WO2017006541A1 - 閃光放電管および閃光放電管を備える発光装置 - Google Patents
閃光放電管および閃光放電管を備える発光装置 Download PDFInfo
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- WO2017006541A1 WO2017006541A1 PCT/JP2016/003115 JP2016003115W WO2017006541A1 WO 2017006541 A1 WO2017006541 A1 WO 2017006541A1 JP 2016003115 W JP2016003115 W JP 2016003115W WO 2017006541 A1 WO2017006541 A1 WO 2017006541A1
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- alkali
- envelope
- flash discharge
- tube
- glass
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/54—Igniting arrangements, e.g. promoting ionisation for starting
- H01J61/547—Igniting arrangements, e.g. promoting ionisation for starting using an auxiliary electrode outside the vessel
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B15/00—Special procedures for taking photographs; Apparatus therefor
- G03B15/02—Illuminating scene
- G03B15/03—Combinations of cameras with lighting apparatus; Flash units
- G03B15/05—Combinations of cameras with electronic flash apparatus; Electronic flash units
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/30—Vessels; Containers
- H01J61/302—Vessels; Containers characterised by the material of the vessel
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/36—Seals between parts of vessels; Seals for leading-in conductors; Leading-in conductors
- H01J61/366—Seals for leading-in conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/24—Manufacture or joining of vessels, leading-in conductors or bases
- H01J9/245—Manufacture or joining of vessels, leading-in conductors or bases specially adapted for gas discharge tubes or lamps
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/24—Manufacture or joining of vessels, leading-in conductors or bases
- H01J9/26—Sealing together parts of vessels
- H01J9/265—Sealing together parts of vessels specially adapted for gas-discharge tubes or lamps
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/24—Manufacture or joining of vessels, leading-in conductors or bases
- H01J9/32—Sealing leading-in conductors
- H01J9/323—Sealing leading-in conductors into a discharge lamp or a gas-filled discharge device
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B15/00—Special procedures for taking photographs; Apparatus therefor
- G03B15/02—Illuminating scene
- G03B15/03—Combinations of cameras with lighting apparatus; Flash units
- G03B15/04—Combinations of cameras with non-electronic flash apparatus; Non-electronic flash units
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F13/00—Illuminated signs; Luminous advertising
- G09F13/26—Signs formed by electric discharge tubes
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F13/00—Illuminated signs; Luminous advertising
- G09F13/44—Illuminated signs; Luminous advertising with gas as lighting source
Definitions
- the present invention relates to a flash discharge tube that emits light by being excited by a trigger circuit, and a light emitting device that includes the flash discharge tube as a light source load.
- a flash discharge tube configured by sealingly sealing discharge electrodes at both ends of a translucent envelope in a state where xenon gas is sealed inside is well known.
- the flash discharge tube is applied with a high-frequency signal output from the trigger circuit, a so-called trigger signal, via an envelope.
- the flash discharge tube instantaneously emits a large amount of light.
- a light emitting device including the flash discharge tube having the above-described configuration as a light source load is well known.
- the light-emitting device include a strobe device that is an artificial light source for illuminating a subject at the time of taking a picture, and a light-emitting device for advertising for the purpose of catch-up.
- a short interval continuous light emitting operation mode in which a flash discharge tube emits light continuously at short intervals.
- the short interval continuous light emission operation mode is a light emission operation mode in which light emission is repeated at short intervals of 1 second or less, for example.
- the strobe device is a light emission operation mode for confirming in advance an irradiation state at the time of shooting (for example, a shadow generation state).
- the advertising light emitting device has a flashing light emitting operation mode for enhancing the catch-up effect. In recent years, it has been desired to emit light with a greater number of continuous light emission operations in the short interval continuous light emission operation mode.
- the flash discharge tube generates heat with the light emission operation. Therefore, during the continuous light emission operation, heat is accumulated as the number of continuous light emission increases, and the flash discharge tube becomes a high temperature state. This may cause so-called lack of light emission that cannot emit light.
- the flash discharge tube is forcibly provided with a light emission suspension period where light emission is suspended.
- the light emitting device or the like controls the light emitting operation in the continuous light emitting operation mode, and prevents the flash discharge tube from becoming high temperature.
- the trigger signal output may be attenuated as the temperature of the flash discharge tube rises.
- the output waveform of the trigger signal during the continuous light emission operation is a desired high peak vibration waveform during the initial light emission operation.
- this is a phenomenon in which an output waveform whose peak is greatly attenuated is observed.
- the phenomenon of attenuation of the output waveform of the trigger signal means that the ability of the trigger signal to induce and induce electron emission from the cathode and the ability to excite the enclosed xenon gas are reduced.
- the attenuation phenomenon of the output of the trigger signal is considered to be a factor causing the lack of light emission in combination with the above-described action of increasing the sealed pressure of the xenon gas.
- the inventor of the present application believes that the cause of the attenuation of the waveform of the trigger signal is due to the composition of the glass constituting the envelope of the flash discharge tube, as shown below.
- the envelope of the flash discharge tube is generally made of a well-known borosilicate glass, which is a hard glass (tungsten sealing glass) for sealing tungsten having a thermal expansion coefficient similar to that of tungsten. Is done.
- borosilicate glass has a characteristic that the line resistance value decreases as the temperature rises, for example, because the relative dielectric constant and the dielectric loss factor increase.
- the energy of the trigger signal is consumed based on the fluctuation state / situation of the electrical characteristics.
- the volume resistivity of the glass tube itself decreases due to the following factors, and the energy consumption of the trigger signal in the glass tube increases. That is, when viewed from the xenon gas in the glass tube or the emitter impregnated in the cathode, the energy amount of the trigger signal is consumed in the glass tube in a high temperature state. Therefore, the input trigger signal energy is not sufficiently supplied to the xenon gas and the emitter in the glass tube. As a result, the xenon gas is not sufficiently excited, resulting in no light emission. In addition, the lighting voltage of the flash discharge tube increases.
