WO2015182124A1 - シリコン材料及び二次電池の負極 - Google Patents
シリコン材料及び二次電池の負極 Download PDFInfo
- Publication number
- WO2015182124A1 WO2015182124A1 PCT/JP2015/002653 JP2015002653W WO2015182124A1 WO 2015182124 A1 WO2015182124 A1 WO 2015182124A1 JP 2015002653 W JP2015002653 W JP 2015002653W WO 2015182124 A1 WO2015182124 A1 WO 2015182124A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- silicon
- negative electrode
- active material
- secondary battery
- electrode active
- Prior art date
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- 239000002210 silicon-based material Substances 0.000 title claims abstract description 76
- 239000007773 negative electrode material Substances 0.000 claims description 44
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 27
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- 239000002105 nanoparticle Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 abstract 2
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- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 36
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 29
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- 229910052731 fluorine Inorganic materials 0.000 description 16
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/02—Silicon
- C01B33/021—Preparation
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/02—Silicon
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/02—Details
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a silicon material used as a negative electrode active material of a lithium ion secondary battery or the like, a negative electrode active material containing the silicon material, and a secondary battery using the negative electrode active material.
- the lithium ion secondary battery is a secondary battery that has a high charge / discharge capacity and can achieve high output. Currently, it is mainly used as a power source for portable electronic devices, and is further expected as a power source for electric vehicles expected to be widely used in the future.
- a lithium ion secondary battery has an active material capable of inserting and removing lithium (Li) on a positive electrode and a negative electrode, respectively. Then, it operates by moving lithium ions in the electrolytic solution provided between both electrodes.
- lithium-containing metal complex oxides such as lithium cobalt complex oxide are mainly used as the active material of the positive electrode, and carbon materials having a multilayer structure are mainly used as the active material of the negative electrode There is.
- the performance of the lithium ion secondary battery depends on the materials of the positive electrode, the negative electrode and the electrolyte that constitute the secondary battery. Above all, research and development of active material materials that form active materials are actively conducted. For example, silicon or silicon oxide having a higher capacity than carbon is being studied as a negative electrode active material.
- silicon As the negative electrode active material, a battery with higher capacity than using a carbon material can be obtained.
- silicon has a large volume change associated with absorption and release of Li during charge and discharge. Therefore, in a secondary battery using silicon as a negative electrode active material, silicon is pulverized during charge and discharge to cause a structural change, and it falls off or peels off the current collector, so that the charge and discharge cycle life of the battery is short. There is a point. Then, the technique which suppresses the volume change accompanying absorption and discharge of Li at the time of charge and discharge rather than silicon is examined by using a silicon oxide as a negative electrode active material.
- SiO x silicon oxide
- SiO x decomposes into Si and SiO 2 when heat-treated. This is called disproportionation reaction, and it is separated into two phases of Si phase and SiO 2 phase by internal reaction of solid.
- the Si phase obtained by separation is very fine.
- the SiO 2 phase covering the Si phase has the function of suppressing the decomposition of the electrolytic solution. Therefore, a secondary battery using a negative electrode active material composed of SiO x decomposed into Si and SiO 2 is excellent in cycle characteristics.
- Patent Document 1 describes a method of heating and subliming metal silicon and SiO 2 into silicon oxide gas and cooling it to produce SiO x .
- JP-A 2009-102219 decomposes a silicon raw material into an elemental state in high temperature plasma, and rapidly cools it to liquid nitrogen temperature to obtain silicon nanoparticles, and then this silicon nanoparticles are A manufacturing method of fixing in a SiO 2 -TiO 2 matrix by a sol-gel method or the like is described.
- the raw material is limited to a sublimable material. Furthermore, it is known that the irreversible Li is generated on the negative electrode by the fact that the SiO 2 phase covering the Si phase changes to lithium silicate when Li is absorbed, and it is necessary to add a surplus active material to the positive electrode. Further, the manufacturing method described in Patent Document 2 requires high energy for plasma discharge. Furthermore, in the silicon composite obtained by these manufacturing methods, there is a problem that the dispersibility of silicon particles in the Si phase is low and aggregation is easy. When the silicon particles aggregate to increase the particle size, the secondary battery using it as a negative electrode active material has a low initial capacity, and the cycle characteristics also deteriorate.
- Non-patent document 2 Materials Research Bulletin, Vol. 31, No. 3, pp. 307-316, 1996 (non-patent document 2) is obtained by reacting hydrogen chloride (HCl) with calcium disilicide (CaSi 2 ). It is described that the layered polysilane was heat-treated at 900 ° C. to obtain plate-like silicon crystals.
- Patent Document 3 describes a lithium ion secondary battery using layered polysilane as a negative electrode active material.
- a secondary battery such as a lithium ion secondary battery
- high capacity can be achieved by using silicon or SiO x as the negative electrode active material.
- a secondary battery using silicon or SiO x as a negative electrode active material may have insufficient life and initial efficiency, and has not been put to practical use. Therefore, in the case of using the above-described silicon material as a negative electrode active material of a secondary battery, it is required to achieve both the improvement of the initial efficiency and the extension of the life.
- a new silicon material useful as a negative electrode active material capable of suitably maintaining the capacity of a secondary battery is required.
