Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
  • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10165—Functional features of the laminated safety glass or glazing
  • B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10165—Functional features of the laminated safety glass or glazing
  • B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
  • B32B17/10201—Dielectric coatings
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10165—Functional features of the laminated safety glass or glazing
  • B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
  • B32B17/1022—Metallic coatings
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
  • B32B17/10559—Shape of the cross-section
  • B32B17/10568—Shape of the cross-section varying in thickness
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
  • B32B17/10614—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising particles for purposes other than dyeing
  • B32B17/10633—Infrared radiation absorbing or reflecting agents
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
  • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
  • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
  • C08J7/04—Coating
  • C08J7/06—Coating with compositions not containing macromolecular substances
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
  • C09D5/32—Radiation-absorbing paints
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2250/00—Layers arrangement
  • B32B2250/02—2 layers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2250/00—Layers arrangement
  • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2307/00—Properties of the layers or laminate
  • B32B2307/40—Properties of the layers or laminate having particular optical properties
  • B32B2307/412—Transparent
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2605/00—Vehicles
  • B32B2605/006—Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/20—Filters
  • G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation

Definitions

• the present invention relates to a method for producing laminated glass sheets having heat-shielding properties by using an interlayer film based on polyvinyl acetal having a heat-shielding coating.
• interlayer films which contain in volume IR absorber.
• nanoscale semiconductor particles such as ITO or ATO
• a disadvantage of this is the limited recyclability of the film, which also has increased production costs.
• Another disadvantage is the difficulty of maintaining the nanoscale distribution of the particles in a film matrix during an extrusion process in the presence of various other ingredients so that agglomeration of the nanoparticles does not result in unacceptable haze.
• WO 2005/059013 A1 proposes the application of heat-absorbing nanoparticles by printing on PVB film with special printing inks.
• the printing may adversely affect the adhesion properties of the film to the glass surface. Due to the fact that PVB films must have a roughened surface for easy removal of the air in a lamination process, it is likely that a layer which is partially absorbed by the visible layer, after being pressed with a glass surface, is visually non-uniform. In addition, the printing of thick plasticized film webs is difficult, since such films lengthen on unwinding and then shrink back.
• the object of the present invention was therefore to provide interlayer films which have heat-shielding properties without having to disperse nanoscale semiconductor particles in the volume of the interlayer film.
• the invention therefore provides a process for the production of heat-shielding laminated glass laminate by bonding two transparent panes with at least one film A and at least one film B, characterized in that the film A and B are positioned between the two transparent panes and stick together
• Film A has a polyvinyl acetal PA and 0 to 16% by weight of at least one plasticizer WA and a heat-shielding coating
• film B has a polyvinyl acetal PB and at least 16% by weight of at least one plasticizer WB.
• heat-shielding coating layers of heat-shielding material applied to the surface of the film without the heat-shielding material being dispersed in the volume of the interlayer film.
• the heat-shielding coating can consist of a film which is completely or partially sheet-like, but can also be composed of discrete structures such as printed conductors, wires, nets constructed therefrom, dots, and combinations thereof.
• the transparent panes may be the same or different from PMMA or polycarbonate glass.
• glass pane or “glass surface” are used synonymously with the terms “transparent pane” or “surface of the transparent pane”.
• the method according to the invention can be carried out by positioning the intermediate layer on a transparent pane by positioning film A on a transparent pane on which film B and a second transparent pane are placed. Alternatively, it is possible to position film B on a transparent disk on which film A and a second transparent disk are then placed.
• the transparent panes can be connected to one another by the layer sequence film A / film B / film A, that is glued or laminated.
• the transparent panes can be connected to one another by the layer sequence foil B / foil A / foil B.
• Heat-shielding coatings on film A used according to the invention preferably have quotients of TL / TTS of more than 1.2 or of more than 1.25 or of more than 1.30 or of more than 1.35 or of more than 1.40 or of more than 1.45.
• the films A have a heat-shielding coating on one or both surfaces.
• Heat-shielding coatings according to the invention include coatings which absorb infrared radiation as well as coatings which reflect infrared radiation and conceivable combinations of both mechanisms in a coating or combinations of different absorbent and reflective layers.
