WO2016030043A1

WO2016030043A1 - Agent and method for the temporary shaping of keratin-containing fibers

Info

Publication number: WO2016030043A1
Application number: PCT/EP2015/064175
Authority: WO
Inventors: Anna Henschel; Jisook Baek; Arne Junge
Original assignee: Henkel Ag & Co. Kgaa
Priority date: 2014-08-25
Filing date: 2015-06-24
Publication date: 2016-03-03
Also published as: DE102014216861A1

Abstract

The invention relates to cosmetic compositions, containing: a) 0.1 to 25 wt.%. of hydrophobised metal oxide powder, b) 0.1 to 20 wt.% of at least one homo- and/or copolymer, c) 0.10 to 20 wt.% of wax, d) 1.0 to 30 wt.% of emulsifier, e) 0.5 to 70 wt.% of an organic polyol, f) 1.0 to 90 wt.% of water, which are suitable in a special manner for the temporary shaping of keratinous fibers.

Description

"Means and Method of Temporarily Deforming Keratinous Fibers"

The application relates to the technical field of temporary deformation keratinhaltiger fibers, especially human hair.

Styling agents for the deformation of keratin-containing fibers have long been known and find use in various embodiments for the construction, for refreshing and for fixing hairstyles, which can be obtained in many hair types only using firming agents. Both hair treatment products, which serve a permanent, as well as those that serve a temporary shaping of the hair, play an important role.

For the temporary shaping keratinhaltiger fibers are sprayable products as well as supply forms, which are incorporated with the help of a comb or with your fingers in the hairstyle. The latter product group includes oils as well as gels, creams and powders. In particular, the powdered styling agents are enjoying increasing popularity due to their ease of dosing and their cosmetic properties such as high hairstyle hold, volume increase, remodeling and their matting effect.

For example, German Patent Application DE102008057261 A1 describes pulverulent compositions which are used for temporary shaping of hair for a very strong hold of the fixed hairstyle.

The subject of the international application WO 2007/05151 1 A1 is the use of a pulverulent composition containing 50 to 95% by weight of an aqueous solvent, hydrophobized silica powder and at least one film-forming and / or setting polymer in the aqueous solvent for the temporary deformation of keratinic fibers.

Although the state-of-the-art powdered hair cosmetics have now achieved good hold, high volume and good dosability. However, the matting effect associated with the use of these agents does not meet the wishes of all consumers and is replaced, at least in part, by the desire for hair care and hair shine.

The object of the present invention was therefore to provide hair treatment composition for temporary shaping available, which in addition to a good hairstyle, high Hair volume, hair strength and remodeling ability are characterized by increased hair shine. The funds should also be applicable to wet as well as dry hair.

It has been found that these tasks can be solved with the aid of a complex mixture of active ingredients, which among other constituents u.a. a hydrophobized metal oxide powder usually used in powdered styling agents is added. A first subject of the present application are cosmetic compositions containing

a) 0, 1 to 25 wt .-% hydrophobized metal oxide powder

b) 0, 1 to 20 wt .-% of at least one homo- and / or copolymer

c) 0, 10 to 20 wt .-% wax

d) 1, 0 to 30 wt .-% emulsifier

e) 0.5 to 70 wt .-% organic polyol

f) 1, 0 to 90 wt .-% water.

The agents according to the invention are preferably in the form of creams or pastes. The viscosity of agents according to the invention is preferably between 70,000 and 600,000 mPas, preferably between 100,000 and 400,000 mPas (20 ° C., DV 2T "Brookfield" rotational viscometer, spindle TE, 5 revolutions per minute and Helipath).

A first essential component of compositions according to the invention is the hydrophobized metal oxide powder. Preferred compositions are characterized in that they contain the hydrophobized metal oxide powder, based on their total weight, in amounts of from 0.1 to 20% by weight, preferably from 0.5 to 15% by weight and in particular from 1.0 to 10% by weight. % contain. In addition to the proportions by weight of the other constituents, the optimum amount depends above all on the hydrophobicity of the silicon dioxide powder used.

For the purposes of the invention, hydrophobed are to be understood as meaning those metal oxides which have been modified at least on the surface of the particles in such a way that the modified particle is wetted less by water than the unmodified particle.

