WO2016132655A1 - Fiber-reinforced resin molded body having damping properties and automobile part using same - Google Patents

Fiber-reinforced resin molded body having damping properties and automobile part using same Download PDF

Info

Publication number
WO2016132655A1
WO2016132655A1 PCT/JP2015/086406 JP2015086406W WO2016132655A1 WO 2016132655 A1 WO2016132655 A1 WO 2016132655A1 JP 2015086406 W JP2015086406 W JP 2015086406W WO 2016132655 A1 WO2016132655 A1 WO 2016132655A1
Authority
WO
WIPO (PCT)
Prior art keywords
fiber
reinforced resin
damping
laminate
layer
Prior art date
Application number
PCT/JP2015/086406
Other languages
French (fr)
Japanese (ja)
Inventor
直樹 小柳津
片山　和孝
有史 橋本
Original Assignee
住友理工株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 住友理工株式会社 filed Critical 住友理工株式会社
Priority to DE112015005173.2T priority Critical patent/DE112015005173T5/en
Priority to JP2016528253A priority patent/JP6002872B1/en
Publication of WO2016132655A1 publication Critical patent/WO2016132655A1/en

Links

Images

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16F—SPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION
    • F16F1/00—Springs
    • F16F1/36—Springs made of rubber or other material having high internal friction, e.g. thermoplastic elastomers
    • F16F1/366—Springs made of rubber or other material having high internal friction, e.g. thermoplastic elastomers made of fibre-reinforced plastics, i.e. characterised by their special construction from such materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
    • B32B19/04—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
    • B32B19/04—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica next to another layer of the same or of a different material
    • B32B19/045—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
    • B32B19/06—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/04—Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/26—Layered products comprising a layer of synthetic resin characterised by the use of special additives using curing agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/281—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/285—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/286—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysulphones; polysulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/288—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyketones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/38—Layered products comprising a layer of synthetic resin comprising epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0261—Polyamide fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0261—Polyamide fibres
    • B32B2262/0269—Aromatic polyamide fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/102—Oxide or hydroxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/107—Ceramic
    • B32B2264/108—Carbon, e.g. graphite particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2274/00—Thermoplastic elastomer material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536—Hardness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546—Flexural strength; Flexion stiffness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/718—Weight, e.g. weight per square meter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00—Buildings or parts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles

