WO2016030043A1 - Agent et procédé pour la mise en forme temporaire de fibres kératiniques - Google Patents

Agent et procédé pour la mise en forme temporaire de fibres kératiniques Download PDF

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Publication number
WO2016030043A1
WO2016030043A1 PCT/EP2015/064175 EP2015064175W WO2016030043A1 WO 2016030043 A1 WO2016030043 A1 WO 2016030043A1 EP 2015064175 W EP2015064175 W EP 2015064175W WO 2016030043 A1 WO2016030043 A1 WO 2016030043A1
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Prior art keywords
compositions according
wax
total weight
copolymer
compositions
Prior art date
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PCT/EP2015/064175
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German (de)
English (en)
Inventor
Anna Henschel
Jisook Baek
Arne Junge
Original Assignee
Henkel Ag & Co. Kgaa
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Publication of WO2016030043A1 publication Critical patent/WO2016030043A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/413—Nanosized, i.e. having sizes below 100 nm
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/61—Surface treated
    • A61K2800/612—By organic compounds

Definitions

  • the application relates to the technical field of temporary deformation keratin braver fibers, especially human hair.
  • Styling agents for the deformation of keratin-containing fibers have long been known and find use in various embodiments for the construction, for refreshing and for fixing hairstyles, which can be obtained in many hair types only using firming agents. Both hair treatment products, which serve a permanent, as well as those that serve a temporary shaping of the hair, play an important role.
  • the temporary shaping keratin braver fibers are sprayable products as well as supply forms, which are incorporated with the help of a comb or with your fingers in the hairstyle.
  • the latter product group includes oils as well as gels, creams and powders.
  • the powdered styling agents are enjoying increasing popularity due to their ease of dosing and their cosmetic properties such as high hairstyle hold, volume increase, remodeling and their matting effect.
  • German Patent Application DE102008057261 A1 describes pulverulent compositions which are used for temporary shaping of hair for a very strong hold of the fixed hairstyle.
  • the subject of the international application WO 2007/05151 1 A1 is the use of a pulverulent composition containing 50 to 95% by weight of an aqueous solvent, hydrophobized silica powder and at least one film-forming and / or setting polymer in the aqueous solvent for the temporary deformation of keratinic fibers.
  • the object of the present invention was therefore to provide hair treatment composition for temporary shaping available, which in addition to a good hairstyle, high Hair volume, hair strength and remodeling ability are characterized by increased hair shine.
  • the funds should also be applicable to wet as well as dry hair.
  • a first subject of the present application are cosmetic compositions containing
  • the agents according to the invention are preferably in the form of creams or pastes.
  • the viscosity of agents according to the invention is preferably between 70,000 and 600,000 mPas, preferably between 100,000 and 400,000 mPas (20 ° C., DV 2T "Brookfield” rotational viscometer, spindle TE, 5 revolutions per minute and Helipath).
  • a first essential component of compositions according to the invention is the hydrophobized metal oxide powder.
  • Preferred compositions are characterized in that they contain the hydrophobized metal oxide powder, based on their total weight, in amounts of from 0.1 to 20% by weight, preferably from 0.5 to 15% by weight and in particular from 1.0 to 10% by weight. % contain. In addition to the proportions by weight of the other constituents, the optimum amount depends above all on the hydrophobicity of the silicon dioxide powder used.
  • hydrophobed are to be understood as meaning those metal oxides which have been modified at least on the surface of the particles in such a way that the modified particle is wetted less by water than the unmodified particle.
  • the particle diameter of the primary particles of preferred hydrophobized metal oxides is preferably less than 5 ⁇ m, particularly preferably less than 1 ⁇ m, and in particular between 1 and 50 nm.
  • At least one member of the group which is formed, from silanes, halosilanes, alkoxysilanes and silazanes is preferably suitable.
  • Preferred hydrophobized metal oxides of the hydrophobized metal oxide powder are selected according to the invention from at least one member of the group which is formed from hydrophobized silicates, hydrophobized aluminum silicates, hydrophobized titanium dioxide and hydrophobized silica.