The particle diameter of the primary particles of preferred hydrophobized metal oxides is preferably less than 5 μm, particularly preferably less than 1 μm, and in particular between 1 and 50 nm.

As reagent for the silanization of the metal oxide, according to the invention, at least one member of the group which is formed, from silanes, halosilanes, alkoxysilanes and silazanes is preferably suitable. Preferred hydrophobized metal oxides of the hydrophobized metal oxide powder are selected according to the invention from at least one member of the group which is formed from hydrophobized silicates, hydrophobized aluminum silicates, hydrophobized titanium dioxide and hydrophobized silica. Hydrophoborated silicates have proved particularly suitable for the preparation of the cosmetic compositions according to the invention, with fumed silica aftertreated by silanization or by reaction with polydimethylsiloxane having particular advantages.

With particular preference the pulverulent composition according to the invention contains as hydrophobized metal oxide powder at least hydrophobized silicon dioxide. Preference is furthermore given to those hydrophobicized silicon dioxides which have a BET specific surface area of between 10 and 400 m ² / g, preferably between 40 and 300 m ² / g and in particular between 80 and 150 m ² / g.

The pulverulent composition according to the invention particularly preferably contains as hydrophobized metal oxide powder at least silanized, hydrophobized silicon dioxide.

As a reagent for silanizing the silicon dioxide, at least one member of the group which is formed from silanes, halosilanes, alkoxysilanes and silazanes is preferably suitable according to the invention.

Preferred representatives of the group of silanes are hexa (C 1 -C 20) alkyldisilanes, in particular hexamethyldisilane.

When a halosilane is used as the silylating agent, as the preferred halosilane, at least one compound selected from the group consisting of the compounds is selected

[(C ₁ -C 20) alkyl] z'SiX (4-z ')

X ₃ Si [(CH ₂ ) _n -R]

X ₂ [(C 1 -C 20) alkyl] Si (CH ₂ ) n R

[(C 1 -C 20) alkyl] ( _{y +1} ) [R- (CH 2) n] (2-y ') SiX

wherein

X represents a chlorine, bromine or iodine atom,

z 'is a number 1, 2 or 3,

y 'is a number 0, 1 or 2

n is an integer from 1 to 20 and

R stands for a rest

(C ₁ -C 10) alkyl, aryl, (C ₁ -C ₆ ) perfluoroalkyl, -NH ₂ , -N ₃ , -SCN, -CH = CH ₂ ,

-0 (0) CC (CH ₃ ) = CH ₂ , -OCH ₂ -CH = CH ₂ ,

-NHC (O) -NC (0) - (CH ₂ ) 5

I i

-NH-C (O) O-Me, -NH-C (O) O-Et, -NH- (CH ₂ ) 3-Si (O (C 1 -C ₆ ) alkyl) 3.

When an alkoxysilane is used as the silylating agent, as the preferred alkoxysilane, at least one compound selected from the group consisting of the compounds is selected

[(C ₁ -C 20) alkyl O] z Si (C ₁ -C 20) alkyl (4-z)

[(C 1 -C 20) alkyl O] z Si [(CH ₂ ) n R] ₍ 4-z) [(C 1 -C 20) alkylO] 2 [(C 1 -C 20) alkyl] Si (CH ₂ ) _n -R

[(Ci-C2o) alkylO] [(Ci-C2o) alkyl] ₂ Si (CH ₂₎ n

[(C 1 -C 20) alkylO] [(C 1 -C 20) alkyl] Si [(CH ₂ ) n R] ₂

(C 1 -C 20 -alkyl) ₃ SiO-C (CH ₃ ) = N-Si (C 1 -C 20) alkyl 3,

wherein

n is an integer from 1 to 20 and

z is a number 1, 2, or 3

R stands for a rest

(C ₁ -C 20) alkyl, aryl, (C ₁ -C ₆ ) perfluoroalkyl, -NH ₂ , -N ₃ , -SCN, -CH = CH ₂ ,

-0 (0) CC (CH ₃ ) = CH ₂ , -OCH ₂ -CH = CH ₂ ,

-NHC (O) -NC (0) - (CH ₂ ) ₅

I i

-NH-C (O) O-Me, -NH-C (O) O-Et, -NH- (CH ₂ ) ₃ -Si (O (C 1 -C ₆ ) alkyl) ₃ .

