WO2015116766A1 - A high loft, nonwoven web exhibiting excellent recovery - Google Patents

A high loft, nonwoven web exhibiting excellent recovery Download PDF

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Publication number
WO2015116766A1
WO2015116766A1 PCT/US2015/013429 US2015013429W WO2015116766A1 WO 2015116766 A1 WO2015116766 A1 WO 2015116766A1 US 2015013429 W US2015013429 W US 2015013429W WO 2015116766 A1 WO2015116766 A1 WO 2015116766A1
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WO
WIPO (PCT)
Prior art keywords
web
nonwoven web
agents
high loft
polyethyienes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2015/013429
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English (en)
French (fr)
Inventor
Mohammad Hassan
Douglas Brown
Jeffrey Stark
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Biax Fiberfilm Corp
Original Assignee
Biax Fiberfilm Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Biax Fiberfilm Corp filed Critical Biax Fiberfilm Corp
Priority to JP2016567456A priority Critical patent/JP2017505390A/ja
Priority to DE112015000561.7T priority patent/DE112015000561T8/de
Publication of WO2015116766A1 publication Critical patent/WO2015116766A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/007Addition polymers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • D04H3/07Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments otherwise than in a plane, e.g. in a tubular way
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]

Definitions

  • PCT PATENT APPUCATSON TITLE A HiGH LOFT, NONWOVEN WEB EXHIBITING EXCELLENT RECOVERY
  • This invention relates to a high loft, nonwoven web exhibiting excellent recovery.
  • polymeric fibers formed by spunbonding, meifbiowing or by some other extrusion process are collected downstream from an emitter, such as a die with a plurality of nozzles, on a horizontal oriented conveyor belt.
  • an emitter such as a die with a plurality of nozzles
  • Such processes tends to produc two-dimensional web where the fibers are oriented in the x and y directions since they are laid down in a horizontal plane. There are few if any fibers within the formed web that are oriented in the z-direetion. Because of this, the finished web tends to lack recovery once it is compressed.
  • this invention relates to a high loft, nonwoven web exhibiting excellent recovery.
  • the high ioft, nonwoven web is a three dimensional structure with fibers oriented in the x, y and z directions.
  • the web can be constructed as a single iayer or be formed with two or more layers.
  • the web has a thickness of less than about 250 millimeters and a basis weight of from between about 50 g/n ' to about 3,000 g/m 2 .
  • the web can be bonded using a thermal bonder, a chemical bonder, a hydro- o mechanical bonder, a mechanical bonder, or be left unbonded.
  • a vertical cross- section of the web when taken parallel to its machine direction, exhibits a piuraiity of snugiy stacked, approximately V, U, or C-shaped structures, with each approximately V, U, or C-shaped shaped structure having an apex facing in the machine direction.
  • the web has a recovery value of from between about 20% to about 99% after being
  • the apparatus includes a die having a plurality of nozzl s each emitting a filament
  • a pair of moving surfaces is located from between about 10 cm to about 150 cm of the distal end of each of the plurality of nozzles.
  • the pair of moving surfaces forms a convergent passage having an entry and an exit.
  • the apparatus also includes a mechanism for depositing the piuraiity of filaments onto and between the pair of moving surfaces.
  • the apparatus further includes a bonder located downstream of it and in vertically alignment with the pair of moving surfaces for bonding the 3 ⁇ dimensiona! structure to create a high ioft, nonwoven web with the filaments transformed into fibers oriented in the x, y and z directions.
  • the o web has a thickness of less than about 250 mm and a basis weight ranging from between about 50 g/m 2 to about 3,000 g/m 2 .
  • a vertical cross-section of the high ioft, nonwoven web when taken parallel to its machine direction, exhibits a plurality of snugly stacked, approximately V, U, or C-shaped structures, with each approximately V, U, or C-shaped structure having an apex facing in the machine direction.
  • the approximately V or U shaped structure is rotated 90 degrees to a horizontal orientation with the apex of each facing to the right.
  • the C-shaped structure is reversed in position so that the apex of each faces to the right.
  • the high loft, nonwovert web has a recovery value ranging from between about 20% to about 99% after being compressed under a pressure of 0,25 psi for a time period of 30 minutes.
  • a process for forming a high loft, nonwoven web includes the steps of
  • Air or gas streams are then used to facilitate movement and drawing/accelerating of the plurality of filaments.
  • the filaments are directed towards a pair of moving surfaces located at a distance of from between about 10 cm to about o 150 cm from the plurality of nozzles.
  • the pair of moving surfaces forms a convergent passage having an entry and an exit.
  • the plurality of filaments is deposited into the entry of the convergent passage.
  • the plurality of filaments is then routed through the convergent passage in descending travel from the entry to the exit and between the pair of moving surfaces in a machine direction to form a 3-dimensional structure with
  • the S-dimensional structure is bonded to form a high loft, nonwoven web having a thickness of less than about 250 millimeters and a basis weight ranging from between about 50 g/m a to about 3,000 g/n .
  • a vertical cross-section of the high loft, nonwoven web when taken parallel to its machine direction, exhibits a plurality
  • the high loft, nonwoven web has a recovery value ranging from between about 20% to about 99% after being compressed under a pressure of 0,25 psi for a time period of 30 minutes,
  • the genera! object of this invention is to provide high loft, nonwoven web exhibiting excellent recovery such that it can be compactly shipped without losing any materia! properties.
  • a more specific object of this invention is to provid high loft, nonwoven web with good thermal insulation and/or acoustical insulation values.
  • Anothe object of this invention is to provide high loft, nonwoven web which o can be used in the bedding, upholstery, filtration, foam replacement materials, and products utilizing cushioning materials.
  • a further object of this invention is to provide a high loft, nonwoven web exhibiting from between about 20% to about 99% recovery after compression, and such web exhibits a high porosity.
  • Stfil another object of this invention is to provide a high loft, nonwoven web exhibiting from between about 30% to about 95% recovery after compression. Still further, an object of this invention is to provide a high ioft, nonwoven web exhibiting from between about 40% to about 90% recovery after compression.
  • Fig. 1 is a perspective view of a high loft, nonwoven web of this invention showing a plurality of snug!y stacked, approximate V, U or C-shaped structures, with each uniqueiy shaped structure having an apex facing in the machine direction of the web.
