WO2015100765A1 - 一种液晶显示装置及相应的制造方法 - Google Patents
一种液晶显示装置及相应的制造方法 Download PDFInfo
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- WO2015100765A1 WO2015100765A1 PCT/CN2014/070332 CN2014070332W WO2015100765A1 WO 2015100765 A1 WO2015100765 A1 WO 2015100765A1 CN 2014070332 W CN2014070332 W CN 2014070332W WO 2015100765 A1 WO2015100765 A1 WO 2015100765A1
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Classifications
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- G02F1/133757—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers with different alignment orientations or pretilt angles on a same surface, e.g. for grey scale or improved viewing angle with different alignment orientations
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- G02F1/133788—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation by light irradiation, e.g. linearly polarised light photo-polymerisation
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- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
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- G02F1/13394—Gaskets; Spacers; Sealing of cells spacers regularly patterned on the cell subtrate, e.g. walls, pillars
Definitions
- the present invention relates to the field of manufacturing thin film transistor liquid crystal display (TFT-LCD), and more particularly to a liquid crystal display device and a corresponding manufacturing method.
- TFT-LCD thin film transistor liquid crystal display
- FIG. 1 it is a schematic diagram of a conventional pixel electrode of a liquid crystal display device of a PSVA mode (Polymer Stabilization Vertical-Alignment); a pixel electrode is shown in the figure.
- the pixel electrode In the conventional liquid crystal display device of the PSVA mode, the pixel electrode is designed to have a "meter" shape, with an intermediate vertical trunk 80, a horizontal trunk 81 and an angle of ⁇ 45 degrees with the X axis, ⁇ 135
- the branch of degree 82 consists of three parts.
- the vertical trunk 80 and the horizontal trunk 81 divide the pixel area into four regions equally, and each region is composed of a tile 82 of oblique 45 degrees.
- FIG. 2 is a schematic diagram showing the reverse direction of the liquid crystal after applying a voltage to the pixel electrode of FIG. 1.
- FIG. 2 is a step of gradually applying the liquid crystal molecules 90 from the outside of the pixel electrode to the inner side after applying a voltage of 4 V to the pixel electrode of FIG. Dumped.
- the angle of the tilt is in the direction of the slit (i.e., in the direction of the branch 82, as indicated by the direction of the arrow in the figure), and the liquid crystal tilting directions of the four regions are ⁇ 45 degrees and ⁇ 135 degrees, respectively, all pointing to the central region of the pixel.
- the angle between the liquid crystal reversal and the X axis is: the first quadrant is -135 degrees, the second quadrant is -45 degrees, the third quadrant is 45 degrees, and the fourth quadrant is 135 degrees.
- the existing PSVA process is to improve the alignment of liquid crystal molecules by designing the pixel electrodes to be "meter" to improve the alignment of the liquid crystal molecules.
- the technical problem to be solved by the present invention is to provide a liquid crystal display device and a corresponding manufacturing method, which have a good alignment effect, and can improve the large-view character bias and increase the aperture ratio.
- the present invention provides a liquid crystal display device comprising: a TFT array substrate having a first electrode layer and a first alignment layer covering the first electrode layer, and a glass substrate on the TFT array substrate Forming a color film layer between the passivation layers, further comprising a black matrix and a spacer; the CF substrate having a second electrode layer and a second alignment layer covering the second electrode layer; and a liquid crystal layer disposed on the TFT array a first alignment layer of the substrate and a second alignment layer of the CF substrate; wherein the first alignment layer and the second alignment layer are each divided into at least one partition, and each partition is divided into a plurality of alignments a predetermined alignment direction of the alignment layer corresponding to the first alignment layer and the second alignment layer is perpendicular to each other; and different alignment regions of the first alignment layer and the second alignment layer are respectively used Irradiating the directionally linearly polarized light, the polarization direction of the linearly polarized light irradiated to each of the
- the black matrix is disposed on the passivation layer of the TFT array substrate; or is disposed on the glass substrate of the TFT array substrate, below the gate line; or a glass substrate disposed on the TFT array substrate Above, both sides of the gate line; or disposed between the color film layer of the TFT array substrate and the data line.
- the spacer is disposed on the black matrix; or is disposed on the passivation layer of the TFT array substrate.
