WO2015196732A1 - Method for manufacturing biomass fuel from garbage - Google Patents

Method for manufacturing biomass fuel from garbage Download PDF

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Publication number
WO2015196732A1
WO2015196732A1 PCT/CN2014/092668 CN2014092668W WO2015196732A1 WO 2015196732 A1 WO2015196732 A1 WO 2015196732A1 CN 2014092668 W CN2014092668 W CN 2014092668W WO 2015196732 A1 WO2015196732 A1 WO 2015196732A1
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WIPO (PCT)
Prior art keywords
garbage
biomass fuel
powder
waste
reaction
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PCT/CN2014/092668
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French (fr)
Chinese (zh)
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沙嫣
沙晓林
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沙嫣
沙晓林
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Publication of WO2015196732A1 publication Critical patent/WO2015196732A1/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/08Non-mechanical pretreatment of the charge, e.g. desulfurization
    • C10B57/10Drying
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/46Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the invention belongs to the technical field of garbage disposal, and particularly relates to a method for manufacturing biomass fuel by using garbage.
  • waste treatment methods mainly include incineration treatment, sanitary landfill, and sorting and composting.
  • Incineration treatment and sanitary landfill are not only significant, but also gradually rising, while sorting and composting is gradually shrinking.
  • the state has little effect in promoting and promoting waste sorting, which makes the garbage disposal more difficult.
  • What is more prominent is that there are many defects in the centralized treatment of garbage in the prior art, which continues to cause secondary pollution to the environment, and the location of the waste incineration plant has a negative impact on social stability.
  • Existing waste disposal methods mainly have the following defects and problems:
  • Incineration of waste will produce 20%-25% of the burning residue.
  • the prior art usually treats the residue in a harmless manner and then extrudes and fills it, which still takes up a lot of land. Because the residue contains heavy metals and other harmful substances, the processing technology is high, the processing equipment is complicated, and the treatment cost is high. If some incineration plants cannot completely treat the residue in a harmless treatment or incomplete treatment, this will cause soil and groundwater. Serious pollution.
  • Incineration of waste requires high investment.
  • An incineration plant that processes 300,000 tons of waste a year needs to invest 320-350 million yuan, mainly for the purchase of large-scale land and complex equipment, especially for the harmless treatment of exhaust gases.
  • the equipment for burning residues has large investment and complicated technology, and generally needs to reach 50% of the total construction investment, which leads to high project cost, long recovery period and reduced economic benefits of project implementation.
  • some enterprises have no way to reduce the investment in these processing equipments, and they have not achieved the harmless treatment effect, which brings great hidden dangers to the surrounding environment and the health of the people.
  • Landfilling is done by stacking garbage or directly burying it in the soil. It does not harm the garbage, and there are a lot of hidden dangers such as bacteria, viruses and heavy metal pollution. The garbage leakage will be buried. Long-term pollution of groundwater resources, some areas will be built on the beach, causing damage to offshore waters and marine life. Landfill not only wastes a lot of land resources needed for landfill, but also causes environmental pollution. Because land pollution is concealed and lagging, it has accumulation and unevenness. The most important thing is that it is irreversible, such as heavy metals. Difficult to degrade leads to a process in which land pollution is basically not completely reversed, and organic pollutants also take a long time to degrade, which brings endless troubles to future generations. At present, many developed countries have banned landfill waste. The competent authorities and technical experts at all levels of the Chinese government believe that this way of dealing with garbage cannot be sustained, but it has not yet found a way to prevent environmental pollution and to replace it with an efficient and simple treatment.
  • Garbage sorting and composting is the ability to decompose organic matter in the waste by means of microbial decomposition. After composting, it becomes crop fertilizer, and the inorganic metal materials, glass and bricks are buried. Rubber and plastics are used. Recycling; but the amount of domestic waste compost is large, nitrogen and phosphorus content is low, long-term use is easy to cause soil compaction and groundwater quality deterioration, but also has the following outstanding problems: 1, odor pollution; 2, operating costs are too high; The technology is not mature; 4, poor factory management, etc., so the garbage sorting and composting technology is not yet mature.
  • the patent name is “Methods for Producing Environmentally Recycled Coal Using Garbage, Straw and Sludge”, and the Chinese invention patent of 201310672617.3, which mixes garbage, straw and sludge by weight ratio.
  • the environmentally-friendly reclaimed coal is mixed in the material machine, but the processing method uses physical methods to treat the raw materials without qualitative changes, and the coal combustion value generated by the machine is low, and the pretreatment step in the manufacturing method needs manual sorting and classification, and the production method tradition, it is difficult to promote industrialization and scale application;
  • the patent name is “New Domestic Waste Environmentally Friendly Recycled Coal Manufacturing Method and Its Products”, the Chinese invention with application number 201210076821.4, uses domestic garbage to prepare reclaimed coal, but a large amount of chemical needs to be added in the preparation.
  • the auxiliary materials cause serious secondary pollution to the environment.
  • garbage as fuel for power generation and gas production
  • the investment is large, the cost is high, the harmless treatment is not perfect, and secondary pollution is formed, and some need to be mixed. A large amount of raw coal or coal is added, which ultimately leads to losses.
  • the process involved in the whole process is carried out in a closed reactor.
  • the equipment used is highly automated. After the previous process is completed, it can automatically enter the next process according to the dynamic monitoring of parameters.
  • the production and processing cost of the invention is low, the production process is non-polluting, and the prepared biomass fuel has high combustion value and low emission.
  • the invention provides a method for manufacturing biomass fuel by using waste, and the specific steps include:
  • Step 1 Transport the garbage from the scattered points to the garbage storage area
  • Step 2 The garbage is automatically or manually transferred from the garbage storage area to the reaction kettle, and the reaction kettle is completely sealed;
  • Step 3 introducing steam into the reaction kettle, and dynamically controlling the temperature of the waste with time to form a carbonization mixture
  • Step 4 lower the temperature and pressure in the reaction vessel, and discharge the liquefied water and gas formed by the reaction;
  • Step 5 The carbonized mixture formed in the third step is poured into a screening device, and the non-combustible material in the carbonized mixture is screened by the screening device, and finally the biomass fuel is obtained.
  • the bearing surface for placing the garbage is provided with a grid plate, and the grid plate is used for leaching the liquid in the garbage, and may be squeezed by the pressing device if necessary. Liquid leaching effect;
  • the garbage storage area in the first step is a completely sealed space, and the odor removal treatment of the garbage in the completely sealed space by spraying, purifying, etc., can ensure that the entire production area has no odor.
  • the garbage in the second step is automatically or manually conveyed, and the garbage is initially screened by any one or more of vibration, magnetism or drum to remove some metals, ceramics and bricks, etc. Rubbish;
  • the garbage is transported from the garbage storage area to the reaction kettle automatically or manually according to the second step, wherein the garbage transportation specifically refers to: first placing the garbage in the reaction box, and then pulling the reaction box through the rail to the reaction kettle.
  • the garbage can be better loaded by the reaction box, so that the garbage can be processed in batches in an orderly manner.
  • the number of reaction tanks can be set to several according to the capacity of the reaction kettle, and the bottom of the reaction tank is The bottom of the reactor is provided with rolling wheels and rails which are matched with each other to facilitate the reaction box entering and leaving the reaction vessel.
  • the second step further comprises the step of removing the moisture from the garbage, specifically, the removing the moisture by the extrusion or/and drying method before the garbage enters the reaction kettle.
  • the second step further comprises pulverizing the garbage, specifically, pulverizing the garbage by mechanical or/and manual means before the garbage enters the reaction kettle.
  • the temperature of the garbage is dynamically controlled according to time, the temperature ranges from 150 ° C to 500 ° C, the pressure ranges from 15 bar to 35 bar, and the total reaction time ranges from 2 h to 7 h.
  • the segment dynamic control is as follows:
  • the temperature ranges from 150 °C to 250 °C, and the pressure ranges from 15 bar to 25 bar;
  • the temperature ranges from 200 °C to 500 °C, and the pressure ranges from 20 bar to 35 bar;
  • the temperature range is from 150 ° C to 300 ° C, and the pressure range is from 18 bar to 25 bar.
  • the pressure and temperature in the reactor change dynamically with time, so that the waste has an efficient carbonization reaction.
  • a catalyst is added to the waste while dynamically controlling the temperature and pressure in the reaction vessel, and the catalyst uses one or a combination of one of the following non-polluting substances: zinc oxide, lapis lazuli powder, mullite powder , serpentite powder, montmorillonite powder, granite powder, bentonite powder, rutile powder, 1:1 mixture of gasoline and butane, marble powder, cryolite powder, talcum powder, coal gangue powder, sodium carbonate, kaolin powder, sea Asphalt powder, iron ore powder, quartz powder, diatomaceous earth powder, bauxite powder, attapulgite powder, phosphate rock powder, graphite powder, lithium polysilicate salt, potassium salt, buckyball, clay powder.
  • non-polluting substances zinc oxide, lapis lazuli powder, mullite powder , serpentite powder, montmorillonite powder, granite powder, bentonite powder, rutile powder, 1:1 mixture of gasoline and butane, marble powder, cryolite powder, tal
  • the carbonization mixture formed in the third step is dried and then poured into a screening device, and the drying temperature is from 20 ° C to 130 ° C.
  • the temperature and pressure in the reactor are lowered as described in step four, specifically: the temperature in the reactor is lowered to 30 ° C - 150 ° C, and the pressure is lowered to standard atmospheric pressure.
  • the liquefied water formed by the reaction is discharged in step 4, specifically, the liquefied water is treated harmlessly through the filter and discharged into the reservoir or/and the sewage pipe network.
  • the gas formed by the reaction in the step 4 is discharged, specifically, the gas is treated harmlessly through the filter and discharged to the atmosphere.
  • the non-combustible substance in the carbonization mixture is screened by the screening device in the step 5, specifically, the carbonization mixture is screened by vibration, magnetic attraction or the like.
  • the carbonized mixture is pulverized before or after the carbonization mixture is subjected to the screening treatment, and the pulverized biomass fuel is formed after the pulverization treatment, if the carbonized mixture is pulverized before the screening treatment, and the screening treatment is performed.
  • the object is a powdery biomass fuel formed by pulverization; if the carbonization mixture is pulverized after the screening treatment, the object of the screening treatment is a high temperature and high pressure carbonized bulk carbonization mixture.
  • the powdered biomass fuel has a particle size of from 20 ⁇ m to 1500 ⁇ m.
