JP2007070232A - Oil-in-water type eyelash cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain an oil-in-water type eyelash cosmetic that has makeup effect on eyelashes (curl effect and volume up effect), excellent usability, make-up lasting quality (durability of effect and no bleeding), light spread and smoothness while exhibiting especially high curling power, consequently prevents bundle sticking, provides a uniform film, as a result, produces durability of curling power and satisfies both high curling power and light and smooth usability. <P>SOLUTION: The oil-in-water type eyelash cosmetic is obtained by mixing (A) a phospholipid with (B) one or more kinds of nonionic surfactants selected from a polyoxyethylene cholesterol ether, a polyoxyethylene cholestanol ether, a polyoxyethylene phytosterol ether and a polyoxyethylene phytostanol ether, (C) 10-30 mass% of solid oil having 60-110°C melting point, (D) a water-insoluble film-forming agent and (E) porous silica. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention is an oil-in-water cocoon that has excellent curling power and is lightly stretched and smoothly attached to the cocoon, volume-up without bundling, and excellent in makeup such as long-lasting curling power and no bleeding over time. It is related to cosmetics.

  Conventionally, as a technique that has been used to obtain an effect of curling and thickening wrinkles in a cosmetic for wrinkles, there is a method of blending a large amount of hard wax (see, for example, Patent Document 1). In addition, as a technique that can smoothly apply cosmetics to wrinkles, a method of blending phospholipid, PVP (polyvinylpyrrolidone) -copolymer and resin (for example, see Patent Document 2). In addition to the above hard wax, polymer, resin, and other oils to curl and increase the volume of the glaze cosmetics, fibers are blended to make it look long, and pigments are blended for coloring. . As a technique for stably and uniformly emulsifying and dispersing these in oil-in-water cosmetics, a technique using a higher fatty acid soap as an emulsifier is generally used (for example, Non-Patent Document 1).

Japanese Patent No. 29898929 JP-T-2004-532879 The latest cosmetic science Yakuji Nipposha (1955 edition) Volume 1, Chapter 3, 3.5 mascara "Prescription 17"

  However, oil-in-water cosmetics using a higher fatty acid soap as an emulsifier are excellent in emulsifying power for oils such as waxes, polymers and resins, dispersibility of pigments and fibers, and stability of the emulsified state. For example, when a method of blending a large amount of hard wax to curl wrinkles is used, it is difficult to obtain a product that is satisfactory in terms of usability, such as hard cosmetics and heavy spread, and smooth application is also possible. In the method of blending the phospholipid, the PVP-copolymer and the resin to obtain it, the curling force and the durability of the curling force are not sufficient. Thus, in oil-in-water cosmetics using a higher fatty acid soap as an emulsifier, a product having both high curling power and light and smooth usability has not been obtained.

Therefore, as a result of intensive studies to solve the above problems, the present inventors have found that phospholipid, specific nonionic surfactant, solid oil having a melting point of 60 to 110 ° C. is 10 to 30% by mass (hereinafter simply referred to as “ %))), A water-insoluble film-forming agent, and porous silica are combined to convert a large amount of solid oil into an oil-in-water type using a phospholipid and a specific nonionic surfactant. By using an agent and porous silica, the stability, usability, and makeup can be improved, so that the cosmetics for wrinkles can be applied to the wrinkle lightly and smoothly, and the curling power and its durability are excellent. As a result, the present invention has been completed.
That is, the present invention provides one or two or more kinds selected from component (A) phospholipid, (B) polyoxyethylene cholesterol ether, polyoxyethylene cholestanol ether, polyoxyethylene phytosterol ether, and polyoxyethylene phytostanol ether. By blending ionic surfactant, (C) 10-30% solid oil with a melting point of 60-110 ° C, (D) film-forming agent, and (E) porous silica, makeup effect, usability, makeup The present invention provides an oil-in-water type cosmetic for silkworms excellent in water.

  The present invention has a makeup effect (curl effect, volume-up effect), good usability, and makeup (long-lasting effect, no blur) of wrinkles, while exhibiting particularly high curling power. Because it is light and smooth, the bundling is prevented and a uniform film is obtained. As a result, the curling force can be maintained, resulting in both high curling power and light smooth use. It is related to cosmetics.