- the inventor of the present application estimates that the variation in the electrical characteristics of the borosilicate glass accompanying the temperature rise is the main factor in the generation of the trigger signal output attenuation phenomenon.
- the inventor of the present application presumes that the cause of the fluctuation in the electrical characteristics is due to the behavior of boron contained in the borosilicate glass tube and the alkali component sodium in the glass tube structure. . That is, for example, borosilicate glass containing sodium as an alkali component increases the mobility of sodium ions in the glass tube structure as the temperature rises. On the other hand, sodium ions also function as conductive carriers. Therefore, the dielectric constant increases as the mobility of sodium ions increases. That is, it is estimated that fluctuations such as the relative dielectric constant cause fluctuations in the electrical characteristics. Further, the alkali component volatilizes from the glass tube at a high temperature, and has various adverse effects on light emission. In addition, the said alkali component means alkali metal components, such as sodium and potassium. The same applies to the following.
- the inventor of the present application confirmed an output attenuation phenomenon when a continuous light emission operation was performed at short intervals in a flash discharge tube employing a quartz tube made of quartz glass as an envelope. At this time, the temperature of the quartz tube rose as in the case of borosilicate glass, but the trigger signal output did not decay.
- Quartz glass does not contain alkali components typified by sodium. That is, even if the temperature rises, quartz glass does not contain the sodium ion component that functions as a conductive carrier. For this reason, the dielectric constant or the like does not greatly increase or decrease. Thereby, since the glass tube does not consume the energy of the trigger signal, it is presumed that the attenuation phenomenon of the output of the trigger signal does not occur. From the above comparison results, the inventor of the present application estimates that alkali components such as sodium ions in the borosilicate glass are the main factors of the trigger signal output attenuation phenomenon.
- a flash discharge tube employing the above quartz tube is mainly made of silicon dioxide. Quartz glass has a small coefficient of thermal expansion, high heat resistance, high heat shock resistance, and high mechanical strength.
- tungsten which is a refractory metal, is usually employed as the electrode pin of the discharge electrode, as in the case of the borosilicate glass tube.
- the thermal expansion coefficient of the quartz tube is about 0.55 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1
- the thermal expansion coefficient of tungsten is 4.4 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 to 4.5 ⁇ 10 ⁇ 6 ⁇ K. -1 . That is, the thermal expansion coefficients of the quartz tube and tungsten are significantly different. For this reason, when the quartz tube and tungsten are directly welded by heating and melting in order to hermetically seal, large distortion occurs in the quartz tube due to the difference in thermal expansion coefficient, and cracks and the like occur.
- a flash discharge tube including an intermediate glass body whose thermal expansion coefficient sequentially changes in the tube axis direction of the quartz tube has been proposed (see, for example, Patent Document 1).
- the intermediate glass body is configured by sequentially arranging a plurality of glass tubes having different thermal expansion coefficients in the tube axis direction.
- the quartz tube and tungsten having different thermal expansion coefficients can be joined.
- the flash discharge tube of Patent Document 1 is prepared in advance with a plurality of intermediate glass bodies having different characteristics of thermal expansion coefficients. Then, an end glass tube formed of borosilicate glass that approximates the thermal expansion coefficient of tungsten of the intermediate glass body and tungsten are first welded.
- an end glass tube mainly composed of silicon dioxide that approximates the thermal expansion coefficient of the quartz tube of the intermediate glass body and the quartz tube are welded.
- the end glass tube and the quartz tube of the intermediate glass body are heated and hermetically sealed.
- the quartz tube and tungsten are indirectly hermetically sealed through the intermediate glass body, thereby forming a flash discharge tube in which cracks and the like are hardly generated.
- a flash discharge tube using an aluminosilicate glass which is a glass for sealing molybdenum, has been conventionally known (for example, see Patent Document 2).
- the aluminosilicate glass does not contain an alkali component or the like that functions as a conductive carrier when the temperature rises, similarly to the quartz glass tube. Therefore, it is estimated that the dielectric constant and the like do not vary greatly.
- Patent Document 2 discloses a tubular valve made of borosilicate glass having a thermal expansion coefficient of about 5.0 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 to 5.5 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1, and a thermal expansion coefficient of about Disclosed is a fluorescent lamp having an electrode pin made of Kovar of about 4.0 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 to 5.5 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 . Note that Patent Document 2 has no suggestion about the above-described attenuation phenomenon accompanying the temperature rise in borosilicate glass, and the constituent materials and the like are merely examples.
- tungsten or molybdenum is disclosed as an example of an electrode pin
- aluminosilicate glass is disclosed as an example of an envelope.
- the linear expansion coefficient thermal expansion coefficient
- lamps and illumination devices using flash discharge tubes are disclosed.
- a light emitting device having a general flash discharge tube generates heat during the light emission operation of the flash discharge tube, and particularly rises to a high temperature state due to accumulation of heat generation during continuous light emission operation at short intervals.
- the trigger signal attenuation phenomenon occurs due to the above.
- a malfunction such as a so-called lack of light emission (non-light emission) occurs in which the flash discharge tube does not emit light.
- the increase in the number of continuous light emission operations is limited. Specifically, for example, after a predetermined number of continuous light emission operations, the light emission operation is controlled by forcibly setting a light emission suspension period as appropriate.
- the flash discharge tube disclosed in Patent Document 1 uses a quartz tube made of quartz glass containing no alkali component as an envelope. As a result, the occurrence of a trigger signal output attenuation phenomenon is prevented, and the number of continuous light emission operations can be significantly increased.
- Patent Document 2 suggests that a well-known aluminosilicate glass is used as an envelope for sealing molybdenum that does not contain an alkali component.
