WO2015099023A1 - 噴霧器 - Google Patents
噴霧器 Download PDFInfo
- Publication number
- WO2015099023A1 WO2015099023A1 PCT/JP2014/084276 JP2014084276W WO2015099023A1 WO 2015099023 A1 WO2015099023 A1 WO 2015099023A1 JP 2014084276 W JP2014084276 W JP 2014084276W WO 2015099023 A1 WO2015099023 A1 WO 2015099023A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- opening
- nozzle
- cosmetic liquid
- gas
- closing cover
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/16—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means
- B65D83/20—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means operated by manual action, e.g. button-type actuator or actuator caps
- B65D83/205—Actuator caps, or peripheral actuator skirts, attachable to the aerosol container
- B65D83/206—Actuator caps, or peripheral actuator skirts, attachable to the aerosol container comprising a cantilevered actuator element, e.g. a lever pivoting about a living hinge
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/06—Gas or vapour producing the flow, e.g. from a compressible bulb or air pump
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/28—Nozzles, nozzle fittings or accessories specially adapted therefor
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/05—Details of containers
- A45D2200/054—Means for supplying liquid to the outlet of the container
- A45D2200/057—Spray nozzles; Generating atomised liquid
Definitions
- the present invention relates to a sprayer capable of spraying a liquid such as a cosmetic liquid on a gas jet.
- Patent Document 1 This type of sprayer is disclosed in Patent Document 1.
- the cosmetic liquid is sucked up from the container by the negative pressure formed by the jet flow. Then, the sucked cosmetic liquid becomes mist from the cosmetic liquid nozzle and is discharged together with the jet flow.
- the present invention has been made by paying attention to such problems existing in the prior art.
- the object is to provide a sprayer which can obtain a fine mist spray.
- a gas nozzle for injecting a gas for injecting a gas, and an opening in a direction intersecting with the central axis of the gas nozzle within a range of an injection flow from the gas nozzle and a liquid supply source.
- a sprayer comprising a liquid nozzle connected to the liquid nozzle and sprayed by a gas jet flow from the gas nozzle, the diameter of the gas nozzle is made larger than the diameter of the liquid nozzle To do.
- a mist of a liquid such as a cosmetic liquid can be made fine, and the sprayer can be used comfortably.
- the perspective view which shows the sprayer of embodiment The front view which shows the state which pulled up the opening / closing cover of the sprayer.
- Sectional drawing which shows the internal structure of a sprayer.
- the perspective view which shows the upper structure of a sprayer.
- Sectional drawing which shows the positional relationship of a gas nozzle and a cosmetic liquid nozzle.
- the partially broken top view which shows the positional relationship of a gas nozzle and a cosmetic liquid nozzle.
- Sectional drawing which shows the front-end
- Sectional drawing which shows the front-end
- Sectional drawing which shows a spherical sealing member.
- the simplified diagram which shows the mechanism which locks opening and closing of a pushbutton, and shows the locked state of a valve
- the simplified diagram which similarly shows the unlocking state of a push button.
- the sectional side view which shows the mechanism which locks opening and closing of a push button, and shows the locked state of a valve
- the front sectional view which shows the mechanism which locks opening and closing of a push button, and shows the locked state of a valve
- the front sectional view which similarly shows the lock release state of a push button.
- the perspective view which shows an opening / closing cover.
- the side view which shows the mechanism which operates the sealing member of a liquid nozzle, and shows a sealing function state.
- the front sectional view which shows the mechanism which closes a cosmetic liquid nozzle. Sectional drawing which shows the seal
- FIG. 36 is a simplified cross-sectional view of a working cam portion showing a state operated from the state of FIG.
- the housing 11 of the sprayer has a main frame 12.
- a lower case 13 is detachably attached to the lower portion of the main frame 12 via a locking mechanism (not shown).
- a vertically long window 131 is formed through the front surface of the lower case 13, and a transparent plate 132 is provided inside the window 131.
- An upper frame 14 constituting a part of the housing 11 is attached to the upper portion of the main frame 12.
- an opening / closing cover 15 as an opening / closing member constituting a part of the housing 11 moves between a lower position indicated by a solid line in FIG. 1 and an upper position indicated by a solid line in FIG. It is installed as possible.
- the upper frame 14 is covered with an upper cover 141.
- a release button 16 is arranged on the front surface of the upper portion of the main frame 12.
- the release button 16 is pushed in, the locking state of the lower case 13 by the locking mechanism is released, and the lower case 13 can be detached from the main frame 12.
- a push button 17 as an operation member for spraying is disposed at the rear upper end of the upper frame 14.
- the push button 17 is rotatably supported on the inner surface of the upper cover 141 at the lower end of the push button 17.
- a discharge port 18 for discharging the spray to the outside is formed on the front surface of the upper frame 14.
- the discharge port 18 is closed by the opening / closing cover 15 when the opening / closing cover 15 is in the lower position, and is opened when the opening / closing cover 15 is in the upper position.
- the opening / closing cover 15 is in the lower position, the upper frame 14 is covered.
- the opening / closing cover 15 is regulated by a regulating structure (not shown) so as to be moved between a lower position indicated by a solid line in FIG. 1 and an upper position indicated by a two-dot chain line in FIG.
- a regulator 21 is fixed in the main frame 12, and an outlet portion of a carbon dioxide gas cylinder (hereinafter simply referred to as a gas cylinder) 22 is detachably connected to a connection portion 27 at the lower end of the regulator 21.
