JP2006193490A - Cosmetic for eyelash - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an extremely excellent cosmetic for eyelashes excellent in refreshing gloss, uniformity and long lash effect of coated film and persistency thereof and further, excellent in adhesion to eyelashes, but being free from adhesion and bunching thereby having good usability and free from bleeding with time. <P>SOLUTION: The cosmetic for eyelashes comprises (A) a highly viscous oil solution having ≥1 Pa×s at 25°C, (B) a volatile oil solution and (C) one or more kinds of water-soluble polymers selected from a polyethylene glycol having high degree of polymerization, sodium polyacrylate, carboxymethylcellulose sodium, sodium hyaluronate, polyvinyl alcohol, polyvinylpyrrolidone and vinylpyrrolidone-vinyl acetate copolymer. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a cosmetic for wrinkles, and relates to a cosmetic for wrinkles that is not sticky, has a fresh gloss and a long lash effect and has excellent durability, and does not bleed over time.

Conventionally, the quality required for cosmetics for eyelashes is a long rush effect that makes the eyelashes look longer, a volume increase effect that makes the eyeglasses thicker and clears the eyes, a curl-up effect that makes the eyeglasses appear larger by curling the eyelids, and colors the eyelids The main effects were the coloring effect to be given and the sustainability of each cosmetic effect. However, in recent years, in addition to the cosmetic effects of the conventional cosmetics for acupuncture listed above, a new cosmetic effect that has never existed before has been desired.睫 Cosmetics with a fresh luster that gives a moist impression.
In cosmetics, techniques that have been used to embody a feeling of gloss include a method of increasing the transparency of the appearance using a specific gelling agent and a method of blending a high viscosity oil agent (for example, patent documents). 1). In addition, in eye makeup cosmetics, there is a technique (for example, see Patent Document 2) in which fibers and a high-viscosity oil agent are combined in order to increase the makeup effect such as increasing the volume of eyebrows and eyebrows to clarify the eyes. there were.
Furthermore, in order to obtain the effect of making wrinkles look longer (long rush effect), in addition to the conventional technology of blending fibers, a technology in which the composition has stringiness (see, for example, Patent Document 3), high-polymerization polyethylene A technique using glycol (see, for example, Patent Document 4) has also been studied.

JP-A-9-235210 JP 2002-179533 A JP 2004-203881 A Japanese Patent Laid-Open No. 11-79940

  However, the combination of a specific gelling agent and a high-viscosity oil agent to make a transparent cosmetic is excellent in gloss, but different from fresh luster, is sticky and not satisfactory in terms of use. On the other hand, blending eye makeup cosmetics with fibers and high-viscosity oils has the effect of increasing the volume of eyelashes and eyebrows, but does not provide a cosmetic effect that is excellent in gloss. Furthermore, in order to obtain a long rush effect, the technology in which the composition has stringiness and the technology of blending with a high polymerization degree polyethylene glycol are insufficient in sustainability even if a long lash effect is obtained, and it is fresh and shiny. Did not have. Thus, no vaginal cosmetics having a fresh gloss without being sticky and having an excellent long lash effect have not been obtained.

Accordingly, as a result of intensive studies to solve the above-mentioned problems, the present inventors impair the fresh luster such as wetness caused by a high-viscosity oil agent by combining a high-viscosity oil agent, a volatile oil agent, and a specific water-soluble polymer. In addition to suppressing stickiness and bleeding over time, and improving the uniformity of the coating film, the freshness of the skin is further improved, and in addition to the freshness of the skin, it has an excellent long lash effect due to high adhesion and viscosity. It has been found that it has the sustainability, and has completed the present invention.
That is, the present invention relates to a component (A) high viscosity oil having a viscosity at 25 ° C. of 1 Pa · s or more, component (B) volatile oil, and component (C) high polymerization degree polyethylene glycol, sodium polyacrylate, carboxymethyl cellulose. The present invention relates to a vaginal cosmetic comprising a water-soluble polymer selected from sodium, sodium hyaluronate, polyvinyl alcohol, polyvinyl pyrrolidone, and (vinyl pyrrolidone-vinyl acetate) copolymer.

  The glazing cosmetic composition of the present invention is used because the coating film has a fresh gloss and uniformity, a long rush effect and their durability, and also has excellent adhesion to wrinkles without stickiness and bundling. It has good properties and does not bleed over time.