- the suggestion content is merely an example as described above. That is, Patent Document 2 merely discloses a technique in which a molybdenum electrode is simply employed as an electrode when aluminosilicate glass is employed.
- the occurrence of the trigger signal output attenuation phenomenon is prevented and the number of continuous light emission operations can be greatly increased.
- the melting point of molybdenum constituting the electrode pin is about 2600 ° C. Therefore, when it is applied to an electrode of a flash discharge tube using an arc discharge phenomenon in which a large current is instantaneously generated, it is disadvantageous in terms of durability as compared with the case where tungsten having a melting point of about 3400 ° C. is used. .
- the present invention provides a flash discharge tube excellent in durability and capable of realizing a continuous light emission operation at a stable short time interval and a light emitting device including the flash discharge tube.
- the flash discharge tube of the present invention includes a translucent envelope, and an anode and a cathode that are hermetically sealed in a state where xenon gas is sealed inside the envelope at both ends of the envelope.
- a trigger circuit that outputs a trigger signal, and a trigger electrode that is formed on the outer surface of the envelope and to which the trigger signal is applied.
- the pair of discharge electrodes have tungsten pins provided in the envelope so as to face each other.
- the envelope is less than the maximum region surrounding the hermetic space formed by hermetically sealing with the pair of discharge electrodes, and more than the minimum region surrounding the arc discharge space formed between the tungsten pins of the pair of discharge electrodes.
- the central region that is in a high temperature state during the light emission operation is provided as an alkali-free region that is made of alkali-free glass excluding quartz glass and does not contain an alkali component or contains a predetermined amount or less of an alkali component.
- the trigger electrode is disposed in the alkali-free region.
- the envelope moves to a high temperature state by continuous light emission operation at short time intervals through the opposing tungsten pins, the deterioration of the tungsten pins can be prevented. Thereby, generation
- the xenon gas is not sufficiently excited.
- the anode is easily melted due to the increased collision energy of the electrons.
- the cathode is volatilized and precipitated from the borosilicate glass by the high temperature caused by the increased electron collision and xenon ions generated by the short-interval continuous light emission, and ion collision occurs due to the decomposed alkali component ions.
- the corner of the discharge surface of the tungsten pin and the discharge surface of the sintered electrode melt. Furthermore, when the volatiles of the alkali component of borosilicate glass adhere to the electrode, the local part of the tip of the tungsten pin is oxidized and the melting point is lowered. Therefore, the tungsten pin is more easily melted.
- the light emitting device of the present invention includes the flash discharge tube as a light source load.
- a flash discharge tube having excellent durability and capable of increasing the number of continuous light emission operations at short time intervals is used as a light source.
- a light emitting device having excellent durability characteristics against arc discharge phenomena and continuous light emission operation characteristics (repetitive light emission characteristics) at short intervals is provided.
- FIG. 1 is a schematic view showing a flash discharge tube according to an embodiment of the present invention.
- FIG. 2A is a schematic diagram illustrating an example of a manufacturing step of the anode of the flash discharge tube according to the embodiment.
- FIG. 2B is a schematic diagram illustrating an example of a manufacturing step of the anode of the flash discharge tube according to the embodiment.
- FIG. 3A is a schematic diagram illustrating an example of a manufacturing step of the cathode of the flash discharge tube according to the embodiment.
- FIG. 3B is a schematic diagram illustrating an example of a manufacturing step of the cathode of the flash discharge tube according to the embodiment.
- FIG. 4A is a schematic diagram illustrating an example of a manufacturing step of the envelope of the flash discharge tube according to the embodiment.
- FIG. 4B is a schematic diagram illustrating an example of a manufacturing step of the envelope of the flash discharge tube according to the embodiment.
- FIG. 5 is a schematic view showing an example of the manufacturing steps of the flash discharge tube according to the embodiment.
- FIG. 6 is a schematic temperature distribution diagram in the longitudinal direction when the flash discharge tube according to the embodiment emits light continuously for a short interval.
- FIG. 7 is a schematic configuration diagram showing a strobe device which is an example of a light emitting device using a flash discharge tube according to an embodiment of the present invention.
- FIG. 1 is a schematic view showing a flash discharge tube according to an embodiment of the present invention.
- a flash discharge tube 1 of the present embodiment includes an envelope 2 and an anode A and a cathode C that are disposed at both ends of the envelope 2 and constitute a pair of discharge electrodes.
- the inside of the envelope 2 is hermetically sealed through a pair of discharge electrodes composed of an anode A and a cathode C in a state in which the xenon gas 3 is sealed.
- the anode A includes an anode bead 4, a tungsten pin 6 constituting an electrode pin, and an external pin 10.
- the cathode C includes a cathode bead 5, a tungsten pin 7 constituting an electrode pin, a sintered electrode 11, and an external pin 12.
- the xenon gas 3 is enclosed in an airtight space X inside the envelope 2 formed by hermetically sealing a pair of discharge electrodes including an anode A and a cathode C.
- the envelope 2 includes a first envelope portion 8 and a second envelope portion 9.
- the first envelope portion 8 forms a space including an arc discharge space Y between the tungsten pins 6 and 7 of the pair of discharge electrodes constituting the anode A and the cathode C.
- the second envelope part 9 is composed of a bonded glass tube connected to at least one end of the first envelope part 8. In the present embodiment, the second envelope section 9 is illustrated only on the cathode C side.
- the first envelope part 8 is an alkali that does not contain an alkali component except quartz glass, or contains an alkali component of a predetermined amount or less (for example, an alkali metal component is 0.1 wt% or less as an allowable impurity). It is a free glass, for example, composed of an aluminosilicate glass tube. Examples of the aluminosilicate glass tube include Glass 8253 manufactured by SCHOTT. That is, the first envelope part 8 forms an alkali-free region.