As a preferred silazane is at least one compound from the class of disilazanes, in particular at least one compound of disilazanes of the formula

selected in which

R 'is a (Ci-C2o) alkyl group and

R "represents a (C 1 -C 20) alkyl group or a vinyl group A particularly preferred silazane is hexamethyldisilazane.

All of the abovementioned alkyl groups, whether (C 1 -C 6) -alkyl, (C 1 -C 10) -alkyl or (C 1 -C 20) -alkyl, may be both cyclic and linear or branched. Examples of alkyl groups which can be used according to the invention are methyl, ethyl, n-propyl, isopropyl, n-butyl, cyclopentyl, cyclohexyl, n-decyl, lauryl, myristyl, cetyl, stearyl, isostearyl and behenyl.

An example of an aryl group according to the invention is the phenyl group.

Examples of a (Ci-C6) perfluoroalkyl group according to the invention are trifluoromethyl, perfluoroethyl, perfluoropropyl and perfluorohexyl.

Preference is given to using hydrophobized silicon dioxides which are obtained by silanization of fumed silica.

Silanized, hydrophobized silicas are particularly preferably selected from at least one compound of the group formed from trimethylsilylate-coated silica, dimethylsilylate-coated silica, octylsilylate-coated silica.

Preference is given to using hydrophobicized silicas obtained by silanization of fumed silica. Compositions which contain as hydrophobized metal oxide powder a hydrophobized silicate obtained by silanization of fumed silica are preferred on account of their product properties, in particular their storage stability and their cosmetic action. A variety of suitable hydrophobized silicas are commercially available. Examples include Aerosil ^® R104 V, Aerosil ^® R106, Aerosil ^® R202, Aerosil ^® R805, Aerosil ^® R812, Aerosil ^® R812S, Aerosil ^® R972 and Aerosil ^® R8200, all Degussa, and HDK ^® H2000, HDK ^® H2050 and HDK ^® H3004 , all Wacker, called.

Particularly preferably, the hydrophobic silicas are used which are available under the names Aerosil ^® R202, Aerosil ^® R812S or Aerosil ^® R972. Most preferably, the silica comes with the INCI name silica Silylate used, which is sold by Degussa under the name Aerosil ^® R812S.

An alternative to hydrophobization by silanization offers the post-treatment with polydimethylsiloxane. Corresponding compositions according to the invention which contain a polydimethylsiloxane aftertreated fumed silica. Corresponding metal oxides with the INCI designation "Silica Dimethicone silylate" are sold for example by Evonik under the trade name Aersoil ^® R202.

A second essential constituent of cosmetic compositions according to the invention is the homo- and / or copolymer b). Preferred compositions are characterized in that they contain the homo- and / or copolymer b), based on their total weight, in amounts of from 0.1 to 18% by weight, preferably from 1.0 to 17% by weight and in particular from 5, 0 to 15 wt .-% included.

As homo- and / or copolymers b) are used with particular preference nonionic polymers. Suitable nonionic homopolymers and / or copolymers b) are, for example:

Polyvinylpyrrolidones, as (BASF) are sold for example under the name Luviskol ^®, preferred homopolymers b).

Vinylpyrrolidone / vinyl ester copolymers, as sold, for example, under the trademark Luviskol ^® (BASF). Luviskol ^® VA 64 and Luviskol ^® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are preferred nonionic copolymers b).

Cellulose ethers, such as hydroxypropyl cellulose, hydroxyethyl cellulose and methyl hydroxypropyl cellulose.

Preferred compositions contain as homo- and / or copolymer b) polyvinylpyrrolidone and / or vinylpyrrolidone / vinyl acetate copolymer, preferably polyvinylpyrrolidone.

As a third essential ingredient containing compositions according to the invention a wax c). The amount of wax used, based on their total weight of Compositions, preferably 0.2 to 15 wt .-%, preferably 0.5 to 12 wt .-% and in particular 1, 0 to 10 wt .-%.

Preferred waxes have a melting point in the range of 40 ° C to 90 ° C, more preferably in the range of 50 ° C to 85 ° C and especially in the range of 50 ° C to 75 ° C.