- a carbon dioxide gas cylinder hereinafter simply referred to as a gas cylinder
- a nozzle holder 23 is fixed to the upper part of the main frame 12, and a nozzle cover 232 having a cylindrical portion 231 is attached to the nozzle holder 23.
- the nozzle holder 23 supports a gas nozzle 24 that corresponds to the discharge port 18 and that faces the front.
- a valve 25 shown in FIG. 4 is connected between the gas nozzle 24 and the downstream portion of the regulator 21.
- the operation piece 19 on the front side of the push button 17 is opposed to the upper part of the operation element 26 of the valve 25.
- a connecting member 32 having a liquid path 31 is fixed to the main frame 12.
- a cosmetic liquid bottle 34 is detachably connected to the connection port 33 at the lower end of the liquid path 31 from below.
- a bottle cap 341 is put on the upper portion of the main body of the bottle 34.
- Projections 344 are formed on both sides of the bottle cap 341, and each projection 344 elastically engages with the corresponding projecting piece 122 of the main frame 12 shown in FIG. Is done. Further, when the bottle 34 is attached to or detached from the connection member 32, a click feeling is generated by the engagement between the protrusions 344 and the protrusions 122 and the release thereof.
- a hollow spherical seal member 35 made of silicone resin is attached to the cylindrical outlet 342 of the bottle cap 341. And the front-end
- a suction pipe 343 made of a synthetic resin connected to the outlet 342 is accommodated in the bottle 34, and the cosmetic liquid in the bottle 34 is sucked up through the suction pipe 343. It is done.
- the lower end opening of the suction pipe 343 is cut into a substantially V shape. That is, as shown in FIG. 18, when the lower end opening of the suction pipe 343 is cut off so as to have a flat end surface, when the suction pipe 343 is curved, the end surface hits the inner side surface of the bottle 34 and the lower end opening. There is a risk that the part will be blocked, and in such a case, it will interfere with the suction of the cosmetic liquid. Such a fear can be prevented if the end surface is V-shaped as described above.
- the bottle cap 341 of the bottle 34 is formed with a vent hole 346, and a porous membrane having fine holes on the inner side surface of the bottle cap 341 so as to cover the vent hole 346 from the lower side. 347 is attached.
- the internal pressure is released through the vent hole 346 and the porous membrane 347.
- the micropores of the porous film 347 do not allow the liquid to pass through, leakage of the cosmetic liquid is prevented.
- the outside air is introduced into the bottle 34 through the porous membrane 347 and the air holes 346 by the amount that the level of the cosmetic liquid in the bottle 34 is lowered by the spraying of the cosmetic liquid, so that the internal pressure of the bottle 34 is prevented from lowering.
- the bottle 34 is made of a transparent synthetic resin so that the internal cosmetic liquid can be seen through from the outside.
- the remaining amount of the cosmetic liquid can be visually confirmed from the outside of the housing 11 through the transparent plate 132 of the window 131 and the bottle 34.
- the main body 340 of the bottle 34 includes an outer cylinder 348 made of a hard resin and an inner cylinder 349 made of a soft resin, and the outer cylinder 348 and the inner cylinder 349 are bonded to each other at their mouths.
- the cosmetic liquid is stored in the inner cylinder 349.
- the inner cylinder 349 is deformed by an amount corresponding to the sucked amount, and the volume of the inner cylinder 349 is reduced.
- the cosmetic liquid is sucked up smoothly in a state where the decrease in the internal pressure of the liquid is suppressed.
- air is introduced into the inner cylinder 349 through the vent holes 346 and the porous film 347, and the deformation of the inner cylinder 349 is restored.
- a cosmetic liquid nozzle 41 as a liquid nozzle is supported upward at the lower end portion of the nozzle holder 23 in the nozzle cover 232.
- the cosmetic liquid nozzle 41 is connected to the liquid path 31 in the connection member 32 through a connection pipe 42.
- the front end opening of the cosmetic liquid nozzle 41 is directed in a direction orthogonal to the central axis 100 of the gas nozzle 24, and is located on the central axis 100 of the gas nozzle 24 within the range of the diameter, that is, the inner diameter of the front end opening of the gas nozzle 24. Therefore, the cosmetic liquid in the cosmetic liquid bottle 34 is sucked up and supplied to the cosmetic liquid nozzle 41 by the negative pressure caused by the jet flow of carbon dioxide gas from the gas nozzle 24. Then, the sucked cosmetic liquid becomes mist by the jet flow of carbon dioxide, and is sprayed from the front opening and the discharge port 18 of the nozzle cover 232 together with the jet flow of carbon dioxide.
- the push button 17, the gas nozzle 24, the valve 25 and the cosmetic liquid nozzle 41 constitute a spray mechanism.
- a chamfer 411 is formed on the outer periphery of the tip of the cosmetic liquid nozzle 41, and this chamfer 411 causes the carbon dioxide gas to flow during the jet flow as compared with the configuration in which the chamfer 411 shown in FIG. 11 is not formed. The generation of the vortex 200 starting from the edge is suppressed.
- the diameter of the opening 43 of the cosmetic liquid nozzle 41 is smaller than the diameter of the opening 44 of the gas nozzle 24, and the opening 43 of the cosmetic liquid nozzle 41 extends from the opening 44 of the gas nozzle 24. It falls within the range 45 of the jet flow.