- the material of the color film layer comprises any one of bone glue, acrylic, polyimide and polyester.
- the present invention also provides a liquid crystal display device comprising: a TFT array substrate having a first electrode layer and a first alignment layer covering the first electrode layer, and a glass substrate on the TFT array substrate Forming a color film layer between the passivation layers, further comprising a black matrix and a spacer; the CF substrate having a second electrode layer and a second alignment layer covering the second electrode layer; and a liquid crystal layer disposed on the TFT array a first alignment layer of the substrate and a second alignment layer of the CF substrate; wherein the first alignment layer and the second alignment layer are each divided into at least one partition, and each partition is divided into a plurality of alignments The first alignment layer and the alignment layer corresponding to the second alignment layer have a predetermined alignment direction perpendicular to each other; the each partition is divided into four alignment areas by two mutually
- the polarization direction of the linearly polarized light irradiated by each of the alignment regions is adapted to the alignment direction, thereby forming an alignment on the first alignment layer and the second alignment layer having a predetermined alignment direction corresponding to each alignment region Month.
- the invention also provides a method of manufacturing a liquid crystal display device, comprising the steps of:
- each partition includes a plurality of alignment regions, and the alignment layer corresponding to the first alignment layer and the second alignment layer is predetermined
- the alignment directions are perpendicular to each other;
- a spacer is disposed on the TFT array substrate.
- the TFT array substrate further includes: a glass substrate, a gate line, a semiconductor layer, and a data line.
- the black matrix is disposed on the passivation layer of the TFT array substrate; or is disposed on the glass substrate of the TFT array substrate, below the gate line; or on the glass substrate of the TFT array substrate, two of the gate lines Side; or disposed between the color film layer of the TFT array substrate and the data line.
- the material of the color film layer comprises any one of bone glue, acrylic, polyimide and polyester.
- the spacer is disposed on the black matrix; or is disposed on the passivation layer of the TFT array substrate.
- a specific alignment direction alignment layer is formed, without
- the pixel electrode is specially designed to avoid dark streaks caused by the pixel electrode in the prior art, thereby improving the transmittance of light;
- the predetermined alignment direction of each of the alignment regions in the first alignment layer and the predetermined alignment direction of each of the alignment regions in the second alignment layer can be flexibly set. , can flexibly realize the alignment of four regions in each pixel structure in the liquid crystal cell, and at the same time, can improve the bias of the big view;
- a black matrix is disposed on the TFT array substrate, which can prevent a problem that the aperture ratio of the pixel region is reduced due to misalignment between the TFT array substrate and the CF substrate;
- the spacer is disposed on the TFT array substrate, which can prevent dark lines between the TFT array substrate and the CF substrate due to misalignment, and avoid misalignment;
- the color film layer can be used as an insulating layer to remove the insulating layer usually placed on the upper and lower surfaces of the color film layer, thereby achieving the effect of reducing cost and increasing productivity.
- FIG. 1 is a pixel electrode of a conventional liquid crystal display device of a PSVA mode
- FIG. 2 is a schematic view showing the reverse direction of the liquid crystal after applying a voltage to the pixel electrode of FIG. 1;
- FIG. 3 is a schematic diagram of a pixel structure in an embodiment of a liquid crystal display device according to the present invention.
- FIG. 4 is a cross-sectional view taken along line A-A of FIG. 3 in an embodiment of a liquid crystal display device according to the present invention
- FIG. 5 is a schematic diagram showing a partition of a TFT array substrate in a first embodiment of the alignment principle of a liquid crystal display device according to the present invention
- FIG. 6 is a schematic diagram showing a partition of a CF substrate in a first embodiment of the alignment principle of a liquid crystal display device according to the present invention
- FIG. 7 is a schematic view showing linearly polarized light irradiation of a CF substrate in a first embodiment of the alignment principle of a liquid crystal display device according to the present invention
- FIG. 8 is a schematic diagram showing the results of liquid crystal alignment in the first embodiment of the alignment principle of a liquid crystal display device provided by the present invention.
- FIG. 9 is a schematic diagram showing the partitioning of a TFT array substrate in a second embodiment of the liquid crystal display device according to the present invention.