Hereinafter, the present invention will be described in detail.
Component (A) used in the present invention, a high viscosity oil having a viscosity at 25 ° C. of 1.0 Pa · s or more, imparts a long rush effect by improving the adhesion to fresh luster and wrinkles in the product of the present invention. Any liquid that is usually used in cosmetics and has a viscosity at 25 ° C. of 1 Pa · s or more can be used without any particular limitation. For example, hydrocarbons such as polyisobutylene, polybutene, heavy liquid isoparaffin, α-olefin oligomer, diisostearyl malate, glyceryl triisostearate, diglyceryl triisostearate, polyglyceryl decaisostearate, N-lauroyl-L- Esters such as di-glutamate (phytosteryl / octyldodecyl), lanolin derivatives such as liquid lanolin acetate, silicones such as highly polymerized dimethylpolysiloxane and methylphenylpolysiloxane, fluorine such as fluorine-modified organopolysiloxane and perfluoropolyether Examples thereof include one or more of these, and one or more of these can be used. Among these, hydrocarbons such as polyisobutylene, polybutene, heavy liquid isoparaffin, and α-olefin oligomer are preferable in terms of fresh gloss.
Although content of a component (A) is not specifically limited, Preferably it is 0.5-10 mass% (henceforth "%" only), More preferably, it is 1-5%. Within this range, satisfactory results can be obtained in terms of fresh luster and uniformity, long rush effect and its durability, usability, and no blur.

The component (B) volatile oil used in the present invention alleviates the stickiness of the component (A) used in the present invention, improves the spread and improves the usability, and is usually used in cosmetics. Anything can be used without particular limitation. For example, volatile silicones such as light isoparaffin, low polymerization degree dimethylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, etc. may be mentioned, and one or more of these may be used. it can.
Although content of a component (B) is not specifically limited, Preferably it is 1 to 15%, More preferably, it is 1 to 10%. Within this range, satisfactory results can be obtained in terms of fresh luster and uniformity, long rush effect and its durability, usability, and no blur.

The water-soluble polymer of component (C) in the present invention is selected from high-polymerization polyethylene glycol, sodium polyacrylate, sodium carboxymethylcellulose, sodium hyaluronate, polyvinyl alcohol, polyvinyl pyrrolidone, and (vinyl pyrrolidone-vinyl acetate) copolymer. Is. Furthermore, when the water-soluble polymer of component (C) is 1% dissolved in water and a metal rod with a diameter of 3 mm is inserted 1 cm and pulled up vertically, a thread of 3 cm or more (the solution adheres to the metal rod) It has a stringiness that occurs when it is not cut, and promotes a fresh luster and a long rush effect due to the component (A), suppresses stickiness, and smoothens the spread. Examples of commercially available polyethylene glycols include polyox WSR-N-60K, polyox WSR-301, polyox WSR COAGULANT, polyox WSR-303 (manufactured by Union Carbide), but molecular weight Is preferably in the range of 2 million to 7 million. Examples of commercially available sodium polyacrylate include Aronbis S (manufactured by Nippon Pure Chemicals Co., Ltd.), and examples of commercially available sodium carboxymethyl cellulose include CMC Daicel 1170, CMC Daicel 1180, CMC Daicel 1270, CMC Daicel 1280, CMC Daicel 1290, CMC Daicel 1350, CMC Daicel 1380 (manufactured by Daicel Chemical Industries, Ltd.) can be exemplified, and hyaluronic acid FCH121-S (1% aqueous solution), hyaluronic acid FCH201S (1% aqueous solution), hyaluronic acid as commercial products of sodium hyaluronate FCHSU-S (manufactured by Kibun Food Chemifa Co., Ltd.) and acetylated sodium hyaluronate (manufactured by Shiseido Fine Chemicals Division) can be exemplified. As a commercially available product of polyvinylpyrrolidone, LUVISKOL K-90 ( (Manufactured by Dish Co., Ltd.), and as commercially available products of polyvinyl alcohol, PVA-205, PVA-217, Kuraray Poval PVA124 (manufactured by Kuraray Co., Ltd.), PVA-EG25, PVA-EG40, PVA-GL05S, PVA-EG05, (Nippon Gosei Co., Ltd.) can be exemplified, and commercially available products of (vinylpyrrolidone-vinyl acetate) copolymer include PVP / VAE-735 (50% ethanol solution), PVP / VA-S630 (above, ISP Van Dyke). Can be illustrated. Among these, sodium polyacrylate is preferable in terms of a long rush effect and smoothness. These water-soluble polymers can be used alone or in combination of two or more as required.
Although content of a component (C) is not specifically limited, Preferably it is 0.001 to 5%, More preferably, it is 0.01 to 2%. Within this range, satisfactory results can be obtained in terms of fresh luster and uniformity, long rush effect and its durability, usability, and no blur.