In principle, all waxes can be used which melt in the temperature range mentioned and which are physiologically compatible. Particularly preferred waxes according to the invention are beeswax, carnauba wax, candelilla wax, montan wax and microcrystalline waxes, but preferably beeswax.

The teaching according to the invention also comprises the combined use of several waxes. Thus, addition of small amounts of carnauba wax can be used to increase the melting and dripping point of another wax and reduce its stickiness. Furthermore, a number of wax mixtures, optionally in admixture with other additives, commercially available. Those under the designations "Spezialwachs 7686 OE" (a mixture of Cetylpalmitat, beeswax, microcrystalline wax and polyethylene with a melting range of 73-75 ° C, manufacturer: Kahl & Co), Polywax ^® GP 200 (a mixture of stearyl alcohol and polyethylene glycol stearate with a melting point of 47-51 ° C, manufactured by Croda), and "Weichceresin ^® FL 400" (a petrolatum / vaseline oil / wax mixture having a melting point of 50- 54 ° C; manufacturer: Parafluid mineral oil company) are examples of the present invention is preferably used mixtures.

By adding wax to the cosmetic preparations used according to the invention, an unexpected increase in volume of the temporarily deformed keratinic fibers could be achieved.

The fourth essential constituent of cosmetic compositions according to the invention is emulsifier d). The proportion by weight of emulsifier d) in the total weight in the total weight of the compositions is preferably from 1.5 to 20% by weight, preferably from 2.0 to 12% by weight and in particular from 2.0 to 10% by weight.

The cosmetic compositions preferably further comprise at least one member selected from the group consisting of anionic, amphoteric, zwitterionic, nonionic, cationic emulsifiers or mixtures thereof. Preference is given to using solid emulsifiers at room temperature (20 ° C.), in particular solid nonionic emulsifiers at room temperature (20 ° C.).

Particularly suitable nonionic emulsifiers are the fatty acid partial glycerides, which are understood as meaning monoglycerides, diglycerides and technical mixtures thereof. When using technical products may contain small quantities of triglycerides due to their production. The partial glycerides preferably follow the formula

I

CH ₂ O (CH ₂ CH ₂ O) _q R ³ in the R, R ² and R ^{3 are} independently of one another hydrogen or a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22, preferably 12 to 18, carbon atoms are provided with the proviso that at least one of these groups is an acyl radical and at least one of these groups is hydrogen. The sum (m + n + q) is 0 or numbers from 1 to 100, preferably 0 or 5 to 25. Preferably, R is an acyl radical and R ² and R ^{3 are} hydrogen and the sum (m + n + q ) is 0. Typical examples are mono- and / or diglycerides based on caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, Elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures. Preferably, oleic acid monoglycerides are used.

Another group of preferred emulsifiers d) are the surface-active, medium-chain fatty alcohols, in particular cetyl alcohol and stearyl alcohol.

Particularly preferred emulsifiers d) are selected

i) from the group of fatty acid partial glycerides, preferably from the group glycerol monostearate and glyceryl distearate

ii) from the group of surface-active, medium-chain fatty alcohols, preferably from the group cetyl alcohol and stearyl alcohol

Very particular preference is given to the use of an emulsifier combination of fatty acid partial glycerides and surface-active, medium-chain fatty alcohols, preferably a combination of glycerol monostearate and glyceryl distearate with cetyl alcohol and stearyl alcohol, in particular a combination of glycerol monostearate and glyceryl distearate with cetyl alcohol and stearyl alcohol.

The compositions according to the invention contain as the fifth essential constituent an organic polyol. Preferred compositions contain the organic polyol e) based on their total weight in amounts of 0.5 to 60, preferably 1, 0 to 50 wt .-% and in particular 1, 5 to 25 wt .-%. The polyol can be used as a single substance or in the form of polyol mixtures. Preferred agents according to the invention are characterized in that they contain less than four, preferably one to three, but in particular only one polyol. Polyols from the group of glycerol, 1,2-ethanediol, polyethylene glycols having MW> 400, propanediol, butanediol, in particular 1,3-butanediol, hexanediol, in particular 1,6-hexanediol, sorbitol, threitol, erythritol, are particularly suitable for the preparation of cosmetic compositions. Arabitol, altritol, ribitol, xylitol, galactitol, mannitol, iditol and panthenol. Particularly suitable organic polyols are glycerol, sorbitol and panthenol. Preferred compositions according to the invention are characterized in that they contain as organic polyol e) at least one polyol from the group consisting of glycerol, polyethylene glycol, propylene glycol, butylene glycol and hexanediol, preferably glycerol.