  • the powdered biomass fuel is processed into a shaped fuel by a forming device according to customer requirements.
  • the shaped biomass fuel is specifically a spherical biomass fuel, a brick biomass fuel, a rod shaped biomass fuel or a honeycomb biomass fuel.
  • the humidity is 5%-30%, and the pressure is 20 MPa-100 MPa.
  • the present invention has the following beneficial effects:
  • the whole production system of the invention has no odor emission and does not cause pollution to the surrounding environment; the high temperature in the reaction kettle in the production process can effectively kill the bacteria in the garbage; the liquefied water and gas formed in the production process only need to pass Simple water treatment equipment and gas purification equipment can form water and gas that can meet the national standards and can be discharged without secondary pollution;
  • the powdery biomass fuel produced by the invention has a high combustion value, and the combustion value is 4,500-6,500 kcal according to different types of garbage;
  • the carbonized mixture is obtained by screening to obtain about 90% of the carbonized mixture.
  • the utilization rate of the powdery biomass fuel produced by the present invention is much higher than other methods of the prior art, that is, The entire production process can convert most of the waste into carbide, and only a small amount of carbon-free substances can be discharged through screening;
  • the powdery biomass fuel produced by the invention is mainly composed of a small amount of carbon dioxide after combustion, and the emission of combustion flue gas is 50%-60% lower than that of ordinary bituminous coal;
  • the powdery powdery biomass fuel produced by the invention can be used as a raw material of carbon fertilizer, thereby further broadening the use of garbage recycling;
  • the present invention economically and efficiently combines environmental protection issues with energy issues, solves social environmental protection problems at an industrialized level, and fully conforms to the national policy orientation, while the market demand is very large, according to the current amount of garbage growth, At least 1,000 garbage incineration plants with a scale of 300,000 tons need to be built.
  • the treatment plant for the preparation of biomass fuels using this technology can build at least 100 domestic plants by 2016, so the implementation of this project is a national environmental protection policy.
  • the vigorous advancement is also a practice of the Chinese dream and has important social significance.
  • Figure 1 is a production flow chart of the invention
  • FIG. 2 is a schematic structural view of a device system used in the production of the patent of the present invention.
  • garbage storage or / and garbage storage pit 1 garbage storage or / and garbage storage pit 1, reaction tank 2, reaction tank 3, gas storage tank 4, gas filter 5, steam generator 6, liquid water storage 7, storage tank or / and sewage pipe
  • the net 8 the drying device 9, the screening device 10, and the molding device 11.
  • the present embodiment provides a method for manufacturing biomass fuel using waste, as shown in FIG. 2, which is a device system required to implement the manufacturing method.
  • the manufacturing method of this embodiment the specific steps include:
  • Step 1 Collecting and storing garbage, specifically: transporting the garbage from each dispersed point to the garbage storage tank or/and the garbage storage pit 1;
  • Step 2 Put the garbage into the reaction box 2, and push the reaction box into the reaction tank 3: the garbage is automatically or manually transferred from the garbage storage tank or/and the garbage storage pit 1 to the reaction tank 2, and then the reaction tank 2 Pushing into the reaction vessel 3 through the rail, and completely sealing the reaction vessel 3;
  • Step 3 introducing steam, automatically controlling the reaction kettle to carry out the reaction: a steam generator 6 generates steam, and introduces steam into the reaction kettle 3, and dynamically controls the temperature change of the waste with time to form a carbonization mixture;
  • Step 4 lowering the temperature and pressure in the reaction vessel, and discharging the liquefied water and gas formed by the reaction, and the generated liquefied water is stored in the liquid water storage device 7 and discharged through the filter to the reservoir or/and the sewage pipe network 8;
  • the generated gas is stored in the gas storage tank 4, and the purified gas is formed by the gas filter 5;
  • Step 5 The reaction box is pulled out from the reaction vessel 3, and the carbonized mixture formed in the third step is poured into a screening device, and the non-combustible substance in the carbonization mixture is screened by the screening device, and finally the biomass fuel is obtained.
  • the bearing surface for placing the garbage is provided with a grid plate, and the grid plate is used for draining the liquid in the garbage;
  • the garbage in the second step is automatically or manually conveyed, and the garbage is initially screened by any one or more of vibration, magnetism or roller to remove part of the metal, ceramics and bricks. Block and other garbage;
  • the garbage in the second step, is transported from the garbage storage or the garbage/garbage storage pit 1 to the reaction tank 2 by an automatic transmission method, specifically, the reaction box is pushed into the reaction tank through an automatic transmission track.
  • the second step further includes removing moisture from the garbage, specifically, before the garbage enters the reaction kettle 3, the garbage is removed by extrusion or/and drying.
  • the second step further comprises pulverizing the garbage, specifically, the pulverizing treatment of the garbage by mechanical or/and manual means before the garbage enters the reaction kettle 3.
  • the temperature and pressure dynamic control of the garbage is changed according to time in the third step, and the overall reaction time is 2 hours, and the dynamic control of the time period is as follows:
  • the temperature is 150 ° C
  • the pressure is: 15 bar
  • the temperature was 150 ° C and the pressure was 18 bar.
  • a catalyst is added to the waste while dynamically controlling the temperature and pressure in the reaction vessel, and the catalyst uses a combination of one or more of the following materials: zinc oxide, lapis lazuli powder, mullite powder, Serpentine powder, montmorillonite powder, granite powder, bentonite powder, rutile powder, 1:1 mixture of gasoline and butane.
  • the carbonization mixture formed in the third step is dried by the drying device 9 and then poured into the screening device 10, and the drying temperature is 20 °C.
  • the temperature and pressure in the reaction vessel are lowered as described in the fourth step. Specifically, the temperature in the reaction vessel is lowered to 30 ° C, and the pressure is lowered to a standard atmospheric pressure.
  • the liquefied water formed by the discharge reaction in the step 4 is specifically treated by the liquefied water through the filter and discharged into the reservoir or/and the sewage pipe network.
  • the gas formed by the discharge reaction described in the fourth step specifically, the gas is harmlessly treated by the filter and discharged to the atmosphere.
  • the non-combustible substance in the carbonization mixture is screened by the screening device, specifically, the carbonization mixture is screened by vibration, magnetic attraction or the like;
  • step 5 before or after the carbonization mixture is subjected to the screening treatment, the carbonized mixture is pulverized, and after the pulverization treatment, the powdery biomass fuel is formed, and if the carbonization mixture is pulverized before the screening treatment, the screening is performed.
  • the object to be treated is a powdery biomass fuel formed by pulverization; if the carbonization mixture is pulverized after the screening treatment, the object of the screening treatment is a high temperature and high pressure carbonized bulk carbonization mixture. Since the process steps of the pulverization process can be adjusted, the processes and equipment corresponding to the pulverization are not shown in FIG. 1 and FIG. 2, and the corresponding contents in the drawings do not affect the understanding and implementation of the technical solution.
  • the powdery biomass fuel has a particle size of 1500 ⁇ m.
  • the powdered biomass fuel is processed into a biomass fuel of a set shape by a molding device 11 according to customer requirements.
  • the shaped biomass fuel is specifically a spherical biomass fuel, a brick biomass fuel, a rod-shaped biomass fuel or a honeycomb biomass fuel.
  • the humidity is 5% and the pressure is 20 MPa.
  • the temperature and pressure dynamic control of the garbage is changed according to time in the third step, and the overall reaction time is 7 hours.
  • the dynamic control of the time period is as follows:
  • the temperature is 250 ° C
  • the pressure is: 25 bar
  • the temperature is 500 ° C
  • the pressure is: 35 bar
  • the temperature was 300 ° C and the pressure was 25 bar.
  • a catalyst is added to the waste while dynamically controlling the temperature and pressure in the reaction vessel, and the catalyst uses a combination of one or more of the following materials: marble powder, cryolite powder, talcum powder, coal gangue Powder, sodium carbonate, kaolin powder, sepiolite powder, iron ore powder.
  • the carbonization mixture formed in the third step is dried and then poured into a screening device, and the drying temperature is 130 ° C.
  • the temperature and pressure in the reaction vessel are lowered as described in the fourth step. Specifically, the temperature in the reaction vessel is lowered to 150 ° C, and the pressure is lowered to a standard atmospheric pressure.
  • the powdery biomass fuel has a particle size of 20 ⁇ m.
  • the humidity is 30% and the pressure is 100 MPa.
  • the temperature control of the garbage is controlled dynamically according to the time in step 3.
  • the overall reaction time is 5 hours, and the dynamic control of the time period is as follows:
  • the temperature is 180 ° C
  • the pressure is: 20 bar
  • the temperature is 300 ° C
  • the pressure is: 30 bar
  • a catalyst is added to the waste while dynamically controlling the temperature and pressure in the reaction vessel, and the catalyst uses a combination of one or more of the following materials: quartz powder, diatomaceous earth powder, bauxite Powder, attapulgite powder, phosphate rock powder, graphite powder, lithium polysilicate salt, potassium salt, buckyball, clay powder.
  • the carbonization mixture formed in the third step is dried and then poured into a screening device, and the drying temperature is 100 ° C.
  • the temperature and pressure in the reaction vessel are lowered as described in the fourth step. Specifically, the temperature in the reaction vessel is lowered to 45 ° C, and the pressure is lowered to a standard atmospheric pressure.
  • the powdery biomass fuel has a particle size of 500 ⁇ m.
  • the humidity is 20% and the pressure is 80 MPa.

Abstract

The present invention is a method for manufacturing biomass fuel from garbage, the specific steps of said method comprising: step 1: garbage is transported from distribution points to a garbage storage area; step 2: the garbage is transported, either automatically or manually, from the garbage storage area into a reactor, and the reactor is completely sealed; step 3: steam is introduced into the reactor, and the temperature and pressure of the garbage is dynamically controlled over time, forming a carbonized mixture; step 4: the temperature and pressure inside the reactor are reduced, and the condensed water and gases formed by reaction are discharged; step 5: the carbonized mixture formed in step 3 is poured into a filtering apparatus; the filtering apparatus filters out noncombustible substances from the carbonized mixture, and lastly, biomass fuel is obtained. The production process of the present invention is non-polluting, and processing costs are low, and the resulting biomass fuel has high calorific value and low emissions.