- the ratio of the diameter of the gas nozzle 24 to the diameter of the cosmetic liquid nozzle 41 is set within 1.07 to 1.60.
- the diameter of the gas nozzle 24 is, for example, 0.35 to 0.50 mm, and the diameter of the cosmetic liquid nozzle 41 is, for example, 0.30 to 0.45 mm.
- the central axis 100 of the gas nozzle 24 is offset upward from the upper end surface of the cosmetic liquid nozzle 41, and the offset amount ⁇ is 5 to 1/100 of the diameter of the gas nozzle 24, for example, about 0.05 mm. is there.
- the distance ⁇ is within four times the diameter of the cosmetic liquid nozzle 41.
- an opening 46 is formed in the upper portion of the nozzle cover 232 at a position corresponding to the cosmetic liquid nozzle 41.
- the opening 46 is mainly for adjusting the spray sound.
- introduction openings 47 extending forward from the rear end of the nozzle holder 23 are provided. These introduction openings 47 are for passing the suction air flow by the ejector effect according to the jet flow from the gas nozzle 24. This air flow rectifies the spray and increases directivity. That is, since the suction flow by the ejector effect becomes an accompanying flow around the spray, the spray is discharged toward the front without being diffused in a wide range. In this case, since the suction flow by the ejector effect is also introduced from the opening portion 46, the opening portion 46 also has the same function as the introduction opening 47.
- a slider 51 as a moving member is supported on the upper portion of the main frame 12 so as to be slidable in the left-right direction.
- a protrusion 52 is formed on the slider 51. Then, by the movement of the slider 51, the protrusion 52 is located between the first position just below the operating piece 19 of the push button 17 as shown in FIG. 19 and the second position away from it as shown in FIG. Is supposed to be moved.
- the projection 52 is arranged at the first position directly below the operating piece 19, the projection 52 invalidates the function of the push button 17 and locks the push button 17 so that it cannot be pushed down. Accordingly, in this state, switching of the valve 25 in the opening direction by the push button 17 is not performed.
- the protrusion 52 moves from the second position in FIG. 20 to the first position in FIG. 19, the slider 51 can move smoothly while avoiding interference between the protrusion 52 and the operating piece 19.
- An arcuate or inclined cam surface 521 for obtaining is formed.
- the slider 51 having the protrusion 52 constitutes a lock mechanism.
- a pair of left and right levers 53 are rotatably supported on the main frame 12 by a shaft 54 at the lower end of each lever 53.
- Each lever 53 is urged outward by a spring 55 in the rotational direction.
- a cam follower 58 is supported at an intermediate portion in the vertical direction of each lever 53.
- the right lever 53 has a connecting pin 56 at its upper end, and the connecting pin 56 is connected to a hole 57 at the end of the slider 51. Then, when the lever 53 is rotated, the slider 51 is slid in the left-right direction.
- an operation cam 61 as a pair of cam members respectively opposed to the both cam followers 58 is integrally formed on the inner surface of the opening / closing cover 15.
- a cam surface 610 is formed on the edge of the cam 61.
- Each cam surface 610 is formed with a top 613, an upper first slope 611 retreating from the top 613, and a lower second slope 612 retreating from the top 613.
- the slider 51 is disposed at the first position in FIGS. 19 and 21 and is held at the lock position of the push button 17.
- the spring force of the spring 55 acts on the opening / closing cover 15 via the cam follower 58 and the operating cam 61, and the engagement between the first inclined surface 611 and the cam follower 58 prevents the opening / closing cover 15 from moving upward. Resistance.
- the spring force of the spring 55 or the first force is applied so that the body side portion of the beauty instrument does not move downward due to its own weight.
- the inclination angle of the slope 611 is set.
- the opening / closing cover 15 moves a distance corresponding to substantially the latter half of the moving stroke.
- the resistance force is weakened by the action of the second slope 612, and an assist force in the upward movement direction acts on the opening / closing cover 15 by the cam action of the second slope 612.
- the cam follower 58 resists the resistance force and moves on the top 613 after moving relatively along the second inclined surface 612.
- the resistance force is weakened by the cam action of the first slope 611 that retreats toward the upper side, and the opening / closing cover 15 has a downward assist force.
- the downward movement of the opening / closing cover 15 with respect to the cam follower 58 from the second slope 612 to the top 613 corresponds to substantially the first half of the movement stroke of the opening / closing cover 15.
- the downward movement of the opening / closing cover 15 with respect to the cam follower 58 along the first slope 611 from the top 613 corresponds to substantially the second half of the movement stroke of the opening / closing cover 15.
- the lever 53, the operation cam 61, and the like constitute a linkage mechanism between the open / close cover 15 and the slider 51.
- the pair of levers 53 are provided symmetrically, so that there is little uneven load acting on the opening / closing cover 15. The elevating operation is stabilized without tilting the open / close cover 15.
- the spring 55, the cam follower 58, and the cam surface 610 constitute resistance applying means and resistance reducing means.
- a pair of guide plates 62 are arranged side by side on the main frame 12, and guide grooves 63 extending in the vertical direction are formed in these guide plates 62. .
- a slope 64 is formed at an intermediate portion in the vertical direction of the guide groove 63, and a wide portion 65 is formed above the guide groove 63 via the slope 64.
- a driven member 66 is fitted so as to be movable up and down with both ends projecting left and right.
- a pair of protrusions 661 that can be engaged with the outer surface of the guide plate 62 are formed on the back surface of the driven member 66. The engagement between the protrusions 661 and the guide plate 62 limits the displacement and inclination of the driven member 66 in the left-right direction.
