例如可以包括:将有机质堆放入发酵车间进行有氧发酵,进行初始温度测量,记录为20℃;隔48小时后,采用翻滚机对原料堆翻滚1次,并且6天后测量且记录实时温度为30℃,接下来,隔48小时,采用翻滚机对原料堆翻滚1次,且每隔24小时,测量一次温度并记录,当温度达到60℃后,每天用翻滚机对原料堆翻滚1次,并维持60℃的温度进行有氧发酵15天后,形成有机肥。In the present invention, a method for preparing an organic fertilizer by fermentation of an organic substance is known to those skilled in the art, and for example, may include: placing an organic matter heap in a fermentation plant for aerobic fermentation, performing initial temperature measurement, and recording at 20 ° C; 48 hours apart After that, the material pile was tumbling once using a tumbling machine, and the real-time temperature was measured after 6 days and recorded at 30 ° C. Next, after 48 hours, the material pile was tumbling once using a tumbling machine, and the temperature was measured every 24 hours. And recorded, when the temperature reached 60 ° C, the raw material pile was tumbled once a day with a tumbling machine, and maintained at a temperature of 60 ° C for 15 days after aerobic fermentation to form an organic fertilizer.
根据本发明所述的制备方法,其中,所述食用油可以为各种食用油,例如可以为植物油和/或动物油。其中,当食用油为植物油和动物油的混合物时,对两者的比例没有特别的限定,本发明中,植物油和动物油的具体种类的不同并不会导致制得的复合有机肥的性质具有差异。植物油的种类包括但不限于大豆油、花生油、玉米油、葵花籽油、茶籽油、菜籽油、以及它们的混合物。The preparation method according to the present invention, wherein the edible oil may be various edible oils, for example, may be vegetable oil and/or animal oil. Among them, when the edible oil is a mixture of vegetable oil and animal oil, the ratio of the two is not particularly limited. In the present invention, the specific types of the vegetable oil and the animal oil do not cause differences in the properties of the obtained composite organic fertilizer. Types of vegetable oils include, but are not limited to, soybean oil, peanut oil, corn oil, sunflower oil, tea seed oil, rapeseed oil, and mixtures thereof.
根据本发明所述的制备方法,其中,优选地,所述接触在密闭环境中进行,接触的时间为2-10小时,从而更有利于复合有机肥的制备。According to the production method of the present invention, preferably, the contacting is carried out in a closed environment for a contact time of 2 to 10 hours, thereby facilitating the preparation of the composite organic fertilizer.
另一方面,本发明还提供了上述方法制备的复合有机肥。In another aspect, the present invention also provides a composite organic fertilizer prepared by the above method.
本发明的复合有机肥能够促进植物的生长,从而有助于提高植物的产量。The composite organic fertilizer of the present invention can promote the growth of plants, thereby contributing to an increase in plant yield.
第三方面,本发明还提供了一种土壤修复剂,该土壤修复剂含有上述的复合有机肥和天然水晶粉,相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为0.01-45重量份。In a third aspect, the present invention provides a soil remediation agent comprising the above composite organic fertilizer and natural crystal powder, wherein the content of the natural crystal powder is 100 parts by weight of the composite organic fertilizer. 0.01-45 parts by weight.
优选地,相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为0.1-20重量份,这样能够进一步提高土壤的效力,增加土壤的产出,进而进一步提高作物、蔬 菜、水果等的产量、品质和抗性等。Preferably, the content of the natural crystal powder is 0.1-20 parts by weight relative to 100 parts by weight of the composite organic fertilizer, which can further improve the efficiency of the soil, increase the yield of the soil, and further improve the crops and vegetables. Yield, quality and resistance of vegetables, fruits, etc.
本发明中,更具体地,相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为0.1-2重量份;相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为2-4重量份;相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为4-6重量份;相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为6-8重量份;相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为8-10重量份;相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为10-12重量份;相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为12-14重量份;相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为14-16重量份;相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为16-18重量份;相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为18-20重量份。In the present invention, more specifically, the content of the natural crystal powder is 0.1 to 2 parts by weight with respect to 100 parts by weight of the composite organic fertilizer; and the natural crystal is relative to 100 parts by weight of the composite organic fertilizer The content of the powder is 2-4 parts by weight; the content of the natural crystal powder is 4-6 parts by weight relative to 100 parts by weight of the composite organic fertilizer; and the 100 parts by weight of the composite organic fertilizer The content of the natural crystal powder is 6-8 parts by weight; the content of the natural crystal powder is 8-10 parts by weight relative to 100 parts by weight of the composite organic fertilizer; and 100 parts by weight of the composite organic fertilizer, The content of the natural crystal powder is 10-12 parts by weight; the content of the natural crystal powder is 12-14 parts by weight relative to 100 parts by weight of the compound organic fertilizer; and the composite organic layer is compared with 100 parts by weight Fertilizer, the content of the natural crystal powder is 14-16 parts by weight; the content of the natural crystal powder is 16-18 parts by weight relative to 100 parts by weight of the compound organic fertilizer; and 100 parts by weight relative to 100 parts by weight Composite organic fertilizer, the content of the natural crystal powder is 18-20 parts by weight .
根据本发明的土壤修复剂,其中,天然水晶粉可以为各种天然水晶粉,例如,可以为白水晶、紫晶、烟水晶(茶晶)、墨晶、黄水晶、蔷薇水晶(芙蓉石)、发晶和彩虹水晶等。为了进一步提高土壤的效力,增加土壤的产出,进而进一步提高作物、蔬菜、水果等的产量、品质和抗性等,优选地,天然水晶粉的平均粒径为200-2000目,更优选为200-1000目。The soil repairing agent according to the present invention, wherein the natural crystal powder may be various natural crystal powders, for example, white crystal, amethyst, smoke crystal (tea crystal), ink crystal, citrine, rose crystal (furong stone), Hair crystal and rainbow crystal. In order to further increase the efficiency of the soil, increase the yield of the soil, and further increase the yield, quality, resistance, and the like of crops, vegetables, fruits, etc., preferably, the average crystal grain size of the natural crystal powder is 200-2000 mesh, more preferably 200-1000 mesh.
本发明中,更具体地,天然水晶粉的平均粒径可以为200-250目、250-300目、300-350目、350-400目、400-450目、450-500目、500-550目、550-600目、600-650目、650-700目、700-750目、750-800目、800-850目、850-900目、900-950目、950-1000目。In the present invention, more specifically, the natural crystal powder may have an average particle diameter of 200-250 mesh, 250-300 mesh, 300-350 mesh, 350-400 mesh, 400-450 mesh, 450-500 mesh, 500-550. Mesh, 550-600 mesh, 600-650 mesh, 650-700 mesh, 700-750 mesh, 750-800 mesh, 800-850 mesh, 850-900 mesh, 900-950 mesh, 950-1000 mesh.