- the present inventors diligently investigated the characteristics of a lithium ion secondary battery using a silicon material obtained by heat treatment of a layered silicon compound as a negative electrode active material. Then, the inventors found that the band gap of the silicon material greatly affects the life (cycle characteristics) which is one of the battery characteristics, and completed the present invention.
- the feature of the silicon material of the present invention for solving the above problems is that the Si / O atomic ratio is in the range of more than 1 / 0.5 and 1 / 0.1 or less, and the band gap is in the range of more than 1.1 eV and less than 2.1 eV. It is to be.
- the feature of the secondary battery of the present invention is to have a negative electrode containing a negative electrode active material using the silicon material of the present invention.
- the silicon material of the present invention is useful as a negative electrode active material of a secondary battery using a non-aqueous electrolyte.
- the secondary battery using the silicon material of the present invention as a negative electrode active material can maintain its capacity suitably and has a long life.
- the silicon material of the present invention has a band gap of more than 1.1 eV and less than or equal to 2.1 eV. It is particularly desirable that the band gap be in the range of 1.2 eV to 1.6 eV.
- Non-Patent Document 2 mentioned above describes that the band gap has been calculated, and it also describes that the band gap of the silicon material changes depending on the annealing conditions of the layered silicon compound. However, there is no description or suggestion regarding the relationship between the band gap and the battery characteristics.
- the present inventors set a silicon material having an Si / O atomic ratio in the range of 1 / 0.5 to 1 / 0.1 or less and a band gap in the range of 1.1 eV or less and 2.1 eV or less as the negative electrode active material. By using it, it was found that the life of the secondary battery is improved while maintaining the initial efficiency high to some extent.
- the band gap can be calculated from the absorption edge wavelength of the light absorption spectrum of the silicon material.
- the silicon material of the present invention has a Si / O atomic ratio in the composition of more than 1 / 0.5 and less than 1 / 0.1. More preferably, the Si / O atomic ratio is in the range of 1 / 0.4 to 1 / 0.2. It is difficult to produce silicon materials with Si / O atomic ratio exceeding 1 / 0.1, and when Si / O atomic ratio is 1 / 0.5 or less, initial capacity and initial capacity of secondary battery using the silicon material as negative electrode active material Efficiency may be reduced.
- the Si / O atomic ratio can be calculated from TEM-EDX data.
- the silicon material of the present invention preferably contains silicon crystallites.
- the silicon crystallite preferably has a crystallite size of 0.5 nm to 300 nm, more preferably 1 nm to 30 nm, and particularly preferably in the range of 1 nm to 10 nm. When the crystallite size exceeds 300 nm, the battery capacity may decrease when used as a negative electrode active material of a secondary battery.
- the crystallite size is calculated from the half width of the diffraction peak of the (111) plane (present at a position of 27 ° to 30 °) in the X-ray diffraction measurement result according to the Scherrer's equation.
- the silicon material of the present invention may be a composite particle further including at least one of amorphous silicon, silicon oxide (SiO x , 0 ⁇ x ⁇ 2), or a silicon compound in addition to silicon crystallites.
- silicon crystallites exist on at least one surface and / or inside of amorphous silicon, silicon oxide (SiO x , 0 ⁇ x ⁇ 2), or silicon compound.
- silicon crystallites may be dispersed like islands in a matrix mainly composed of amorphous silicon, or may be adhered like islands on the surface of particles mainly composed of amorphous silicon.
- the initial capacity is low when used as a negative electrode active material of a secondary battery. If the concentration of silicon crystallite is too high, the expansion and contraction amount of the whole active material may be increased, and the life (cycle characteristics) may be deteriorated.
- the particle size of the silicon material (composite particles) of the present invention is not particularly limited, but when used as a negative electrode active material of a secondary battery, it is preferable to use one classified in the range of 2 ⁇ m to 20 ⁇ m.
- the silicon material of the present invention contains fluorine (F).
- fluorine By containing fluorine, the content of chlorine (Cl) and oxygen (O) can be reduced, and when used as a negative electrode active material of a secondary battery, the reaction between chlorine or oxygen and lithium can be reduced.
- the content of fluorine in the silicon material can be in the range of 0.01 to 10% by mass. If the amount of fluorine is less than this range, the amount of chlorine (Cl) and oxygen (O) will increase, and the conductive resistance will increase, and the initial efficiency of a secondary battery using such a silicon material as a negative electrode active material descend. When the amount of fluorine in the silicon material is larger than this range, the capacity of a secondary battery using the silicon material as a negative electrode active material may decrease.
- the particularly preferred range is 1 to 5% by mass.
- the silicon material of the present invention preferably has a BET specific surface area of 3 to 100 m 2 / g, and 4 to 80 m 2 / g, in consideration of battery characteristics when used as a negative electrode active material of a secondary battery. Is desirable, and 7 to 60 m 2 / g is particularly desirable. Moreover, as for the silicon material of this invention, it is desirable that the amount of oxygen contained is 20 mass% or less. For example, although the amount of oxygen of silicon obtained by heat-treating the layered silicon compounds described in Non-Patent Documents 1 and 2 is as large as about 33 mass%, the amount of oxygen of silicon material containing fluorine is as small as 30 mass% or less.
- the silicon material of the present invention can be produced by heat-treating a layered silicon compound obtained by reacting an acid and CaSi 2 at about 350 ° C. to 950 ° C. in a non-oxidizing atmosphere.