The addition of the polyol e) improves the properties of inventive compositions during storage and application and has advantageous cosmetic effects.

The proportion by weight of the polyol be on the total weight of compositions according to the invention can vary within wide ranges. In compositions according to the invention having a low polyol content, a larger amount of water is preferably added to the compositions in equilibrium. The water content erindungsgemäßer compositions is preferably 10 to 85 wt .-%, preferably 40 to 85 wt .-% and in particular 65 to 82 wt .-%.

Combine contain preferred compositions of the invention

a) 1, 0 to 10 wt .-% hydrophobized metal oxide powder

b) 5.0 to 15 wt .-% of at least one homo- and / or copolymer

c) 1, 0 to 10 wt .-% wax

d) 4.0 to 10 wt .-% emulsifier

e) 2.0 to 20 wt .-% organic polyol

f) 65 to 82% by weight of water

A more concrete embodiment of such a preferred composition according to the invention

a) 1, 0 to 10 wt .-% obtained by silanization of fumed silica hydrophobic silicate

b) 5.0 to 15% by weight of polyvinylpyrrolidone

c) 1, 0 to 10 wt .-% beeswax

d) 4.0 to 10 wt .-% emulsifier

e) 2.0 to 20 wt .-% glycerol

f) 65 to 82% by weight of water. The composition of some preferred cosmetic agents can be found in the following tables (data in% by weight based on the total weight of the cosmetic agent, unless stated otherwise).

Formula 16 Formula 17 Formula 18 Formula 19 Formula 20 Hydrophobic 0.1 to 25 0.1 to 20 0.5 to 15 0.5 to 15 1.0 to 10 silicon dioxide

Homo- and / or 0.1 to 20 0.1 to 18 1.0 to 17 1.0 to 17 5.0 to 15 copolymer

Wax 0.1 to 20 0.2 to 15 0.5 to 12 0.5 to 12 1.0 to 10

Fatty acid polyglyceride 1.0 to 30 1.5 to 20 2.0 to 12 2.0 to 10 2.0 to 10 organic polyol 0.5 to 70 0.5 to 60 1, 0 to 50 1.5 to 25 1 , 5 to 25

Water 1.0 to 90 10 to 85 40 to 85 65 to 82 65 to 82

Optional Additives add 100 add 100 add 100 add 100 add 100

Formula 31 Formula 32 Formula 33 Formula 34 Formula 35

Hydrophobic 0.1 to 25 0.1 to 20 0.5 to 15 0.5 to 15 1.0 to 10 silicon dioxide

Vinyl pyrrolidone homo- or 0.1 to 20 0.1 to 18 1.0 to 17 1.0 to 17 5.0 to 15 copolymer Wax 0.1 to 20 0.2 to 15 0.5 to 12 0.5 to 12 1.0 to 10

Water 1.0 to 90 10 to 85 40 to 85 65 to 82 65 to 82

Optional Additives add 100 add 100 add 100 add 100 add 100

Formula 46 Formula 47 Formula 48 Formula 49 Formula 50

Hydrophobic 0.1 to 25 0.1 to 20 0.5 to 15 0.5 to 15 1.0 to 10 silicon dioxide

Vinyl pyrrolidone homo- or 0.1 to 20 0.1 to 18 1.0 to 17 1.0 to 17 5.0 to 15 copolymer

Wax 0.1 to 20 0.2 to 15 0.5 to 12 0.5 to 12 1.0 to 10

C16-18 fat liquor 1.0 to 30 1.5 to 20 2.0 to 12 2.0 to 10 2.0 to 10

Polyol 0.5 to 70 0.5 to 60 1.0 to 50 1.5 to 25 1.5 to 25

Water 1.0 to 90 10 to 85 40 to 85 65 to 82 65 to 82 Optional Additives add 100 add 100 add 100 add 100 add 100

