WO2015091599A1 - Textile à propriétés améliorées destiné à des vêtements de sport - Google Patents

Textile à propriétés améliorées destiné à des vêtements de sport Download PDF

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Publication number
WO2015091599A1
WO2015091599A1 PCT/EP2014/078138 EP2014078138W WO2015091599A1 WO 2015091599 A1 WO2015091599 A1 WO 2015091599A1 EP 2014078138 W EP2014078138 W EP 2014078138W WO 2015091599 A1 WO2015091599 A1 WO 2015091599A1
Authority
WO
WIPO (PCT)
Prior art keywords
textile
microcapsules
content
sportswear
skin
Prior art date
Application number
PCT/EP2014/078138
Other languages
German (de)
English (en)
Inventor
Yvonne NEUMANN
Katja Warnke
Anja Eitrich
Juliane Schade
Original Assignee
Beiersdorf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102013226337.6A external-priority patent/DE102013226337A1/de
Priority claimed from DE201320011206 external-priority patent/DE202013011206U1/de
Application filed by Beiersdorf Ag filed Critical Beiersdorf Ag
Priority to EP14828021.7A priority Critical patent/EP3082674A1/fr
Publication of WO2015091599A1 publication Critical patent/WO2015091599A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/00051—Accessories for dressings
    • A61F13/00063—Accessories for dressings comprising medicaments or additives, e.g. odor control, PH control, debriding, antimicrobic
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D1/00—Garments
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0204—Specific forms not provided for by any of groups A61K8/0208 - A61K8/14
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/66—Enzymes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/06—Preparations for care of the skin for countering cellulitis
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/08—Anti-ageing preparations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
    • B01J13/14—Polymerisation; cross-linking
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12—Processes in which the treating agent is incorporated in microcapsules
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B17/00—Selection of special materials for underwear
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Definitions