- the bonded glass tube of the second envelope part 9 is composed of a borosilicate glass tube designed to contain an alkaline component so that the softening point (for example, a range of about 700 to 830 ° C.) is lowered.
- the borosilicate glass tube for example, Glass 8487 manufactured by SCHOTT having a softening point of 775 ° C. is exemplified.
- the aluminosilicate glass tube itself is a well-known glass tube as described above. That is, the aluminosilicate glass tube contains almost no alkali component.
- aluminum oxide is 16.5 wt%
- silicon dioxide is 16.5 wt%
- alkaline earth metal oxide is 13 wt% calcium oxide
- barium oxide is 8 wt%.
- % Sodium oxide which is an alkali oxide, less than 0.02 wt%, and the like. Further, Glass 8253 is set so that the total content of alkali oxides is less than 0.03 wt%.
- Glass 8253 has a softening point of about 1000 ° C. and a thermal expansion coefficient of 4.7 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 . That is, the softening point of the glass 8253 is higher than about 700 to 830 ° C. of borosilicate glass containing an alkali component.
- the thermal expansion coefficient of glass 8253 is larger than 3.2 to 4.1 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 of borosilicate glass and 0.55 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 of quartz glass.
- the anode A includes the tungsten pin 6 to which the anode bead 4 is welded and the external pin 10 welded to the tungsten pin 6.
- the tungsten pin 6 has an extremely high characteristic with a thermal expansion coefficient of 4.4 to 4.5 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 and a melting point of about 3400 ° C.
- the anode bead 4 is made of a well-known borosilicate glass such as Glass 8487 manufactured by SCHOTT.
- the external pin 10 is formed of, for example, pure nickel or a nickel-based metal such as iron nickel or manganese nickel having a melting point of about 1455 ° C., and constitutes a connection terminal with the outside.
- the external pin 10 is not sealed with the glass of the flash discharge tube and is installed outside the tube, so it is not particularly necessary to match the expansion coefficient on the glass side.
- the anode bead 4 includes a first anode bead 4a and a second anode bead 4b.
- the first anode bead 4 a is disposed by being welded directly to the tungsten pin 6.
- the second anode bead 4b is welded to the outside of the first anode bead 4a.
- the outer diameter of the end face 4bb (see FIG. 5) of the second anode bead 4b is formed to be substantially equal to the same as the outer diameter of the first envelope portion 8 made of an aluminosilicate glass tube.
- it is melt-bonded to the thickness (thickness) portion of the end surface 8a (see FIG. 5) of the first envelope portion 8 via the end surface 4bb.
- the hermetic sealing between the first envelope part 8 and the tungsten pin 6 is indirectly realized.
- the double structure of the anode bead 4 can improve sealing reliability by first sealing the end surface 8a of the aluminosilicate glass tube and the second anode bead 4b. Furthermore, by providing a first anode bead that fits within the aluminosilicate glass tube, the anode A can be easily aligned with the central axis of the aluminosilicate glass tube. Therefore, the above double structure is used. More specifically, when joining glasses having different thermal expansion coefficients, joining in the tube axis direction can increase the reliability with respect to hermetic sealing. Therefore, the end surface 8a of the first envelope part 8 and the end surface 4bb of the second anode bead 4b are intentionally joined in the tube axis direction.
- the first anode bead 4a is provided in order to make it easier to install the tungsten pin 6 at the center in the tube axis direction with respect to the circumferential direction of the inner diameter of the glass tube during the sealing process.
- the anode bead 4 has a double structure.
- the cathode C is composed of the cathode bead 5, the tungsten pin 7, the sintered electrode 11, and the external pin 12 as described above.
- the tungsten pin 7 is disposed with the cathode bead 5 being hermetically welded.
- the sintered electrode 11 is attached to the tip end side (side facing the anode A) of the tungsten pin 7 by, for example, a caulking method.
- the external pin 12 is welded to the tungsten pin 7 and constitutes a connection terminal with the outside.
- the cathode bead 5, the tungsten pin 7 and the external pin 12 constituting the cathode C are also made of borosilicate glass, tungsten, and nickel-based metal, respectively, as with the anode A.
- the side surface portion 5 a of the cathode bead 5 has an outer diameter substantially equal to the inner diameter of the second envelope portion 9. Then, as will be described later, it is melt-bonded to the inner peripheral surface 9c of the second envelope portion 9 via the side surface portion 5a. Thereby, the hermetic sealing between the second envelope part 9 and the tungsten pin 7 is indirectly realized.
- the first envelope unit 8 includes a transparent conductive film 13a and a trigger electrode 13.
- the transparent conductive film 13a is formed along the longitudinal direction of at least the arc discharge space Y, for example, in a region of, for example, about a half circumference on the outer surface excluding the end region of the first envelope portion 8, for example.
- the trigger electrode 13 includes a trigger band 13b wound around one end of the transparent conductive film 13a (for example, the end on the cathode C side), for example, a metal lead wire fixed with conductive paint.
- the flash discharge tube 1 of the present embodiment is configured.
- FIGS. 2A and 2B are schematic views showing an example of manufacturing steps of the anode A.
- FIG. 3A and 3B are schematic views illustrating an example of manufacturing steps of the cathode C.
- FIG. 4A and 4B are schematic diagrams illustrating an example of manufacturing steps of the envelope 2.
- FIG. 5 is a schematic view showing an example of manufacturing steps for manufacturing the flash discharge tube of the present embodiment using the anode A and the cathode C manufactured in the manufacturing steps of FIGS. 2A to 4B.
- an external pin 10 made of a nickel-based metal is welded to a tungsten pin 6 having a thermal expansion coefficient of 4.4 to 4.5 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 .
- an anode bead 4 (a first anode bead 4a and a first anode bead 4a) made of borosilicate glass having a thermal expansion coefficient of 3.2 to 4.1 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 formed in a hollow cylindrical shape on the tungsten pin 6 is formed.
