JP2007077115A - Eyelash cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an eyelash cosmetic which has an eyelash volume-increasing (eyelash-thickening) effect and a gloss-imparting effect, can glossily and thickly show eyelashes in unnatural and beautiful finishes, gives makeup effects emphasizing portions around eyes, does not blot with the passage of time, and has a good makeup-lasting property. <P>SOLUTION: This eyelash cosmetic is characterized by comprising (A) 0.1 to 3 mass% of a (alkyl acrylate/alkyl acrylamide) copolymer, (B) organic powder, (C) porous silica, and (D) ethanol. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a vaginal cosmetic that is excellent in the effect of increasing the volume of wrinkles (enriching wrinkles) and the effect of imparting gloss, and does not cause bleeding over time.

  Conventionally, as a technique that has been used to obtain an effect of thickening wrinkles (volume up) in cosmetics for koji, a method of blending a specific amount of a specific sucrose fatty acid ester and a fatty acid soap (for example, see Patent Document 1) ) And a method of blending a specific amount of an acrylic acid alkylamide / alkyl acid ester copolymer (for example, see Patent Document 2). In addition, as a technique that has been used to give gloss to the cocoon, there is a method of making a cosmetic with high appearance transparency using a water-soluble carboxyvinyl polymer, a basic substance, and dextrin (see, for example, Patent Document 3). ).

Japanese Patent No. 3565548 JP 2001-31526 A Japanese Patent No. 2818831

However, conventional volume-up type vaginal cosmetics often have an unnatural finish because the coated surface is not uniform. This has been prioritized to increase the amount attached to the wrinkles, so it was realized by increasing the viscosity of the cosmetics itself or increasing the adhesion, but the elongation deteriorates, and if it is overcoated many times This was due to the unevenness of the coated surface and the loss of gloss. For example, the method of blending a specific amount of a specific sucrose fatty acid ester and a fatty acid soap, or the method of blending a specific amount of an alkyl amide / alkyl acid ester copolymer with an acrylate can be easily applied to a koji and increase the volume. On the other hand, when blended in a large amount, the gloss decreased and stickiness sometimes occurred.
In addition, in the technology in which only the luster is given to the heel, the change in the texture (shiny feeling) is difficult to appear. For example, in order to give gloss to the glaze, a method of making a formulation with high appearance transparency using a water-soluble carboxyvinyl polymer, a basic substance, and dextrin is colored because the gloss of the cosmetic is high but the cosmetic is highly transparent. Insufficient power and no satisfactory volume-up effect.

Therefore, the present inventors believe that by having both the volume-up effect and the effect of imparting gloss, the eyelids appear glossy and dark, and a cosmetic effect that emphasizes the eyes with a beautiful finish without unnaturalness is obtained, As a result of earnest research, the present invention was completed by blending 0.1 to 3% by mass of an (alkyl acrylate / alkyl acrylamide) copolymer and combining organic powder, porous silica, and ethanol. .
That is, the present invention comprises 0.1 to 3% by mass of component (A) (alkyl acrylate / alkyl acrylamide) copolymer, component (B) organic powder, component (C) porous silica, component (D) ethanol. It is related with the cosmetics for vaginals characterized by mix | blending.

  The present invention relates to a vaginal cosmetic that is excellent in the effect of increasing the volume of a wrinkle and imparting a gloss, and does not cause bleeding over time.

Hereinafter, the present invention will be described in detail.
The component (A) (alkyl acrylate / alkyl acrylamide) copolymer used in the present invention mainly comprises a copolymer of alkyl amide acrylate, acrylic acid, methacrylic acid and alkyl esters (C _{1 to} C ₈ ) thereof. Is. It improves the uniformity and gloss of the coating film in the product of the present invention, and any one can be used as long as it is used in ordinary cosmetics. For example, the INCI name (International Nomenclature Cosmetic Labeling Names) And acrylates / octylacrylamide copolymer. Examples of commercially available products include Amphomer 28-4961, Amphomer HC, Dermacryl 79, Dermacry V-42, and Resyn XP (manufactured by National Star & Chemical), and one or more of them can be used. These can be used either neutralized or neutralized. Examples of the neutralizing agent include triethanolamine, aminomethylpropanol, aminomethylpropanediol, aminoethylpropanediol, L-arginine, potassium hydroxide, sodium hydroxide and the like.
The compounding quantity of a component (A) is 0.1-3 mass% (Hereinafter, it only shows with "%".), Preferably it is 0.2-2%. If it is less than 0.1%, the effect of improving the gloss of the coating film cannot be obtained, and if it exceeds 3% and it is blended in a particularly large amount, stickiness occurs and the gloss of the coating film is impaired.