  • the invention relates to textiles for the production of sportswear with improved properties, in particular with improved sun protection, improved comfort and with skin care properties.
  • the production of sportswear with improved properties is also part of the present invention.
  • clothing for the pursuit of recreational sports in the fresh air should provide the wearer with sunscreen, since during sports activity applied to the skin sunscreen creams, lotions, gels or the like can cope with friction or sweating and so your protection against UV radiation of sunlight can not or only insufficiently unfold.
  • US 2013/0209744 A1 discloses a composite textile of at least three layers, consisting of an outer elastane layer, a middle foam layer and an inner artificial leather or nylon layer. The manufacturing process is complicated and the resulting composite textile heavy and not suitable for sportswear.
  • textiles which can have positive effects on the skin by releasing skin-care active ingredients.
  • WO 2010/006442 A1 discloses loaded with microparticles
  • the microparticles consist of an organic vehicle impregnated with an active substance and a surface agent and a binder. When rubbed, the microparticles erode and release the active ingredient gradually.
  • WO 2005/005712 A2 discloses compositions for the application of microcapsules containing active ingredients to textiles. In the process, the active ingredients are gradually released when the textiles are worn by diffusing through the shells of the microcapsules.
  • the invention provides a textile loaded with fragile microcapsules of polyurethane, wherein the textile is a nylon-elastane blend knitwear, and the microcapsules are designed to break under mechanical force and release their content in the fabric, and wherein the content of the microcapsules comprises a skin care composition.
  • the microcapsules preferably have a breaking stress between 50 and 150 ⁇ , and a diameter between 5 and 15 ⁇ .
  • the invention is based on the idea that with the above composition of knitwear, on the one hand, good protection against UV or sunlight is obtained, and at the same time the wearing comfort is increased by a short drying time and associated low loss of heat insulation.
  • a long-term and uniform action of Skin care composition achieved. This allows a particularly effective action on and in the skin and the skin sustainably improved. Due to the nature of the microcapsules in fracture stress and diameter in the areas according to the invention is advantageously and surprisingly achieved that the active ingredient over many wearing and washing operations remains available and is released only gradually when worn to the skin. This allows a long use of the textile according to the invention.
  • microcapsules according to the invention advantageously enable a stable release rate of the active ingredient, so that the release of the active ingredient can be relatively well established and adequately dosed over a period of time and, above all, evenly distributed.
  • skin care is provided by wearing apparel made from a textile loaded with microcapsules according to embodiments of the present invention containing a skin care composition.
  • the content of the microcapsules is lipophilic.
  • Microcapsules as active substance at least one of the following: Aloe Vera (CAS 85507-69-3) and / or almond oil (CAS 8007-69-0).
  • Aloe Vera CAS 85507-69-3
  • / or almond oil CAS 8007-69-0.
  • a particularly good skin care is achieved by the permanent action of aloe vera and / or almond oil achieved by the microcapsules according to the invention.
  • the content of aloe vera is preferably from 0.1 to
  • 100 ⁇ g / cm 2 textile for example from 0.1 to 10 ⁇ g / cm 2 textile.
  • the content of almond oil is preferably from 0.1 to 500 ⁇ g / cm 2 of textile, for example from 1 to 100 ⁇ g / cm 2 of textile.
  • these content ranges of the different ingredients a particularly good skin care has been shown, but the invention is not limited to these ranges.
  • the skin care active ingredients can dissolve particularly well and can penetrate into the skin.
  • the one or more triglycerides may be selected from caprylic and / or capric acid derived triglycerides, such as CAS number 65381 -09-1 / 73398-61 -5.
  • the textile according to the invention contains from 15 to 25% by weight of elastane. In a further preferred embodiment, the textile according to the invention contains from 75 to 85% by weight of nylon.
  • a particularly comfortable carrying is possible. Furthermore, such a mixture supports a mechanical tightening of the skin.
  • the textile according to the invention has a basis weight of 150 to 250 g / m 2 .
  • the advantage of this is that at such basis weights of the UV protection is pronounced, while at the same time wearing is comfortable to exercise, and the textile is given a sufficiently short drying time to ensure comfort.
  • the textile of the invention has an Ultraviolet Protection Factor (UPF) of 40 or greater.
  • UPF Ultraviolet Protection Factor
  • the textile according to the invention has a drying time according to BPI 1.3: 2009-01 of 30 minutes or less.
  • the short drying time ensures that during sports the sportswear produced from the textile does not lose its heat-insulating or only slightly. This ensures comfort and possible health restrictions by cooling the skin during exercise are avoided.
  • the invention relates to
  • Sportswear and other articles made of the textile according to the invention relate to elastic sports apparel made of a textile that can exert compression on the skin when worn.
  • the invention relates to a
  • Fig. 1 is an electron micrograph of an inventive with
  • Fig. 2 is an electron micrograph of an inventive with
  • Fig. 3 is an electron micrograph of an intact microcapsule on a textile according to the invention.
  • Fig. 4 is an electron micrograph of a broken microcapsule on a textile according to the invention after release of the contents.
  • textiles which provide UV protection of the skin, increase wearing comfort and release active ingredients.
  • the textiles can have an elastane content of
  • the textiles may have a nylon content of 75% to 85%, for example from 78 to 82%, such as about 80%.
  • other fibrous materials such as natural or synthetic fibers may be present in small amounts without significantly affecting the properties of the product.
  • Textiles have a basis weight of 150 to 250 g / m 2 . Depending on the requirements, heavier textiles may have improved UV protection properties, while lighter textiles may have improved drying times.
  • the textiles of the invention may have a basis weight of 160 to 240 g / m 2 , for example from 180 to 220 g / m 2 , such as about 190 g / m 2 or about 200 g / m 2 .
  • the textiles of the invention may have an Ultraviolet Protection Factor (UPF) of 40 or greater. As described herein, the UPF is measured according to UV Standard 810. In one embodiment, the UPF may be equal to 50 or higher, or 60 or higher, such as about 70 or about 80.
  • UPF Ultraviolet Protection Factor
  • the textiles of the invention may have a drying time of 30 minutes or less.
  • the drying time is calculated according to BPI 1.3: 2009-01, as of the Germans Accreditation Body GmbH, and as described on https://www.vumpu.com/de/document/view/9451551/tik-ak mecanicticiansstelle- gmbh-anlaqe-zum-dakks / 15.
  • the low drying time improves wearing comfort, as it prevents sweating during sweating.
  • the drying time of BPI 1 .3: 2009-01 in embodiments may be 25 minutes or less, such as 22 minutes or less, for example, about 21 minutes or about 18 minutes. This can be partially made possible by the fact that the textiles according to the invention have a low water retention capacity. At the same time, the wearing comfort can be further improved by improving the heat insulation of the wet textile.