Description

利用垃圾制造生物质燃料的方法Method for manufacturing biomass fuel by using garbage 技术领域Technical field
本发明属于垃圾处理技术领域,具体涉及一种利用垃圾制造生物质燃料的方法。The invention belongs to the technical field of garbage disposal, and particularly relates to a method for manufacturing biomass fuel by using garbage.
背景技术Background technique
据资料显示,我国城市生活垃圾年均增长率为8%~10%,2013年城市生活垃圾达2.6亿吨,农村全年生活垃圾也近亿吨,与日俱增的生活垃圾已成为困扰经济发展和环境治理的重大问题。对此,国家和地方各级政府高度重视,近年我国新出台了一系列的新政策和新规划,对垃圾处理问题作出政策性和实践性全面阐述,特别是“十二五”时期,国家对环保领域和废弃物管理制定重大规划,为我国生活垃圾处理项目提供了重要发展机遇。同时,“十八大”明确提出了“生态文明”、“美丽中国”、“节约资源”、“保护环境”等内容,这也给垃圾处理行业创造了很大的发展空间。目前涉及垃圾处理的主要文件有:According to the data, the average annual growth rate of urban domestic garbage in China is 8% to 10%. In 2013, urban domestic garbage reached 260 million tons. The annual domestic garbage in rural areas is also close to 100 million tons. The growing domestic garbage has become a trouble for economic development and the environment. Major issues of governance. In this regard, the governments at the national and local levels attach great importance to it. In recent years, China has introduced a series of new policies and new plans, and made a comprehensive policy and practical interpretation of the problem of garbage disposal, especially during the “Twelfth Five-Year Plan” period. Major plans for environmental protection and waste management have provided important development opportunities for China's domestic waste treatment projects. At the same time, the "18th National Congress" clearly put forward "ecological civilization", "beautiful China", "saving resources", "protecting the environment" and so on, which also created a lot of room for development in the garbage disposal industry. The main documents currently involved in garbage disposal are:
①2012年4月19日,国务院办公厅印发了《“十二五”全国城镇生活垃圾无害化处理设施建设规划》(国办发[2012]23号),该规划由发展改革委、住房城乡建设部、环境保护部三部委联合组织编制,阐明了“十二五”时期全国城镇生活垃圾无害化处理设施建设的目标、主要任务和保障措施,明确政府工作重点。这是我国生活垃圾处理设施建设的纲领性文件,规划建设总投资2636亿元。1 On April 19, 2012, the General Office of the State Council issued the “12th Five-Year Plan for the Construction of Harmless Treatment Facilities for Urban Domestic Garbage” (Guo Ban Fa [2012] No. 23), which was developed by the Development and Reform Commission and housing urban and rural areas. The Ministry of Construction and the Ministry of Environmental Protection have jointly organized and compiled the objectives, main tasks and safeguard measures for the construction of the harmless treatment facilities for urban domestic garbage in the “Twelfth Five-Year Plan” period, and clarified the priorities of the government. This is a programmatic document for the construction of domestic garbage treatment facilities, with a total planned investment of 263.6 billion yuan.
②2012年6月16日,国务院印发了《“十二五”节能环保产业发展规划》(国发[2012]19号),涉及到技术装备、节能产品、节能环保服务等方面的内容,特别是在重点领域里专门提到了再生资源利用,餐厨废弃物资源化利用和垃圾处理等方面的相关内容。2 On June 16, 2012, the State Council issued the “Twelfth Five-Year Plan for Energy Conservation and Environmental Protection Industry Development” (Guo Fa [2012] No. 19), covering technical equipment, energy-saving products, energy conservation and environmental protection services, etc. In the key areas, we have specifically mentioned the use of renewable resources, the utilization of kitchen waste, and waste disposal.
③2012年7月9日,国务院印发了《“十二五”国家战略性新兴产业发展规划》(国发[2012]28号),提出发展先进环保产业,推动垃圾和危险废物处理处置等内容;发展资源循环利用产业,重点发展以先进技术支撑的废旧商品回收体系,餐厨废弃物、农林废弃物、废旧纺织品和废旧塑料制品资源化利用等内容。3 On July 9, 2012, the State Council issued the “Twelfth Five-Year National Strategic Emerging Industry Development Plan” (Guo Fa [2012] No. 28), proposing to develop advanced environmental protection industries and promote the disposal and disposal of garbage and hazardous waste; Develop resources recycling industry, focus on the development of waste product recycling system supported by advanced technology, kitchen waste, agricultural and forestry waste, waste textiles and recycling of waste plastic products.
④2012年8月6日,国务院印发了《关于印发节能减排的“十二五”规划的通知》 (国发[2012]40号),提出加强城镇环境基础设施建设;实施农村清洁工程,鼓励生活垃圾分类收集和就地减量无害化处理,选择经济、适用、安全的处理处置技术,提高垃圾无害化处理水平,城镇周边和环境敏感区的农村逐步推广城乡一体化垃圾处理模式;加快城镇生活垃圾处理处置设施建设,强化垃圾渗滤液处置;加强政策落实和引导,鼓励采用合同能源管理实施节能改造,推动城镇污水、垃圾处理以及企业污染治理等环保设施社会化、专业化运营。4 On August 6, 2012, the State Council issued the Notice on Printing and Distributing the 12th Five-Year Plan for Energy Conservation and Emission Reduction. (Guo Fa [2012] No. 40), proposed to strengthen the construction of urban environmental infrastructure; implement rural clean-up projects, encourage the classification and collection of domestic wastes, and reduce the harmless treatment on the spot, and select economic, applicable and safe treatment and disposal technologies to improve The level of garbage incineration treatment, rural areas and environmentally sensitive areas in rural areas gradually promote urban and rural integrated garbage disposal mode; accelerate the construction of urban domestic garbage treatment and disposal facilities, strengthen the disposal of landfill leachate; strengthen policy implementation and guidance, encourage the use of contract energy management Implement energy-saving renovation and promote the socialization and professional operation of environmental protection facilities such as urban sewage, garbage disposal and corporate pollution control.
⑤2012年10月8日,环境保护部、国家发改委、工信部、卫生部四部委联合印发了《“十二五”危险废物污染防治规划》(环发[2012]123号),提出了开展危险废物调查,积极探索危险废物源头减量,统筹推进危险废物焚烧、填埋等集中处置设施建设,科学发展危险废物利用和服务行业,加强涉重金属危险废物无害化利用处置,推进医疗废物无害化处置,推动非工业源和历史遗留危险废物利用处置,提升运营管理和技术水平,加强危险废物监管体系建设等9大任务。5 On October 8, 2012, the Ministry of Environmental Protection, the National Development and Reform Commission, the Ministry of Industry and Information Technology, and the Ministry of Health jointly issued the “Twelfth Five-Year Plan for the Prevention and Control of Hazardous Waste Pollution” (Huanfa [2012] No. 123), which proposed the development of hazardous waste. Investigate, actively explore the source of hazardous waste reduction, comprehensively promote the construction of centralized disposal facilities such as hazardous waste incineration and landfill, scientifically develop hazardous waste utilization and service industries, strengthen the harmless utilization of heavy metal-related hazardous wastes, and promote the harmless treatment of medical wastes. Disposal, promote non-industrial sources and historical waste hazardous waste utilization and disposal, improve operational management and technical level, and strengthen the construction of hazardous waste supervision system and other nine major tasks.
根据上述这些国家文件,可以非常清晰的看到,垃圾处理已成为国家十分重视的技术领域,但同时我们也看到目前垃圾处理技术还存在很多的不足、弊端和技术空白。According to these national documents, it can be clearly seen that garbage disposal has become a technical field that the country attaches great importance to. However, we also see that there are still many shortcomings, drawbacks and technical gaps in the current garbage disposal technology.
纵观世界其他国家,垃圾处理同样存在非常严峻的问题,尤其是发展中国家与相对贫穷落后的国家,垃圾堆积如山、环境污染严重等问题日益突出,亟需采用科学、高效、环保的方法处理垃圾。Throughout the rest of the world, garbage disposal also has very serious problems, especially in developing countries and relatively poor and backward countries. The problems of garbage accumulation and serious environmental pollution are becoming more and more prominent, and it is urgent to adopt a scientific, efficient and environmentally friendly approach. Rubbish.
目前垃圾处理方法主要包括焚烧处理、卫生填埋、分拣堆肥。焚烧处理和卫生填埋不仅比重大,还呈逐渐上升之势,而分拣堆肥逐渐萎缩,另一方面,国家在宣传和推进垃圾分类处理方面的效果甚微,这都使垃圾处理难度加大。更为突出的是,现有技术中对垃圾的集中处理均存在诸多缺陷,继续给环境造成二次污染,垃圾焚烧厂的选址更给社会稳定造成负面影响。现有垃圾处理方法主要存在以下缺陷和问题:At present, waste treatment methods mainly include incineration treatment, sanitary landfill, and sorting and composting. Incineration treatment and sanitary landfill are not only significant, but also gradually rising, while sorting and composting is gradually shrinking. On the other hand, the state has little effect in promoting and promoting waste sorting, which makes the garbage disposal more difficult. . What is more prominent is that there are many defects in the centralized treatment of garbage in the prior art, which continues to cause secondary pollution to the environment, and the location of the waste incineration plant has a negative impact on social stability. Existing waste disposal methods mainly have the following defects and problems:
(一)焚烧处理(1) Incineration treatment
1、气体排放,造成二次污染1, gas emissions, causing secondary pollution
采用焚烧方式处理垃圾,通常需要添加辅助燃料,比如5-10%的煤,不仅增加了成本,同时增加了一氧化碳、二氧化硫的排放,另外燃烧中更是产生多种有害气体,对环境造成了二次污染。其中对环境影响最为突出的是二恶英,二恶英的毒性十分大,是氰化物的130倍、砒霜的900倍,有“世纪之毒”之称。同时,垃圾焚烧厂均存在整个厂区臭气熏天的问题,对周边的常规空气环境也有非常明显的影响。正是因为垃圾焚烧处理对周边环境有着非常严重的影响,近来我国广东佛山、浙江杭州等地区发生了多起群众 抗议政府建设垃圾焚烧项目的群体性事件,影响极为恶劣。The use of incineration to treat garbage usually requires the addition of auxiliary fuels, such as 5-10% coal, which not only increases the cost, but also increases the emission of carbon monoxide and sulfur dioxide. In addition, it produces a variety of harmful gases in the combustion, causing two environmental impacts. Secondary pollution. Among them, the most prominent environmental impact is dioxins. The toxicity of dioxins is very large, 130 times that of cyanide and 900 times that of arsenic. It is called “the poison of the century”. At the same time, the waste incineration plant has the problem of smelling the whole plant, and it also has a very obvious impact on the surrounding conventional air environment. It is precisely because the waste incineration treatment has a very serious impact on the surrounding environment. Recently, there have been many people in Foshan, Zhejiang, Hangzhou, etc. The group incidents that protested the government's construction of waste incineration projects were extremely bad.