The component (B) organic powder used in the present invention improves the gloss by increasing the volume-up effect and the uniformity of the coating film in the product of the present invention, and may be used in ordinary cosmetics. Any of them can be used. The shape and particle diameter are not particularly limited, but spherical or similar ones are preferred, and those having a particle diameter of 1 to 30 μm are preferred. In addition to the gloss obtained from the component (A) by using organic powder, the cosmetics are improved in elongation, so that the uniformity of the coating film is further improved, the gloss is given, and smooth use without powderiness There is an advantage that a feeling can be obtained.
In addition, these organic powders improve gloss and are excellent in oil resistance. From the viewpoint of excellent oil resistance, polystyrene, poly (meth) acrylate alkyl, polyamide, polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polybutylene. Polyesters such as naphthalate are preferred. Commercially available products include Gantz Pearl GS-0605 (manufactured by Gantz Kasei Co., Ltd.) as polystyrene, and Matsumoto Microsphere M-305, M-306, M-503, M-600 as poly (meth) acrylate alkyl. M-311 (manufactured by Matsumoto Yushi Kogyo Co., Ltd.), as polyamide, Gantz Pearl GPA-550 (manufactured by Gantz Kasei Co., Ltd.), Rilsan Powder L, S (manufactured by Atfina Japan Co., Ltd.) SP-500 (made by Toray Industries, Inc.) etc. can be illustrated and these can be used 1 type, or 2 or more types.
Although the compounding quantity of a component (B) is not specifically limited, Preferably it is 1-30%, More preferably, it is 1-15%. If it is this range, the cosmetics for wrinkles which are more excellent in the volume-up effect, the uniformity of a coating film, and gloss are obtained.

The component (C) porous silica in the present invention provides a volume-up effect in the present invention, and prevents bleeding over time without impairing the gloss, thereby improving the longevity of the makeup.
The specific surface area of the porous silica used in the present invention is preferably 100 to 1000 m ² / g (BET method using N ₂ gas), and the particle diameter is preferably 1 to 20 μm. Commercially available products include Silicia 550, 770 (above, manufactured by Fuji Silysia Chemical), God Ball D11-796C, E2-824C (above, manufactured by Suzuki Yushi Kogyo Co., Ltd.), Silica Microbead P-1500, P- Examples thereof include 1505 (manufactured by Catalyst Kasei Kogyo Co., Ltd.), and these can be used alone or in combination of two or more. These porous silicas may be used without any treatment on the surface or may be subjected to various treatments.
Although the compounding quantity of a component (C) is not specifically limited, Preferably it is 0.5 to 10%, More preferably, it is 1 to 5%. Within this range, it is possible to obtain a vaginal cosmetic that is more excellent in volume-up effect and that prevents bleeding over time without impairing gloss and improves the longevity of the makeup.

The component (D) ethanol in the present invention is used as a solvent for the component (A) in the present invention and improves the uniformity of the coating film.
Although the compounding quantity of a component (D) is not specifically limited, (A) :( D) = 1: 1-1: 100 are preferable at a compounding quantity ratio with a component (A). If it is this range, it will be more useful as a solvent of a component (A), and the thing excellent also in the point of the uniformity of the coating film will be obtained.