Formula 66 Formula 67 Formula 68 Formula 69 Formula 60

Hydrophobic 0.1 to 25 0, 1 to 20 0.5 to 15 0.5 to 15 1, 0 to 10 silicon dioxide Vinyl pyrrolidone vinyl acetate 0.1 to 20 0.1 to 18 1.0 to 17 1.0 to 17 5.0 to 15 Copolymer

Wax 0.1 to 20 0.2 to 15 0.5 to 12 0.5 to 12 1.0 to 10

C16-18 fat liquor 1.0 to 30 1.5 to 20 2.0 to 12 2.0 to 10 2.0 to 10

Polyol 0.5 to 70 0.5 to 60 1.0 to 50 1.5 to 25 1.5 to 25

Water 1.0 to 90 10 to 85 40 to 85 65 to 82 65 to 82

Optional Additives add 100 add 100 add 100 add 100 add 100

Formula 71 Formula 72 Formula 73 Formula 74 Formula 75

Hydrophobic 0.1 to 25 0.1 to 20 0.5 to 15 0.5 to 15 1.0 to 10 silicon dioxide

Polyvinylpyrrolidone 0.1 to 20 0.1 to 18 1.0 to 17 1.0 to 17 5.0 to 15

Beeswax 0.1 to 20 0.2 to 15 0.5 to 12 0.5 to 12 1.0 to 10

Fatty acid polyglyceride 2.0 to 30 3.0 to 20 4.0 to 12 4.0 to 10 4.0 to 10 and C16-18 fatty alcohol

Polyol 0.5 to 70 0.5 to 60 1.0 to 50 1.5 to 25 1.5 to 25 Water 1, 0 to 90 10 to 85 40 to 85 65 to 82 65 to 82

Optional Additives add 100 add 100 add 100 add 100 add 100

A second subject of this application is the use of a cosmetic composition according to the invention for the temporary deformation of keratin-containing fibers, in particular human hair. A third subject of this application is a method for the temporary deformation of keratin-containing fibers, in particular human hair, in which the keratinic fibers are acted upon by a cosmetic composition according to the invention and temporarily fixed in their form.

The compositions, uses, and methods of the invention, and some of their preferred embodiments, are characterized by the following items:

1. Cosmetic compositions containing

a) 0, 1 to 25 wt .-% hydrophobized metal oxide powder

b) 0, 1 to 20 wt .-% of at least one homo- and / or copolymer

c) 0, 10 to 20 wt .-% wax

d) 1, 0 to 30 wt .-% emulsifier

e) 0.5 to 70 wt .-% organic polyol

f) 1, 0 to 90 wt .-% water

2. Compositions according to item 1, characterized in that it comprises the hydrophobized metal oxide powder based on their total weight in amounts of 0, 1 to 20 wt .-%, preferably from 0.5 to 15 wt .-% and in particular from 1, 0 to Contains 10 wt .-%.

3. Compositions according to one of the preceding points, characterized in that it contains as hydrophobized metal oxide powder obtained by silanization of fumed silica hydrophobic silicate.

4. Compositions according to one of the preceding points, characterized in that they the homo- and / or copolymer b) based on their total weight in amounts of 0.1 to 18 wt .-%, preferably from 1, 0 to 17 parts by weight. % and in particular from 5.0 to 15 wt .-%.

5. Compositions according to one of the preceding points, characterized in that they contain as homo- and / or copolymer b) polyvinylpyrrolidone and / or vinylpyrrolidone / vinyl acetate copolymer, preferably polyvinylpyrrolidone.

6. Compositions according to one of the preceding points, characterized in that the wax c) based on their total weight in amounts of 0.2 to 15 wt .-%, preferably from 0.5 to 12 wt .-% and in particular of 1, 0 to 10 wt .-%.

7. Compositions according to one of the preceding points, characterized in that the wax c) at least one wax from the group beeswax, carnauba wax, candelilla wax, montan wax and microcrystalline waxes, preferably beeswax. 8. Compositions according to one of the preceding points, characterized in that they contain the emulsifier d) based on their total weight in amounts of 1, 5 to 20 wt .-%, preferably from 2.0 to 12 wt .-% and in particular from 2 , 0 to 10 wt .-%.