Definitions

  • the present invention provides a vibration-damping fiber-reinforced resin molded body in which vibration-damping property is imparted to a molded body made of a fiber-reinforced resin in which strength is improved by combining fibers such as carbon fiber and glass fiber with resin, and
  • the present invention relates to an automobile part using the same as a constituent member.
  • FRP fiber reinforced resin
  • FRP is superior in terms of strength
  • the stickiness to bending is inferior to that of metal, so there is a problem that it is difficult to adopt for a member that causes a major accident when it is broken, such as a suspension arm. Remain.
  • the present invention has been made in view of such circumstances, and its object is to provide a vibration-damping fiber-reinforced resin molded article having high strength and excellent vibration damping properties, and an automotive part using the same as a constituent member.
  • the present invention provides a vibration-damping fiber-reinforced resin molded body that is a laminate of a fiber-reinforced resin layer in which a resin is infiltrated into a woven fabric and a vibration-damping layer made of a synthetic resin.
  • the layer located in the center with respect to the thickness direction of the laminate is a central fiber reinforced resin layer, and upper and lower vibration damping layers are provided so as to sandwich it, and outer fiber reinforced resin layers are respectively provided on the outside thereof.
  • a vehicle component having a body as a first gist and being a torque rod, suspension arm, lower arm, tower bar, propeller shaft, impact beam, stabilizer bar, sub-frame, bumper or side door beam.
  • a second gist of the present invention is an automotive part that uses a vibration fiber reinforced resin molded article as a constituent member.
  • the present inventors have conducted intensive research to solve the above problems.
  • the present inventors have laminated a fiber reinforced resin molded body from a fiber reinforced resin layer in which a resin is infiltrated into a woven fabric and a vibration damping layer made of a synthetic resin from the viewpoint of strength and the like. Recalling that it was formed as a body, repeated trials and repeated various experiments. As a result, it was found that the thickness and the layer structure of the damping layer have a great influence on the damping properties and the characteristics such as strength and rigidity.
  • the layer located in the center with respect to the thickness direction of the laminate is a fiber reinforced resin layer (central fiber reinforced resin layer), and upper and lower vibration damping layers are provided so as to sandwich the layer, and further the fiber reinforced resin layer And a thickness (X) from the center of the laminate that is the center plane in the thickness direction of the laminate to the interface between the central fiber reinforced resin layer and each damping layer, and from the center of the laminate
  • the inventors have found that the object can be achieved and have reached the present invention.
  • the vibration-damping fiber reinforced resin molded product of the present invention is a vibration-damping fiber reinforced fiber that is a laminate of a fiber-reinforced resin layer obtained by infiltrating a resin into a woven fabric and a vibration-damping layer made of a synthetic resin.
  • a resin molded body in which the layer located in the center with respect to the thickness direction of the laminate is a central fiber reinforced resin layer, and upper and lower vibration damping layers are provided so as to sandwich the layer, and an outer fiber reinforced resin is provided outside the layer.
  • Each layer is provided, and the thickness (X) from the center surface of the laminate, which is the center plane in the thickness direction of the laminate, to the interface between the central fiber reinforced resin layer and each damping layer, and the center of the laminate
  • the vibration damping layer is made of a polyamide resin and the resin of the fiber reinforced resin layer is made of an epoxy resin, the interlayer adhesion between the two layers becomes more excellent.
  • the vibration damping layer is made of a woven fabric made of synthetic resin, stronger interlayer adhesion can be obtained.
  • the central fiber reinforced resin layer is composed of a laminate of a plurality of fiber reinforced resin layers, the thickness of the central fiber reinforced resin layer can be easily set.
  • the moldability is good.
  • the vibration damping layer is 0.04 to 0.4 mm, the vibration damping performance and bending strength are good.
  • the woven fabric is formed by weaving a continuous fiber of carbon fiber, glass fiber, aramid fiber or basalt fiber, weave, plain weave, or satin weave, it is favorable in terms of reinforcement.
  • the fiber reinforced resin layer contains at least one inorganic material selected from the group consisting of potassium titanate, alumina, zinc oxide, and titanium oxide, the improvement in strength and rigidity can be achieved. Become better.
  • the vibration-damping fiber reinforced resin molded product of the present invention is an automobile such as a torque rod, a suspension arm, a lower arm, a tower bar, a propeller shaft, an impact beam, a stabilizer bar, a subframe, a bumper, and a side door beam due to the above effects. It can be effectively used as a component member of a machine part.
  • the vibration-damping fiber reinforced resin molded article of the present invention can also be provided as a molded product of a sheet-like vibration-damping fiber reinforced resin molded article.
  • the vibration-damping fiber-reinforced resin molded body of the present invention is a vibration-damping fiber-reinforced resin molded body that is a laminate of a fiber-reinforced resin layer obtained by infiltrating a resin into a woven fabric and a vibration-damping layer made of a synthetic resin.
  • the layer located in the center with respect to the thickness direction of the laminate is the central fiber reinforced resin layer, and the upper and lower vibration damping layers are provided so as to sandwich the layer, and the outer fiber reinforced resin layer is provided outside thereof.
  • laminated body central plane means the central plane in the thickness direction of the laminated body as described above, and therefore, it does not matter whether it is an actual plane (interlayer interface) or not.
  • the “central fiber reinforced resin layer” may be composed of a single fiber reinforced resin layer as long as it is a layer made of only fiber reinforced resin, but is composed of a plurality of fiber reinforced resin layers. When the center fiber reinforced resin layer is formed to a desired thickness, it is easier to make and the resin is more easily infiltrated.
  • FIG. 1 is a schematic view showing an example of a cross section of the fiber reinforced resin molded article of the present invention (Example 1 described later), where 1 is a fiber reinforced resin layer and 2 is a vibration damping layer.
  • the said center fiber reinforced resin layer consists of two layers of fiber reinforced resin layers 1 as shown in figure, and the laminated body center from the interface with the damping layer 2 which pinches
  • the thickness up to the surface is X in the figure, and the thickness from the laminate center plane to the laminate surface is Y in the figure. Further, in the present invention, as shown in FIG.
  • the stacked structure is vertically symmetrical on the center plane of the stacked body, but the present invention is not limited to this, As long as the X / Y relationship and the d / D relationship described above are satisfied both in the upper and lower directions, they may be asymmetrical.
  • only one damping layer 2 is provided on both the upper and lower sides between the laminated body center plane and the laminated body surface.
  • the laminated body central plane to the laminated body surface are provided. Two or more damping layers may be provided between them.
  • the above X needs to be defined by the thickness from the interface between the vibration damping layer closest to the laminate center plane and the central fiber reinforced resin layer to the laminate center plane. Further, in FIG. 1, since the damping layer 2 is provided in total two layers, the above d is the total thickness of these two layers in FIG.
  • the above D that is, the thickness of the entire vibration-damping fiber-reinforced resin molded body of the present invention is preferably 1.9 to 7.4 mm, more preferably 2 from the viewpoint of moldability.
  • the range is from 0.0 to 3.0 mm.
  • the thickness of the damping layer is preferably 0.04 to 0.4 mm, more preferably 0.12 to 0.2 mm, from the viewpoint of damping control and bending strength.
  • the vibration-damping fiber reinforced resin molded product of the present invention is not limited to a sheet-like product as shown in FIG. 1, but is molded to a desired shape by press molding or the like. May be. However, even in that case, it is necessary to satisfy the relationship of the layer configuration of the present invention described above.
  • the fiber-reinforced resin layer is a layer formed by infiltrating a resin into a woven fabric as described above.
  • the woven fabric is made by twilling, plain weaving, or satin weaving continuous fibers of carbon fiber, glass fiber, aramid fiber or basalt fiber. ) May be used.
  • a woven fabric made of carbon fiber is preferable from the viewpoint of strength against forces from various angles (directions) and fatigue resistance, and a woven fabric made of glass fiber is preferable from the viewpoint of cost and the like.
  • the woven fabric is formed by weaving 1000 to 24000 continuous fibers having a width of 2 to 20 mm and a fiber diameter of 5 to 7 ⁇ m, and the weight of the woven fabric is 61 to 200 g / m 2.
  • the thickness is preferably 0.085 to 0.25 mm from the viewpoint of reinforcing properties and the like.
  • thermoplastic resin or a thermosetting resin is used as the resin to be infiltrated into the woven fabric.
  • thermoplastic resin examples include polyamide resin, polyolefin resin, acrylonitrile butadiene styrene resin, polyester resin, polycarbonate resin, polystyrene resin, polyacetal resin, modified polyphenylene ether resin, polyphenylene sulfide resin, polyether imide resin, polyether ether ketone resin, Examples thereof include polyether sulfone resin and thermoplastic elastomer. These may be used alone or in combination of two or more.
  • thermosetting resin examples include epoxy resins, unsaturated polyester resins, vinyl ester resins, and phenol resins. These may be used alone or in combination of two or more.
  • inorganic materials such as talc, silica, carbon black, titanium oxide, zinc oxide, potassium titanate, and alumina are added to the resin for the purpose of improving strength and rigidity and preventing shrinkage (sinking and warping). May be.
  • an inorganic material having a Mohs hardness of 4 or more is preferable from the viewpoint of improving the strength and rigidity expression rate.
  • inorganic materials such as potassium titanate, alumina, zinc oxide, and titanium oxide are used.
  • the Mohs hardness is a value measured with a Mohs hardness meter (manufactured by Tokyo Science).
  • the amount of the inorganic material added is preferably 1 to 15 parts by weight, more preferably 5 to 10 parts by weight with respect to 100 parts by weight of the resin, from the viewpoint of improving the strength and rigidity expression rate. is there. It is appropriate to knead the resin with (three) rolls, kneaders, Banbury mixers, etc., and kneading with a roll is particularly preferred in terms of processability.
  • the bending elastic modulus of the vibration-damping fiber reinforced resin molded article of the present invention is increased, and the impact resistance and energy absorption capacity are increased. .
  • the infiltration of the resin into the woven fabric is performed by hand lay-up molding in the case of a thermosetting resin, and in the case of a thermoplastic resin, the woven fabric and a thermoplastic resin sheet are overlapped and subjected to a heat press or the like, It is performed by melting a thermoplastic resin sheet.
  • the above hand lay-up molding is performed by applying a resin solution to the woven fabric or immersing the woven fabric in the resin solution, and further spreading it uniformly with a roller or the like so as to soak the resin solution into the woven fabric. Done.
  • the vibration-damping layer is a layer made of a synthetic resin, and may be a layer made of a thermoplastic resin, and is thermoset. It may be a layer made of a functional resin.
  • an alloy material in which polypropylene is added to polyamide 6 or polyamide 12 is preferable because vibration damping properties and the like are improved.
  • the damping layer is made of a polyamide resin (or an alloy material of the polyamide resin as described above), and the resin of the fiber-reinforced resin layer is made of an epoxy resin. It is preferable. This is because this combination is excellent in interlayer adhesion between both layers.
  • the resin of the fiber reinforced resin layer is more easily infiltrated into the woven fabric when the epoxy resin is used, and the strength of the fiber reinforced resin layer is also easily increased. As a result, the vibration control performance will be improved.
  • the vibration damping layer is formed by repeatedly applying the resin solution.
  • a thermoplastic resin it is extruded by a T-die or the like, and a thermoplastic resin having a desired thickness is formed. It is made by preparing a sheet (thermoplastic resin film) and laminating it.
  • the vibration damping layer is made of a woven fabric obtained by twilling, plain weaving, or satin weaving continuous fibers made of the various synthetic resins described above (preferably, continuous fibers made of polyamide 6 and polyamide 66). May be.
  • the damping layer is preferably composed of a thermoplastic resin sheet, but from the viewpoint of interlayer adhesion, bending strength, and elongation at bending break, the damping layer is What was comprised with the woven fabric (preferably the woven fabric which consists of polyamide 6 and polyamide 66) consisting of the various synthetic resin of the said description is preferable. That is, the resin of the fiber reinforced resin layer permeates between the weaves of the woven fabric to ensure strong interlayer adhesion, and the bending properties of the vibration damping layer are enhanced by the weave of the woven fabric.
  • the woven fabric preferably the woven fabric which consists of polyamide 6 and polyamide 66
  • the woven fabric is formed by weaving 39 to 65 continuous fibers having a 1 cm width and a fiber diameter of 0.01 to 0.08 mm, and has a thickness of 0.02 to 0.1 mm.
  • the weight of the woven fabric is preferably 1.4 to 1.7 g / cm 2 from the viewpoints of bending strength and bending elongation at break.
  • the fiber reinforced resin layer and the vibration damping layer are laminated in the order prescribed in the present invention, and if necessary, it is molded using a mold or the like to obtain the desired vibration damping fiber reinforced resin molded product. Obtainable.
  • the fiber reinforced resin layer is formed by hand lay-up molding as described above,
  • the damping layer can be formed by laminating a thermoplastic resin film to obtain a desired laminate.
  • the laminate is put in a bag, evacuated with a vacuum pump, and crushed with a press machine (pressure is 5 kN to 100 kN). Done. An appropriate temperature may be applied during the pressing.
  • the fiber reinforced resin layer when the resin of the fiber reinforced resin layer is a thermoplastic resin and the vibration damping layer is made of a thermosetting resin, the fiber reinforced resin layer includes a woven fabric and a thermoplastic resin sheet as described above.
  • the thermoplastic resin sheet is formed by melting and heat-pressing and the like, and the damping layer is formed by repeatedly applying the resin solution to obtain a target laminate.
  • the laminate is pressed at a temperature equal to or higher than the melting point of the thermoplastic resin or higher than the curing temperature of the vibration damping layer. Also good. And if needed, it can shape
  • the vibration-damping fiber-reinforced resin molded article of the present invention obtained as described above is excellent in strength / rigidity and vibration-damping property, and has higher bending resistance than ordinary FRP, and fatigue durability. Because of its excellent characteristics and heat resistance, it can be used for automobiles such as torque rods, suspension arms, lower arms, tower bars, propeller shafts, impact beams, stabilizer bars, subframes, bumpers, and side door beams. It is suitably used as a component member of a part. Further, the vibration-damping fiber reinforced resin molded body of the present invention can be used for various purposes (robot forks, bridges, houses, wheelchairs, electric motors) in addition to automotive parts, as long as it retains the laminated structure that is the feature. It can be used for components such as carts and bicycles.
  • each layer was laminated on a plane so as to have the layer structure shown in Table 1, Table 2, and Table 4 below, and a laminate of fiber reinforced resin was produced.
  • the “CFRP” layer shown in Table 1, Table 2 and Table 4 is an epoxy resin (manufactured by Daito Sangyo Co., Ltd., Daito Sizer 828) and its curing agent (manufactured by ADEKA Co., Ltd., Adeka Hardener EH6007) by weight ratio.
  • the “PA12” layer shown in Tables 1, 2 and 4 is a laminate of polyamide 12 alloy material (Ube Industries, 3030JI6L), and the “PA6” layer is made of polyamide 6. A film made of an alloy material (Dupont, ST811HS) is laminated.
  • the “PA6 cloth” layer shown in Tables 1, 2 and 4 is a woven fabric obtained by plain weaving AMIRAN 235T-24-720 (manufactured by Toray Industries, Inc.) using a loom, and the “PA66 cloth” layer is 4700 (a plain fabric manufactured by Asahi Kasei Fibers).
  • “X / Y” shown in Table 1, Table 2 and Table 4 is obtained by calculating “X / Y” defined in claim 1 of the present application, and “d / D” is calculated in claim 1 of the present application. This is the calculated “d / D”.
  • each layer was laminated on a plane so as to have a layer configuration shown in Table 3 to be described later, and a laminate of fiber reinforced resin was produced.
  • the “CFRP” layer shown in Table 3 consists of 100 parts by weight of an epoxy resin (manufactured by Daito Sangyo Co., Ltd., Daito Sizer 828), 50 parts by weight of its curing agent (manufactured by ADEKA Co., Ltd., Adeka Hardener EH6007), and an inorganic material (Otsuka).
  • the “PA6 cloth” layer shown in Table 3 is a woven fabric obtained by plain weaving Amilan 235T-24-720 (manufactured by Toray Industries, Inc.) using a loom, and the “PA66 cloth” layer is 4700 (manufactured by Asahi Kasei Corporation). Plain fabric).
  • “X / Y” shown in Table 3 is obtained by calculating “X / Y” defined in claim 1 of the present application, and “d / D” is “d / D” defined in claim 1 of the present application. Is calculated.
  • Reference Example 1 A steel plate having a thickness of 2.0 mm was prepared and used as Reference Example 1.
  • Reference Example 2 An aluminum plate having a thickness of 2.0 mm was prepared and used as Reference Example 2.
  • Each laminate (a reference example is a metal plate) was cut into a strip of 150 mm ⁇ 10 mm, and the flexural modulus was measured using this as a sample.
  • a three-point bending test was performed on this sample in accordance with JIS K7074 at room temperature at a test speed of 2 mm / min and a span distance of 64 mm, and a stress gradient with a strain amount (0.05 to 0.25%) was obtained.
  • Each laminate (a reference example is a metal plate) was cut into a strip of 150 mm ⁇ 10 mm, and the bending strength was measured using this as a sample. That is, according to JIS K7074, this sample was subjected to a three-point bending test at room temperature at a test speed of 2 mm / min and a span distance of 64 mm, and the bending strength (MPa) at that time was measured.
  • Each laminated body (reference example is a metal plate) was cut into a strip shape of 150 mm ⁇ 10 mm, and the elongation at the time of bending fracture was measured using this as a sample. That is, according to JIS K7074, this sample was subjected to a three-point bending test at room temperature at a test speed of 2 mm / min and a span distance of 64 mm. The elongation at break (%) was measured.
  • Attenuation coefficient Each laminate (a reference example is a metal plate) was cut into a strip of 150 mm ⁇ 10 mm, and the attenuation coefficient was measured using this as a sample. That is, this sample was tested by the single-end fixed impact method in accordance with JIS G0602 “Test method for vibration damping characteristics of damping steel plate”, and the loss factor (damping factor) at normal time was calculated using Hilbert transform. Asked.
  • the fiber reinforced resin laminates of the examples have high bending strength, excellent rigidity, and a large damping coefficient, so that they also have excellent vibration damping properties.
  • the fiber reinforced resin laminate of Comparative Example 1 had no layer to be a damping layer, the damping coefficient was smaller than that of the example and resulted in inferior damping properties.
  • the fiber reinforced resin laminate of Comparative Example 2 has a layer serving as a vibration damping layer, since it has only one layer, the damping coefficient is also smaller than that of the example and results in inferior vibration damping properties.
  • the fiber reinforced resin laminate of Comparative Example 3 has a large number of PA layers serving as damping layers, and the ratio (d / D) of the total thickness of all PA layers contained in the laminate is the present invention. Therefore, the bending strength was smaller than that of the example and the rigidity was inferior.
  • the ratio (d / D) of the total thickness of all PA layers contained in the laminate is within the specified range of the present invention, but the damping layer
  • the PA layer is provided on the outermost layer (outermost side), and the interface between the CFRP layer and the PA layer is too far from the center of the laminate (“X / Y” exceeds the specified range of the present invention) Therefore, the bending strength was smaller than that of the example and the result was inferior in rigidity.
  • the vibration-damping fiber-reinforced resin molded body of the present invention can be used for various applications (robot forks, bridges, houses, wheelchairs, electric carts, It can be used for components such as bicycles.

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Body Structure For Vehicles (AREA)
  • Vehicle Body Suspensions (AREA)
  • Vibration Prevention Devices (AREA)

Abstract

A fiber-reinforced resin molded body having damping properties, said molded body being a laminate that comprises fiber-reinforced resin layers prepared by impregnating a woven fabric with a resin and damping layers formed of a synthetic resin, wherein: a layer positioned at the center in the thickness direction of the laminate is a central fiber-reinforced resin layer; upper and lower damping layers are disposed so as to sandwich the central fiber-reinforced resin layer; outer fiber-reinforced resin layers are respectively provided outside the damping layers; the thickness (X) from the central face of the laminate that is the central face in the thickness direction of the laminate to the interface between the central fiber-reinforced resin layer and each damping layer and the thickness (Y) from the central face of the laminate to the surface of the laminate satisfy the requirement that X/Y is 0.19-0.89; and the sum (d) of the thicknesses of all of the damping layers contained in the laminate and the overall thickness (D) of the laminate satisfy the requirement that d/D is 0.02-0.18. Thus, a fiber-reinforced resin molded body having damping properties, which has a high strength and excellent damping properties, and an automobile part, which comprises the same as a constituting member, can be provided.