  In addition to the above-mentioned essential components, the vaginal cosmetics of the present invention are components that are usually used in cosmetics, such as aqueous components, film-forming polymer emulsions that have the effect of improving adhesion, durability, and stability. , Water-soluble polymer, powder component for touch adjustment and coloring purposes, oil component as base, emollient component, surfactant for stabilization of dosage form, moisture retention, powder dispersion, touch adjustment, UV light Absorbers, humectants, oil-soluble resins, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, fragrances, and the like can be appropriately blended within a range that does not impair the effects of the present invention.

  The aqueous component may be any component that is soluble in water, for example, alcohols such as ethyl alcohol and isopropyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol and dipropylene glycol, glycerin, Other than glycerols such as diglycerin and polyglycerin, saccharides such as sorbitol, maltitol, sucrose, starch sugar and lactitol, component (C), guar gum, sodium chondroitin sulfate, gum arabic, sodium alginate, carrageenan, methylcellulose, hydroxy Water-soluble polymers such as ethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, salts such as sodium chloride, magnesium chloride, sodium lactate, aloe vera, witch hazel, hamamelis, Yuuri, lemon, lavender, plant extracts such as rose, and the like.

  The film-forming polymer emulsion is obtained by dispersing a water-insoluble polymer compound in an aqueous solvent and is not particularly limited as long as it is usually used in cosmetics, and any of them can be used. For example, (meth) acrylic acid alkyl polymer emulsion, (meth) alkyl acrylate copolymer emulsion, (meth) acrylic acid / (meth) alkyl acrylate copolymer emulsion, (meth) alkyl acrylate / styrene copolymer Examples thereof include a coalescence emulsion, a vinyl acetate-containing copolymer emulsion, a vinylpyrrolidone / styrene copolymer emulsion, a silicone-containing polymer emulsion, and a silicone-containing copolymer emulsion. These polymer emulsions can use 1 type (s) or 2 or more types as needed.

  As the oil-soluble resin, any oil-soluble resin can be used as long as it forms a film when it is used as a coating film. For example, rosin acid derivatives such as rosin acid pentaerythritol, polyvinyl isobutyl ether, Silicone resins such as acrylic-modified silicone and trimethylsiloxysilicic acid, and candelilla resin (here, candelilla resin is a resin fraction obtained by fractionating from candelilla wax using an organic solvent, and the resin content is preferably 65%. More preferably, it is contained at a ratio of 85% or more and has a softening point of 35 to 55 ° C.). These oil-soluble resins can be used alone or in combination of two or more as required.

  As oil components, other than components (A) and (B), origins of animal oils, vegetable oils, synthetic oils, and solid oils, semi-solid oils, liquid oils having a viscosity at 25 ° C. of less than 1 Pa · s, etc. Any shape can be used, hydrocarbons, oils and fats, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gels Examples thereof include agents. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin wax, ceresin wax, microcrystalline wax, polyethylene wax, ethylene / propylene copolymer, montan wax, Fischer-Tropsch wax, olive oil, castor oil, jojoba oil, Fats and oils such as mink oil and macadamian nut oil, beeswax, carnauba wax, candelilla wax, waxes such as gay wax, moscow, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, trioctanoic acid Glyceryl, glyceryl tribehenate, rosin acid pentaerythritol ester, neopentyl glycol dioctanoate, cholesterol fatty acid ester, N-lauroyl- -Esters such as diglutamate (cholesteryl, behenyl, octyldodecyl), stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid and other fatty acids, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, Higher alcohols such as isostearyl alcohol and behenyl alcohol, silicones such as low polymerization dimethylpolysiloxane and cross-linked organopolysiloxane, fluorine oils such as perfluorodecane and perfluorooctane, lanolin, lanolin fatty acid isopropyl, lanolin alcohol Lanolin derivatives such as dextrin fatty acid ester, sucrose fatty acid ester, 12-hydroxystearic acid, starch fatty acid ester, aluminum isostearate, Oily gelling agents such as calcium phosphate, alpha-olefin-vinyl pyrrolidone copolymer, and the like.