In this invention, by mix | blending component (E) oil-soluble resin, the adhesiveness to a wrinkle and the gloss of a coating film can be improved further. Any oil-soluble resin can be used as long as it is an oil-soluble resin used in ordinary cosmetics, but a film-forming oil-soluble resin is preferred. For example, rosin acid derivatives such as rosin acid pentaerythritol, polyvinyl isobutyl ether, polyisobutylene, silicone resins such as acrylic modified silicone and trimethylsiloxysilicic acid, candelilla resin (here, candelilla resin is candelilla wax) The resin content is obtained by fractionation using an organic solvent, and the resin content is preferably 65% or more, more preferably 85% or more, and the softening point is 35 to 55 ° C.) , Α-olefin / vinylpyrrolidone copolymer, and the like. In addition, commercially available products include ester gum HP of rosin acid derivative (manufactured by Arakawa Chemical Industries), candelilla resin E-1 (manufactured by Nippon Natural Products) of candelilla resin, and KP-561, KP-562 as silicone resins. KP-571, KP-541 (solid content 60 mass%), KP-545 (solid content 30 mass%), KF7312J, KF7312K, KF9021 (all solid content 50 mass%) (all manufactured by Shin-Etsu Chemical Co., Ltd.), ANTARON V-220 (made by ISP) etc. can be illustrated and these can be used 1 type, or 2 or more types.
Although the compounding quantity of a component (E) is not specifically limited, Preferably it is 0.5 to 3%, More preferably, it is 0.5 to 20%. If it is this range, the adhesiveness to wrinkles will improve more, and the cosmetics for wrinkles which are excellent in gloss and do not bleed over time will be obtained.

  In addition to the essential components described above, the oil-in-water cosmetic for cosmetics of the present invention is usually used in cosmetics, for example, aqueous components, water-soluble polymers, film-forming polymer emulsions, feel adjustment and coloring. In addition to organic powders and porous silica, powder components and fibers, emollient components as oil components, formulation stabilization, moisture retention, powder dispersion, surfactants for touch adjustment, UV absorbers, moisture retention Agents, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, fragrances, and the like can be appropriately blended within a range that does not impair the effects of the present invention.

    As the aqueous component, any component other than component (D) other than water may be used as long as it is soluble in water. For example, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerin, Glycerols such as diglycerin and polyglycerin, sugars such as sorbitol, maltitol, sucrose, starch sugar, lactitol, guar gum, sodium chondroitin sulfate, gum arabic, sodium alginate, carrageenan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, carboxyvinyl polymer Water-soluble such as polyethylene glycol with high polymerization degree, sodium polyacrylate, sodium carboxymethylcellulose, sodium hyaluronate, polyvinyl alcohol, polyvinylpyrrolidone Polymer, sodium chloride, magnesium chloride, salts such as sodium lactate, aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, plant extracts such as rose, and the like.

  As the film-forming polymer emulsion, a film-forming polymer is dispersed in an aqueous medium. For example, (meth) acrylic acid alkyl polymer emulsion, (meth) alkyl acrylate copolymer emulsion, (meth) acrylic acid・ (Meth) acrylic acid alkyl copolymer emulsion, (meth) acrylic acid / styrene copolymer emulsion, vinyl acetate blended copolymer emulsion, vinylpyrrolidone / styrene copolymer emulsion, silicone blended polymer emulsion, silicone blended Examples include copolymer emulsions.

  The powder component is not particularly limited by components other than components (B) and (C), such as a plate shape, a spindle shape, a needle shape, etc., a particle diameter, a porous structure, a nonporous structure, etc. Examples thereof include powders, glitter powders, pigment powders, and composite powders. Specifically, conch, ultramarine, bengara, yellow iron oxide, black iron oxide, titanium oxide, zinc oxide, aluminum oxide, cerium oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, Inorganic powders such as carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc, kaolin, silicon carbide, barium sulfate, bentonite, smectite, boron nitride , Bismuth oxychloride, titanium mica, iron oxide coated mica, iron oxide mica titanium, organic pigment-treated mica titanium, aluminum powder and other glitter powders, organic tar pigments, organic pigment lake pigments and other pigment powders , Fine titanium oxide coated mica titanium, fine Child zinc oxide-coated mica titanium, barium-coated mica titanium sulfate, titanium oxide blending silicon dioxide, composite powder of zinc oxide blended silicon dioxide, and the like, can be used more than those one or two. In addition, these powders may be used singly or in combination of two or more, and the surface is treated with oil agent, silicone compound treatment, fluorine compound treatment, metal soap treatment, surfactant treatment, amino acid compound treatment, A water-soluble polymer treatment or the like may be applied.

  The fiber is not particularly limited as long as it is generally used in cosmetics. Synthetic fibers such as polyamide, polypropylene and polyester, artificial fibers such as rayon, natural fibers such as cellulose, and semisynthetic fibers such as acetate silk. Etc. These fibers can be used singly or in combination of two or more, and are subjected to surface treatment by a known method using a fluorine compound, silicone oil, powder, oil agent, gelling agent, emulsion polymer, surfactant or the like. It may be what you did.