  • Fig. 2 is a schematic of a vertical cross-section of a section of a high loft, nonwoven we showing a plurality of snugly stacked, approximate V, U or C-shaped structures, with each uniquely shaped structure having an apex facing in the machine direction of the web.
  • Fig. 3 is a cross-sectional view of a two layer web.
  • Fig. 4 is a cross-sectional view of a multi-layer web.
  • Fig, 5 is a perspective view of an alternative embodiment of a high loft, nonwoven web depicting textured upper and lower surfaces
  • Fig. 8 is a schematic of the textured upper surface of the high loft, nonwoven web shown in Fig. 4.
  • Fig. 7 is a schematic of an apparatus utilizing a pair of rotatabie drums !ocated immediately downstream of a die.
  • Fig, 8 i a schematic of an alternative apparatus utilizing a pair of angled conveyors located immediately downstream of a die.
  • Fig. 9 is a schematic of still another apparatus using a combination of a spunbond die positioned between first and second meltb!own dies.
  • a high loft, nonwoven web 10 Is shown.
  • the high Soft, nonwoven web 10 is a 3-dimensionai structure with a piura!ity of fibers 12 oriented in the x, y and z directions, !n Fig. 1 ,
  • X— X represents the longitudinal central axis, Y-Y represents the vertical central axis, and Z--Z represents the transverse centra! axis.
  • 'web it is meant a fabric or materia! manufactured in sheet form.
  • high loft if is meant a iow density, fibrous web characterized by a high ratio of thickness to weight per unit area.
  • the fibers in the web 10 may be continuous or discontinuous, bonded or unbounded.
  • the fibers 12 are continuous and some of the fibers 12 are bonded.
  • a high loft web has from between about 5% to about 60% solids by volume.
  • nonwoven it is meant a web, sheet or haft of natural and/or man-made fibers or filaments (excluding paper) that have not been converted into yams, and that are bonded to each other by thermal, chemical, mechanical, hydro-mechanical, or by some other means known to those skilled in the art.
  • the high Soft, nonwoven web 10 can be formed from a variety of materials.
  • the high loft, nonwoven web 10 can be formed from man-made fibers.
  • the fibers can be staple fibers.
  • the high loft, nonwoven web 10 is formed from a polymer.
  • the polymer can be selected from the group consisting of: pofyofeftns, polyesters, polyethylene terephthalates, polybutylene terephfhaiates, polycyclohexy!ene dimethylene terephthalates, polytrimethyiene terephfhaiates, po!ymethyl methacryfates, poiyamides, nylons, poiyacrylics, polystyrenes, polyvinyls, poiytetrafiuoroethyienes, ultrahigh molecular weight polyethylenes, very high moiecuiar weight polyeihylenes, high molecular weight polyethylenes, poiyether ether ketones, non-fibrous piasticize celluloses, polyethylenes, poSypropylenes, poiybutylenes, polymethylpenfenes, low-density polyethylenes, linear low-density polyethylenes, high-density polyethylenes, polystyre
  • the high loft, nonwoven web 10 can be formed or manufactured using many different kinds and types of equipment and processes. Some commonly known technology which can be used to form the high loft, nonwoven web 10 include, but are not limited to: spinning processes such as meltbiowing, spunbond, spunmeit, 5 solution blowing, e!ectrospinning. in addition, the high Soft, nonwoven web 10 can be manufactured by a dry-laid process such as an air-lay process, a carding process or any combination of any two or more such processes where fibers are laid down at a ni between two moving surfaces. The manufactured high loft, nonwoven web 10 can be bonded or be unbounded. A bonding step adds strength and integrity io the finished web 10.
  • 'spunbond it is meant a process for producing strong fibrous nonwovens webs directly from thermoplastic polymers by attenuating the spun filaments using low temperature, high speed air while quenching the fibers near the spinnerette face, individual fibers are then laid down randomly on a coilection belt and are then conveyed io a bonder.
  • the bonder gives the web strength and integrity.
  • Fiber size is usually below 250 ⁇ , the average fiber size is in the range of from between about 10 microns to about 50 microns and the fibers are very strong compared to meitbiown fibers because of the molecular chain alignment that is achieved during the attenuating of the crystallized (solidified) filaments.
  • a typical spunbond die has multiple rows of polymer nozzie holes, A typical melt flow rate is below about 500 grams/10 minutes.
  • spunmeit it is meant a process where fibers are spun from molten polymers through a plurality of nozzles located in a die head connected to one or more extruders.
  • a spunmeit process may include meltbiowing and/or spunbonding, s
  • meltbiowing it is meant a process where a plurality of molten polymer streams are attenuated using an elevated temperature, high speed gas stream.
  • the gas can be air or other gases known to those skilled in the art.
  • the attenuated fibers are then collected on a moving belt, conveyor or a duai drum collector.
  • meltbiowing die typically has around 35 nozzles per inch, a row of spinnereites and two ) inclined air or gas jets for attenuating the fiber streams
  • U.S. Patent 4,380,570 and WO 2005/ 06,085 A1 teach meltbiowing processes where multiple rows of polymer nozzle are surrounded by air nozzles and the streams flowing therefrom are aligned parallel to one another
  • the high Soft, nonwoven web 10 can be 5 constructed as a single layer 1 of material.
  • the high loft, nonwoven web 10 can be formed using equipment where air or gas is used to facilitate movement and drawing of the molten polymer through a piuraiity of nozzles into a plurality of filaments. Each of the piuraiity of filaments is emitted through a single nozzle.
  • the high loft, nonwoven web 10' can a!so be formed of two separate and distinct layers, 14 and 16, see Fig. 3, or the web 10" can have multiple layers, see Fig. 4.
  • multiple layers it is meant 3, 4, 5, 8, 7 or more separate and distinct layers.
  • Some of the layers can be similar and/or identical in composition and characteristics to another layer, while one or more layers can vary in composition and/or characteristics from one or more of the remaining layers.
  • three separate and distinct layers 18, 20 and 22 are present. It should be understood that the web 10, consisting of a single layer 14, the web 10', consisting of two layers 14 and 16, or the web 10", consisting of three layers 18, 20 and 22, can be bonded to provide strength and integrity.
  • the web 10 ! is a two layer embodiment having an upper layer 14 and a lower layer 16.
  • the web 10" is a three layer embodiment having an upper !ayer 18, a middle layer 20 and a lower layer 22.
  • each layer can var in the type of polymer it is made from, in addition, the characteristics of a given layer can vary. For example, the characteristics of one layer can be different from another layer.