  The powder component is not particularly limited by the shape of a plate, spindle, needle, etc., particle size, particle structure such as porous, non-porous, etc., inorganic powders, glitter powders, organic Examples thereof include powders, pigment powders, and composite powders. Specifically, conch, ultramarine, bengara, yellow iron oxide, black iron oxide, titanium oxide, zinc oxide, aluminum oxide, cerium oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, Carbon black, anhydrous silicic acid, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc, kaolin, silicon carbide, barium sulfate, bentonite, smectite, boron nitride, etc. Inorganic powders, bismuth oxychloride, mica titanium, iron oxide coated mica, iron oxide mica titanium, organic pigment-treated mica titanium, aluminum powder and other glittering powders, magnesium stearate, zinc stearate, N-acyl lysine, Existence of nylon etc. Dye powders such as powders, organic tar pigments, lake pigments of organic dyes, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide containing silicon dioxide, zinc oxide contained Examples include composite powders such as silicon dioxide, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, and the like. Use one or more of these. Can do. These powders may be used alone or in combination of two or more, and the surface is treated with an oil agent, a silicone compound, a fluorine compound, a metal soap, a surfactant, an amino acid compound. Alternatively, a water-soluble polymer treatment or the like may be applied.

As the surfactant, any surfactant that is generally used in cosmetics can be used. Nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, and the like can be used. Can be mentioned.
Examples of the nonionic surfactant include glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol addition. Sorbitol fatty acid ester and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, lanolin alkylene Glycol adduct, polyoxyalkylene alkyl co-modified silicone, polyether-modified silicone And the like.
Examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, and α-sulfonated fatty acid. Salt, acylmethyl taurate, N-methyl-N-alkyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl Examples thereof include phenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkyl sulfosuccinate and the like.
Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts.
Examples of amphoteric surfactants include amino acid type and betaine type carboxylic acid types, sulfate ester types, sulfonic acid types, and phosphate ester types, and those that are safe for the human body can be used. For example, N, N-dimethyl-N-alkyl-N-carboxylmethylammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N- Examples include dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, and lecithin.

  Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin, etc., antioxidants such as α-tocopherol, ascorbic acid, etc., cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines, etc., antiseptics such as paraoxybenzoic acid esters, phenoxyethanol, etc. Can be mentioned.

  The method for producing the vaginal cosmetic of the present invention is not particularly limited. For example, an oily component containing a high-viscosity oil having a viscosity at 25 ° C. of 1 Pa · s or more and a volatile oil is heated and mixed at a high temperature. A water component containing a water-soluble polymer selected from polyethylene glycol, sodium polyacrylate, sodium carboxymethyl cellulose, sodium hyaluronate, polyvinyl alcohol, polyvinyl pyrrolidone and (vinyl pyrrolidone-vinyl acetate) copolymer is added to the product. Preferably, it can be obtained by emulsifying with a surfactant or the like, cooling, degassing and filling.

  The vaginal cosmetic composition of the present invention needs to contain at least a small amount of water in addition to the essential components. Examples of the dosage form include oil-containing water, water-in-oil type, and oil-in-water type. It is done. An oil-in-water type is preferable in order to obtain a long rush effect. Examples of the form include cream, gel, and liquid. Among them, cream is preferable. As a product, it can be applied to mascara, mascara substrate, mascara top coat, etc.

  Hereinafter, the present invention will be further described with reference to examples. In addition, these do not limit this invention at all.

Examples 1 to 5 and Comparative Examples 1 to 4 mascara (oil-in-water type)
A mascara having the formulation shown in Table 1 was prepared, and the following methods were applied to the coating film with fresh gloss, long lash effect, makeup effect (fresh gloss and long lash effect), non-stickiness, and bleed over time. The sensory evaluation was performed. Moreover, about the long rush effect, in addition to sensory evaluation, it evaluated using the following measuring equipment. These results are also shown in Table 1.