  • Hydrophoborated silicates have proved particularly suitable for the preparation of the cosmetic compositions according to the invention, with fumed silica aftertreated by silanization or by reaction with polydimethylsiloxane having particular advantages.
  • the pulverulent composition according to the invention contains as hydrophobized metal oxide powder at least hydrophobized silicon dioxide.
  • hydrophobized silicon dioxides which have a BET specific surface area of between 10 and 400 m 2 / g, preferably between 40 and 300 m 2 / g and in particular between 80 and 150 m 2 / g.
  • the pulverulent composition according to the invention particularly preferably contains as hydrophobized metal oxide powder at least silanized, hydrophobized silicon dioxide.
  • At least one member of the group which is formed from silanes, halosilanes, alkoxysilanes and silazanes is preferably suitable according to the invention.
  • Preferred representatives of the group of silanes are hexa (C 1 -C 20) alkyldisilanes, in particular hexamethyldisilane.
  • halosilane when a halosilane is used as the silylating agent, as the preferred halosilane, at least one compound selected from the group consisting of the compounds is selected
  • X represents a chlorine, bromine or iodine atom
  • z ' is a number 1, 2 or 3
  • y ' is a number 0, 1 or 2
  • n is an integer from 1 to 20 and
  • alkoxysilane As the silylating agent, as the preferred alkoxysilane, at least one compound selected from the group consisting of the compounds is selected
  • n is an integer from 1 to 20 and
  • z is a number 1, 2, or 3
  • silazane is at least one compound from the class of disilazanes, in particular at least one compound of disilazanes of the formula
  • R ' is a (Ci-C2o) alkyl group
  • R represents a (C 1 -C 20) alkyl group or a vinyl group
  • a particularly preferred silazane is hexamethyldisilazane.
  • alkyl groups may be both cyclic and linear or branched.
  • alkyl groups which can be used according to the invention are methyl, ethyl, n-propyl, isopropyl, n-butyl, cyclopentyl, cyclohexyl, n-decyl, lauryl, myristyl, cetyl, stearyl, isostearyl and behenyl.
  • An example of an aryl group according to the invention is the phenyl group.
  • Examples of a (Ci-C6) perfluoroalkyl group according to the invention are trifluoromethyl, perfluoroethyl, perfluoropropyl and perfluorohexyl.
  • Silanized, hydrophobized silicas are particularly preferably selected from at least one compound of the group formed from trimethylsilylate-coated silica, dimethylsilylate-coated silica, octylsilylate-coated silica.
  • hydrophobicized silicas obtained by silanization of fumed silica Preference is given to using hydrophobicized silicas obtained by silanization of fumed silica.
  • Compositions which contain as hydrophobized metal oxide powder a hydrophobized silicate obtained by silanization of fumed silica are preferred on account of their product properties, in particular their storage stability and their cosmetic action.
  • a variety of suitable hydrophobized silicas are commercially available.
  • Aerosil ® R104 V Aerosil ® R106
  • Aerosil ® R202 Aerosil ® R805
  • Aerosil ® R812 Aerosil ® R812S
  • Aerosil ® R972 Aerosil ® R8200
  • HDK ® H2000 HDK ® H2050 and HDK ® H3004 , all Wacker, called.
  • the hydrophobic silicas are used which are available under the names Aerosil ® R202, Aerosil ® R812S or Aerosil ® R972.
  • the silica comes with the INCI name silica Silylate used, which is sold by Degussa under the name Aerosil ® R812S.
  • compositions according to the invention which contain a polydimethylsiloxane aftertreated fumed silica.
  • Corresponding metal oxides with the INCI designation "Silica Dimethicone silylate” are sold for example by Evonik under the trade name Aersoil ® R202.
  • a second essential constituent of cosmetic compositions according to the invention is the homo- and / or copolymer b).
  • Preferred compositions are characterized in that they contain the homo- and / or copolymer b), based on their total weight, in amounts of from 0.1 to 18% by weight, preferably from 1.0 to 17% by weight and in particular from 5, 0 to 15 wt .-% included.
  • nonionic polymers As homo- and / or copolymers b) are used with particular preference nonionic polymers. Suitable nonionic homopolymers and / or copolymers b) are, for example:
  • Polyvinylpyrrolidones as (BASF) are sold for example under the name Luviskol ®, preferred homopolymers b).
  • Vinylpyrrolidone / vinyl ester copolymers as sold, for example, under the trademark Luviskol ® (BASF).
  • Luviskol ® VA 64 and Luviskol ® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are preferred nonionic copolymers b).
  • Cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methyl hydroxypropyl cellulose.
  • compositions contain as homo- and / or copolymer b) polyvinylpyrrolidone and / or vinylpyrrolidone / vinyl acetate copolymer, preferably polyvinylpyrrolidone.
  • a wax c As a third essential ingredient containing compositions according to the invention a wax c).
  • the amount of wax used based on their total weight of Compositions, preferably 0.2 to 15 wt .-%, preferably 0.5 to 12 wt .-% and in particular 1, 0 to 10 wt .-%.
  • Preferred waxes have a melting point in the range of 40 ° C to 90 ° C, more preferably in the range of 50 ° C to 85 ° C and especially in the range of 50 ° C to 75 ° C.
  • waxes can be used which melt in the temperature range mentioned and which are physiologically compatible.
  • Particularly preferred waxes according to the invention are beeswax, carnauba wax, candelilla wax, montan wax and microcrystalline waxes, but preferably beeswax.
  • the teaching according to the invention also comprises the combined use of several waxes.
  • addition of small amounts of carnauba wax can be used to increase the melting and dripping point of another wax and reduce its stickiness.
  • Spezialwachs 7686 OE a mixture of Cetylpalmitat, beeswax, microcrystalline wax and polyethylene with a melting range of 73-75 ° C, manufacturer: Kahl & Co
  • Polywax ® GP 200 a mixture of stearyl alcohol and polyethylene glycol stearate with a melting point of 47-51 ° C, manufactured by Croda
  • Weightceresin ® FL 400 a petrolatum / vaseline oil / wax mixture having a melting point of 50- 54 ° C; manufacturer: Parafluid mineral oil company
  • the fourth essential constituent of cosmetic compositions according to the invention is emulsifier d).
  • the proportion by weight of emulsifier d) in the total weight in the total weight of the compositions is preferably from 1.5 to 20% by weight, preferably from 2.0 to 12% by weight and in particular from 2.0 to 10% by weight.
  • the cosmetic compositions preferably further comprise at least one member selected from the group consisting of anionic, amphoteric, zwitterionic, nonionic, cationic emulsifiers or mixtures thereof. Preference is given to using solid emulsifiers at room temperature (20 ° C.), in particular solid nonionic emulsifiers at room temperature (20 ° C.).
  • Particularly suitable nonionic emulsifiers are the fatty acid partial glycerides, which are understood as meaning monoglycerides, diglycerides and technical mixtures thereof. When using technical products may contain small quantities of triglycerides due to their production.
  • the partial glycerides preferably follow the formula
  • R 3 in the R, R 2 and R 3 are independently of one another hydrogen or a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22, preferably 12 to 18, carbon atoms are provided with the proviso that at least one of these groups is an acyl radical and at least one of these groups is hydrogen.
  • the sum (m + n + q) is 0 or numbers from 1 to 100, preferably 0 or 5 to 25.
  • R is an acyl radical and R 2 and R 3 are hydrogen and the sum (m + n + q ) is 0.
  • Typical examples are mono- and / or diglycerides based on caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, Elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures.
  • oleic acid monoglycerides are used.
  • emulsifiers d) are the surface-active, medium-chain fatty alcohols, in particular cetyl alcohol and stearyl alcohol.
  • Particularly preferred emulsifiers d) are selected
  • an emulsifier combination of fatty acid partial glycerides and surface-active, medium-chain fatty alcohols preferably a combination of glycerol monostearate and glyceryl distearate with cetyl alcohol and stearyl alcohol, in particular a combination of glycerol monostearate and glyceryl distearate with cetyl alcohol and stearyl alcohol.
  • compositions according to the invention contain as the fifth essential constituent an organic polyol.
  • Preferred compositions contain the organic polyol e) based on their total weight in amounts of 0.5 to 60, preferably 1, 0 to 50 wt .-% and in particular 1, 5 to 25 wt .-%.
  • the polyol can be used as a single substance or in the form of polyol mixtures.
  • Preferred agents according to the invention are characterized in that they contain less than four, preferably one to three, but in particular only one polyol.
  • Polyols from the group of glycerol, 1,2-ethanediol, polyethylene glycols having MW> 400, propanediol, butanediol, in particular 1,3-butanediol, hexanediol, in particular 1,6-hexanediol, sorbitol, threitol, erythritol, are particularly suitable for the preparation of cosmetic compositions.
  • Particularly suitable organic polyols are glycerol, sorbitol and panthenol.