• the heat-shielding coating may be formed by various methods such as uniformly applying liquid suspensions to a film web, such as a film. Dip coating, curtain coating, reverse gravure coating and slot coating are applied. In these cases, the suspensions and the resulting heat-shielding coatings preferably contain heat-absorbing semiconductor particles.
• the coatings used according to the invention may consist entirely of heat-shielding material such as heat-absorbing nanoparticles.
• the weight fraction of heat-shielding material in the heat-absorbing coatings after drying may be between 10% -80% and preferably between 30% -60%.
• heat-shielding layers can also be applied to the film A by means of printing methods.
• patterns of different geometries e.g. grid-shaped or in the form of pixels, to be printed.
• printable or wet-coating methods include one or more solvents and binders.
• the solvent contains water and or alcohols such as methanol, ethanol.
• it may also contain ethers such as butyl glycol, amides such as dimethylformamide (DMF) or plasticizers.
• Polyvinyl acetals, polyvinyl alcohols of various degrees of hydrolysis, acrylic polymers and other polymers or condensates can be used as binders.
• the binder is a polyvinyl acetal or a polyvinyl alcohol. It is particularly preferred to use as binder the same polyvinyl acetal which was also used to prepare the film A.
• semiconductor particles in the heat-shielding coating e.g. ITO, ATO, AZO, IZO, zinc antimonates, tin-doped zinc oxide, silicon-doped zinc oxide, gallium-doped zinc oxide, tungstates, e.g. LiWO3, NaWO3, CsWO3, lanthanum hexaboride or cerium hexaboride.
• said materials are in the form of finely divided particles, e.g. so-called nanoparticles.
• the size of the primary particles is preferably less than 1 ⁇ m.
• the coatings used according to the invention preferably have layer thicknesses in the range from 1 to 50 ⁇ m, particularly preferably in the range from 2 to 30 ⁇ m and most preferably in the range from 3 to 15 ⁇ m.
• the heat-shielding coatings can also be obtained by chemical vapor deposition (CVD), physical vapor deposition (PVD) or cathode sputtering or electrolytic deposition on the film A.
• CVD chemical vapor deposition
• PVD physical vapor deposition
• cathode sputtering electrolytic deposition
• electrolytic deposition on the film A.
• coatings which reflect infrared radiation they may contain, in addition to optional dielectric layers, metals such as silver, aluminum, gold, chromium or indium.
• Coatings produced in this manner according to the invention have layer thicknesses in the range of 0.01-5 ⁇ m, preferably in the range of 0.05-2 ⁇ m, used in accordance with the invention.
• the films A and B may contain a single plasticizer as well as mixtures of plasticizers of both different and the same composition in the initial state before laminating the layers as well as in the interlayer stack located in the laminated glass laminate.
• different composition is meant both the nature of the plasticizers and their proportion in the mixture.
• the film A and film B after laminating i. in the finished laminated glass the same plasticizer WA and WB.
• the film A contains no plasticizer in its initial state and, after lamination, the plasticizer WB.
• Plasticizer-containing films B used according to the invention in the initial state before lamination of the layers contain at least 16% by weight, such as 16.1-36.0% by weight, preferably 22.0-32.0% by weight and in particular 26.0-30.0% by weight plasticizer.
• Films A used in the present invention, prior to lamination of the layers, may be less than 16 weight percent (such as 15.9 weight percent), less than 12 weight percent, less than 8 weight percent, less than 6 weight percent, in the initial state. less than 4% by weight, less than 3% by weight, less than 2% by weight, less than 1% by weight, each having the lower limit of 0% by weight of at least one plasticizer WA.
• the low-plasticizer films A preferably contain from 0.0 to 8% by weight of at least one plasticizer WA.
• the film A in the initial state before the lamination of the layers has a thickness of not more than 20%, preferably 15% and preferably not more than 10% of the thickness of the film or the films B.
• the thickness of the film A includes the heat-shielding coating.
• the thickness of a film A in the initial state before laminating the layers is 10-150 ⁇ m, preferably 20-120 ⁇ m, preferably 30-100 ⁇ m, preferably 40-80 ⁇ m and most preferably 50-70 ⁇ m.
• the thickness of the film increases due to the transition of plasticizer from film B.
• Film A is produced separately from film B (e.g., extruded and either does not have any plasticizer or plasticizer portion so low that it neither stretches too much nor is too tacky during mechanical stressing and processing).
• the thickness of a film B in the initial state is 450-2500 ⁇ m, preferably 600-1000 ⁇ m, preferably 700-900 ⁇ m.
• films B are stretched prior to making the sandwich and / or additionally arcuately conformed to the shape of a disk (e.g., windshield), the indicated thicknesses at the time of lamination may be reduced by as much as 20%.
• At least one thin film A with the heat-insulating coating is oriented to a glass surface of the laminated glass laminate according to the invention.
• the film A can in this case be applied to the surface, which has the heat-insulating coating or the surface, which does not have the heat-insulating coating, on the glass surface.
• a film A to both glass surfaces, so that a laminated glass laminate with a layer sequence of glass / film A / film B / film A / glass is present.
• the decoration of the films A may be the same or different.
• one of the films A may have the heat-insulating coating and the second film A may have other layers with optical or electrical functions.
• the plasticizer-poor film A can be cut and positioned so that it does not reach all the way to the edge of the laminate in the laminated glass laminate.
• the film A in the edge region can be smaller by at least 1 mm than at least one glass pane so that the film B is in direct contact with at least one glass pane in this edge region.
