WO2016171124A1 - 方向性電磁鋼板 - Google Patents
方向性電磁鋼板 Download PDFInfo
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- WO2016171124A1 WO2016171124A1 PCT/JP2016/062356 JP2016062356W WO2016171124A1 WO 2016171124 A1 WO2016171124 A1 WO 2016171124A1 JP 2016062356 W JP2016062356 W JP 2016062356W WO 2016171124 A1 WO2016171124 A1 WO 2016171124A1
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- Prior art keywords
- groove
- steel sheet
- grain
- oriented electrical
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 173
- 239000010959 steel Substances 0.000 title claims abstract description 173
- 238000005096 rolling process Methods 0.000 claims abstract description 29
- 229910001224 Grain-oriented electrical steel Inorganic materials 0.000 claims description 103
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 99
- 239000011521 glass Substances 0.000 claims description 66
- 239000011248 coating agent Substances 0.000 claims description 62
- 238000000576 coating method Methods 0.000 claims description 62
- 239000002245 particle Substances 0.000 claims description 57
- 229910052742 iron Inorganic materials 0.000 claims description 46
- 239000000126 substance Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 description 67
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 53
- 238000000137 annealing Methods 0.000 description 36
- 239000007789 gas Substances 0.000 description 34
- 230000005381 magnetic domain Effects 0.000 description 29
- 238000012795 verification Methods 0.000 description 24
- 238000004519 manufacturing process Methods 0.000 description 22
- 239000013078 crystal Substances 0.000 description 21
- 239000010960 cold rolled steel Substances 0.000 description 17
- 238000002347 injection Methods 0.000 description 16
- 239000007924 injection Substances 0.000 description 16
- 230000003746 surface roughness Effects 0.000 description 15
- 230000000694 effects Effects 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 230000001066 destructive effect Effects 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000012535 impurity Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000002159 abnormal effect Effects 0.000 description 6
- 238000005097 cold rolling Methods 0.000 description 6
- 238000005261 decarburization Methods 0.000 description 6
- 238000000866 electrolytic etching Methods 0.000 description 6
- 229910052787 antimony Inorganic materials 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 229910052711 selenium Inorganic materials 0.000 description 5
- 229910052718 tin Inorganic materials 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005098 hot rolling Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 229910000976 Electrical steel Inorganic materials 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000008119 colloidal silica Substances 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 238000001953 recrystallisation Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 101001056180 Homo sapiens Induced myeloid leukemia cell differentiation protein Mcl-1 Proteins 0.000 description 2
- 102100026539 Induced myeloid leukemia cell differentiation protein Mcl-1 Human genes 0.000 description 2
- 229910004283 SiO 4 Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- 229910052839 forsterite Inorganic materials 0.000 description 2
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910020068 MgAl Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Images
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1277—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular surface treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/36—Removing material
- B23K26/362—Laser etching
- B23K26/364—Laser etching for making a groove or trench, e.g. for scribing a break initiation groove
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- C21D10/00—Modifying the physical properties by methods other than heat treatment or deformation
- C21D10/005—Modifying the physical properties by methods other than heat treatment or deformation by laser shock processing
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- C21D3/00—Diffusion processes for extraction of non-metals; Furnaces therefor
- C21D3/02—Extraction of non-metals
- C21D3/04—Decarburising
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- C21D6/00—Heat treatment of ferrous alloys
- C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
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- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
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- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/005—Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1255—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest with diffusion of elements, e.g. decarburising, nitriding
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1261—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest following hot rolling
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1277—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular surface treatment
- C21D8/1283—Application of a separating or insulating coating
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- C—CHEMISTRY; METALLURGY
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- C22C—ALLOYS
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- C—CHEMISTRY; METALLURGY
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- C22C—ALLOYS
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- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
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- C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/14766—Fe-Si based alloys
- H01F1/14775—Fe-Si based alloys in the form of sheets
- H01F1/14783—Fe-Si based alloys in the form of sheets with insulating coating
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/16—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/16—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets
- H01F1/18—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets with insulating coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/02—Iron or ferrous alloys
- B23K2103/04—Steel or steel alloys
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/352—Working by laser beam, e.g. welding, cutting or boring for surface treatment
- B23K26/359—Working by laser beam, e.g. welding, cutting or boring for surface treatment by providing a line or line pattern, e.g. a dotted break initiation line
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
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- C22C2202/02—Magnetic
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
Definitions
- the present invention relates to a grain-oriented electrical steel sheet. This application claims priority based on Japanese Patent Application No. 2015-086299 for which it applied to Japan on April 20, 2015, and uses the content here.
- grain-oriented electrical steel sheets that exhibit excellent magnetic properties in a specific direction are known as steel sheets for transformer cores.
- This grain-oriented electrical steel sheet is a steel sheet whose crystal orientation is controlled by a combination of a cold rolling process and an annealing process so that the easy axis of crystal grains coincides with the rolling direction. It is desirable that the iron loss of the grain-oriented electrical steel sheet is as low as possible.
- Iron loss is classified into eddy current loss and hysteresis loss. Furthermore, eddy current loss is classified into classical eddy current loss and abnormal eddy current loss.
- a grain-oriented electrical steel sheet in which an insulating film is formed on the surface of a steel sheet (ground iron) whose crystal orientation is controlled as described above is generally known. This insulating film plays a role of giving not only electrical insulation but also tension and heat resistance to the steel sheet.
- grain-oriented electrical steel sheets in which a glass film is formed between a steel sheet and an insulating film are also known.
- the magnetic domain control method includes a non-destructive magnetic domain control method in which the above-described distortion is imparted to a steel sheet of a grain-oriented electrical steel sheet by a non-destructive means, and a destructive magnetic domain control method such as forming a groove on the surface of the steel sheet. being classified.
- the destructive magnetic domain control method is generally employed for the wound core as a method for reducing abnormal eddy current loss.
- problems such as deformation deformation of the winding core do not occur, so either the nondestructive magnetic domain control method or the destructive magnetic domain control method is selectively adopted. can do.
- an electrolytic etching method (see Patent Document 1 below) in which grooves are formed on the steel sheet surface of the grain-oriented electrical steel sheet by electrolytic etching, and mechanically pressing a gear on the steel sheet surface of the grain-oriented electrical steel sheet
- the gear press method for forming grooves on the steel sheet surface (see Patent Document 2 below) and the laser irradiation method for forming grooves on the steel sheet surface of grain-oriented electrical steel sheets by laser irradiation (see Patent Document 3 below) Known.
- the insulating film (or glass film) on the surface of the steel sheet is linearly removed by laser or mechanical means, and then a groove is formed on the surface of the steel sheet by performing electrolytic etching on the exposed portion of the steel sheet.
- electrolytic etching method for example, the manufacturing process of the grain-oriented electrical steel sheet becomes complicated, resulting in an increase in manufacturing cost.
- gear press method since the steel plate of the grain-oriented electrical steel plate is a very hard steel plate containing about 3% by mass of Si, gear wear and damage are likely to occur.
- gear press method since the steel plate of the grain-oriented electrical steel plate is a very hard steel plate containing about 3% by mass of Si, gear wear and damage are likely to occur.
- gear press method since such a gear press method is employed, there is a problem that the effect of reducing abnormal eddy current loss cannot be sufficiently obtained because the groove depth varies when the gear is worn.
- the laser irradiation method is adopted as the magnetic domain control method for the grain-oriented electrical steel sheet
- the surface of the steel sheet is irradiated by irradiating the laser from above the insulating film toward the surface of the steel sheet.
- One of the manufacturing processes is to form a groove in the substrate. In this case, since the groove immediately after laser irradiation is exposed to the outside, it is necessary to form an insulating film on the steel sheet again after the groove is formed in order to prevent rusting in the groove.
- the thickness of the insulating film in the region where the groove is formed is larger than the thickness of the insulating film in the other region, the adhesion between the steel sheet and the insulating film in the region where the groove is formed is different from that of the other region. It gets worse compared. As a result, the insulating film around the groove tends to crack or peel off. When cracks or peeling occurs in the insulating film, rust is likely to occur in the steel sheet.
- a laser irradiation method is employ
- adopted as a magnetic domain control method of a grain-oriented electrical steel sheet there exists a problem that the rust resistance of a grain-oriented electrical steel sheet falls.
- the present invention has been made in view of the above problems, and an object thereof is to improve the rust resistance of a grain-oriented electrical steel sheet in which grooves are formed on the surface of the steel sheet for magnetic domain fragmentation.
- a grain-oriented electrical steel sheet according to an aspect of the present invention includes a steel sheet having a steel sheet surface extending in a direction intersecting with the rolling direction and having a groove in which a groove depth direction is a sheet thickness direction.
- the arithmetic average height Ra of the roughness curve defining the groove bottom region of the groove is 1 ⁇ m or more and 3 ⁇ m or less
- the average length RSm of the roughness curve element forming the contour of the groove bottom region is 10 ⁇ m or more and 150 ⁇ m or less.
- the grain-oriented electrical steel sheet further comprises an insulating film, and when the groove is viewed in a groove short cross section perpendicular to the groove extending direction, the groove short cross section starts from the boundary between the groove and the steel sheet surface.
- the region of 10 ⁇ m or more and 500 ⁇ m or less is defined as the particle existence region in the direction perpendicular to the plate thickness direction and away from the groove, the insulating film in the particle existence region has an equivalent circle diameter of 0.1 ⁇ m or more and 2 ⁇ m.
- the ratio of the area of the iron-containing particles to the area of the particle-containing region is 0.1% or more and less than 30%, and the chemical component of the iron-containing particles is 80 to 100% by mass Fe, 0 to 10% by mass of Si, and 0 to 10% by mass of Mg.