  • Preferred compositions according to the invention are characterized in that they contain as organic polyol e) at least one polyol from the group consisting of glycerol, polyethylene glycol, propylene glycol, butylene glycol and hexanediol, preferably glycerol.
  • the addition of the polyol e) improves the properties of inventive compositions during storage and application and has advantageous cosmetic effects.
  • the proportion by weight of the polyol be on the total weight of compositions according to the invention can vary within wide ranges.
  • a larger amount of water is preferably added to the compositions in equilibrium.
  • the water content erindungswasher compositions is preferably 10 to 85 wt .-%, preferably 40 to 85 wt .-% and in particular 65 to 82 wt .-%.
  • composition of some preferred cosmetic agents can be found in the following tables (data in% by weight based on the total weight of the cosmetic agent, unless stated otherwise).
  • Formula 16 Formula 17
  • Formula 18 Formula 19
  • Hydrophobic 0.1 to 25 0.1 to 20 0.5 to 15 0.5 to 15 1.0 to 10 silicon dioxide
  • Fatty acid polyglyceride 1.0 to 30 1.5 to 20 2.0 to 12 2.0 to 10 2.0 to 10 organic polyol 0.5 to 70 0.5 to 60 1, 0 to 50 1.5 to 25 1 , 5 to 25
  • Fatty acid polyglyceride 1.0 to 30 1.5 to 20 2.0 to 12 2.0 to 10 2.0 to 10 organic polyol 0.5 to 70 0.5 to 60 1, 0 to 50 1.5 to 25 1 , 5 to 25
  • Polyol 0.5 to 70 0.5 to 60 1.0 to 50 1.5 to 25 1.5 to 25
  • Polyol 0.5 to 70 0.5 to 60 1.0 to 50 1.5 to 25 1.5 to 25
  • Polyol 0.5 to 70 0.5 to 60 1.0 to 50 1.5 to 25 1.5 to 25 Water 1, 0 to 90 10 to 85 40 to 85 65 to 82 65 to 82
  • a second subject of this application is the use of a cosmetic composition according to the invention for the temporary deformation of keratin-containing fibers, in particular human hair.
  • a third subject of this application is a method for the temporary deformation of keratin-containing fibers, in particular human hair, in which the keratinic fibers are acted upon by a cosmetic composition according to the invention and temporarily fixed in their form.
  • compositions, uses, and methods of the invention are characterized by the following items:
  • compositions according to item 1 characterized in that it comprises the hydrophobized metal oxide powder based on their total weight in amounts of 0, 1 to 20 wt .-%, preferably from 0.5 to 15 wt .-% and in particular from 1, 0 to Contains 10 wt .-%.
  • compositions according to one of the preceding points characterized in that it contains as hydrophobized metal oxide powder obtained by silanization of fumed silica hydrophobic silicate.
  • compositions according to one of the preceding points characterized in that they the homo- and / or copolymer b) based on their total weight in amounts of 0.1 to 18 wt .-%, preferably from 1, 0 to 17 parts by weight. % and in particular from 5.0 to 15 wt .-%.
  • compositions according to one of the preceding points characterized in that they contain as homo- and / or copolymer b) polyvinylpyrrolidone and / or vinylpyrrolidone / vinyl acetate copolymer, preferably polyvinylpyrrolidone.
  • compositions according to one of the preceding points characterized in that the wax c) based on their total weight in amounts of 0.2 to 15 wt .-%, preferably from 0.5 to 12 wt .-% and in particular of 1, 0 to 10 wt .-%.
  • compositions according to one of the preceding points characterized in that the wax c) at least one wax from the group beeswax, carnauba wax, candelilla wax, montan wax and microcrystalline waxes, preferably beeswax.
  • the wax c) at least one wax from the group beeswax, carnauba wax, candelilla wax, montan wax and microcrystalline waxes, preferably beeswax.
  • the wax c) at least one wax from the group beeswax, carnauba wax, candelilla wax, montan wax and microcrystalline waxes, preferably beeswax.
  • the emulsifier d) based on their total weight in amounts of 1, 5 to 20 wt .-%, preferably from 2.0 to 12 wt .-% and in particular from 2 , 0 to 10 wt .-%.
  • composition according to one of the preceding points characterized in that the emulsifier d) is selected
  • compositions according to one of the preceding points characterized in that they the organic polyol e) based on their total weight in amounts of 0.5 to 60, preferably 1, 0 to 50 wt .-% and in particular 1, 5 to 25 wt .-% contains.
  • compositions according to one of the preceding points characterized in that they contain as organic polyol e) at least one polyol from the group glycerol, polyethylene glycol, propylene glycol, butylene glycol and hexanediol, preferably glycerol.
  • compositions according to one of the preceding points characterized in that they contain 10 to 85 wt .-%, preferably 40 to 85 wt .-% and in particular 65 to 82 wt .-% water.

