EP3086755A1 - Agents et procédés pour mettre en forme temporairement des fibres kératiniques - Google Patents

Agents et procédés pour mettre en forme temporairement des fibres kératiniques

Info

Publication number
EP3086755A1
EP3086755A1 EP14796691.5A EP14796691A EP3086755A1 EP 3086755 A1 EP3086755 A1 EP 3086755A1 EP 14796691 A EP14796691 A EP 14796691A EP 3086755 A1 EP3086755 A1 EP 3086755A1
Authority
EP
European Patent Office
Prior art keywords
composition according
weight
total weight
water
contain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP14796691.5A
Other languages
German (de)
English (en)
Inventor
Jisook Baek
Anna Henschel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3086755A1 publication Critical patent/EP3086755A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/022—Powders; Compacted Powders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/56—Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms

Definitions

  • the application relates to the technical field of temporary deformation keratin braver fibers, especially human hair.
  • Styling agents for the deformation of keratin-containing fibers have long been known and find use in various embodiments for the construction, for refreshing and for fixing hairstyles, which can be obtained in many hair types only using firming agents.
  • Both hair treatment products which serve a permanent, as well as those that serve a temporary shaping of the hair, play an important role.
  • Temporary shapes, which should give a good grip, without affecting the healthy appearance of the hair, such as their gloss, can be achieved for example by hair sprays, hair waxes, hair gels, hair drier, etc.
  • Corresponding temporary shaping agents usually contain synthetic polymers as the shaping component. Preparations containing a polymer can be applied to the hair by means of propellants or by a pumping mechanism. Hair gels and hair waxes, however, are usually not applied directly to the hair, but distributed by means of a comb or hands in the hair.
  • Hair sprays can be distributed more evenly over the hair. However, since the user has no ability to visually detect the total amount of styling agent applied, there is a risk that more styling agent will be applied to the hair than would actually be required.
  • Powdered cosmetics are known and have been used for some time in the field of skin treatment for example. Typical examples include make-up powder or eye shadow.
  • a powdery carrier material is required.
  • a suitable carrier material may be used, for example, a metal oxide such as silicon dioxide.
  • Hydrophoborated metal oxide or silicon dioxide is of particular interest. This can be obtained, for example, starting from fumed silica, which is commercially available in various specifications. Wearing on the surface untreated pyrogenic silica silanol and siloxane groups. As a result, it has a high affinity for water, ie it is hydrophilic.
  • alkylsilyl groups can be chemically bonded to the surface of the fumed silica.
  • modified silica powder which are no longer wetted by water, ie have the hydrophobic properties.
  • These hydrophobicized silicon dioxides are suitable for the production of so-called dry water, in which the water droplets are prevented from rejoining.
  • the resulting powdery solids may have water content of up to 95%. Under mechanical stress, for example rubbing on the skin, the trapped water is released again.
  • Cosmetic or pharmaceutical liquefiable powder compositions are described, for example, in European Patent EP 1 235 554 B1.
  • International application WO 03/037287 A1 discloses the use of granules based on pyrogenic silicon dioxide in cosmetic compositions.
  • the specific granules can be silanized, i. be hydrophobic and are suitable for the preparation of cosmetic compositions of any consistency, such as liquids, foams, sprays or powders.
  • the international application WO 2007/05151 1 A1 describes the use of a pulverulent composition containing 50 to 95 wt .-% of an aqueous solvent, hydrophobized silica powder and at least in the aqueous solvent located film-forming and / or setting polymer for the temporary deformation of keratinous fibers.
  • the German patent application DE102008057261 A1 has powdered compositions which are used for the temporary forming of hair for very strong hold the fixed hairstyle.
  • the powdered hair cosmetics of the prior art have now been acceptable for hair shaping hold and are characterized by a good metering.
  • the result achieved with these agents in terms of the parameters of natural gloss as well as the elasticity and the hold is in need of improvement as well as their applicability, for example by hand and hair.
  • the previously known powdered hair cosmetics are only partially suitable for incorporation of oils such as perfume oils, since these reduce the stability of the powdered agent.
  • the fragrance effect of these perfume-containing powders only lasts for a short time and the fragrances are very difficult to apply uniformly on the hair.
  • Object of the present invention was therefore to provide storage-stable powdered hair treatment compositions for temporary shaping available, which are characterized by an improved scent effect, can be precisely and easily dosed and applied, the hair does not stick together, the hair a fuller and natural feel and natural Give shine.