- the second anode bead 4b) is inserted, for example, by moving downward (in the direction of the arrow). Thereafter, as shown in FIG. 2B, the tungsten pin 6 and the anode bead 4 are heated and melt-bonded by a bead heating burner B1. Thereby, the anode A is formed.
- the cathode C first has an external pin 12 made of a nickel-based metal on a tungsten pin 7 having a thermal expansion coefficient of 4.4 to 4.5 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1. Weld. As shown in FIG. 3A, for example, it is preferable to provide a stepped portion larger than the inner diameter of the cathode bead 5 on the welding surface of the external pin 10. Thereby, the position of the cathode bead 5 of the cathode C can be determined easily.
- a cathode bead 5 made of borosilicate glass having a thermal expansion coefficient of 3.2 to 4.1 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 formed in a hollow cylindrical shape is placed on the tungsten pin 7, for example, downward (in the direction of the arrow). ) To insert. After that, as shown in FIG. 3B, the tungsten pin 7 and the cathode bead 5 are heated by a burner B2 for bead heating to be melt-bonded.
- a sintered electrode 11 obtained by sintering a powder of a high melting point metal such as tantalum, niobium, zirconium, nickel is attached to the vicinity of the tip of the tungsten pin 7 by using, for example, a caulking method. Thereby, the cathode C is formed.
- the difference in thermal expansion coefficient between the tungsten pins 6 and 7 constituting the anode A and the cathode C, and the anode beads 4 and the cathode beads 5 is small, specifically, 1 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 or less. It is set to be. As a result, the occurrence of inconvenience based on the difference in thermal expansion coefficient during melt bonding by heating is prevented in advance.
- FIG. 4A it consists of the 1st envelope part 8 which consists of an aluminosilicate glass tube, and the borosilicate glass tube containing an alkaline component, and includes the same inside and outside diameter of the 1st envelope part 8
- the second envelope part 9 having substantially the same inner and outer diameters is moved, for example, downward (in the direction of the arrow) shown in the figure, so that the end face 8a and the end face 9a are brought into contact with each other.
- the end face 8a and the end face 9a are brought into contact with each other.
- it heats and melt-joins by burner B3.
- the envelope 2 is formed.
- the thermal expansion coefficient (4.6 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 ) of the aluminosilicate glass tube forming the first envelope part 8 and the borosilicate glass tube forming the second envelope part 9 The difference from the coefficient of thermal expansion (3.2 to 4.1 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 ) is about 1 ⁇ 10 ⁇ 6 ⁇ K ⁇ 1 . Therefore, when the outer peripheral surface 9b of the second envelope part 9 is inserted into the inner peripheral surface 8b of the first envelope part 8 and melt-bonded in the radial direction, defects such as cracks occur due to the difference in thermal expansion coefficient between the two. May occur.
- the pipe shaft is connected via the thickness (thickness) of the end surface 8a of the first envelope portion 8 and the thickness (thickness) of the end surface 9a of the second envelope portion 9. Melt-bond in the direction. Thereby, generation
- a trigger electrode 13 made of a transparent conductive film 13 a such as tin oxide is formed in a predetermined region of the outer peripheral surface 8 c of the first envelope portion 8 of the envelope 2.
- the transparent conductive film 13a is formed by a known method such as a vapor deposition method.
- a trigger voltage for exciting the xenon gas sealed inside is applied to the trigger electrode 13.
- region of the outer peripheral surface 8c of the 1st envelope part 8 is an area
- the anode A and the cathode C manufactured by the method shown in FIGS. 2A to 4B are combined with the envelope 2 as follows.
- the anode A is moved downward as indicated by an arrow A1 in the drawing. Then, the end face 4bb of the second anode bead 4b of the anode bead 4 of the anode A and the end face 8a of the first envelope portion 8 of the envelope 2 are brought into contact with each other. Thereafter, the contact portion is heated by, for example, burner B4. Thereby, the end surface 4bb of the second anode bead 4b and the end surface 8a of the first envelope part 8 are melt-bonded. As a result, the anode A is hermetically sealed to the envelope 2 via the first envelope portion 8.
- the cathode C is moved upward as indicated by an arrow A2 in the figure. Then, the side surface portion 5 a of the cathode bead 5 of the cathode C is inserted into the inside along the inner peripheral surface 9 c of the second envelope portion 9 of the envelope 2.
- the second envelope portion 9 is heated by, for example, the burner B5. Thereby, the side surface portion 5a of the cathode bead 5 of the cathode C and the inner peripheral surface 9c of the second envelope portion 9 are melt-bonded. As a result, the cathode C is hermetically sealed to the envelope 2 (second envelope portion 9).
- a step of setting the external pin 10 of the anode A and the external pin 12 of the cathode C to a desired length and a step of applying preliminary solder to the external pins 10 and 12 are executed.
- the trigger electrode to which a trigger voltage is applied together with the transparent conductive film 13a is formed at the cathode C side end of the transparent conductive film 13a formed in the first envelope part 8 A step of providing a trigger band 13b is performed as necessary.
- the flash discharge tube 1 of the present embodiment shown in FIG. 1 is formed.
- the flash discharge tube according to the present embodiment is configured without using an intermediate glass body or a stepped glass tube that requires complicated processing steps. Therefore, the manufacturing steps of the flash discharge tube 1 can be simplified. As a result, the flash discharge tube 1 can be provided at low cost.
- FIG. 6 is a schematic temperature distribution diagram in the longitudinal direction when the flash discharge tube according to the same embodiment emits light continuously for a short interval.
- the temperature distribution shown in FIG. 6 was measured under a continuous light emission operation condition in which an operation of emitting light at a time of several ms, for example, was performed 250 times at intervals of 0.8 s.