- the grain-oriented electrical steel sheet according to (1) may further include a glass film between the steel sheet and the insulating film.
- the Mg content in the glass film and the insulating film satisfying 1.3 times or more on average
- the region is defined as an Mg-concentrated region
- the Mg-concentrated region starts from the boundary between the groove and the steel plate surface when the groove is viewed in a short cross section perpendicular to the groove extending direction.
- the groove may be included in a region of 0.1 ⁇ m or more and 10 ⁇ m or less in a direction perpendicular to the plate thickness direction and away from the groove in the short cross section of the groove.
- the Mg concentrated region is continuously present along the groove extending direction, or a plurality of the Mg concentrated regions are along the groove extending direction.
- the distance between the Mg concentration regions adjacent to each other along the groove extending direction may be more than 0 and not more than 100 ⁇ m.
- the glass film having an average thickness of 0 ⁇ m to 5 ⁇ m and the insulating film having an average thickness of 1 ⁇ m to 5 ⁇ m are formed on the groove.
- the glass film having an average thickness of 0.5 ⁇ m or more and 5 ⁇ m or less and the insulating film having an average thickness of 1 ⁇ m or more and 5 ⁇ m or less are formed on the steel plate, and the glass film is formed on the groove.
- the average thickness of the glass coating may be thinner than the average thickness of the glass coating formed on the steel plate.
- the grain size of crystal grains in contact with the grooves may be 5 ⁇ m or more in the steel sheet.
- FIG. 1 is a plan view of a grain-oriented electrical steel sheet 1 according to an embodiment of the present invention.
- FIG. 2 is a cross-sectional view taken along the line AA in FIG. 1 (a view of the groove 5 in a cross section including the groove extending direction).
- FIG. 6 is a cross-sectional view taken along line BB in FIG. 1 (a view of the groove 5 in a cross section orthogonal to the groove extending direction).
- FIG. 6 is a first explanatory diagram regarding the definition of a groove reference line BL of the groove 5.
- 12 is a second explanatory diagram regarding the definition of the groove reference line BL of the groove 5.
- FIG. 10 is a third explanatory diagram regarding the definition of the groove reference line BL of the groove 5.
- FIG. 10 is a fourth explanatory diagram regarding the definition of the groove reference line BL of the groove 5.
- FIG. 7 is a cross-sectional view taken along the line CC of FIG. 6 and is an explanatory diagram regarding the definition of the groove bottom region 5a of the groove 5. It is a schematic diagram which shows the roughness curve RC which comprises the outline of the groove bottom area
- FIG. 7 is a cross-sectional view taken along the line EE in FIG. 6 and is an explanatory diagram relating to the definition of the groove region 5b, the steel plate region 2b, the particle existence region W1, and the Mg concentration region W2. It is a schematic diagram which shows Mg concentration area
- FIG. 3 is a flowchart showing a manufacturing process of the grain-oriented electrical steel sheet 1. It is 1st explanatory drawing regarding laser irradiation process S08 in the manufacturing process of grain-oriented electrical steel sheet 1.
- FIG. It is 2nd explanatory drawing regarding laser irradiation process S08 in the manufacturing process of grain-oriented electrical steel sheet 1.
- FIG. It is 3rd explanatory drawing regarding laser irradiation process S08 in the manufacturing process of grain-oriented electrical steel sheet 1.
- FIG. 1 is a plan view of a grain-oriented electrical steel sheet 1 according to the present embodiment.
- 2 is a cross-sectional view taken along line AA in FIG. 3 is a cross-sectional view taken along the line BB in FIG. 1 to 3
- the rolling direction of the grain-oriented electrical steel sheet 1 is X
- the sheet width direction of the grain-oriented electrical steel sheet 1 is Y
- the grain-oriented electrical steel sheet 1 The thickness direction (direction orthogonal to the XY plane) is defined as Z.
- the grain orientation of the grain-oriented electrical steel sheet 1 is controlled so that the easy axis of crystal grains coincides with the rolling direction X by a combination of cold rolling and annealing.
- a steel plate (ground iron) 2, a glass coating 3 formed on the surface of the steel plate 2 (steel plate surface 2 a), and an insulating coating 4 formed on the surface of the glass coating 3 are provided.
- FIG. 1 a plurality of grooves 5 extending in a direction intersecting the rolling direction X and having a groove depth direction coinciding with the sheet thickness direction Z are formed on the steel plate surface 2a for magnetic domain subdivision. It is formed at predetermined intervals along the rolling direction X. That is, FIG. 2 is a view of one groove 5 as seen in a cross section including the groove extending direction and the plate thickness direction Z. FIG. 3 is a view of one groove 5 as seen in a cross section perpendicular to the groove extending direction.
- channel 5 should just be provided so that the rolling direction X may be crossed, and the groove extension direction and the rolling direction X do not necessarily need to be orthogonal.
- the groove extending direction and the rolling direction X are orthogonal to each other is illustrated for convenience of explanation.
- the groove 5 may have an arcuate shape when viewed from the plate thickness direction Z (when the groove 5 is viewed in plan).
- channel 5 which has a linear shape is illustrated for convenience of explanation.
- Steel plate 2 has chemical fractions of mass fractions of Si: 0.8% to 7%, C: more than 0% to 0.085%, acid-soluble Al: 0% to 0.065%, N: 0% 0.012%, Mn: 0% to 1%, Cr: 0% to 0.3%, Cu: 0% to 0.4%, P: 0% to 0.5%, Sn: 0% to 0% .3%, Sb: 0% to 0.3%, Ni: 0% to 1%, S: 0% to 0.015%, Se: 0% to 0.015%, with the balance being Fe and Consists of impurities.
- the chemical component of the steel sheet 2 is a preferable chemical component for controlling the Goss texture in which the crystal orientation is accumulated in the ⁇ 110 ⁇ ⁇ 001> orientation.
- Si and C are basic elements
- acid-soluble Al, N, Mn, Cr, Cu, P, Sn, Sb, Ni, S, and Se are selective elements. Since the above-mentioned selective element may be contained according to the purpose, it is not necessary to limit the lower limit value, and the lower limit value may be 0%. Even if these selective elements are contained as impurities, the effect of the present embodiment is not impaired.
- the balance of the basic element and the selective element may be made of Fe and impurities.
- an impurity means the element mixed unavoidable from the ore as a raw material, a scrap, or a manufacturing environment, when manufacturing the steel plate 2 industrially.
- a magnetic steel sheet it is common for a magnetic steel sheet to undergo purification annealing during secondary recrystallization.
- the purification annealing the inhibitor forming elements are discharged out of the system.
- the decrease in the concentration is remarkable, and it becomes 50 ppm or less. Under normal purification annealing conditions, 9 ppm or less, further 6 ppm or less. If the purification annealing is sufficiently performed, it reaches a level that cannot be detected by general analysis (1 ppm or less).
- the chemical composition of the steel plate 2 may be measured by a general steel analysis method.
- the chemical component of the steel plate 2 may be measured using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry). Specifically, by measuring a 35 mm square test piece from the central position of the steel plate 2 after removal of the film with ICPS-8100 manufactured by Shimadzu Corporation (measuring device) under conditions based on a calibration curve prepared in advance. Can be identified. C and S may be measured using a combustion-infrared absorption method, and N may be measured using an inert gas melting-thermal conductivity method.
- ICP-AES Inductively Coupled Plasma-Atomic Emission Spectrometry
- the glass film 3 is made of, for example, a composite oxide such as forsterite (Mg 2 SiO 4 ), spinel (MgAl 2 O 4 ), or cordierite (Mg 2 Al 4 Si 5 O 16 ).
- the glass coating 3 is a coating formed to prevent seizure from occurring in the steel plate 2 in the finish annealing step, which is one of the manufacturing processes of the grain-oriented electrical steel plate 1. Therefore, the glass coating 3 is not an essential element as a component of the grain-oriented electrical steel sheet 1.
- the insulating film 4 contains, for example, colloidal silica and phosphate, and plays a role of giving the steel sheet 2 not only electrical insulation but also tension, corrosion resistance, heat resistance, and the like.
- the glass film 3 and the insulating film 4 of the grain-oriented electrical steel sheet 1 can be removed by the following method, for example.
- the grain-oriented electrical steel sheet 1 having the glass coating 3 or the insulating coating 4 is immersed in a NaOH aqueous solution of NaOH: 10% by mass + H 2 O: 90% by mass at 80 ° C. for 15 minutes.
- a sulfuric acid aqueous solution of H 2 SO 4 10% by mass + H 2 O: 90% by mass at 80 ° C. for 3 minutes.
- the substrate is dipped and washed with a nitric acid aqueous solution of HNO 3 : 10% by mass + H 2 O: 90% by mass for 1 minute at room temperature.
- the grain-oriented electrical steel sheet 1 has the following three configurations A, B, C, and D as characteristic configurations for improving rust resistance.
- A The values of the surface roughness parameters (Ra, RSm) indicating the surface roughness of the groove bottom region of the groove 5 are within a predetermined range.
- B It is preferable that the insulating film 4 contains iron-containing particles.
- C In the glass coating 3 and the insulating coating 4, it is preferable that an Mg concentration region exists along the groove extending direction at a position adjacent to the groove 5.
- D In the steel plate 2, the grain size of the crystal grains in contact with the groove 5 is preferably 5 ⁇ m or more.