Hereinafter, the present invention will be described in detail.
The component (A) phospholipid used in the present invention functions as an emulsifier in the product of the present invention, and any phospholipid used in ordinary cosmetics can be used. Specifically, soybean-derived phospholipid, soybean-derived hydrogenated phospholipid, soybean-derived lysophospholipid, soybean-derived hydrogenated lysophospholipid, egg yolk-derived phospholipid, egg yolk-derived hydrogenated phospholipid, egg yolk-derived lysophospholipid, egg yolk-derived hydrogenated lysoline Lipid etc. are mentioned, and these can be used alone or in combination.
Although the compounding quantity of a component (A) is not specifically limited, Preferably it is 0.1-10.0 mass% (henceforth "%" only), More preferably, it is 0.5-5.0%. It is. If it is this range, it is excellent in emulsifying and stabilizing an oil component, and the oil-in-water type cosmetics for lightly sticking and sticking smoothly are obtained.

The component (B) used in the present invention is one or more nonionic surfactants selected from polyoxyethylene cholesterol ether, polyoxyethylene cholestanol ether, polyoxyethylene phytosterol ether, and polyoxyethylene phytostanol ether The agent functions as an emulsifier together with the phospholipid of component (A) in the product of the present invention. Further, the polyoxyethylene chain of these nonionic surfactants is preferably 5 to 60 mol from the viewpoint of stably emulsifying oil components such as wax.
Although the compounding quantity of a component (B) is not specifically limited, Preferably it is 0.1-10.0%, More preferably, it is 0.5-5.0%. If it is this range, the oil-in-water type cosmetics for an oil-in-water type | mold which are excellent in the emulsifying power of the solid oil of a component (C) lightly, and stick to a candy smoothly are obtained.

The solid oil having a melting point of 60 to 110 ° C. of the component (C) used in the present invention gives a strong curling force and its durability in the present invention, and any solid oil used in ordinary cosmetics can be used. Can also be used. Specifically, hydrocarbons such as paraffin wax, ceresin wax, microcrystalline wax, polyethylene wax, ethylene / propylene copolymer, montan wax, Fischer-Tropsch wax, waxes such as beeswax, carnauba wax, candelilla wax, gay wax, Molecules, α-olefin / vinylpyrrolidone copolymers, glyceryl tribehenate, and the like can be used, and one or more of these can be used.
The compounding quantity of a component (C) is 10.0-30.0%, More preferably, it is 10.0-25.0%. If it is this range, the oil-in-water type | mold cosmetic for cosmetics which is excellent in stronger curl power and its sustainability is obtained.