- FIG. 10 is a schematic diagram showing the partitioning of a CF substrate in a second embodiment of the alignment principle of a liquid crystal display device according to the present invention.
- FIG. 11 is a schematic view showing the liquid crystal alignment result in the second embodiment of the liquid crystal display device according to the present invention.
- FIG. 12 is a schematic diagram showing the partitioning of a TFT array substrate in a third embodiment of the alignment principle of a liquid crystal display device according to the present invention.
- FIG. 13 is a schematic diagram showing the partitioning of a CF substrate in a third embodiment of the alignment principle of a liquid crystal display device according to the present invention.
- FIG. 14 is a schematic view showing the liquid crystal alignment result in the third embodiment of the alignment principle of the liquid crystal display device provided by the present invention.
- FIG. 15 is a cross-sectional view showing another embodiment of a liquid crystal display device according to the present invention
- FIG. 16 is a cross-sectional view showing still another embodiment of a liquid crystal display device according to the present invention.
- FIG. 3 and FIG. 4 are schematic diagrams showing the structure of an embodiment of a liquid crystal display device according to the present invention.
- the liquid crystal display device includes:
- the TFT array substrate 1 has a first electrode layer 15 and a first alignment layer 19 covering the first electrode layer 15, and a color film layer 18 is formed between the glass substrate 11 and the passivation layer 180 of the TFT array substrate, and is also provided with black.
- CF Color Filter
- the liquid crystal layer 3 is disposed between the first alignment layer 19 of the TFT array substrate 1 and the second alignment layer 29 of the CF substrate 2;
- the first alignment layer 19 and the second alignment layer 29 are each divided into at least one partition, each partition is divided into a plurality of alignment regions, and the first alignment layer 19 and the second alignment layer 29 correspond to an alignment region thereof.
- the alignment directions are perpendicular to each other;
- the respective alignment regions of the first alignment layer 19 and the second alignment layer 29 are respectively irradiated with linearly polarized light of different directions, and the polarization direction of the linearly polarized light irradiated for each alignment region is adapted to the alignment direction, thereby An alignment layer 19 and a second alignment layer 29 are formed with alignment axes having a predetermined alignment direction corresponding to the respective alignment regions.
- each partition 10 Divided into four alignment zones 100 by two mutually perpendicular dividing lines (only one partition 10 is shown divided into four alignment zones in the figure, here only for example), wherein each alignment zone 100 is There is a predetermined alignment direction (shown by the arrow in the figure), and the predetermined alignment direction of at least two alignment areas 100 in one partition 10 is not the same. In the same manner, the predetermined alignment direction of the two alignment areas 100 on the left side is upward, and the predetermined alignment direction of the two alignment areas 100 on the right side is downward.
- the second alignment layer of the CF substrate 2 is divided into a plurality of partitions 20, and each of the partitions 20 further includes a plurality of alignment regions 200.
- each of the partitions 20 is perpendicular to each other.
- the dividing line is divided into four alignment zones 200, wherein each alignment zone 200 is predetermined to have an alignment direction (shown by an arrow in the figure), and a predetermined alignment of at least two alignment zones 200 in one zone 20 The directions are different, wherein the predetermined alignment direction of the two alignment areas 200 on the upper side is rightward, and the predetermined alignment direction of the two alignment areas 200 on the lower side is leftward.
- each of the alignment regions 100 of the first alignment layer and the alignment regions 200 corresponding to the second alignment layer have a predetermined alignment direction perpendicular to each other.
- FIG. 7 shows a case where the ultraviolet light is irradiated to the lower alignment region 200 in one of the sections 20 of the second alignment layer of the CF substrate 2 in FIG.
- the direction of the arrow is the direction of illumination of the linearly polarized light
- the horizontal line of the black line indicates the polarization direction of the linearly polarized light.
- the polarization direction of the linearly polarized light and the partition 20 of the second alignment layer are required to be ensured.
- the predetermined alignment direction of the lower alignment region 200 is adapted (e.g., the same) so that the alignment region 200 can be formed into an alignment film having a predetermined alignment direction by irradiation of linearly polarized light.
- FIG. 8 a schematic diagram of liquid crystal alignment results in a first embodiment of a liquid crystal display device provided by the present invention is shown.