- the average length RSm of the roughness curve element forming the outline of the groove bottom region 5a is 10 ⁇ m or more and 150 ⁇ m or less, preferably 40 ⁇ m or more and 145 ⁇ m or less, more preferably 60 ⁇ m or more and 140 ⁇ m or less. It is.
- the groove bottom region 5a has a certain degree of roughness, and therefore the adhesion between the steel plate 2 and the glass coating 3 or the insulating coating 4 is achieved by the anchor effect. improves. For this reason, cracks or peeling hardly occur in the glass coating 3 or the insulating coating 4 around the groove 5. As a result, the rust resistance of the grain-oriented electrical steel sheet 1 in which the grooves 5 are formed on the surface of the steel sheet 2 for magnetic domain refinement is improved.
- the depth of the groove 5 is not necessarily constant in the width direction of the groove 5. Therefore, it is necessary to clarify the groove bottom region 5a when the groove 5 is viewed in the longitudinal section of the groove. Below, an example of the identification method of the groove bottom area
- the observation range 50 is set to a part of the groove 5, and a plurality of grooves are provided along the groove extending direction.
- (N) virtual lines L 1 to Ln are virtually set within the observation range 50.
- the observation range 50 is desirably set in a region excluding an end in the extending direction of the groove 5 (that is, a region where the shape of the groove bottom is stable).
- the observation range 50 may be an observation region whose length in the groove extending direction is about 300 ⁇ m.
- the band-pass filters (cut-off values ⁇ f and ⁇ c) are applied to the cross-sectional curve.
- a wavy curve LWC1 that forms the contour in the groove extending direction of the groove 5 is obtained along the virtual line L1, as shown in FIG. 5B.
- the waviness curve is a kind of contour curve together with the roughness curve described later.
- the roughness curve is particularly suitable for accurately indicating the surface roughness of the contour, whereas the waviness curve is a contour curve. It is a contour curve suitable for simplifying the shape itself with a smooth line.
- the plate thickness between the steel plate surface 2a and the contour of the groove 5 (that is, the waviness curve LWC1) at each of a plurality of (m) positions along the virtual line L1.
- a distance in the direction Z (depth d1 to dm: unit is ⁇ m) is obtained.
- an average value of these depths d1 to dm (groove average depth D1) is obtained.
- the groove average depths D2 to Dn are obtained for each of the other virtual lines L2 to Ln.
- the position (height) of the steel plate surface 2a in the Z direction is measured for each of a plurality of locations on the steel plate surface 2a within the observation range 50 using a laser-type surface roughness measuring instrument, and the average value of the measurement results is determined as the steel plate surface 2a. You may use as the height of.
- a virtual line that satisfies the condition that the groove average depth is maximized along the groove extending direction is selected as the groove reference line BL.
- the average groove depth of the groove reference line BL is defined as the groove depth D (unit: ⁇ m) of the groove 5.
- the virtual line L3 is connected to the groove reference line BL.
- the groove average depth D3 of the imaginary line L3 is defined as the groove depth D of the groove 5.
- the groove depth D of the groove 5 in this embodiment is preferably 5 ⁇ m or more and 40 ⁇ m or less in order to obtain the effect of magnetic domain subdivision preferably.
- the groove width W of the groove 5 in this embodiment is preferably 10 ⁇ m to 250 ⁇ m.
- the groove width W is such that the depth from the steel plate surface 2a toward the surface of the groove 5 in the plate thickness direction Z on the undulation curve of the groove 5 in the groove short cross section perpendicular to the groove extending direction is the groove depth of the groove 5 What is necessary is just to obtain
- FIG. 7 is a cross-sectional view taken along the line CC of FIG. That is, FIG. 7 is a view of the groove 5 in a groove longitudinal section including the groove reference line BL and the plate thickness direction Z.
- the outline of the groove 5 that appears in the observation range 50 is defined as the groove bottom region 5 a. Define.
- the groove bottom region 5a of the groove 5 is specified by the above method. That is, in the present embodiment, as shown in FIG. 8, it is obtained by converting the measurement cross section curve that forms the contour of the groove bottom region 5 a of the groove 5 that appears in the groove longitudinal section including the groove reference line BL and the plate thickness direction Z.
- the arithmetic average height Ra of the roughness curve RC is 1 ⁇ m or more and 3 ⁇ m or less, preferably 1.2 ⁇ m or more and 2.5 ⁇ m or less, more preferably 1.3 ⁇ m or more and 2.3 ⁇ m or less.
- the average length RSm of the roughness curve element obtained by converting the measurement cross-sectional curve forming the contour of the region 5a is 10 ⁇ m or more and 150 ⁇ m or less, preferably 40 ⁇ m or more and 145 ⁇ m or less, more preferably 60 ⁇ m or more and 140 ⁇ m or less. It is.
- the roughness curve RC is obtained by applying a low-pass filter having a cutoff value ⁇ s to the measured cross-sectional curve obtained for the groove reference line BL, and then obtaining a high-pass filter (cut-off value ⁇ c) on the cross-sectional curve. Is applied to remove a long wavelength component from the cross-sectional curve.
- the definitions of the arithmetic average height Ra of the roughness curve RC and the average length RSm of the roughness curve element conform to Japanese Industrial Standards JIS B0601 (2013).
- the insulating film 4 in the particle existence region W1 includes iron-containing particles 6 having a circle-equivalent diameter of 0.1 ⁇ m or more and 2 ⁇ m or less.
- the ratio of the area of the iron-containing particles 6 to the area of the particle existence region W1 is 0.1% or more and less than 30%.
- the area of the iron-containing particles 6 is the total value (total area) of the areas (surface areas of the particles) of the iron-containing particles 6 present in a plurality in the particle existence region W1 of the insulating coating 4.
- the ratio of the area of the iron-containing particles 6 to the area of the particle-existing region W1 is 0.1% or more, the strength of the insulating film 4 is increased and the cracking of the insulating film 4 due to cracks is reduced.
- the rust resistance of the electromagnetic steel sheet 1 is improved. Therefore, the ratio of the area of the iron-containing particles 6 to the area of the particle existence region W1 is preferably 0.1% or more.
- the ratio of the area of the iron-containing particles 6 to the area of the particle existence region W1 exceeds 30%, the conductivity due to iron increases, and the short-circuit current flows due to the lower interlayer resistance, and the vortex of the grain-oriented electrical steel sheet 1 Current loss increases.
- the ratio of the area of the iron-containing particles 6 to the area of the particle existence region W1 is preferably less than 30%.
- the iron-containing particles 6 contain 80% or more and 100% or less iron by mass fraction.
- the iron-containing particles 6 may further contain 0% or more and 10% or less Si and 0% or more and 10% or less Mg by mass fraction.
- the width of the particle existence region W1 satisfies the above range and the equivalent circle diameter and area of the iron-containing particles 6 satisfy the above range, the strength of the insulating film 4 in the particle existence region W1 is improved. Insulating film 4 is less likely to crack or peel off. As a result, the rust resistance of the grain-oriented electrical steel sheet 1 in which the grooves 5 are formed on the surface of the steel sheet 2 for magnetic domain refinement is further improved.
- FIG. 9 is a cross-sectional view taken along line EE in FIG. That is, FIG. 9 is a view of the groove 5 as viewed in a short cross section perpendicular to the groove extending direction.
- the measurement cross section curve that forms the outline of the groove 5 appearing in the groove short cross section is converted into a wavy curve as a groove short wavy curve SWC.
- a virtual line Ls orthogonal to the groove reference line BL is virtually set in the XY plane, and the surface roughness of the steel plate 2 including the groove 5 is measured using a laser type surface roughness measuring instrument or the like. Is measured along the imaginary line Ls, a measurement cross-sectional curve that forms the contour of the groove 5 in the short cross section of the groove is obtained along the imaginary line Ls.
- the groove short wave undulation curve SWC appearing in the groove short cross section is obtained by applying a low-pass filter (cutoff value ⁇ s) to the measurement cross sectional curve obtained for the virtual line Ls as described above, This is obtained by applying band-pass filters (cut-off values ⁇ f and ⁇ c) to the cross-sectional curve and removing the long wavelength component and the short wavelength component from the cross-sectional curve.
- a low-pass filter cutoff value ⁇ s
- band-pass filters cut-off values ⁇ f and ⁇ c
- a distance (depth f1 to fp: unit is ⁇ m) in the thickness direction Z between the five contours (that is, the groove short swell curve SWC) is obtained.
- a region satisfying the following conditional expression (2) is defined as a groove region 5b, and a region other than the groove region 5b is defined as a steel plate region 2b. To do.
- a boundary between the groove region 5b and the steel plate region 2b is specified as a boundary G between the groove 5 and the steel plate surface 2a.
- the width of the groove region 5b corresponds to the groove width W.
- the Mg content is 1.3 times or more on average.
- a region that satisfies the above is defined as an Mg-enriched region W2.
- the Mg concentration region W2 is the boundary G between the groove 5 and the steel plate surface 2a. Is included in the region of 0.1 ⁇ m or more and 10 ⁇ m or less in the direction perpendicular to the plate thickness direction Z and away from the groove 5 in the short cross section of the groove.
- the average Mg content in the mass fraction of the glass coating 3 and the insulating coating 4 in the Mg concentration region W2 shown in FIG. 3 is the average Mg content in the mass fraction contained in the glass coating 3 and the insulating coating 4. Is 1.3 times or more.
- the boundary between the groove region 5b and the steel plate region 2b is specified as the boundary G between the groove 5 and the steel plate surface 2a (see FIG. 9).
- the groove 5 when the groove 5 is viewed from the plate thickness direction Z (when the groove 5 is viewed in plan), a plurality of the Mg enriched regions W2 exist along the groove extending direction. .