* 1: Candelilla resin E-1 (manufactured by Nippon Natural Products)
* 2: Pearl Ream 18 (Nippon Yushi Co., Ltd.) (viscosity 42 Pa · s)
* 3: High call K-350 (manufactured by Kaneda) (viscosity 0.2 Pa · s)
* 4: IP solvent 1620MU (made by Idemitsu Petrochemical Co., Ltd.)
* 5: Primal ASE-75 (solid content 40%) (manufactured by Polymer Latex)
* 6: ANTARA430 (solid content 40%) (made by ISP Van Dyck)
* 7: Aronbis S (Nippon Pure Chemicals)
* 8: PVP / VAE-735 (solid content 50%) (made by ISP Van Dyke)
(Production method)
Examples 1-5 and Comparative Examples 1-4
A. Ingredients (1) to (10) are uniformly dissolved by heating to 80 ° C.
B. Ingredients (11) to (20) are uniformly mixed and brought to 80 ° C.
C. B is added to A and emulsified.
D. C is cooled, degassed, and filled into a container to obtain a product.

(Evaluation methods)
Each sample was evaluated in 7 stages by absolute evaluation with respect to the following a to e by 10 sensory test panels, and judged according to a 4-stage criterion from the average value of the scores of all the panels of each sample. For the evaluation items c and e, the sample was applied to a bag and the panel was allowed to live a normal life, and the makeup effect and blurring after 6 hours were evaluated.
(Evaluation item)
a. Fresh gloss of coated film b. Long rush effect (sensory test)
c. Persistence of makeup effect d. No stickiness e. Absolute evaluation with no blur over time (rating): (Evaluation)
6: Very good 5: Good 4: Slightly good 3: Normal 2: Slightly bad 1: Bad 0: Very bad 4-level criterion exceeds 5 points: Very good: ◎
Over 3 points and under 5 points: Good: ○
More than 1 point and less than 3 points: Somewhat bad: △
1 point or less: Defect: ×
(Evaluation methods)
Each sample is uniformly and horizontally filled in a cylindrical container having a diameter of 30 mm or more and a depth of 10 mm or more. In an environment of 25 ° C., a rheometer (NRM-20002D · D, manufactured by Fudo Kogyo Co., Ltd.) was used to insert a 10 mm diameter adapter (disk shape: stainless steel) into the sample in the container 5 mm, and then pulled away at a speed of 2 cm / min. The height of the adapter when the sample attached to the adapter breaks with the sample in the container was used as an indicator of the long rush effect.
(Evaluation item)
b. Long rush effect (instrument measurement)
The height of the 4-step judgment standard adapter exceeds 7 mm: Very good: ◎
Over 6 mm and 7 mm or less: Good: ○
More than 4mm and less than 6mm: Somewhat bad: △
4 mm or less: Defect: ×

As is clear from the results in Table 1, the mascara of Examples 1 to 5 are more glossy than the coated films, long lash effect, long lasting makeup effect, no stickiness, compared to the mascara of Comparative Examples 1 to 4. It can be seen that both are excellent in terms of blurring over time. In particular, the mascara of the present invention has excellent gloss and uniformity of coating film, excellent long rush effect and their sustainability, and also has excellent adhesion to wrinkles, so there is no stickiness and bundling does not occur. Is excellent and has no bleeding over time.
On the other hand, in Comparative Example 1 which does not contain the component (A) high-viscosity oil, a particularly satisfactory product cannot be obtained in terms of fresh luster, long lash effect, and durability of the cosmetic effect. In Comparative Example 2 in which the oil agent was replaced with low-viscosity liquid paraffin, a particularly satisfactory one was not obtained in terms of fresh luster, long rush effect, long-lasting cosmetic effect, and no bleeding over time. ) In Comparative Example 3 containing no volatile oil, no satisfactory product was obtained in terms of fresh luster, long lash effect, durability of makeup effect and non-stickiness, and component (C) water-soluble polymer In Comparative Example 4 that does not contain, a coating film that is particularly satisfactory in terms of fresh gloss, long rush effect, long-lasting makeup effect, no stickiness, and no bleeding over time is obtained. It was not.

