WO2017006381A1 - Système d'électrolyse - Google Patents

Système d'électrolyse Download PDF

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Publication number
WO2017006381A1
WO2017006381A1 PCT/JP2015/069255 JP2015069255W WO2017006381A1 WO 2017006381 A1 WO2017006381 A1 WO 2017006381A1 JP 2015069255 W JP2015069255 W JP 2015069255W WO 2017006381 A1 WO2017006381 A1 WO 2017006381A1
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WO
WIPO (PCT)
Prior art keywords
cell
plate
anode plate
cathode
electrolysis
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Application number
PCT/JP2015/069255
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English (en)
Japanese (ja)
Inventor
雄樹 工藤
Original Assignee
萩谷 公康
Ｊｅｔｓ株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 萩谷 公康, Ｊｅｔｓ株式会社 filed Critical 萩谷 公康
Priority to PCT/JP2015/069255 priority Critical patent/WO2017006381A1/fr
Publication of WO2017006381A1 publication Critical patent/WO2017006381A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/02—Process control or regulation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells

Definitions

  • the present invention relates to an electrolysis system including an electrolyzer that generates hydrogen gas and oxygen gas by electrolysis.
  • an electrolysis apparatus that includes an electrolytic solution, an anode, and a cathode in an electrolysis cell, generates oxygen gas from the anode, and generates hydrogen gas from the cathode by electrolyzing the electrolyte solution is known.
  • the temperature in the cell rises as the number of ions generated increases. Due to the temperature rise, the cell may be deformed or the evaporation of the electrolyte solution may be promoted, resulting in an unexpected decrease in the solution. Therefore, for example, according to Patent Document 1, the electrolyte solution is diffused in order to reduce the temperature in the cell.
  • a diffusion channel In the conventional electrolysis apparatus, in order to diffuse the electrolyte solution, a diffusion channel has to be provided separately, and there is a problem that the cell is enlarged accordingly. Further, when used in a high temperature environment, the temperature of the diffusion channel also rises, and there is a problem that sufficient cooling cannot be performed. Furthermore, when the cell temperature rises, the liquid resistance decreases and the current value in the cell also increases. If the current value increases and an overcurrent occurs, the wiring may be damaged. Moreover, when the current value increases, a vicious cycle occurs in which the temperature further increases.
  • This invention makes it a subject to provide the electrolysis system which ensured safety
  • the present invention includes a housing body and a lid, a solution containing an electrolyte held in a cell formed inside the housing body, and an anode plate and a cathode plate in which at least a part of the solution is infiltrated.
  • An electrolysis system having an electrolysis apparatus in which a voltage is applied to the anode plate and the cathode plate to generate oxygen gas from the anode plate and to generate hydrogen gas from the cathode plate, which is connected to a power source and from the power source
  • a power supply circuit that controls the current flowing through the electrolyzer to be constant
  • the housing body includes temperature measuring means for measuring a temperature of the housing body; and the temperature measuring means includes the housing
  • An electrolysis system characterized by shutting off electricity from the power supply to the power supply circuit when the body body reaches a predetermined temperature or higher.
  • the cell may include a pair of the cathode plates and the anode plate located between the cathode plates, and a spacer may be provided between the cathode plate and the anode plate.
  • a pair of the cathode plates and the anode plate positioned between the cathode plates are disposed, and the cathode plate and the anode plate are joined to each other by a fixing plate which is an electric conductor. May be.
  • the entire system can be reduced in size and safety can be ensured.
  • FIG. 1 is a schematic diagram of an electrolysis system according to an embodiment of the present invention.
  • FIG. 5 is a sectional view taken along line VV in FIG. 2.
  • FIG. 6 is a sectional view taken along line VI-VI in FIG. 2. Explanatory drawing of a cathode plate and an anode plate.