Description

制振性繊維強化樹脂成形体およびそれを用いた自動車用部品Damped fiber reinforced resin molded article and automotive parts using the same
　本発明は、炭素繊維やガラス繊維等の繊維を樹脂に複合化させて強度を向上させた繊維強化樹脂からなる成形体に、制振性を付与した、制振性繊維強化樹脂成形体、およびそれを構成部材とする自動車用部品に関するものである。 The present invention provides a vibration-damping fiber-reinforced resin molded body in which vibration-damping property is imparted to a molded body made of a fiber-reinforced resin in which strength is improved by combining fibers such as carbon fiber and glass fiber with resin, and The present invention relates to an automobile part using the same as a constituent member.
　従来、トルクロッド，サスペンションアーム等といった自動車用部品の構成材料には、強度や耐熱性の観点から、主に、鉄やアルミ等の金属が用いられている。また、ガラス繊維や炭素繊維等の繊維を樹脂に複合化させて強度を向上させた繊維強化樹脂（ＦＲＰ）も、金属と同様に強度が高く、しかも軽量化が図れることから、金属に代わる材料として期待されている（特許文献１、２等参照）。 Conventionally, metals such as iron and aluminum are mainly used as constituent materials for automotive parts such as torque rods and suspension arms from the viewpoint of strength and heat resistance. In addition, fiber reinforced resin (FRP), which is improved in strength by compounding fibers such as glass fiber and carbon fiber with resin, is as strong as metal and can be reduced in weight. (See Patent Documents 1 and 2 etc.).
特開２０１３－１０８１９４号公報JP 2013-108194 A 特開２００８－２６５１０８号公報JP 2008-265108 A 特許第５３７３６６７号公報Japanese Patent No. 5373667 特許第３７７２２１６号公報Japanese Patent No. 3772216
　しかしながら、ＦＲＰは、強度の点では優れるものの、曲げに対する粘りが金属よりも劣ることから、サスペンションアーム等のように、破損した際に大事故につながるような部材には、採用し難いといった課題が残る。 However, although FRP is superior in terms of strength, the stickiness to bending is inferior to that of metal, so there is a problem that it is difficult to adopt for a member that causes a major accident when it is broken, such as a suspension arm. Remain.
　また、自動車用部品には、強度の他、制振性が要望されることも多い。しかしながら、金属製あるいはＦＲＰ製の自動車用部品そのもので制振性を充足するという発想は殆どなかった。そのようななか、自動車用部品に関する技術ではないが、近年、炭素繊維やガラス繊維等の繊維フィラーを含有するＦＲＰ層間に、ゴム層やエラストマー層といった制振層を設けることにより、制振性を向上させる技術が提案されている（特許文献３および４参照）。しかし、サスペンションアーム等の自動車用部品に、これらの技術をそのまま転用したところで、所望の強度が得られないことから、その点での改善が求められる。 Also, in addition to strength, automotive parts often require vibration damping. However, there has been almost no idea that the metal or FRP automotive parts themselves satisfy the vibration damping performance. Under such circumstances, although it is not a technology related to automotive parts, in recent years, damping properties such as rubber layers and elastomer layers have been improved by providing damping layers such as rubber layers and elastomer layers between FRP layers containing fiber fillers such as carbon fibers and glass fibers. The technique to make is proposed (refer patent document 3 and 4). However, when these technologies are directly applied to automobile parts such as suspension arms, desired strength cannot be obtained, and improvements in that respect are required.
　本発明は、このような事情に鑑みなされたもので、高い強度を有するとともに制振性に優れる、制振性繊維強化樹脂成形体、およびそれを構成部材とする自動車用部品の提供をその目的とする。 The present invention has been made in view of such circumstances, and its object is to provide a vibration-damping fiber-reinforced resin molded article having high strength and excellent vibration damping properties, and an automotive part using the same as a constituent member. And
　上記の目的を達成するため、本発明は、樹脂を織布に浸潤させてなる繊維強化樹脂層と合成樹脂製の制振層との積層体である制振性繊維強化樹脂成形体であって、その積層体の厚み方向に対し中央に位置する層が中央繊維強化樹脂層であり、それを挟むように上下の制振層が設けられ、その外側に外側繊維強化樹脂層がそれぞれ設けられ、かつ、上記積層体の厚み方向の中心面である積層体中心面から上記中央繊維強化樹脂層と各制振層との界面までの厚み（Ｘ）と、上記積層体中心面から積層体表面までの厚み（Ｙ）が、Ｘ／Ｙ＝０．１９～０．８９の関係を満たし、さらに、上記積層体に含まれる全ての制振層の厚みの合計（ｄ）と、上記積層体全体の厚み（Ｄ）が、ｄ／Ｄ＝０．０２～０．１８の関係を満たす制振性繊維強化樹脂成形体を第一の要旨とし、トルクロッド、サスペンションアーム、ロアアーム、タワーバー、プロペラシャフト、インパクトビーム、スタビバー、サブフレーム、バンパーまたはサイドドアビームである自動車用部品であって、上記第一の要旨の制振性繊維強化樹脂成形体を構成部材としてなる自動車用部品を第二の要旨とする。 In order to achieve the above object, the present invention provides a vibration-damping fiber-reinforced resin molded body that is a laminate of a fiber-reinforced resin layer in which a resin is infiltrated into a woven fabric and a vibration-damping layer made of a synthetic resin. In addition, the layer located in the center with respect to the thickness direction of the laminate is a central fiber reinforced resin layer, and upper and lower vibration damping layers are provided so as to sandwich it, and outer fiber reinforced resin layers are respectively provided on the outside thereof. And the thickness (X) from the laminated body center plane which is the central plane of the thickness direction of the laminated body to the interface between the central fiber reinforced resin layer and each damping layer, and from the laminated body central plane to the laminated body surface Satisfies the relationship of X / Y = 0.19 to 0.89. Furthermore, the total thickness (d) of all the damping layers included in the laminate, and the entire laminate A damping fiber reinforced resin composition having a thickness (D) satisfying the relationship of d / D = 0.02 to 0.18 A vehicle component having a body as a first gist and being a torque rod, suspension arm, lower arm, tower bar, propeller shaft, impact beam, stabilizer bar, sub-frame, bumper or side door beam. A second gist of the present invention is an automotive part that uses a vibration fiber reinforced resin molded article as a constituent member.
　すなわち、本発明者らは、前記課題を解決するため鋭意研究を重ねた。その研究の過程で、本発明者らは、繊維強化樹脂成形体を、強度等の観点から、樹脂を織布に浸潤させてなる繊維強化樹脂層と、合成樹脂製の制振層との積層体として形成することを想起し、試作を重ね、各種実験を繰り返し行った。その結果、制振層の厚みや層構成が、制振性や、強度・剛性といった特性に大きく影響することを突き止めた。そして、その積層体の厚み方向に対し中央に位置する層を繊維強化樹脂層（中央繊維強化樹脂層）とし、それを挟むように上下の制振層を設け、さらにその外側に繊維強化樹脂層をそれぞれ設け、かつ、上記積層体の厚み方向の中心面である積層体中心面から上記中央繊維強化樹脂層と各制振層との界面までの厚み（Ｘ）と、上記積層体中心面から積層体表面までの厚み（Ｙ）が、Ｘ／Ｙ＝０．１９～０．８９の関係を満たし、さらに、上記積層体に含まれる全ての制振層の厚みの合計（ｄ）と、上記積層体全体の厚み（Ｄ）が、ｄ／Ｄ＝０．０２～０．１８の関係を満たすようにしたところ、強度や剛性を損なうことなく、制振性に優れるようになり、所期の目的が達成できることを見いだし、本発明に到達した。 That is, the present inventors have conducted intensive research to solve the above problems. In the course of the research, the present inventors have laminated a fiber reinforced resin molded body from a fiber reinforced resin layer in which a resin is infiltrated into a woven fabric and a vibration damping layer made of a synthetic resin from the viewpoint of strength and the like. Recalling that it was formed as a body, repeated trials and repeated various experiments. As a result, it was found that the thickness and the layer structure of the damping layer have a great influence on the damping properties and the characteristics such as strength and rigidity. And the layer located in the center with respect to the thickness direction of the laminate is a fiber reinforced resin layer (central fiber reinforced resin layer), and upper and lower vibration damping layers are provided so as to sandwich the layer, and further the fiber reinforced resin layer And a thickness (X) from the center of the laminate that is the center plane in the thickness direction of the laminate to the interface between the central fiber reinforced resin layer and each damping layer, and from the center of the laminate The thickness (Y) to the surface of the laminate satisfies the relationship of X / Y = 0.19 to 0.89, and further, the total thickness (d) of all the damping layers included in the laminate, When the thickness (D) of the entire laminated body satisfies the relationship of d / D = 0.02 to 0.18, the damping performance is improved without impairing the strength and rigidity. The inventors have found that the object can be achieved and have reached the present invention.
　以上のように、本発明の制振性繊維強化樹脂成形体は、樹脂を織布に浸潤させてなる繊維強化樹脂層と合成樹脂製の制振層との積層体である制振性繊維強化樹脂成形体であって、その積層体の厚み方向に対し中央に位置する層が中央繊維強化樹脂層であり、それを挟むように上下の制振層が設けられ、その外側に外側繊維強化樹脂層がそれぞれ設けられ、かつ、上記積層体の厚み方向の中心面である積層体中心面から上記中央繊維強化樹脂層と各制振層との界面までの厚み（Ｘ）と、上記積層体中心面から積層体表面までの厚み（Ｙ）が、Ｘ／Ｙ＝０．１９～０．８９の関係を満たし、さらに、上記積層体に含まれる全ての制振層の厚みの合計（ｄ）と、上記積層体全体の厚み（Ｄ）が、ｄ／Ｄ＝０．０２～０．１８の関係を満たす。そのため、強度・剛性や、制振性に優れており、さらには、通常のＦＲＰよりも曲げに対する粘りが高く、疲労耐久特性にも優れているとともに、耐熱性も高いことから、自動車用部品等の用途に好ましく用いることができる。 As described above, the vibration-damping fiber reinforced resin molded product of the present invention is a vibration-damping fiber reinforced fiber that is a laminate of a fiber-reinforced resin layer obtained by infiltrating a resin into a woven fabric and a vibration-damping layer made of a synthetic resin. A resin molded body in which the layer located in the center with respect to the thickness direction of the laminate is a central fiber reinforced resin layer, and upper and lower vibration damping layers are provided so as to sandwich the layer, and an outer fiber reinforced resin is provided outside the layer. Each layer is provided, and the thickness (X) from the center surface of the laminate, which is the center plane in the thickness direction of the laminate, to the interface between the central fiber reinforced resin layer and each damping layer, and the center of the laminate The thickness (Y) from the surface to the laminate surface satisfies the relationship of X / Y = 0.19 to 0.89, and the total thickness (d) of all the damping layers included in the laminate The thickness (D) of the entire laminate satisfies the relationship d / D = 0.02 to 0.18. Therefore, it has excellent strength / rigidity and vibration damping properties. Furthermore, it has higher bending resistance than normal FRP, excellent fatigue durability characteristics, and high heat resistance. It can be preferably used for the use.
　特に、上記制振層がポリアミド樹脂からなり、上記繊維強化樹脂層の樹脂がエポキシ樹脂からなると、両層の層間接着性において、より優れるようになる。 In particular, when the vibration damping layer is made of a polyamide resin and the resin of the fiber reinforced resin layer is made of an epoxy resin, the interlayer adhesion between the two layers becomes more excellent.
　また、上記制振層が、合成樹脂製の織布からなると、より強固な層間接着性が得られるようになる。 Further, when the vibration damping layer is made of a woven fabric made of synthetic resin, stronger interlayer adhesion can be obtained.
　また、上記中央繊維強化樹脂層が、複数の繊維強化樹脂層の積層体からなると、中央繊維強化樹脂層の厚みの設定等がしやすくなる。 Further, when the central fiber reinforced resin layer is composed of a laminate of a plurality of fiber reinforced resin layers, the thickness of the central fiber reinforced resin layer can be easily set.
　また、上記積層体全体の厚みが１．９～７．４ｍｍであると、成形性の点で良好となる。 In addition, when the thickness of the entire laminate is 1.9 to 7.4 mm, the moldability is good.
　また、上記制振層の厚みが０．０４～０．４ｍｍであると、制振性制御や曲げ強度等の点で良好となる。 In addition, when the thickness of the vibration damping layer is 0.04 to 0.4 mm, the vibration damping performance and bending strength are good.