  • the durability of the styling result should not be affected.
  • powdery cosmetic compositions based on a polyol-emulsifier mixture solve the aforementioned object.
  • a first subject of the present application are powdered cosmetic compositions containing
  • the pulverulent compositions according to the invention are preferably in the form of core-shell particles whose shell contains particles of at least one hydrophobized metal oxide powder and whose liquid core contains organic polyol and optionally water.
  • particles are particles which are present as grains (see DIN 66160: 1992-09) of solids.
  • powders are compositions whose particles are freely free-flowing under their own weight (see DIN EN ISO 6186: 1998-08).
  • the pulverulent compositions according to the invention are characterized in that the liquid core is released from the core-shell particle by mechanical loading of the core-shell particles, in particular by friction and / or pressure, and thereby the powdered composition becomes a liquid forms. It is thus a powdered powder-to-liquid composition.
  • the pulverulent compositions according to the invention can be metered very easily. They can also be very evenly distributed in the hair, since the liquid core is released only under mechanical stress at the site of action and targeted wetting of the hair fibers is possible. The powder can therefore be first carefully distributed in the hair and only then be subjected to mechanical stress, for example, by targeted massaging the powder into the hair. As a result, the styling effect is only deployed directly on the desired hair part.
  • the powdered compositions used contain hydrophobized metal oxide.
  • Preferred compositions are characterized in that they contain the hydrophobized metal oxide powder in amounts of from 10 to 25, preferably 12, relative to their total weight contain up to 22 wt .-%. The optimum amount depends primarily on the hydrophobicity of the silica powder used. The more hydrophobic the silica powder is, the less of it is needed to obtain a stable, powdered product.
  • hydrophobicized metal oxide is not limited in principle, as long as it is ensured that the intense mixing with the liquid, aqueous phase results in a powdery product.
  • hydrophobed are to be understood as meaning those metal oxides which have been modified at least on the surface of the particles in such a way that the modified particle is wetted less by water than the unmodified particle.
  • silanized, hydrophobized metal oxides are preferred.
  • at least one member of the group which is formed, from silanes, halosilanes, alkoxysilanes and silazanes is preferably suitable.
  • Preferred hydrophobized metal oxides of the hydrophobized metal oxide powder are selected according to the invention from at least one member of the group formed from hydrophobized silicates, hydrophobicized aluminum silicates, hydrophobized titanium dioxide and hydrophobized silica.
  • Hydrophoborated silicates have proved particularly suitable for the preparation of the cosmetic compositions according to the invention, with fumed silica aftertreated by silanization or by reaction with polydimethylsiloxane having particular advantages.
  • the powdered compositions used preferably contain hydrophobized silica.
  • the nature of the hydrophobicized silica is not limited in principle, as long as it is ensured that the intensive mixing with the polyol b), the copolymer c) and optionally other ingredients, a powdered product is formed.
  • the pulverulent composition according to the invention particularly preferably contains as hydrophobized metal oxide powder at least silanized, hydrophobized silicon dioxide.
  • At least one member of the group which is formed from silanes, halosilanes, alkoxysilanes and silazanes is preferably suitable according to the invention.
  • Preferred representatives of the group of silanes are hexa (C 1 -C 20) alkyldisilanes, in particular hexamethyldisilane.
  • halosilane when a halosilane is used as the silylating agent, as the preferred halosilane, at least one compound selected from the group consisting of the compounds is selected
  • X represents a chlorine, bromine or iodine atom
  • z ' is a number 1, 2 or 3
  • y ' is a number 0, 1 or 2
  • n is an integer from 1 to 20 and
  • alkoxysilane As the silylating agent, as the preferred alkoxysilane, at least one compound selected from the group consisting of the compounds is selected
  • n is an integer from 1 to 20 and
  • z is a number 1, 2, or 3
  • silazane is at least one compound from the class of disilazanes, in particular at least one compound of disilazanes of the formula
  • R ' is a (Ci-C2o) alkyl group and R "represents a (C 1 -C 20) alkyl group or a vinyl group
  • a particularly preferred silazane is hexamethyldisilazane.
  • alkyl groups may be both cyclic and linear or branched.
  • alkyl groups which can be used according to the invention are methyl, ethyl, n-propyl, isopropyl, n-butyl, cyclopentyl, cyclohexyl, n-decyl, lauryl, myristyl, cetyl, stearyl, isostearyl and behenyl.
  • An example of an aryl group according to the invention is the phenyl group.
  • Examples of a (Ci-C6) perfluoroalkyl group according to the invention are trifluoromethyl, perfluoroethyl, perfluoropropyl and perfluorohexyl.