- a cylindrical seal member 67 is attached to the hole 662 at the center lower portion of the driven member 66 so as to face the cosmetic liquid nozzle 41 and as a blocking member capable of closing the cosmetic liquid nozzle 41. It has been.
- the seal member 67 is made of an elastomer such as silicone rubber or fluorine rubber.
- a spring 68 that biases the driven member 66 downward is interposed between the driven member 66 and the main frame 12. As the driven member 66 moves up and down, the central portion of the driven member 66 and the seal member 67 enter and exit the opening 46 (see FIGS. 5 and 9) of the nozzle cover 232.
- a projection 69 is formed on the inner peripheral surface of the opening / closing cover 15, and a slope 70 is formed on the upper surface thereof.
- the driven member 66 since the driven member 66 is held by the inclined surface 64 of the wide portion 65 of the guide groove 63, the spring force of the spring 68 does not act on the protrusion 69, that is, the opening / closing cover 15.
- the protrusion 69 is lowered, so that the driven member 66 is lowered along the inclination of the slope 64 by the spring force of the spring 68. 28 and 29, the driven member 66 is disposed at the lower position by the spring force of the spring 68, and the cosmetic liquid nozzle 41 is sealed by the seal member 67.
- the guide plate 62, the driven member 66, the protrusion 69 of the opening / closing cover 15, etc. constitute a linkage mechanism between the opening / closing cover 15 and the seal member 67.
- the protruding portion 671 of the seal member 67 downward from the driven member 66 is formed to have a larger diameter than the portion inserted into the hole 662. For this reason, in a state where the cosmetic liquid nozzle 41 is sealed by the spring force of the spring 68, buckling and lateral bending are regulated, and the sealed state is appropriately maintained.
- a flange portion 672 for preventing interference between the seal member 67 and the gas nozzle 24 is formed in the lower part of the seal member 67.
- a protective cap 81 that covers the spherical seal member 35 is attached to the bottle cap 341 before the bottle 34 is mounted in the sprayer.
- the protective cap 81 is used in a distribution stage or the like, and is removed when the bottle 34 is mounted in the sprayer.
- a pin 82 projects from the inner center of the protective cap 81, and a holding cylinder 83 is formed integrally therewith. The pin 82 is inserted into the takeout port 342 of the bottle 34 and plugs the takeout port 342.
- the holding cylinder 83 engages with the outer peripheral surface of the spherical seal member 35.
- a step 811 positioned at the same height as the lower end of the holding cylinder 83 is formed on the inner peripheral surface of the bottle cap 341, and an annular shape around the vent hole 346 of the bottle cap 341 is formed between the holding cylinder 83 and the step 811.
- a sealing plate 84 made of silicone rubber corresponding to the wall 350 is fixed. And, for example, even when the pressure difference is generated inside and outside the bottle 34 and the pressure inside the bottle 34 is higher than the outside, as in the case of an aircraft flying at high altitude, the protective cap 81 is put on. As a result, the sealing plate 84 abuts on the annular wall 350 and the vent hole 346 is closed. By this closure, leakage of the cosmetic liquid in the bottle 34 is prevented.
- the operation cam 61 is disposed at the lower position as shown in FIGS.
- the cam follower 58 of the lever 53 is engaged with the first inclined surface 611 above the top portion 613 of the cam surface 610 of the operating cam 61 by the spring force of the spring 55, and the lever 53 is moved to the inner position by the biasing force of the spring 55. Placed and held in place.
- the slider 51 is disposed at the position shown in FIGS. 19 and 21, and the protrusion 52 at the top is located below the push button 17. For this reason, the push-down of the push button 17 is locked, the valve 25 is kept closed, and the release of carbon dioxide from the gas cylinder 22 is prevented.
- the opening / closing cover 15 is pulled up as shown in FIG. In this way, as shown in FIG. 27, the driven member 66 is pulled up against the spring force of the spring 68, the seal member 67 is separated upward from the cosmetic liquid nozzle 41, and the cosmetic liquid nozzle 41 is closed. From the state to the open state.
- the cam follower 58 climbs over the top portion 613 of the working cam 61 due to the raising of the working cam 61 based on the raising of the opening and closing cover 15, so to speak, the second point of the working cam 61. Transition to the slope 612 side. Since the second inclined surface 612 retreats outward toward the lower side, the pressure contact force of the cam follower 58 by the spring 55 against the operating cam 61 is weakened, and thus the resistance force against the opening of the opening / closing cover 15 is weakened. The assist force by the cam action of the second inclined surface 612 also acts, and the open / close cover 15 can be moved to the open side with a light force.
- the lever 53 is rotated outward according to the second inclined surface 612 by the action of the spring 55, so that the slider 51 is moved to the second position in FIG. Therefore, the protrusion 52 is retracted from the position where the push button 17 is locked, and the push button 17 can be operated.
- the valve 25 is opened and the carbon dioxide gas in the gas cylinder 22 is ejected from the gas nozzle 24.
- the opening of the cosmetic liquid nozzle 41 becomes negative pressure
- the cosmetic liquid in the bottle 34 is sucked up
- the cosmetic liquid from the cosmetic liquid nozzle 41 becomes mist by the jet of carbon dioxide gas
- the mist becomes the discharge port 18. From outside. Therefore, the cosmetic liquid can be used for makeup.