2、燃烧残渣,仍需占地填埋2, burning residue, still need to occupy landfill
焚烧处理垃圾会产生20%-25%的燃烧残渣,现有技术通常是将残渣无害化处理后挤压成型并填埋,这仍要占用了大量土地。由于残渣中含有重金属和其他有害物质,处理技术要求高、处理设备复杂、处理成本高,如果有些焚烧厂不能完全地残渣进行无害化处理或处理不彻底,这将又会给土壤、地下水造成严重的污染。Incineration of waste will produce 20%-25% of the burning residue. The prior art usually treats the residue in a harmless manner and then extrudes and fills it, which still takes up a lot of land. Because the residue contains heavy metals and other harmful substances, the processing technology is high, the processing equipment is complicated, and the treatment cost is high. If some incineration plants cannot completely treat the residue in a harmless treatment or incomplete treatment, this will cause soil and groundwater. Serious pollution.
3、高额投资,经济回报甚微3. High investment, with little economic return
焚烧处理垃圾需要高额投资,一个年处理垃圾30万吨的焚烧厂需要投资3.2亿-3.5亿,主要用于购买大面积的土地、复杂的设备,尤其是用于无害化处理排放气体和燃烧残渣的设备投资大、技术复杂,一般要达到建设总投资的50%,这导致项目成本高、回收周期长、降低了项目实施的经济效益。更有个别企业为利益不择手段减少这些处理设备的投资而达不到无害化处理的效果,给周边环境和百姓健康带来极大隐患。Incineration of waste requires high investment. An incineration plant that processes 300,000 tons of waste a year needs to invest 320-350 million yuan, mainly for the purchase of large-scale land and complex equipment, especially for the harmless treatment of exhaust gases. The equipment for burning residues has large investment and complicated technology, and generally needs to reach 50% of the total construction investment, which leads to high project cost, long recovery period and reduced economic benefits of project implementation. In addition, some enterprises have no way to reduce the investment in these processing equipments, and they have not achieved the harmless treatment effect, which brings great hidden dangers to the surrounding environment and the health of the people.
(二)卫生填埋(2) Sanitary landfill
垃圾填埋其通过将垃圾集中堆放或者直接埋入土壤里,并没有对垃圾进行无害化处理,残留着大量的细菌、病毒、重金属污染等隐患一并埋入地下;其垃圾渗漏液会长久地污染地下水资源,有的地区将填埋场建在海边,给近海水和海洋生物造成危害。垃圾填埋不仅浪费大量填埋所需的土地资源,而且导致的环境污染,由于土地污染具有隐蔽性、滞后性,并具有积累性、不均匀性,最重要的是具有难可逆性,比如重金属难以降解导致对土地污染基本是不可完全逆转的过程,有机污染物也需要较长时间才能降解,这都给子孙后代带来无穷的后患。目前许多发达国家明令禁止填埋垃圾。我国政府的各级主管部门和技术专家均认为此种方式处理垃圾不能持久,但又尚未找到一个即防止环境污染、又高效简便的处理方式替换此类处理方式。Landfilling is done by stacking garbage or directly burying it in the soil. It does not harm the garbage, and there are a lot of hidden dangers such as bacteria, viruses and heavy metal pollution. The garbage leakage will be buried. Long-term pollution of groundwater resources, some areas will be built on the beach, causing damage to offshore waters and marine life. Landfill not only wastes a lot of land resources needed for landfill, but also causes environmental pollution. Because land pollution is concealed and lagging, it has accumulation and unevenness. The most important thing is that it is irreversible, such as heavy metals. Difficult to degrade leads to a process in which land pollution is basically not completely reversed, and organic pollutants also take a long time to degrade, which brings endless troubles to future generations. At present, many developed countries have banned landfill waste. The competent authorities and technical experts at all levels of the Chinese government believe that this way of dealing with garbage cannot be sustained, but it has not yet found a way to prevent environmental pollution and to replace it with an efficient and simple treatment.
(三)分拣堆肥(3) Sorting and composting
垃圾分拣堆肥是借助微生物分解的能力,将垃圾中的有机物分解,经过堆肥处理后,变成农作物肥料,并将其中的无机的金属物及玻璃、砖块等进行填埋,橡胶塑料等则回收;但生活垃圾堆肥量大,氮、磷含量低,长期使用易造成土壤板结和地下水质变坏,同时还具有下述突出的问题:1、臭气污染;2、运行费用过高;3、技术不成熟;4、工厂管理不良等,所以垃圾分拣堆肥技术目前尚不成熟。Garbage sorting and composting is the ability to decompose organic matter in the waste by means of microbial decomposition. After composting, it becomes crop fertilizer, and the inorganic metal materials, glass and bricks are buried. Rubber and plastics are used. Recycling; but the amount of domestic waste compost is large, nitrogen and phosphorus content is low, long-term use is easy to cause soil compaction and groundwater quality deterioration, but also has the following outstanding problems: 1, odor pollution; 2, operating costs are too high; The technology is not mature; 4, poor factory management, etc., so the garbage sorting and composting technology is not yet mature.
对现有技术检索发现,专利名称为《使用垃圾、秸秆和污泥制造环保再生煤的方法》,申请号为201310672617.3的中国发明专利,该专利中将垃圾、秸秆、污泥按重量比在混 料机中混合制得环保再生煤,但是加工过程采用物理方法对原材料处理并没有质的变化,其生成的煤燃烧值低,同时制造方法中的预处理环节需要人工分拣、分类,制作方法传统,难以产业化推广和规模应用;专利名称为《新型生活垃圾环保再生煤制造方法及其产品》,申请号为201210076821.4的中国发明,利用生活垃圾制备再生煤,但制备中需添加大量的化学品辅料,给环境造成严重的二次污染;另外,我国也有以垃圾为燃料发电、制煤气等的例子,但是投资大、成本高、无害化处理不完善,形成二次污染,有些需要掺入大量原煤或者煤液,最终导致得不偿失。For the prior art search, the patent name is “Methods for Producing Environmentally Recycled Coal Using Garbage, Straw and Sludge”, and the Chinese invention patent of 201310672617.3, which mixes garbage, straw and sludge by weight ratio. The environmentally-friendly reclaimed coal is mixed in the material machine, but the processing method uses physical methods to treat the raw materials without qualitative changes, and the coal combustion value generated by the machine is low, and the pretreatment step in the manufacturing method needs manual sorting and classification, and the production method Tradition, it is difficult to promote industrialization and scale application; the patent name is “New Domestic Waste Environmentally Friendly Recycled Coal Manufacturing Method and Its Products”, the Chinese invention with application number 201210076821.4, uses domestic garbage to prepare reclaimed coal, but a large amount of chemical needs to be added in the preparation. The auxiliary materials cause serious secondary pollution to the environment. In addition, there are examples of using garbage as fuel for power generation and gas production, but the investment is large, the cost is high, the harmless treatment is not perfect, and secondary pollution is formed, and some need to be mixed. A large amount of raw coal or coal is added, which ultimately leads to losses.
综上,现有技术中还没有一项真正科学、高效、无污染处理垃圾的方法,更没有能够将垃圾在低成本、无污染情况下,生成燃烧值高、无二次污染的煤的生产技术。In summary, there is no real scientific, efficient and pollution-free method for treating garbage in the prior art, and it is not able to produce coal with high combustion value and no secondary pollution under low-cost and non-polluting conditions. technology.
发明内容Summary of the invention
针对现有技术中的缺陷,本发明的目的是提供一种利用垃圾制造生物质燃料的方法,通过在反应釜中对垃圾进行随时间变化的温度压强动态控制,将垃圾转化成生物质燃料。整个方法所涉工序是在一个封闭的反应釜中进行,所用设备自动化程度高,上一工序完成后,根据参数动态监控,可自动进入下一工序。本发明的生产加工成本低、生产加工过程无污染,并且制得的生物质燃料燃烧值高、排放低。In view of the deficiencies in the prior art, it is an object of the present invention to provide a method of manufacturing biomass fuel using waste, which converts waste into biomass fuel by dynamically controlling the temperature of the waste over time in the reactor. The process involved in the whole process is carried out in a closed reactor. The equipment used is highly automated. After the previous process is completed, it can automatically enter the next process according to the dynamic monitoring of parameters. The production and processing cost of the invention is low, the production process is non-polluting, and the prepared biomass fuel has high combustion value and low emission.
本发明是通过以下技术方案实现的:The invention is achieved by the following technical solutions:
本发明提供一种利用垃圾制造生物质燃料的方法,具体步骤包括:The invention provides a method for manufacturing biomass fuel by using waste, and the specific steps include:
步骤一:将垃圾从各分散点运输至垃圾存放区;Step 1: Transport the garbage from the scattered points to the garbage storage area;
步骤二:将垃圾通过自动或人工方式从垃圾存放区输送至反应釜中,并将反应釜完全密封;Step 2: The garbage is automatically or manually transferred from the garbage storage area to the reaction kettle, and the reaction kettle is completely sealed;
步骤三:向反应釜中导入蒸汽,并对垃圾进行随时间变化的温度压强动态控制,形成碳化混合物;Step 3: introducing steam into the reaction kettle, and dynamically controlling the temperature of the waste with time to form a carbonization mixture;
步骤四:降低反应釜中的温度和压强,排出反应形成的液化水、气体;Step 4: lower the temperature and pressure in the reaction vessel, and discharge the liquefied water and gas formed by the reaction;
步骤五:将步骤三形成的碳化混合物倒入筛选装置,由筛选装置筛选出碳化混合物中不可燃烧的物质,并最终得到生物质燃料。Step 5: The carbonized mixture formed in the third step is poured into a screening device, and the non-combustible material in the carbonized mixture is screened by the screening device, and finally the biomass fuel is obtained.