- the distance dw between the Mg enriched regions W2 adjacent to each other along the groove extending direction is more than 0 and not more than 100 ⁇ m.
- the Mg enriched region W2 may exist continuously along the groove extending direction.
- the Mg content can be measured using EPMA (Electron Probe Micro Micro Analyzer) or the like.
- the width of the Mg concentrated region W2 is included in the above range, and the distance dw between the Mg concentrated regions W2 adjacent to each other is included in the above range, whereby the insulating film 4 and the surface of the steel plate 2 are firmly bonded. As a result, cracks or delamination is unlikely to occur in the insulating film 4 around the groove 5. As a result, the rust resistance of the grain-oriented electrical steel sheet 1 in which the grooves 5 are formed on the surface of the steel sheet 2 for magnetic domain refinement is further improved.
- the average grain size of the crystal grains in contact with the groove 5 is 5 ⁇ m or more.
- the crystal grain size in contact with the groove 5 becomes fine. In this case, there is a high possibility that the crystal orientation will eventually deviate from the ⁇ 110 ⁇ ⁇ 001> orientation, and there is a high possibility that favorable magnetic properties will not be obtained. Therefore, it is preferable that there is no melt-solidified region around the groove 5.
- the average grain size of the crystal grains (secondary recrystallized grains) in contact with the groove 5 is 5 ⁇ m or more.
- the upper limit of the grain size of the crystal grains in contact with the groove 5 is not particularly limited, but the upper limit may be 100 ⁇ 10 3 ⁇ m or less.
- the grain size of the crystal grains means a circle equivalent diameter.
- the crystal grain size may be obtained by a general crystal grain size measurement method such as ASTM E112, or may be obtained by an EBSD (Electron Back Scattering Diffraction Pattern) method.
- the crystal grains in contact with the groove 5 may be observed in the groove short cross section or a cross section perpendicular to the plate thickness direction Z.
- the groove 5 having no melt-solidified region can be obtained by, for example, a manufacturing method described later.
- the glass film 3 does not exist in the groove
- a glass coating 3 having an average thickness of more than 0 ⁇ m and 5 ⁇ m or less and an insulating coating 4 having an average thickness of 1 ⁇ m or more and 5 ⁇ m or less may be arranged in the groove 5.
- a glass coating 3 having an average thickness of 0.5 ⁇ m or more and 5 ⁇ m or less and an insulating coating 4 having an average thickness of 1 ⁇ m or more and 5 ⁇ m or less may be disposed on the steel plate surface 2a (steel plate region 2b).
- the average thickness of the glass coating 3 in the groove 5 may be thinner than the average thickness of the glass coating 3 on the steel plate surface 2a.
- the thicknesses of the glass coating 3 and the insulating coating 4 As described above, by setting the thicknesses of the glass coating 3 and the insulating coating 4, cracking or peeling is less likely to occur in the insulating coating 4 around the groove 5. Will be improved. Further, by adopting a configuration in which the glass coating 3 does not exist in the groove 5 (that is, a configuration in which the average thickness of the glass coating 3 in the groove 5 is 0 ⁇ m), the distance (groove width) between the walls of the grooves facing each other can be reduced. Since it can be made narrower, the magnetic domain refinement effect (that is, the effect of reducing abnormal eddy current loss) by the groove 5 can be further improved.
- the directional electromagnetic steel plate 1 provided with the glass film 3 was illustrated, since the glass film 3 is not an essential component as mentioned above, the direction comprised only with the steel plate 2 and the insulating film 4 The effect of improving rust resistance can also be obtained by applying the present invention to the refractory electrical steel sheet.
- the insulating coating 4 having an average thickness of 1 ⁇ m or more and 5 ⁇ m or less is disposed in the groove 5 (groove region 5b), and the steel plate surface 2a (steel plate region 2b).
- an insulating film 4 having an average thickness of 1 ⁇ m or more and 5 ⁇ m or less may be disposed.
- FIG. 11 is a flowchart showing a manufacturing process of the grain-oriented electrical steel sheet 1.
- Si 0.8% to 7%
- C more than 0% to 0.085%
- acid-soluble Al 0% to 0.065 %
- N 0% to 0.012%
- Mn 0% to 1%
- Cr 0% to 0.3%
- Cu 0% to 0.4%
- P 0% to 0.5%
- Sn 0% to 0.3%
- Sb 0% to 0.3%
- Se 0% to 0.015%
- the molten steel which has a chemical component which the remainder consists of Fe and an impurity is supplied to a continuous casting machine, and a slab is produced continuously.
- the slab obtained from the casting step S01 is heated to a predetermined temperature (for example, 1150 to 1400 ° C.), and then hot rolling is performed on the slab.
- a predetermined temperature for example, 1150 to 1400 ° C.
- the hot-rolled steel sheet obtained from the hot rolling step S02 is annealed under a predetermined temperature condition (for example, a condition of heating at 750 to 1200 ° C. for 30 seconds to 10 minutes).
- a predetermined temperature condition for example, a condition of heating at 750 to 1200 ° C. for 30 seconds to 10 minutes.
- the cold rolling process S04 after the pickling process is performed on the surface of the hot-rolled steel sheet subjected to the annealing process in the annealing process S03, the hot-rolled steel sheet is cold-rolled. Thereby, for example, a cold-rolled steel sheet having a thickness of 0.15 to 0.35 mm is obtained.
- the cold-rolled steel sheet obtained from the cold rolling step S04 is heat-treated under a predetermined temperature condition (for example, a condition of heating at 700 to 900 ° C. for 1 to 3 minutes). That is, decarburization annealing treatment is performed. If such a decarburization annealing process is implemented, in a cold-rolled steel plate, carbon will be reduced to a predetermined amount or less, and a primary recrystallized structure will be formed.
- a predetermined temperature condition for example, a condition of heating at 700 to 900 ° C. for 1 to 3 minutes. That is, decarburization annealing treatment is performed. If such a decarburization annealing process is implemented, in a cold-rolled steel plate, carbon will be reduced to a predetermined amount or less, and a primary recrystallized structure will be formed.
- an oxide layer containing silica (SiO 2 ) as a main component is formed on the surface of the cold rolled steel sheet.
- an annealing separator containing magnesia (MgO) as a main component is applied to the surface of the cold rolled steel sheet (the surface of the oxide layer).
- the finish annealing step S07 the cold-rolled steel sheet coated with the annealing separator is subjected to a heat treatment (ie, finishing at a temperature of 1100 to 1300 ° C. for 20 to 24 hours) under a predetermined temperature condition. Annealing treatment is performed. When such a finish annealing treatment is performed, secondary recrystallization occurs in the cold-rolled steel sheet, and the cold-rolled steel sheet is purified.
- the cold-rolled steel sheet that is, the groove 5 of the grain-oriented electrical steel sheet 1 having the chemical composition of the steel sheet 2 and the crystal orientation controlled so that the easy axis of crystal grains and the rolling direction X coincide with each other.
- a steel plate 2) in a state before formation is obtained.
- the oxide layer containing silica as a main component reacts with an annealing separator containing magnesia as a main component, so that forsterite ( A glass film 3 containing a complex oxide such as Mg 2 SiO 4 ) is formed.
- the finish annealing process is performed in a state where the steel plate 2 is wound in a coil shape.
- the surface of the steel plate 2 on which the glass coating 3 is formed (only one side) is irradiated with laser to thereby extend the surface of the steel plate 2 in a direction intersecting the rolling direction X.
- the grooves 5 are formed at predetermined intervals along the rolling direction X.
- the laser YL emitted from the laser light source (not shown) is transmitted to the laser irradiation apparatus 10 through the optical fiber 9.
- the laser irradiation device 10 incorporates a polygon mirror and its rotation drive device (both not shown).
- the laser irradiation device 10 irradiates the surface of the steel plate 2 with the laser YL by rotating the polygon mirror, and scans the laser YL substantially parallel to the plate width direction Y of the steel plate 2.
- an assist gas 25 such as air or an inert gas is blown onto the portion of the steel plate 2 to be irradiated with the laser YL.
- the inert gas is, for example, nitrogen or argon.
- the assist gas 25 has a role of removing components scattered or evaporated from the steel plate 2 by laser irradiation. By blowing the assist gas 25, the laser YL reaches the steel plate 2 without being inhibited by the scattered or evaporated components, so that the grooves 5 are stably formed. Moreover, it can suppress that the said component adheres to the steel plate 2 by spraying of the assist gas 25. FIG. As a result, the groove 5 is formed along the scanning line of the laser YL.
- the surface of the steel plate 2 is irradiated with the laser YL while the steel plate 2 is conveyed along the sheet passing direction that coincides with the rolling direction X.
- the rotation speed of the polygon mirror is synchronously controlled with respect to the conveying speed of the steel plate 2 so that the grooves 5 are formed at a predetermined interval PL along the rolling direction X.
- a plurality of grooves 5 intersecting the rolling direction X are formed on the surface of the steel plate 2 at a predetermined interval PL along the rolling direction X.
- a fiber laser can be used as the laser light source.
- a high-power laser generally used for industrial use such as a YAG laser, a semiconductor laser, or a CO 2 laser, may be used as the laser light source.
- a pulse laser or a continuous wave laser may be used as a laser light source as long as the groove 5 can be stably formed.
- the laser YL it is preferable to use a single mode laser which has a high light condensing property and is suitable for forming a groove.