  • Silanized hydrophobized silicas are particularly preferably selected from at least one compound of the group formed from trimethylsilylate-coated silica, dimethylsilylate-coated silica, octylsilylate-coated silica.
  • hydrophobized silicas are commercially available. Examples include Aerosil ® R104 V, Aerosil ® R106, Aerosil ® R202, Aerosil ® R805, Aerosil ® R812, Aerosil ® R812S, Aerosil ® R972 and Aerosil ® R8200, all Degussa, and HDK ® H2000, HDK ® H2050 and HDK ® H3004 , all Wacker, called.
  • the hydrophobic silicas are used which are available under the names Aerosil ® R202, Aerosil ® R812S or Aerosil ® R972.
  • the silica comes with the INCI name silica Silyiate used, which is sold by Degussa under the name Aerosil ® R812S.
  • compositions according to the invention are therefore characterized in that they contain as hydrophobized metal oxide powder a hydrophobized silicate, preferably a polydimethylsiloxane aftertreated fumed silica.
  • a hydrophobized silicate preferably a polydimethylsiloxane aftertreated fumed silica.
  • Corresponding metal oxides with the INCI designation "Silica Dimethicone Silyiate” are sold for example by Evonik under the trade name Aersoil ® R202.
  • the particle diameter of the primary particles of preferred hydrophobized metal oxides is preferably less than 5 ⁇ m, particularly preferably less than 1 ⁇ m, and in particular between 1 and 50 nm.
  • hydrophobicized silicon dioxides which have a BET specific surface area of between 10 and 400 m 2 / g, preferably between 40 and 300 m 2 / g and in particular between 80 and 150 m 2 / g.
  • compositions according to the invention contain as the second essential constituent a polar solvent.
  • Preferred compositions contain the polar solvent based on their total weight in amounts of from 42 to 88% by weight, preferably from 45 to 87% by weight.
  • polar solvent Einzelsubtanzen As a polar solvent Einzelsubtanzen or mixtures of substances can be used.
  • Preferred polar solvents besides water are the polyols.
  • Preferred agents according to the invention are characterized in that they contain less than four, preferably one to three, but in particular only one polyol.
  • Polyols from the group of glycerol, 1,2-ethanediol, polyethylene glycols with MW> 400 are particularly suitable for the preparation of cosmetic compositions.
  • Particularly suitable organic polyols are glycerol, sorbitol and panthenol.
  • compositions according to the invention are therefore characterized in that they contain as organic polyol at least one compound from the group of glycerol, sorbitol and panthenol, preferably glycerol.
  • compositions which contain as polar solvent b) at least one solvent from the group consisting of water and glycerol, preferably water.
  • compositions according to the invention which contain primarily or exclusively water as the polar solvent.
  • compositions according to the invention which contain primarily or exclusively water as the polar solvent.
  • compositions according to the invention which contain primarily or exclusively water as the polar solvent.
  • Corresponding preferred compositions are characterized in that they are based on their total weight
  • glycerol less than 10% by weight, preferably less than 5% by weight, preferably less than 1% by weight, of glycerol.
  • compositions according to the invention having a low polyol content it is preferred to add a further polar solvent to the compositions in the balance, wherein the addition of water is particularly preferred.
  • Preferred compositions are therefore characterized by being based on their total weight
  • compositions preferred according to the invention are characterized in that they are based on their total weight
  • the addition of the polyol improves the mechanical properties of compositions according to the invention during storage and application and has advantageous cosmetic effects.
  • the compositions according to the invention contain 0.01 to 5.0% by weight of encapsulated perfume preparation c).
  • the weight percentage of the encapsulated fragrance preparation c) in the total weight of the compositions is preferably from 0.05 to 3.0% by weight, preferably from 0.1 to 2.0% by weight and in particular from 0.2 to 1.0% by weight. %.
  • perfume oils or fragrances can be individual perfume compounds, for example the synthetic products of the ester type, ethers, aldehydes, Ketones, alcohols and hydrocarbons are used. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance.
  • perfume oils may also contain natural fragrance mixtures such as those available from vegetable sources, such as pine, citrus, jasmine, patchouly, rose or ylang-ylang oil.
  • a fragrance In order to be perceptible, a fragrance must be volatile, whereby besides the nature of the functional groups and the structure of the chemical compound, the molecular weight also plays an important role. For example, most odorants have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and above are more of an exception. Due to the different volatility of fragrances, the smell of a perfume or fragrance composed of several fragrances changes during evaporation, whereby the odor impressions in "top note”, “middle note” or “body note” ) and “base note” (end note or dry out).
  • the top note of a perfume does not consist solely of volatile compounds, while the base note is largely made up of less volatile, i. adherent fragrances.