  • the electrolysis system 1 includes an electrolysis apparatus 2, a power supply circuit 3 connected to the electrolysis apparatus 2, and a thermostat 5 that is a temperature measurement unit connected to the power supply circuit 3.
  • the power supply circuit 3 is connected to a battery 4 as a power supply via a thermostat 5 and controls the current flowing from the battery 4 to the electrolysis device 2 to be constant.
  • a switching system circuit that controls the on / off time ratio of the semiconductor switch element by a feedback circuit can be used.
  • the electrolyzer 2 has a vertical direction Y, a horizontal direction X, and a height direction Z that are orthogonal to each other, and includes a housing body 10 and a lid 20.
  • the housing body 10 includes a front surface 10 ⁇ / b> A and a rear surface 10 ⁇ / b> B that are separated in the vertical direction Y, and a pair of side surfaces 10 ⁇ / b> C that are separated in the lateral direction X.
  • a thermostat 5 is attached to the rear surface 10 ⁇ / b> B of the housing body 10 and below the height direction Z, and the thermostat 5 is covered with a covering body 6.
  • the covering 6 is, for example, an aluminum foil tape or the like having high thermal conductivity.
  • the thermostat 5 measures the temperature of the housing body 10 and shuts off electricity from the battery 4 to the power supply circuit 3 when the temperature exceeds a predetermined upper limit temperature.
  • the thermostat 5 may energize the battery 4 to the power supply circuit 3 when the temperature of the housing body 10 again falls below a predetermined lower limit temperature.
  • the housing body 10 is partitioned into a plurality of cells 12 by a plurality of partition plates 11 that extend in the height direction Z and that are spaced apart from each other in the lateral direction X.
  • the One end of the partition plate 11 is in contact with the front surface 10A, and the other end is in contact with the back surface 10B to form the cells 12 arranged in the lateral direction X.
  • the cell 12 includes a first cell 12A, a second cell 12B, a third cell 12C, a fourth cell 12D, a fifth cell 12E, and a sixth cell 12F.
  • the lid 20 is formed with a groove 31 into which a part of the housing body 10 and the partition plate 11 are fitted, so that the housing body 10 and the lid 20 can be connected.
  • the housing body 10 and the lid 20 are joined in a watertight manner.
  • the lid 20 may be removable with respect to the housing body 10 or may not be removable with an adhesive or the like.
  • Each cell 12 is injected with a solution 13 containing an electrolyte.
  • sodium bicarbonate is used as the electrolyte.
  • the electrolyte those containing metal ions such as potassium, calcium, magnesium, and aluminum having a high ionization tendency and sulfide ions, nitrate ions, and hydroxide ions can be used.
  • the visual recognition part 19 which can confirm the water level of the solution 13 in the inside is provided in the front surface 10A of the housing body 10 at a position corresponding to each cell 12.
  • the visual recognition part 19 is formed by making the housing body 10 thinner than other parts.
  • Each cell 12 is provided with a cathode plate 14 and an anode plate 15 respectively. More specifically, in each cell 12, an anode plate 15 is disposed between the pair of cathode plates 14 in the lateral direction X.
  • the cathode plate 14 for example, a stainless steel plate having a thickness of about 1 mm can be used, and as the anode plate 15, for example, a titanium plate having a thickness of about 1 mm can be used.
  • other metal plates such as platinum and lead can be used as long as hydrogen gas is generated from the cathode plate 14 and oxygen gas is generated from the anode plate 15.
  • the cathode plate 14 has a plate shape extending in the vertical direction Y and the height direction Z, and is immersed in the solution 13 to mainly participate in the generation of hydrogen gas.
  • the dimension of the vertical direction Y is smaller than the gas generation part 14A, and the extension part 14B extended in the height direction Z from the gas generation part 14A is included.
  • the anode plate 15 has a plate shape extending in the vertical direction Y and the height direction Z.
  • the anode plate 15 is immersed in the solution 13 and mainly involved in the generation of oxygen gas, and the vertical direction is higher than the gas generation unit 15A.