- the laser output is 200 W to 2000 W
- the focused spot diameter in the rolling direction X of the laser YL (that is, the diameter including 86% of the laser output, hereinafter abbreviated as 86% diameter) is 10 ⁇ m to
- the focused spot diameter (86% diameter) in the plate width direction Y of the laser YL is 10 ⁇ m to 1000 ⁇ m
- the laser scanning speed is 5 m / s to 100 m / s
- the laser scanning pitch (interval PL) is 2 mm to 10 mm. It is preferable to set to.
- These laser irradiation conditions may be adjusted as appropriate so that a desired groove depth D can be obtained. For example, in order to obtain a deep groove depth D, the laser scanning speed may be set slower and the laser output may be set higher.
- the laser scanning direction SD plate of the laser YL
- the assist gas 25 is injected from the direction having the inclination of the first angle ⁇ 1 with respect to the width direction Y) so as to follow the laser YL.
- FIG. 13B when the steel plate 2 conveyed along the plate passing direction TD is viewed from the plate width direction Y (laser scanning direction SD), the inclination of the second angle ⁇ 2 with respect to the steel plate surface 2a is increased.
- the assist gas 25 is jetted from the direction of holding so as to follow the laser YL.
- the first angle ⁇ 1 is preferably set in the range of 90 ° to 180 °
- the second angle ⁇ 2 is preferably set in the range of 1 ° to 85 °.
- the flow rate of the assist gas 25 is preferably set in the range of 10 to 1000 liters per minute.
- the surface roughness (Ra, RSm) of the groove bottom region 5a can be accurately controlled by setting the first angle ⁇ 1, which is the assist gas injection angle with respect to the laser scanning direction, within the above range.
- the surface roughness (especially RSm) of the groove bottom region 5a can be controlled with higher accuracy by setting the number of particles having a diameter of 0.5 ⁇ m or more present in the through-plate atmosphere within the above range. .
- the range and interval dw of the Mg enriched region W2 can be accurately controlled.
- the second angle ⁇ 2 that is the assist gas injection angle with respect to the steel plate surface 2a within the above range, the range of the particle existence region W1, the equivalent circle diameter and the area of the iron-containing particles 6 can be controlled with high accuracy.
- the flow rate of the assist gas 25 and the flow through atmosphere By defining the amount of particles, not only the surface roughness (Ra, RSm) of the groove bottom region 5a, but also the range and interval dw of the Mg concentrated region W2, the range of the particle existing region W1, and the circle equivalent to the iron-containing particles 6 It has been found that the diameter and area can be accurately controlled.
- the method for producing a grain-oriented electrical steel sheet according to this embodiment is a novel production method that cannot be predicted by those skilled in the art. It has new configurations A, B, C and D that cannot be expected.
- a plurality of laser irradiation devices 10 are used. You may form the groove
- an insulating material containing colloidal silica and phosphate is applied to the steel plate surface 2a on which the groove 5 is formed by the laser irradiation step S08.
- a coating solution is applied from above the glass coating 3.
- heat treatment is performed under a predetermined temperature condition (for example, 840 to 920 ° C.), and finally, the steel plate 2, the glass coating 3 and the groove 5 are formed as shown in FIGS.
- a grain-oriented electrical steel sheet 1 having an insulating film 4 and having configurations A, B, C, and D is obtained.
- the steel sheet 2 of the grain-oriented electrical steel sheet 1 manufactured as described above has, as chemical components, mass ratios of Si: 0.8% to 7%, C: more than 0% to 0.085%, acid-soluble Al. : 0% to 0.065%, N: 0% to 0.012%, Mn: 0% to 1%, Cr: 0% to 0.3%, Cu: 0% to 0.4%, P: 0 % To 0.5%, Sn: 0% to 0.3%, Sb: 0% to 0.3%, Ni: 0% to 1%, S: 0% to 0.015%, Se: 0% to 0.015%, with the balance being Fe and impurities.
- the manufacturing process of forming the grooves 5 on the steel plate surface 2a by laser irradiation before the insulating coating 4 is formed on the steel plate surface 2a and then forming the insulating coating 4 on the steel plate surface 2a is performed.
- adopts was illustrated.
- the laser beam YL is irradiated from above the insulating coating 4 toward the steel plate surface 2a, thereby forming the grooves 5 on the steel plate surface 2a. You may employ
- the glass film 3 or the insulating film 4 may be formed.
- the grain-oriented electrical steel sheet according to the present embodiment includes the grain-oriented electrical steel sheet 1 in which the high-temperature annealing for secondary recrystallization is completed and the coating of the glass film 3 and the insulating film 4 is completed. Further, the grain-oriented electrical steel sheet before the coating of the glass film 3 or the insulating film 4 is completed and after the grooves 5 are formed is also included. That is, you may obtain a final product by forming the glass film 3 or the insulating film 4 as a post process using the grain-oriented electrical steel sheet which concerns on this embodiment.
- the shape and roughness of the groove 5 are as follows. It is confirmed that the glass film 3 or the insulating film 4 is the same as before.
- laser irradiation process S08 was implemented after finish annealing process S07 was illustrated in the said embodiment, you may implement a laser irradiation process between cold rolling process S04 and decarburization annealing process S05. . That is, by performing laser irradiation and assist gas injection on the cold-rolled steel sheet obtained from the cold rolling step S04, grooves 5 are formed on the steel sheet surface 2a of the cold-rolled steel sheet, and then removed from the cold-rolled steel sheet. Charcoal annealing may be performed.
- the conditions in the examples are one example of conditions adopted for confirming the feasibility and effects of the present invention.
- the invention is not limited to this one condition example.
- the present invention can adopt various conditions as long as the object of the present invention is achieved without departing from the gist of the present invention.
- the grain-oriented electrical steel sheet used in this verification 1 was manufactured as follows. By mass fraction, Si: 3.0%, C: 0.08%, acid-soluble Al: 0.05%, N: 0.01%, Mn: 0.12%, Cr: 0.05%, Cu : 0.04%, P: 0.01%, Sn: 0.02%, Sb: 0.01%, Ni: 0.005%, S: 0.007%, Se: 0.001% And the hot rolling was implemented with respect to the slab which has a chemical component which the remainder consists of Fe and an impurity, and the hot-rolled steel plate of thickness 2.3mm was obtained.
- the above-described hot-rolled steel sheet was annealed under a temperature condition of heating at 1000 ° C. for 1 minute. After the pickling treatment was performed on the surface of the hot-rolled steel sheet that had been annealed, the hot-rolled steel sheet was cold-rolled to obtain a cold-rolled steel sheet having a thickness of 0.23 mm. Subsequently, after the decarburization annealing treatment is performed under the temperature condition of heating at 800 ° C. for 2 minutes with respect to the cold-rolled steel sheet, an annealing separator containing magnesia (MgO) as a main component, It was applied to the surface of the cold rolled steel sheet.
- MgO magnesia
- a finish annealing treatment was performed on the cold-rolled steel sheet coated with the annealing separator under a temperature condition of heating at 1200 ° C. for 20 hours.
- a cold-rolled steel sheet (steel sheet having a glass coating formed on the surface) having the above-described chemical composition and controlled in crystal orientation so that the easy axis of crystal grains and the rolling direction coincide with each other was obtained.
- the laser output is set to 200 to 2000 W
- the focused spot diameter (86% diameter) in the laser rolling direction is set to 10 to 1000 ⁇ m
- % Diameter was set to 10 to 4000 ⁇ m
- the laser scanning speed was set to 1 to 100 m / s
- the laser scanning pitch was set to 4 to 10 mm.
- the assist gas was sprayed on the part of the steel plate irradiated with the laser.
- the assist gas injection angle (first angle ⁇ 1) with respect to the laser scanning direction, the assist gas injection angle (second angle ⁇ 2) with respect to the steel plate surface, and the flow rate of the assist gas were adjusted so as to satisfy the above conditions 1 and 2.
- the first angle ⁇ 1 was adjusted in the range of 90 ° to 180 °.
- the second angle ⁇ 2 was adjusted in the range of 1 ° to 85 °.
- the assist gas flow rate was adjusted in the range of 10 to 1000 liters per minute.
- the atmosphere was controlled so that the number of particles having a diameter of 0.5 ⁇ m or more present in the through-plate atmosphere at the time of laser irradiation was 10 or more and less than 10,000 per 1 CF.
- the insulating coating liquid containing colloidal silica and phosphate is applied from above the glass film to the steel sheet in which the grooves are formed, it is heated at 850 ° C. for 1 minute. In the end, a grain-oriented electrical steel sheet provided with a steel sheet having a groove, a glass film and an insulating film was obtained.
- the groove bottom region of the groove was specified by the specifying method described in the above embodiment.
- the surface roughness parameters (Ra, RSm) indicating the surface roughness of the groove bottom region a laser surface roughness measuring instrument (VK-9700 manufactured by Keyence Corporation) was used.
- VK-9700 manufactured by Keyence Corporation was used for measurement of the surface roughness parameters (Ra, RSm) indicating the surface roughness of the groove bottom region.
- Each of the grain oriented electrical steel sheets corresponding to Examples 1 to 8 and Comparative Examples 1 to 4 was verified for rust resistance. Specifically, a 30 mm square test piece is collected from each grain-oriented electrical steel sheet, and the test piece is left in an atmosphere of a temperature of 50 ° C. and a humidity of 91% for one week, and the test piece before and after the test piece. The weight was evaluated based on the change in weight. Since the weight of the test piece increases when rust occurs, the smaller the weight increase, the better the rust resistance.
- the rust resistance of a test piece having a weight increase of 1.0 mg / m 2 or less is evaluated as “excellent”, and the rust resistance of a test piece having a weight increase of 5.0 mg / m 2 or less is evaluated.