The water-insoluble film-forming agent of component (D) used in the present invention provides a strong curling power and durability in the present invention, and improves cosmetic durability such as preventing bleeding over time. Any film can be used as long as it forms a film after coating on the ridge. For example, rosin acid derivatives such as rosin pentaerythritol, polyvinyl isobutyl ether, polyisobutylene, silicone resins such as acrylic modified silicone and trimethylsiloxysilicic acid, and candelilla resin (where candelilla resin is more organic than candelilla wax) A resin component obtained by fractionation using a solvent, wherein the resin component is preferably 65% or more, more preferably 85% or more, and the softening point is 35 to 55 ° C.) ( (Meth) alkyl acrylate polymer, (meth) alkyl acrylate copolymer, (meth) acrylic acid / (meth) alkyl acrylate copolymer, (meth) alkyl acrylate / styrene copolymer, vinyl acetate-containing copolymer (Co) polymers such as polymers and vinylpyrrolidone / styrene copolymers. These film-forming agents can be blended with the oil-in-water cosmetic for cosmetics of the present invention by mixing with an oil agent, or can be blended in the form of an emulsion dispersed in an aqueous solvent. More than one species can be used. As emulsions, (meth) acrylic acid alkyl polymer emulsion, (meth) alkyl acrylate copolymer emulsion, (meth) acrylic acid / (meth) acrylic acid alkyl copolymer emulsion, (meth) acrylic acid Examples include alkyl / styrene copolymer emulsions, vinyl acetate-containing copolymer emulsions, vinylpyrrolidone / styrene copolymer emulsions, silicone-containing polymer emulsions, and silicone-containing copolymer emulsions. Among these, (meth) acrylic acid Alkyl polymers, (meth) acrylic acid alkyl copolymers, (meth) acrylic acid / (meth) alkyl acrylate copolymers, (meth) alkyl acrylate / styrene copolymers, styrene / vinyl pyrrolidone copolymers Polymer dispersed in aqueous medium Marushon is further preferred in terms of emulsion stability and cosmetics have.
As commercially available products of component (D), rosin acid derivative ester gum HP (made by Arakawa Chemical Industries), candelilla resin candelilla resin E-1 (made by Nippon Natural Products), silicone resins KP-561, KP -562, KP-545 (solid content 30%), KF7312J, KF9021 (all solid content 50%), KF7312K (solid content 60%) (above, manufactured by Shin-Etsu Chemical Co., Ltd.) and the like. Moreover, as polymer emulsion, PLEXTOL B500 (manufactured by Polymer Latex Co., Ltd.), YODOSOL GH800, GH810, GH41 (manufactured by Nippon NSC Co., Ltd.), ANTARA 430 (manufactured by ISP Co., Ltd.), Ricabond ET-F527 (manufactured by Chuo Rika Kogyo Co., Ltd.) And Vinibrand GV-5651 (manufactured by Nissin Chemical Industry Co., Ltd.).
0.5-25.0% of the compounding quantity of a component (D) is preferable, More preferably, it is 0.5-20.0%. In the case of a polymer emulsion, the solid content is used. Within this range, an oil-in-water cosmetic for cosmetics that gives a stronger curling power and its durability and is excellent in long-lasting makeup such as no bleeding over time can be obtained.

The porous silica of component (E) used in the present invention increases the volume without bundling in the present invention and prevents bleeding over time to improve the longevity of the makeup. The specific surface area of the porous silica is preferably 100 to 1000 m ² / g (BET method using N ₂ gas), and commercially available products include Sirisia 550 and 770 (manufactured by Fuji Silysia Chemical Ltd.), God Ball D11-796C, E2 -824C (above, manufactured by Suzuki Yushi Kogyo Co., Ltd.), silica microbeads P-1500, P-1505 (above, manufactured by Catalyst Kasei Kogyo Co., Ltd.) and the like.
Even if these porous silicas are used without treatment on the surface, they are treated with oil agent, silicone compound treatment, fluorine compound treatment, metal soap treatment, surfactant treatment, amino acid compound treatment, water-soluble polymer treatment, etc. It doesn't matter. One or more of these can be used.
The compounding quantity of a component (E) is 0.5-10.0%, More preferably, it is 1.0-5.0%. If it is in this range, the oil-in-water type cosmetic for cosmetics that can be increased in volume without bundling and that prevents bleeding over time and has a long makeup life can be obtained.

In addition, although the oil-in-water cosmetic for cosmetics of this invention mix | blends water as a base, when component (D) is a polymer emulsion, the water which is the solvent can be used as a base.
In addition to the above-mentioned essential components, the oil-in-water type cosmetic for cosmetics of the present invention is a component that is usually used in cosmetics, for example, an aqueous component, a water-soluble polymer, and porous silica for touch adjustment and coloring purposes. Non-powder components and fibers, oily components as emollient components, dosage form stabilization, moisturizing, powder dispersion, surfactant for adjusting touch, thickener, UV absorber, moisturizer, anti-fading agent, Antioxidants, antifoaming agents, cosmetic ingredients, preservatives, fragrances, and the like can be appropriately blended within a range that does not impair the effects of the present invention.

  The aqueous component may be any component that is soluble in water, for example, alcohols such as ethyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerin, diglycerin, Glycerols such as polyglycerol, sugars such as sorbitol, maltitol, sucrose, starch sugar, lactitol, guar gum, sodium chondroitin sulfate, gum arabic, sodium alginate, carrageenan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, carboxyvinyl polymer, high Degree of polymerization polyethylene glycol, sodium polyacrylate, sodium carboxymethyl cellulose, sodium hyaluronate, polyvinyl alcohol, polyvinyl pyrrole Water-soluble polymers emissions such as sodium chloride, magnesium chloride, salts such as sodium lactate, aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, plant extracts such as rose, and the like.