  • the dimension of the direction Y is small, and the extension part 15B extended in the height direction Z from 15 A of gas generation parts is included. Note that the extending portions 14B and 15B do not generate any gas, and gas is generated as long as they are immersed in the solution 13 although the amount is smaller than that of the gas generating portions 14A and 15A.
  • the extension part 14B of the cathode plate 14 and the extension part 15B of the anode plate 15 are located at either one end in the longitudinal direction Y. Within the same cell 12, the extending part 14B and the extending part 15B are separated in the longitudinal direction Y. In the adjacent cells 12, the extending portions 14B are separated from each other in the longitudinal direction Y, and the extending portions 15B are also separated from each other in the longitudinal direction Y. That is, the extended portion 14B of the cathode plate 14 is positioned on the front side in the longitudinal direction Y in the first cell 12A, the third cell 12C, and the fifth cell 12E, and the second cell 12B, the fourth cell 12D, In 6 cell 12F, it is located in the drawing back side.
  • the extending portion 15B of the anode plate 15 is located on the back side in the longitudinal direction Y, and the second cell 12B, the fourth cell 12D, In 6 cell 12F, it is located on the near side of the drawing.
  • the extension part 14B of the pair of cathode plates 14 provided in each cell 12 and the extension part 15B of the anode plate 15 of the adjacent cell 12 are connected to each other by a fixed plate 16 that is an electric conductor.
  • the extending portion 14B and the extending portion 15B can be connected to each other by welding to the fixing plate 16.
  • the extension 15B of the anode plate 15 of the first cell 12A is not connected to the extension 14B of the cathode plate 14 of another cell.
  • the extending portions 14B of the cathode plate 14 of the sixth cell 12F are connected to each other by the fixing plate 16, and are not connected to the anode plates 15 of other cells.
  • the extending portion 14B of the cathode plate 14 of the first cell 12A and the extending portion 15B of the anode plate 15 of the second cell 12B are electrically connected.
  • the anode plate 15 of the cell 12E, the cathode plate 14 of the fifth cell 12E, and the anode plate 15 of the sixth cell 12F are electrically connected via the fixed plate 16, respectively.
  • a positive electrode terminal 25 is connected to the anode plate 15 of the first cell 12A located at one end via an extension 15B, and the cathode plate 14 of the sixth cell 12F located at the other end is connected to the anode plate 15 of the first cell 12A located at one end.
  • the negative electrode terminal 26 is connected via the fixed plate 16.
  • the positive electrode terminal 25 and the negative electrode terminal 26 protrude from the outer surface 20B of the lid 20 and are located on the back surface 10B side in the vertical direction Y.
  • Such a positive electrode terminal 25 and a negative electrode terminal 26 can be connected to the battery 4 via the power supply circuit 3.
  • the cathode plate 14 and the anode plate 15 in the solution 13 can be energized via the solution 13.
  • each cell 12 the dimensions in the lateral direction X of the anode plate 15 and each cathode plate 14 are made substantially equal. In this way, by making the distance between the anode plate 15 and the cathode plate 14 equal, an approximately equal amount of oxygen gas is generated from both sides of the anode plate 15 in the lateral direction X. Further, in the cathode plate 14, hydrogen gas is generated from the surface facing the anode plate 15, so that a substantially equal amount of hydrogen gas can be generated in the pair of cathode plates 14.
  • a spacer 17 is disposed between the cathode plate 14 and the anode plate 15 (see FIG. 5).
  • the spacer 17 includes a pair of fitting pieces 17A and 17B that are fitted together.
  • the anode plate 15 is provided with a through hole 18 into which at least one of the fitting pieces 17A and 17B can be inserted.
  • a part of the fitting piece 17 ⁇ / b> A has a size that can penetrate the through-hole 18, and the other part and the fitting piece 17 ⁇ / b> B are made larger than the through-hole 18.