9. Composition according to one of the preceding points, characterized in that the emulsifier d) is selected

ii) from the group grenflächenaktiven, medium-chain fatty alcohols, preferably from the group cetyl alcohol and stearyl alcohol

10. Compositions according to one of the preceding points, characterized in that they the organic polyol e) based on their total weight in amounts of 0.5 to 60, preferably 1, 0 to 50 wt .-% and in particular 1, 5 to 25 wt .-% contains.

1 1. Compositions according to one of the preceding points, characterized in that they contain as organic polyol e) at least one polyol from the group glycerol, polyethylene glycol, propylene glycol, butylene glycol and hexanediol, preferably glycerol.

12. Compositions according to one of the preceding points, characterized in that they contain 10 to 85 wt .-%, preferably 40 to 85 wt .-% and in particular 65 to 82 wt .-% water.

13. Containing compositions

a) 1, 0 to 10 wt .-% hydrophobized metal oxide powder

b) 5.0 to 15 wt .-% of at least one homo- and / or copolymer

c) 1, 0 to 10 wt .-% wax

d) 4.0 to 10 wt .-% emulsifier

e) 2.0 to 20 wt .-% organic polyol

f) 65 to 82% by weight of water

14. Containing compositions

b) 5.0 to 15% by weight of polyvinylpyrrolidone

c) 1, 0 to 10 wt .-% beeswax

d) 4.0 to 10 wt .-% emulsifier

e) 2.0 to 20 wt .-% glycerol f) 65 to 82% by weight of water

15. Use of a cosmetic composition according to one of the preceding points for the temporary deformation of keratin-containing fibers, in particular human hair.

16. A method for the temporary deformation keratin fibers, in particular human hair, in which the keratinic fibers are acted upon with a cosmetic composition according to any one of items 1 to 14 and temporarily fixed in their shape.

Claims

claims

1. Cosmetic compositions containing

a) 0, 1 to 25 wt .-% hydrophobized metal oxide powder

b) 0, 1 to 20 wt .-% of at least one homo- and / or copolymer

c) 0, 10 to 20 wt .-% wax

d) 1, 0 to 30 wt .-% emulsifier

e) 0.5 to 70 wt .-% organic polyol

f) 1, 0 to 90 wt .-% water

2. Compositions according to claim 1, characterized in that it comprises the hydrophobized metal oxide powder, based on its total weight in amounts of 0.1 to 20 wt .-%, preferably from 0.5 to 15 wt .-% and in particular from 1, 0 to Contains 10 wt .-%.

3. Compositions according to one of the preceding claims, characterized in that it contains as hydrophobized metal oxide powder obtained by silanization of fumed silica hydrophobic silicate.

4. Compositions according to one of the preceding claims, characterized in that they the homo- and / or copolymer b) based on their total weight in amounts of 0, 1 to 18% by weight, preferably from 1, 0 to 17 wt. % and in particular from 5.0 to 15 wt .-%.

5. Compositions according to one of the preceding claims, characterized in that they contain as homo- and / or copolymer b) polyvinylpyrrolidone and / or vinylpyrrolidone / vinyl acetate copolymer, preferably polyvinylpyrrolidone.

6. Compositions according to one of the preceding claims, characterized in that they the wax c) based on their total weight in amounts of 0.2 to 15 wt .-%, preferably from 0.5 to 12 wt .-% and in particular of 1, 0 to 10 wt .-%.

7. Compositions according to one of the preceding claims, characterized in that they the emulsifier d) based on their total weight in amounts of 1, 5 to 20 wt .-%, preferably from 2.0 to 12 wt .-% and in particular of 2 , 0 to 10 wt .-%.

8. Compositions according to one of the preceding claims, characterized in that they the organic polyol e) based on their total weight in amounts of 0.5 to 60, preferably 1, 0 to 50 wt .-% and in particular 1, 5 to 25 wt .-% contains.

9. Use of a cosmetic composition according to one of the preceding claims for the temporary deformation of keratin-containing fibers, in particular human hair.

10. A method for the temporary deformation keratin fibers, in particular human hair, in which the keratinic fibers are acted upon with a cosmetic composition according to any one of claims 1 to 8 and temporarily fixed in its shape.