• the thin, low-plasticizer or plasticizer-free film A in the initial state can be perforated prior to insertion into the glass / film sandwich, so that it can have recesses such as openings, holes, slots in any geometric patterns.
• the film A may have at least one recess, so that the film B through this recess in direct contact with at least one glass sheet.
• the film B is glued with in the initial state higher plasticizer content at these points with the glass without interruption.
• recesses can thus be obtained at locations of the laminated glass, behind which sensor, optical, antenna elements would otherwise be impaired by a heat-shielding layer in their function.
• the films A and B used according to the invention contain polyvinyl acetals which are prepared by acetalization of polyvinyl alcohol or ethylene-vinyl alcohol copolymer.
• the films may contain polyvinyl acetals, each with different polyvinyl alcohol content, degree of acetalization, residual acetate content, ethylene content, molecular weight or different chain lengths of the aldehyde of the acetal groups.
• the aldehydes or keto compounds used to prepare the polyvinyl acetals may be linear or branched (i.e., of the "n” or “iso” type) of 2 to 10 carbon atoms, resulting in corresponding linear or branched acetal groups.
• the polyvinyl acetals are accordingly referred to as “polyvinyl (iso) acetals” or “polyvinyl (n) acetals”.
• the polyvinyl (n) acetal used according to the invention results in particular from the reaction of at least one polyvinyl alcohol with one or more aliphatic unbranched keto compounds having 2 to 10 carbon atoms.
• n-butyraldehyde is used for this purpose.
• the polyvinyl alcohols or ethylene-vinyl alcohol copolymers used to prepare the polyvinyl acetals in films A or B may each be the same or different, pure or a mixture of polyvinyl alcohols or ethylene-vinyl alcohol copolymers having different degrees of polymerization or degree of hydrolysis.
• the polyvinyl acetate content of the polyvinyl acetals in the films A or B can be adjusted by using a polyvinyl alcohol or ethylene-vinyl alcohol copolymer saponified to a corresponding degree.
• the polyvinyl acetate content influences the polarity of the polyvinyl acetal, which also changes the plasticizer compatibility and the mechanical strength of the respective layer. It is also possible to carry out the acetalization of the polyvinyl alcohols or ethylene-vinyl alcohol copolymers with a mixture of several aldehydes or keto compounds.
• the films A or B preferably contain polyvinyl acetals with a proportion of polyvinyl acetate groups, based on the layers, in each case identically or differently, 0.1 to 20 mol%, preferably 0.5 to 3 mol% or 5 to 8 mol%.
• the polyvinyl alcohol content of the polyvinyl acetal PA used in the lower plasticizer A film can between 6 - 26 wt .-%, 8 - 24 wt .-%, 10 - 22 wt .-%, 12 - 21 wt .-%, 14 - 20 wt .-%, 16 to 19 wt .-% and preferably between 16 and 21 wt .-% or 10 - 16 wt .-% amount.
• the polyvinyl alcohol content of the polyvinyl acetals PB used in the plasticizer-rich film B in the starting state can be between 14-26% by weight, 16-24% by weight, 17-23% by weight and preferably between 18 and 21% by weight.
• the films A or B preferably contain uncrosslinked polyvinyl acetal.
• the use of crosslinked polyvinyl acetals is also possible.
• Methods for crosslinking polyvinyl acetals are e.g. in EP 1527107 B1 and WO 2004/063231 A1 (thermal self-crosslinking of polyvinyl acetals containing carboxyl groups), EP 1606325 A1 (polyvinyl acetals crosslinked with polyaldehydes) and WO 03/020776 A1 (polyvinyl acetals crosslinked with glyoxylic acid).
• plasticizers are high boiling organic liquids. For this reason, other types of organic liquids with a boiling point higher than 120 ° C can be used as a plasticizer.
• the films contain A in the variants in which a plasticizer WA is present in film A in AusgansPark and films B 1,2-Cyclohexandicarbon Acidiisononylester (DINCH) or triethylene glycol bis-2-ethylhexanoate (3GO or 3G8) as a plasticizer.
• a plasticizer WA is present in film A in AusgansPark and films B 1,2-Cyclohexandicarbonkladiisononylester (DINCH) or triethylene glycol bis-2-ethylhexanoate (3GO or 3G8) as a plasticizer.
• films A and B may contain other additives such as residual amounts of water, UV absorbers, antioxidants, adhesion regulators, optical brighteners or fluorescent additives, stabilizers, colorants, processing aids, organic or inorganic nanoparticles, fumed silica and / or surface-active substances included .
• film B as adhesion regulators may have from 0.001 to 0.1% by weight of alkali metal and / or alkaline earth metal salts of carboxylic acids.
• the anticorrosive agent may be contained before lamination in film B and pass during and after the bonding with film A by diffusion in the thinner film A and in the range of their coating.
• the corrosion inhibitor before lamination is already contained in film A.
• Preference is given to using corrosion inhibitors in amounts of 0.005 to 5% by weight in film B and / or A.
• Preference is given to using unsubstituted or substituted benzotriazoles as corrosion inhibitors.
• the film A has less than 150 ppm of chloride ions and / or nitrate ions and / or sulfate ions.
• the chloride content of the film A may be less than 150 ppm, preferably less than 100 ppm and in particular less than 50 ppm. Ideally, the chloride content of the film A is less than 10 ppm or even 0 ppm.
• the nitrate content of the film A film can be less than 150 ppm, preferably less than 100 ppm and in particular less than 50 ppm. Ideally, the nitrate content of the film A is less than 10 ppm or even 0 ppm.
• the sulphate content of the film A film can be less than 150 ppm, preferably less than 100 ppm and in particular less than 50 ppm. Ideally, the sulphate content of film A is less than 10 ppm or even 0 ppm.
• film A may contain more than 0 ppm of magnesium ions.