- an acid to be used hydrochloric acid (HCl) may be used as described in Non-patent Document 2, and it is also preferable to use an acid containing at least an anion of fluorine.
- HCl hydrochloric acid
- an acid containing fluorine as at least an anion, the amount of oxygen (O) contained in the layered silicon compound and the silicon material can be reduced.
- fluorine (F) the amount of chlorine (Cl) can be zero or reduced. Therefore, when the fluorine-containing silicon material of the present invention is used as a negative electrode active material of a lithium ion secondary battery or the like, the initial capacity is suitably improved.
- a layered silicon compound obtained by reacting a chemical solution containing at least an anion with an acid containing fluorine with CaSi 2 is heat-treated at 350 ° C. or higher in a non-oxidizing atmosphere. preferable.
- hydrofluoric acid tetrafluoroboric acid, hexafluorophosphoric acid, hexafluoroarsenic acid, fluoroantimonic acid, hexafluorosilicic acid, hexafluorogermanic acid, hexafluorotin (IV)
- acids trifluoroacetic acid, hexafluorotitanic acid, hexafluorozirconate, trifluoromethanesulfonic acid, fluorosulfonic acid and the like.
- acids may contain other acids.
- other acids include hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, methanesulfonic acid, nitric acid, phosphoric acid, formic acid, acetic acid and the like.
- the reaction of a chemical solution containing an acid containing fluorine at least in the anion with CaSi 2 can be carried out under the same conditions as those described in Non-Patent Documents 1 and 2.
- the reaction is preferably carried out at a low temperature below room temperature, preferably on an ice bath.
- the obtained layered silicon compound has a smaller amount of oxygen and contains fluorine as compared to the layered silicon compound obtained by the method described in Non-Patent Documents 1 and 2.
- the process of producing a layered silicon compound may be referred to as a layered silicon compound production process.
- hydrofluoric acid (HF) is used as an acid containing fluorine at least in the anion in the layered silicon compound production step
- hydrochloric acid (HCl) is preferable to use in combination.
- HF hydrofluoric acid
- HCl hydrochloric acid
- hydrochloric acid (HCl) it is the same as that of nonpatent literature 1, 2, and only the layered silicon compound with many amounts of oxygen can be obtained.
- the amount of hydrofluoric acid (HF) exceeds this ratio, many impurities such as CaF 2 and CaSiO may be generated, and it is not preferable because it is difficult to separate the impurities from the layered silicon compound.
- the amount of hydrofluoric acid (HF) is smaller than this ratio, the etching action on Si-O bond by hydrofluoric acid (HF) is weak, and a large amount of oxygen may remain in the obtained layered silicon compound.
- the compounding ratio of a mixture of hydrofluoric acid (HF) and hydrochloric acid (HCl) to calcium disilicide (CaSi 2 ) is preferably such that the acid is in excess of the equivalent.
- the reaction atmosphere is preferably performed under vacuum or under an inert gas atmosphere.
- reaction time becomes short compared with the manufacturing method of a nonpatent literature 1,2. If the reaction time is too long, Si and HF react further to form SiF 4, so a reaction time of about 0.25 to 24 hours is sufficient.
- CaCl 2 and the like are produced by the reaction, they can be easily removed by washing with water, and purification of the layered silicon compound is easy.
- tetrafluoroboric acid HHF 4
- HCF 4 tetrafluoroboric acid
- hydrochloric acid HCl
- HCF 4 tetrafluoroboric acid
- It can be reacted with calcium disilicide (CaSi 2 ).
- the reaction conditions can be carried out in the same manner as described above. According to this method, since chlorine (Cl) is not contained in the layered silicon compound and the silicon material to be obtained, the resistance can be further reduced when the silicon material of the present invention is used as the negative electrode active material.
- the layered silicon compound obtained in the above-described layered silicon compound production process has a Raman shift of 330 ⁇ 20 cm ⁇ 1 , 360 ⁇ 20 cm ⁇ 1 , 498 ⁇ 20 cm ⁇ 1 , 638 ⁇ 20 cm ⁇ 1 , 734 ⁇ 20 cm ⁇ 1 in the Raman spectrum. Peak exists in the This layered silicon compound has as a main component a structure represented by a composition formula (SiH) n in which a plurality of six-membered rings composed of silicon atoms are linked.
- the layered silicon compound obtained is subjected to a heat treatment.
- the heat treatment is performed in a non-oxidative atmosphere.
- the non-oxidizing atmosphere include a reduced pressure atmosphere, a vacuum atmosphere and an inert gas atmosphere.
- the heat treatment temperature is preferably in the range of 350 ° C. or more and less than 950 ° C., and particularly preferably in the range of 400 ° C. or more and 800 ° C. or less.
- the layered silicon compound obtained by reacting the acid and CaSi 2 is heat-treated in a non-oxidizing atmosphere to obtain a silicon material. Depending on the conditions, a silicon material containing nano-sized silicon crystallites is obtained.
- the heat treatment time varies depending on the heat treatment temperature, but can be 1 hour to 48 hours, preferably 2 hours to 12 hours, for heat treatment of 500 ° C. or higher.
- the silicon material of the present invention can be used as a negative electrode active material in a secondary battery such as a lithium ion secondary battery.