  • the spacer 17 can be formed by fitting the fitting piece 17 ⁇ / b> A and the fitting piece 17 ⁇ / b> B through the through hole 18.
  • the spacer 17 can maintain a constant distance between the anode plate 15 and the cathode plate 14 adjacent thereto. Therefore, it is possible to prevent the adjacent cathode plate 14 and anode plate 15 from contacting each other unintentionally.
  • the configuration of the spacer 17 is not limited to the configuration in this embodiment, and any configuration may be used as long as the adjacent cathode plate 14 and anode plate 15 can be given and separated from each other.
  • the lid 20 includes a first lid portion 21 that covers the opening of the housing body 10 and a second lid portion 22 that is placed so as to cover a part of the first lid portion 21.
  • the first lid portion 21 and the second lid portion 22 are provided with a passage 27 that communicates each cell 12 with the outside.
  • the passage 27 opens to the outer surface 20B of the lid 20 and communicates with the outer surface opening 27A passing through the first lid 21 and the outer surface opening 27A and between the first lid 21 and the second lid 22.
  • An internal passage 27B that is provided and extends in the lateral direction X and a cell opening 27C that opens to the internal passage 27B and each cell 12 and penetrates the second lid portion 22 in the height direction Z are provided.
  • Each cell 12 communicates with the outside of the housing body 10 via the outer surface opening 27A, the inner passage 27B, and the cell opening 27C. Therefore, hydrogen gas and oxygen gas generated in the cell 12 are guided to the outside of the housing body 10 through the cell opening 27C, the internal passage 27B, and the outer surface opening 27A.
  • a pipe (not shown) is attached to the outer surface opening 27A, and hydrogen gas and oxygen gas can be supplied from the tip of the pipe to the internal combustion engine.
  • the end of the pipe is inserted into an air hose for intake of the engine so that hydrogen gas and oxygen gas are supplied to the engine along with intake air when the engine is driven. be able to.
  • the lid 20 is formed with a slot 23 that penetrates the casing body 10 in the height direction Z and corresponds to each position of the first cell 12A to the sixth cell 12F.
  • the inlet 23 is for replenishing each cell 12 when the solution 13 decreases.
  • Such an insertion port 23 is provided on the front surface 10A side, and caps 24 for holding the insertion port 23 in a watertight manner are attached to the insertion port 23, respectively.
  • the cap 24 can be made of metal, resin, or the like, but it is preferable to use a cap that is not easily deformed even at high temperatures.
  • the amount of the solution 13 can be determined by the visual recognition unit 19.
  • the insertion port 23 is provided on the front surface 10A side, and the positive electrode terminal 25 and the negative electrode terminal 26 are provided on the rear surface 10B side.
  • the cathode plate 14 and the anode plate 15 that are alternately arranged are connected to the plus electrode terminal 25 and the minus electrode terminal 26, and the cathode plate 14 and the anode plate 15 are arranged in the back surface 10 ⁇ / b> B rather than the front surface 10 ⁇ / b> A in the housing body 10. Arranged to approach. Accordingly, it is possible to prevent the solution 13 from coming into direct contact with the cathode plate 14 and the anode plate 15 when the solution 13 is introduced from the introduction port 23.
  • the lid 20 can be obtained, for example, by molding a synthetic resin, and can form the outer surface opening 27A, the inner passage 27B, and the cell opening 27C at the time of molding.
  • the fixing plate 16 can be fixed so as to be embedded therein.
  • the cathode plate 14 and the anode plate 15 can be insulated from each other than the fixing plate 16. Further, the cathode plate 14 and the anode plate 15 can be fixed to the lid 20 without using other members such as screws, and the number of parts can be reduced.
  • the screws may be rusted, and there is a concern about problems due to the occurrence of rust, but the screws are not used. This can prevent this problem.