Example 6 Mascara (oil-in-water type)
(Ingredient) (%)
(1) Stearic acid 3
(2) Carnauba wax 1
(3) Beeswax 1
(4) Paraffin wax 1
(5) α-olefin / polyvinylpyrrolidone copolymer * 9 2
(6) High viscosity oil agent of component (A) * 10 2
(7) Self-emulsifying glyceryl monostearate 1
(8) Sucrose fatty acid ester 2
(9) Polyoxyethylene sorbitan monooleate (20E.O.) 1.3
(10) Sorbitan sesquioleate 0.5
(11) Volatile oil for component (B) * 11 2
(12) Bengala 5
(13) Silicic anhydride 0.1
(14) Triethanolamine 1.2
(15) 1,3-butylene glycol 8
(16) Paraoxybenzoic acid ester 0.2
(17) Alkyl acrylate copolymer emulsion (solid content 50%) * 12 10
(18) Polyvinyl acetate emulsion (solid content: 42 to 48%) * 13 0.5
(19) Water-soluble polymer of component (C) * 7 0.005
(20) Water-soluble polymer of component (C) * 14 0.01
(21) Yokuinin extract 0.03
(22) Purified water remaining amount * 9 ANTARON V-220 (manufactured by ISP Van Dyke)
* 10 Polybutene 2000H (manufactured by Idemitsu Petrochemical Co., Ltd.) (viscosity 500 Pa · s)
* 11 Isododecane (manufactured by Bayer)
* 12 PLEXTOL B500 (Polymer Latex)
* 13 Vinibrand GV-5651 (manufactured by Nissin Chemical Industry Co., Ltd.)
* 14 Polyox WSR-N-60K (manufactured by Union Carbide) (molecular weight 2 million)
(Manufacturing method)
A. Components (1) to (11) are dissolved by heating, and component (12) is added, mixed uniformly, and heated to 80 ° C.
B. Components (13) to (22) are mixed uniformly and heated to 80 ° C.
C. Add B to A and emulsify.
D. C is cooled, degassed, and filled into a container to obtain a product.
The mascara (oil-in-water type) of the present invention is excellent in fresh gloss and uniformity of coating film, long rush effect and their durability, and also has excellent adhesion to wrinkles without stickiness and bundling. Therefore, it was very excellent in usability and free from bleeding over time.

Example 6 Mascara (oil-in-water type)
(Ingredient) (%)
(1) Stearic acid 2
(2) Candelilla wax 3
(3) Beeswah 4.5
(4) Cetanol 0.1
(5) α-olefin / vinylpyrrolidone copolymer * 9 5
(6) Glycerin monostearate 0.9
(7) Sucrose fatty acid ester 1.5
(8) Polyoxyethylene sorbitan monooleate (20E.O.) 1.3
(9) Sorbitan sesquioleate 0.5
(10) Rosin acid pentaerythrit 3
(11) High viscosity oil agent of component (A) * 15 5
(12) Volatile oil for component (B) * 16 5
(13) Bengala 1.4
(14) Yellow iron oxide 2.6
(15) Talc 2
(16) Mica 3
(17) Triethanolamine 1.1
(18) 1,3-butylene glycol 7
(19) Alkyl acrylate copolymer emulsion (solid content 50%) * 12 10
(20) Polyvinyl acetate emulsion (solid content: 42 to 48%) * 13 20
(21) Water-soluble polymer of component (C) * 8 2
(22) Nylon fiber (3 denier, 1 mm) 2
(23) Silicic anhydride 2.5
(24) Fragrance 0.1
(25) Preservative 0.2
(26) Purified water remaining amount * 15 KF-96H-50,000 CS (manufactured by Shin-Etsu Chemical Co., Ltd.) (viscosity: 46 Pa · s)
* 16 KF-995 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Manufacturing method)
A. Components (1) to (12) are dissolved by heating, components (12) to (16) are added, mixed uniformly, and heated to 80 ° C.
B. Ingredients (17) to (26) are uniformly mixed and heated to 80 ° C.
C. Add B to A and emulsify.
D. C is cooled, degassed, and filled into a container to obtain a product.
The mascara (oil-in-water type) of the present invention has a fresh gloss and uniformity, a long lash effect and long-lasting effect of the coating film, and also has excellent adhesion to wrinkles without stickiness and bundling. It was very excellent in usability and free from bleeding over time.