- the diameter of the gas nozzle 24 is larger than the diameter of the cosmetic liquid nozzle 41, and the cosmetic liquid nozzle 41 is located within the range 45 of the jet flow from the gas nozzle 24. A fine mist is injected with almost no occurrence. Therefore, the nebulizer can be used comfortably.
- a resistance force in the closing direction is applied to the opening / closing cover 15, and when the opening / closing cover 15 exceeds the dead point, the resistance force is reduced and the opening / closing is performed by the cam action of the first slope 611.
- a downward assisting force acts on the cover 15, and the opening / closing cover 15 can be moved to the closed position with a light force.
- the cam follower 58 cannot travel on the first slope 611 away from the top 613, that is, outward, so that the opening / closing cover 15 moves in the opening direction. Be blocked.
- the present embodiment has the following effects. (1) That is, a gas nozzle 24 for injecting carbon dioxide gas as a gas, a valve 25 for opening and closing a flow path supplied to the gas nozzle 24, and a cosmetic liquid nozzle 41 as a liquid nozzle close to the tip of the gas nozzle 24 And a spraying mechanism comprising a push button 17 as an operation member for opening and closing the valve 25, and a manually operable blocking member for blocking the leakage of the cosmetic liquid as the liquid from the cosmetic liquid nozzle 41
- the sealing member 67 is provided. That is, the sealing member 67 is provided for preventing the cosmetic liquid from leaking out from the cosmetic liquid nozzle 41 when the push button 17 for spraying is not depressed. See FIGS. For this reason, even when the internal pressure of the bottle 34 rises, such as at high temperatures in summer, the cosmetic liquid in the bottle 34 can be prevented from leaking from the cosmetic liquid nozzle 41.
- the diameter of the opening 44 of the gas nozzle 24 is made larger than the diameter of the opening 43 of the cosmetic liquid nozzle 41 so that the opening 43 of the cosmetic liquid nozzle 41 is positioned within the range 45 of the jet flow from the gas nozzle 24. See FIGS. For this reason, the cosmetic liquid is sucked up smoothly, and the sucked-up cosmetic liquid is effectively misted. Therefore, useless consumption of the cosmetic liquid can be avoided.
- the cosmetic liquid when the diameter of the opening 44 of the gas nozzle 24 is smaller than the diameter of the opening 43 of the cosmetic liquid nozzle 41 and the opening 43 of the cosmetic liquid nozzle 41 protrudes from the range 45, the cosmetic liquid In some cases, the suction force is insufficient, or a portion of the sucked cosmetic liquid is not misted and dripped into a dripping state that is not used effectively.
- a hollow spherical seal member 35 made of silicone resin held in the connection port 33 of the connection member 32 is provided at the mouth of the bottle 34 detachably accommodated in the housing 11. See FIGS. Therefore, not only can the sealing function between the mouth portion of the bottle 34 and the connection member 32 be ensured, but the attachment and detachment of the bottle 34 can be easily performed with a small resistance without receiving strong frictional resistance. Then, with the attachment and detachment, the user can be given a mechanical feel close to a click feeling, and even if the fitting state between the spherical seal member 35 and the connecting member 32 cannot be visually confirmed, the fitting state is sounded.
- Appropriate confirmation can be made based on the touch of the hand, and the quality of the mounted state of the bottle 34 can be recognized.
- a general O-ring made of a rubber material is used in place of the spherical seal member 35, a strong frictional resistance is applied to the connection member 32 due to the high friction coefficient and flexibility inherent to the rubber material.
- the cosmetic liquid nozzle 41 has a tapered chamfer 411 at the tip thereof, and therefore, the disturbance due to the vortex 200 compared to the configuration without the chamfer 411. Generation of flow can be suppressed. That is, when the chamfer 411 is not formed at the tip but is formed in a cut-off shape, a large vortex starting from the edge of the tip is formed at the tip of the cosmetic liquid nozzle 41 due to gas injection from the gas nozzle 24. 200 occurs and turbulence is generated. When the turbulent flow is generated in this way, the negative pressure at the tip of the cosmetic liquid nozzle 41 is less likely to be generated, and the suction liquid P of the cosmetic liquid is weakened.
- a force Q in the reverse flow direction may act.
- spraying is unlikely to occur.
- the generation of the vortex 200 is suppressed by the chamfer 411, a sufficient amount of spray can be obtained.
- the cover 15 Resistance applying means for applying resistance to the opening / closing operation of the cover, and resistance reducing means for weakening the resistance applying state by the resistance applying means during the opening / closing stroke of the cover. That is, as shown in FIG. 19, in the closed state of the opening / closing cover 15, resistance in the opening direction is strongly applied to the opening / closing cover 15 via the cam follower 58 and the operating cam 61 by the spring force of the spring 55.
- the cam follower 58 gets over the top 613 of the operating cam 61 just before the closing is completed, so that the assist force acts on the user and the touch resembles a click feeling.
- the opening / closing cover 15 is closed.
- the user can open and close the open / close cover 15 with a moderate resistance without rattling, and can recognize the closed state and the open state in a bodily sense, thereby obtaining a high-grade operation feeling and assist power. Can be easily opened and closed without performing other operations for opening and closing.
- Example 2 Examples in which a plurality of types of gas nozzles 24 having different diameters and a cosmetic liquid nozzle 41 are combined will be described with reference to Tables 1 to 12.