　また、上記織布が、炭素繊維，ガラス繊維，アラミド繊維またはバサルト繊維の連続繊維を、綾織，平織または朱子織りしてなるものであると、補強性等の点で良好となる。 Further, when the woven fabric is formed by weaving a continuous fiber of carbon fiber, glass fiber, aramid fiber or basalt fiber, weave, plain weave, or satin weave, it is favorable in terms of reinforcement.
　また、上記繊維強化樹脂層の樹脂中に、チタン酸カリウム、アルミナ、酸化亜鉛、および酸化チタンからなる群から選ばれた少なくとも一つの無機材料を含有すると、強度・剛性の発現率の向上性により優れるようになる。 Moreover, when the fiber reinforced resin layer contains at least one inorganic material selected from the group consisting of potassium titanate, alumina, zinc oxide, and titanium oxide, the improvement in strength and rigidity can be achieved. Become better.
　そして、本発明の制振性繊維強化樹脂成形体は、上記のような効果により、トルクロッド、サスペンションアーム、ロアアーム、タワーバー、プロペラシャフト、インパクトビーム、スタビバー、サブフレーム、バンパー、サイドドアビームといった自動車用部品の構成部材として有効に使用することができる。また、本発明の制振性繊維強化樹脂成形体は、シート状の制振性繊維強化樹脂成形体の賦型品として提供することもできる。 And the vibration-damping fiber reinforced resin molded product of the present invention is an automobile such as a torque rod, a suspension arm, a lower arm, a tower bar, a propeller shaft, an impact beam, a stabilizer bar, a subframe, a bumper, and a side door beam due to the above effects. It can be effectively used as a component member of a machine part. The vibration-damping fiber reinforced resin molded article of the present invention can also be provided as a molded product of a sheet-like vibration-damping fiber reinforced resin molded article.
本発明の制振性繊維強化樹脂成形体断面の一例を示す模式図である。It is a schematic diagram which shows an example of the cross section of the damping fiber reinforced resin molding of this invention.
　つぎに、本発明の実施の形態を詳しく説明する。 Next, an embodiment of the present invention will be described in detail.
　本発明の制振性繊維強化樹脂成形体は、樹脂を織布に浸潤させてなる繊維強化樹脂層と合成樹脂製の制振層との積層体である制振性繊維強化樹脂成形体であって、その積層体の厚み方向に対し中央に位置する層が中央繊維強化樹脂層であり、それを挟むように上下の制振層が設けられ、その外側に外側繊維強化樹脂層がそれぞれ設けられ、かつ、上記積層体の厚み方向の中心面である積層体中心面から上記中央繊維強化樹脂層と各制振層との界面までの厚み（Ｘ）と、上記積層体中心面から積層体表面までの厚み（Ｙ）が、Ｘ／Ｙ＝０．１９～０．８９の関係を満たし、さらに、上記積層体に含まれる全ての制振層の厚みの合計（ｄ）と、上記積層体全体の厚み（Ｄ）が、ｄ／Ｄ＝０．０２～０．１８の関係を満たす必要がある。なお、曲げ強度と制振性の両立といった観点から、Ｘ／Ｙ＝０．２３～０．６９であることが好ましく、同様の観点から、ｄ／Ｄ＝０．０３～０．０８であることが好ましい。 The vibration-damping fiber-reinforced resin molded body of the present invention is a vibration-damping fiber-reinforced resin molded body that is a laminate of a fiber-reinforced resin layer obtained by infiltrating a resin into a woven fabric and a vibration-damping layer made of a synthetic resin. The layer located in the center with respect to the thickness direction of the laminate is the central fiber reinforced resin layer, and the upper and lower vibration damping layers are provided so as to sandwich the layer, and the outer fiber reinforced resin layer is provided outside thereof. And the thickness (X) from the laminated body center plane which is the central plane of the thickness direction of the laminated body to the interface between the central fiber reinforced resin layer and each damping layer, and the laminated body surface from the laminated body central plane Thickness (Y) satisfies the relationship of X / Y = 0.19 to 0.89, and further, the total thickness (d) of all the damping layers included in the laminate, and the entire laminate Needs to satisfy the relationship of d / D = 0.02 to 0.18. Note that X / Y = 0.23 to 0.69 is preferable from the viewpoint of achieving both bending strength and vibration damping properties, and d / D = 0.03 to 0.08 from the same viewpoint. Is preferred.
　本発明において、「積層体中心面」とは、上記のように、積層体の厚み方向の中心面を意味するため、実際の面（層間の界面）になるか否かを問わない。また、本発明において、「中央繊維強化樹脂層」は、繊維強化樹脂のみからなる層であるのなら、単層の繊維強化樹脂層で構成してもよいが、複数の繊維強化樹脂層で構成するほうが、上記中央繊維強化樹脂層を所望の厚みに形成するに際し、作りやすく、樹脂の浸潤もしやすくなる。 In the present invention, “laminated body central plane” means the central plane in the thickness direction of the laminated body as described above, and therefore, it does not matter whether it is an actual plane (interlayer interface) or not. Further, in the present invention, the “central fiber reinforced resin layer” may be composed of a single fiber reinforced resin layer as long as it is a layer made of only fiber reinforced resin, but is composed of a plurality of fiber reinforced resin layers. When the center fiber reinforced resin layer is formed to a desired thickness, it is easier to make and the resin is more easily infiltrated.
　なお、図１は、本発明の繊維強化樹脂成形体の断面の一例（後述の実施例１）を示す模式図であり、１は繊維強化樹脂層、２は制振層である。そして、図１では、上記中央繊維強化樹脂層は、図示のように二層の繊維強化樹脂層１からなり、その中央繊維強化樹脂層を上下に挟む制振層２との界面から積層体中心面までの厚みが、図示のＸであり、上記積層体中心面から積層体表面までの厚みが、図示のＹである。また、本発明では、図１に示すように、その積層構造が、積層体中心面で上下対称となっていることが制振性等の観点から好ましいが、本発明はこれに限定されず、先に述べたＸ／Ｙの関係およびｄ／Ｄの関係を上下とも満たすのであれば、非対称であってもよい。また、図１では、上記積層体中心面から積層体表面までの間に制振層２が上下とも一層ずつしか設けられていないが、本発明では、上記積層体中心面から積層体表面までの間に制振層を二層以上設けるようにしてもよい。その場合、上記Ｘは、最も積層体中心面に近い制振層と中央繊維強化樹脂層との界面から、積層体中心面までの厚みで規定する必要がある。また、図１では、制振層２は合計二層設けられていることから、上記ｄは、図１においては、この二層の厚みの合計である。 FIG. 1 is a schematic view showing an example of a cross section of the fiber reinforced resin molded article of the present invention (Example 1 described later), where 1 is a fiber reinforced resin layer and 2 is a vibration damping layer. And in FIG. 1, the said center fiber reinforced resin layer consists of two layers of fiber reinforced resin layers 1 as shown in figure, and the laminated body center from the interface with the damping layer 2 which pinches | interposes the center fiber reinforced resin layer up and down. The thickness up to the surface is X in the figure, and the thickness from the laminate center plane to the laminate surface is Y in the figure. Further, in the present invention, as shown in FIG. 1, it is preferable from the viewpoint of vibration damping properties and the like that the stacked structure is vertically symmetrical on the center plane of the stacked body, but the present invention is not limited to this, As long as the X / Y relationship and the d / D relationship described above are satisfied both in the upper and lower directions, they may be asymmetrical. Further, in FIG. 1, only one damping layer 2 is provided on both the upper and lower sides between the laminated body center plane and the laminated body surface. However, in the present invention, the laminated body central plane to the laminated body surface are provided. Two or more damping layers may be provided between them. In that case, the above X needs to be defined by the thickness from the interface between the vibration damping layer closest to the laminate center plane and the central fiber reinforced resin layer to the laminate center plane. Further, in FIG. 1, since the damping layer 2 is provided in total two layers, the above d is the total thickness of these two layers in FIG.
　また、図１からも明らかなように、本発明では、上記Ｄと、上記Ｙとは、Ｄ＝２Ｙの関係にある。そして、本発明において、上記Ｄ、すなわち、本発明の制振性繊維強化樹脂成形体全体の厚みは、成形性の観点から、１．９～７．４ｍｍであることが好ましく、より好ましくは２．０～３．０ｍｍの範囲である。また、上記制振層の厚みは、制振性制御や曲げ強度等の観点から、０．０４～０．４ｍｍであることが好ましく、より好ましくは０．１２～０．２ｍｍの範囲である。 Further, as is clear from FIG. 1, in the present invention, the above D and the above Y have a relationship of D = 2Y. In the present invention, the above D, that is, the thickness of the entire vibration-damping fiber-reinforced resin molded body of the present invention is preferably 1.9 to 7.4 mm, more preferably 2 from the viewpoint of moldability. The range is from 0.0 to 3.0 mm. The thickness of the damping layer is preferably 0.04 to 0.4 mm, more preferably 0.12 to 0.2 mm, from the viewpoint of damping control and bending strength.
　なお、本発明の制振性繊維強化樹脂成形体は、図１に示すようなシート状のものに限定されるものではなく、プレス成型等により、所望の形状となるよう賦型したものであってもよい。但し、その場合であっても、先に述べた本発明の層構成の関係は満たす必要がある。 The vibration-damping fiber reinforced resin molded product of the present invention is not limited to a sheet-like product as shown in FIG. 1, but is molded to a desired shape by press molding or the like. May be. However, even in that case, it is necessary to satisfy the relationship of the layer configuration of the present invention described above.
　本発明の制振性繊維強化樹脂成形体において、上記繊維強化樹脂層は、先に述べたように、樹脂を織布に浸潤させてなる層である。そして、上記織布は、炭素繊維，ガラス繊維，アラミド繊維またはバサルト繊維の連続繊維を、綾織，平織または朱子織りしてなるものであるが、一部に一方向に配列した繊維（一方向繊維）を用いても構わない。特に、成形体として様々な角度（方向）からの力に対する強度、耐疲労性の観点からは、炭素繊維からなる織布が好ましく、コスト等の観点からは、ガラス繊維からなる織布が好ましい。また、上記織布は、２～２０ｍｍ幅で１０００～２４０００本の、繊維径５～７μｍの連続繊維を織って形成されるものであり、その織布の重さは、６１～２００ｇ／ｍ2、厚みは０．０８５～０．２５ｍｍであることが、補強性等の観点から好ましい。 In the vibration-damping fiber-reinforced resin molded body of the present invention, the fiber-reinforced resin layer is a layer formed by infiltrating a resin into a woven fabric as described above. The woven fabric is made by twilling, plain weaving, or satin weaving continuous fibers of carbon fiber, glass fiber, aramid fiber or basalt fiber. ) May be used. In particular, a woven fabric made of carbon fiber is preferable from the viewpoint of strength against forces from various angles (directions) and fatigue resistance, and a woven fabric made of glass fiber is preferable from the viewpoint of cost and the like. The woven fabric is formed by weaving 1000 to 24000 continuous fibers having a width of 2 to 20 mm and a fiber diameter of 5 to 7 μm, and the weight of the woven fabric is 61 to 200 g / m 2. The thickness is preferably 0.085 to 0.25 mm from the viewpoint of reinforcing properties and the like.
　そして、上記織布に浸潤させる樹脂としては、熱可塑性樹脂または熱硬化性樹脂が用いられる。 Further, as the resin to be infiltrated into the woven fabric, a thermoplastic resin or a thermosetting resin is used.
　上記熱可塑性樹脂としては、ポリアミド樹脂、ポリオレフィン樹脂、アクリロニトリルブタジエンスチレン樹脂、ポリエステル樹脂、ポリカーボネート樹脂、ポリスチレン樹脂、ポリアセタール樹脂、変性ポリフェニレンエーテル樹脂、ポリフェニレンサルファイド樹脂、ポリエーテルイミド樹脂、ポリエーテルエーテルケトン樹脂、ポリエーテルサルホン樹脂、熱可塑性エラストマー等があげられる。これらは単独でもしくは二種以上併せて用いられる。 Examples of the thermoplastic resin include polyamide resin, polyolefin resin, acrylonitrile butadiene styrene resin, polyester resin, polycarbonate resin, polystyrene resin, polyacetal resin, modified polyphenylene ether resin, polyphenylene sulfide resin, polyether imide resin, polyether ether ketone resin, Examples thereof include polyether sulfone resin and thermoplastic elastomer. These may be used alone or in combination of two or more.
　上記熱硬化性樹脂としては、エポキシ樹脂、不飽和ポリエステル樹脂、ビニルエステル樹脂、フェノール樹脂等があげられる。これらは単独でもしくは二種以上併せて用いられる。 Examples of the thermosetting resin include epoxy resins, unsaturated polyester resins, vinyl ester resins, and phenol resins. These may be used alone or in combination of two or more.