  • the thickness of each layer in the web 10" can vary or be the same.
  • the density of each layer in the web 0" can also vary or be the same.
  • the basis weight of each layer in the web 10" can also vary or be the same.
  • the high loft, nonwoven web 10 is depicted as a single layer structure.
  • the high loft, nonwoven web 10 has a thickness t which can vary in dimensions.
  • the thickness t of the high loft, nonwoven web 10 can range from between about 5 millimeters (mm) to about 300 mm. Desirabfy, the thickness t of the high loft, nonwoven web is less than about 250 millimeters. More desirably, the thickness t of the high loft, nonwoven web 10 is less than about 200 mm. Even more desirably, the thickness t of the high loft, nonwoven web 10 is less than about 100 mm.
  • the thickness t of the high loft, nonwoven web 10 is less than about 50 mm.
  • the overall thickness of the web 10' or 10" can double, triple, etc. depending upon how many layers are present.
  • the high loft, nonwoven web 10 can be formed with different basis weights. Generally, the basis weight of the high loft, nonwoven web 10 ranges from between about 50 grams per square meter ⁇ g/m 3 ⁇ to about 3,000 g/m s Desirabfy, the basis weight of the high loft, nonwoven web 10 ranges from between about 750 grams per square meter (g/m 2 ) to about 2,500 g/m 2 . More desirably, the basis weight of the high loft, nonwoven web 10 ranges from between about 100 grams per square meter ⁇ g/m 2 ) to about 1 ,000 g/m 2 . Even more desirably, the basis weight of the high Soft, nonwoven web 10 is less than about 600 g/m 3 .
  • the high ioft, nonwoven web 10 can also vary in density.
  • the high 5 loft, nonwoven web 10 has a density ranging from between about 10 kilograms per cubic meters (Kg/m 3) to about 250 Kg/m 3 .
  • the high ioft, nonwoven web 0 has a density ranging from between about 20 Kg/m :i to about 200 Kg/m 3 .
  • the high Soft, nonwoven web 10 has a density ranging from between about 30 Kg/tTT to about 150 Kg/m 3 .
  • the high ioft, nonwoven web 10 has a density ranging from between about 40 Kg/m J to about 100 Kg/m 3 .
  • the high loft, nonwoven web 10 can be bonded or unbounded. Desirably, the high Soft, nonwoven web 10 is bonded. Bonding generally imparts strength and integrity to the web 10. Bonding can be performed using different type of equipment and processes known to those skilled in the art. Various bonders include: mechanical bonders such as needle bonding, hydro-mechanicai bonders, aiso known as wet bonding, thermal bonders, which include through air bonding and oven thermal bonding and chemical bonding. Whichever type of bonder is utilized, some of the fibers 12, 14, 16, 18, 20 and 22 are bonded together to make the high loft, nonwoven web 10, 10' and 0 " stronger.
  • mechanical bonders such as needle bonding, hydro-mechanicai bonders, aiso known as wet bonding
  • thermal bonders which include through air bonding and oven thermal bonding and chemical bonding. Whichever type of bonder is utilized, some of the fibers 12, 14, 16, 18, 20 and 22 are bonded together to make the high loft, nonwoven web 10, 10' and 0
  • the high loft, nonwoven web 10 can be formed from polypropylene having a melt flow rate ranging from between about 4 g/10 min. to about 6,000 g/1Qmin at a temperature of 230 °C and at a pressure of 2.18 kg according to the teachings of AST D 1238 testing method.
  • the high ioft, nonwoven web 0 can be formed from polypropylene having a meit flow rate ranging s from between about 35 g/10 min. to about 2,500 g/10min at a temperature of 230 °C and at a pressure of 2.16 kg.
  • the high Soft, nonwoven web 10 can be formed from polypropylene having a melt flow rate ranging from between about 500 g/10 min.
  • the high loft, nonwoven web 10 can be formed from ) polypropylene having a melt flow rate ranging from between about 500 g/10 min, to about 1 ,500 g/10min at a temperature of 230 °C and at a pressure of 2.16 kg.
  • the schematic clearly shows a vertical cross-section of the high loft, nonwoven web 10 taken parallel to the machine direction (MID).
  • MID machine direction
  • the material advances from left 5 to right.
  • the leading edge of the high Soft, nonwoven web 10 is to the right.
  • the high loft, nonwoven web 10 exhibits a plurality of snugly stacked, approximately V, U or C- shaped structures 24. These V, U or C-shaped structures 24 are also depicted in Fig. 1.
  • Each of the approximately , U or C-shaped structures 24 has an apex 26 which faces in the machine direction (MO), In other words, the approximately V or U shaped structure is rotated 90 degrees to a horizontai orientation with the apex of each facing to the right.
  • the C-shaped structure is reversed in position so that the
  • the high loft, nonwoven web 10 has a recovery vaiue ranging from between about 20% to about 99% after being compressed under a pressure of 0.25 psi for a time period of 30 o minutes, according to the guidelines of the INDA Standard Test Method (1ST 120.2 (01 )).
  • the high ioft, nonwoven web 10 has a recovery vaiue ranging from between about 30% to about 95% according to the guidelines of the iST 120.2 (01 ). ore desirably, the high ioft, nonwoven web 10 has a recovery vaiue ranging from between about 40% to about 90% according to the guidelines of the 1ST 120.2 (01 ).
  • the high ioft, nonwoven web 0 has a recovery vaiue ranging from between about 50% to about 80% according to the guidelines of the iST 120.2 (01 ).
  • the two layered web 10' has a three dimensional structure with fibers oriented in the x, y and z directions.
  • This two layer web 10' has a thickness t ⁇ of from between about 5 millimeters to about 500 millimeters and a basis weight of from between about 50 g/m 2 to about 2,000 g/m 2
  • the two layered o web 0' does not have to be bonded but desirably is thermally or chemically bonded.
  • the web 10' couid be mechanically or hydro-mechanical iy bonded.
  • Each of the two layers, 14 and 18, of the web 10' exhibits a vertical cross-section, when taken parallel to the machine direction (MD) during manufacture of the two layered web 10', which exhibits a piuraiity of snugly stacked, approximately V, U or
  • Each of the approximately V, U or C-shaped structures 24 has an apex 26 facing in the machine direction (MD). in other words, the approximately V or U shaped structure is rotated 90 degrees to a horizontal orientation with the apex of each facing to the right.