本发明中,天然水晶粉可以商购也可以自制,当自制时,可以使用球磨机将天然水晶研磨成具有上述平均粒径范围的粉末。In the present invention, the natural crystal powder may be commercially available or may be self-made. When self-made, the natural crystal may be ground into a powder having the above average particle diameter range using a ball mill.
根据本发明的土壤修复剂,其中,复合有机肥为上述制得的复合有机肥,但是,为了进一步提高土壤的效力,增加土壤的产出,进而进一步提高作物、蔬菜、水果等的产量、品质和抗性等,优选地,复合有机肥含有氮、磷、钾、钙、镁和锌元素中的至少一种,以所述复合有机肥的总重量为基准,复合有机肥中氮、磷、钾、钙、镁和锌元素的总含量为5-20重量%,更优选地,所述复合有机肥中氮、磷、钾、钙、镁和锌元素的总含量为5-15重量%。其中,对氮、磷、钾、钙、镁和锌元素各自的量没有特别的限定,只要总量在上述优选的范围内即可。The soil remediation agent according to the present invention, wherein the composite organic fertilizer is the composite organic fertilizer prepared as described above, but in order to further improve the efficiency of the soil, increase the yield of the soil, thereby further increasing the yield and quality of the crops, vegetables, fruits, and the like. And resistance, etc., preferably, the composite organic fertilizer contains at least one of nitrogen, phosphorus, potassium, calcium, magnesium and zinc elements, based on the total weight of the composite organic fertilizer, nitrogen, phosphorus, The total content of potassium, calcium, magnesium and zinc elements is from 5 to 20% by weight, and more preferably, the total content of nitrogen, phosphorus, potassium, calcium, magnesium and zinc elements in the composite organic fertilizer is from 5 to 15% by weight. Here, the respective amounts of the elements of nitrogen, phosphorus, potassium, calcium, magnesium and zinc are not particularly limited as long as the total amount is within the above preferred range.
第三方面,本发明还提供了上述土壤修复剂在土壤修复中的应用。In a third aspect, the invention also provides the use of the above soil remediation agent in soil remediation.
对于本发明的土壤修复剂的施用,可以根据实际需要来确定用量,一般地,相对 于1亩地,土壤修复剂的用量为100-400斤。For the application of the soil remediation agent of the present invention, the dosage can be determined according to actual needs, generally, relative In 1 mu of land, the amount of soil remediation agent is 100-400 kg.
对本发明中土壤修复剂的使用可以拌在土壤中施用,也可以将该土壤修复剂和水调成糊状,对病虫害的树木进行病灶处涂抹,涂抹后用稻草包裹,做好防雨冲泡工作。The use of the soil remediation agent in the present invention can be applied in the soil, or the soil remediation agent and water can be adjusted into a paste, and the trees of the pests and diseases are applied to the lesions, coated with straw, and made into a rainproof brewing. jobs.
本发明的土壤修复剂可以适用于各种土壤类型,例如盐碱土壤、沙漠化土壤等,以改善土壤状况,提高土壤效力,甚至在经土壤修复剂改良后的盐碱土壤和沙漠土壤上的植物的生长状态比普通未退化的土壤上植物的的生长状态还要好,因此,增强了盐碱土壤和沙漠土壤的可利用性。The soil remediation agent of the present invention can be applied to various soil types, such as saline soil, desertified soil, etc., to improve soil condition, improve soil efficiency, even in saline-alkali soil and desert soil after improvement by soil remediation agent. The growth state of the plants is better than that of the plants on the undegraded soil, thus enhancing the availability of saline soil and desert soil.
第四方面,本发明还提供了一种植物的种植方法,该方法使用上述的土壤修复剂或者上述的复合有机肥。In a fourth aspect, the present invention also provides a method of planting a plant using the above soil restorative agent or the above composite organic fertilizer.
本发明的种植方法可以用于各种植物的种植,例如可以促进树木、蔬菜、花卉和粮食作物等的生长,增加植物的抗病、抗旱、抗涝、抗沙化和耐盐碱等各种抗性。The planting method of the invention can be used for planting various plants, for example, can promote the growth of trees, vegetables, flowers and food crops, and increase various resistances of plants such as disease resistance, drought resistance, mites resistance, sand resistance and salt and alkali resistance. Sex.
本发明的土壤修复剂可以在种植植物前施用于土壤,也可以在植物的种植过程施用于土壤,其施用用量和方法如上所述。The soil remediation agent of the present invention can be applied to the soil before planting the plant, or can be applied to the soil during the planting process of the plant, and the application amount and method are as described above.
本发明中,还可以单独施用复合有机肥于土壤中,相对于1亩地,复合有机肥的用量可以为100-500斤,复合有机肥的施用方法可以为常规的肥料的施用方法,例如也可以拌在土壤中施用。In the present invention, the composite organic fertilizer can also be separately applied to the soil, and the amount of the composite organic fertilizer can be 100-500 jins relative to 1 mu of land, and the application method of the composite organic fertilizer can be a conventional fertilizer application method, for example, It can be applied in the soil.
实施例Example
有机肥的制备过程为:将木薯渣、豆渣、地沟油按照重量比1:1:1堆放入发酵车间进行有氧发酵,进行初始温度测量,记录为20℃;隔48小时后,采用翻滚机对原料堆翻滚1次,并且6天后测量且记录实时温度为30℃,接下来,隔48小时,采用翻滚机对原料堆翻滚1次,且每隔24小时,测量一次温度并记录,当温度达到60℃后,每天用翻滚机对原料堆翻滚1次,并维持60℃的温度进行有氧发酵15天后,形成有机肥。The preparation process of organic fertilizer is as follows: the cassava residue, the bean dregs and the waste oil are put into the fermentation workshop according to the weight ratio of 1:1:1, and the aerobic fermentation is carried out, and the initial temperature measurement is performed, and the temperature is recorded as 20 ° C; after 48 hours, the tumbling is adopted. The machine rolls over the raw material pile once, and measures it after 6 days and records the real-time temperature at 30 ° C. Next, every 48 hours, the material pile is tumbling once using a tumbling machine, and every 24 hours, the temperature is measured and recorded. After the temperature reached 60 ° C, the raw material pile was tumbled once a day with a tumbling machine, and maintained at a temperature of 60 ° C for 15 days after aerobic fermentation to form an organic fertilizer.
制备例1Preparation Example 1
复合有机肥的制备:将100g上述制得的有机肥、0.01g乙醇水溶液(乙醇的浓度为20重量%)和0.01g大豆油混合,在密闭环境中接触2小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 0.01 g of an aqueous ethanol solution (concentration of ethanol: 20% by weight) and 0.01 g of soybean oil were mixed and contacted in a closed environment for 2 hours to prepare a composite organic fertilizer.
制备例2Preparation Example 2
复合有机肥的制备:将100g上述制得的有机肥、1g乙醇水溶液(乙醇的浓度为 25重量%)和1g猪油混合,在密闭环境中接触2.5小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer and 1 g of aqueous ethanol solution (the concentration of ethanol is 25 wt%) was mixed with 1 g of lard and exposed to a closed environment for 2.5 hours to prepare a composite organic fertilizer.