- the first electrode on the TFT array substrate and the second electrode on the CF substrate are energized by the steps to complete the alignment of the liquid crystal molecules in the liquid crystal cell. Since the respective alignment regions 100 of the first alignment layer are perpendicular to the predetermined alignment direction of the alignment regions 200 on the corresponding second alignment layer, the liquid crystal cell can be made under the action of the first alignment layer and the second alignment layer.
- the liquid crystal molecules corresponding to the respective alignment regions are reversed to complete the alignment.
- a schematic diagram of the alignment of liquid crystal molecules corresponding to one of the partitions in FIGS. 5 and 6 is shown in FIG.
- the liquid crystal molecules finally in the third quadrant form an a degree angle with the X axis, and the liquid crystal molecules in the first quadrant form an angle of -a degrees with the X axis,
- the liquid crystal molecules in the second corner limit form an (a-180) degree angle with the X-axis, and the liquid crystal molecules in the fourth corner limit form a (180-a) degree angle with the X-axis, thereby improving the large-view character. Partial problem.
- the alignment of the liquid crystal molecules at other partitions is similar.
- a second embodiment of the present invention is shown.
- the predetermined alignment direction of the upper two alignment areas 100 is downward, and the predetermined alignment direction of the lower two alignment areas 100 is In the corresponding partition 20 of the second alignment of the CF substrate 2, the predetermined alignment direction of the right two alignment areas 200 is to the left, and the predetermined alignment direction of the two left alignment areas 200 is to the right;
- the liquid crystal molecules in the region corresponding to the liquid crystal display device are both oriented toward the center position after the end of the alignment (see FIG. 11), wherein the liquid crystal molecules at the first quadrant form an angle c with the X axis.
- a third embodiment of the present invention is shown.
- the predetermined alignment direction of the right alignment areas 100 on the right side is rightward, and the predetermined alignment direction of the two alignment areas 100 on the left side is To the left;
- the predetermined alignment direction of the upper two alignment regions 200 is upward, and the predetermined alignment direction of the lower two alignment regions 200 is downward;
- the liquid crystal molecules in the region corresponding to the liquid crystal display device are far from the center position after the end of the alignment (see FIG. 14), wherein the liquid crystal molecules at the first quadrant form an angle b with the X axis.
- the predetermined alignment directions of the respective alignment regions in the respective sections of the first alignment layer can also be adjusted as needed.
- the first electrode layer 15 is a pixel electrode layer; and the second electrode layer 24 is a common electrode layer.
- each partition size of the alignment layer may correspond to the size and position of one pixel structure of the TFT array substrate 1.
- the TFT array substrate 1 further includes:
- a semiconductor layer 17 is disposed above the gate line 13
- a data line 12 for forming a drain and a source is disposed on the semiconductor layer 17, and then a passivation layer 180 is disposed thereon, in the passivation layer 180 A pixel electrode 15 is formed thereon, and the first alignment layer 19 is disposed above the pixel electrode 15.
- the color film layer 18 In order to planarize the upper and lower surfaces of the liquid crystal cell (liquid crystal layer), it is necessary to arrange the color film layer 18 between the glass substrate 11 of the TFT P train substrate 1 and the passivation layer 180. By selecting an appropriate color film material, the color film layer 18 can be used as an insulating layer to remove the insulating layer usually placed on the upper and lower surfaces of the color film layer 18, thereby achieving the effect of reducing cost and increasing productivity.
- Color film materials include bone glue, acrylic, polyimide, polyester and the like.
- the CF substrate 2 specifically includes: a glass substrate 21 and a common electrode layer 24 overlying the glass substrate 21; wherein the second alignment layer 29 is disposed on the common electrode layer 24.
- the liquid crystal layer 3 specifically includes liquid crystal molecules (not shown) and a spacer 30.
- the black matrix 22 is provided on the TFT array substrate.
- the black matrix 22 is disposed on the passivation layer 180 of the TFT array substrate 1, and the black matrix is not disposed on the CF substrate 2.
- Figure 15 is a cross-sectional view showing another embodiment of a liquid crystal display device according to the present invention.