- the test piece having a weight increase of more than 10.0 mg / m 2 was evaluated as “bad”.
- Table 1 as a result of verifying the rust resistance of the grain-oriented electrical steel sheets corresponding to Examples 1 to 8, by satisfying the above conditions 1 and 2 (that is, by adopting the configuration A), It was confirmed that the rust resistance of the grain-oriented electrical steel sheet was improved.
- the iron loss of Examples 1 to 8 having a rust resistance of “good” as a result of measuring the magnetic properties (iron loss W17 / 50) after the rust resistance test is 0.702 to 0. 0. 0. It was 822 W / kg.
- the iron loss of Comparative Example 1 in which the rust resistance was “poor” was 0.951 W / kg.
- the iron loss of Comparative Example 4 in which the rust resistance was “bad” was 0.794 W / kg.
- the grain size of the crystal grains in contact with the grooves in the steel sheet was 5 ⁇ m or more.
- the groove depth D was 5 ⁇ m or more and 40 ⁇ m or less
- the groove width W was 10 ⁇ m or more and 250 ⁇ m or less.
- Example 9 a grain-oriented electrical steel sheet satisfying the above conditions 1 and 2 and having no glass film was prepared as Example 9 using a known manufacturing method. Further, as Comparative Examples 5 to 7, grain oriented electrical steel sheets that did not satisfy at least one of the above conditions 1 and 2 and were not provided with a glass film were prepared. The chemical composition of the steel sheet is the same as in the above verification 1.
- the assist gas injection angle (first angle ⁇ 1) with respect to the laser scanning direction
- the assist gas injection angle (second angle ⁇ 2) with respect to the steel plate surface
- the assist gas injection angle (second angle ⁇ 2) with respect to the steel plate surface
- the flow rate of the gas 25 and the amount of particles in the through plate atmosphere were adjusted within the range described in the above embodiment.
- rust resistance was verified using the same verification method as in the above verification 1. As a result, as shown in Table 2, it was confirmed that the rust resistance was improved by adopting the configuration A satisfying the above conditions 1 and 2 even in the grain-oriented electrical steel sheet not provided with the glass film. It was.
- the iron loss of Example 9 in which the rust resistance was “good” was 0.832 W / kg.
- the iron loss of Comparative Example 5 in which the rust resistance was “poor” was 0.925 W / kg.
- the iron loss of Comparative Example 6 in which the rust resistance was “poor” was 0.736 W / kg.
- the groove depth D was 5 ⁇ m or more and 40 ⁇ m or less
- the groove width W was 10 ⁇ m or more and 250 ⁇ m or less.
- the distance dw between the Mg concentration regions adjacent to each other along the groove extending direction is greater than 0 and equal to or less than 100 ⁇ m.
- grain oriented electrical steel sheets satisfying the above conditions 1 and 2 and satisfying the above conditions 3 and 4 were prepared as Examples 10 to 18 by the same process as in the above verification 1.
- grain oriented electrical steel sheets that satisfy the above conditions 1 and 2 and do not satisfy at least one of the above conditions 3 and 4 were prepared.
- the assist gas injection angle (first angle ⁇ 1) with respect to the laser scanning direction, the assist gas injection angle (second angle ⁇ 2) with respect to the steel plate surface, and the assist gas so as to satisfy the above conditions 1 to 4 Were adjusted within the range described in the above embodiment.
- the arithmetic mean height Ra of the roughness curve defining the groove bottom region is 2.1 ⁇ m, and the roughness curve element defining the groove bottom region of the groove
- the average length RSm was 45 ⁇ m.
- channel were removed by brushing.
- Mg content was analyzed using EPMA.
- each of the grain-oriented electrical steel sheets corresponding to Examples 10 to 21 was verified for rust resistance using the same verification method as in Verification 1 above.
- Table 3 in addition to the above conditions 1 and 2, satisfying the above conditions 3 and 4 (that is, by adopting configurations A and C), the rust resistance of the grain-oriented electrical steel sheet It was confirmed that it improved further.
- the iron loss of Example 10 in which the rust resistance was “excellent” was 0.836 W / kg. .
- the iron loss of Example 19 whose rust resistance was "good” was 0.701 W / kg.
- the groove depth D was 5 ⁇ m or more and 40 ⁇ m or less
- the groove width W was 10 ⁇ m or more and 250 ⁇ m or less.
- the equivalent circle diameter of the iron-containing particles contained in the insulating film in the particle existence region is 0.1 ⁇ m or more and 2 ⁇ m or less, and the ratio of the area of the iron-containing particles to the area of the particle existence region is 0.1% or more and less than 30%. is there.
- grain oriented electrical steel sheets satisfying the above conditions 1 and 2 and satisfying the above conditions 5 and 6 were prepared as Examples 22 to 30 by the same process as in the above verification 1.
- grain oriented electrical steel sheets that satisfy the above conditions 1 and 2 and do not satisfy at least one of the above conditions 5 and 6 were prepared.
- the assist gas injection angle (first angle ⁇ 1) with respect to the laser scanning direction and the assist gas injection angle (second angle ⁇ 2) with respect to the steel plate surface so as to satisfy the above conditions 1, 2, 5, and 6. Then, the flow rate of the assist gas and the amount of particles in the through-plate atmosphere were adjusted within the range described in the above embodiment.
- the arithmetic mean height Ra of the roughness curve defining the groove bottom region is 1.9 ⁇ m, and the roughness curve element defining the groove bottom region of the groove
- the average length RSm was 42 ⁇ m.
- rust resistance was verified using the same verification method as in the above verification 1.
- Table 4 in addition to the above conditions 1 and 2, satisfying the above conditions 5 and 6 (that is, by adopting configurations A and B), the rust resistance of the grain-oriented electrical steel sheet It was confirmed that it improved further.
- the magnetic loss iron loss W17 / 50
- the iron loss of Example 22 in which the rust resistance was “excellent” was 0.823 W / kg.
- the iron loss of Example 31 whose rust resistance was "good” was 0.718 W / kg.
- the groove depth D was 5 ⁇ m or more and 40 ⁇ m or less
- the groove width W was 10 ⁇ m or more and 250 ⁇ m or less.
- Example 38 to 40 grain oriented electrical steel sheets that satisfy the above conditions 3, 4, 5, and 6 and that do not satisfy at least one of the above conditions 1 and 2 were prepared.
- Examples 41 to 43 grain oriented electrical steel sheets that satisfy the above conditions 1, 2, 5, and 6 and that do not satisfy at least one of the above conditions 3 and 4 were prepared.
- Examples 44 to 46 grain oriented electrical steel sheets that satisfy the above conditions 1, 2, 3, and 4 and that do not satisfy at least one of the above conditions 5 and 6 were prepared.
- the assist gas injection angle (first angle ⁇ 1) with respect to the laser scanning direction and the assist gas injection angle (second angle ⁇ 2) with respect to the steel plate surface so as to satisfy the above conditions 1, 2, 3, and 4. Then, the flow rate of the assist gas and the amount of particles in the through-plate atmosphere were adjusted within the range described in the above embodiment.
- the rust resistance was verified using the same verification method as in the above verification 1.
- Table 5 by satisfying the conditions 5 and 6 in addition to the above conditions 1, 2, 3 and 4 (that is, by adopting all the configurations A, B and C), the directional electromagnetic It was confirmed that the rust resistance of the steel sheet was further improved.
- the groove depth D was 5 ⁇ m or more and 40 ⁇ m or less
- the groove width W was 10 ⁇ m or more and 250 ⁇ m or less.