• the magnesium content is preferably more than 5 ppm, more preferably 10 ppm, in particular 5-20 ppm
• the films A and B can be positioned together between two glass sheets and fused at elevated temperature.
• the gluing of the transparent slices through the films A and B, i. the laminating step for producing a laminated glass is preferably carried out so that the films A and B are positioned between two glass sheets and the thus prepared composite is pressed under increased or reduced pressure and elevated temperature to form a laminate.
• vacuum laminators consist of a heatable and evacuable chamber, in which laminated glazing can be laminated within 30 - 60 minutes. Reduced pressures of 0.01 to 300 mbar and temperatures of 100 to 200 ° C, in particular 130-160 ° C have proven in practice.
• film A or B is positioned on a glass pane and synchronously or subsequently the further film B or A. Subsequently, the second glass pane is placed and a glass-film composite is produced. Excess air may thereafter be removed by any pre-bonding technique known to those skilled in the art. This is also already a first slight bonding of the layers with each other and with the glass.
• the glass-film composite can finally be subjected to an autoclave process.
• film A is positioned on the first glass sheet and covered with the thicker film B before the second glass sheet is laid up.
• the method can be carried out in many conceivable and basically practicable variants.
• film A is simply taken from a roll of appropriate width whereas film B was previously cut to size of the laminated glass to be produced. This is particularly advantageous in the case of windshields and other automotive glazing parts. In this case, it is particularly advantageous to additionally stretch the thicker film B before cutting. This allows a more economical use of foil or, in the case that foil B has a color wedge, adapting its curvature to the upper edge of the disc.
• films are frequently used which have a so-called ink ribbon in the upper region.
• the upper part of the films A and B can be co-extruded with a correspondingly colored polymer melt or, in a multi-layer system, one of the films A and B can have a different coloration in some areas. In the present invention, this can be achieved by completely or partially coloring at least one of the films A and B.
• the foils B can therefore have a color wedge, which in particular has already been adapted in an upstream process step to the geometry of a windshield.
• the films B have a wedge-shaped thickness profile.
• the laminated glass laminate according to the invention obtains a wedge-shaped thickness profile even with plane-parallel thickness profile of the film A and can be used in automotive windscreens for HUD displays.
• the film B is a commercially available PVB film with or without ribbon and with or without a wedge-shaped thickness profile. Also, films B with nanoparticles dispersed therein for IR protection as well as colored films may be used. Of course, a film B may also be a film with an acoustic function, so that by combining with a film A improved Schalldämmeigenschaften be obtained. Of course, a film B can already combine several of these functions in itself.
• the preparation of the thin films A is usually carried out by extrusion using a cast film line or as a blown film.
• a surface roughness by controlled flow break or the cast-film process can additionally be done by using a structured chill roll.
• an already produced film can be impressed by a stamping process between at least one pair of rollers a regular, non-stochastic roughness.
• Films used according to the invention preferably have a one-sided surface structure with a roughness Rz of 0 to 25 ⁇ m, preferably Rz of 1 to 20 ⁇ m, particularly preferably Rz of 3 to 15 ⁇ m and in particular Rz of 4 to 12 ⁇ m. It is particularly preferred if the side of the film A coming into contact with the glass pane has a surface roughness Rz of not more than 20% of its thickness.
• the surface provided with the heat-shielding coating preferably has a particularly low surface roughness before application of the coating. In particular, here the roughness parameter Ra is less than 3 ⁇ m and Rz is less than 5 ⁇ m.
• the films for (comparative) Examples 1-4 were made on a small extruder with a chill roll unit of 35 cm width in the indicated thicknesses with the indicated amounts and types of plasticizer.
• the polyvinyl butyral (Mowital® B60H from Kuraray Europe GmbH) used had a PVOH content of 19.8% by weight and a residual acetate of 1% by weight.
• the starting films A were provided by hand with the coating shown in the table (Examples 2, 3, 4).
• the application was carried out in suspension with a laboratory doctor blade and, after drying, resulted in a layer thickness of the coating of about 5 ⁇ m.
• the films were stored in a climate of 23 ° C / 23% RH prior to further processing.
• TROSIFOL VG R10 0.76 is a commercial uncoloured, standard automotive film with a uniform thickness profile for lamination of windscreens in a thickness of 760 microns, with a plasticizer content of 27.5 wt .-%.
• the PVB batch used for production had a PVOH content of 20.3% by weight.
• the glass transition temperature (TB) was measured to be 19.2 ° C.
• the lower discs were placed on a laying table and the films A of Examples 1-4 (V1 is comparative example without coating) are each unwound from a roll over it.
• a sheet of film B (TROSIFOL VG R10) was placed over it, before the sandwich was completed by placing the upper Planilux disk. Protruding film was cut flush with a sharp knife.
• the sandwiches were pre-bonded by an industry standard Walzenvorverbundstrom, so that the glass surface temperature was 65 ° C when exiting the plant, and finally glued for 90 minutes in an autoclave at maximum 140 ° C and 12 bar pressure to the final composite.
• test laminates with good heat-shielding properties could thus be produced in a simple manner.