  • the C-shaped structure is reversed in position so that the apex of each faces to the right.
  • the two layered web 10' has a recovery value of from between about 20% to about 99% after being compressed under a pressure of 0,25 psi for a time period of 30 minutes according to
  • the two layered web 10' has a recovery value ranging from between about 30% to about 85% according to the guideiines of the 1ST 120,2 (01 ). More desirably, the two layered web 10' has a recovery value ranging from between about 40% to about 90% according to the guidelines of the !ST 120,2 ⁇ 01 ⁇ . Even more desirably, the two layered web 10 ' has a o recovery value ranging from between about 50% to about 80% according to the guidelines of the iST 120.2 (01 ),
  • the two layer web 10' can be formed as two separate !ayers14 and 6 from comingled fibrous materials where each layer has a different fiber size, is formed from a different material, has different fiber cross-
  • the two layered web 10' could be laminated to one or more layers.
  • the additional layers could be a thermoplastic film, a film, another nonwoven material, paper, cardboard, etc.
  • the three layered web 10" has a three dimensional structure with fibers oriented in the x : y and z directions.
  • 0 has a thickness t 2 of from between about 5 millimeters to about 750 millimeters and a basis weight of from between about 50 g/m 3 to about 2,000 g/ro s
  • the three layered web 10" does not have to be bonded but desirably is thermally or chemically bonded. Alternatively, the web 10 * could be mechanically or hydro-mechanicaify bonded.
  • Each of the three layers, 18. 20 and 22, of the web 10" exhibits a vertical cross-
  • the three layered web 10 has a recovery value of from between about 20% to about 99% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes according to 1ST 120.2 (01 ). Desirably, the three layered web 10 has a recovery value ranging from between about 30% to about
  • the three layered web 10 has a recovery value ranging from between about 40% to about 90% according to 1ST 120.2 (01 ). Even more desirably, the three layered web 10 has a recovery va!ue ranging from between about 60% to about 80% according to iST 120.2 (01 ).
  • an additive can be incorporated into the high Soft, nonwoven web 10, 10 ' or 10".
  • the additive (not shown) can be applied to the high loft, nonwoven web 10, 10 : or 10" during manufacture.
  • the additive can be appiied in various ways, including but not limited to; being sprayed on, being sprinkled on, being extruded, being combined with, being painted on, being immersed, etc.
  • the additive can be a gas, a liquid, a so!id or a semi-solid.
  • the additive can be selected from the group consisting of: a superabsor ent, absorbent particles, pu!p fibers, polymers, nanoparticies, abrasive particulars, active particles, active compounds, ion exchange resins, zeolites, softening agents, plasticizers, ceramic particles pigments, dyes, fiavorants, aromas, controlled release vesicles, binders, adhesives, tackifiers, surface modification agents, lubricating agents, emuisifiers, vitamins, peroxides, antimicrobials, deodorizers, fire retardants, flame retardants, antifoaming agents, anil-static agents, biocldes, antifungals, degradation agents, stabilizing agents, conductivity modifying agents, or any combination thereof.
  • Figs. 5 and 6 an alternative embodiment of high loft, nonwoven web 1 1 is shown having been formed as a single layer 14 with two major surfaces 28 and 30, The two major surfaces 28 and 30 are aligned opposite to one another, in Fig. 5, the two major surfaces include the upper surface 28 and the iower surface 30.
  • two major surfaces it is meant the two surfaces of the web 11 which have the greatest surface area.
  • the web 11 has two major surfaces, 28 and 30, and both of these major surfaces 28 and 30 are textured.
  • B "textured” it is meant a rough or grainy surface quality, as opposed to being smooth. The texture can be formed various ways during processing of the web 1 1 . in Fig.
  • a plurality of protuberances 32 extends upward from the upper surface 28 and downward from the lower surface 30.
  • protuberance it is meant a bulge, knob or swelling that protrudes outward.
  • indentations, cavities or depressions cou!d be formed in the upper and/or Iower surfaces, 28 and 30 respectively, to obtain a simiiar textured effect, Desirably, at least one of the two major surfaces, 28 and 30 of the web 11 is textured. More desirably, both of the two major surfaces, 28 and 30 of a web 11 are textured.
  • an apparatus 34 for producing a high loft, nonwoven web 10, 10', 10" or 11.
  • the apparatus 34 is shown being oriented in a horizontal configuration, although it couid be arranged vertically or at some other angle relative to the vertical axis.
  • the high Soft, nonwoven web 10, 10 ' . 10" or 11 has a three dimensional structure with fibers oriented in the x, y and z directions.
  • the apparatus 34 includes a die 36 having a plurality of nozzles 38 each emitting, ejecting or extruding a filament 40. Each of the plurality of nozzles 38 has a distal
  • the apparatus 34 uses air or gas to facilitate movement and drawing of the molten polymer from the plurality of nozzles 38 into a plurality of filaments.
  • a pair of moving surfaces, 44 and 46 is located from between about 10 centimeters (cm) to about 150 cm; of the distal end 42 of each of the plurality of nozzles 38.
  • the pair of moving surfaces, 44 and 46 can be a first rotatable drum 48 and a second rotatable o drum 50, as is shown in Fig. 7.
  • the pair of moving surfaces, 44 and 46 can be a first conveyor belt 52 and a second conveyor belt 54, as is shown in Fig. 8.
  • Other forms of moving surfaces, 44 and 46 known to those skilled in the art can also be employed.
  • the first rotatable drum 48 wili have a diameter ci
  • the second rotatable drum 50 will have a diameter d 2
  • the diameter d ⁇ is approximateiy equai to the diameter d 2.
  • the diameters s and d 2 are identical.
  • the first and second rotatabie drums, 48 and 50 respectively, will be aligned parallel to one another on the same plane X -Xi. It should be
  • the apparatus 34 is horizontally oriented so that the filaments 40 will move from left to right in a machine direction ( D) between the first and second rotatabie drums, 48 and 50 respectively.
  • the speed of the first and second rotatable drums, 48 and 50 respectively can vary. Desirably, each of the first and second rotatable drums, 48 and 50 respectively, wiii rotate at the same speed. Alternatively, one of the first and second rotatable drums, 48 and 50 respectively, o could rotate at a different speed than the other drum and therefore a different cross- sectional structure may be produced in the machine direction such as S or S-like shape.