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Abstract
Description
本願は、2015年4月20日に日本に出願された特願2015-086299号に基づき優先権を主張し、その内容をここに援用する。
このように、方向性電磁鋼板の磁区制御法としてレーザ照射法を採用する場合、方向性電磁鋼板の耐錆性が低下するという問題がある。例えば、錆が発生するとその周辺の皮膜が剥離し、層間電流が著しく流れた場合には鉄損が増大する可能性がある。さらに万が一、錆びによって鋼板が浸食した場合は非磁性部が広がり、最適な磁区細分化条件が保たれないこともあり得る。
なお、鋼板の表面に絶縁皮膜が形成される前に、レーザ照射によって鋼板の表面に溝を形成し、その後に鋼板の表面に絶縁皮膜を形成するという製造プロセスを採用する場合においても、上記の問題は発生する。
(1)本発明の一態様に係る方向性電磁鋼板は、圧延方向と交差する方向に延在し且つ溝深さ方向が板厚方向となる溝が形成された鋼板表面を有する鋼板を備え、溝延在方向及び前記板厚方向を含む溝長手断面で前記溝を視た場合に、前記溝の溝底領域の輪郭を成す粗さ曲線の算術平均高さRaが、1μm以上3μm以下であり、前記溝底領域の前記輪郭を成す粗さ曲線要素の平均長さRSmが、10μm以上150μm以下である。この方向性電磁鋼板が絶縁皮膜をさらに備え、前記溝延在方向に直交する溝短手断面で前記溝を視た場合に、前記溝と前記鋼板表面との境界を起点として、前記溝短手断面にて前記板厚方向と直交し且つ前記溝から遠ざかる方向に10μm以上500μm以下の領域を粒子存在領域と定義したとき、前記粒子存在領域における前記絶縁皮膜は、円相当径が0.1μm以上2μm以下である鉄含有粒子を含み、前記粒子存在領域の面積に対する前記鉄含有粒子の面積の割合が0.1%以上30%未満であり、前記鉄含有粒子の化学成分が、80~100質量%のFeと、0~10質量%のSiと、0~10質量%のMgとを含む。
ただ、下限値に「超」と示す数値限定範囲には下限値が含まれず、上限値に「未満」と示す数値限定範囲には上限値が含まれない。
図1は、本実施形態に係る方向性電磁鋼板1の平面図である。図2は、図1のA-A線における矢視断面図である。図3は、図1のB-B線における矢視断面図である。なお、図1~図3において、方向性電磁鋼板1の圧延方向をX、方向性電磁鋼板1の板幅方向(同一平面内で圧延方向に直交する方向)をY、方向性電磁鋼板1の板厚方向(XY平面に直交する方向)をZと定義する。
また、電磁鋼板では二次再結晶時に純化焼鈍を経ることが一般的である。純化焼鈍においてはインヒビター形成元素の系外への排出が起きる。特にN、Sについては濃度の低下が顕著で、50ppm以下になる。通常の純化焼鈍条件であれば、9ppm以下、さらには6ppm以下、純化焼鈍を十分に行えば、一般的な分析では検出できない程度(1ppm以下)にまで達する。
(A)溝5の溝底領域の表面粗さを示す表面粗さパラメータ(Ra、RSm)の値が所定範囲内である。
(B)絶縁皮膜4が鉄含有粒子を含んでいることが好ましい。
(C)グラス皮膜3及び絶縁皮膜4には、溝5に隣接する位置にMg濃化領域が溝延在方向に沿って存在することが好ましい。
(D)鋼板2では溝5に接する結晶粒の粒径が5μm以上であることが好ましい。
以下、上記構成A、B、C、及びDのそれぞれについて詳細に説明する。
本実施形態では、図2に示すように、溝延在方向(本実施形態では板幅方向Yに平行な方向)及び板厚方向Zを含む断面(溝長手断面)で溝5を視た場合に、溝5の溝底領域5aの輪郭を成す粗さ曲線の算術平均高さRaが、1μm以上3μm以下であり、好適には1.2μm以上2.5μm以下、更に好適には1.3μm以上2.3μm以下であり、上記溝底領域5aの輪郭を成す粗さ曲線要素の平均長さRSmが、10μm以上150μm以下であり、好適には40μm以上145μm以下、更に好適には60μm以上140μm以下である。
なお、鋼板表面2aと溝5の輪郭(うねり曲線LWC1)との間の距離を測定するためには、Z方向における鋼板表面2aの位置(高さ)を予め測定しておく必要がある。例えば、観察範囲50内の鋼板表面2aにおける複数箇所のそれぞれについて、レーザ式表面粗さ測定器を用いてZ方向の位置(高さ)を測定し、それらの測定結果の平均値を鋼板表面2aの高さとして利用してもよい。
なお、磁区細分化の効果を好ましく得るためには、本実施形態における溝5の溝幅Wが10μm~250μmであることが好ましい。この溝幅Wは、溝延在方向に直交する溝短手断面での溝5のうねり曲線上で、鋼板表面2aから板厚方向Zに溝5の表面に向かう深さが、溝5の溝深さDに対し0.05×Dとなる2つの点を結ぶ線分の長さ(溝開口部)として求めればよい(図9参照)。
図3に示すように、本実施形態では、溝延在方向に直交する溝短手断面で溝5を視た場合に、溝5と鋼板表面2aとの境界Gを起点として、溝短手断面にて板厚方向Zと直交し且つ溝5から遠ざかる方向に10μm以上500μm以下の長さで延在する領域を粒子存在領域W1と定義する。
fi ≧ 0.05×D …(2)
(ただし、iは、1~pの整数)
本実施形態では、グラス皮膜3及び絶縁皮膜4のうち、グラス皮膜3及び絶縁皮膜4に含まれる質量分率での平均Mg含有量と比較して、Mg含有量が平均で1.3倍以上を満足する領域をMg濃化領域W2と定義する。図3に示すように、本実施形態では、溝延在方向に直交する溝短手断面で溝5を視た場合に、上記のMg濃化領域W2が、溝5と鋼板表面2aとの境界Gを起点として、溝短手断面にて板厚方向Zと直交し且つ溝5から遠ざかる方向に0.1μm以上10μm以下の領域に含まれている。
本実施形態では、鋼板2において、溝5に接する結晶粒の粒径が平均で5μm以上であることが好ましい。溝5の周辺に、溝5の形成に由来する溶融凝固領域が存在する場合、溝5に接する結晶粒の粒径は微細となる。この場合、最終的に結晶方位が{110}<001>方位から逸脱する可能性が高くなり、好ましい磁気特性が得られない可能性が高くなる。従って、溝5の周辺には、溶融凝固領域が存在しないことが好ましい。溝5の周辺に溶融凝固領域が存在しない場合には、溝5に接する結晶粒(二次再結晶粒)の粒径が平均で5μm以上となる。また、溝5に接する結晶粒の粒径の上限は特に限定されないが、この上限を100×103μm以下としてもよい。なお、結晶粒の粒径は、円相当径を意味する。結晶粒の粒径は、例えばASTM E112などの一般的な結晶粒径測定法によって求めればよく、またはEBSD(Electron Back Scattering Diffraction Pattern)法によって求めてもよい。また、溝5に接する結晶粒は、上記の溝短手断面または板厚方向Zに垂直な断面にて観察すればよい。
上記の溶融凝固領域を有さない溝5は、例えば、後述の製造方法によって得ることが可能である。
図11は、方向性電磁鋼板1の製造プロセスを示すフローチャートである。図11に示すように、最初の鋳造工程S01では、質量分率で、Si:0.8%~7%、C:0%超~0.085%、酸可溶性Al:0%~0.065%、N:0%~0.012%、Mn:0%~1%、Cr:0%~0.3%、Cu:0%~0.4%、P:0%~0.5%、Sn:0%~0.3%、Sb:0%~0.3%、Ni:0%~1%、S:0%~0.015%、Se:0%~0.015%、を含有し、残部がFe及び不純物からなる化学成分を有する溶鋼が連続鋳造機に供給されて、スラブが連続的に製出される。
さらに、鋼板2の通板雰囲気に存在する、0.5μm以上の径を有する粒子の数量が、1CF(キュービックフィート)当たり10個以上10000個未満となるように雰囲気制御を行うことが好ましい。
まず、下記条件1及び条件2を満足する方向性電磁鋼板の耐錆性を検証した。
(条件1)
溝長手断面で溝を視た場合に、溝の溝底領域の輪郭を成す粗さ曲線の算術平均高さRaが、1μm以上3μm以下である。
(条件2)
溝長手断面で溝を視た場合に、溝の溝底領域の輪郭を成す粗さ曲線要素の平均長さRSmが、10μm以上150μm以下である。
質量分率で、Si:3.0%、C:0.08%、酸可溶性Al:0.05%、N:0.01%、Mn:0.12%、Cr:0.05%、Cu:0.04%、P:0.01%、Sn:0.02%、Sb:0.01%、Ni:0.005%、S:0.007%、Se:0.001%、を含有し、残部がFe及び不純物からなる化学成分を有するスラブに対して熱間圧延が実施され、厚さ2.3mmの熱延鋼板が得られた。
続いて、表2に示すように、公知の製造方法を用いて、実施例9として、上記条件1及び条件2を満足し、且つグラス皮膜を備えない方向性電磁鋼板を用意した。また、比較例5~7として、上記条件1及び条件2の少なくとも一方を満足せず、且つグラス皮膜を備えない方向性電磁鋼板を用意した。鋼板の化学組成は、上記検証1と同じである。上記検証1と同様に、上記条件1及び条件2を満たすために、レーザ走査方向に対するアシストガス噴射角(第1角度θ1)と、鋼板表面に対するアシストガス噴射角(第2角度θ2)と、アシストガス25の流量と、通板雰囲気中の粒子量とを上記実施形態で説明した範囲内で調整した。
参考までに、耐錆性の試験後に磁気特性(鉄損W17/50)を測定した結果、耐錆性が“良”であった実施例9の鉄損は、0.832W/kgであった。耐錆性が“不良”であった比較例5の鉄損は、0.925W/kgであった。同じく耐錆性が“不良”であった比較例6の鉄損は、0.736W/kgであった。なお、実施例9及び比較例5~7ともに、溝深さDが5μm以上40μm以下、溝幅Wが10μm以上250μm以下であった。
続いて、上記条件1及び2に加えて、以下の条件3及び条件4を満足する方向性電磁鋼板の耐錆性を検証した。
(条件3)
グラス皮膜および絶縁皮膜に含まれる質量分率での平均Mg含有量と比較して、Mg含有量が平均で1.3倍以上を満足するグラス皮膜および絶縁皮膜中の領域をMg濃化領域と定義したとき、溝短手断面で溝を視た場合に、上記Mg濃化領域が、溝と鋼板表面との境界を起点として、溝短手断面にて板厚方向と直交し且つ溝から遠ざかる方向に0.1μm以上10μm以下の領域に含まれる。
(条件4)
板厚方向から溝を視た場合(溝を平面視した場合)に、溝延在方向に沿って互いに隣り合うMg濃化領域の間の距離dwが、0超100μm以下である。
参考までに、耐錆性の試験後に磁気特性(鉄損W17/50)を測定した結果、耐錆性が“優良”であった実施例10の鉄損は、0.836W/kgであった。また、耐錆性が“良”であった実施例19の鉄損は、0.701W/kgであった。なお、実施例10~21において、溝深さDが5μm以上40μm以下、溝幅Wが10μm以上250μm以下であった。
続いて、上記条件1及び2に加えて、以下の条件5及び条件6を満足する方向性電磁鋼板の耐錆性を検証した。
(条件5)
溝短手断面で溝を視た場合に、溝と鋼板表面との境界を起点として、溝短手断面にて板厚方向と直交し且つ溝から遠ざかる方向に10μm以上500μm以下の長さで延在する領域を粒子存在領域と定義したとき、粒子存在領域における絶縁皮膜が鉄含有粒子を含む。
(条件6)