Abstract

L'invention concerne des compositions cosmétiques, contenant a) 0,1 à 25 % en poids de poudre d'oxyde métallique rendue hydrophobe, b) 0,1 à 20 % en poids d'au moins un homopolymère et/ou copolymère, c) 0,10 à 20 % en poids de cire, d) 1,0 à 30 % en poids d'émulsifiant, e) 0,5 à 70 % en poids de polyol organique, et f) 1,0 à 90 % en poids d'eau, qui conviennent en particulier pour la mise en forme temporaire de fibres kératiniques.
PCT/EP2015/064175 2014-08-25 2015-06-24 Agent et procédé pour la mise en forme temporaire de fibres kératiniques WO2016030043A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014216861.9 2014-08-25
DE102014216861.9A DE102014216861A1 (de) 2014-08-25 2014-08-25 "Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern"

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Publication Number Publication Date
WO2016030043A1 true WO2016030043A1 (fr) 2016-03-03

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021110656A1 (fr) 2019-12-02 2021-06-10 Janssen Pharmaceutica Nv Composés inhibiteurs d'oga
US11273106B2 (en) 2016-12-19 2022-03-15 Henkel Ag & Co. Kgaa Agent and method for the temporary shaping of keratinous fibers

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Publication number Priority date Publication date Assignee Title
JP2007070232A (ja) * 2005-09-02 2007-03-22 Kose Corp 水中油型睫用化粧料
WO2009082565A1 (fr) * 2007-12-20 2009-07-02 Avon Products, Inc. Compositions cosmétiques pour conférer des films superhydrophobes
EP2248513A1 (fr) * 2008-01-25 2010-11-10 Shiseido Company, Ltd. Préparation de type émulsion pour la coiffure
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