  • the speed of the first and second rotatabie drums, 48 and SO respectively should be adjusted according to the basis weight of the material that is being produced, the thickness of the desired web 10, the kind of polymer being extruded,
  • the first and second rotatable drums, 48 and 50 respectively can be operated at room temperature.
  • the first and second rotatable drums, 48 and 50 respectively couid be operated at an e!evated temperature or at a temperature below room temperature.
  • the first and second rotatabie drums, 48 and 50 respectively are operated at room temperature.
  • the first and second rotatabie drums. 48 and 50 respectively can be hollow cylinders with their outer peripheries covered with a forming wire or screen.
  • the forming wire or screen can be produced from a variety of different materials known to those skilled in the art.
  • the forming wire or screen could be made from a synthetic material, such as polyethylene terephthalaie (PET).
  • PET polyethylene terephthalaie
  • the forming wire or screen could be made from: metal, steel, aluminum, a plastic, a thermoplastics, etc.
  • the first and second rotatabie drums, 48 and 50 respectively, couid also be constructed out of various materials, such as wood, steel, cast iron, aluminum, etc.
  • the metal belts couid be ferrous or non-ferrous.
  • the metal belts could contain a plurality of apertures, openings or holes arranged in a predetermined pattern or couid be randomly arranged. The size and shape of the apertures, openings or holes can vary.
  • each of the first and second rotatabie drums, 48 and 50 respectively can be equipped with adjustable vacuum chamber, if desired.
  • the open mesh design of a wire, screen or a metal belt containing apertures, openings or holes can form a specific texture or pattern onto the outer surfaces of the high loft, nonwoven web 10, 10', 10" or 11 that is being produced.
  • Such texture or pattern may enhance the sound insulation and/or thermal absorption properties of the finished web 10, 0', 10" or 11 This is an important attribute when the finished high loft, nonwoven web 1Q, 10 ⁇ 10" or 11 is to be used for sound and/or thermal insulation purposes.
  • each of the first and second rotatabie drums, 48 and 50 respectively has a centra! axis 58 and 58, respectively.
  • each of the central axes 56 and 58 are aligned on a common vertical p!ane, designated X-p- X-s
  • X-p- X-s A horizontal distance measured from the distal end 42 of each nozzle 38 perpendicular to the vertical plane X ⁇ -X, established a Die-to- Co!iector Distance (DCD).
  • This DCD distance can range from between about 10 cm to about 150 cm. Desirabiy, the DCD distance is less than about 100 cm. IViore desirably, the DCD distance is less than about 90 cm.
  • the DCD distance is less than about 80 cm. Most desirabiy, the DCD distance is less than about 60 cm.
  • the exact DCD distance is dependent upon a number of factors inducing but not limited to: the rneit temperature of the poiymer being extruded, the polymer throughput through the plurality of nozzles 38, etc. However, it has been found through experimentation, that the closer the moving surfaces 44 and 46 are !ocated from the distal end 42 of each of the piuraiity of nozz!es 38, the better the recovery value of the manufactured high Soft, nonwoven web 10, 10', 10" or 1 1 is after compression. When the DCD distance ranges from between about 45 em to about 75 cm, a high Soft, nonwoven web 10, 10', 10" or 11 can be manufactured with a good recovery value after compression.
  • the outer peripheries of the first and second rotatable drums, 48 and 50 respectively, are spaced apart from one another thereby creating a convergence passage 60,
  • convergent passage it is meant a point of converging, to approach a point.
  • This converging passage 60 narrows down to a dimension equal to a nip 62 established between the first and second rotatable drums, 48 and 50 respectively.
  • the nip 82 can vary in dimension.
  • the first and second rotating drums, 48 and SO respectively, should be mounted such that the dimension of the nip 62 established therebetween can be easily adjusted. Generally, the nip 62 can range from between about 0,5 cm to about 25 cm.
  • the nip 62 is greater than about 0,5 cm, More desirably, the nip 62 ranges from between about 0,5 cm to about 10 cm. Even more desirably, the nip 62 ranges from between about 0.5 cm to about 8 cm. Most desirably, the nip 62 is less than about 5 cm.
  • the convergent passage 80 has an entry 64 and an exit 88 established by the circumference of the first and second rotatable drums, 48 and 50 respectively.
  • the piuraiity of filaments 40 are deposited at the entry 64 of the convergent passage 60 they are directed and routed onto and between the pair of moving surfaces 44 and 46.
  • the routing i facilitated by the rotation of the first and second rotatable drums, 48 and 50 respectively.
  • the routing causes the piuraiity of filaments 40 to pass through the convergent passage 60 in descending travel from the entr 64 to the exit 66.
  • the rotational movement of the first and second rotatable drums, 48 and 50 respectively, will cause some of the plurality of filaments 40 to temporarily contact the outer peripheries of the first and second rotatable drums, 48 and 50 respectively.
  • These filaments 40 will be compressed against the remaining filaments 40 passing through the nip 62 to create a 3-dimertsionai structure 68.
  • the piuraiity of filaments 40 will be compressed at the nip 62 and this confined space helps the filaments 40, which are transformed into fibers 12 as they coo!, to be aligned in the x, y and z directions.
  • Transformed it is meant to change markedly the appearance or form of; to change the nature, function, or condition of; convert.
  • a 3-dimensionai structure 68 is produced instead of a 2-dimensionai structure.
  • the 3-dimensional structure $8 usually wiil not have a very good recovery vaiue unless fiber-to-fiber bonds are created using some known bonding process to stabilize the formed 3- dimensional structure 68.
  • the 3-dimensiona! structure 88 is advanced in the machine direction (MD) in a horizontal direction.
  • a conveyor belt 70 can be utilized.
  • the conveyor belt 70 can be constructed with a screen having a porous o open pattern to allow heat to pass therethrough freeiy.
  • the conveyor belt 70 can move in a given direction over a plurality of rollers 72.
  • Four rollers 72 are depicted in Fig. 7, although any number of rollers 72 can be utilized.
  • One of the rollers 72 is the drive roller and the remaining rollers 72, 72 and 72 are idler or follower roilers.
  • the conveyor belt 70 makes a continuous loop and is illustrated moving in a clockwise direction so as to advance the 3-dimensional structure 68 in the downward machine direction (WD).