　なお、上記樹脂中には、強度・剛性向上および収縮（ヒケ・ソリ）防止などを目的として、タルク、シリカ、カーボンブラック、酸化チタン、酸化亜鉛、チタン酸カリウム、アルミナ等の無機材料を添加してもよい。なかでも、モース硬度が４以上の無機材料を添加することが、強度・剛性の発現率の向上の観点から好ましい。具体的には、チタン酸カリウム、アルミナ、酸化亜鉛、酸化チタンといった無機材料である。なお、上記モース硬度は、モース硬度計(東京サイエンス社製)により測定された値である。上記無機材料の添加量は、強度・剛性の発現率の向上の観点から、上記樹脂１００重量部に対し、１～１５重量部とすることが好ましく、より好ましくは５～１０重量部の範囲である。上記樹脂の混練は、（三本）ロール、ニーダー、バンバリーミキサー等で行うことが適当であり、特に加工性の面で、ロールによる混練が好ましい。
　このようにして、繊維強化樹脂層中に無機材料が含まれることにより、本発明の制振性繊維強化樹脂成形体の曲げ弾性率は高くなり、耐衝撃性やエネルギー吸収能が高まることとなる。 In addition, inorganic materials such as talc, silica, carbon black, titanium oxide, zinc oxide, potassium titanate, and alumina are added to the resin for the purpose of improving strength and rigidity and preventing shrinkage (sinking and warping). May be. Of these, the addition of an inorganic material having a Mohs hardness of 4 or more is preferable from the viewpoint of improving the strength and rigidity expression rate. Specifically, inorganic materials such as potassium titanate, alumina, zinc oxide, and titanium oxide are used. The Mohs hardness is a value measured with a Mohs hardness meter (manufactured by Tokyo Science). The amount of the inorganic material added is preferably 1 to 15 parts by weight, more preferably 5 to 10 parts by weight with respect to 100 parts by weight of the resin, from the viewpoint of improving the strength and rigidity expression rate. is there. It is appropriate to knead the resin with (three) rolls, kneaders, Banbury mixers, etc., and kneading with a roll is particularly preferred in terms of processability.
Thus, by including an inorganic material in the fiber reinforced resin layer, the bending elastic modulus of the vibration-damping fiber reinforced resin molded article of the present invention is increased, and the impact resistance and energy absorption capacity are increased. .
　上記織布への樹脂の浸潤は、熱硬化性樹脂の場合はハンドレイアップ成形により行われ、熱可塑性樹脂の場合は、織布と熱可塑性樹脂シートとを重ね合わせて熱プレス等して、熱可塑性樹脂シートを溶融させることにより行われる。なお、上記ハンドレイアップ成形は、織布に樹脂溶液を塗布したり、樹脂溶液に織布を浸漬したりし、さらに、適宜ローラー等で均一にのばし、織布に樹脂溶液を染み込ませることにより行われる。 The infiltration of the resin into the woven fabric is performed by hand lay-up molding in the case of a thermosetting resin, and in the case of a thermoplastic resin, the woven fabric and a thermoplastic resin sheet are overlapped and subjected to a heat press or the like, It is performed by melting a thermoplastic resin sheet. The above hand lay-up molding is performed by applying a resin solution to the woven fabric or immersing the woven fabric in the resin solution, and further spreading it uniformly with a roller or the like so as to soak the resin solution into the woven fabric. Done.
　また、本発明の制振性繊維強化樹脂成形体において、上記制振層は、先に述べたように、合成樹脂からなる層であり、熱可塑性樹脂からなる層であってもよく、熱硬化性樹脂からなる層であってもよい。但し、制振性が要求されることから、２５℃下で、ｔａｎδ＝０．０３以上の樹脂であることが望ましい。特に、ポリアミド６やポリアミド１２にポリプロピレンを含有させたアロイ材が、制振性等が高まるため、好ましい。 Further, in the vibration-damping fiber reinforced resin molded article of the present invention, as described above, the vibration-damping layer is a layer made of a synthetic resin, and may be a layer made of a thermoplastic resin, and is thermoset. It may be a layer made of a functional resin. However, since vibration damping is required, it is desirable that the resin is tan δ = 0.03 or more at 25 ° C. In particular, an alloy material in which polypropylene is added to polyamide 6 or polyamide 12 is preferable because vibration damping properties and the like are improved.
　なお、本発明の制振性繊維強化樹脂成形体においては、上記制振層がポリアミド樹脂（もしくは上記のようなポリアミド樹脂のアロイ材）からなり、上記繊維強化樹脂層の樹脂がエポキシ樹脂からなるものであることが好ましい。なぜなら、この組合せが、両層の層間接着性に優れるからである。なお、上記のように繊維強化樹脂層の樹脂はエポキシ樹脂のほうが、織布に浸潤しやすく、繊維強化樹脂層の強度も出やすくなり、また、上記のように制振層がポリアミド樹脂を材料とするほうが、制振性が高まるようにもなる。 In the vibration-damping fiber reinforced resin molded product of the present invention, the damping layer is made of a polyamide resin (or an alloy material of the polyamide resin as described above), and the resin of the fiber-reinforced resin layer is made of an epoxy resin. It is preferable. This is because this combination is excellent in interlayer adhesion between both layers. In addition, as described above, the resin of the fiber reinforced resin layer is more easily infiltrated into the woven fabric when the epoxy resin is used, and the strength of the fiber reinforced resin layer is also easily increased. As a result, the vibration control performance will be improved.
　上記制振層の形成は、熱硬化性樹脂の場合は、その樹脂溶液の塗布を繰り返し行うことによりなされ、熱可塑性樹脂の場合は、Ｔダイ等で押し出し成形し、所望の厚みの熱可塑性樹脂シート（熱可塑性樹脂フィルム）を作製し、それを積層することによりなされる。また、上記制振層は、上記記載の各種合成樹脂からなる連続繊維（好ましくは、ポリアミド６、ポリアミド６６からなる連続繊維）を、綾織，平織または朱子織りして得られた織布で構成してもよい。そして、制振性の観点からは、上記制振層は、熱可塑性樹脂シートで構成したものが好ましいが、層間密着性、曲げ強度、曲げ破断時伸びの観点からは、上記制振層は、上記記載の各種合成樹脂からなる織布（好適には、ポリアミド６、ポリアミド６６からなる織布）で構成したものが好ましい。すなわち、上記織布の織り目の間に繊維強化樹脂層の樹脂が浸透して強固な層間密着性が確保され、さらに、上記織布の織り目により制振層の曲げ特性が高まるからである。なお、上記織布は、１ｃｍ幅で３９～６５本の、繊維径０．０１～０．０８ｍｍの連続繊維を織って形成されるものであり、厚みは０．０２～０．１ｍｍで、その織布の重さは、１．４～１．７ｇ／ｃｍ2であることが、曲げ強度および曲げ破断時伸びの等の観点から好ましい。 In the case of a thermosetting resin, the vibration damping layer is formed by repeatedly applying the resin solution. In the case of a thermoplastic resin, it is extruded by a T-die or the like, and a thermoplastic resin having a desired thickness is formed. It is made by preparing a sheet (thermoplastic resin film) and laminating it. The vibration damping layer is made of a woven fabric obtained by twilling, plain weaving, or satin weaving continuous fibers made of the various synthetic resins described above (preferably, continuous fibers made of polyamide 6 and polyamide 66). May be. And, from the viewpoint of damping properties, the damping layer is preferably composed of a thermoplastic resin sheet, but from the viewpoint of interlayer adhesion, bending strength, and elongation at bending break, the damping layer is What was comprised with the woven fabric (preferably the woven fabric which consists of polyamide 6 and polyamide 66) consisting of the various synthetic resin of the said description is preferable. That is, the resin of the fiber reinforced resin layer permeates between the weaves of the woven fabric to ensure strong interlayer adhesion, and the bending properties of the vibration damping layer are enhanced by the weave of the woven fabric. The woven fabric is formed by weaving 39 to 65 continuous fibers having a 1 cm width and a fiber diameter of 0.01 to 0.08 mm, and has a thickness of 0.02 to 0.1 mm. The weight of the woven fabric is preferably 1.4 to 1.7 g / cm 2 from the viewpoints of bending strength and bending elongation at break.
　そして、本発明に規定された順序で繊維強化樹脂層および制振層を積層し、必要に応じ、金型等を用いて賦型することにより、目的とする制振性繊維強化樹脂成形体を得ることができる。 And the fiber reinforced resin layer and the vibration damping layer are laminated in the order prescribed in the present invention, and if necessary, it is molded using a mold or the like to obtain the desired vibration damping fiber reinforced resin molded product. Obtainable.
　ここで、例えば、繊維強化樹脂層の樹脂が熱硬化性樹脂であり、制振層が熱可塑性樹脂からなる場合、繊維強化樹脂層は、先に述べたようにハンドレイアップ成形により形成し、制振層は熱可塑性樹脂フィルムを積層することにより形成して、目的とする積層体を得ることができる。なお、上記積層体を所望の形状に賦型する際には、上記積層体を袋に入れて真空ポンプで空気を抜き、プレス機でつぶす（圧力は５ｋＮ～１００ｋＮ）ことにより、その賦型が行われる。なお、上記プレス時には適当な温度を加えてもよい。 Here, for example, when the resin of the fiber reinforced resin layer is a thermosetting resin and the vibration damping layer is made of a thermoplastic resin, the fiber reinforced resin layer is formed by hand lay-up molding as described above, The damping layer can be formed by laminating a thermoplastic resin film to obtain a desired laminate. When the laminate is molded into a desired shape, the laminate is put in a bag, evacuated with a vacuum pump, and crushed with a press machine (pressure is 5 kN to 100 kN). Done. An appropriate temperature may be applied during the pressing.
　また、例えば、繊維強化樹脂層の樹脂が熱可塑性樹脂であり、制振層が熱硬化性樹脂からなる場合、繊維強化樹脂層は、先に述べたように織布と熱可塑性樹脂シートとを重ね合わせて熱プレス等して、熱可塑性樹脂シートを溶融させることにより形成し、制振層はその樹脂溶液の塗布を繰り返し行うことにより形成して、目的とする積層体を得ることができる。なお、上記熱プレスは、制振層用の樹脂溶液の塗布も含め、全て行った後、その積層体に対し、熱可塑性樹脂の融点以上あるいは制振層の硬化温度以上でプレスするようにしてもよい。そして、必要に応じ、上記熱プレスに際し、金型等を用いて所望の形状となるよう賦型することができる。 For example, when the resin of the fiber reinforced resin layer is a thermoplastic resin and the vibration damping layer is made of a thermosetting resin, the fiber reinforced resin layer includes a woven fabric and a thermoplastic resin sheet as described above. The thermoplastic resin sheet is formed by melting and heat-pressing and the like, and the damping layer is formed by repeatedly applying the resin solution to obtain a target laminate. In addition, after performing all the heat presses including the application of the resin solution for the vibration damping layer, the laminate is pressed at a temperature equal to or higher than the melting point of the thermoplastic resin or higher than the curing temperature of the vibration damping layer. Also good. And if needed, it can shape | mold so that it may become a desired shape using the metal mold | die etc. in the case of the said hot press.
　上記のようにして得られた本発明の制振性繊維強化樹脂成形体は、強度・剛性や、制振性に優れており、さらには、通常のＦＲＰよりも曲げに対する粘りが高く、疲労耐久特性にも優れているとともに、耐熱性にも優れていることから、例えば、トルクロッド，サスペンションアーム，ロアアーム，タワーバー，プロペラシャフト，インパクトビーム，スタビバー，サブフレーム，バンパー，サイドドアビーム等の自動車用部品の構成部材として好適に用いられる。また、本発明の制振性繊維強化樹脂成形体は、その特徴である積層構造を保持するものであれば、自動車用部品以外にも、各種の用途（ロボットフォーク、橋梁、家屋、車椅子、電動カート、自転車等の構成部材）に用いることが可能である。 The vibration-damping fiber-reinforced resin molded article of the present invention obtained as described above is excellent in strength / rigidity and vibration-damping property, and has higher bending resistance than ordinary FRP, and fatigue durability. Because of its excellent characteristics and heat resistance, it can be used for automobiles such as torque rods, suspension arms, lower arms, tower bars, propeller shafts, impact beams, stabilizer bars, subframes, bumpers, and side door beams. It is suitably used as a component member of a part. Further, the vibration-damping fiber reinforced resin molded body of the present invention can be used for various purposes (robot forks, bridges, houses, wheelchairs, electric motors) in addition to automotive parts, as long as it retains the laminated structure that is the feature. It can be used for components such as carts and bicycles.
　つぎに、実施例について、比較例および参考例と併せて説明する。ただし、本発明は、その要旨を超えない限り、これら実施例に限定されるものではない。 Next, examples will be described together with comparative examples and reference examples. However, the present invention is not limited to these examples as long as the gist thereof is not exceeded.