  The powder component is not particularly limited by the shape other than the component (E), such as plate shape, spindle shape, needle shape, particle size, particle structure such as porous, nonporous, etc. Examples include glitter powders, organic powders, pigment powders, and composite powders. Specifically, conch, ultramarine, bengara, yellow iron oxide, black iron oxide, titanium oxide, zinc oxide, aluminum oxide, cerium oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, Inorganic powders such as carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc, kaolin, silicon carbide, barium sulfate, bentonite, smectite, boron nitride , Bismuth oxychloride, titanium mica, iron oxide coated mica, iron oxide mica titanium, organic pigment treated mica titanium, aluminum powder and other glittering powders, magnesium stearate, zinc stearate, N-acyl lysine, nylon and other organic Powders, yes Dust powders such as tar pigments, organic pigment lake pigments, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide containing silica, zinc oxide containing silica, etc. And polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, and the like, and one or more of them can be used. These powders may be used alone or in combination of two or more, and the surface is treated with an oil agent, a silicone compound, a fluorine compound, a metal soap, a surfactant, an amino acid compound. Alternatively, a water-soluble polymer treatment or the like may be applied.

  As oily components, hydrocarbons, fats and oils, hardened oils, ester oils, fatty acids, higher alcohols, regardless of the origin of animal oils, vegetable oils, synthetic oils, etc., other than components (C) and (D) , Silicone oils, fluorine-based oils, lanolin derivatives, oily gelling agents and the like. Specifically, hydrocarbons such as liquid paraffin, squalane and petrolatum, oils and fats such as olive oil, castor oil, jojoba oil, mink oil, macadamian nut oil, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, Esters such as octyldodecyl myristate, glyceryl trioctanoate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, N-lauroyl-L-glutamate (cholesteryl, behenyl, octyldodecyl), stearic acid, lauric acid, myristic acid, behen Fatty acids such as acid, isostearic acid and oleic acid, and higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, and behenyl alcohol Low polymerization degree dimethylpolysiloxane, cross-linked organopolysiloxane, fluorine-modified polysiloxane and other silicones, fluorinated oils such as perfluorodecane and perfluorooctane, lanolin, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, dextrin Examples thereof include oily gelling agents such as fatty acid esters, sucrose fatty acid esters, 12-hydroxystearic acid, starch fatty acid esters, aluminum isostearate and calcium stearate.

  The fiber is not particularly limited as long as it is generally used in cosmetics, synthetic fibers such as nylon, polyester, and polypropylene, artificial fibers such as rayon, natural fibers such as cellulose, and semisynthetic fibers such as acetate silk. Etc. These fibers can be used singly or in combination of two or more, and are subjected to a surface treatment by a known method using a fluorine compound, silicone oil, powder, oil agent, gelling agent, surfactant or the like. There may be.

As the surfactant, any component other than the components (A) and (B) can be used as long as it is a surfactant generally used in cosmetics. A nonionic surfactant, an anionic surfactant, Examples include cationic surfactants and amphoteric surfactants.
Examples of nonionic surfactants include glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid esters and alkylene glycol adducts thereof, propylene glycol fatty acid esters and alkylene glycol adducts thereof, sorbitan fatty acid esters and alkylene glycols thereof. Adduct, fatty acid ester of sorbitol and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, lanolin Alkylene glycol adduct, polyoxyalkylene alkyl co-modified silicone, polyether-modified silicone Etc. The.
Examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, and α-sulfonated fatty acid. Salt, acylmethyl taurate, N-methyl-N-alkyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl Examples thereof include phenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkyl sulfosuccinate and the like.
Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts.
Amphoteric surfactants include amino acid type and betaine type carboxylic acid types, sulfate ester types, sulfonic acid types, and phosphate ester types. For example, N, N-dimethyl-N-alkyl-N-carboxylmethylammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N- Examples thereof include dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine and 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine.