- FIG. 6 shows a schematic temperature distribution in the tube axis (longitudinal) direction in the case where the flash discharge tube having the above configuration is caused to emit light 250 times at intervals of 0.8 s.
- FIG. 6 shows that the maximum temperature reached by the flash discharge tube reaches a high temperature exceeding 700 ° C.
- the temperature distribution in the tube axis direction in the arc discharge space Y where arc discharge occurs between the pair of discharge electrodes is maintained at a uniform distribution at a high temperature of about 700 ° C.
- the temperature distribution in the vicinity of the so-called sealing portion including the anode bead 4 of the anode A and the cathode bead 5 of the cathode C is lower than the arc discharge space Y but is a high temperature of about 400 ° C. to 550 ° C.
- the temperature on the anode A side is higher than the temperature in the vicinity of the sealing portion on the cathode C side.
- the tungsten pin 6 constituting the anode A in the airtight space X in which the xenon gas is sealed is configured to be relatively long. Therefore, it can be seen that there is a temperature drop region near the center of the tungsten pin 6.
- the temperature drop region occurs due to a spatial distance between the tungsten pin heated by the discharge and the inner diameter of the glass tube. That is, the heat conduction in the temperature lowering region is heating of the tungsten pin by discharge, xenon gas, and heat conduction from the inner surface to the outer surface of the glass tube.
- the sealing surface of the anode bead 4 and the glass tube serves as heat conduction to the sealing portion of tungsten, the anode bead 4 and the glass tube. Due to this difference, a temperature drop region occurs.
- a temperature drop region occurs in the region where the trigger band 13b is formed.
- a trigger wire is wound around the outer surface of the glass tube on which the sintered electrode 11 is installed, and is fixed with silver paint. Therefore, heat is radiated into the air via the trigger wire. As a result, a region having a lower temperature is formed.
- the alkali of borosilicate glass It is considered that the trigger signal decay phenomenon occurs due to the component. That is, if a trigger signal is supplied to the area
- a part of the region surrounding the hermetic space X in which the arc discharge space Y and the xenon gas are enclosed in the region that is in a high temperature state is made of an aluminosilicate glass tube.
- An alkali-free region is formed by one envelope portion 8.
- the trigger electrode 13 is formed in the first envelope part 8 (alkali-free region).
- a tungsten pin that is a discharge electrode and an aluminosilicate glass tube that constitutes an envelope are interposed with a bonding glass tube made of borosilicate glass that is a sealing glass having an expansion coefficient that matches that of the tungsten pin.
- the structure is hermetically sealed.
- the hermetic sealing method for the anode A and the xenon gas sealing method can be variously changed as follows.
- the configuration in which the second envelope part 9 is melt-bonded only to one end of the first envelope part 8 has been described as an example, but the present invention is not limited thereto.
- the second envelope part 9 may be formed at both ends of the first envelope part 8.
- the anode A may be melt-bonded via the second envelope portion 9.
- the anode bead 4 of the anode A needs to be formed so that the outer diameter thereof is smaller than the inner diameter of the second envelope portion 9 like the cathode bead 5.
- the outer peripheral surface of the anode bead 4 is melt-bonded to the inner peripheral surface 9c of the corresponding second envelope part 9.
- the same effect as described above can be obtained.
- the envelope 2 is configured by the first envelope portion 8 and the second envelope portion 9 has been described, but is not limited thereto.
- the envelope 2 may be configured by only the first envelope portion 8.
- the outer diameters of the anode beads 4 of the anode A and the cathode beads 5 of the cathode C are formed to be smaller than the inner diameter of the first envelope portion 8.
- the first envelope part 8 is formed in an elongated shape so as to have a dimension that is, for example, twice or more the inner diameter in the tube axis direction. And it is preferable to insert each side part of the anode bead 4 and the cathode bead 5 along the inner peripheral surface of the corresponding 1st envelope part 8, and to melt-join. Thereby, the same effect is acquired.
- the anode bead 4 has been described as an example of the first anode bead 4a and the second anode bead 4b.
- the present invention is not limited to this.
- the anode bead 4 may be formed of only the second anode bead 4b and welded directly to the tungsten pin 6. Thereby, the same effect can be obtained with a simple configuration.
- the cathode C is hermetically sealed with the burner B5 while the xenon gas 3 is sealed inside the envelope 2, but the present invention is not limited to this.
- it may be hermetically sealed using a carbon heater.
- a vacuum vessel provided with a work space capable of filling the envelope 2 sealed with the anode A shown in FIG. 5 except the burner B5, the cathode C, and the carbon heater with xenon gas at a predetermined pressure. Place in. Then, in the vacuum vessel, the xenon gas is filled, and the fusion bonding between the cathode bead 5 of the cathode C and the second envelope part 9 of the envelope 2 is performed by a carbon heater.
- the exhaust pipe may be hermetically sealed by a known method of chip-off. Good.
- the envelope 2 is configured by only the first envelope portion 8 without bonding the second envelope portion 9 which is a bonded glass tube.
- the configuration of the cathode bead 5 including the end outer diameter is the same as the configuration of the anode bead 4. Thereby, like the anode A, it is preferable to melt-bond the cathode bead 5 directly to one end of the first envelope part 8 through the thickness thereof.
- the trigger electrode 13 is configured by the transparent conductive film 13a and the trigger band 13b has been described.
- the present invention is not limited thereto.
- the trigger electrode 13 may be configured by only a transparent conductive film or a configuration including a trigger band and a metal wire wound around the first envelope portion 8.
- the alkali-free region is formed in the range of the first envelope portion 8 .
- the present invention is not limited to this.
- the entire region that becomes high temperature due to the light emitting operation may be an alkali-free region.
- the same effect is acquired irrespective of the sealing method.
- the tungsten pins 6 and 7 and the aluminosilicate glass tube of the first envelope are hermetically sealed with the anode beads 4 and cathode beads 5 of borosilicate glass interposed therebetween.