  • nonwoven webs 10 can be formed from certain materials and for certain uses, wherein bonding is not necessary. However, for most high loft, nonwoven webs 10, it is advantageous to subject the 3- dimensional structure 68 to a bonding process. Bonding generally imparts strength and integrity into the finished web 10. Various bonding techniques can be utiSized. A single bonder or a pair of oppositely aligned bonders can be utilized.
  • a bonder 74 is shown located downstream of and in vertically aiignment with the pair of moving surfaces 44 and 46 for bonding the 3- dimenslonal structure 68.
  • the bonder 74 Is located such that the 3-dimensional structure 68 passes therethrough.
  • the bonder 74 can be a thermal bonder, such as: a through air bonder or an oven bonder.
  • a thermal bonder can function by creating heat.
  • the heat can be created by a heated fluid, such as gases or liquid, burning a solid, such as coal, heating inert gases, using steam, using secondary radiation from nanoparticies, using infra-red heat, etc.
  • the bonder 74 itself ca include a furnace, an oven, thermoelectric elements, etc., or any combination thereof, in addition, the bonder 74 can be a chemical bonder, a mechanical bonder, a hydro-mechanical bonder, needle bonder, a wet bonder, etc.
  • the heat from a thermal bonder will lock some of the fibers 12 to one another in the x, y and z directions. Aii the fibers 12 do not have to be bonded together, just enough to create the high loft, nonwoven web 10.
  • the fibers 12 are created as the p!ura!ity of filaments 40 solidify in the 3-dimensional structure 68, By bonding some of the plurality of fibers 12 together, a high Soft, nonwoven web 10 is create having a thickness of less than about 250 mm, desirably, less than about 200 mm, and more desirably, less than about 100 mm.
  • the high loft, nonwoven web 10 also has a basis weight ranging from between about 50 g/m 3 to about 3,000 g/m* desirably, from between about 100 g/m 2 to about 2,000 g/m 2 , and more desirably, from between
  • a vertical cross-section of the web 10 when taken parallel to its machine direction, exhibits a plurality of snugly stacked, approximately V, U, or C-shaped structures 24.
  • Each of the approxirrtateiy V, U or C- shaped structures 24 has an apex 26 facing in the machine direction, in other words, the approximately V or U shaped structure is rotated 90 degrees to a horizontal o orientation with the apex of each facing to the right.
  • the C-shaped structure is reversed in position so that the apex of each faces to the right.
  • This high loft, nonwoven web 10 has a recovery value ranging from between about 20% to about 99% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes, according to 1ST 120,2 (01 ).
  • the 1ST 120,2 (01 ) test requires the material
  • the high loft, nonwoven web 10 has a recovery value ranging from between about 30% to about 95% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes, according to 1ST 120.2 (01 ).
  • the high loft, nonwoven web 10 has a recovery vaiue ranging from between about 40% to
  • the high loft, nonwoven web 10 has a recovery vaiue ranging from between about 50% to about 80% after being compressed under a pressure of 0,25 psi for a time period of 30 minutes, according to iST 120.2 (01 ).
  • the apparatus 34 may further include one or more dispensing mechanisms 78 and 78 for adding chemical binders, or dispensing one or more additives 80 to the high loft, nonwoven web 10.
  • Two dispensing mechanisms 76 and 78 are illustrated in Fig. 7.
  • Chemical bonding system can be utilized instead of the thermai bonding systems.
  • Chemica! binders may impart some new features to o the web such as different surface chemistry, more stiffness or roughness.
  • the exact number of dispensing mechanisms can vary.
  • one or two dispensing mechanisms 76 or 78 are utilized to add one or more additives to the high Soft, nonwoven web 10,
  • the additive SO can be any of those described above, as well as others known to those skilled in the art.
  • the high loft, nonwoven web 10 could also be partially or fully immersed in a liquid solution containing an additive 80.
  • the liquid soiution could be c emica!iy or electrically charged so as to cause the additive 80 to better adhere to the high loft, nonwoven web 10,
  • the apparatus 34 may also include a conditioning unit 82 situated downstream from the last dispensing mechanism 78 or 78.
  • the conditioning unit 82 situated downstream from the last dispensing mechanism 78 or 78.
  • conditioning unit 82 can vary in design and function.
  • the conditioning unit 82 could be a dryer that can remove moisture from the web 10 by utilizing heat or some other process when the high loft, nonwoven web 10 has to be dried.
  • the conditioning unit 82 could be a cooler that could blow cool air onto the high loft, nonwoven web 10 and reduce its temperature.
  • the conditioning unit 82 o could perform some other function, for example embossing the web 10, printing the web 10, combining the high loft, nonwoven web 10 with another layer, etc. Dryers and coolers are appliances well known to those skilled in the art.
  • FIG. 8 another embodiment of an apparatus 34' is depicted wherein the pair of moving surfaces 44 and 46 is shown as a first conveyor belt 52
  • the orientation of the apparatus 34' is vertical although other orientations cou!d also be employed.
  • the first conveyor belt 52 moves in a counterclockwise direction while the second conveyor belt S4 moves in a clockwise direction. This arrangement causes the plurality of filaments 40 emitted, ejected or extruded from the plurality of nozzles 38 to move vertically downward in a
  • the first and second conveyor beits, 52 and 54 respectively can run at various speeds. Desirably, the first and second conveyor belts, 52 and 54 respectively, will run at the same speed.
  • the first and second conveyor belts, 52 and 54 respectively, converge toward one another at a point located farthest away from the distal end 42 of each of said
  • An opening 55 equivalent to the nip 82, is present between the first and second conveyor belts 52 and 54 respectively.
  • the opening 55 occurs and is situated at a plane Xr ⁇ X a.
  • the plane X 2 - ⁇ X 2 is equivalent to the plane X-r-X-i, shown in Fig. 7.
  • a vertical distance measured from the distal end 42 of each nozzle 38 perpendicular to the plane X S ⁇ X 2 established a Die-to-Coliec!or Distance (DCD), o This DCD distance can range from between about 10 cm to about 150 cm.
  • DCD Die-to-Coliec!or Distance
  • the DCD distance is less than about 100 cm. More desirably, the DCD distance is less than about 90 cm. Even more desirably, the DCD distance is less than about 80 cm. Most desirably, the DCD distance is less than about 60 cm. The exact DCD distance is dependent upon a number of factors including but not limited
  • the first and second conveyor be!ts, 52 and 54 respectively are aligned at an angle alpha (a) to one another.