制备例3Preparation Example 3
复合有机肥的制备:将100g上述制得的有机肥、2g乙醇水溶液(乙醇的浓度为30重量%)和3g食用油(大豆油和猪油的比例为1:1)混合,在密闭环境中接触3小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 2 g of an aqueous ethanol solution (concentration of ethanol: 30% by weight) and 3 g of edible oil (the ratio of soybean oil to lard are 1:1) are mixed in a closed environment. After contact for 3 hours, a composite organic fertilizer was prepared.
制备例4Preparation Example 4
复合有机肥的制备:将100g上述制得的有机肥、3g乙醇水溶液(乙醇的浓度为35重量%)和5g食用油(大豆油和猪油的比例为1:4)混合,在密闭环境中接触3.5小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 3 g of an aqueous ethanol solution (concentration of ethanol: 35 wt%) and 5 g of edible oil (the ratio of soybean oil and lard are 1:4) are mixed in a closed environment. After contacting for 3.5 hours, a composite organic fertilizer was obtained.
制备例5Preparation Example 5
复合有机肥的制备:将100g上述制得的有机肥、4g乙醇水溶液(乙醇的浓度为40重量%)和7g食用油(花生油和猪油的比例为2:1)混合,在密闭环境中接触4小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 4 g of an aqueous ethanol solution (concentration of ethanol: 40% by weight) and 7 g of edible oil (ratio of peanut oil and lard are 2:1) are mixed and contacted in a closed environment. 4 hours, a compound organic fertilizer was obtained.
制备例6Preparation Example 6
复合有机肥的制备:将100g上述制得的有机肥、5g乙醇水溶液(乙醇的浓度为45重量%)和9g食用油(花生油和猪油的比例为4:1)混合,在密闭环境中接触4.5小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 5 g of an aqueous ethanol solution (concentration of ethanol: 45% by weight) and 9 g of edible oil (the ratio of peanut oil to lard are 4:1) are mixed and contacted in a closed environment. 4.5 hours, a composite organic fertilizer was prepared.
制备例7Preparation Example 7
复合有机肥的制备:将100g上述制得的有机肥、6g乙醇水溶液(乙醇的浓度为50重量%)和11g花生油混合,在密闭环境中接触5小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 6 g of an aqueous ethanol solution (concentration of ethanol: 50% by weight) and 11 g of peanut oil were mixed and exposed to a closed environment for 5 hours to prepare a composite organic fertilizer.
制备例8Preparation Example 8
复合有机肥的制备:将100g上述制得的有机肥、7g乙醇水溶液(乙醇的浓度为55重量%)和13g菜籽油混合,在密闭环境中接触5.5小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 7 g of an aqueous ethanol solution (concentration of ethanol: 55 wt%) and 13 g of rapeseed oil were mixed and exposed to a closed environment for 5.5 hours to prepare a composite organic fertilizer.
制备例9 Preparation Example 9
复合有机肥的制备:将100g上述制得的有机肥、8g乙醇水溶液(乙醇的浓度为60重量%)和15g茶籽油混合,在密闭环境中接触6小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 8 g of an aqueous ethanol solution (concentration of ethanol of 60% by weight) and 15 g of tea seed oil were mixed and contacted in a closed environment for 6 hours to prepare a composite organic fertilizer.
制备例10Preparation Example 10
复合有机肥的制备:将100g上述制得的有机肥、9g乙醇水溶液(乙醇的浓度为65重量%)和17g猪油混合,在密闭环境中接触6.5小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 9 g of an aqueous ethanol solution (concentration of ethanol: 65 wt%) and 17 g of lard were mixed and exposed to a 6.5 hour in a closed environment to prepare a composite organic fertilizer.
制备例11Preparation Example 11
复合有机肥的制备:将100g上述制得的有机肥、10g乙醇水溶液(乙醇的浓度为70重量%)和19g葵花籽油混合,在密闭环境中接触7小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 70% by weight) and 19 g of sunflower oil were mixed and contacted in a closed environment for 7 hours to prepare a composite organic fertilizer.
制备例12Preparation Example 12
复合有机肥的制备:将100g上述制得的有机肥、10g乙醇水溶液(乙醇的浓度为75重量%)和20g牛油混合,在密闭环境中接触7.5小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 75% by weight) and 20 g of tallow were mixed and exposed in a closed environment for 7.5 hours to prepare a composite organic fertilizer.
制备例13Preparation Example 13
复合有机肥的制备:将100g上述制得的有机肥、10g乙醇水溶液(乙醇的浓度为80重量%)和20g大豆油混合,在密闭环境中接触8小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 80% by weight) and 20 g of soybean oil were mixed and contacted in a closed environment for 8 hours to prepare a composite organic fertilizer.
制备例14Preparation Example 14
复合有机肥的制备:将100g上述制得的有机肥、10g乙醇水溶液(乙醇的浓度为85重量%)和20g大豆油混合,在密闭环境中接触9小时,制得复合有机肥。Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 85% by weight) and 20 g of soybean oil were mixed and exposed to a closed environment for 9 hours to prepare a composite organic fertilizer.
制备例15Preparation Example 15
复合有机肥的制备:将100g上述制得的有机肥、10g乙醇水溶液(乙醇的浓度为90重量%)和20g大豆油混合,在密闭环境中接触9.5小时,制得复合有机肥。Preparation of Compound Organic Fertilizer: 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 90% by weight) and 20 g of soybean oil were mixed and exposed in a closed environment for 9.5 hours to prepare a composite organic fertilizer.
制备例16Preparation Example 16
复合有机肥的制备:将100g上述制得的有机肥、10g乙醇水溶液(乙醇的浓度为95重量%)和20g大豆油混合,在密闭环境中接触10小时,制得复合有机肥。 Preparation of compound organic fertilizer: 100 g of the above-prepared organic fertilizer, 10 g of an aqueous ethanol solution (concentration of ethanol: 95% by weight) and 20 g of soybean oil were mixed and contacted in a closed environment for 10 hours to prepare a composite organic fertilizer.
制备例17Preparation Example 17
按照制备例1的方法制备复合有机肥,不同的是,相对于100g的有机肥,乙醇水溶液的用量为12g,菜籽油的用量为22g,制得复合有机肥。The composite organic fertilizer was prepared according to the method of Preparation Example 1, except that the amount of the aqueous ethanol solution was 12 g and the amount of the rapeseed oil was 22 g with respect to 100 g of the organic fertilizer, and a composite organic fertilizer was obtained.
制备例18Preparation Example 18
按照制备例1的方法制备复合有机肥,不同的是,乙醇水溶液中乙醇的浓度为18重量%,制得复合有机肥。A composite organic fertilizer was prepared according to the method of Preparation Example 1, except that the concentration of ethanol in the aqueous ethanol solution was 18% by weight to prepare a composite organic fertilizer.