优选地,步骤一中所述垃圾存放区,其用于放置垃圾的承载面设有格栅板,格栅板用于沥出垃圾中的液体,必要情况下可以通过加压装置挤压加大液体的沥净效果;Preferably, in the garbage storage area in the first step, the bearing surface for placing the garbage is provided with a grid plate, and the grid plate is used for leaching the liquid in the garbage, and may be squeezed by the pressing device if necessary. Liquid leaching effect;
优选地,步骤一中所述垃圾存放区,为完全密封空间,在该完全密封空间内通过喷淋、净化等方式对垃圾进行除异味处理,可以保证整个生产区域无臭味。 Preferably, the garbage storage area in the first step is a completely sealed space, and the odor removal treatment of the garbage in the completely sealed space by spraying, purifying, etc., can ensure that the entire production area has no odor.
优选地,步骤二中所述垃圾通过自动或人工方式输送中,通过震动、磁吸或滚筒等方式中的任一种或任多种对垃圾进行初步筛选,去除部分金属、陶瓷和砖块等垃圾;Preferably, the garbage in the second step is automatically or manually conveyed, and the garbage is initially screened by any one or more of vibration, magnetism or drum to remove some metals, ceramics and bricks, etc. Rubbish;
优选地,步骤二中所述将垃圾通过自动或人工方式从垃圾存放区输送至反应釜,其中垃圾输送具体是指:先将垃圾放置在反应箱中,然后将反应箱通过轨道牵引至反应釜内,通过反应箱对垃圾的盛放,可以更好的装载垃圾,以便能分批次有序处理垃圾,同时,反应箱的数量可以根据反应釜的容量设置为若干个,反应箱的底部与反应釜的底部设置有相互契合的滚动轮和轨道,便于反应箱进出反应釜。Preferably, the garbage is transported from the garbage storage area to the reaction kettle automatically or manually according to the second step, wherein the garbage transportation specifically refers to: first placing the garbage in the reaction box, and then pulling the reaction box through the rail to the reaction kettle. Within the container, the garbage can be better loaded by the reaction box, so that the garbage can be processed in batches in an orderly manner. At the same time, the number of reaction tanks can be set to several according to the capacity of the reaction kettle, and the bottom of the reaction tank is The bottom of the reactor is provided with rolling wheels and rails which are matched with each other to facilitate the reaction box entering and leaving the reaction vessel.
优选地,步骤二中还包括对垃圾进行去除水分处理,具体是指在垃圾进入反应釜的之前,对垃圾通过挤压或/和烘干方式进行去除水分处理。Preferably, the second step further comprises the step of removing the moisture from the garbage, specifically, the removing the moisture by the extrusion or/and drying method before the garbage enters the reaction kettle.
优选地,步骤二中还包括对垃圾进行粉碎处理,具体是指在垃圾进入反应釜之前,对垃圾通过机械或/和人工方式进行粉碎处理。Preferably, the second step further comprises pulverizing the garbage, specifically, pulverizing the garbage by mechanical or/and manual means before the garbage enters the reaction kettle.
优选地,步骤三中所述对垃圾进行随时间变化的温度压强动态控制,温度取值范围为150℃-500℃,压强取值范围为15bar-35bar,总体反应时间为2h-7h,分时间段动态控制具体如下:Preferably, in step 3, the temperature of the garbage is dynamically controlled according to time, the temperature ranges from 150 ° C to 500 ° C, the pressure ranges from 15 bar to 35 bar, and the total reaction time ranges from 2 h to 7 h. The segment dynamic control is as follows:
总体反应前1/4-1/3的时间段内,温度取值范围为150℃-250℃,压强取值范围为:15bar-25bar;In the period of 1/4-1/3 of the total reaction, the temperature ranges from 150 °C to 250 °C, and the pressure ranges from 15 bar to 25 bar;
总体反应后2/4-1/3的时间段内,温度取值范围为200℃-500℃,压强取值范围为:20bar-35bar;In the period of 2/4-1/3 after the overall reaction, the temperature ranges from 200 °C to 500 °C, and the pressure ranges from 20 bar to 35 bar;
总体反应中间1/4-1/3的时间段内,温度取值范围为150℃-300℃,压强取值范围为:18bar-25bar。In the middle of the overall reaction period of 1/4-1/3, the temperature range is from 150 ° C to 300 ° C, and the pressure range is from 18 bar to 25 bar.
上述技术方案中,反应釜内压力和温度随时间变化动态变化,使得垃圾发生高效的炭化反应。In the above technical solution, the pressure and temperature in the reactor change dynamically with time, so that the waste has an efficient carbonization reaction.
优选地,步骤三中在动态控制反应容器内温度与压强的同时向垃圾中添加催化剂,催化剂使用下述无污染的物质其中之一或多种的组合:氧化锌、天青石粉、莫来石粉、蛇纹石粉、蒙脱石粉、花岗岩粉、膨润土粉、金红石粉、汽油与丁烷1:1混合物、大理石粉、冰晶石粉、滑石粉、煤矸石粉、碳酸盐钠、高岭土粉、海泡石粉、铁矿石粉、石英粉、硅藻土粉、铝矾土粉、凹凸棒土粉、磷矿粉、石墨粉、含聚硅酸锂盐、钾盐、巴基球、粘土粉。Preferably, in step 3, a catalyst is added to the waste while dynamically controlling the temperature and pressure in the reaction vessel, and the catalyst uses one or a combination of one of the following non-polluting substances: zinc oxide, lapis lazuli powder, mullite powder , serpentite powder, montmorillonite powder, granite powder, bentonite powder, rutile powder, 1:1 mixture of gasoline and butane, marble powder, cryolite powder, talcum powder, coal gangue powder, sodium carbonate, kaolin powder, sea Asphalt powder, iron ore powder, quartz powder, diatomaceous earth powder, bauxite powder, attapulgite powder, phosphate rock powder, graphite powder, lithium polysilicate salt, potassium salt, buckyball, clay powder.
优选地,步骤三中形成的碳化混合物,对该碳化混合物进行烘干处理后再倒入筛选装置中,烘干温度为:20℃-130℃。 Preferably, the carbonization mixture formed in the third step is dried and then poured into a screening device, and the drying temperature is from 20 ° C to 130 ° C.
优选地,步骤四中所述降低反应釜中的温度和压强,具体是:将所述反应釜内的温度降至30℃-150℃,压强降至标准大气压。Preferably, the temperature and pressure in the reactor are lowered as described in step four, specifically: the temperature in the reactor is lowered to 30 ° C - 150 ° C, and the pressure is lowered to standard atmospheric pressure.
优选地,步骤四中所述排出反应形成的液化水,具体是将液化水通过过滤器无害化处理并排入蓄水池或/和污水管网。Preferably, the liquefied water formed by the reaction is discharged in step 4, specifically, the liquefied water is treated harmlessly through the filter and discharged into the reservoir or/and the sewage pipe network.
优选地,步骤四中所述排出反应形成的气体,具体是将气体通过过滤器无害化处理并排向大气。Preferably, the gas formed by the reaction in the step 4 is discharged, specifically, the gas is treated harmlessly through the filter and discharged to the atmosphere.
优选地,步骤五中所述由筛选装置筛选出碳化混合物中不可燃烧的物质,具体是通过震动、磁吸等方式对碳化混合物进行筛选。Preferably, the non-combustible substance in the carbonization mixture is screened by the screening device in the step 5, specifically, the carbonization mixture is screened by vibration, magnetic attraction or the like.
优选地,步骤五中,在将碳化混合物进行筛选处理之前或之后,对碳化混合物进行粉碎处理,粉碎处理后形成粉状生物质燃料,如是在筛选处理之前对碳化混合物进行粉碎处理,筛选处理的对象是粉碎形成的粉状生物质燃料;如是在筛选处理之后对碳化混合物进行粉碎处理,筛选处理的对象则是高温高压碳化处理的块状碳化混合物。Preferably, in step 5, the carbonized mixture is pulverized before or after the carbonization mixture is subjected to the screening treatment, and the pulverized biomass fuel is formed after the pulverization treatment, if the carbonized mixture is pulverized before the screening treatment, and the screening treatment is performed. The object is a powdery biomass fuel formed by pulverization; if the carbonization mixture is pulverized after the screening treatment, the object of the screening treatment is a high temperature and high pressure carbonized bulk carbonization mixture.
优选地,所述粉状生物质燃料,其颗粒大小为:20μm-1500μm。Preferably, the powdered biomass fuel has a particle size of from 20 μm to 1500 μm.
优选地,所述粉状生物质燃料,根据客户需求通过成型装置加工成设定形状的生物质燃料。Preferably, the powdered biomass fuel is processed into a shaped fuel by a forming device according to customer requirements.
优选地,所述设定形状的生物质燃料,具体为球形生物质燃料、砖形生物质燃料、棒形生物质燃料或蜂窝形生物质燃料。Preferably, the shaped biomass fuel is specifically a spherical biomass fuel, a brick biomass fuel, a rod shaped biomass fuel or a honeycomb biomass fuel.
优选地,所述对粉状生物质燃料成型处理时,湿度为:5%-30%,压力为:20MPa~100MPa。Preferably, in the molding process of the powdery biomass fuel, the humidity is 5%-30%, and the pressure is 20 MPa-100 MPa.