- the combination in the case where the diameter of the gas nozzle 24 is smaller than the diameter of the cosmetic liquid nozzle 41 is a comparative example that is out of the present embodiment.
- the gas cylinder 22 is connected to the primary side of the flow rate adjusting valve 90 with a meter, and the gas nozzle 24 is connected to the secondary side of the valve 90 via a tube 95. Furthermore, the result of having verified the dripping and the bodily sensation when spray is applied to the cheek in a state where the bottle 34 is connected to the cosmetic liquid nozzle 41 is shown. Then, the meter pointer of the flow control valve 90 was set to have two stages of 0.12 MPa (megapascal) and 0.15 MPa, and verification was performed in both stages. In this case, it was confirmed that the actual ejection pressure from the gas nozzle 24 was reduced by 8 to 12% with respect to the meter pointer due to the flow resistance in the tube 95 and the like.
- the cosmetic liquid nozzle 41 has a diameter of 0.3 mm, 0.45 mm, and 0.55 mm. Three kinds of things were prepared and combined. And the cosmetic liquid nozzle 41 was arrange
- Tables 5 and 6 are obtained by combining the results of Table 1, Table 3, Table 2, and Table 4 for each gas injection pressure with respect to verification of dripping and bodily sensation.
- the combination of “O” and “O” in Tables 1 and 2 was “O” (good), and the other combinations were “X” (defect). According to this evaluation result, good results can be obtained when the diameter of the gas nozzle 24 is larger than the diameter of the cosmetic liquid nozzle 41.
- Tables 7 and 8 show the change in the amount of the cosmetic liquid in the cosmetic liquid bottle 34 in one spray, in grams. That is, in each combination of nozzles 24 and 41 in two cases with different spraying pressures, spraying 20 times every 12 seconds, measuring the change in the weight of each cosmetic liquid in grams, and calculating the average value of consumption for one time And the average values are shown in Tables 7 and 8. The result shows a tendency that the smaller the diameter of the gas nozzle 24, the smaller the amount of change in weight, that is, the amount of cosmetic liquid consumed.
- Tables 9 and 10 show that the time until carbon dioxide gas is continuously injected from the gas nozzle 24 at the meter pointer pressures of 0.12 MPa and 0.15 MPa and the injection stops, that is, the gas cylinder 22 can be injected. It is a time measured until carbon dioxide is consumed. In this case as well, the smaller the diameter of the gas nozzle 24, the longer the injection duration. Further, the injection duration is longer when the carbon dioxide gas injection pressure is low. Therefore, when the diameter of the gas nozzle 24 is small and the ejection pressure of the carbon dioxide gas is low, one gas cylinder 22 can be used for a long time.
- Table 11 shows the ratio of the diameter of the cosmetic liquid nozzle 41 to the diameter of the gas nozzle 24.
- Table 12 shows the relationship between the aperture ratio of Table 11 and Tables 5 and 6. That is, regardless of whether the carbon dioxide gas jet pressure is high or low, the ratio of the diameter of the cosmetic liquid nozzle 41 to the diameter of the gas nozzle 24 is 1.07 to 1.60.
- the present invention is embodied in a spraying apparatus for spraying a liquid other than a cosmetic liquid, for example, a perfume or a face wash.
- a liquid other than a cosmetic liquid for example, a perfume or a face wash.
- the inner cylinder 349 of the cosmetic liquid bottle 34 is deformed into a volume-reduced state according to the sucked amount.
- outside air is sucked into the cosmetic liquid bottle 34 from the cosmetic liquid nozzle 41 or the like, and the deformation of the inner cylinder 34 is restored. .
- the present invention is embodied in a sprayer of a type in which the gas cylinder 22 and the cosmetic liquid bottle 34 are installed outside the housing. -Instead of the sealing member 67 shown in FIG.28 and FIG.29, the member for preventing the leakage of a cosmetic liquid is provided in the path
- an O ring for sealing is provided on the outer periphery of the mouth of the bottle 34 or the inner periphery of the connection port 33 of the connection member 32.
- the caliber of the gas nozzle 24 and the cosmetic liquid nozzle 41 is set to a value other than the values in the above embodiment. In this case, the diameter of the gas nozzle 24 is made larger than the diameter of the cosmetic liquid nozzle 41.
- a cylinder filled with a gas other than carbon dioxide, for example, a gas such as air or nitrogen gas is used.
- a dedicated operation member for moving the slider 51 and the driven member 66 is provided separately from the opening / closing cover 15. That is, the movement of the slider 51 and the driven member 66 can be directly or indirectly operated without the action of the cam follower 58 and the operating cam 61.
- the operating cam 61 is supported by the open / close cover 15 via a spring 80, and a contact 87 as a cam follower that engages the operating cam 61 is provided at a fixed position of the upper frame 14. As shown in FIG.
- a contact 87 that engages with the operating cam 61 is provided on the upper frame 14 via a spring 88 so as to be able to advance and retract. In this way, opening / closing resistance can be applied to the opening / closing cover 15, but the operation of the opening / closing cover 15 and the operation of the slider 51 can be separated.
- a seal ring 85 for sealing the upper surface of the bottle cap 341 is provided inside the protective cap 81. Then, when the atmospheric pressure decreases in the airplane or the like, and the pressure inside the seal ring 85 becomes higher than the outside, the seal portion 851 of the seal ring 85 bulges outside in a contact state with the bottle cap 341. As a result, the contact pressure between the seal portion 851 and the bottle cap 341 increases. For this reason, even if the cosmetic liquid in the bottle 34 leaks, it is prevented from leaking outside the protective cap 81.