- it is desirable to constitute an alkali-free region by avoiding a region that is melt-bonded to borosilicate glass whose electrical characteristics fluctuate due to temperature rise.
- the airtight space X including the anode bead 4 and the cathode bead 5 and excluding the so-called sealing portion, in which xenon gas is sealed is set as the maximum region.
- a region surrounding the arc discharge space Y between the tips of the tungsten pins 6 and 7 of the pair of discharge electrodes is set as a minimum region.
- the alkali-free region is formed in a central region that is at a high temperature and has a range that is not less than the minimum region and less than the maximum region. Therefore, in the present embodiment, the alkali-free region shown in FIG. 1 is formed as a region surrounding the arc discharge space Y between the above-described pair of discharge electrodes and a part of the airtight space X connected to the arc discharge space Y. ing.
- the flash discharge tube 1 of the present embodiment is formed.
- FIG. 7 is a schematic configuration diagram showing a strobe device S which is an example of a light emitting device including the flash discharge tube 1 according to the embodiment of the present invention.
- a strobe device S which is an example of the light emitting device of the present embodiment includes a main body 14, a flash discharge tube 1, a reflector 16, an optical member 17, and an optical control unit in the main body 14. 18 and a light emission operation control unit 19 and the like.
- the flash discharge tube 1 serves as an illumination light source that illuminates the subject 15 and the like.
- the reflector 16 guides light emitted from the flash discharge tube 1 toward the subject 15.
- the optical member 17 is disposed between the flash discharge tube 1 and the subject 15 and blocks light in a short wavelength region, for example, light of 400 nm or less.
- the optical control unit 18 controls an emission direction, an emission angle, and the like of light incident through the optical member 17.
- the light emission operation control unit 19 controls the light emission operation of the flash discharge tube 1.
- the strobe device S is controlled by the light emission operation control unit 19 and operates as follows.
- the flash discharge tube 1 reaches the optical member 17 directly and by being reflected by the reflector 16.
- the reached light is blocked by the optical member 17 in the short wavelength region. Therefore, for example, light that does not include light with a wavelength of 400 nm or less is emitted from the optical member 17.
- the emitted light is irradiated to the subject 15 by the optical control unit 18, for example, by controlling the irradiation angle.
- the strobe device S of the present embodiment includes the flash discharge tube 1 of the present embodiment as a light source.
- the flash discharge tube 1 is configured by using a tungsten pin as an electrode pin, and using an alkali-free glass other than quartz glass in an appropriate region of the envelope that becomes high temperature in a continuous light emission operation at short intervals. is doing.
- the flash discharge tube 1 having an inexpensive configuration suppresses the attenuation of the output of the trigger signal, and reduces the occurrence of lack of light emission (non-light emission), for example. That is, the flashlight discharge tube 1 having excellent durability and realizing stable continuous light emission operation at short time intervals at low cost is used.
- the strobe device S has been described as an example of the light emitting device of the present embodiment. It is not limited to this.
- the above flash discharge tube may be used as a light source for various light emitting devices such as aircraft obstacle lights installed in high places such as bridges and high-rise buildings, and warning lights mounted on emergency vehicles such as aircraft and police cars. Good.
- the flash discharge tube of the present invention is hermetically sealed with a light-transmitting envelope and xenon gas sealed inside the envelope at both ends of the envelope.
- a pair of discharge electrodes including an anode and a cathode provided, a trigger circuit that outputs a trigger signal, and a trigger electrode that is formed on the outer surface of the envelope and to which the trigger signal is applied.
- the pair of discharge electrodes have tungsten pins provided in the envelope so as to face each other.
- the envelope is less than the maximum region surrounding the hermetic space formed by hermetically sealing with the pair of discharge electrodes, and more than the minimum region surrounding the arc discharge space formed between the tungsten pins of the pair of discharge electrodes.
- the central region that is in a high temperature state during the light emission operation is provided as an alkali-free region that is an alkali-free glass excluding quartz glass and does not contain an alkali component or contains a predetermined amount or less of an alkali component. And it is good also as a structure which arrange
- the envelope moves to a high temperature state by continuous light emission operation at short time intervals through the opposing tungsten pins, the deterioration of the tungsten pins can be prevented. Thereby, generation
- the envelope of the flash discharge tube of the present invention is an alkali-free glass tube made of alkali-free glass other than a quartz glass tube that forms an arc discharge space that surrounds at least the arc discharge region as an alkali-free region, It has a joining glass tube made of borosilicate glass having a substantially equal inner and outer diameter including the same inner and outer diameter of the alkali-free glass tube and melt-bonded to at least one end face of the alkali-free glass tube.
- the flash discharge tube has a trigger electrode formed on the outer surface excluding both ends of the alkali-free glass tube, and a discharge electrode including a tungsten pin forming an anode, and has an outer diameter substantially equal to the outer diameter of the alkali-free glass tube.
- an anode bead made of borosilicate glass which is hermetically welded so as to form an end face portion and is melt-bonded to one end of the alkali-free glass tube via the end face portion.
- the discharge electrode including the tungsten pin forming the cathode is hermetically welded so as to form a side surface having an outer diameter substantially equal to the inner diameter of the bonded glass tube. It is good also as a structure provided with the cathode bead which consists of borosilicate glass melt-joined through a side part in a glass tube.
- the anode bead and the bonded glass tube are welded to the thickness portion of the end face of the alkali-free glass tube.
- it welds not in the radial direction of an alkali free glass tube but in a tube axial direction.
- it is possible to greatly suppress the occurrence of leaks due to, for example, a peeling phenomenon caused by the difference in thermal expansion coefficient between the members to be welded.
- the hermetically sealing operation between the cathode and the envelope can be performed through a bonded glass tube made of borosilicate glass similar to the conventional one. For this reason, facilities, work conditions, etc. in the airtight wearing work can be set as before. As a result, a flash discharge tube having high characteristics can be formed without reducing productivity.