与现有技术相比,本发明具有如下的有益效果:Compared with the prior art, the present invention has the following beneficial effects:
(1)本发明工艺路线先进合理,对垃圾分类要求低,几乎所有生活垃圾均可处理;(1) The process route of the invention is advanced and reasonable, the classification of garbage is low, and almost all domestic garbage can be disposed of;
(2)本发明制备方法所用装备自动化程度高,上一工序完成后,根据参数动态监控,可自动进入下一工序,因此运行成本经济,非常符合垃圾处理的无害化、资源化、产业化发展方向;(2) The equipment used in the preparation method of the invention has high degree of automation. After the completion of the previous process, according to the dynamic monitoring of parameters, the process can be automatically entered into the next process, so the operation cost is economical, and it is in line with the harmless, resourceful and industrialized waste disposal. Direction of development;
(3)本发明整个生产系统无臭气排放,不会周围环境造成污染;生产过程中反应釜内的高温可以有效杀灭垃圾中的病菌;生产过程中形成的液化水、气体,仅需通过简单的水处理设备和气体净化设备,即可形成可符合国家标准的、可排放的水和气体,不会产生二次污染;(3) The whole production system of the invention has no odor emission and does not cause pollution to the surrounding environment; the high temperature in the reaction kettle in the production process can effectively kill the bacteria in the garbage; the liquefied water and gas formed in the production process only need to pass Simple water treatment equipment and gas purification equipment can form water and gas that can meet the national standards and can be discharged without secondary pollution;
(4)本发明生产得到的粉状生物质燃料燃烧值较高,根据不同的垃圾种类,燃烧值为4500-6500大卡; (4) The powdery biomass fuel produced by the invention has a high combustion value, and the combustion value is 4,500-6,500 kcal according to different types of garbage;
(5)本发明生产过程中,碳化混合物通过筛选得到碳化物约为所述碳化混合物的90%,本发明利用垃圾生产粉状生物质燃料的利用率远高于现有技术的其他方法,即整个生产过程可以将绝大部分的垃圾转化为碳化物,而只有较少的不含碳成分的物质可以通过筛选排出;(5) In the production process of the present invention, the carbonized mixture is obtained by screening to obtain about 90% of the carbonized mixture. The utilization rate of the powdery biomass fuel produced by the present invention is much higher than other methods of the prior art, that is, The entire production process can convert most of the waste into carbide, and only a small amount of carbon-free substances can be discharged through screening;
(6)本发明生成的粉状生物质燃料,燃烧后的排放以少量二氧化碳为主,燃烧烟气排放量比普通烟煤低50%-60%;(6) The powdery biomass fuel produced by the invention is mainly composed of a small amount of carbon dioxide after combustion, and the emission of combustion flue gas is 50%-60% lower than that of ordinary bituminous coal;
(7)本发明生成的粉状粉状生物质燃料,可以作为碳肥的原料,从而进一步拓宽了垃圾回收利用的用途;(7) The powdery powdery biomass fuel produced by the invention can be used as a raw material of carbon fertilizer, thereby further broadening the use of garbage recycling;
(8)本发明方法的建设项目所需投入资金少,回报快,因为工艺简单,设备也无需复杂装置,所以建设一座年处理垃圾30万吨垃圾制备生物质燃料的装备和配套生产工厂,约需投入5000万元人民币,回收期约二年,是同等处理量垃圾焚烧厂投资的15%左右;(8) The construction project of the method of the invention requires less capital investment and quick return. Because the process is simple and the equipment does not need complicated equipment, an equipment and supporting production plant for preparing biomass fuel with 300,000 tons of garbage per year is constructed. It is necessary to invest 50 million yuan, and the payback period is about two years, which is about 15% of the same amount of waste incineration plant investment;
(9)本发明技术方案合理,设备先进,所需厂房占地面积小,建一座年处理垃圾30万吨的工厂,仅需100亩左右的土地,而建同等处理量的垃圾焚烧厂需400-500亩;(9) The technical scheme of the invention is reasonable, the equipment is advanced, and the required workshop area is small. To build a factory that processes 300,000 tons of garbage per year, only about 100 mu of land is needed, and the garbage incineration plant with the same treatment capacity needs 400. -500 acres;
(10)本发明经济、高效地将环保问题与能源问题有机结合,在产业化高度上解决社会环保问题,完全符合国家的政策导向,同时市场需求非常巨大,根据目前的垃圾增长量来看,至少需要建设1000多家30万吨规模的垃圾焚烧厂,使用本技术建设制备生物质燃料的处理工厂,在2016年前至少可以在国内建设100家左右,所以本项目的实施是对国家环保政策的有力推进,也是对中国梦的践行,具有重要社会意义。(10) The present invention economically and efficiently combines environmental protection issues with energy issues, solves social environmental protection problems at an industrialized level, and fully conforms to the national policy orientation, while the market demand is very large, according to the current amount of garbage growth, At least 1,000 garbage incineration plants with a scale of 300,000 tons need to be built. The treatment plant for the preparation of biomass fuels using this technology can build at least 100 domestic plants by 2016, so the implementation of this project is a national environmental protection policy. The vigorous advancement is also a practice of the Chinese dream and has important social significance.
附图说明DRAWINGS
通过阅读参照以下附图对非限制性实施例所作的详细描述,本发明的其它特征、目的和优点将会变得更明显:Other features, objects, and advantages of the present invention will become apparent from the Detailed Description of Description
图1为本发明专利的生产流程图;Figure 1 is a production flow chart of the invention;
图2为本发明专利生产中所使用的设备系统结构示意图;2 is a schematic structural view of a device system used in the production of the patent of the present invention;
其中,垃圾存放库或/和垃圾存放坑1、反应箱2、反应釜3、气体存储箱4、气体过滤器5、蒸汽发生器6、液态水存放器7、蓄水池或/和污水管网8、烘干装置9、筛选装置10、成型装置11。Among them, garbage storage or / and garbage storage pit 1, reaction tank 2, reaction tank 3, gas storage tank 4, gas filter 5, steam generator 6, liquid water storage 7, storage tank or / and sewage pipe The net 8, the drying device 9, the screening device 10, and the molding device 11.
具体实施方式 detailed description
下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明,但不以任何形式限制本发明。应当指出的是,对本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进。这些都属于本发明的保护范围。The invention will now be described in detail in connection with specific embodiments. The following examples are intended to further understand the invention, but are not intended to limit the invention in any way. It should be noted that a number of variations and modifications may be made by those skilled in the art without departing from the inventive concept. These are all within the scope of protection of the present invention.
实施例1Example 1
如图1所示,本实施例提供一种利用垃圾制造生物质燃料的方法,如图2所示,是实现本制造方法所需的设备系统。As shown in FIG. 1, the present embodiment provides a method for manufacturing biomass fuel using waste, as shown in FIG. 2, which is a device system required to implement the manufacturing method.
本实施例的制造方法,具体步骤包括:The manufacturing method of this embodiment, the specific steps include:
步骤一:收集和存放垃圾,具体是将:将垃圾从各分散点运输至垃圾存放库或/和垃圾存放坑1;Step 1: Collecting and storing garbage, specifically: transporting the garbage from each dispersed point to the garbage storage tank or/and the garbage storage pit 1;
步骤二:将垃圾放入反应箱2,并将反应箱推入反应釜3:将垃圾通过自动或人工方式从垃圾存放库或/和垃圾存放坑1输送至反应箱2,然后将反应箱2通过轨道推入反应釜3,并将反应釜3完全密封;Step 2: Put the garbage into the reaction box 2, and push the reaction box into the reaction tank 3: the garbage is automatically or manually transferred from the garbage storage tank or/and the garbage storage pit 1 to the reaction tank 2, and then the reaction tank 2 Pushing into the reaction vessel 3 through the rail, and completely sealing the reaction vessel 3;
步骤三:导入蒸汽,自动控制反应釜进行反应:有蒸汽发生器6产生蒸汽,并向反应釜3中导入蒸汽,并对垃圾进行随时间变化的温度压强动态控制,形成碳化混合物;Step 3: introducing steam, automatically controlling the reaction kettle to carry out the reaction: a steam generator 6 generates steam, and introduces steam into the reaction kettle 3, and dynamically controls the temperature change of the waste with time to form a carbonization mixture;
步骤四:降低反应釜中的温度和压强,并排出反应形成的液化水、气体,生成的液化水存储于液态水存放器7,通过过滤器排放至蓄水池或/和污水管网8;生成的气体存储于气体存储箱4,通过气体过滤器5形成净化后的气体;Step 4: lowering the temperature and pressure in the reaction vessel, and discharging the liquefied water and gas formed by the reaction, and the generated liquefied water is stored in the liquid water storage device 7 and discharged through the filter to the reservoir or/and the sewage pipe network 8; The generated gas is stored in the gas storage tank 4, and the purified gas is formed by the gas filter 5;
步骤五:将反应箱从反应釜3中拉出,将步骤三形成的碳化混合物倒入筛选装置,由筛选装置筛选出碳化混合物中不可燃烧的物质,并最终得到生物质燃料。Step 5: The reaction box is pulled out from the reaction vessel 3, and the carbonized mixture formed in the third step is poured into a screening device, and the non-combustible substance in the carbonization mixture is screened by the screening device, and finally the biomass fuel is obtained.
本实施例中,步骤一中所述垃圾存放区,其用于放置垃圾的承载面设有格栅板,格栅板用于沥出垃圾中的液体;In this embodiment, in the garbage storage area in the first step, the bearing surface for placing the garbage is provided with a grid plate, and the grid plate is used for draining the liquid in the garbage;
本实施例中,步骤二中所述垃圾通过自动或人工方式输送中,通过震动、磁吸或滚筒等方式中的任一种或任多种对垃圾进行初步筛选,去除部分金属、陶瓷和砖块等垃圾;In this embodiment, the garbage in the second step is automatically or manually conveyed, and the garbage is initially screened by any one or more of vibration, magnetism or roller to remove part of the metal, ceramics and bricks. Block and other garbage;
本实施例中,步骤二中将垃圾通过自动传输方式从垃圾存放库或垃/和圾存放坑1输送至反应箱2中,具体是将反应箱通过自动传输轨道推入反应釜中。In the embodiment, in the second step, the garbage is transported from the garbage storage or the garbage/garbage storage pit 1 to the reaction tank 2 by an automatic transmission method, specifically, the reaction box is pushed into the reaction tank through an automatic transmission track.
本实施例中,步骤二中还包括对垃圾进行去除水分处理,具体是指在垃圾进入反应釜3的之前,对垃圾通过挤压或/和烘干方式进行去除水分处理。In the embodiment, the second step further includes removing moisture from the garbage, specifically, before the garbage enters the reaction kettle 3, the garbage is removed by extrusion or/and drying.
本实施例中,步骤二中还包括对垃圾进行粉碎处理,具体是指在垃圾进入反应釜3之前,对垃圾通过机械或/和人工方式进行粉碎处理。 In the embodiment, the second step further comprises pulverizing the garbage, specifically, the pulverizing treatment of the garbage by mechanical or/and manual means before the garbage enters the reaction kettle 3.
本实施例中,步骤三中所述对垃圾进行随时间变化的温度压强动态控制,总体反应时间为2小时,分时间段动态控制具体如下:In this embodiment, the temperature and pressure dynamic control of the garbage is changed according to time in the third step, and the overall reaction time is 2 hours, and the dynamic control of the time period is as follows:
总体反应前1/4的时间段内,温度为150℃,压强为:15bar;In the first quarter of the total reaction, the temperature is 150 ° C, the pressure is: 15 bar;
总体反应中间2/4的时间段内,温度为200℃,压强为:20bar;In the middle of the overall reaction period of 2/4, the temperature is 200 ° C, the pressure is: 20 bar;
总体反应后1/4的时间段内,温度为150℃,压强为:18bar。In the period of 1/4 of the total reaction, the temperature was 150 ° C and the pressure was 18 bar.