［実施例１～１２、比較例１～５］
　ハンドレイアップ成形により、後記の表１、表２および表４に示す層構成となるよう各層を平面上に積層し、繊維強化樹脂の積層体を作製した。なお、表１、表２および表４に示す「ＣＦＲＰ」層は、エポキシ樹脂（大都産業社製、ダイトサイザー８２８）と、その硬化剤（ＡＤＥＫＡ社製、アデカハードナーＥＨ６００７）を、重量比で、エポキシ樹脂：硬化剤＝２：１でブレンドして得られた樹脂溶液を、炭素繊維クロス（東邦テナックス社製、テナックス（織組織：２ｍｍ幅で３０００本の炭素繊維（繊維径７μｍ）を綾織したもの、重さ：２００ｇ／ｍ2、厚み：０．２５ｍｍ））に塗布しローラーで均一にのばして、炭素繊維クロスに樹脂溶液を浸潤させて形成したものである。また、表１、表２および表４に示す「ＰＡ１２」層は、ポリアミド１２のアロイ材（宇部興産社製、３０３０ＪＩ６Ｌ）からなるフィルムを積層したものであり、「ＰＡ６」層は、ポリアミド６のアロイ材（Ｄｕｐｏｎｔ社製、ＳＴ８１１ＨＳ）からなるフィルムを積層したものである。また、表１、表２および表４に示す「ＰＡ６クロス」層は、アミラン２３５Ｔ－２４－７２０（東レ社製）を、織機を使用して平織した織物であり、「ＰＡ６６クロス」層は、４７００（旭化成せんい社製の平織物）である。また、表１、表２および表４に示す「Ｘ／Ｙ」は、本願請求項１に規定の「Ｘ／Ｙ」を計算したものであり、「ｄ／Ｄ」は、本願請求項１に規定の「ｄ／Ｄ」を計算したものである。 [Examples 1 to 12, Comparative Examples 1 to 5]
By hand lay-up molding, each layer was laminated on a plane so as to have the layer structure shown in Table 1, Table 2, and Table 4 below, and a laminate of fiber reinforced resin was produced. In addition, the “CFRP” layer shown in Table 1, Table 2 and Table 4 is an epoxy resin (manufactured by Daito Sangyo Co., Ltd., Daito Sizer 828) and its curing agent (manufactured by ADEKA Co., Ltd., Adeka Hardener EH6007) by weight ratio. The resin solution obtained by blending with epoxy resin: curing agent = 2: 1 was carbon fiber cloth (manufactured by Toho Tenax Co., Ltd., Tenax (woven structure: 2 mm width and 3000 carbon fibers (fiber diameter 7 μm)). , Weight: 200 g / m 2 , thickness: 0.25 mm)) and uniformly stretched with a roller, and a carbon fiber cloth is infiltrated with a resin solution. The “PA12” layer shown in Tables 1, 2 and 4 is a laminate of polyamide 12 alloy material (Ube Industries, 3030JI6L), and the “PA6” layer is made of polyamide 6. A film made of an alloy material (Dupont, ST811HS) is laminated. The “PA6 cloth” layer shown in Tables 1, 2 and 4 is a woven fabric obtained by plain weaving AMIRAN 235T-24-720 (manufactured by Toray Industries, Inc.) using a loom, and the “PA66 cloth” layer is 4700 (a plain fabric manufactured by Asahi Kasei Fibers). Further, “X / Y” shown in Table 1, Table 2 and Table 4 is obtained by calculating “X / Y” defined in claim 1 of the present application, and “d / D” is calculated in claim 1 of the present application. This is the calculated “d / D”.
［実施例１３～１６］
　ハンドレイアップ成形により、後記の表３に示す層構成となるよう各層を平面上に積層し、繊維強化樹脂の積層体を作製した。なお、表３に示す「ＣＦＲＰ」層は、エポキシ樹脂（大都産業社製、ダイトサイザー８２８）１００重量部と、その硬化剤（ＡＤＥＫＡ社製、アデカハードナーＥＨ６００７）５０重量部と、無機材料(大塚化学社製、ティスモＤ)５重量部とを三本ロール(井上製作所社製)によりブレンドして得られた樹脂溶液を、炭素繊維クロス（東邦テナックス社製、テナックス（織組織：２ｍｍ幅で３０００本の炭素繊維（繊維径７μｍ）を綾織したもの、重さ：２００ｇ／ｍ2、厚み：０．２５ｍｍ））に塗布しローラーで均一にのばして、炭素繊維クロスに樹脂溶液を浸潤させて形成したものである。また、表３に示す「ＰＡ６クロス」層は、アミラン２３５Ｔ－２４－７２０（東レ社製）を、織機を使用して平織した織物であり、「ＰＡ６６クロス」層は、４７００（旭化成せんい社製の平織物）である。また、表３に示す「Ｘ／Ｙ」は、本願請求項１に規定の「Ｘ／Ｙ」を計算したものであり、「ｄ／Ｄ」は、本願請求項１に規定の「ｄ／Ｄ」を計算したものである。 [Examples 13 to 16]
By hand lay-up molding, each layer was laminated on a plane so as to have a layer configuration shown in Table 3 to be described later, and a laminate of fiber reinforced resin was produced. The “CFRP” layer shown in Table 3 consists of 100 parts by weight of an epoxy resin (manufactured by Daito Sangyo Co., Ltd., Daito Sizer 828), 50 parts by weight of its curing agent (manufactured by ADEKA Co., Ltd., Adeka Hardener EH6007), and an inorganic material (Otsuka). A resin solution obtained by blending 5 parts by weight of Tismo D, manufactured by Kagaku Co., Ltd., with a three roll (manufactured by Inoue Seisakusho Co., Ltd.) was used as a carbon fiber cloth (manufactured by Toho Tenax Co., Ltd. A carbon fiber cloth (fiber diameter 7 μm) twilled, weight: 200 g / m 2 , thickness: 0.25 mm)) and uniformly stretched with a roller to infiltrate the resin solution into the carbon fiber cloth. It is a thing. The “PA6 cloth” layer shown in Table 3 is a woven fabric obtained by plain weaving Amilan 235T-24-720 (manufactured by Toray Industries, Inc.) using a loom, and the “PA66 cloth” layer is 4700 (manufactured by Asahi Kasei Corporation). Plain fabric). “X / Y” shown in Table 3 is obtained by calculating “X / Y” defined in claim 1 of the present application, and “d / D” is “d / D” defined in claim 1 of the present application. Is calculated.
［参考例１］
　厚み２．０ｍｍの鋼板を用意し、これを参考例１とした。 [Reference Example 1]
A steel plate having a thickness of 2.0 mm was prepared and used as Reference Example 1.
［参考例２］
　厚み２．０ｍｍのアルミ板を用意し、これを参考例２とした。 [Reference Example 2]
An aluminum plate having a thickness of 2.0 mm was prepared and used as Reference Example 2.
　上記のようにして得られた実施例および比較例の繊維強化樹脂積層体、並びに参考例の金属板に対し、下記の基準に従い、各特性の評価を行った。これらの結果を、後記の表１～表４に併せて示した。 The properties of the fiber reinforced resin laminates of Examples and Comparative Examples obtained as described above and the metal plates of Reference Examples were evaluated according to the following criteria. These results are also shown in Tables 1 to 4 below.
〔曲げ弾性率〕
　各積層体（参考例は金属板）を、１５０ｍｍ×１０ｍｍの短冊状に切り出し、これをサンプルとして曲げ弾性率を測定した。このサンプルに対し、ＪＩＳ　Ｋ７０７４に準拠して、室温にて、試験速度２ｍｍ／ｍｉｎ、スパン間距離６４ｍｍで、３点曲げ試験を行い、歪み量（０．０５～０．２５％）の応力勾配を用いて曲げ弾性率（ＭＰａ）を測定した。 (Bending elastic modulus)
Each laminate (a reference example is a metal plate) was cut into a strip of 150 mm × 10 mm, and the flexural modulus was measured using this as a sample. A three-point bending test was performed on this sample in accordance with JIS K7074 at room temperature at a test speed of 2 mm / min and a span distance of 64 mm, and a stress gradient with a strain amount (0.05 to 0.25%) was obtained. Was used to measure the flexural modulus (MPa).
〔曲げ強度〕
　各積層体（参考例は金属板）を、１５０ｍｍ×１０ｍｍの短冊状に切り出し、これをサンプルとして曲げ強度を測定した。すなわち、このサンプルに対し、ＪＩＳ　Ｋ７０７４に準拠して、室温にて、試験速度２ｍｍ／ｍｉｎ、スパン間距離６４ｍｍで、３点曲げ試験を行い、その際の曲げ強度（ＭＰａ）を測定した。 [Bending strength]
Each laminate (a reference example is a metal plate) was cut into a strip of 150 mm × 10 mm, and the bending strength was measured using this as a sample. That is, according to JIS K7074, this sample was subjected to a three-point bending test at room temperature at a test speed of 2 mm / min and a span distance of 64 mm, and the bending strength (MPa) at that time was measured.
〔曲げ破断時伸び〕
　各積層体（参考例は金属板）を、１５０ｍｍ×１０ｍｍの短冊状に切り出し、これをサンプルとして曲げ破断時伸びを測定した。すなわち、このサンプルに対し、ＪＩＳ　Ｋ７０７４に準拠して、室温にて、試験速度２ｍｍ／ｍｉｎ、スパン間距離６４ｍｍで、３点曲げ試験を行い、その際の破断に至るまでの変位量から、曲げ破断時伸び（％）を測定した。 [Elongation at bending fracture]
Each laminated body (reference example is a metal plate) was cut into a strip shape of 150 mm × 10 mm, and the elongation at the time of bending fracture was measured using this as a sample. That is, according to JIS K7074, this sample was subjected to a three-point bending test at room temperature at a test speed of 2 mm / min and a span distance of 64 mm. The elongation at break (%) was measured.
〔減衰係数〕
　各積層体（参考例は金属板）を、１５０ｍｍ×１０ｍｍの短冊状に切り出し、これをサンプルとして減衰係数を測定した。すなわち、このサンプルに対し、ＪＩＳ　Ｇ０６０２「制振鋼板の振動減衰特性試験法」に準拠して、片端固定打撃法にて試験を実施し、ヒルベルト変換を用いて常態時損失係数（減衰係数）を求めた。 [Attenuation coefficient]
Each laminate (a reference example is a metal plate) was cut into a strip of 150 mm × 10 mm, and the attenuation coefficient was measured using this as a sample. That is, this sample was tested by the single-end fixed impact method in accordance with JIS G0602 “Test method for vibration damping characteristics of damping steel plate”, and the loss factor (damping factor) at normal time was calculated using Hilbert transform. Asked.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
　上記結果より、実施例の繊維強化樹脂積層体は、曲げ強度が高く、剛性に優れているとともに、減衰係数が大きいことから、制振性にも優れることがわかる。 From the above results, it can be seen that the fiber reinforced resin laminates of the examples have high bending strength, excellent rigidity, and a large damping coefficient, so that they also have excellent vibration damping properties.
　これに対し、比較例１の繊維強化樹脂積層体は、制振層となる層がないことから、実施例のものよりも減衰係数が小さく、制振性に劣る結果となった。比較例２の繊維強化樹脂積層体は、制振層となる層を有するものの、１層しかないことから、やはり実施例のものよりも減衰係数が小さく、制振性に劣る結果となった。比較例３の繊維強化樹脂積層体は、制振層となるＰＡ層を多数有しており、積層体に含まれる全てのＰＡ層の厚みの合計が占める割合（ｄ／Ｄ）が、本願発明の規定範囲を超えるものであることから、実施例のものよりも曲げ強度が小さく、剛性に劣る結果となった。比較例４および比較例５の繊維強化樹脂積層体は、積層体に含まれる全てのＰＡ層の厚みの合計が占める割合（ｄ／Ｄ）は本願発明の規定範囲内であるものの、制振層であるＰＡ層が最外層(一番外側)に設けられており、ＣＦＲＰ層とＰＡ層との界面が積層体の中央から離れ過ぎている（「Ｘ／Ｙ」が本願発明の規定範囲を超える）ことから、実施例のものよりも曲げ強度が小さく、剛性に劣る結果となった。 On the other hand, since the fiber reinforced resin laminate of Comparative Example 1 had no layer to be a damping layer, the damping coefficient was smaller than that of the example and resulted in inferior damping properties. Although the fiber reinforced resin laminate of Comparative Example 2 has a layer serving as a vibration damping layer, since it has only one layer, the damping coefficient is also smaller than that of the example and results in inferior vibration damping properties. The fiber reinforced resin laminate of Comparative Example 3 has a large number of PA layers serving as damping layers, and the ratio (d / D) of the total thickness of all PA layers contained in the laminate is the present invention. Therefore, the bending strength was smaller than that of the example and the rigidity was inferior. In the fiber reinforced resin laminates of Comparative Example 4 and Comparative Example 5, the ratio (d / D) of the total thickness of all PA layers contained in the laminate is within the specified range of the present invention, but the damping layer The PA layer is provided on the outermost layer (outermost side), and the interface between the CFRP layer and the PA layer is too far from the center of the laminate (“X / Y” exceeds the specified range of the present invention) Therefore, the bending strength was smaller than that of the example and the result was inferior in rigidity.
　なお、上記実施例においては、本発明における具体的な形態について示したが、上記実施例は単なる例示にすぎず、限定的に解釈されるものではない。当業者に明らかな様々な変形は、本発明の範囲内であることが企図されている。 In addition, although the specific form in this invention was shown in the said Example, the said Example is only a mere illustration and is not interpreted limitedly. Various modifications apparent to those skilled in the art are contemplated to be within the scope of this invention.
　本発明の制振性繊維強化樹脂成形体は、その特徴である積層構造を保持するものであれば、自動車用部品以外にも、各種の用途（ロボットフォーク、橋梁、家屋、車椅子、電動カート、自転車等の構成部材）に用いることが可能である。 The vibration-damping fiber-reinforced resin molded body of the present invention can be used for various applications (robot forks, bridges, houses, wheelchairs, electric carts, It can be used for components such as bicycles.
　１：繊維強化樹脂層
　２：制振層 1: Fiber reinforced resin layer 2: Damping layer