  • the angle a can vary. Desirably, the angie a is less than about 90 degrees. More desirably, the angle o is less than about 60 degrees. Even more desirably, the angle a is less than about 50
  • the angle a is less than about 45 degrees.
  • An angle a of from between about 15 degrees to about 45 degrees works welt. This orientation creates a convergent passage 60 and a nip 62.
  • the plurality of filaments 40 are deposited at the entry 64 of the convergent passage 60 as they are directed and routed onto and between the first and second conveyor belts, 52 and 54 respectively.
  • the routing is facilitates by the movement of the first and second conveyor belts, 52 and 54 respectively.
  • the routing causes the plurality of filaments 40 to pass through the convergent passage 60 in descending travel from the entry 64 to the exit 66.
  • the movement of the first and second conveyor be!ts, 52 and 54 respectively, will cause some of the plurality of filaments 40 to temporarily contact the outer peripheries of
  • a 3-dimensionai structure 68 is produced instead of a 2-dimensional structure.
  • the 3-dimensionai structure 68 usually will not have a very good recovery value unless fiber-to-fiber bonds are created using some known bonding process to stabilize the formed 3-dimensionai structure 68.
  • the apparatus 34' also differs from the apparatus 34, shown in Fig. 7, in that the 3-dimensionai structure 68 is advanced in a verticai, downward direction until i contacts a conveyor beii 84.
  • the conveyor beii 84 is positioned perpendicular to the downward direction of the 3-dimensionai structure 68.
  • the conveyor belt 84 moves through a continuous loop in a clockwise direction.
  • the o conveyor belt 84 causes the 3-dimensiona! structure 68 to make a 90 degree turn to the right. This new horizontal, rightward movement is referred to as machine direction (MD ).
  • MD machine direction
  • the conveyor belt 84 is mounted on a plurality of rollers 86, Four rotters 86 are depicted in Fig, 8 although any number of roliers 86 can be utilized.
  • One of the 5 rollers 86 is the drive roller and the remaining roliers 86, 86 and 88 are idier or follower rollers.
  • St should be understood that some high loft, nonwoven webs 10 can be formed from certain materials and for certain uses, wherein bonding is not necessary. However, it is advantageous when producing most nonwoven webs 10 to subject the 3-dimensfonaf structure 88 to a bonding process. Bonding generally imparts strength and integrity into the finished web 10.
  • Various bonding techniques can be utilized, in Fig. 8, a single bonder 74 is utilized. Upon exiting the bonder 74, a high loft, nonwoven web 10 will be formed. The high loft, nonwoven web 10 has a thickness t.
  • FIG. 9 still another apparatus 34" is shown which utilized a combination of a first meitblown die 88, a spun bond die 90 and a second me!tbiown die 92.
  • the apparatus 34" is shown being oriented in a vertical configuration, although other configurations are possible.
  • the spunbond die 90 is positioned between the first and second meitblown dies, 88 and 32 respectively. This die arrangement produces a comingled, high !oft hybrid nonwoven web that may have different fiber size, different polymeric materials, and/or different fiber cross-section.
  • the Die-io-Coilecior Distance is calculated by the distance from the middle spunbond die 90 to the plane X -Xi. Again, this DCD distance can range from .between about 10 cm to about 150 cm. Desirably, the DCD distance is less than about 100 cm. More desirably, the DCD distance is less than about 90 cm. Even more desirably, the DCD distance is less than about 80 cm. Most desirably, the DCD distance is less than about 60 cm. The exact DCD distance is dependent upon a number of factors including but not limited to: the melt temperature of the polymer being extruded, the polymer throughput through the plurality of nozzles 38, etc.
  • a S-dimensionaS structure 68 emerges from the exit 66 of the convergent passage 60.
  • a bonder 74 is positioned downstream of the first and second rotaiable drums 48 and 50 respectively.
  • the bonder 74 can be any of the various kinds of bonders explained above. Desirably, the bonder 74 is a thermal or chemical bonder.
  • any of the three apparatuses 34, 34' or 34' ' described above that one couid add one or more features to them.
  • non- thermoplastic materials could also be added to the webs 10, 10 ⁇ 10 s or 11 during manufacture
  • one couid spin or extrude multi-component fibers, fibers having different cross-sectional diameters, use curly fibers within the webs 10, 0', 10' or 11 , or otherwise treat the fibers 12 is a particular way to obtain a unique finished high loft, nonwoven web 10, 10", 10" or 1 1.
  • the various processes such as me!tblown, spunbond, spunmeli, etc. may require that th filaments be attenuated at different temperatures, pressures, flow rates, etc.
  • the process air couid be colder or hotter than the polymer melt.
  • the process of forming the high Soft, nonwoven web 10, 10', 10" or 11 will be explains with reference to Figs, 7 - 9.
  • the process includes introducing a molten polymer to a die 36,
  • the die 36 has a plurality of nozzles 38 each having a distal end 42.
  • the molten polymer is emitted through the plurality of nozzles 38 to form a plurality of filaments 40.
  • emitting it is meant extruding, ejecting, spinning, forcing or discharging the molten polymer under pressure, in any of the known processes described above and/or known to those skilled in the art.
  • the process also includes using air or gas streams to facilitate movement and drawing of the plurality of filaments 30.
  • the filaments 40 are directed towards a pair of moving surfaces 44 and 46, located at a distance of from between about 10 cm to about 150 cm from the plurality of nozzles 38.
  • the pair of moving surfaces 44 and 48 can be first and second rotatabSe drums, 48 and 50 respectively, or can be first and second conveyor beits, 52 and 54 respectively.
  • the pair of moving surfaces 44 and 46 forms a convergent passage 60 having an entry 64 and an exit 68.
  • the plurality of filaments 40 are deposited into the entry 64 of the convergent passage 60.
  • the plurality of filaments 40 are then routed through the convergent passage 60 in descending travel from the entry 84 to the exit 6$ and between the pair of moving surfaces 44 and 46 in a machine direction to form a 3-dimensional structure 68.
  • the filaments 40 are transformed upon cooling into fibers 12 oriented in the x, y and z directions.
  • the process further includes bonding the 3-dimensional structure 68 to form a high loft, nonwoven web 10, 10', 10 * or 11 having a thickness t, t 3 ⁇ 4 or k of less than about 250 millimeters and a basis weight ranging from between about 50 g/tn 2 to about 3,000 g/m ?