制备例19Preparation Example 19
按照制备例1的方法制备复合有机肥,不同的是,乙醇水溶液中乙醇的浓度为97重量%,制得复合有机肥。A composite organic fertilizer was prepared according to the method of Preparation Example 1, except that the concentration of ethanol in the aqueous ethanol solution was 97% by weight to prepare a composite organic fertilizer.
制备例20Preparation Example 20
按照制备例1的方法制备复合有机肥,不同的是,接触不在密闭环境中进行,且接触的时间为1.5小时,制得复合有机肥。The composite organic fertilizer was prepared according to the method of Preparation Example 1, except that the contact was not carried out in a closed environment, and the contact time was 1.5 hours to prepare a composite organic fertilizer.
实施例1Example 1
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
(1)采用ICP-MS(电感耦合等离子体质谱仪)测定制备例1制得的复合有机肥中各元素的含量,测得该复合有机肥中氮元素、磷元素、钾元素、钙元素、镁元素和锌元素的含量各为1重量%、1重量%、1重量%、0.5重量%、0.5重量%、1重量%,即总含量为5重量%;(1) The content of each element in the composite organic fertilizer prepared in Preparation Example 1 was measured by ICP-MS (inductively coupled plasma mass spectrometer), and nitrogen, phosphorus, potassium, calcium, The content of the magnesium element and the zinc element are each 1% by weight, 1% by weight, 1% by weight, 0.5% by weight, 0.5% by weight, and 1% by weight, that is, the total content is 5% by weight;
(2)使用球磨机将天然水晶研磨成平均粒径为200目的天然水晶粉;(2) grinding the natural crystal into a natural crystal powder having an average particle diameter of 200 mesh using a ball mill;
(3)将制备例1制得的复合有机肥和步骤(2)制得的天然水晶粉按照重量比1:0.001混合,制得土壤修复剂。(3) The composite organic fertilizer prepared in Preparation Example 1 and the natural crystal powder obtained in the step (2) were mixed at a weight ratio of 1:0.001 to prepare a soil resturant.
实施例2Example 2
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
(1)采用ICP-MS(电感耦合等离子体质谱仪)测定制备例2制得的复合有机肥中各元素的含量,测得该复合有机肥中氮元素、磷元素、钾元素、钙元素和镁元素的含 量各为2重量%、2重量%、2重量%、1重量%、1重量%,即总含量为8重量%;(1) The content of each element in the composite organic fertilizer prepared in Preparation Example 2 was determined by ICP-MS (inductively coupled plasma mass spectrometer), and nitrogen, phosphorus, potassium, calcium and Containing magnesium The amount is 2% by weight, 2% by weight, 2% by weight, 1% by weight, 1% by weight, that is, the total content is 8% by weight;
(2)使用球磨机将天然水晶研磨成平均粒径为250目的天然水晶粉;(2) grinding the natural crystal into a natural crystal powder having an average particle diameter of 250 mesh using a ball mill;
(3)将制备例2制得的复合有机肥和步骤(2)制得的天然水晶粉按照重量比1:0.02混合,制得土壤修复剂。(3) The composite organic fertilizer prepared in Preparation Example 2 and the natural crystal powder obtained in the step (2) were mixed at a weight ratio of 1:0.02 to prepare a soil repairing agent.
实施例3Example 3
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
(1)采用ICP-MS(电感耦合等离子体质谱仪)测定制备例3制得的复合有机肥中各元素的含量,测得该复合有机肥中氮元素、磷元素、钙元素和锌元素的含量各为3重量%、3重量%、2重量%、2重量%,即总含量为10重量%;(1) The content of each element in the composite organic fertilizer prepared in Preparation Example 3 was measured by ICP-MS (inductively coupled plasma mass spectrometer), and the nitrogen, phosphorus, calcium and zinc elements in the composite organic fertilizer were measured. The content is each 3% by weight, 3% by weight, 2% by weight, and 2% by weight, that is, the total content is 10% by weight;
(2)使用球磨机将天然水晶研磨成平均粒径为300目的天然水晶粉;(2) grinding the natural crystal into a natural crystal powder having an average particle diameter of 300 mesh using a ball mill;
(3)将制备例3制得的复合有机肥和步骤(2)制得的天然水晶粉按照重量比1:0.04混合,制得土壤修复剂。(3) The composite organic fertilizer prepared in Preparation Example 3 and the natural crystal powder obtained in the step (2) were mixed at a weight ratio of 1:0.04 to prepare a soil repairing agent.
实施例4Example 4
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例4制得的复合有机肥(氮元素、磷元素、钾元素、钙元素、镁元素和锌元素的含量各为2重量%、5重量%、2重量%、3重量%、2重量%、1重量%,即总含量为15重量%)和步骤(2)制得的天然水晶粉(平均粒径为350目)按照重量比1:0.06混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, potassium element, calcium element, magnesium element and zinc element) prepared in Preparation Example 4 was 2% by weight each. , 5% by weight, 2% by weight, 3% by weight, 2% by weight, 1% by weight, that is, 15% by weight total) and the natural crystal powder obtained by the step (2) (average particle diameter of 350 mesh) by weight Mixing with 1:0.06 to prepare a soil remediation agent.
实施例5Example 5
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例5制得的复合有机肥(氮元素、磷元素、钾元素、钙元素和镁元素的含量各为4重量%、2重量%、2重量%、1重量%、1重量%,即总含量为10重量%)和步骤(2)制得的天然水晶粉(平均粒径为400目)按照重量比1:0.08混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, potassium element, calcium element and magnesium element) prepared in Preparation Example 5 was 4% by weight and 2 parts each. %, 2% by weight, 1% by weight, 1% by weight, that is, the total content is 10% by weight), and the natural crystal powder (average particle diameter of 400 mesh) obtained in the step (2) is mixed at a weight ratio of 1:0.08. Get soil repair agent.
实施例6Example 6
本实施例用于说明本发明的土壤修复剂。 This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例6制得的复合有机肥(氮元素、磷元素、钙元素和锌元素的含量各为5重量%、5重量%、3重量%、2重量%,即总含量为15重量%)和步骤(2)制得的天然水晶粉(平均粒径为450目)按照重量比1:0.1混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, calcium element and zinc element) prepared in Preparation Example 6 was 5% by weight, 5% by weight, and 3, respectively. The weight %, 2% by weight, i.e., the total content of 15% by weight) and the natural crystal powder (average particle diameter of 450 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.1 to prepare a soil resturant.
实施例7Example 7
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例7制得的复合有机肥(氮元素、磷元素、钙元素和镁元素的含量各为5重量%、5重量%、3重量%、2重量%,即总含量为15重量%)和步骤(2)制得的天然水晶粉(平均粒径为500目)按照重量比1:0.12混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, calcium element, and magnesium element) prepared in Preparation Example 7 was 5% by weight, 5% by weight, and 3, respectively. The weight %, 2% by weight, that is, the total content of 15% by weight) and the natural crystal powder (average particle diameter of 500 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.12 to prepare a soil resturant.