Claims (10)

  1. 　樹脂を織布に浸潤させてなる繊維強化樹脂層と合成樹脂製の制振層との積層体である制振性繊維強化樹脂成形体であって、その積層体の厚み方向に対し中央に位置する層が中央繊維強化樹脂層であり、それを挟むように上下の制振層が設けられ、その外側に外側繊維強化樹脂層がそれぞれ設けられ、かつ、上記積層体の厚み方向の中心面である積層体中心面から上記中央繊維強化樹脂層と各制振層との界面までの厚み（Ｘ）と、上記積層体中心面から積層体表面までの厚み（Ｙ）が、Ｘ／Ｙ＝０．１９～０．８９の関係を満たし、さらに、上記積層体に含まれる全ての制振層の厚みの合計（ｄ）と、上記積層体全体の厚み（Ｄ）が、ｄ／Ｄ＝０．０２～０．１８の関係を満たすことを特徴とする制振性繊維強化樹脂成形体。 A vibration-damping fiber-reinforced resin molded body that is a laminate of a fiber-reinforced resin layer infiltrated into a woven fabric and a synthetic resin damping layer, and is located in the center with respect to the thickness direction of the laminate And the upper and lower damping layers are provided so as to sandwich the layer, the outer fiber reinforced resin layers are provided on the outer sides thereof, and the center surface in the thickness direction of the laminate is provided. The thickness (X) from a certain laminate central surface to the interface between the central fiber reinforced resin layer and each damping layer and the thickness (Y) from the laminate central surface to the laminate surface are X / Y = 0. 19 to 0.89, and the total thickness (d) of all the damping layers included in the laminate and the total thickness (D) of the laminate are d / D = 0. A vibration-damping fiber-reinforced resin molded product satisfying the relationship of 02 to 0.18.
  2. 　上記制振層がポリアミド樹脂からなり、上記繊維強化樹脂層の樹脂がエポキシ樹脂からなる、請求項１記載の制振性繊維強化樹脂成形体。 The vibration-damping fiber reinforced resin molded article according to claim 1, wherein the vibration damping layer is made of a polyamide resin, and the resin of the fiber reinforced resin layer is made of an epoxy resin.
  3. 　上記制振層が、合成樹脂製の織布からなる、請求項１または２記載の制振性繊維強化樹脂成形体。 The vibration-damping fiber-reinforced resin molded body according to claim 1 or 2, wherein the vibration-damping layer is made of a synthetic resin woven fabric.
  4. 　上記中央繊維強化樹脂層が、複数の繊維強化樹脂層の積層体からなる、請求項１～３のいずれか一項に記載の制振性繊維強化樹脂成形体。 The vibration-damping fiber-reinforced resin molded product according to any one of claims 1 to 3, wherein the central fiber-reinforced resin layer is composed of a laminate of a plurality of fiber-reinforced resin layers.
  5. 　上記積層体全体の厚みが１．９～７．４ｍｍである、請求項１～４のいずれか一項に記載の制振性繊維強化樹脂成形体。 The vibration-damping fiber-reinforced resin molded body according to any one of claims 1 to 4, wherein the thickness of the entire laminate is 1.9 to 7.4 mm.
  6. 　上記制振層の厚みが０．０４～０．４ｍｍである、請求項１～５のいずれか一項に記載の制振性繊維強化樹脂成形体。 The vibration-damping fiber-reinforced resin molded article according to any one of claims 1 to 5, wherein the vibration-damping layer has a thickness of 0.04 to 0.4 mm.
  7. 　上記織布が、炭素繊維，ガラス繊維，アラミド繊維またはバサルト繊維の連続繊維を、綾織，平織または朱子織りしてなるものである、請求項１～６のいずれか一項に記載の制振性繊維強化樹脂成形体。 The vibration damping property according to any one of claims 1 to 6, wherein the woven fabric is formed by twilling, plain weaving, or satin weaving continuous fibers of carbon fiber, glass fiber, aramid fiber or basalt fiber. Fiber reinforced resin molding.
  8. 　上記繊維強化樹脂層の樹脂中に、チタン酸カリウム、アルミナ、酸化亜鉛、および酸化チタンからなる群から選ばれた少なくとも一つの無機材料を含有する、請求項１～７のいずれか一項に記載の制振性繊維強化樹脂成形体。 The resin of the fiber-reinforced resin layer contains at least one inorganic material selected from the group consisting of potassium titanate, alumina, zinc oxide, and titanium oxide. Vibration-damping fiber reinforced resin molding.
  9. 　請求項１～８のいずれか一項に記載の制振性繊維強化樹脂成形体であってシート状のものが、賦型されてなる、制振性繊維強化樹脂成形体。 9. A vibration-damping fiber-reinforced resin molded body according to any one of claims 1 to 8, wherein the vibration-damping fiber-reinforced resin molded body is shaped into a sheet.
  10. 　トルクロッド、サスペンションアーム、ロアアーム、タワーバー、プロペラシャフト、インパクトビーム、スタビバー、サブフレーム、バンパーまたはサイドドアビームである自動車用部品であって、請求項１～９のいずれか一項に記載の制振性繊維強化樹脂成形体を構成部材とすることを特徴とする自動車用部品。 The vibration control unit according to any one of claims 1 to 9, wherein the vehicle part is a torque rod, suspension arm, lower arm, tower bar, propeller shaft, impact beam, stabilizer bar, subframe, bumper or side door beam. A component for automobiles, characterized in that the molded article is a reinforced fiber reinforced resin molding.
PCT/JP2015/086406 2015-02-19 2015-12-25 Fiber-reinforced resin molded body having damping properties and automobile part using same WO2016132655A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE112015005173.2T DE112015005173T5 (en) 2015-02-19 2015-12-25 Vibration-damping molded product of fiber-reinforced resin and motor vehicle component, in which this is used
JP2016528253A JP6002872B1 (en) 2015-02-19 2015-12-25 Damped fiber reinforced resin molded article and automotive parts using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2015-030393 2015-02-19
JP2015030393 2015-02-19