- the alkali-free glass tube may be composed of an aluminosilicate glass tube.
- the aluminosilicate glass tube has a higher softening point than the borosilicate glass tube, the temperature of the processing operation is high, but it can be processed at a temperature much lower than the processing temperature of the quartz glass tube. Therefore, the workability of the hermetically sealing step of the anode and the cathode can be improved as compared with a flash discharge tube using a quartz glass tube that requires an intermediate glass body or the like.
- the trigger electrode may be provided on the outer surface of the envelope excluding both ends of the alkali-free region.
- the trigger electrode may be formed of a transparent conductive film.
- the light emitting device of the present invention may include the flash discharge tube as a light source load.
- a flash discharge tube having excellent durability and capable of increasing the number of continuous light emission operations at short time intervals is used as a light source.
- a light emitting device having excellent durability characteristics against arc discharge phenomena and continuous light emission operation characteristics (repetitive light emission characteristics) at short intervals is provided.
- the present invention is applicable to fields such as a flash discharge tube and a light emitting device including the flash discharge tube which are inexpensive and require durability characteristics against high emission and repeated emission durability characteristics at short intervals.
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Abstract
Description
2 外囲器
3 キセノンガス
4 陽極ビード
4a 第1陽極ビード
4b 第2陽極ビード
4bb,8a,9a 端面
5 陰極ビード
5a 側面部
6,7 タングステンピン
8 第1外囲器部
8b,9c 内周面
8c,9b 外周面
9 第2外囲器部
10,12 外部ピン
11 焼結電極
13 トリガー電極
13a 透明導電性被膜
13b トリガーバンド
14 本体
15 被写体
16 反射傘
17 光学部材
18 光学制御部
19 発光動作制御部
Claims (6)
- 透光性の外囲器と、
前記外囲器の両端に、前記外囲器の内部にキセノンガスを封入した状態で、気密封着してなる陽極と陰極からなる一対の放電電極と、
トリガー信号を出力するトリガー回路と、
前記外囲器の外表面に形成され、前記トリガー信号が印加されるトリガー電極と、を備え、
前記一対の放電電極は、相対向して前記外囲器内に設けられるタングステンピンを、有し、
前記外囲器は、前記一対の放電電極で気密封着して形成される気密空間を囲む最大領域未満で、前記一対の放電電極の前記タングステンピン間で形成されるアーク放電空間を囲む最小領域以上の、発光動作時に高温状態となる中央領域を、石英ガラスを除くアルカリフリーガラスで、アルカリ成分を含まない、あるいは所定量以下のアルカリ成分を含むアルカリフリー領域として、備え、
前記トリガー電極は、前記アルカリフリー領域に配置される閃光放電管。 - 前記外囲器は、少なくとも前記アーク放電領域を囲んで形成されるアーク放電空間をアルカリフリー領域として形成する石英ガラス以外のアルカリフリーガラスからなるアルカリフリーガラス管と、
前記アルカリフリーガラス管の内外径と同一を含む略等しい内外径を有し、前記アルカリフリーガラス管の少なくとも一端の端面に溶融接合されるホウ珪酸ガラスからなる接合ガラス管と、
前記陽極を形成する前記タングステンピンを含む前記放電電極に前記アルカリフリーガラス管の外径と略等しい外径を有する端面部を形成するように気密溶着され、前記アルカリフリーガラス管の一端に前記端面部を介して溶融接合されるホウ珪酸ガラスからなる陽極ビードと、
前記陽極の先端部に固着される焼結電極と共に前記陰極を形成する前記タングステンピンを含む前記放電電極に前記接合ガラス管の内径と略等しい外径を有する側面部を形成するように気密溶着され、前記接合ガラス管内に前記側面部を介して溶融接合されるホウ珪酸ガラスからなる陰極ビードと、
を備えて構成される請求項1に記載の閃光放電管。 - 前記アルカリフリーガラス管は、アルミノシリケートガラス管である請求項2に記載の閃光放電管。
- 前記トリガー電極は、前記アルカリフリー領域の両端部を除く、前記外囲器の外表面に設けられる請求項1に記載の閃光放電管。
- 前記トリガー電極は、透明導電性被膜である請求項4に記載の閃光放電管。
- 請求項1に記載の閃光放電管を光源負荷として備える発光装置。
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US15/509,944 US9870913B2 (en) | 2015-07-08 | 2016-06-29 | Flash discharge tube and light-emitting device equipped with the flash discharge tube |
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Citations (2)
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JP2005093422A (ja) * | 2003-08-08 | 2005-04-07 | Nippon Electric Glass Co Ltd | 外部電極蛍光ランプ用外套容器 |
JP5262911B2 (ja) * | 2009-03-30 | 2013-08-14 | パナソニック株式会社 | 放電管及び放電管の製造方法 |
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JPH11238489A (ja) | 1998-02-20 | 1999-08-31 | Harison Electric Co Ltd | ランプおよび照明装置 |
JP3678197B2 (ja) * | 2001-12-28 | 2005-08-03 | ウシオ電機株式会社 | フラッシュランプ装置および閃光放射装置 |
JP5423240B2 (ja) * | 2009-08-24 | 2014-02-19 | パナソニック株式会社 | 閃光放電管用電極及び閃光放電管 |
JP5505446B2 (ja) * | 2012-03-19 | 2014-05-28 | ウシオ電機株式会社 | フラッシュランプ |
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JP2005093422A (ja) * | 2003-08-08 | 2005-04-07 | Nippon Electric Glass Co Ltd | 外部電極蛍光ランプ用外套容器 |
JP5262911B2 (ja) * | 2009-03-30 | 2013-08-14 | パナソニック株式会社 | 放電管及び放電管の製造方法 |
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