粒子存在領域における絶縁皮膜に含まれる鉄含有粒子の円相当径が、0.1μm以上2μm以下であり、粒子存在領域の面積に対する鉄含有粒子の面積の割合が0.1%以上30%未満である。
なお、実施例22~34に対応する方向性電磁鋼板において、溝底領域の輪郭を成す粗さ曲線の算術平均高さRaが1.9μm、溝の溝底領域の輪郭を成す粗さ曲線要素の平均長さRSmが42μmであった。
参考までに、耐錆性の試験後に磁気特性(鉄損W17/50)を測定した結果、耐錆性が“優良”であった実施例22の鉄損は、0.823W/kgであった。また、耐錆性が“良”であった実施例31の鉄損は、0.718W/kgであった。なお、実施例22~34において、溝深さDが5μm以上40μm以下、溝幅Wが10μm以上250μm以下であった。
続いて、上記条件1、2、3、及び4に加えて、条件5及び条件6を満足する方向性電磁鋼板の耐錆性を検証した。
2 鋼板
2a 鋼板表面
2b 鋼板領域
3 グラス皮膜
4 絶縁皮膜
5 溝
5a 溝底領域
5b 溝領域
6 鉄含有粒子
BL 溝基準線
LWC 溝長手うねり曲線
SWC 溝短手うねり曲線
RC 粗さ曲線
W1 粒子存在領域
W2 Mg濃化領域
W 溝幅
X 圧延方向
Y 板幅方向
Z 板厚方向
Claims (4)
- 圧延方向と交差する方向に延在し且つ溝深さ方向が板厚方向となる溝が形成された鋼板表面を有する鋼板を備える方向性電磁鋼板において、
溝延在方向及び前記板厚方向を含む溝長手断面で前記溝を視た場合に、
前記溝の溝底領域の輪郭を成す粗さ曲線の算術平均高さRaが、1μm以上3μm以下であり、
前記溝底領域の前記輪郭を成す粗さ曲線要素の平均長さRSmが、10μm以上150μm以下であり、
前記方向性電磁鋼板が絶縁皮膜をさらに備え、
前記溝延在方向に直交する溝短手断面で前記溝を視た場合に、
前記溝と前記鋼板表面との境界を起点として、前記溝短手断面にて前記板厚方向と直交し且つ前記溝から遠ざかる方向に10μm以上500μm以下の領域を粒子存在領域と定義したとき、
前記粒子存在領域における前記絶縁皮膜は、円相当径が0.1μm以上2μm以下である鉄含有粒子を含み、
前記粒子存在領域の面積に対する前記鉄含有粒子の面積の割合が0.1%以上30%未満であり、
前記鉄含有粒子の化学成分が、80~100質量%のFeと、0~10質量%のSiと、0~10質量%のMgとを含む
ことを特徴とする方向性電磁鋼板。 - 前記方向性電磁鋼板が前記鋼板と前記絶縁皮膜との間にグラス皮膜をさらに備え、
前記グラス皮膜及び前記絶縁皮膜に含まれる質量分率での平均Mg含有量と比較して、Mg含有量が平均で1.3倍以上を満足する前記グラス皮膜及び前記絶縁皮膜中の領域をMg濃化領域と定義したとき、
前記溝延在方向に直交する溝短手断面で前記溝を視た場合に、
前記Mg濃化領域が、前記溝と前記鋼板表面との境界を起点として、前記溝短手断面にて前記板厚方向と直交し且つ前記溝から遠ざかる方向に0.1μm以上10μm以下の領域に含まれており、かつ、
前記板厚方向から前記溝を視た場合に、
前記Mg濃化領域が前記溝延在方向に沿って連続的に存在する、
または、複数の前記Mg濃化領域が前記溝延在方向に沿って間隔を有して存在し、前記溝延在方向に沿って互いに隣り合う前記Mg濃化領域の間の距離が、0超100μm以下である
ことを特徴とする請求項1に記載の方向性電磁鋼板。 - 前記溝上に、平均厚さが0μm以上5μm以下の前記グラス皮膜と、平均厚さが1μm以上5μm以下の前記絶縁皮膜とが形成されており、
前記鋼板上に、平均厚さが0.5μm以上5μm以下の前記グラス皮膜と、平均厚さが1μm以上5μm以下の前記絶縁皮膜とが形成されており、
前記溝上に形成された前記グラス皮膜の前記平均厚さが、前記鋼板上に形成された前記グラス皮膜の前記平均厚さよりも薄い
ことを特徴とする請求項2に記載の方向性電磁鋼板。 - 前記鋼板では前記溝に接する結晶粒の粒径が5μm以上であることを特徴とする請求項1~3のいずれか一項に記載の方向性電磁鋼板。
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WO2019156220A1 (ja) | 2018-02-08 | 2019-08-15 | 日本製鉄株式会社 | 方向性電磁鋼板 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101892226B1 (ko) * | 2016-12-23 | 2018-08-27 | 주식회사 포스코 | 방향성 전기강판 및 그 자구미세화 방법 |
JP6939852B2 (ja) * | 2019-07-31 | 2021-09-22 | Jfeスチール株式会社 | 線状溝形成方法および方向性電磁鋼板の製造方法 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06116642A (ja) * | 1992-10-06 | 1994-04-26 | Nippon Steel Corp | 方向性電磁鋼板の微細疵付与方法 |
JP2007002334A (ja) * | 2005-05-09 | 2007-01-11 | Nippon Steel Corp | 低鉄損方向性電磁鋼板およびその製造方法 |
JP2007051314A (ja) * | 2005-08-16 | 2007-03-01 | Nippon Steel Corp | 皮膜密着性の極めて優れた方向性電磁鋼板およびその製造方法 |
JP2007169762A (ja) * | 2005-12-26 | 2007-07-05 | Jfe Steel Kk | 低鉄損方向性電磁鋼板の製造方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6254873A (ja) | 1985-09-03 | 1987-03-10 | Sanyo Electric Co Ltd | 固定ヘツド型デイジタル磁気再生装置 |
JPS6253579A (ja) | 1985-09-03 | 1987-03-09 | Seiko Epson Corp | 携帯用受信機器 |
JP2563729B2 (ja) | 1992-08-07 | 1996-12-18 | 新日本製鐵株式会社 | パルスco2レーザを用いた方向性電磁鋼板の鉄損改善方法および装置 |
JP3726289B2 (ja) * | 1994-03-31 | 2005-12-14 | Jfeスチール株式会社 | 鉄損の低い方向性電磁鋼板 |
TWI305548B (en) * | 2005-05-09 | 2009-01-21 | Nippon Steel Corp | Low core loss grain-oriented electrical steel sheet and method for producing the same |
BR112012024448B1 (pt) * | 2010-04-01 | 2018-06-05 | Nippon Steel & Sumitomo Metal Corporation | Folha de aço elétrico de grão orientado e método para produzir a mesma |
CN104099458B (zh) * | 2010-09-09 | 2016-05-11 | 新日铁住金株式会社 | 方向性电磁钢板的制造方法 |
CA2808774C (en) * | 2010-09-10 | 2015-05-05 | Jfe Steel Corporation | Grain oriented electrical steel sheet and method for manufacturing the same |
JP5891578B2 (ja) * | 2010-09-28 | 2016-03-23 | Jfeスチール株式会社 | 方向性電磁鋼板 |
BR112013030412B1 (pt) * | 2011-05-27 | 2019-10-29 | Nippon Steel & Sumitomo Metal Corp | folha de aço eletromagnética orientada por grãos e método de fabricação de folha de aço eletromagnética orientada por grãos |
JP5884165B2 (ja) | 2011-12-28 | 2016-03-15 | Jfeスチール株式会社 | 方向性電磁鋼板およびその製造方法 |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06116642A (ja) * | 1992-10-06 | 1994-04-26 | Nippon Steel Corp | 方向性電磁鋼板の微細疵付与方法 |
JP2007002334A (ja) * | 2005-05-09 | 2007-01-11 | Nippon Steel Corp | 低鉄損方向性電磁鋼板およびその製造方法 |
JP2007051314A (ja) * | 2005-08-16 | 2007-03-01 | Nippon Steel Corp | 皮膜密着性の極めて優れた方向性電磁鋼板およびその製造方法 |
JP2007169762A (ja) * | 2005-12-26 | 2007-07-05 | Jfe Steel Kk | 低鉄損方向性電磁鋼板の製造方法 |
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Also Published As
Publication number | Publication date |
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KR102010165B1 (ko) | 2019-08-12 |
KR20170107084A (ko) | 2017-09-22 |
EP3287538A1 (en) | 2018-02-28 |
EP3287538A4 (en) | 2018-11-14 |
RU2682363C1 (ru) | 2019-03-19 |
US10385418B2 (en) | 2019-08-20 |
JP6409960B2 (ja) | 2018-10-24 |
CN107406935B (zh) | 2019-03-12 |
PL3287538T3 (pl) | 2020-07-13 |
JPWO2016171124A1 (ja) | 2017-11-24 |
EP3287538B1 (en) | 2020-01-01 |
US20180066334A1 (en) | 2018-03-08 |
CN107406935A (zh) | 2017-11-28 |
BR112017018677A2 (ja) | 2018-04-17 |
BR112017018677B1 (pt) | 2021-08-17 |
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