Publications (1)

Publication Number Publication Date
WO2016132655A1 true WO2016132655A1 (en) 2016-08-25

Family

ID=56689375

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2015/086406 WO2016132655A1 (en) 2015-02-19 2015-12-25 Fiber-reinforced resin molded body having damping properties and automobile part using same

Country Status (3)

Country Link
JP (1) JP6002872B1 (en)
DE (1) DE112015005173T5 (en)
WO (1) WO2016132655A1 (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107215298A (en) * 2017-04-25 2017-09-29 南宁市钱隆汽车租赁有限公司 Bumper
KR101949666B1 (en) * 2018-08-29 2019-02-19 (주)화신 Subframe for vehicle
KR101949664B1 (en) * 2018-08-29 2019-02-19 (주)화신 Subframe for vehicle
KR101949663B1 (en) * 2018-08-29 2019-02-19 (주)화신 Subframe for vehicle
KR101949665B1 (en) * 2018-08-29 2019-02-19 (주)화신 Subframe for vehicle
KR101949662B1 (en) * 2017-08-14 2019-02-19 (주)화신 Subframe for vehicle
WO2019087877A1 (en) 2017-11-02 2019-05-09 日鉄ケミカル＆マテリアル株式会社 Epoxy resin composition and cured object obtained therefrom
JP2019186469A (en) * 2018-04-16 2019-10-24 東芝三菱電機産業システム株式会社 Vibration absorbing and fixing member for potential heavy load for power conversion device
JP2019217738A (en) * 2018-06-22 2019-12-26 株式会社日立製作所 Resin laminate and method for producing resin laminate
EP3628701A1 (en) 2018-09-28 2020-04-01 NIPPON STEEL Chemical & Material Co., Ltd. Prepreg and molding product thereof
JP2021059637A (en) * 2019-10-03 2021-04-15 宇部興産株式会社 Polyamide resin film for bonding to prepreg, and laminate
CN115003499A (en) * 2020-01-24 2022-09-02 住友化学株式会社 Optical laminate and display device
CN115059809A (en) * 2017-01-20 2022-09-16 三井化学株式会社 Tape winding tube
US11858555B2 (en) * 2021-02-26 2024-01-02 Mazda Motor Corporation Front body structure of vehicle

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0428542A (en) * 1990-05-24 1992-01-31 Toray Ind Inc Oscillation attenuation material
JP2010248669A (en) * 2009-04-17 2010-11-04 Teijin Techno Products Ltd Damping material and damping composite material
JP2011011346A (en) * 2009-06-30 2011-01-20 Mitsubishi Plastics Inc Resin composite material, and beam structure member using the same
WO2012011487A1 (en) * 2010-07-21 2012-01-26 東レ株式会社 Prepreg, fiber-reinforced composite material, and process for producing prepreg
JP2012162062A (en) * 2011-02-09 2012-08-30 Jx Nippon Oil & Energy Corp Carbon fiber-reinforced plastic molding

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009078422A (en) * 2007-09-26 2009-04-16 Toray Ind Inc Vibration-damping fiber-reinforced composite material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0428542A (en) * 1990-05-24 1992-01-31 Toray Ind Inc Oscillation attenuation material
JP2010248669A (en) * 2009-04-17 2010-11-04 Teijin Techno Products Ltd Damping material and damping composite material
JP2011011346A (en) * 2009-06-30 2011-01-20 Mitsubishi Plastics Inc Resin composite material, and beam structure member using the same
WO2012011487A1 (en) * 2010-07-21 2012-01-26 東レ株式会社 Prepreg, fiber-reinforced composite material, and process for producing prepreg
JP2012162062A (en) * 2011-02-09 2012-08-30 Jx Nippon Oil & Energy Corp Carbon fiber-reinforced plastic molding

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115059809A (en) * 2017-01-20 2022-09-16 三井化学株式会社 Tape winding tube
CN115059809B (en) * 2017-01-20 2023-12-08 三井化学株式会社 Tape winding tube
CN107215298A (en) * 2017-04-25 2017-09-29 南宁市钱隆汽车租赁有限公司 Bumper
KR101949662B1 (en) * 2017-08-14 2019-02-19 (주)화신 Subframe for vehicle
US11396597B2 (en) 2017-11-02 2022-07-26 Nippon Steel Chemical & Material Co., Ltd. Epoxy resin composition and cured object obtained therefrom
WO2019087877A1 (en) 2017-11-02 2019-05-09 日鉄ケミカル＆マテリアル株式会社 Epoxy resin composition and cured object obtained therefrom
JP2019186469A (en) * 2018-04-16 2019-10-24 東芝三菱電機産業システム株式会社 Vibration absorbing and fixing member for potential heavy load for power conversion device
WO2019244395A1 (en) * 2018-06-22 2019-12-26 株式会社日立製作所 Resin laminate and method of manufacturing resin laminate
JP2019217738A (en) * 2018-06-22 2019-12-26 株式会社日立製作所 Resin laminate and method for producing resin laminate
JP7038012B2 (en) 2018-06-22 2022-03-17 株式会社日立製作所 Method for manufacturing resin laminate and resin laminate
KR101949665B1 (en) * 2018-08-29 2019-02-19 (주)화신 Subframe for vehicle
KR101949663B1 (en) * 2018-08-29 2019-02-19 (주)화신 Subframe for vehicle
KR101949664B1 (en) * 2018-08-29 2019-02-19 (주)화신 Subframe for vehicle
KR101949666B1 (en) * 2018-08-29 2019-02-19 (주)화신 Subframe for vehicle
EP3628701A1 (en) 2018-09-28 2020-04-01 NIPPON STEEL Chemical & Material Co., Ltd. Prepreg and molding product thereof
US11059949B2 (en) 2018-09-28 2021-07-13 Nippon Steel Chemical & Material Co., Ltd. Prepreg and molding product thereof
JP2021059637A (en) * 2019-10-03 2021-04-15 宇部興産株式会社 Polyamide resin film for bonding to prepreg, and laminate
JP7395923B2 (en) 2019-10-03 2023-12-12 Ｕｂｅ株式会社 Polyamide resin film and laminate for bonding with prepreg
CN115003499A (en) * 2020-01-24 2022-09-02 住友化学株式会社 Optical laminate and display device
US11858555B2 (en) * 2021-02-26 2024-01-02 Mazda Motor Corporation Front body structure of vehicle

Also Published As

Publication number Publication date
DE112015005173T5 (en) 2017-08-17
JP6002872B1 (en) 2016-10-05
JPWO2016132655A1 (en) 2017-04-27

Similar Documents

Publication Publication Date Title
JP6002872B1 (en) Damped fiber reinforced resin molded article and automotive parts using the same
EP2085215B1 (en) High-toughness fiber-metal laminate
KR102006511B1 (en) Composite laminate having improved impact strength and the use thereof
KR100967834B1 (en) High impact strength, elastic, composite, fibre, metal laminate
US20130316148A1 (en) Metal sheet-fiber reinforced composite laminate
Dogan et al. The effect of hygrothermal aging and UV radiation on the low-velocity impact behavior of the glass fiber-reinforced epoxy composites
JP2013543035A (en) Epoxy resin composition, prepreg, and fiber reinforced composite material for fiber reinforced composite material
US20170190150A1 (en) Laminate of a Metal Sheet and an Adhesive Layer Bonded Thereto
EP3698935A1 (en) Manufacturing method for fiber-reinforced plastic composite
KR20130136164A (en) Method for manufacturing thermoplastic composite using continuous fiber reinforced thermoplastic prepreg sheet and thermoplastic compositemanufactured by that method
JP2016107485A (en) Composite molding, and production method thereof
WO2007061304A1 (en) Laminate of metal sheets and polymer
JP3641553B2 (en) Fiber reinforced composite material molding
Hadzreel et al. Effect of reinforcement alignment on the properties of polymer matrix composite
KR20180126762A (en) Hybrid type fiber reinforced composite material
JP5112732B2 (en) Prepreg
JP5966969B2 (en) Manufacturing method of prepreg
JP2007144919A (en) Frp sandwich structure
JP5239350B2 (en) Prepreg and fiber reinforced composite materials
JP5565565B2 (en) Carbon fiber reinforced plastic molding
CA2874973A1 (en) Method of making a 3d glass fiber metal laminate and 3d laminate structural panel
WO2024176998A1 (en) Frp
EP4385714A1 (en) Sheet-type fiber-reinforced composite having heterogeneous properties and mehtod for manufacturing the same
JP7473416B2 (en) Method for producing fiber-reinforced composite material
JP5076493B2 (en) Manufacturing method of fiber reinforced plastic and fiber reinforced plastic

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2016528253

Country of ref document: JP

Kind code of ref document: A

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 15882756

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 112015005173

Country of ref document: DE

122 Ep: pct application non-entry in european phase

Ref document number: 15882756

Country of ref document: EP

Kind code of ref document: A1