  Examples of the thickener include water-swellable clay minerals, organically modified ones thereof, and polymer substances. Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin, etc., antioxidants such as α-tocopherol, ascorbic acid, etc., cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines, etc., antiseptics such as paraoxybenzoic acid esters, phenoxyethanol, etc. Can be mentioned.

  The method for producing the oil-in-water cosmetic for cosmetics of the present invention is not particularly limited. For example, the component (C) having a melting point of 60 to 110 ° C. dissolved at a high temperature and the component (D) film-forming agent An aqueous component containing porous silica of component (E) is added to an oily component containing phospholipid of component (A), and polyoxyethylene cholesterol ether, polyoxyethylene cholestanol ether, poly (ethylene) of component (B) It can be obtained by emulsifying in an oil-in-water type with one or two or more nonionic surfactants selected from oxyethylene phytosterol ether and polyoxyethylene phytostanol ether, and then cooling and defoaming to obtain.

  The oil-in-water cosmetic for cosmetics of the present invention can be applied to mascara, mascara base, mascara top coat and the like. Examples of the form include cream, gel, and liquid, with cream being preferred.

  Hereinafter, the present invention will be further described with reference to examples. In addition, these do not limit this invention at all.

Examples 1-4 and Comparative Examples 1-5 mascara (cream)
A mascara having the formulation shown in Table 1 was prepared by the following production method, and sensory evaluation was performed by the following method for curling power, curling durability, lack of bundling, volume-up effect, and non-bleeding over time. The results are also shown in Table 1.

* 1: Candelilla resin E-1 (manufactured by Nippon Natural Products)
* 2: Sugar wax S-10E (Daiichi Kogyo Seiyaku Co., Ltd.)
* 3: HSL-70 (manufactured by YMC)
* 4: Triethanolamine * 5: PLEXTOL B500 (solid content 50%) (manufactured by Polymer Latex)
* 6: ANTARA430 (solid content 40%) (made by ISP Van Dyck)
* 7: Primal ASE-75 (alkali thickening polymer emulsion) (solid content 40%) (manufactured by Polymer Latex)
* 8: Silysia 550 (Fuji Silysia Chemical)
* 9: Pearl fluoroalkyl phosphate diethanolamine salt 10% treated fiber 7 denier-2mm
* 10: Methyl paraoxybenzoate

(Production method)
Examples 1-4 and Comparative Examples 2-5
A. Components (1) to (10) are heated and mixed at 80 ° C. and dispersed.
B. Ingredients (11) to (15) are uniformly mixed and dispersed to 80 ° C.
C. Components (16) to (23) are uniformly mixed and dispersed to 80 ° C.
D. Add B to A and mix.
E. Add C to D and emulsify.
F. E is cooled and degassed, and components (24) to (26) are added and mixed, and then filled into a container to obtain a product.
Comparative Example 1
A. Components (1) to (10) are heated and mixed at 80 ° C. and dispersed.
B. Components (11) to (23) are uniformly mixed and dispersed to 80 ° C.
C. B is added to A and emulsified.
D. C is cooled and degassed, and components (24) to (26) are added and mixed, and then filled into a container to obtain a product.

(Evaluation methods)
Each sample of each sample was evaluated by 10 sensory test panels with respect to the following a to e based on an absolute evaluation in 7 levels, and the average value of the scores of all the panel members for each sample was determined based on a 4-level criterion. . For evaluation items b and e, the sample was applied to a candy and the panel was allowed to live a normal life, and the curling effect and the absence of bleeding were evaluated after 6 hours. In addition, light and smooth usability is strongly related to bundling. Therefore, the evaluation item was usability and lack of bundling.
(Evaluation item)
a. Curling force b. Curl persistence c. No bundle d. Volume up effect e. Absolute evaluation with no blur over time (rating): (Evaluation)
6: Very good 5: Good 4: Slightly good 3: Normal 2: Slightly bad 1: Bad 0: Very bad 4-level criterion exceeds 5 points: Very good: ◎
Over 3 points and under 5 points: Good: ○
More than 1 point and less than 3 points: Somewhat bad: △
1 point or less: Defect: ×