  • FIG. 1 shows an electron micrograph of a textile according to the invention, in which the microcapsules are clearly visible.
  • the microcapsules are made of polyurethane prepared by polymerizing toluene-2,4-diisocyanate with polyols.
  • the preparation process may be designed to obtain polyurethane microcapsules having a diameter of 5 to 15 ⁇ m and a fracture stress between 50 and 150 ⁇ .
  • the preparation of the microcapsules and their loading with ingredients and the application to textile are known to the person skilled in the art.
  • the microcapsules are applied as an aqueous emulsion together with a second polyurethane as a binder to the textile, whereby the binder covalently binds to the microcapsules and the textile fibers, and thus charges the microcapsules on the textile.
  • emulsions are, for example, 20 to 30 wt .-% of caprylic and / or capric acid derived triglycerides, 1 to 6 wt .-% of an active ingredient combination, and water, polymer and preservative.
  • 3 and 4 show a microcapsule present in the textile according to the invention before and after its breakage.
  • the breaking strength of the microcapsules can be measured by axisymmetric deformation using optical microscopy.
  • the mechanical deformation is carried out with a Nanolndenter on an atomic force microscope.
  • Test head is a spherical sapphire whose size (800 ⁇ in diameter) allows a quasi-planar contact surface with the much smaller capsules (diameter, for example, 1 1 ⁇ ).
  • the microcapsules themselves are immobilized on a transparent glass slide.
  • the capsule contents include almond oil and aloe vera.
  • the aloe vera content may preferably be between 0.1 and 1% by weight and the almond oil content may preferably be between 1 and 5% by weight.
  • the microcapsules further contain a skin care composition, such as one or more triglycerides, such as triglycerides derived from caprylic and / or capric acid (CAS Nos. 538-23-8 / 65381 -09-1 / 73398-61- 5).
  • a skin care composition such as one or more triglycerides, such as triglycerides derived from caprylic and / or capric acid (CAS Nos. 538-23-8 / 65381 -09-1 / 73398-61- 5).
  • Other skin care components known to those skilled in the art such as coenzyme ubiquinone, avocado oil, dexpanthenol, glyceryl-glucose, cucumis sativus juice, tocophenol, tocopheryl acetate, corn oil, jojoba oil or mixtures thereof, may be included in the microcapsules.
  • the content of triglycerides derived from caprylic acid and / or capric acid can be increased by 200% to 300%.
  • Microcapsules containing active ingredients also after hand or machine washing of a garment made from the textile according to the invention stops.
  • a release of almond oil could still be detected.
  • Table I relate to text samples of embodiments according to the invention having an initial content of almond oil of 5 ⁇ g / cm 2 of textile.
  • the samples had an average weight of 1.80 g at one Size of about 50 cm 2 (Karl Schröder KG) and were washed in a commercial washing machine with commercial detergent with standard washes and then extracted with acetone, centrifuged and analyzed by HPLC-MS / MS.
  • FIG. 2 shows a corresponding electron microscope photograph of a textile loaded with microcapsules according to the invention after 30 washes, wherein the active substance remaining on the textile can be recognized.
  • Preferred embodiments of the present invention relate to sportswear and other textile articles for use on the skin for improving skin elasticity, as well as for protection against UV radiation and cooling of the skin.
  • These garments or articles may consist of the above-described inventive fabric, such as a nylon / spandex blend, for example having a nylon content of about 75 to 85% and an elastane content of about 15 to 25%, such as a nylon content of about 78% and an elastane content of about 22%, or a nylon content of about 80% and an elastane content of about 20%, or a nylon content of about 82% and an elastane Share of about 18%.
  • a nylon / spandex blend for example having a nylon content of about 75 to 85% and an elastane content of about 15 to 25%, such as a nylon content of about 78% and an elastane content of about 22%, or a nylon content of about 80% and an elastane content of about 20%, or a nylon content of about 8
  • Textile includes trousers, long and short panties, briefs, panties, singlets, camisoles, sports bras, tops, bodysuits, bathing suits and pants, sports jerseys, biker pants, leotards, muscle shirts, socks, stockings, tights, leggings, leggings, T-shirts Shirts, thermal shirts, thermal underwear, corsetry, armwarmers, leg warmers, leg warmers, leggings, leggings, pajamas, corsets, sleeping masks, face masks, gloves and the like.
  • Other textile articles of the textile according to the invention include dressings, support bandages, protective bandages, envelopes, bandages, support bandages, sweatbands and diaper wraps.
  • the active substance-releasing textile By using the active substance-releasing textile according to the invention additional effects can be achieved, for example if the released active ingredients contain a skin care component and / or Q-10 and / or almond oil and / or aloe vera and / or menthol.
  • the following active ingredients may be present in the capsules alone or in combination: vitamin C, caffeine, carnitine, carotene, avocado oil, dexpanthenol, glyceryl-glucose, Cucumis sativus juice, tocopherol, tocopheryl acetate, corn oil, jojoba oil.
  • Perfumes are present. These may be selected from the group methyl dihydrojasmonate, phenethyl alcohol, linalyl acetate, 1, 3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran, methyl cedryl ketone, hexyl salicylate , 4-t-butylcyclohexyl acetate, tetrahydrolinalool, orange terpene, heliotropin, terpinyl acetate, omega-pentadecalactone, methyl-alpha-ionone, lavandin oil, lemon oil, 7-acetyl-1,1,1,4,4,6-hexamethyltetralin, coumarin, Amyl salicylate, 2-tert-pentylcyclohexyl acetate, 3-methyl-5-phenyl-1-pentanol, cedrole, benzyl benzoate, cash
  • the garments or textile articles may according to the invention be wholly or partly made of the textile according to the invention.
  • water retention (AG) and heat insulation of the wet textile (Ret * ) were measured.
  • the results shown in Table III are averages of three different measurements for samples A, B and C.
  • samples A and B according to the invention show consistently improved properties over comparison sample C for drying time and water retention, without the heat insulation of the wet textile being significantly impaired.
  • Sample A absorbs only very little water, whereby the drying time on the body is very short.
  • Samples A and B have a drying time of 21 minutes or less, while sample C has by far the highest water retention, and a drying time that is more than twice as long as in samples A and B according to the invention.
  • part of the present innovation are any one of the present innovation.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Organic Chemistry (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Gerontology & Geriatric Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Vascular Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Textile pour la confection de vêtements de sport, chargé de microcapsules frangibles en polyuréthane. Ce textile est un tricot constitué d'un mélange nylon-élasthanne, et les microcapsules sont conçues pour se rompre sous l'action d'une force mécanique et pour libérer leur contenu dans le textile. Ledit contenu contient une composition de soin de la peau. Ledit textile est caractérisé en ce que les microcapsules présentent une contrainte de rupture comprise entre 50 et 150 µN, et un diamètre compris entre 5 et 15 µm.
PCT/EP2014/078138 2013-12-18 2014-12-17 Textile à propriétés améliorées destiné à des vêtements de sport WO2015091599A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP14828021.7A EP3082674A1 (fr) 2013-12-18 2014-12-17 Textile à propriétés améliorées destiné à des vêtements de sport