实施例8Example 8
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例8制得的复合有机肥(氮元素、磷元素和钙元素的含量各为4重量%、4重量%、2重量%,即总含量为10重量%)和步骤(2)制得的天然水晶粉(平均粒径为550目)按照重量比1:0.14混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the nitrogen compound, phosphorus element and calcium element prepared in Preparation Example 8 was 4% by weight, 4% by weight, and 2% by weight, respectively. That is, the total content of 10% by weight) and the natural crystal powder (average particle diameter of 550 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.14 to prepare a soil repairing agent.
实施例9Example 9
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例9制得的复合有机肥(氮元素、磷元素和镁元素的含量各为4重量%、4重量%、2重量%,即总含量为10重量%)和步骤(2)制得的天然水晶粉(平均粒径为600目)按照重量比1:0.16混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the nitrogen compound, phosphorus element and magnesium element prepared in Preparation Example 9 was 4% by weight, 4% by weight, and 2% by weight, respectively. That is, the total content of 10% by weight) and the natural crystal powder (average particle diameter of 600 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.16 to prepare a soil repairing agent.
实施例10Example 10
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例10制得的复合有机肥(氮元素、磷元素和锌元素的含量各为4重量%、4重量%、2重量%,即总含量为10 重量%)和步骤(2)制得的天然水晶粉(平均粒径为650目)按照重量比1:0.18混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the nitrogen compound, the phosphorus element, and the zinc element prepared in Preparation Example 10 was 4% by weight, 4% by weight, and 2% by weight, respectively. That is, the total content is 10 The natural crystal powder (average particle diameter of 650 mesh) obtained by the step (2) was mixed at a weight ratio of 1:0.18 to prepare a soil repairing agent.
实施例11Example 11
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例11制得的复合有机肥(氮元素、磷元素、钾元素、钙元素、镁元素和锌元素的含量各为5重量%、5重量%、5重量%、2重量%、2重量%、1重量%,即总含量为20重量%)和步骤(2)制得的天然水晶粉(平均粒径为700目)按照重量比1:0.2混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, potassium element, calcium element, magnesium element and zinc element) prepared in Preparation Example 11 was 5% by weight each. , 5 wt%, 5% by weight, 2 wt%, 2 wt%, 1 wt%, i.e., a total content of 20 wt%) and the natural crystal powder obtained by the step (2) (average particle diameter of 700 mesh) by weight Mixing with 1:0.2 to prepare a soil remediation agent.
实施例12Example 12
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例12制得的复合有机肥(氮元素、磷元素、钾元素、钙元素和镁元素的含量各为7重量%、5重量%、5重量%、2重量%、1重量%,即总含量为20重量%)和步骤(2)制得的天然水晶粉(平均粒径为750目)按照重量比1:0.2混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, potassium element, calcium element and magnesium element) prepared in Preparation Example 12 was 7 wt% and 5 wt%, respectively. %, 5% by weight, 2% by weight, 1% by weight, that is, a total content of 20% by weight) and the natural crystal powder (average particle diameter of 750 mesh) obtained in the step (2) are mixed at a weight ratio of 1:0.2. Get soil repair agent.
实施例13Example 13
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例13制得的复合有机肥(氮元素、磷元素、钙元素和锌元素的含量各为10重量%、5重量%、3重量%、2重量%,即总含量为20重量%)和步骤(2)制得的天然水晶粉(平均粒径为800目)按照重量比1:0.2混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, calcium element and zinc element) prepared in Preparation Example 13 was 10% by weight, 5% by weight, and 3, respectively. The weight %, 2% by weight, i.e., the total content of 20% by weight) and the natural crystal powder (average particle diameter of 800 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.2 to prepare a soil repairing agent.
实施例14Example 14
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例14制得的复合有机肥(氮元素、磷元素、钾元素、钙元素、镁元素和锌元素的含量各为5重量%、2重量%、2重量%、3重量%、2重量%、1重量%,即总含量为15重量%)和步骤(2)制得的天然水晶粉(平均粒径为850目)按照重量比1:0.2混合,制得土壤修复剂。 A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the composite organic fertilizer (nitrogen element, phosphorus element, potassium element, calcium element, magnesium element and zinc element) prepared in Preparation Example 14 was 5% by weight each. 2% by weight, 2% by weight, 3% by weight, 2% by weight, 1% by weight, that is, 15% by weight total) and the natural crystal powder obtained by the step (2) (average particle diameter of 850 mesh) by weight Mixing with 1:0.2 to prepare a soil remediation agent.
实施例15Example 15
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例15制得的复合有机肥(氮元素、磷元素、钙元素和锌元素的含量各为5重量%、5重量%、2重量%、3重量%,即总含量为15重量%)和步骤(2)制得的天然水晶粉(平均粒径为900目)按照重量比1:0.2混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, calcium element and zinc element) prepared in Preparation Example 15 was 5% by weight, 5% by weight, and 2, respectively. The weight %, 3% by weight, i.e., the total content of 15% by weight) and the natural crystal powder (average particle diameter of 900 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.2 to prepare a soil repairing agent.
实施例16Example 16
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例16制得的复合有机肥(氮元素、磷元素、钙元素和镁元素的含量各为5重量%、5重量%、2重量%、3重量%,即总含量为15重量%)和步骤(2)制得的天然水晶粉(平均粒径为950目)按照重量比1:0.2混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the compound organic fertilizer (nitrogen element, phosphorus element, calcium element and magnesium element) prepared in Preparation Example 16 was 5% by weight, 5% by weight, and 2, respectively. The weight %, 3% by weight, that is, the total content of 15% by weight) and the natural crystal powder (average particle diameter of 950 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.2 to prepare a soil repairing agent.
实施例17Example 17
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例17制得的复合有机肥(氮元素、磷元素和钙元素的含量各为4重量%、2重量%、4重量%,即总含量为10重量%)和步骤(2)制得的天然水晶粉(平均粒径为1000目)按照重量比1:0.2混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the nitrogen compound, the phosphorus element, and the calcium element prepared in Preparation Example 17 was 4% by weight, 2% by weight, and 4% by weight, respectively. That is, the total content of 10% by weight) and the natural crystal powder (average particle diameter of 1000 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.2 to prepare a soil repairing agent.
实施例18Example 18
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,将制备例18制得的复合有机肥(氮元素、磷元素和镁元素的含量各为4重量%、2重量%、4重量%,即总含量为10重量%)和步骤(2)制得的天然水晶粉(平均粒径为1500目)按照重量比1:0.2混合,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1, except that the content of the nitrogen compound, phosphorus element and magnesium element prepared in Preparation Example 18 was 4% by weight, 2% by weight, and 4% by weight, respectively. That is, the total content of 10% by weight) and the natural crystal powder (average particle diameter of 1500 mesh) obtained in the step (2) were mixed at a weight ratio of 1:0.2 to prepare a soil repairing agent.