本实施例中,步骤三中在动态控制反应容器内温度与压强的同时向垃圾中添加催化剂,催化剂使用下述物质其中之一或多种的组合:氧化锌、天青石粉、莫来石粉、蛇纹石粉、蒙脱石粉、花岗岩粉、膨润土粉、金红石粉、汽油与丁烷1:1混合物。In this embodiment, in step 3, a catalyst is added to the waste while dynamically controlling the temperature and pressure in the reaction vessel, and the catalyst uses a combination of one or more of the following materials: zinc oxide, lapis lazuli powder, mullite powder, Serpentine powder, montmorillonite powder, granite powder, bentonite powder, rutile powder, 1:1 mixture of gasoline and butane.
本实施例中,步骤三中形成的碳化混合物,对该碳化混合物通过烘干装置9进行烘干处理后再倒入筛选装置10中,烘干温度为:20℃。In this embodiment, the carbonization mixture formed in the third step is dried by the drying device 9 and then poured into the screening device 10, and the drying temperature is 20 °C.
本实施例中,步骤四中所述降低反应釜中的温度和压强,具体是:将所述反应釜内的温度降至30℃,压强降至标准大气压。In this embodiment, the temperature and pressure in the reaction vessel are lowered as described in the fourth step. Specifically, the temperature in the reaction vessel is lowered to 30 ° C, and the pressure is lowered to a standard atmospheric pressure.
本实施例中,步骤四中所述排出反应形成的液化水,具体是将液化水通过过滤器无害化处理并排入蓄水池或/和污水管网。In the present embodiment, the liquefied water formed by the discharge reaction in the step 4 is specifically treated by the liquefied water through the filter and discharged into the reservoir or/and the sewage pipe network.
本实施例中,步骤四中所述排出反应形成的气体,具体是将气体通过过滤器无害化处理并排向大气。In the present embodiment, the gas formed by the discharge reaction described in the fourth step, specifically, the gas is harmlessly treated by the filter and discharged to the atmosphere.
本实施例中,步骤五中所述由筛选装置筛选出碳化混合物中不可燃烧的物质,具体是通过震动、磁吸等方式对碳化混合物进行筛选;In this embodiment, in the fifth step, the non-combustible substance in the carbonization mixture is screened by the screening device, specifically, the carbonization mixture is screened by vibration, magnetic attraction or the like;
本实施例中,步骤五中,在将碳化混合物进行筛选处理之前或之后,对碳化混合物进行粉碎处理,粉碎处理后形成粉状生物质燃料,如是在筛选处理之前对碳化混合物进行粉碎处理,筛选处理的对象是粉碎形成的粉状生物质燃料;如是在筛选处理之后对碳化混合物进行粉碎处理,筛选处理的对象则是高温高压碳化处理的块状碳化混合物。因为粉碎处理的工序环节可以调节,所以附图1和附图2中,未画出粉碎对应的工序与设备,附图中未体现相应的内容不影响本技术方案的理解与实现。In the embodiment, in step 5, before or after the carbonization mixture is subjected to the screening treatment, the carbonized mixture is pulverized, and after the pulverization treatment, the powdery biomass fuel is formed, and if the carbonization mixture is pulverized before the screening treatment, the screening is performed. The object to be treated is a powdery biomass fuel formed by pulverization; if the carbonization mixture is pulverized after the screening treatment, the object of the screening treatment is a high temperature and high pressure carbonized bulk carbonization mixture. Since the process steps of the pulverization process can be adjusted, the processes and equipment corresponding to the pulverization are not shown in FIG. 1 and FIG. 2, and the corresponding contents in the drawings do not affect the understanding and implementation of the technical solution.
本实施例中,所述粉状生物质燃料,其颗粒大小为:1500μm。In this embodiment, the powdery biomass fuel has a particle size of 1500 μm.
本实施例中,所述粉状生物质燃料,根据客户需求通过成型装置11加工成设定形状的生物质燃料。In the present embodiment, the powdered biomass fuel is processed into a biomass fuel of a set shape by a molding device 11 according to customer requirements.
本实施例中,所述设定形状的生物质燃料,具体为球形生物质燃料、砖形生物质燃料、棒形生物质燃料或蜂窝形生物质燃料。In this embodiment, the shaped biomass fuel is specifically a spherical biomass fuel, a brick biomass fuel, a rod-shaped biomass fuel or a honeycomb biomass fuel.
本实施例中,所述对粉状生物质燃料成型处理时,湿度为:5%,压强为:20MPa。 In the present embodiment, when the powdery biomass fuel is molded, the humidity is 5% and the pressure is 20 MPa.
实施例2Example 2
本实施例的总体制备方法与实施例1相同,涉及不同的参数限定如下:The overall preparation method of this embodiment is the same as that of Embodiment 1, and the different parameters are defined as follows:
本实施例中,步骤三中所述对垃圾进行随时间变化的温度压强动态控制,总体反应时间为7小时,分时间段动态控制具体如下:In this embodiment, the temperature and pressure dynamic control of the garbage is changed according to time in the third step, and the overall reaction time is 7 hours. The dynamic control of the time period is as follows:
总体反应前1/3的时间段内,温度为250℃,压强为:25bar;In the first 1/3 of the total reaction period, the temperature is 250 ° C, the pressure is: 25 bar;
总体反应中间1/3的时间段内,温度为500℃,压强为:35bar;In the middle 1/3 of the overall reaction, the temperature is 500 ° C, the pressure is: 35 bar;
总体反应后1/3的时间段内,温度为300℃,压强为:25bar。In the period of 1/3 of the overall reaction, the temperature was 300 ° C and the pressure was 25 bar.
本实施例中,步骤三中在动态控制反应容器内温度与压强的同时向垃圾中添加催化剂,催化剂使用下述物质其中之一或多种的组合:大理石粉、冰晶石粉、滑石粉、煤矸石粉、碳酸盐钠、高岭土粉、海泡石粉、铁矿石粉。In this embodiment, in step 3, a catalyst is added to the waste while dynamically controlling the temperature and pressure in the reaction vessel, and the catalyst uses a combination of one or more of the following materials: marble powder, cryolite powder, talcum powder, coal gangue Powder, sodium carbonate, kaolin powder, sepiolite powder, iron ore powder.
本实施例中,步骤三中形成的碳化混合物,对该碳化混合物进行烘干处理后再倒入筛选装置中,烘干温度为:130℃。In this embodiment, the carbonization mixture formed in the third step is dried and then poured into a screening device, and the drying temperature is 130 ° C.
本实施例中,步骤四中所述降低反应釜中的温度和压强,具体是:将所述反应釜内的温度降至150℃,压强降至标准大气压。In this embodiment, the temperature and pressure in the reaction vessel are lowered as described in the fourth step. Specifically, the temperature in the reaction vessel is lowered to 150 ° C, and the pressure is lowered to a standard atmospheric pressure.
本实施例中,所述粉状生物质燃料,其颗粒大小为:20μm。In this embodiment, the powdery biomass fuel has a particle size of 20 μm.
本实施例中,所述对粉状生物质燃料成型处理时,湿度为:30%,压强为:100MPa。In the present embodiment, when the powdery biomass fuel is molded, the humidity is 30% and the pressure is 100 MPa.
实施例3Example 3
本实施例的总体制备方法与实施例1相同,涉及不同的参数限定如下:The overall preparation method of this embodiment is the same as that of Embodiment 1, and the different parameters are defined as follows:
本实施例中,步骤三中所述对垃圾进行随时间变化的温度压强动态控制,总体反应时间为5小时,分时间段动态控制具体如下:In this embodiment, the temperature control of the garbage is controlled dynamically according to the time in step 3. The overall reaction time is 5 hours, and the dynamic control of the time period is as follows:
总体反应前1/4的时间段内,温度为180℃,压强为:20bar;In the first quarter of the total reaction, the temperature is 180 ° C, the pressure is: 20 bar;
总体反应中间2/4的时间段内,温度为300℃,压强为:30bar;In the middle of the overall reaction period of 2/4, the temperature is 300 ° C, the pressure is: 30 bar;
总体反应后1/4的时间段内,温度为200℃,压强为:23bar。In the period of 1/4 of the total reaction, the temperature was 200 ° C and the pressure was 23 bar.
本实施例中,步骤三中在动态控制反应容器内温度与压强的同时向垃圾中添加催化剂,催化剂使用下述物质其中之一或多种的组合:石英粉、硅藻土粉、铝矾土粉、凹凸棒土粉、磷矿粉、石墨粉、含聚硅酸锂盐、钾盐、巴基球、粘土粉。In this embodiment, in step 3, a catalyst is added to the waste while dynamically controlling the temperature and pressure in the reaction vessel, and the catalyst uses a combination of one or more of the following materials: quartz powder, diatomaceous earth powder, bauxite Powder, attapulgite powder, phosphate rock powder, graphite powder, lithium polysilicate salt, potassium salt, buckyball, clay powder.
本实施例中,步骤三中形成的碳化混合物,对该碳化混合物进行烘干处理后再倒入筛选装置中,烘干温度为:100℃。 In this embodiment, the carbonization mixture formed in the third step is dried and then poured into a screening device, and the drying temperature is 100 ° C.
本实施例中,步骤四中所述降低反应釜中的温度和压强,具体是:将所述反应釜内的温度降至45℃,压强降至标准大气压。In this embodiment, the temperature and pressure in the reaction vessel are lowered as described in the fourth step. Specifically, the temperature in the reaction vessel is lowered to 45 ° C, and the pressure is lowered to a standard atmospheric pressure.
本实施例中,所述粉状生物质燃料,其颗粒大小为:500μm。In this embodiment, the powdery biomass fuel has a particle size of 500 μm.
本实施例中,所述对粉状生物质燃料成型处理时,湿度为:20%,压强为:80MPa。In the present embodiment, when the powdery biomass fuel is molded, the humidity is 20% and the pressure is 80 MPa.
以上对本发明的具体实施例进行了描述。需要理解的是,本发明并不局限于上述特定实施方式,本领域技术人员可以在权利要求的范围内做出各种变形或修改,这并不影响本发明的实质内容。 The specific embodiments of the present invention have been described above. It is to be understood that the invention is not limited to the specific embodiments described above, and various modifications and changes may be made by those skilled in the art without departing from the scope of the invention.