- ⁇ Provide a link mechanism as a configuration that provides resistance to opening and closing of the opening and closing cover 15.
- a pair of long holes 94 is formed in the upper frame 14, and pins 92 at one ends of the links 91 are slidably supported in the long holes 94, and each link 91 is supported. Is supported by a common pin 93 on the opening / closing cover 15. As the opening / closing cover 15 moves up and down, the common pin 93 crosses the dead point on the central axis 110 passing through the pair of pins 92 in the long hole 94 in both directions.
- SYMBOLS 11 Housing, 22 ... Gas cylinder, 23 ... Nozzle holder, 24 ... Gas nozzle, 25 ... Valve, 34 ... Cosmetic liquid bottle, 41 ... Cosmetic liquid nozzle, 100 ... Center axis, 411 ... Chamfering, alpha ... Offset amount.
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Nozzles (AREA)
Abstract
Description
以下、一実施形態を図面に従って説明する。
図1~図4に示すように、噴霧器のハウジング11は、メインフレーム12を有している。このメインフレーム12の下部に下部ケース13が図示しない係止機構を介して着脱可能に取り付けられている。下部ケース13の前面には縦長の窓131が透設され、その内側には透明板132が設けられている。メインフレーム12の上部には前記ハウジング11の一部を構成する上部フレーム14が取付けられている。図4に示す上部フレーム14の外側にはハウジング11の一部を構成する開閉部材としての開閉カバー15が図1に実線で示す下方位置と、図2に実線で示す上方位置との間において移動可能に装着されている。図3に示すように、上部フレーム14は上部カバー141によって覆われている。
図10に示すように、化粧液ノズル41の先端外周には面取り411が形成されており、この面取り411により、図11に示す面取り411が形成されない構成と比較して炭酸ガスの噴射流中にエッジを起点とした渦200の発生が抑制されるようになっている。
図5、図19、図20、図23及び図24に示すように、メインフレーム12には、左右一対のレバー53が各レバー53の下端の軸54により回動可能に支持されている。各レバー53は、スプリング55により外側へ回動方向に付勢されている。各レバー53の上下方向の中間部にはカムフォロワ58が支持されている。図19において、右方のレバー53はその上端に連結ピン56を有し、その連結ピン56は前記スライダ51の端部の孔57に連結されている。そして、このレバー53が回動されることにより、スライダ51が左右方向にスライドされる。
(1)すなわち、気体としての炭酸ガスが噴射されるガスノズル24と、そのガスノズル24に供給される流路を開閉するバルブ25と、前記ガスノズル24の先端に近接する液体ノズルとしての化粧液ノズル41と、前記バルブ25を開閉操作するための操作部材としての押しボタン17よりなる噴霧機構を備え、前記化粧液ノズル41からの液体としての化粧液の漏出を阻止するための手動操作可能な阻止部材としてのシール部材67を設けている。つまり、噴霧のための押しボタン17が押し下げ操作されていないときに、化粧液ノズル41からの化粧液の漏出を阻止するためのシール部材67が備えられている。図28、29参照。このため、夏季の高温時等、ボトル34の内部圧力が上昇する場合であっても、ボトル34内の化粧液が化粧液ノズル41から漏出することを防止できる。
複数種類の口径のガスノズル24及び化粧液ノズル41を組み合わせた実施例を、表1~表12に従って説明する。ここで、ガスノズル24の口径が化粧液ノズル41の口径より小さい場合の組み合わせは、本実施例から外れた比較例とする。
表5及び表6は、液だれ及び体感の検証に関してガス噴射圧力ごとに、表1、表3及び表2、表4の結果をそれぞれ合体して評価したものである。ここで、表1及び表2の「○」と「○」との組み合わせを「○」(良好)、それ以外の組み合わせを「×」(不良)とした。この評価結果によれば、ガスノズル24の口径が化粧液ノズル41の口径より大きい場合に良好な結果を得ることができる。
表7及び表8は、1回の噴霧における化粧液ボトル34内の化粧液の量の変化をグラム単位で表したものである。すなわち、噴射圧力の異なる2つケースにおけるノズル24、41の各組み合わせにおいて、20秒ずつ12回噴霧して各回の化粧液の重量の変化をグラム単位で計測し、1回分の消費量の平均値を算出し、それらの平均値を表7及び表8に記したものである。その結果は、ガスノズル24の口径が小さいほど重量変化量、すなわち化粧液の消費量が少ない傾向を表している。
表9及び表10は、0.12MPa及び0.15MPaのメータ指針圧力で、ガスノズル24から炭酸ガスをそれぞれ連続噴射させて、その噴射が停止するまでの時間、すなわち、ガスボンベ22内の噴出可能な炭酸ガスが消費されるまでの時間を計測したものである。この場合も、ガスノズル24の口径が小さいほど噴射持続時間が長い。また、炭酸ガスの噴出圧力が低い場合のほうが噴射持続時間が長い。従って、ガスノズル24の口径が小さく、炭酸ガスの噴出圧力が低い場合に、1本のガスボンベ22を長く使用できる。
表12は、表11の口径比率と、表5及び表6との関係を示したものである。つまり、炭酸ガスの噴出圧力が高低いずれのケースにおいても、ガスノズル24の口径に対する化粧液ノズル41の口径の比率が1.07~1.60の場合が好結果である。
・化粧液ボトル34の多孔質膜347を有する通気孔346を設けないようにすること。このように構成した場合、化粧液が噴霧によって吸い上げられると、その吸い上げ量に応じて化粧液ボトル34の内筒349が容積縮小状態に変形される。そして、その後、例えば、噴霧直後にシール部材67によって化粧液ノズル41が閉鎖される直前において、外気が化粧液ノズル41等から化粧液ボトル34内に吸引されて内筒34の変形が復元される。