  • more volatile fragrances can be bound to certain fixatives, preventing them from evaporating too quickly.
  • fixatives preventing them from evaporating too quickly.
  • compositions according to the invention contain fragrances or perfume mixtures in encapsulated form.
  • capsule materials for these fragrances or perfume mixtures in particular the organic polymers have been proven.
  • Preferred compositions are characterized in that the encapsulated fragrance preparation c) comprises a polymeric capsule material, preferably a capsule material from the group of anionic or nonionic polysaccharides, in particular a capsule material from the group sodium starch octenylsuccinate and (optionally modified) corn starch.
  • compositions according to the invention are copolymers d) which are obtained by polymerization of the monomers N-tert-octylacrylamide, acrylic acid and tert-butylaminoethylmethacrylic acid.
  • Preferred copolymers d) consist of at least 90% by weight, preferably at least 95% by weight and in particular at least 97% by weight, of the monomers N-tert-octylacrylamide, acrylic acid and tert. Butylaminoethylmethacrylkla.
  • Particularly preferred copolymers d) were obtained exclusively from the monomers N-tert-octylacrylamide, acrylic acid and tert-butylaminoethylmethacrylic acid.
  • copolymers d) described above for example, under the name Amphomer ® INCI name: distributed Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer from the company National Starch.
  • compositions according to the invention are characterized in that the weight fraction of the copolymer d) in the total weight of the composition is 0.01 to 15% by weight, preferably 0.02 to 12% by weight, preferably 0.03 to 8.0% by weight. % and in particular from 0.05 to 1, 0 wt .-% is.
  • compositions which, based on their total weight, 0.01 to 15 wt .-%, preferably 0.02 to 12 wt .-%, preferably 0.03 to 8.0 wt .-% and in particular of 0 , 05 to 1, 0 wt .-% of at least one copolymer d) from the monomers
  • composition of some preferred cosmetic agents can be found in the following tables (data in% by weight based on the total weight of the cosmetic agent, unless stated otherwise).
  • Polar solvent 40 to 89 42 to 88 42 to 88 45 to 87 45 to 87 encapsulated perfume 0.01 to 5.0 0.05 to 3.0 0.1 to 2.0 0.1 to 2.0 0.2 until 10
  • the cosmetic compositions of the invention may contain other auxiliaries, care agents and additives.
  • the proportion by weight of the further constituents contained in the pulverulent compositions according to the invention in addition to the components a) to c), in particular the further auxiliaries, care agents and additives contained in these compositions in the total weight of the pulverulent compositions according to the invention is preferably less than 10% by weight, preferably less than 5.0% by weight, especially preferably less than 2.0% by weight and in particular less than 1.0% by weight.
  • the proportion by weight of these auxiliaries, care agents and additives in the total weight of the cosmetic compositions according to the invention can be, for example, from 0.001 to 2% by weight, in particular from 0.01 to 0.5% by weight.
  • the pulverulent compositions according to the invention can be formulated in arbitrary containers, as long as it is ensured that the mechanical loading of the powder during the removal of the composition does not lead to liquefaction.
  • Suitable, for example, crucibles, bottles or tetra packs, the container can be configured for example with a bulk and metering device.
  • a further subject of the present application is the use of a cosmetic composition according to the invention for the temporary deformation of keratin-containing fibers, in particular human hair.
  • the powdery composition for the temporary deformation of keratinous fibers
  • the desired amount of the pulverulent composition is first removed from the container.
  • the composition can be applied directly to the keratinic fiber to be treated or, for example, to the hand.
  • the applied powder directly on the keratin fiber can be subjected to a mechanical load, for example by means of the hands, whereby the liquid, aqueous phase is released directly on the fiber.
  • the powdered composition is first given to the hand, then it can first be carefully distributed in the hair and then again be subjected to greater mechanical stress, for example by targeted massaging the powder into the hair. This releases the liquid, aqueous phase on the hair.
  • the powdery composition can also be applied with an aid, such as a brush, a sponge, a cloth, a brush or a comb.
  • a further subject of the present application is a method for the temporary deformation of keratin-containing fibers, in particular human hair, in which the keratinic fibers are acted upon by a cosmetic composition according to the invention and temporarily fixed in their form, characterized in that from the cosmetic Composition before, during or after application to the keratinic fibers by the action of a force a plastically deformable mass is formed.
  • the powdered styling agents V1 to V6 were prepared as described below (in% by weight):
  • Amphomer.RTM ® (INCI name: octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer) National Starch.
  • the finished styling powder thus obtained was filled into polyethylene bottles.