实施例19Example 19
本实施例用于说明本发明的土壤修复剂。 This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,天然水晶粉的平均粒径为150目,制得土壤修复剂。A soil remediation agent was prepared in the same manner as in Example 1 except that the natural crystal powder had an average particle diameter of 150 mesh to prepare a soil remediation agent.
实施例20Example 20
本实施例用于说明本发明的土壤修复剂。This example is intended to illustrate the soil restorative agent of the present invention.
按照实施例1的方式制备土壤修复剂,不同的是,复合有机肥和天然水晶粉的重量比为1:0.3。A soil remediation agent was prepared in the same manner as in Example 1 except that the weight ratio of the composite organic fertilizer to the natural crystal powder was 1:0.3.
测试例1Test example 1
将一块农业用地分为两个部分,两个部分分别种植水稻,在其中一部分的土壤上每亩施用200斤制备例1制备的复合有机肥,另一部分施用等量的无机肥,两部分实验用地中水稻的其它管理措施均相同,实验进行30天后,记录两部分稻田中水稻的生长状态,施用复合有机肥的结果见图1,施用无机肥的结果见图2。The agricultural land is divided into two parts. The two parts are planted separately. In one part of the soil, 200 kg of compound organic fertilizer prepared in Example 1 is applied per acre, and the other part is applied with the same amount of inorganic fertilizer, and the two parts are experimentally used. The other management measures of rice were the same. After 30 days of experiment, the growth status of rice in two rice fields was recorded. The results of applying compound organic fertilizer are shown in Figure 1. The results of applying inorganic fertilizer are shown in Figure 2.
测试例2Test example 2
将一块种植有山茶的农业用地分为两个部分,在其中一部分的土壤上每亩施用100斤实施例1制备的土壤修复剂,另一部分施用等量的无机肥,两部分实验用地中山茶的其它管理措施均相同,实验进行21天后,记录两块稻田中山茶的生长状态,施用土壤修复剂的结果见图3,施用无机肥的结果见图4。The agricultural land planted with Camellia is divided into two parts. On one part of the soil, 100 kg of the soil remediation agent prepared in Example 1 is applied per acre, and the other part is applied with the same amount of inorganic fertilizer, and the two parts of the experimental land are used in the mountain tea. The other management measures were the same. After 21 days of experimentation, the growth status of two rice fields in the rice field was recorded. The results of applying the soil remediation agent are shown in Fig. 3. The results of applying inorganic fertilizer are shown in Fig. 4.
测试例3Test Example 3
将一块种植有桉树的正常的农业用地分为两个部分,两个部分内桉树的树龄相同、生长状态均健康,在其中一部分的土壤上每亩施用200斤实施例1制备的土壤修复剂,另一部分的土壤上不施用土壤修复剂,而施用等量的无机肥,两部分实验用地中桉树的其它管理措施均相同,实验进行21天后,记录两棵桉树的生长状态,施用修复剂的结果见图5,未施用修复剂的结果见图6。The normal agricultural land planted with eucalyptus is divided into two parts. The eucalyptus trees in the two parts are of the same age and healthy in growth state. On the part of the soil, 200 kg of soil remediation agent prepared in Example 1 is applied per acre. On the other part of the soil, no soil remediation agent was applied, and the same amount of inorganic fertilizer was applied. The other management measures of the eucalyptus in the two parts of the experiment were the same. After 21 days of experiment, the growth status of the two eucalyptus trees was recorded, and the results of applying the repair agent were recorded. See Figure 5, the results of no application of repair agent are shown in Figure 6.
测试例4Test Example 4
将退化的农业土壤划分成21块试验田,分别在每块试验田上,每亩地施用200斤实施例1-20制备的土壤修复剂、200斤制备例1制得的复合有机肥,以将退化的农业土 壤进行改良,然后,分别在改良的土壤上和未改良的土壤(不施用土壤修复剂,也不施用制备例的复合有机肥,而施用等量的商购的无机肥)上种植食用菊花,采集鲜菊花送谱尼测试集团(PONY)测定鲜菊花花瓣中硒元素的含量,结果见表1。The degraded agricultural soil was divided into 21 experimental fields, and 200 kg of the soil remediation agent prepared in Examples 1-20 and 200 kg of the composite organic fertilizer prepared in Preparation Example 1 were applied to each test field to degenerate. Agricultural soil The soil is modified, and then the edible chrysanthemum is planted on the modified soil and the unmodified soil (without applying the soil remediation agent, or applying the composite organic fertilizer of the preparation example, and applying the same amount of commercially available inorganic fertilizer). The fresh chrysanthemum was collected by PONY to determine the content of selenium in the petals of fresh chrysanthemum. The results are shown in Table 1.
同上,按照上述方法种植胡萝卜,同样,将收获的胡萝卜送谱尼测试集团(PONY)测定胡萝卜中硒元素的含量,结果见表1。Same as above, the carrots were planted according to the above method. Similarly, the harvested carrots were sent to the PONY test to determine the content of selenium in the carrots. The results are shown in Table 1.
表1Table 1
Figure PCTCN2016095617-appb-000001
Figure PCTCN2016095617-appb-000001
测试例5Test Example 5
选取一块种植有萝卜幼苗的农业用地,将其分为两个部分,在其中一个部分的土壤上每亩施用300斤实施例1制备的土壤修复剂,即进行土壤改良,另一部分不施用土壤修复剂,而施用等量的无机肥,即不进行土壤改良,然后,记录两部分试验用地上长出的萝卜的状态,改良的土壤上长出的萝卜见图7,未改良的土壤上长出的萝卜见图8。 Select a piece of agricultural land with radish seedlings and divide it into two parts. Apply 300 kg of soil remediation agent prepared in Example 1 per acre to the soil of one part, ie soil improvement, and no soil remediation in the other part. The same amount of inorganic fertilizer was applied, that is, no soil improvement was carried out. Then, the state of the radish grown on the two parts of the test plot was recorded, and the radish grown on the modified soil is shown in Fig. 7, and the unmodified soil grows. The radish is shown in Figure 8.
测试例6Test Example 6
在冬季,选取两个种植草莓的塑料大棚,在其中一个大棚土壤上每亩施用200斤实施例1制备的土壤修复剂,另一个不施用土壤修复剂,而施用等量的无机肥,其它的管理措施均相同,冷害后,分别记录两个草莓大棚的生长状态,施用土壤修复剂的大棚草莓的生长状态见图9,未施用土壤修复剂的大棚草莓的生长状态见图10。In the winter, two plastic greenhouses for growing strawberries were selected, and 200 kg of the soil remediation agent prepared in Example 1 was applied per mu on one of the greenhouse soils, and the other was not applied with the soil remediation agent, but the same amount of inorganic fertilizer was applied, and the other The management measures were the same. After the chilling injury, the growth status of the two strawberry greenhouses was recorded separately. The growth state of the strawberry in the greenhouse using the soil remediation agent is shown in Fig. 9. The growth state of the strawberry in the greenhouse without the soil remediation agent is shown in Fig. 10.