  As oily components, other than components (A) and (E), regardless of the origin of animal oils, vegetable oils, synthetic oils, and properties such as solid oils, semi-solid oils, liquid oils, hydrocarbons, fats and oils, Examples thereof include waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, lanolin derivatives, and oily gelling agents. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, polybutene, hydrogenated polyisobutene, paraffin wax, ceresin wax, microcrystalline wax, polyethylene wax, ethylene / propylene copolymer, montan wax, Fischer-Tropsch wax, mole, Oils such as olive oil, castor oil, mink oil, macadamian nut oil, wax such as beeswax, carnauba wax, candelilla wax, gallow, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate Glyceryl trioctanoate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, N-lauroyl-L-glutamate di (cholesteryl Hexyl octyldodecyl), esters such as jojoba oil, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol , Higher alcohols such as behenyl alcohol, low polymerization dimethylpolysiloxane, high polymerization dimethylpolysiloxane, methylphenylpolysiloxane, partially crosslinked organopolysiloxane, silicones such as fluorine-modified polysiloxane, perfluorodecane, perfluorooctane , Fluorinated oils such as perfluoropolysiloxane, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, dextrin fatty acid ester Sucrose fatty acid esters, 12-hydroxystearic acid, starch fatty acid esters, aluminum isostearate, oily gelling agents such as calcium stearate.

As the surfactant, any surfactant that is generally used in cosmetics can be used. Nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, etc. Is mentioned.
Examples of nonionic surfactants include glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid esters and alkylene glycol adducts thereof, propylene glycol fatty acid esters and alkylene glycol adducts thereof, sorbitan fatty acid esters and alkylene glycols thereof. Adduct, fatty acid ester of sorbitol and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, lanolin Alkylene glycol adduct, polyoxyalkylene alkyl co-modified silicone, polyether-modified organo Polysiloxane, and the like.
Examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, and α-sulfonated fatty acid. Salt, acylmethyl taurate, N-methyl-N-alkyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl Examples thereof include phenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkyl sulfosuccinate and the like.
Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts.
Examples of the amphoteric surfactant include phospholipid, amino acid type and betaine type carboxylic acid types, sulfate ester types, sulfonic acid types, and phosphate ester types. For example, N, N-dimethyl-N-alkyl-N-carboxylmethylammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N- Examples thereof include dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine and 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine.

  Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin, etc., antioxidants such as α-tocopherol, ascorbic acid, etc., cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines, etc., antiseptics such as paraoxybenzoic acid esters, phenoxyethanol, etc. Can be mentioned.

  The method for producing the vaginal cosmetic of the present invention is not particularly limited. In the case of an oil-in-water type, for example, the organic powder of component (B) and the oil-soluble resin of component (E) mixed at a high temperature. An aqueous component containing the porous silica of the component (C) is added to the oily component containing the component, emulsified and then cooled, the component (A) (alkyl acrylate / alkylacrylamide) copolymer and the ethanol of the component (D) Can be obtained by uniformly mixing, defoaming and filling.

  The vaginal cosmetic of the present invention can be applied to mascara, mascara base, mascara top coat, and the like. Examples of the form include cream, gel, and liquid, with cream being preferred. Examples of the dosage form include oily, oil-in-water and water-in-oil emulsified types, and aqueous.

  Hereinafter, the present invention will be further described with reference to examples. In addition, these do not limit this invention at all.

Invention products 1 to 4 and Comparative Examples 1 to 5 mascara (oil-in-water cream)
A mascara having the formulation shown in Table 1 was prepared, and sensory evaluation was performed by the following methods for the volume-up effect, the uniformity of the coating film, the gloss of the coating film, and the lack of bleeding over time. The results are also shown in Table 1.