- the negative electrode active material powder contained in the slurry it is preferable to use one having a particle size classified in the range of 2 ⁇ m to 20 ⁇ m.
- the particle diameter is less than 2 ⁇ m, the contact interface with the electrolyte increases, and the decomposition product of the electrolyte may increase during use as a secondary battery.
- particles having a particle size of more than 20 ⁇ m may increase the stress of the outermost shell and may cause breakage or detachment of the negative electrode active material layer.
- the thickness of the negative electrode active material layer depends on the particle size of the negative electrode active material, which may make it difficult to control the thickness. A known method can be used as the classification method.
- the binder is required to bind the active material and the like in a small amount as much as possible, but the addition amount thereof is preferably 0.5% by mass to 50% by mass of the total of the active material, the conductive additive and the binder.
- the binder is less than 0.5% by mass, the formability of the electrode is reduced, and when it is more than 50% by mass, the energy density of the electrode is reduced.
- any of solvent based binders and aqueous binders can be used.
- solvent-based binders include polyvinylidene fluoride (PVdF), polytetrafluoroethylene (PTFE), styrene-butadiene rubber (SBR), polyimide (PI), polyamide imide (PAI), polyamide (PA), and poly Examples include vinyl chloride (PVC), polymethacrylic acid (PMA), polyacrylonitrile (PAN), modified polyphenylene oxide (PPO), polyethylene oxide (PEO), polyethylene (PE), polypropylene (PP) and the like.
- PVdF polyvinylidene fluoride
- PTFE polytetrafluoroethylene
- SBR styrene-butadiene rubber
- PI polyimide
- PAI polyamide imide
- PA polyamide
- PVC vinyl chloride
- PMA polymethacrylic acid
- PAN polyacrylonitrile
- PPO polyphenylene oxide
- the aqueous binder means a binder to be used by mixing with an active material in a state in which the binder is dispersed or dissolved in water, and representative examples thereof include polyacrylic acid (PAA), styrene butadiene rubber (SBR), sodium alginate, Ammonium alginate can be used.
- PAA polyacrylic acid
- SBR styrene butadiene rubber
- Ammonium alginate can be used.
- What mixed carboxymethylcellulose (CMC) with these binders can also be used as a water-based binder, and it can change to SBR and / or PAA, and can also use CMC alone as a water-based binder.
- crosslinked body of water-soluble polymer as an aqueous binder
- water-soluble cellulose ester crosslinked bodies such as a CMC crosslinked body, a starch / acrylic acid graft polymer, etc. can be used.
- polyvinylidene fluoride When polyvinylidene fluoride is used as a binder, the potential of the negative electrode can be lowered, and the voltage of the secondary battery can be improved. Moreover, initial efficiency and discharge capacity may be improved by using polyamide imide (PAI) or polyacrylic acid (PAA) as a binder.
- PAI polyamide imide
- PAA polyacrylic acid
- a current collector is a chemically inert electron conductor for keeping current flowing to an electrode during discharge or charge.
- the current collector may be in the form of a foil, a plate or the like, but is not particularly limited as long as it has a shape according to the purpose.
- copper foil or aluminum foil can be suitably used as the current collector.
- the negative electrode active material known materials such as graphite, hard carbon, silicon, carbon fiber, tin (Sn) and silicon oxide can be mixed with the silicon material of the present invention.
- silicon oxides represented by SiO x (0.3 ⁇ x ⁇ 1.6) are particularly preferable.
- Each particle of this silicon oxide powder is composed of fine Si by the disproportionation reaction and SiO 2 covering Si.
- x is less than the lower limit value, the Si ratio increases, so that the volume change at the time of charge and discharge becomes too large, and the cycle characteristics deteriorate. If x exceeds the upper limit value, the Si ratio decreases and the energy density decreases.
- the range of 0.5 ⁇ x ⁇ 1.5 is preferable, and the range of 0.7 ⁇ x ⁇ 1.2 is more preferable.
- the negative electrode active material one obtained by compounding a carbon material with 1 to 50% by mass with respect to SiO x can also be used.
- the composite of the carbon material improves the cycle characteristics of the secondary battery.
- the composite amount of the carbon material is preferably in the range of 5 to 30% by mass with respect to SiO x , and more preferably in the range of 5 to 20% by mass.
- a CVD method or the like can be used to complex the carbon material with SiO x .
- the silicon oxide powder desirably has an average particle size in the range of 1 ⁇ m to 10 ⁇ m.
- the average particle size is larger than 10 ⁇ m, the durability of the non-aqueous secondary battery is reduced, and when the average particle size is smaller than 1 ⁇ m, the non-aqueous secondary battery also decreases in durability because it is aggregated to form coarse particles. There is a case.
- a conductive aid is added to enhance the conductivity of the electrode.
- carbon black fine particles carbon black, natural graphite, granulated graphite, artificial graphite, flame retardant graphite, acetylene black (AB), ketjen black (KB) (registered trademark), vapor grown carbon fiber (Vapor Grown Carbon Fiber: VGCF) etc. may be added alone or in combination of two or more.
- the use amount of the conductive aid is not particularly limited, but can be, for example, about 20 to 100 parts by mass with respect to 100 parts by mass of the active material.
- the amount of the conductive additive is less than 20 parts by mass, efficient conductive paths can not be formed, and if it exceeds 100 parts by mass, the formability of the electrode is deteriorated and the energy density is lowered.