  • the pair of cathode plates 14 in one cell 12 and the anode plate 15 of the adjacent cell 12 are connected by the fixed plate 16, energization from the first cell 12A to the sixth cell 12F is performed. Even if it is an attempt, the electrical connection wiring can be simplified. Moreover, since the fixing plate 16 can be fixed to the lid 20 at the same time as the lid 20 is molded, the manufacturing cost and processing cost thereof can be greatly reduced. Further, by disposing the cathode plate 14 and the anode plate 15 in this way, space can be saved and the entire system can be reduced in size.
  • the temperature in the electrolysis apparatus 2 changes as the solution 13 is electrolyzed. Since the liquid resistance of the electrolyzer 2 changes according to temperature, the voltage and current of the electrolyzer 2 are not proportional. In particular, when the temperature rises, the liquid resistance of the electrolysis device 2 decreases, the current increases, and there is a possibility of wiring damage due to overcurrent. Therefore, in this embodiment, the power supply circuit 3 controls the current flowing from the battery 4 to the electrolysis device 2 to be constant.
  • the thermostat 5 is provided on the back surface 10B side where the cathode plate 14 and the anode plate 15 are close to each other.
  • the temperature of the back surface 10B in which the cathode plate 14 and the anode plate 15 are close to each other is higher than that of the front surface 10A, and the thermostat 5 can be arranged on the back surface 10B to further consider safety.
  • the power switch 3 and the battery 4 are energized when the main engine starts when the engine key is in the accessory (ACC) position in the ignition switch of the automobile. Can do.
  • the power supply circuit 3 and the battery 4 are energized, electricity flows from the power supply circuit 3 to the electrolysis device 2.
  • the solution 13 in the cell 12 is electrolyzed, hydrogen gas is generated from the cathode plate 14, and oxygen gas is generated from the anode plate 15.
  • hydrogen gas and oxygen gas can be generated by the electrolyzer 2 simultaneously with the start of the engine, and when the accelerator is subsequently depressed, Hydrogen gas and oxygen gas can be supplied to the engine.
  • the accelerator when the accelerator is stepped on, the engine is most heavily loaded and the fuel consumption is deteriorated. Accordingly, by supplying hydrogen gas and oxygen gas accordingly, the fuel consumption can be improved efficiently.
  • hydrogen gas and oxygen gas can be supplied immediately after the engine is started, it is not necessary to store these gases in a tank or the like for starting the engine, thereby reducing the size and safety of the entire system. Can be achieved.
  • hydrogen gas and oxygen gas generated in the electrolyzer 2 can be supplied to the internal combustion engine, and these gases can improve the combustion efficiency of fuel in the internal combustion engine.
  • water vapor is generated in addition to hydrogen gas and oxygen gas, and the water vapor is supplied to the internal combustion engine together with the hydrogen gas and oxygen gas.
  • carbon adhering to the inside of the internal combustion engine can be peeled off, which is considered to be useful for purification inside the engine.
  • the hydrogen gas and oxygen gas generated in the electrolyzer 2 need only be connected to an air hose for intake of an automobile through a pipe connected to the outer surface opening 27A, and no other special device is required.
  • the electrolysis system 1 can be mounted. That is, since hydrogen gas and oxygen gas are also sucked into the internal combustion engine with intake air in the internal combustion engine, no special device such as a pump is required to supply the gas to the internal combustion engine.
  • a hydrocarbon liquid fuel such as gasoline or light oil
  • a hydrocarbon liquid fuel such as gasoline or light oil
  • it can be used not only for automobiles but also for boiler devices, construction machines, and the like.
  • the electrolysis system 1 is mounted on a large vehicle such as a truck, a plurality of electrolyzers 2 and a plurality of power supply circuits 3 can be used. By using a plurality of electrolysis devices 2 and power supply circuits 3 in this way, each electrolysis device 2 can be controlled independently.
  • Electrolysis system DESCRIPTION OF SYMBOLS 1 Electrolysis system 2 Electrolysis apparatus 3 Power supply circuit 5 Thermostat (temperature measurement means) 10 Housing body 12 Cell 13 Solution 14 Cathode plate 15 Anode plate 16 Fixing plate 17 Spacer 20 Lid