・図28及び図29に示すシール部材67に代えて、化粧液の漏洩を防止するための部材を化粧液ボトル34と化粧液ノズル41との間の経路中に設けること。
・ガスノズル24及び化粧液ノズル41の口径を前記実施例の値以外の値にすること。この場合、ガスノズル24の口径を化粧液ノズル41の口径より大きくする。
・スライダ51や被動部材66を移動させるための専用の操作部材を開閉カバー15とは別に設けること。つまり、スライダ51や被動部材66の移動をカムフォロワ58及び作動カム61の作用によらずに直接あるいは間接に操作できるようにすること。例えば、図33に示すように、作動カム61をスプリング80を介して開閉カバー15に支持するとともに、上部フレーム14の固定位置に作動カム61と係合するカムフォロワとしての接触子87を設けたり、図34に示すように、作動カム61に係合する接触子87をスプリング88介して上部フレーム14に進退可能に設けたりすること。このようにすれば、開閉カバー15に対して開閉の抵抗を付与することができるが、開閉カバー15の動作とスライダ51の動作とを切り離すことができる。
Claims (6)
- 気体が噴射されるガスノズルと、そのガスノズルからの噴射流の範囲内においてガスノズルの中心軸線と交差する方向に向かって開口するとともに、液体供給源に接続された液体ノズルとを備え、ガスノズルからの気体の噴射流によって液体ノズルからの液体が噴霧されるようにした噴霧器において、
前記ガスノズルの口径を液体ノズルの口径より大きくした噴霧器。 - 前記液体ノズルの口径に対するガスノズルの口径の比率を1.07~1.60の範囲内にした請求項1に記載の噴霧器。
- 液体ノズルの先端に面取りを形成した請求項1または2に記載の噴霧器。
- ガスノズル及び液体ノズルを覆うカバーを設けた請求項1~3のうちのいずれか一項に記載の噴霧器。
- 前記ガスノズルの周囲に向かう空気流を導入するための開口をガスノズルの後方において前記カバーに設けた請求項4に記載の噴霧器。
- 前記ガスノズル及び液体ノズルを噴霧器ハウジングによって覆った請求項1~5のうちのいずれか一項に記載の噴霧器。
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CN201480070454.4A CN105849008A (zh) | 2013-12-26 | 2014-12-25 | 喷雾器 |
JP2015554991A JPWO2015099023A1 (ja) | 2013-12-26 | 2014-12-25 | 噴霧器 |
KR1020167019583A KR20160102241A (ko) | 2013-12-26 | 2014-12-25 | 분무기 |
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USD918732S1 (en) * | 2019-10-21 | 2021-05-11 | Glaspray Engineering & Manufacturing Co., Ltd. | Cosmetic container |
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CN108577137A (zh) * | 2018-06-02 | 2018-09-28 | 余姚市永佳电器有限公司 | 便携式喷粉美妆仪 |
CN112498990B (zh) * | 2020-10-30 | 2022-08-02 | 怡业股份有限公司 | 按压瓶容器 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992006793A1 (en) * | 1990-10-17 | 1992-04-30 | S.C. Johnson & Son, Inc. | Fluid spray device |
JP2005329341A (ja) * | 2004-05-20 | 2005-12-02 | Soft99 Corporation | 内容物噴射機構およびこの機構を備えた塗料スプレー |
WO2013157595A1 (ja) * | 2012-04-18 | 2013-10-24 | 株式会社 Mtg | 噴霧器 |
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JP3572546B2 (ja) * | 2001-09-17 | 2004-10-06 | 株式会社Gsiクレオス | 塗装スプレー装置 |
JP2013233957A (ja) | 2012-05-08 | 2013-11-21 | Mtg:Kk | 噴霧装置における液漏れ防止構造 |
-
2014
- 2014-12-25 KR KR1020167019583A patent/KR20160102241A/ko not_active Application Discontinuation
- 2014-12-25 TW TW103145455A patent/TW201531259A/zh unknown
- 2014-12-25 JP JP2015554991A patent/JPWO2015099023A1/ja active Pending
- 2014-12-25 WO PCT/JP2014/084276 patent/WO2015099023A1/ja active Application Filing
- 2014-12-25 CN CN201480070454.4A patent/CN105849008A/zh active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992006793A1 (en) * | 1990-10-17 | 1992-04-30 | S.C. Johnson & Son, Inc. | Fluid spray device |
JP2005329341A (ja) * | 2004-05-20 | 2005-12-02 | Soft99 Corporation | 内容物噴射機構およびこの機構を備えた塗料スプレー |
WO2013157595A1 (ja) * | 2012-04-18 | 2013-10-24 | 株式会社 Mtg | 噴霧器 |
Cited By (1)
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USD918732S1 (en) * | 2019-10-21 | 2021-05-11 | Glaspray Engineering & Manufacturing Co., Ltd. | Cosmetic container |
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TW201531259A (zh) | 2015-08-16 |
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