- the addition amount of the conductive support agent can be reduced or eliminated.
- organic solvent there is no particular limitation on the organic solvent, and a mixture of plural solvents may be used.
- mixed solvent of N-methyl-2-pyrrolidone, N-methyl-2-pyrrolidone and ester solvent ethyl acetate, n-butyl acetate, butyl cellosolve acetate, butyl carbitol acetate etc.
- N-methyl-2-pyrrolidone Particularly preferred is a mixed solvent of pyrrolidone and a glyme solvent (diglyme, triglyme, tetraglyme, etc.).
- the negative electrode can also be predoped with lithium.
- the negative electrode for example, an electrode forming method in which a half cell is assembled using metallic lithium as a counter electrode and electrochemically dope lithium can be used.
- the doping amount of lithium is not particularly limited.
- the secondary battery of the present invention is a lithium ion secondary battery
- known positive electrodes, electrolytes and separators which are not particularly limited can be used.
- the positive electrode may be one that can be used in a lithium ion secondary battery.
- the positive electrode has a current collector and a positive electrode active material layer bound on the current collector.
- the positive electrode active material layer contains a positive electrode active material and a binder, and may further contain a conductive aid.
- the positive electrode active material, the conductive additive and the binder are not particularly limited as long as they can be used in a non-aqueous secondary battery.
- the positive electrode active material metal lithium, LiCoO 2 , Li x Ni a Co b Mn c O 2 , Li x Co b Mn c O 2 , Li x Ni a Mn c O 2 , Li x Ni a Co b O 2 and Li compounds or solid solutions selected from Li 2 MnO 3 (provided that 0.5 ⁇ x ⁇ 1.5, 0.1 ⁇ a ⁇ 1, 0.1 ⁇ b ⁇ 1, 0.1 ⁇ c ⁇ 1), Li 2 MnO 3 , sulfur and the like can be mentioned.
- the current collector may be any one commonly used for a positive electrode of a lithium ion secondary battery, such as aluminum, nickel, stainless steel and the like.
- the conductive additive the same one as described in the above-mentioned negative electrode can be used.
- the electrolytic solution is one in which a lithium metal salt which is an electrolyte is dissolved in an organic solvent.
- an organic solvent use is made of one or more selected from aprotic organic solvents such as propylene carbonate (PC), ethylene carbonate (EC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC), etc. Can.
- a lithium metal salt soluble in an organic solvent such as LiPF 6 , LiBF 4 , LiAsF 6 , LiI, LiClO 4 and LiCF 3 SO 3 can be used.
- an electrolytic solution for example, 0.5 mol / L to 1.7 mol / L of lithium metal salt such as LiClO 4 , LiPF 6 , LiBF 4 , LiCF 3 SO 3 and the like in an organic solvent such as ethylene carbonate, dimethyl carbonate, propylene carbonate, dimethyl carbonate It is possible to use solutions dissolved at a certain concentration.
- lithium metal salt such as LiClO 4 , LiPF 6 , LiBF 4 , LiCF 3 SO 3 and the like
- organic solvent such as ethylene carbonate, dimethyl carbonate, propylene carbonate, dimethyl carbonate
- the separator is not particularly limited as long as it can be used for non-aqueous secondary batteries.
- the separator separates the positive electrode and the negative electrode and holds the electrolytic solution, and a thin microporous film such as polyethylene or polypropylene can be used.
- the shape of the secondary battery of the present invention is not particularly limited, and various shapes such as a cylindrical shape, a laminated shape, and a coin shape can be adopted.
- the separator is interposed between the positive electrode and the negative electrode to form an electrode body, and the distance from the positive electrode current collector and the negative electrode current collector to the positive electrode terminal and the negative electrode terminal leading to the outside is for current collection After connection using a lead or the like, the electrode body is sealed in a battery case together with an electrolytic solution to form a battery.
- Example 1 65 ml of a 36% by weight aqueous solution of HCl was brought to 0 ° C. in an ice bath, and 3.3 g of calcium disilicide (CaSi 2 ) was added thereto in an argon gas flow and stirred. After confirming that the foaming was completed, the temperature was raised to room temperature, and after stirring for another 2 hours at room temperature, 20 ml of distilled water was added and the mixture was further stirred for 10 minutes. At this time, yellow powder floated. The resulting mixed solution was filtered and the residue was washed with 10 ml of distilled water and then with 10 ml of ethanol and dried under vacuum for 12 hours to obtain 3.5 g of layered silicon compound.
- CaSi 2 calcium disilicide
- the Raman spectrum of this layered silicon compound is shown in FIG. There are peaks at 330 ⁇ 10 cm ⁇ 1 , 360 ⁇ 10 cm ⁇ 1 , 498 ⁇ 10 cm ⁇ 1 , 638 ⁇ 10 cm ⁇ 1 , and 734 ⁇ 10 cm ⁇ 1 of the Raman shift.
- this layered silicon compound was weighed, and heat treatment was carried out by holding it at 500 ° C. for 12 hours in an argon gas with an amount of O 2 of 1 volume% or less to obtain 1.45 g of a brown silicon material.
- the BET specific surface area of this silicon material was 7.6 m 2 / g.