Landscapes

• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Wood Science & Technology (AREA)
• Joining Of Glass To Other Materials (AREA)
• Laminated Bodies (AREA)

Priority Applications (4)

Applications Claiming Priority (2)

Publications (1)

Family

ID=49759017

Family Applications (1)

Country Status (5)

Cited By (4)

Families Citing this family (7)

Citations (2)

Family Cites Families (17)

• 2013
  • 2013-11-29 EP EP13195122.0A patent/EP2878442A1/de not_active Withdrawn
• 2014
  • 2014-11-27 EP EP17191985.5A patent/EP3281785A1/de not_active Withdrawn
  • 2014-11-27 EP EP14805576.7A patent/EP3074220B1/de active Active
  • 2014-11-27 JP JP2016534984A patent/JP6444407B2/ja not_active Expired - Fee Related
  • 2014-11-27 CN CN201480063904.7A patent/CN105722678B/zh active Active
  • 2014-11-27 WO PCT/EP2014/075853 patent/WO2015078989A1/de not_active Ceased
  • 2014-11-27 US US15/036,500 patent/US10099451B2/en active Active
• 2017
  • 2017-10-31 JP JP2017211029A patent/JP6726151B2/ja active Active

Patent Citations (2)

Also Published As

Similar Documents

Legal Events