- the black matrix is 22 is disposed on the glass substrate 1 of the TFT P train substrate 1 below the gate line 13; and no black matrix is disposed on the CF substrate 2, and other structures are the same as those in the embodiment shown in FIG.
- the description of FIG. 4 can be referred to together.
- Figure 16 is a cross-sectional view showing still another embodiment of a liquid crystal display device according to the present invention.
- the main difference from the embodiment shown in FIG. 4 is that, in this embodiment, the black matrix 22 is disposed on the glass substrate 1 of the TFT array substrate 1 on both sides of the gate line 13; On the other hand, the black matrix is not provided on the CF substrate 2.
- the other structure is the same as that of the embodiment shown in Fig. 4. It will not be described in detail here, and the description of Fig. 4 can be referred to together.
- the black matrix 22 can be disposed at other positions of the TFT array substrate 1 as needed.
- the black matrix 22 can be disposed on the color film layer 18 of the TFT array substrate 1. Between data lines 12. The position of the setting can be referred to the above description, and the same effect can be achieved, so it will not be described here.
- the present invention also provides a photo spacer 30 on the TFT array substrate 1.
- the spacer 30 is disposed on the black matrix 22.
- the spacers are disposed on the passivation layer 180.
- the purpose of disposing the spacer 30 (Photo spacer) on the TFT P train substrate 1 is to prevent the CF substrate 2 from being displaced from the TFT array substrate 1 to cause a disclination line of the pixel region. Since the height of the spacer 30 is large, the flatness in the liquid crystal cell in the vicinity thereof is changed to cause poor alignment.
- the spacer 30 is disposed outside a certain distance from the display area, but if the spacer 30 is placed on the CF substrate 2, when the CF substrate 2 and the TFT array substrate 1 are misaligned, the spacer 30 may enter the TFT P car.
- the display area of the column substrate 1 causes poor alignment (dark lines are caused by poor alignment of the liquid crystal).
- the spacer 30 can be in contact with the CF substrate 2 or can be kept at a certain distance.
- FIG. 17 is a schematic diagram showing the main flow of an embodiment of a method for manufacturing a liquid crystal display device according to the present invention.
- the manufacturing method includes the following steps:
- Step S10 providing a TFT array substrate and a CF substrate, forming a color film layer between the glass substrate and the passivation layer of the TFT array substrate, and coating a polarization sensitive material on the first electrode layer of the TFT array substrate to form a first alignment layer Applying a polarization sensitive material on the second electrode layer of the CF substrate to form a second alignment layer;
- Step S11 dividing the first alignment layer and the second alignment layer into at least one partition, each partition includes a plurality of alignment regions, and the alignment directions corresponding to the first alignment layer and the second alignment layer have a predetermined alignment direction perpendicular to each other;
- Step S12 the respective alignment regions of the first alignment layer and the second alignment layer are respectively irradiated with linearly polarized light of different directions, and the polarization direction of the linearly polarized light irradiated for each alignment region is adapted to the alignment direction, thereby An alignment layer and a second alignment direction form an alignment moon having a predetermined alignment direction corresponding to each alignment region;
- Step S13 energizing the first electrode layer on the TFT array substrate and the second electrode layer on the CF substrate to complete alignment of the liquid crystal molecules in the liquid crystal cell;
- Step S14 the black matrix is disposed on the TFT array substrate
- Step S15 the spacer is disposed on the TFT array substrate.
- the black matrix is disposed on the passivation layer of the TFT array substrate; or is disposed on the glass substrate of the TFT array substrate, below the gate line; or is disposed on the TFT array
- the glass substrate of the substrate is on both sides of the gate line; or is disposed at other positions on the TFT array substrate, for example, between the color film layer and the data line of the TFT array substrate.
- step S15 the spacer is disposed on the black matrix; or is disposed on the passivation layer of the TFT array substrate.
- the color film layer is disposed in the TFT array substrate, so that the upper and lower surfaces of the liquid crystal cell can be planarized, so that a better alignment effect can be obtained in step S13.
- the color film layer can be used as an insulating layer function, thereby removing the insulating layer usually placed on the upper and lower surfaces of the color film layer, thereby achieving the effect of reducing cost and increasing productivity.
- Color film materials include bone glue, acrylic, polyimide, polyester and the like.