* 1: Candelilla resin E-1 (manufactured by Nippon Natural Products)
* 2: Sugar wax S-10E (Daiichi Kogyo Seiyaku Co., Ltd.)
* 3: Gantz Pearl GS-0605 (manufactured by Gantz Kasei)
* 4: PLEXTOL B500 (50% solid content) (manufactured by Polymer Latex)
* 5: Primal ASE-75 (solid content 40%) (manufactured by Polymer Latex)
* 6: Silicia 550 (Fuji Silysia Chemical)
* 7: Dermacryl 79 (NSC Japan)
(Production method)
Examples 1-4 and Comparative Examples 1-5
A. Components (1) to (12) are heated and mixed at 80 ° C. and dispersed.
B. Ingredients (13) to (19) are mixed uniformly and brought to 80 ° C.
C. B is added to A and emulsified.
D. Components (20) to (23) are mixed uniformly.
E. C is cooled and degassed, D is added and mixed, and then filled into a container to obtain a product.

(Evaluation methods)
Each sample was evaluated in 10 levels by absolute evaluation for each sample for the following a to d by 10 sensory test panels, and determined based on the average value of the scores of all the panel members for each sample according to a 4-step criterion. . For the evaluation item d, the sample was applied to the candy, and the panel was allowed to live a normal life, and the absence of bleeding after 6 hours was evaluated.
(Evaluation item)
a. Volume-up effect b. Uniformity of coating film c. Gloss of coating film d. Absolute evaluation with no blur over time (rating): (Evaluation)
6: Very good 5: Good 4: Slightly good 3: Normal 2: Slightly bad 1: Bad 0: Very bad 4-level criterion exceeds 5 points: Very good: ◎
Over 3 points and under 5 points: Good: ○
More than 1 point and less than 3 points: Somewhat bad: △
1 point or less: Defect: ×

As is clear from the results in Table 1, the mascara of Examples 1 to 4 which are the products of the present invention are all excellent in volume increase effect, uniformity of the coating film, gloss of the coating film, and no bleeding over time. I understand that. And by combining the effect of increasing the volume and giving luster, it is possible to obtain a makeup effect that makes the eyelids look lustrous and dark, has no unnaturalness and emphasizes the eyes with a beautiful finish, and bleeds over time. No makeup occurred and the makeup lasting was good.
On the other hand, Comparative Example 1 in which the component (A) (alkyl acrylate / alkyl acrylamide) copolymer was not blended was particularly satisfactory in terms of uniformity of the coating film, gloss of the coating film, and no bleeding over time. In Comparative Example 2 in which mica was blended in place of the organic powder of component (B), satisfactory results were not obtained in terms of volume increase effect, coating film uniformity and gloss. In Comparative Example 3 in which the component (C) porous silica was not blended, the component (D) ethanol was not blended in terms of the volume-up effect, the gloss of the coating film, and the lack of bleeding over time. In Example 4, the dispersibility of the component (A) is poor, and the (alkyl acrylate / alkyl acrylamide) copolymer of the component (A) is blended in a large amount in terms of uniformity of the coating film and no bleeding over time. Comparative example In those going particularly satisfactory in terms of lack of bleeding in gloss and time of the coating film was not obtained.

Example 5 Mascara (water-in-oil type, cream type)
(Ingredient) (%)
(1) Ozoquelite wax 3
(2) Carnauba wax 1
(3) Beeswax 3
(4) Candelilla wax 1
(5) Component (E) Oil-soluble resin * 8 10
(6) Lecithin 1
(7) Black iron oxide 5
(8) Bengala 3
(9) Component (B) Organic powder * 9 10
(10) Component (C) Porous silica * 10 3
(11) Polypropylene fiber 2
(12) Dimethyl distearyl ammonium hectorite 3
(13) Light liquid isoparaffin remaining amount (14) dextrin palmitate 1
(15) 1,3-butylene glycol 2
(16) Purified water 20
(17) Polyvinyl acetate emulsion (solid content: 42 to 48%) * 11 5
(18) Sodium polyacrylate * 12 0.001
(19) Paraoxybenzoic acid ester 0.2
(20) Yokuinin extract 0.1
(21) Component (A) (alkyl acrylate / alkyl acrylamide)
Copolymer * 13 1
(22) Component (D) Ethanol 5
(23) Triethanolamine 0.5
* 8 ANTARON V-220 (manufactured by ISP Van Dyke)
* 9 Matsumoto Microsphere M-305 (Matsumoto Yushi Seiyaku Co., Ltd.)
* 10 Silicia 770 (Fuji Silysia Chemical)
* 11 Vinibrand GV-5651 (manufactured by Nissin Chemical Industry Co., Ltd.)
* 12 Aronbis S (Nippon Pure Chemicals)
* 13 Dermacry V-42 (NSC Japan)
(Manufacturing method)
A. Components (1) to (14) are uniformly mixed, dispersed and heated to 80 ° C.
B. Ingredients (15) to (23) are mixed and dispersed uniformly and heated to 80 ° C.
C. Add B to A and emulsify.
D. C is cooled, degassed, and filled into a container to obtain a product.
The present invention was excellent in the effect of increasing the volume of wrinkles and the effect of imparting a gloss, and did not cause bleeding over time, and had good makeup lasting.