测试例7Test Example 7
选取海南的两块正常状态相似的胡椒种植地,在其中一块地上每亩施用300斤实施例1制备的土壤修复剂,另一个不施用土壤修复剂,而施用等量的无机肥,21天内均不浇水,其它的管理措施均相同,施用土壤修复剂21天后,分别记录两块种植地胡椒的生长状态,施用土壤修复剂的胡椒的生长状态见图11,未施用土壤修复剂的胡椒的生长状态见图12。Two pieces of pepper plantings with similar normal conditions in Hainan were selected. 300 kg of soil remediation agent prepared in Example 1 was applied to one of the grounds, and the other was not applied with soil remediation agent. The same amount of inorganic fertilizer was applied for 21 days. Without watering, the other management measures were the same. After applying the soil remediation agent for 21 days, the growth status of the two planting peppers was recorded separately. The growth state of the pepper to which the soil remediation agent was applied is shown in Fig. 11, and the pepper without the soil remediation agent was applied. The growth state is shown in Figure 12.
测试例8Test Example 8
在山东淄博华山荒漠上选择两块地,在其中一块地上每亩施用300斤实施例1制备的土壤修复剂,另一个不施用土壤修复剂,而施用等量的无机肥,然后种植谷子,并记录谷子的生长状态,施用土壤修复剂的土壤上生长的收获季节谷子的状态如图13所示。Two plots were selected on the Huashan desert in Zibo, Shandong. On one of the plots, 300 kg of soil remediation agent prepared in Example 1 was applied per acre, and the other did not apply soil remediation agent, but an equal amount of inorganic fertilizer was applied, and then the millet was planted. The state of growth of the millet was recorded, and the state of the millet in the harvest season on the soil to which the soil conditioner was applied was as shown in FIG.
通过图1和2比较可以看出,施用本发明复合有机肥的水稻比施用无机肥的水稻的幼苗更粗壮,根系更发达。另外,施用本发明复合有机肥的水稻产量更高,重金属含量更低,水稻的重金属残留低至几乎为零,因此,施用本发明的复合有机肥种植的水稻,复合国家绿色标准。As can be seen from the comparison of Figures 1 and 2, the rice to which the composite organic fertilizer of the present invention is applied is thicker and the root system is more developed than the seedling of the rice to which the inorganic fertilizer is applied. In addition, the rice to which the composite organic fertilizer of the present invention is applied has higher yield, lower heavy metal content, and the heavy metal residue of rice is as low as almost zero. Therefore, the rice planted by the composite organic fertilizer of the present invention is compounded by the national green standard.
通过图3和4比较可以看出,施用本发明土壤修复剂的山茶比施用无机肥的山茶生长更快、叶片更饱满、且产量也更高,尤其是清明前产量可提高3倍。As can be seen from the comparison of Figures 3 and 4, the camellia to which the soil remediation agent of the present invention is applied grows faster, the leaves are more full, and the yield is higher than that of the application of the inorganic fertilizer, especially the yield before the clearing can be increased by three times.
通过图5和6比较可以看出,土壤修复剂种植的桉树其树高、胸径、材积明显高于常规施肥,说明本发明的土壤修复剂能够促进树木的快速生长。It can be seen from the comparison of Figures 5 and 6 that the tree height, the DBH and the volume of the eucalyptus planted by the soil remediation agent are significantly higher than the conventional fertilization, indicating that the soil remediation agent of the present invention can promote the rapid growth of trees.
通过表1的数据可以看出,施用土壤修复剂后种植的食用菊花和胡萝卜中硒元素的含量均高于未使用修复剂的土壤种植的食用菊花和胡萝卜,说明土壤修复剂可以增加改善果实品质。 It can be seen from the data in Table 1 that the content of selenium in edible chrysanthemums and carrots planted after application of soil remediation agent is higher than that of edible chrysanthemums and carrots grown in soil without using remediation agents, indicating that soil remediation agents can improve the quality of fruits. .
通过图7和8比较可以看出,施用土壤修复剂后的土壤上收获的萝卜个头较大,其中较大的萝卜体长为46cm,直径为15cm,重达5.2kg,并且收获的萝卜口感极好,回到本然的味道,产量也较高。As can be seen from the comparison of Figures 7 and 8, the radish harvested on the soil after application of the soil remediation agent has a larger head, wherein the larger radish has a body length of 46 cm, a diameter of 15 cm, a weight of 5.2 kg, and the harvested radish tastes extremely Ok, returning to the natural taste, the yield is also high.
通过图9和10比较可以看出,施用土壤修复剂使得地温提高了2-4℃,作为的长势未受影响,且产量大幅增加,因此,在低温条件下,施用土壤修复剂的大棚草莓明显比未使用土壤修复剂的大棚草莓的更抗冻,因此,说明本发明的土壤修复剂能够显著提高植物的抗寒性。It can be seen from the comparison of Figures 9 and 10 that the application of the soil remediation agent increases the ground temperature by 2-4 ° C, and the growth is unaffected, and the yield is greatly increased. Therefore, in the low temperature condition, the strawberry in the greenhouse is obviously applied with the soil repair agent. It is more resistant to freezing than greenhouse strawberries that do not use soil remediation agents. Therefore, the soil remediation agent of the present invention can significantly improve the cold resistance of plants.
通过图11和12比较可以看出,在干旱条件下,施用土壤修复剂的胡椒明显比未使用土壤修复剂的胡椒的更抗旱,因此,说明本发明的土壤修复剂能够显著提高植物的抗旱性。It can be seen from the comparison of Figures 11 and 12 that under drought conditions, the pepper applied with the soil remediation agent is significantly more drought-resistant than the pepper without the soil remediation agent, thus indicating that the soil remediation agent of the present invention can significantly improve the drought resistance of the plant. .
通过测试例8的结果可以看出,未施用土壤修复剂的土壤上,由于土层只有2-3厘米,土层下均是沙子岩石,因此,根本无法生长谷子。而施用本发明土壤修复剂的土壤上谷子结穗较大,产量较高,证实本发明的土壤修复剂能够改造沙质土壤,这在全世界都是绝无仅有的。As can be seen from the results of Test Example 8, on the soil to which the soil remediation agent was not applied, since the soil layer was only 2-3 cm, and the soil layer was sand rock, the millet could not be grown at all. On the soil to which the soil repairing agent of the present invention is applied, the grain of the millet is large and the yield is high, which proves that the soil repairing agent of the present invention can transform the sandy soil, which is unique in the world.