Abstract

L'invention concerne des compositions cosmétiques pulvérulentes contenant a) de 10 à 30 % en poids d'une poudre d'oxyde métallique rendue hydrophobe, b) de 40 à 89 % en poids d'un solvant polaire et c) de 0,01 à 5,0 % d'une préparation de parfum encapsulée. Ces compositions sont particulièrement destinées à mettre en forme et parfumer des fibres kératiniques et confèrent de la brillance, de la texture et de la souplesse.
EP14796691.5A 2013-12-23 2014-10-08 Agents et procédés pour mettre en forme temporairement des fibres kératiniques Ceased EP3086755A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013227118.2A DE102013227118A1 (de) 2013-12-23 2013-12-23 Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern
PCT/DE2014/200538 WO2015096837A1 (fr) 2013-12-23 2014-10-08 Agents et procédés pour mettre en forme temporairement des fibres kératiniques

Publications (1)

Publication Number Publication Date
EP3086755A1 true EP3086755A1 (fr) 2016-11-02

Family

ID=51897038

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14796691.5A Ceased EP3086755A1 (fr) 2013-12-23 2014-10-08 Agents et procédés pour mettre en forme temporairement des fibres kératiniques

Country Status (4)

Country Link
US (1) US20160287486A1 (fr)
EP (1) EP3086755A1 (fr)
DE (1) DE102013227118A1 (fr)
WO (1) WO2015096837A1 (fr)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040048771A1 (en) * 2002-09-09 2004-03-11 Mcdermott Keith J. Encapsulated perfume compositions in hair and skin products which release a burst of fragrance after initial topical application

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6290941B1 (en) 1999-11-23 2001-09-18 Color Access, Inc. Powder to liquid compositions
DE10153077A1 (de) 2001-10-30 2003-05-22 Degussa Verwendung von Granulaten auf Basis von Pyrogen hergestelltem Siliciumdioxid in kosmetischen Zusammensetzungen
DE102004056862A1 (de) * 2004-11-25 2006-06-14 Degussa Ag Pulverförmige, kosmetische Zubereitung mit hohem Wassergehalt
US20070207174A1 (en) * 2005-05-06 2007-09-06 Pluyter Johan G L Encapsulated fragrance materials and methods for making same
DE102005052585A1 (de) 2005-11-02 2007-05-03 Henkel Kgaa Pulverförmiges Stylingmittel
DE102008057261A1 (de) 2008-11-13 2010-05-20 Henkel Ag & Co. Kgaa Pulverförmige Stylingmittel
DE102009002267A1 (de) * 2009-04-07 2010-10-14 Henkel Ag & Co. Kgaa Pulverförmige Zusammensetzung zur Form- und Glanzgebung keratinischer Fasern
FR2944438B1 (fr) * 2009-04-15 2011-06-17 Oreal Procede de mise en forme des cheveux au moyen d'une composition reductrice et d'un chauffage.

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040048771A1 (en) * 2002-09-09 2004-03-11 Mcdermott Keith J. Encapsulated perfume compositions in hair and skin products which release a burst of fragrance after initial topical application

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2015096837A1 *

Also Published As

Publication number Publication date
DE102013227118A1 (de) 2015-06-25
WO2015096837A1 (fr) 2015-07-02
US20160287486A1 (en) 2016-10-06

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