  • the 3-dimensional structure 68 can be bonded using a variety of different bonders. Some bonders which can be used include but are not limited to: thermal bonding, through air bonding, oven bonding, chemical bonding, wet bonding, mechanical bonding or hydro-roechanica! bonding.
  • a vertical cross-section of the high loft, nonwoven web 10, 10', 10" or 1 1 when taken parallel to the machine direction (MD), exhibits a plurality of snugiy stacked, approximately V, U or C -shaped structures 24.
  • Each of the approximately V, U or C-shaped structure 24 has an apex 26 facing in the machine direction (MD).
  • the approximately V or U shaped structure is rotated 90 degrees to a horizontal orientation with the apex of each facing to the right.
  • the C-shaped structure is reversed in position so that the apex of each faces to the right.
  • the high loft, nonwoven web 10, 10 ⁇ 10" or 11 has a recovery value ranging from between about 20% to about 99% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes.
  • an additive 80 can be added to the high loft, nonwoven web 0, 10', 10 * or 11 downstream of the bonder 74.
  • the additive 80 can be any of those mentioned above.
  • the additive 80 can be deposited onto the high Soft, nonwoven web 10, 1G ⁇ 10" or 11 , or it could be sprayed thereon.
  • the high loft, nonwoven web 10, 10 ' , 10" or 1 1 could be immersed in a liquid solution containing an additive SO.
  • the high ioft, nonwoven web 10, 10', 0 " or 1 1 can be dried downstream of the bonder 74.
  • the high ioft, nonwoven web 10, 10', 10" or 1 1 couid be cooled downstream of the bonder 74, Such cooling could reduce the temperature of the high ioft, nonwoven web 10, 10', 10" or 1 1 to room temperature or thereabout.
  • a number of high ioft, rtortwovens sample webs were produced using a meitblowing piiot line that had a 381 mm meitblowing die with multi-row spinnerettes known as the Biax meitbiowing (MS) die.
  • This die is commercially available from Biax-Fiberfilm Corporation having an office ai N9S2 Quality Drive, Suite 8, Greenville, WS 54942.
  • the meitblowing spinnerettes had 242 polymer nozzles.
  • the inside diameter of each spinnerette was 0.5 ⁇ 8 mii!imeters (mm) while the outside diameter of each spinnerette was 0.711 mm.
  • Each poiymer nozzle was surrounded by an air nozzle where the blowing air was coming from the annular space between the poiymer nozzle and the air nozzle. Th diameter of each of the air nozzles was 1 .4 mm.
  • the Biax meitblowing (MB) die design is taught in U.S. Patent 5,476,616 and U.S. Patent Publication 2005/0056956 A , Typical commercial Biax meitblowing (MB) dies have from between about 8,000 to about 11 ,000 nozzles per meter.
  • the first seven (7) nonwoven web samples were made of polypropylene that was provided by Exxon-Mobii under the trade name: ACHIEVE 6338G1. This polypropylene had a typical melt flow rate of 1 ,550 grams per 10 minutes (according to ASTM test D 1238, 230 °C, 2.16 kg).
  • the last two (2) nonwoven web samples (samples 8 and 9) were made of poiy!actic acid that was provided by Naiureworks under the trad name: INGEO PLA 6202D, The poiy!actic acid had a melt flow rate of 15 grams (g) to 30 g per 10 minutes (according to AST test D 1238, 210 °C S 2.16 kg).
  • Polypropylene samples were fabricated at the following process conditions: Poly mer melt temperature: 190 °C
  • the basis weight of these samples varied from between about 150 g/m s to 500 g/m 2 by varying the speed of the first and second roiatabSe drums or by varying the speed of the first and second conveyor belts.
  • the Die to Collector Distance (DCD) varied between about 30 centimeters (cm) to about 45 cm.
  • the basis weight was around 500 g/m 2 and the Die-to-Collector Distance (DCD) was around 75 cm.
  • Some of the samples were thermally bonded using an infra-red oven at a temperature of 120 °C and the dwell time (contact time) was about 3 seconds to about 5 seconds.
  • Basis weight is defined as the mass per unit area and it can be measured in grams per meter squared (g/m 2 ).
  • the basis weight test is done according the INDA standard 1ST 130.1 which is equivalent to the ASTW standard ASTM D3778, Ten (10) different samples were die cut from different locations in a larger sample web and each one had an individual area equal to 100 cm*. The weight of each replicate was measured using a sensitive balance within ⁇ 0.1% of weight on the balance. The basis weight in grams/m 2 was measured by multiplying the average weight by 100. 3.2 T tickr>ess of ⁇
  • Thickness is defined as the distance between one surface and an opposite surface of a single web measured under a specified pressure.
  • the apparatus include a thickness testing instrument that had: an anvil, a presser foot, and a scale indicating the distance between these two parallel plates.
  • the foot presser was 305 mm x 305 mm ⁇ 12 inches x 12 inches) in size and had a weight of 288 grams.
  • Five representative specimens of the fabric were die cut and tested in the standard atmosphere for testing as prescribed in ASTM D1776. Sampies were handled carefully to avoid altering the naturai state of the fabric. Each specimen was placed on the bottom plate and the presser foot was placed with care on the top of the sample. The average thickness of these specimens is reported along with a standard deviation.
  • the presser foot was raised and the 288 gram weight was replaced with 16.33 Kg (36 pounds) to provide a pressure of 1720 Pa (0.25 ps .
  • the presser foot with the new weight was placed on top of the high loft, nonwoven webs sampies for 30 minutes and then the compressed thickness T2 was measured.
  • the presser foot was raised and replaced by the 36 pound weight with the 288 gram weight. After five (5) minutes, the presser foot was lowered to measure the thickness recovered, T3.
  • Sample 9 was also stronger than sample 8 during handling and had a better structure integrity as sample 9 was not faliing apart because of the fiber-io-fiber bonds that were created during the post heat treatment, it is well known that structural integrity of the loose fibers can be enhanced by using other bonding techniques, such as through air bonding or chemical bonding.

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  • Engineering & Computer Science (AREA)
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  • Nonwoven Fabrics (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
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WO2018117266A1 (ja) * 2016-12-22 2018-06-28 株式会社ダイセル 骨固定材
JPWO2018117265A1 (ja) 2016-12-22 2019-12-12 株式会社ダイセル 血液フィルター
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JP2017505390A (ja) 2017-02-16
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JP2020020088A (ja) 2020-02-06
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