本发明的复合有机肥能够显著提高植物的产量,并且本发明的土壤修复剂可以通过协调水分和营养的关系,能够为植物特别是逆境中的植物提供一个完善的、和谐的根际环境,可以促进植物的快速生长,提高作物的产量和果实品质,增强植物的抗性,例如抗旱、抗寒、抗病和耐盐碱性,因此,本发明的土壤修复剂不仅适用于普通的农业用地,还适用于各种盐碱地、退化和污染的土壤用地,以及可以改善土壤的沙漠化。总之,本发明的土壤修复剂可以在防沙治沙、土壤改良、生态恢复、农业、林业种植(偏重于经济作物)、城乡绿化和园林建设、节水农业、经济林建设、公路和铁路路域绿化、城乡有机废弃物无害化和资源化处理等方面发挥作用。The composite organic fertilizer of the invention can significantly increase the yield of the plant, and the soil repairing agent of the invention can provide a perfect and harmonious rhizosphere environment for the plants, especially the plants in the adversity, by coordinating the relationship between water and nutrition. Promote rapid growth of plants, increase crop yield and fruit quality, and enhance plant resistance, such as drought resistance, cold resistance, disease resistance and salt and alkali resistance. Therefore, the soil remediation agent of the present invention is not only suitable for ordinary agricultural land, It is also suitable for a variety of saline-alkali soils, degraded and polluted soil sites, and can improve soil desertification. In summary, the soil remediation agent of the present invention can be used for sand control, soil improvement, ecological restoration, agriculture, forestry planting (emphasis on economic crops), urban and rural greening and garden construction, water-saving agriculture, economic forest construction, road and railway roads. Greening, urban and rural organic wastes are harmless and resource-based treatment plays a role.
以上详细描述了本发明的优选实施方式,但是,本发明并不限于上述实施方式中的具体细节,在本发明的技术构思范围内,可以对本发明的技术方案进行多种简单变型,这些简单变型均属于本发明的保护范围。The preferred embodiments of the present invention have been described in detail above, but the present invention is not limited to the specific details of the above embodiments, and various simple modifications can be made to the technical solutions of the present invention within the scope of the technical idea of the present invention. These simple variants All fall within the scope of protection of the present invention.
另外需要说明的是,在上述具体实施方式中所描述的各个具体技术特征,在不矛盾的情况下,可以通过任何合适的方式进行组合,为了避免不必要的重复,本发明对各种可能的组合方式不再另行说明。It should be further noted that the specific technical features described in the above specific embodiments may be combined in any suitable manner without contradiction. To avoid unnecessary repetition, the present invention has various possibilities. The combination method will not be described separately.
此外,本发明的各种不同的实施方式之间也可以进行任意组合,只要其不违背本发明的思想,其同样应当视为本发明所公开的内容。 In addition, any combination of various embodiments of the invention may be made as long as it does not deviate from the idea of the invention, and it should be regarded as the disclosure of the invention.

Claims (11)

  1. 一种复合有机肥的制备方法,其特征在于,该方法包括:将有机肥、乙醇水溶液和油混合,接触1小时以上,所述油为食用油。A method for preparing a composite organic fertilizer, comprising the steps of: mixing an organic fertilizer, an aqueous ethanol solution and an oil for more than one hour, wherein the oil is an edible oil.
  2. 根据权利要求1所述的方法,其中,相对于100重量份的所述有机肥,所述乙醇水溶液的用量为0.01-10重量份,所述油的用量为0.01-20重量份。The method according to claim 1, wherein the aqueous ethanol solution is used in an amount of 0.01 to 10 parts by weight, based on 100 parts by weight of the organic fertilizer, and the oil is used in an amount of 0.01 to 20 parts by weight.
  3. 根据权利要求1或2所述的方法,其中,所述乙醇水溶液中乙醇的浓度为20-95重量%;所述有机肥为有机质经发酵制得的有机肥,The method according to claim 1 or 2, wherein the concentration of ethanol in the aqueous ethanol solution is 20 to 95% by weight; the organic fertilizer is an organic fertilizer obtained by fermentation of an organic substance,
    优选地,所述有机质为有机废弃物,所述有机废弃物为木薯渣、豆渣、地沟油、酒糟、和动物粪便中的至少一种;或者Preferably, the organic matter is organic waste, and the organic waste is at least one of cassava residue, bean dregs, waste oil, vinasse, and animal waste; or
    所述食用油为植物油和/或动物油。The edible oil is a vegetable oil and/or an animal oil.
  4. 根据权利要求1所述的方法,其中,所述接触在密闭环境中进行,接触的时间为2-10小时。The method of claim 1 wherein said contacting is carried out in a closed environment for a period of from 2 to 10 hours.
  5. 权利要求1-4中任意一项所述的方法制备的复合有机肥。A composite organic fertilizer prepared by the method of any of claims 1-4.
  6. 一种土壤修复剂,其特征在于,该土壤修复剂含有权利要求5所述的复合有机肥和天然水晶粉,相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为0.01-45重量份。A soil remediation agent, comprising the composite organic fertilizer according to claim 5 and natural crystal powder, wherein the content of the natural crystal powder is 0.01 with respect to 100 parts by weight of the composite organic fertilizer. - 45 parts by weight.
  7. 根据权利要求6所述的土壤修复剂,其中,相对于100重量份的所述复合有机肥,所述天然水晶粉的含量为0.1-20重量份。The soil remediation agent according to claim 6, wherein the natural crystal powder is contained in an amount of 0.1 to 20 parts by weight based on 100 parts by weight of the composite organic fertilizer.
  8. 根据权利要求6或7所述的土壤修复剂,其中,所述天然水晶粉的平均粒径为200-2000目,优选为200-1000目。The soil remediation agent according to claim 6 or 7, wherein the natural crystal powder has an average particle diameter of 200 to 2000 mesh, preferably 200 to 1000 mesh.
  9. 根据权利要求6所述的土壤修复剂,其中,所述复合有机肥含有氮、磷、钾、钙、镁和锌元素中的至少一种,以所述复合有机肥的总重量为基准,所述复合有机肥中 氮、磷、钾、钙、镁和锌元素的总含量为5-20重量%,优选地,所述复合有机肥中氮、磷、钾、钙、镁和锌元素的总含量为5-15重量%。The soil remediation agent according to claim 6, wherein the composite organic fertilizer contains at least one of nitrogen, phosphorus, potassium, calcium, magnesium and zinc elements, based on the total weight of the composite organic fertilizer. Compound organic fertilizer The total content of nitrogen, phosphorus, potassium, calcium, magnesium and zinc elements is 5-20% by weight, preferably, the total content of nitrogen, phosphorus, potassium, calcium, magnesium and zinc in the composite organic fertilizer is 5-15 weight%.
  10. 权利要求6-9中任意一项所述的土壤修复剂在土壤修复中的应用。Use of the soil remediation agent according to any one of claims 6-9 for soil remediation.
  11. 一种植物的种植方法,其特征在于,该方法使用权利要求6-9中任意一项所述的土壤修复剂或者权利要求5所述的复合有机肥。 A method of planting a plant, characterized in that the method uses the soil remediation agent according to any one of claims 6 to 9 or the composite organic fertilizer according to claim 5.
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