- the obtained silicon material was subjected to X-ray diffraction measurement (XRD measurement) using a CuK ⁇ ray. Three peaks derived from silicon crystallite were present in the XRD chart. And, the crystallite size calculated from the Scherrer's equation from the half width of the diffraction peak of the (111) plane (present at a position of 27 ° to 30 °) is in the nm order and the silicon including nanosize silicon crystallite It was a material.
- the diffuse reflection absorption spectrum of this silicon material was measured, and the band gap was calculated from the absorption edge wavelength. As shown in Table 1, it was 1.6 eV.
- the Si / O atomic ratio calculated by TEM-EDX was 1 / 0.36.
- Example 2 Using the layered silicon compound produced in the same manner as in Example 1, a silicon material was obtained in the same manner as in Example 1 except that the heat treatment temperature was set to 700 ° C.
- the band gap of this silicon material was calculated from the absorption edge wavelength of the light absorption spectrum, and as shown in Table 1, it was 1.4 eV.
- the Si / O atomic ratio calculated by TEM-EDX was 1 / 0.36.
- Example 3 A layered silicon compound manufactured in the same manner as in Example 1 was used, and a silicon material was obtained in the same manner as in Example 1 except that the heat treatment temperature was 800 ° C.
- the band gap of this silicon material was calculated from the absorption edge wavelength of the light absorption spectrum, and as shown in Table 1, it was 1.4 eV.
- the Si / O atomic ratio calculated by TEM-EDX was 1 / 0.34.
- Example 4 A layered silicon compound manufactured in the same manner as in Example 1 was used, and a silicon material was obtained in the same manner as in Example 1 except that the heat treatment temperature was set to 900 ° C.
- the band gap of this silicon material was calculated from the absorption edge wavelength of the light absorption spectrum, and as shown in Table 1, it was 1.3 eV.
- the Si / O atomic ratio calculated by TEM-EDX was 1 / 0.34.
- Example 5 Using the layered silicon compound produced in the same manner as in Example 1, a silicon material was obtained in the same manner as in Example 1 except that the heat treatment temperature was set to 300 ° C.
- the band gap of this silicon material was calculated from the absorption edge wavelength of the light absorption spectrum, and as shown in Table 1, it was 2.1 eV.
- the Si / O atomic ratio calculated by TEM-EDX was 1 / 0.36.
- Example 6 A mixed solution of 2 ml of a 46% by weight aqueous solution of HF and 63 ml of a 36% by weight aqueous solution of HCl is brought to 0 ° C. in an ice bath and 3.3 g of calcium disilicide (CaSi 2 ) there in an argon gas stream was added and stirred. After confirming that the foaming was completed, the temperature was raised to room temperature, and after stirring for another 2 hours at room temperature, 20 ml of distilled water was added and the mixture was further stirred for 10 minutes. At this time, yellow powder floated.
- CaSi 2 calcium disilicide
- the resulting mixed solution was filtered, and the residue was washed with 10 ml of distilled water and then with 10 ml of ethanol and vacuum dried to obtain 2.5 g of a layered silicon compound.
- the band gap of this silicon material was calculated from the absorption edge wavelength of the light absorption spectrum, and as shown in Table 1, it was 1.6 eV.
- the Si / O atomic ratio calculated by TEM-EDX was 1 / 0.15.
- Example 7 Using the layered silicon compound produced in the same manner as in Example 6, a silicon material was obtained in the same manner as in Example 6 except that the heat treatment temperature was set to 700 ° C.
- the band gap of this silicon material was calculated from the absorption edge wavelength of the light absorption spectrum, and as shown in Table 1, it was 1.4 eV.
- the Si / O atomic ratio calculated by TEM-EDX was 1 / 0.21.
- Example 8 A layered silicon compound manufactured in the same manner as in Example 6 was used, and a silicon material was obtained in the same manner as in Example 6 except that the heat treatment temperature was set to 900 ° C.
- the band gap of this silicon material was calculated from the absorption edge wavelength of the light absorption spectrum, and as shown in Table 1, it was 1.2 eV.
- the Si / O atomic ratio calculated by TEM-EDX was 1 / 0.12.
- Example 9 A layered silicon compound manufactured in the same manner as in Example 6 was used, and a silicon material was obtained in the same manner as in Example 6 except that the heat treatment temperature was set to 300 ° C.
- the band gap of this silicon material was calculated from the absorption edge wavelength of the light absorption spectrum, and as shown in Table 1, it was 2.1 eV.
- the Si / O atomic ratio calculated by TEM-EDX was 1 / 0.16.
- Comparative example 1 A commercially available crystalline silicon (manufactured by Rare Metallic Co., Ltd.) was used as Comparative Example 1.
- the band gap of this crystalline silicon was calculated from the absorption edge wavelength of the light absorption spectrum, and as shown in Table 1, it was 1.1 eV.
- the band gap of this SiO x was calculated from the absorption edge wavelength of the light absorption spectrum, and as shown in Table 1, it was 1.8 eV.
- the Si / O atomic ratio is 1 / 1.1.
- Each slurry was prepared by mixing 45 parts by mass of each of the silicon materials of Examples and Comparative Examples, 40 parts by mass of natural graphite powder, 5 parts by mass of acetylene black, and 33 parts by mass of a binder solution.
- a binder solution a solution in which 30% by mass of polyamideimide (PAI) resin is dissolved in N-methyl-2-pyrrolidone (NMP) is used.