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE202013011206.9 2013-12-18
DE102013226337.6A DE102013226337A1 (de) 2013-12-18 2013-12-18 Textil für wirkstofffreisetzende Bekleidung
DE201320011206 DE202013011206U1 (de) 2013-12-18 2013-12-18 Textil für wirkstofffreisetzende Bekleidung
DE102013226337.6 2013-12-18

Publications (1)

Publication Number Publication Date
WO2015091599A1 true WO2015091599A1 (fr) 2015-06-25

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PCT/EP2014/078138 WO2015091599A1 (fr) 2013-12-18 2014-12-17 Textile à propriétés améliorées destiné à des vêtements de sport
PCT/EP2014/078156 WO2015091608A1 (fr) 2013-12-18 2014-12-17 Textile pour des vêtements à libération de principe actif

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PCT/EP2014/078156 WO2015091608A1 (fr) 2013-12-18 2014-12-17 Textile pour des vêtements à libération de principe actif

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WO (2) WO2015091599A1 (fr)

Cited By (2)

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Publication number Priority date Publication date Assignee Title
DE102017001191A1 (de) 2017-02-09 2018-08-09 CI Consult International UG (haftungsbeschränkt) & Co. KG Funktions-Oberkörperbekleidung zur Körperoberflächentemperaturverteilungsoptimierung und gezielter Körper-Zonen-Temperaturniveau-Beeinflussung
CN109402838A (zh) * 2018-12-25 2019-03-01 东丽酒伊织染（南通）有限公司 一种低透气性防风高挺阔复古感面料及其制备方法

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ES2849826A1 (es) * 2020-02-22 2021-08-23 Patino Marcela Viviana Sinisterra Pijama con textil inteligente

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WO2010006442A1 (fr) 2008-07-18 2010-01-21 Biomod Inc. Articles manufacturés libérant un ingrédient actif
DE102009002174A1 (de) * 2009-04-03 2010-02-11 Henkel Ag & Co. Kgaa Ölhaltige Mikrokapseln für flüssige Wasch- oder Reinigungsmittel
DE202013005558U1 (de) 2013-06-19 2013-07-26 Norbert Neubauer Pflegesocke
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DE10023629A1 (de) * 2000-04-29 2001-11-08 Deotexis Inc Textilmaterial und Verfahren zum Herstellen eines solchen
DE10241000A1 (de) * 2001-09-10 2003-03-27 Bayer Ag Mikrokapsel-haltige Vliese
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