As is clear from the results in Table 1, the mascara of Examples 1 to 4 are compared with the mascara of Comparative Examples 1 to 5, compared with the mascara of Comparative Examples 1 to 5. It can be seen that they are all excellent in terms of blurring. In particular, since the mascara of the present invention can be applied lightly and smoothly, it is uniformly applied to the wrinkles without being bundled, and a high curling force and its curling have been maintained for a long time.
On the other hand, in Comparative Example 1 in which the phospholipid as the component (A) emulsifier was replaced with stearic acid and triethanolamine, a particularly satisfactory one was not obtained in terms of curling power, curling durability, and lack of bundling. In Comparative Example 2 in which the nonionic surfactant of component (B) is not blended, uniform emulsification cannot be performed, so that the curl force, the curl persistence, the lack of bundling, and the volume increase effect point are satisfactory. I couldn't get anything. In Comparative Example 3 in which the component (C) wax is not blended and in Comparative Example 4 in which the amount of the wax is small, the film-forming agent of the component (D) is used in terms of curling power, curling durability, and volume increase effect. In Comparative Example 5 that was not blended, in terms of curling power and its sustainability, volume increase effect, no bleeding over time, and in Comparative Example 6 in which the porous silica of component (E) was replaced with mica, We were not able to obtain anything particularly satisfactory in terms of lack of bundling and volume increase effect.

Example 5 Mascara (cream)
(Ingredient) (%)
(1) Component (C) Ozokerite wax 3
(2) Component (C) Carnauba wax 3
(3) Component (C) Beeswax 5
(4) Component (C) Candelilla wax 3
(5) Component (C) Vinylpyrrolidone / α-olefin copolymer * 11 3
(6) Sorbitan monostearate 2
(7) Black iron oxide 2
(8) Bengala 5
(9) Cetanol 1
(10) Component (A) Phospholipid * 12 1
(11) Component (B) Polyoxyethylene (30EO)
Phytosterol ether 1
(12) Glycerin 3
(13) 1,3-butylene glycol 8
(14) Alkaline agent * 4 1
(15) Preservative * 10 0.2
(16) Component (D) Alkyl acrylate copolymer emulsion (solid content: 42 to 48%) * 13 10
(17) Component (D) Polyvinyl acetate emulsion (solid content: 42 to 48%) * 14 20
(18) Thickener * 15 0.005
(19) Thickener * 16 4
(20) Cosmetic ingredients * 17 0.1
(21) Purified water Remaining amount (22) Component (E) Porous silica * 18 2
(23) Polypropylene fiber (5.6 denier, 2 mm) 2
* 11 ANTARON V-220 (manufactured by ISP Van Dyke)
* 12 Basis LS-60HR (Nisshin Oilio Co., Ltd.)
* 13 YODOSOL GH810 (NSC Japan)
* 14 Vinibrand GV-5651 (manufactured by Nissin Chemical Industry Co., Ltd.)
* 15 Aronbis S (Nippon Pure Chemicals)
* 16 SALCARE SC81 (alkali thickening polymer emulsion) (CIBA SPECIALITY CHEMICALS)
* 17 Yokuinin extract * 18 Silysia 770 (manufactured by Fuji Silysia Chemical)
(Manufacturing method)
A. Ingredients (1) to (9) are uniformly dispersed after heat dispersion and adjusted to 80 ° C., and ingredients (10) to (13) are added and mixed.
B. Components (14) to (23) are uniformly mixed and heated to 80 ° C.
C. Add B to A and emulsify.
D. C is cooled, degassed, and filled into a container to obtain a product.
The mascara of the present invention has a strong curling power and durability, and it is lightly stretched and smoothly attached to the eyelids, volume-up without bundling, and does not bleed over time and has excellent makeup. .