- PAI polyamideimide
- NMP N-methyl-2-pyrrolidone
- the current collector and the negative electrode active material layer were firmly and closely bonded by a roll press.
- the resultant was vacuum-dried at 100 ° C. for 2 hours to form a negative electrode having a basis weight of 2.0 mg / cm 2 and an electrode density of 1.0 g / cm 3 , respectively.
- Lithium secondary batteries (half cells) were produced using the negative electrode produced according to the above procedure as an evaluation electrode.
- the counter electrode was a metal lithium foil (thickness 500 ⁇ m).
- the counter electrode was cut into a diameter of 13 mm, and the evaluation electrode was cut into a diameter of 11 mm, and a separator (a glass filter made by Hoechst Celanese and "Celgard 2400" made by Celgard) was interposed therebetween to obtain an electrode body battery.
- the electrode battery was housed in a battery case (CR2032 type coin battery member, manufactured by Takasen Co., Ltd.).
- a non-aqueous electrolytic solution in which LiPF 6 is dissolved at a concentration of 1 M in a mixed solvent in which ethylene carbonate and diethyl carbonate are mixed at a ratio of 1: 1 (volume ratio) is sealed. Obtained a lithium secondary battery.
- ⁇ Battery characteristic test> For the lithium secondary batteries of Examples and Comparative Examples, 50 cycles of charge and discharge tests were performed under the conditions of current: 0.1 C and voltage: 0.01-0.8 V. The initial charge capacity and the discharge capacity were measured, and the initial efficiency (100 ⁇ discharge capacity / charge capacity) was calculated. The results are shown in Table 1. In addition, the capacity retention ratio, which is the ratio of the discharge capacity after 50 cycles to the initial discharge capacity, was calculated, and is shown in Table 1 as the life. Furthermore, FIG. 2 shows the relationship between the band gap and the capacity retention rate, and FIG. 3 shows the relationship between the band gap and the initial efficiency.
- FIGS. 2 and 3 black circles indicate silicon materials obtained using only hydrochloric acid (HCl) as acid species, and white circles indicate a mixture of hydrochloric acid (HCl) and hydrofluoric acid (HF) as acid species.
- HCl hydrochloric acid
- HF hydrofluoric acid
- the silicon material of the present invention can be used as a negative electrode active material of a storage device such as a secondary battery, an electric double layer capacitor, and a lithium ion capacitor.
- a storage device such as a secondary battery, an electric double layer capacitor, and a lithium ion capacitor.
- the secondary battery is useful as a non-aqueous secondary battery used for driving motors of electric vehicles and hybrid vehicles, personal computers, mobile communication devices, home appliances, office devices, industrial devices, etc. It can be used optimally for the motor drive of an electric car or hybrid car that requires an output.
- the degree of freedom of heat treatment temperature is high and the size of the specific surface area can be controlled to be complexed with other materials, it can also be used as a semiconductor material such as CMOS, semiconductor memory, solar cell material, photocatalyst material, etc. .
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Abstract
Description