Example 6 Mascara substrate (aqueous, gelled)
(Ingredient) (%)
(1) Component (A) (alkyl acrylate / alkyl acrylamide)
Copolymer * 7 3
(2) Component (D) Ethanol 15
(3) Aminomethylpropanol 1
(4) Purified water remaining amount (5) Alkali thickening polymer emulsion * 15 3
(6) Alkyl acrylate copolymer emulsion (solid content 50%) * 4 30
(7) Sorbitan trioleate 2
(8) Polyoxyethylene (20E.O.) sorbitan monooleate 2
(9) Lecithin 0.5
(10) 1,3-butylene glycol 5
(11) Paraoxybenzoic acid ester 0.2
(12) Component (B) Organic powder * 16 2
(13) Component (C) Porous silica * 6 1
(14) Vinylpyrrolidone / vinyl acetate copolymer liquid (solid content 50%) * 17 2
(15) Perfume appropriate amount * 15 ACULYN 33A (Rohm)
* 16 Gantz Pearl GPA-550 (manufactured by Gantz Kasei)
* 17 PVP / VAE-735 (manufactured by ISP)
(Manufacturing method)
A. Components (1) to (15) are uniformly mixed and dispersed.
B. A is degassed and filled into a container to obtain a product.
The present invention is excellent in the effect of increasing the volume of the wrinkles and the effect of imparting gloss, and does not cause bleeding over time and has a good makeup.

Example 7 Mascara top coat (oil-based, gel-like)
(Ingredient) (%)
(1) Beeswax 5
(2) Component (E) Oil-soluble resin * 18 10
(3) Component (E) Oil-soluble resin * 19 10
(4) Light liquid isoparaffin remaining amount (5) Decamethylcyclopentasiloxane 5
(6) Mica titanium 2
(7) Iron oxide coated mica titanium 1
(8) Titanium oxide coated glass flakes 5
(9) Lecithin 1
(10) Component (B) Organic powder * 3 20
(11) Component (C) Porous silica * 20 3
(12) Component (A) (alkyl acrylate / alkyl acrylamide)
Copolymer * 7 2
(13) Component (D) Ethanol 10
(14) Sodium hyaluronate * 21 0.05
(15) Phenosoxyethanol appropriate amount * 18 KF-9021 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 19 Ester gum HP (Arakawa Chemical Industries)
* 20 God Ball D11-796C (manufactured by Suzuki Yushi Kogyo Co., Ltd.)
* 21 Hyaluronic acid FCH121-S (manufactured by Kibun Food Chemifa)
(Manufacturing method)
A. Components (1) to (5) are dissolved by heating, components (6) to (11) are added, and they are mixed and dispersed uniformly.
B. Ingredients (12) to (15) are mixed uniformly.
C. Add B to A and disperse.
D. C is degassed and filled into a container to obtain a product.
The present invention is excellent in the effect of increasing the volume of the wrinkles and the effect of imparting gloss, and does not cause bleeding over time and has a good makeup.

Claims (4)

The following components (A) to (D);
(A) 0.1-3 mass% of (alkyl acrylate / alkyl acrylamide) copolymer
(B) Organic powder (C) Porous silica (D) Ethanol cosmetics characterized by including ethanol.   2. The vaginal cosmetic according to claim 1, wherein the component (B) is one or more organic powders selected from polyamide, polystyrene, poly (meth) alkyl acrylate, and polyester.   Component (A) is a (alkyl acrylate / octyl acrylamide) copolymer, The vaginal cosmetic according to claim 1 or 2.   Furthermore, oil-soluble resin is mix | blended as a component (E), The cosmetics for glazing in any one of Claims 1-3 characterized by the above-mentioned.