Example 6 Mascara base (cream)
(Ingredient) (%)
(1) Component (C) Ethylene / propylene copolymer 0.5
(2) Component (C) Carnauba wax 1
(3) Component (C) Beeswax 5
(4) Component (C) Microcrystalline wax 4
(5) Cetanol 2
(6) Sorbitan trioleate 3
(7) Nonporous silylated silica 0.5
(8) Component (A) Phospholipid * 19 3
(9) Component (B) Polyoxyethylene (30EO)
Cholestanol ether 3
(10) Polyethylene glycol monostearate 0.5
(11) Glycerin 5
(12) 1,3-butylene glycol 5
(13) Alkaline agent * 4 0.5
(14) Preservative * 10 0.2
(15) Ethyl alcohol 3
(16) Component (D) Alkyl acrylate copolymer emulsion (solid content 50%) * 5 30
(17) Thickener * 20 3
(18) Talc 1
(19) Component (E) Porous silica * 8 1
(20) Component (D) Vinylpyrrolidone / vinyl acetate copolymer liquid (solid content 50%) * 21 2
(21) Purified water Remaining amount (22) Fragrance appropriate amount * 19 Resinol S-10 (Nikko Chemicals)
* 20 ACULYN 33A (alkali thickening polymer emulsion) (Rohm)
* 21 PVP / VAE-735 (made by ISP)
(Manufacturing method)
A. Components (1) to (7) are uniformly mixed after heat dispersion and adjusted to 80 ° C., and components (8) to (12) are added and mixed.
B. Components (13) to (22) are mixed uniformly and heated to 80 ° C.
C. Add B to A and emulsify.
D. C is cooled, degassed, and filled into a container to obtain a product.
By using the mascara substrate of the present invention before using a normal mascara, it has a strong curling power and its durability while being lightly stretched and smoothly attached to the wrinkles, and without increasing the volume, There was no blur and the makeup was excellent.

Example 7 Mascara Top Coat (Cream)
(Ingredient) (%)
(1) Component (C) Beeswax 5
(2) Component (C) Candelilla wax 5
(3) Component (D) Silicone resin solution (solid content 50%) * 22 20
(4) Titanium oxide coated glass flakes * 23 5
(5) Iron oxide-coated mica titanium 0.1
(6) Mica titanium 2
(7) Component (A) Phospholipid * 19 3
(8) Component (B) Polyoxyethylene (30EO)
Cholestanol ether 3
(9) Polyoxyethylene / methylpolysiloxane copolymer * 24 0.5
(10) Glycerin 5
(11) 1,3-butylene glycol 3
(12) Component (D) Polyvinyl acetate emulsion (solid content 42-48%) * 14 10
(13) Purified water remaining amount (14) Cosmetic ingredient * 25 0.05
(15) Ethyl alcohol 5
(16) Component (E) Porous silica * 7 3
* 22 KF-9021 Shin-Etsu Chemical Co., Ltd.)
* 23 Metashine 1080-S (manufactured by Nippon Sheet Glass Co., Ltd.)
* 24 NUC silicone SS2802 (Nihon Unicar)
* 25 Hyaluronic acid FCH121-S (manufactured by Kibun Food Chemifa)
(Manufacturing method)
A. Components (1) to (6) are uniformly mixed after heat dispersion and adjusted to 80 ° C., and components (7) to (11) are added and mixed.
B. Components (12) to (16) are mixed uniformly and heated to 80 ° C.
C. Add B to A and emulsify.
D. C is cooled, degassed, and filled into a container to obtain a product.
The mascara top coat of the present invention is used on a normal mascara, so that it has a strong curling power and its durability while being lightly stretched and smoothly attached to the wrinkles, increasing its volume without bundling, and It was excellent in makeup, such as no bleeding.

Claims (2)

The following components (A) to (E);
(A) Phospholipid (B) One or two or more nonionic surfactants selected from polyoxyethylene cholesterol ether, polyoxyethylene cholestanol ether, polyoxyethylene phytosterol ether, polyoxyethylene phytostanol ether (C ) 10-30% by mass of solid oil with a melting point of 60-110 ° C.
(D) A water-insoluble film-forming agent (E) An oil-in-water vaginal cosmetic comprising a porous silica.   Component (D) is (meth) acrylic acid alkyl polymer, (meth) alkyl acrylate copolymer, (meth) acrylic acid / (meth) alkyl acrylate copolymer, (meth) alkyl acrylate / styrene copolymer 2. The oil-in-water cosmetic for cosmetics according to claim 1, wherein the cosmetic is one or more selected from a styrene / vinyl pyrrolidone copolymer.