- the first electrode layer 15 is a pixel electrode layer; and the second electrode layer 24 is a common electrode layer.
- each partition size of the alignment layer may correspond to the size and position of one pixel structure of the TFT array substrate 1.
- a specific alignment direction alignment layer is formed, without
- the pixel electrode is specially designed to avoid dark streaks caused by the pixel electrode in the prior art, thereby improving the transmittance of light;
- the predetermined alignment direction of each of the alignment regions in the first alignment layer and the predetermined alignment direction of each of the alignment regions in the second alignment layer can be flexibly set. , can flexibly realize the alignment of four regions in each pixel structure in the liquid crystal cell, and at the same time, can improve the large-view role bias;
- a black matrix is disposed on the TFT array substrate, which can prevent a problem that the aperture ratio of the pixel region is reduced due to misalignment between the TFT array substrate and the CF substrate;
- the spacer is disposed on the TFT array substrate, which can prevent dark lines between the TFT array substrate and the CF substrate due to misalignment, and avoid misalignment;
- the color film layer can be used as an insulating layer function, thereby removing the insulating layer usually placed on the upper and lower surfaces of the color film layer, thereby achieving cost reduction and productivity improvement. fruit.
- the upper and lower surfaces of the liquid crystal cell can be flattened, and the effect of liquid crystal alignment can be improved.
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Abstract
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JP2016542712A JP2017500613A (ja) | 2013-12-31 | 2014-01-08 | 液晶表示装置及びその製造方法 |
US14/234,388 US9229278B2 (en) | 2013-12-31 | 2014-01-08 | Liquid crystal device and the manufacturing method thereof |
GB1610680.9A GB2535942B (en) | 2013-12-31 | 2014-01-08 | Liquid crystal device the manufacturing method thereof |
RU2016125807A RU2664289C1 (ru) | 2013-12-31 | 2014-01-08 | Жидкокристаллическое устройство и способ его изготовления |
KR1020167020860A KR20160106105A (ko) | 2013-12-31 | 2014-01-08 | 액정 표시장치 및 그 제조방법 |
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AU2015274635B2 (en) * | 2014-06-13 | 2018-04-19 | Gilead Sciences, Inc. | Phosphatidylinositol 3-kinase inhibitors |
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CN103728781A (zh) * | 2013-12-31 | 2014-04-16 | 深圳市华星光电技术有限公司 | 一种液晶显示器及其制造方法 |
CN104317111A (zh) * | 2014-10-14 | 2015-01-28 | 深圳市华星光电技术有限公司 | 液晶显示面板 |
CN104570495B (zh) * | 2015-01-29 | 2017-09-29 | 深圳市华星光电技术有限公司 | 液晶显示面板的制作方法 |
CN104678666A (zh) * | 2015-03-19 | 2015-06-03 | 京东方科技集团股份有限公司 | 显示面板及其制备方法 |
KR102304983B1 (ko) * | 2015-04-28 | 2021-09-27 | 삼성디스플레이 주식회사 | 액정 표시 장치 |
CN105182625A (zh) * | 2015-09-28 | 2015-12-23 | 京东方科技集团股份有限公司 | 一种显示基板及其制作方法和显示装置 |
KR102420398B1 (ko) * | 2015-11-24 | 2022-07-14 | 삼성디스플레이 주식회사 | 액정 표시 장치 및 그 제조방법 |
KR102388820B1 (ko) * | 2018-02-05 | 2022-04-21 | 삼성디스플레이 주식회사 | 표시 장치 |
KR102629598B1 (ko) | 2020-12-31 | 2024-01-29 | 서울대학교병원 | 암세포 전이능 측정 시스템 및 이를 이용한 암세포 전이능 측정 방법 |
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RU2664289C1 (ru) | 2018-08-16 |
GB201610680D0 (en) | 2016-08-03 |
US9229278B2 (en) | 2016-01-05 |
GB2535942A (en) | 2016-08-31 |
KR20160106105A (ko) | 2016-09-09 |
CN103728782A (zh) | 2014-04-16 |
RU2016125807A (ru) | 2018-01-10 |
JP2017500613A (ja) | 2017-01-05 |
GB2535942B (en) | 2021-04-21 |
US20150219968A1 (en) | 2015-08-06 |
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