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Automation & Control Theory (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

[Problème] Fournir un système d'électrolyse de sorte que la taille du système dans son ensemble soit réduite et la sécurité soit assurée. [Solution] La présente invention concerne un système d'électrolyse 1 qui comprend un dispositif d'électrolyse 2 et un circuit de source d'alimentation 3 connecté au dispositif d'électrolyse 2. Le circuit de source d'alimentation 3 est connecté à une batterie de source d'alimentation 4 par l'intermédiaire d'un thermostat 5 qui est un moyen de mesure de température, et le circuit de source d'alimentation 3 effectue une commande de sorte qu'un courant électrique circulant de la batterie 4 vers le dispositif d'électrolyse 2 soit constant. Le thermostat 5 est fixé à une surface externe d'un corps de boîtier 10, et mesure la température du corps de boîtier 10 et coupe l'électricité de la batterie 4 vers le circuit de source d'alimentation 3 lorsque la température du corps de boîtier 10 est égale ou supérieure à une température limite supérieure prédéterminée.
PCT/JP2015/069255 2015-07-03 2015-07-03 Système d'électrolyse WO2017006381A1 (fr)

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PCT/JP2015/069255 WO2017006381A1 (fr) 2015-07-03 2015-07-03 Système d'électrolyse

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WO2017006381A1 true WO2017006381A1 (fr) 2017-01-12

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0892780A (ja) * 1994-09-27 1996-04-09 Dalnivast Aktion Opushestva Atokurita Chiipa Praizuvotsuto Izuje Elektron Darielektron 水電解ガス発生装置
JP2001009455A (ja) * 1999-06-29 2001-01-16 Tsukuba Rika Seiki Kk 電気分解用多層電極板構造及び電気分解装置
JP3101713U (ja) * 2003-11-12 2004-06-17 有限会社光陽商会 水素と酸素の混合ガス発生装置
JP2005048239A (ja) * 2003-07-29 2005-02-24 Suiso Power Kk 水素／酸素発生装置における電解槽の異常検知装置
JP3124769U (ja) * 2006-05-29 2006-08-31 廣田 伊那吉 水素酸素混合ガス発生装置
JP2008240030A (ja) * 2007-03-26 2008-10-09 Toshigoro Sato 水素・酸素混成ガス発生装置
WO2011030556A1 (fr) * 2009-09-10 2011-03-17 株式会社レガルシィ Appareil pour produire un gaz mélangé d'hydrogène et d'oxygène et moteur à combustion interne utilisant cet appareil
JP2013023717A (ja) * 2011-07-19 2013-02-04 Mitsubishi Heavy Ind Ltd 水電解装置及び水電解装置の動作方法
JP2014189839A (ja) * 2013-03-27 2014-10-06 Jets Co Ltd 電解システム

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0892780A (ja) * 1994-09-27 1996-04-09 Dalnivast Aktion Opushestva Atokurita Chiipa Praizuvotsuto Izuje Elektron Darielektron 水電解ガス発生装置
JP2001009455A (ja) * 1999-06-29 2001-01-16 Tsukuba Rika Seiki Kk 電気分解用多層電極板構造及び電気分解装置
JP2005048239A (ja) * 2003-07-29 2005-02-24 Suiso Power Kk 水素／酸素発生装置における電解槽の異常検知装置
JP3101713U (ja) * 2003-11-12 2004-06-17 有限会社光陽商会 水素と酸素の混合ガス発生装置
JP3124769U (ja) * 2006-05-29 2006-08-31 廣田 伊那吉 水素酸素混合ガス発生装置
JP2008240030A (ja) * 2007-03-26 2008-10-09 Toshigoro Sato 水素・酸素混成ガス発生装置
WO2011030556A1 (fr) * 2009-09-10 2011-03-17 株式会社レガルシィ Appareil pour produire un gaz mélangé d'hydrogène et d'oxygène et moteur à combustion interne utilisant cet appareil
JP2013023717A (ja) * 2011-07-19 2013-02-04 Mitsubishi Heavy Ind Ltd 水電解装置及び水電解装置の動作方法
JP2014189839A (ja) * 2013-03-27 2014-10-06 Jets Co Ltd 電解システム

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