本発明のシリコン材料は、バンドギャップが1.1eVを超えかつ2.1eV以下の範囲にある。バンドギャップが1.2eV~1.6eVの範囲にあることが特に望ましい。前述した非特許文献2には、バンドギャップを算出したことが記載され、層状シリコン化合物のアニール条件によってシリコン材料のバンドギャップが変化することが記載されている。しかしバンドギャップと電池特性との関係に関しては、記載も示唆もない。
本発明のシリコン材料は、酸とCaSi2とを反応させて得られた層状シリコン化合物を非酸化性雰囲気にて350℃~950℃程度で熱処理することで製造することができる。用いる酸としては、非特許文献2に記載されたように塩酸(HCl)を用いてもよいし、少なくともアニオンにフッ素を含む酸を用いることも好ましい。少なくともアニオンにフッ素を含む酸を用いることで、層状シリコン化合物及びシリコン材料に含まれる酸素(O)量を低減することができる。またフッ素(F)を含むことで、塩素(Cl)量をゼロ若しくは低減できる。したがって本発明のフッ素を含むシリコン材料をリチウムイオン二次電池の負極活物質などに用いた場合には、初期容量が好適に向上する。
層状シリコン化合物製造工程において、少なくともアニオンにフッ素を含む酸としてフッ化水素酸(HF)を用いる場合は、塩酸(HCl)を混合して用いることが好ましい。フッ化水素酸(HF)のみを用いた場合でも層状シリコン化合物が得られるものの、得られる層状シリコン化合物は活性が高く微量の空気によって酸化され、酸素量が増大するため好ましくない。また塩酸(HCl)のみを用いた場合は、非特許文献1,2と同様であり、酸素量が多い層状シリコン化合物しか得られない。
本発明のシリコン材料は、リチウムイオン二次電池などの二次電池における負極活物質として用いることができる。本発明のシリコン材料を用いて、例えば非水系二次電池の負極を作製するには、本発明のシリコン材料を含む負極活物質粉末と、炭素粉末などの導電助剤と、バインダーと、適量の有機溶剤を加えて混合しスラリーにしたものを、ロールコート法、ディップコート法、ドクターブレード法、スプレーコート法、カーテンコート法などの方法で集電体上に塗布し、バインダーを乾燥あるいは硬化させることによって作製することができる。
い。セパレータは、正極と負極とを分離し電解液を保持するものであり、ポリエチレン、ポリプロピレン等の薄い微多孔膜を用いることができる。
濃度36質量%のHCl水溶液65mlを氷浴中で0℃とし、アルゴンガス気流中にてそこへ3.3gの二ケイ化カルシウム(CaSi2)を加えて撹拌した。発泡が完了したのを確認した後に室温まで昇温し、室温でさらに2時間撹拌した後、蒸留水20mlを加えてさらに10分間撹拌した。このとき黄色粉末が浮遊した。得られた混合溶液を濾過し、残渣を10mlの蒸留水で洗浄した後、10mlのエタノールで洗浄し、真空下で12時間乾燥して3.5gの層状シリコン化合物を得た。
実施例1と同様に製造された層状シリコン化合物を用い、熱処理温度を700℃としたこと以外は実施例1と同様にしてシリコン材料を得た。
実施例1と同様に製造された層状シリコン化合物を用い、熱処理温度を800℃としたこと以外は実施例1と同様にしてシリコン材料を得た。
実施例1と同様に製造された層状シリコン化合物を用い、熱処理温度を900℃としたこと以外は実施例1と同様にしてシリコン材料を得た。
実施例1と同様に製造された層状シリコン化合物を用い、熱処理温度を300℃としたこと以外は実施例1と同様にしてシリコン材料を得た。
濃度46質量%のHF水溶液2mlと、濃度36質量%のHCl水溶液63mlとの混合溶液を氷浴中で0℃とし、アルゴンガス気流中にてそこへ3.3gの二ケイ化カルシウム(CaSi2)を加えて撹拌した。発泡が完了したのを確認した後に室温まで昇温し、室温でさらに2時間撹拌した後、蒸留水20mlを加えてさらに10分間撹拌した。このとき黄色粉末が浮遊した。
実施例6と同様に製造された層状シリコン化合物を用い、熱処理温度を700℃としたこと以外は実施例6と同様にしてシリコン材料を得た。
実施例6と同様に製造された層状シリコン化合物を用い、熱処理温度を900℃としたこと以外は実施例6と同様にしてシリコン材料を得た。
実施例6と同様に製造された層状シリコン化合物を用い、熱処理温度を300℃としたこと以外は実施例6と同様にしてシリコン材料を得た。
市販の結晶シリコン(レアメタリック社製)を比較例1とした。この結晶シリコンについて、光吸収スペクトルの吸収端波長からバンドギャップを算出したところ、表1にも示すように1.1eVであった。
市販のSiOx(x=0.5~1.6)(「酸化ケイ素」大阪チタニウム社製)を比較例2とした。このSiOxについて、光吸収スペクトルの吸収端波長からバンドギャップを算出したところ、表1にも示すように1.8eVであった。Si/O原子比は1/1.1である。
各実施例及び各比較例のシリコン材料それぞれ45質量部と、天然黒鉛粉末40質量部と、アセチレンブラック5質量部と、バインダー溶液33質量部とを混合してそれぞれのスラリーを調製した。バインダー溶液には、ポリアミドイミド(PAI)樹脂がN-メチル-2-ピロリドン(NMP)に30質量%溶解した溶液を用いている。これらのスラリーを、厚さ約20μmの電解銅箔(集電体)の表面にドクターブレードを用いてそれぞれ塗布し、乾燥して銅箔上に負極活物質層を形成した。その後、ロールプレス機により、集電体と負極活物質層を強固に密着接合させた。これを100℃で2時間真空乾燥し、負極活物質層の目付け量が2.0mg/cm2、電極密度が1.0g/cm3の負極をそれぞれ形成した。
各実施例及び各比較例のリチウム二次電池について、電流:0.1C、電圧:0.01-0.8Vの条件で、それぞれ50サイクルの充放電試験を行った。初期の充電容量と放電容量を測定し、初期効率(100×放電容量/充電容量)を算出した結果を表1に示す。また初期の放電容量に対する50サイクル後の放電容量の割合である容量維持率を算出し、寿命として表1に示す。さらに、バンドギャップと容量維持率との関係を図2に、バンドギャップと初期効率との関係を図3に示す。
Claims (5)
- Si/O原子比が1/0.5を超えかつ1/0.1以下の範囲にあり、バンドギャップが1.1eVを超えかつ2.1eV以下の範囲にあることを特徴とするシリコン材料。
- ナノサイズのシリコン結晶子を含む請求項1に記載のシリコン材料。
- 請求項1又は請求項2に記載のシリコン材料からなることを特徴とする負極活物質。
- 請求項3に記載の負極活物質を含むことを特徴とする負極。
- 請求項4に記載の負極を有することを特徴とする二次電池。
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JPWO2015182124A1 (ja) | 2017-04-20 |
KR101841871B1 (ko) | 2018-03-23 |
US20170194623A1 (en) | 2017-07-06 |
EP3150554B1 (en) | 2018-07-11 |
US10217990B2 (en) | 2019-02-26 |
RU2650976C1 (ru) | 2018-04-18 |
JP6176511B2 (ja) | 2017-08-09 |
KR20160143791A (ko) | 2016-12-14 |
CA2950251C (en) | 2019-06-25 |
EP3150554A1 (en) | 2017-04-05 |
EP3150554A4 (en) | 2017-05-10 |
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