Claims (19)

  1. 一种利用垃圾制造生物质燃料的方法,具体步骤包括:A method for manufacturing biomass fuel using waste, and the specific steps include:
    步骤一:将垃圾从各分散点运输至垃圾存放区;Step 1: Transport the garbage from the scattered points to the garbage storage area;
    步骤二:将垃圾通过自动或人工方式从垃圾存放区输送至反应釜中,并将反应釜完全密封;Step 2: The garbage is automatically or manually transferred from the garbage storage area to the reaction kettle, and the reaction kettle is completely sealed;
    步骤三:向反应釜中导入蒸汽,并对垃圾进行随时间变化的温度压强动态控制,形成碳化混合物;Step 3: introducing steam into the reaction kettle, and dynamically controlling the temperature of the waste with time to form a carbonization mixture;
    步骤四:降低反应釜中的温度和压强,排出反应形成的液化水、气体;Step 4: lower the temperature and pressure in the reaction vessel, and discharge the liquefied water and gas formed by the reaction;
    步骤五:将步骤三形成的碳化混合物倒入筛选装置,由筛选装置筛选出碳化混合物中不可燃烧的物质,并最终得到生物质燃料。Step 5: The carbonized mixture formed in the third step is poured into a screening device, and the non-combustible material in the carbonized mixture is screened by the screening device, and finally the biomass fuel is obtained.
  2. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤一中所述垃圾存放区,其用于放置垃圾的承载面设有格栅板,格栅板用于沥出垃圾中的液体。The method for manufacturing biomass fuel by using the garbage according to claim 1, wherein in the garbage storage area in the first step, the bearing surface for placing the garbage is provided with a grid plate, and the grid plate is used for leaching Liquid in the trash.
  3. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤一中所述垃圾存放区,为完全密封空间,在该完全密封空间内通过喷淋或/和净化方式对垃圾进行除异味处理。The method for manufacturing biomass fuel by using the garbage according to claim 1, wherein the garbage storage area in the first step is a completely sealed space, and the garbage is sprayed or/and purified in the completely sealed space. Perform odor removal treatment.
  4. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤二中所述垃圾通过自动或人工方式输送中,通过震动、磁吸和滚筒中的任一种或任多种的方式对垃圾进行初步筛选,去除部分金属、陶瓷、塑料和砖块垃圾。The method for manufacturing biomass fuel by using the garbage according to claim 1, wherein the garbage in the second step is conveyed by automatic or manual means, by any one or more of vibration, magnetism and drum The way to initially screen the waste to remove some metal, ceramic, plastic and brick waste.
  5. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤二中所述将垃圾通过自动或人工方式从垃圾存放区输送至反应釜,其中垃圾输送具体是指:先将垃圾放置在反应箱中,然后将反应箱通过轨道推入反应釜。The method for manufacturing biomass fuel by using the garbage according to claim 1, wherein the garbage is automatically or manually transported from the garbage storage area to the reaction kettle in the second step, wherein the garbage transportation specifically refers to: The waste is placed in the reaction tank, and then the reaction tank is pushed into the reaction vessel through the rail.
  6. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤二中还包括对垃圾进行去除水分处理,具体是指在垃圾进入反应釜之前,对垃圾通过挤压或/和烘干方式进行去除水分处理。The method for manufacturing biomass fuel by using waste according to claim 1, wherein the step 2 further comprises: removing moisture from the garbage, specifically, pressing the garbage or/or the garbage before the garbage enters the reaction kettle. The drying method is performed to remove the moisture treatment.
  7. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤二中还包括对垃圾进行粉碎处理,具体是指在垃圾进入反应釜之前,对垃圾通过机械或/和人工方式进行粉碎处理。The method for manufacturing biomass fuel by using waste according to claim 1, wherein the step 2 further comprises pulverizing the garbage, specifically, the mechanical or/and manual means of the garbage before the garbage enters the reaction kettle. The pulverization treatment is carried out.
  8. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤三中所述对垃圾进行随时间变化的温度压强动态控制,温度取值范围为150℃-500℃,压强 取值范围为15bar-35bar,总体反应时间为2h-7h,分时间段动态控制具体如下:The method for manufacturing biomass fuel by using waste according to claim 1, wherein in step 3, the temperature of the garbage is dynamically controlled according to time, and the temperature ranges from 150 ° C to 500 ° C, and the pressure is The range of values is 15bar-35bar, and the overall reaction time is 2h-7h. The dynamic control of the time period is as follows:
    总体反应前1/4-1/3的时间段内,温度取值范围为150℃-250℃,压强取值范围为:15bar-25bar;In the period of 1/4-1/3 of the total reaction, the temperature ranges from 150 °C to 250 °C, and the pressure ranges from 15 bar to 25 bar;
    总体反应后2/4-1/3的时间段内,温度取值范围为200℃-500℃,压强取值范围为:20bar-35bar;In the period of 2/4-1/3 after the overall reaction, the temperature ranges from 200 °C to 500 °C, and the pressure ranges from 20 bar to 35 bar;
    总体反应中间1/4-1/3的时间段内,温度取值范围为150℃-300℃,压强取值范围为:18bar-25bar。In the middle of the overall reaction period of 1/4-1/3, the temperature range is from 150 ° C to 300 ° C, and the pressure range is from 18 bar to 25 bar.
  9. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤三中在动态控制反应容器内温度与压强的同时向垃圾中添加催化剂,催化剂使用下述物质其中之一或多种的组合:氧化锌、天青石粉、莫来石粉、蛇纹石粉、蒙脱石粉、花岗岩粉、膨润土粉、金红石粉、汽油与丁烷1:1混合物、大理石粉、冰晶石粉、滑石粉、煤矸石粉、碳酸盐钠、高岭土粉、海泡石粉、铁矿石粉、石英粉、硅藻土粉、铝矾土粉、凹凸棒土粉、磷矿粉、石墨粉、含聚硅酸锂盐、钾盐、巴基球、粘土粉。The method for manufacturing biomass fuel by using waste according to claim 1, wherein in step 3, a catalyst is added to the waste while dynamically controlling the temperature and pressure in the reaction vessel, and the catalyst uses one or more of the following substances; Combination of: zinc oxide, lapis lazuli powder, mullite powder, serpentine powder, montmorillonite powder, granite powder, bentonite powder, rutile powder, 1:1 mixture of gasoline and butane, marble powder, cryolite powder, talcum powder , coal gangue powder, sodium carbonate, kaolin powder, sepiolite powder, iron ore powder, quartz powder, diatomaceous earth powder, bauxite powder, attapulgite powder, phosphate rock powder, graphite powder, polysilicate Lithium salt, potassium salt, buckyball, clay powder.
  10. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤三中形成的碳化混合物,对该碳化混合物进行烘干处理后再倒入筛选装置中,烘干温度为:20℃-130℃。The method for manufacturing biomass fuel by using the waste product according to claim 1, wherein the carbonization mixture formed in the third step is dried and then poured into a screening device, and the drying temperature is: 20 °C-130 °C.
  11. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤四中所述降低反应釜中的温度和压强,具体是:将所述反应釜内的温度降至30℃-150℃,压强降至标准大气压。The method for manufacturing biomass fuel by using the waste according to claim 1, wherein the temperature and pressure in the reaction vessel are lowered in the fourth step, specifically, the temperature in the reaction vessel is lowered to 30 ° C - At 150 ° C, the pressure drops to standard atmospheric pressure.
  12. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤四中所述排出反应形成的液化水,具体是将液化水通过过滤器无害化处理并排入蓄水池或/和污水管网。The method for manufacturing biomass fuel by using the waste according to claim 1, wherein the liquefied water formed by the discharge reaction in the step 4 is specifically treated by the liquefied water through the filter and discharged into the reservoir. Or / and sewage pipe network.
  13. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤四中所述排出反应形成的气体,具体是将气体通过过滤器无害化处理并排向大气。The method for producing biomass fuel by using the waste according to claim 1, wherein the gas formed by the discharge reaction in the fourth step is specifically treated by the filter through the filter and discharged to the atmosphere.
  14. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤五中所述由筛选装置筛选出碳化混合物中不可燃烧的物质,具体是通过震动或/和磁吸的方式对碳化混合物进行筛选。The method for manufacturing biomass fuel by using waste according to claim 1, wherein in step 5, the non-combustible substance in the carbonization mixture is selected by the screening device, specifically by vibration or/and magnetic attraction. The carbonized mixture was screened.
  15. 根据权利要求1所述的利用垃圾制造生物质燃料的方法,其特征是,步骤五中,在将碳化混合物进行筛选处理之前或之后,对碳化混合物进行粉碎处理,粉碎处理后形成粉状生物质燃料。 The method for producing biomass fuel by using waste according to claim 1, wherein in step 5, the carbonized mixture is pulverized before or after the carbonization mixture is subjected to a screening treatment, and the pulverized biomass is formed into a powdery biomass. fuel.
  16. 根据权利要求15所述的利用垃圾制造生物质燃料的方法,其特征是,所述粉状生物质燃料,其颗粒大小为:20μm-1500μm。The method of manufacturing biomass fuel using waste according to claim 15, wherein the powdery biomass fuel has a particle size of from 20 μm to 1500 μm.
  17. 根据权利要求15所述的利用垃圾制造生物质燃料的方法,其特征是,所述粉状生物质燃料,根据客户需求通过成型装置加工成设定形状的生物质燃料。The method of manufacturing biomass fuel using waste according to claim 15, wherein the powdery biomass fuel is processed into a biomass fuel of a set shape by a molding apparatus according to a customer's demand.
  18. 根据权利要求17所述的利用垃圾制造生物质燃料的方法,其特征是,所述设定形状的生物质燃料,具体为球形生物质燃料、砖形生物质燃料、棒形生物质燃料或蜂窝形生物质燃料。A method of manufacturing biomass fuel using waste according to claim 17, wherein said shaped biomass fuel is specifically spherical biomass fuel, brick biomass fuel, rod biomass fuel or honeycomb Shaped biomass fuel.
  19. 根据权利要求17所述的利用垃圾制造生物质燃料的方法,其特征是,所述对粉状生物质燃料成型处理时,湿度为:5%-30%,压强为:20MPa~100MPa。 The method for producing biomass fuel by using the waste according to claim 17, wherein the powdery biomass fuel is subjected to a molding process with a humidity of 5% to 30% and a pressure of 20 MPa to 100 MPa.
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