Example 7 Mascara top coat (water-in-oil type)
(Ingredient) (%)
(1) Volatile oil agent for component (B) * 16 3
(2) Component (B) volatile oil * 4 5
(3) Trimethylsiloxysilicate solution * 17 4
(4) High viscosity oil agent of component (A) * 18 1
(5) High viscosity oil agent of component (A) * 2 4
(6) Polyoxyethylene / methylpolysiloxane copolymer * 19 2
(7) Dimethyl distearyl ammonium hectorite * 20 5
(8) Silicic anhydride 3
(9) Titanium oxide coated glass flakes * 21 2
(10) Fluorine compound-treated black iron oxide * 22 0.5
(11) Silicone compound-treated mica titanium * 23 5
(12) Polyvinyl acetate emulsion (solid content: 42 to 48%) * 13 10
(13) Water-soluble polymer of component (C) * 7 0.3
(14) Water-soluble polymer of component (C) * 24 0.05
(15) Purified water remaining amount * 17 KF-9021 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 18 Pearl Ream 46 (Nippon Yushi Co., Ltd.) (viscosity 660 Pa · s)
* 19 NUC silicone SS2802 (Nihon Unicar)
* 20 BENTONE 38V BC (Made by Elementis)
* 21 Metashine 1080-S (manufactured by Nippon Sheet Glass)
* 22 Perfluoroalkyl phosphate diethanolamine 5% treatment * 23 Methyl hydrogen polysiloxane 2% treatment * 24 Hyaluronic acid FCH121-S (manufactured by Kibun Food Chemifa)
(Manufacturing method)
A. Ingredients (1) to (11) are mixed uniformly.
B. Ingredients (12) to (15) are mixed uniformly.
C. Add B to A and emulsify at room temperature.
D. C is degassed and filled into a container to obtain a product.
The mascara top coat (water-in-oil type) of the present invention has a fresh gloss and uniformity, excellent long lash effect and long-lasting effect of the coating film, and also has excellent stickiness to adhere to mackerel with a mascara. In addition, it was excellent in usability because there was no bundling and no bleeding over time.

Example 8 Mascara substrate (oil-in-water type)
(Ingredient) (%)
(1) Candelilla resin * 1 5
(2) Inulin stearate * 25 5
(3) Beeswax 4
(4) α-olefin / vinylpyrrolidone copolymer * 26 1
(5) High viscosity oil agent of component (A) * 27 2
(6) Volatile oil for component (B) * 16 10
(7) Dimethyl distearyl ammonium hectorite * 20 1
(8) Mica titanium 5
(9) Polyoxyethylene (60) hydrogenated castor oil 1.5
(10) Purified water Residual amount (11) Polyvinyl acetate emulsion (solid content: 42 to 48%) * 13 20
(12) Water-soluble polymer of component (C) * 28 0.1
(13) Soybean phospholipid 0.5
(14) Glycerin 3
(15) Ethyl alcohol 2
(16) Surface treated nylon fiber * 29 4
* 25 Leo Pearl ISK (Chiba Flour Mills)
* 26 GANEX V-220 (manufactured by ISP)
* 27 Purified polybutene HV-100F (SB) (viscosity 43 Pa · s)
* 28 PVA-EG25 (Nippon Gosei Co., Ltd.)
* 29 Pearl fluoroalkyl phosphate diethanolamine salt 10% treated fiber 7 denier-2mm
(Manufacturing method)
A. Components (1) to (5) are uniformly heated and dissolved at 110 ° C., and then components (6) to (8) are added and mixed uniformly.
B. Components (9) to (16) are mixed uniformly and heated to 80 ° C.
C. Add A to B and emulsify.
D. C is cooled, degassed, and filled into a container to obtain a product.
The mascara substrate of the present invention has excellent fresh gloss and uniformity of coating film, long rush effect and durability thereof, and also has excellent adhesion of mascara applied on the ridge and substrate, without stickiness and bundling Therefore, it was excellent in usability and free from bleeding over time.

Claims (3)

The following components (A), (B) and (C);
(A) High viscosity oil having a viscosity at 25 ° C. of 1 Pa · s or more (B) Volatile oil (C) High polymerization degree polyethylene glycol, sodium polyacrylate, sodium carboxymethylcellulose, sodium hyaluronate, polyvinyl alcohol, polyvinylpyrrolidone A vaginal cosmetic comprising one or more water-soluble polymers selected from (vinylpyrrolidone-vinyl acetate) copolymers.   2. The vaginal cosmetic according to claim 1, which is an oil-in-water emulsified cosmetic.   3. The cosmetic for salmon according to claim 1, wherein the component (A) is one or more hydrocarbons selected from polyisobutylene, polybutene, heavy liquid isoparaffin, and α-olefin oligomer. .