WO2015073372A2 - Système régénérable pour éliminer les composés soufrés d'un flux gazeux - Google Patents
Système régénérable pour éliminer les composés soufrés d'un flux gazeux Download PDFInfo
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- WO2015073372A2 WO2015073372A2 PCT/US2014/064832 US2014064832W WO2015073372A2 WO 2015073372 A2 WO2015073372 A2 WO 2015073372A2 US 2014064832 W US2014064832 W US 2014064832W WO 2015073372 A2 WO2015073372 A2 WO 2015073372A2
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
- B01D53/82—Solid phase processes with stationary reactants
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0233—Compounds of Cu, Ag, Au
- B01J20/0237—Compounds of Cu
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/024—Compounds of Zn, Cd, Hg
- B01J20/0244—Compounds of Zn
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- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
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- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
- B01J20/28007—Sorbent size or size distribution, e.g. particle size with size in the range 1-100 nanometers, e.g. nanosized particles, nanofibers, nanotubes, nanowires or the like
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- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28016—Particle form
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
- B01J20/28064—Surface area, e.g. B.E.T specific surface area being in the range 500-1000 m2/g
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
- B01J20/28076—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being more than 1.0 ml/g
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
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- B01J20/28078—Pore diameter
- B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
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- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
- B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
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- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
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- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
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- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
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- B01D2253/1124—Metal oxides
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- B01D2253/25—Coated, impregnated or composite adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D2257/308—Carbonoxysulfide COS
Definitions
- the invention relates to sorbent materials and to processes for preparing and using the sorbents. More specifically, the invention relates to highly regenerable sorbents, and to processes for removing sulfur compounds, particularly H2S, from gas streams.
- H2S high-strength sulfur
- sulfur compounds include, but are not limited to, fuel gases, Claus plant tail gases, and hydrocarbon feeds for refining and other processes.
- the removal of sulfur compounds from gas streams is an important part of industrial processes including those used in petroleum refining operations. Sulfur is both an environmental hazard when it is a contaminant in fuel for combustion and a poison for several catalytic materials when used in electrochemical systems such as fuel cells.
- the present invention provides sorbent compositions capable of removing sulfur compounds from a gas stream.
- the sorbent compositions are highly regenerable, and can readily be produced with the necessary sulfur capacity (meeting current environmental regulations), stability, and mechanical strength properties, allowing their use across a wide temperature range including relatively low temperatures and relatively high temperatures.
- the sorbent compositions lower capital and operating costs associated with sulfur removal and are in a suitable physical form and size for a small footprint and low maintenance process.
- the present invention provides a sulfidized sorbent composition
- a sulfidized sorbent composition comprising a porous silica support material impregnated with CuO nanoparticles, wherein the nanoparticles are essentially uniformly distributed throughout the porous silica support and sulfur compounds are adsorbed on the nanoparticles.
- the silica support material can have a median pore diameter of about 5 to about 50 nm, or about 5 to about 15 nm, or about 7 to about 8 nm, or about 8 nm.
- the nanoparticles can have an average diameter of about 3 to about 6 nm, or less than about 6 nm, or about 5 nm.
- the CuO nanoparticles can further comprise Zn.
- the Cu/Zn molar ratio can be in the range of about 20: 1 to about 1 : 1.
- the porous silica support can have a pore volume in the range of about 0.3 to about 3.0 ml/g.
- the average interparticle distance between the nanoparticles can be at the theoretical maximum distance.
- the silica support material can also have a surface area of about 100 to about 1000 m 2 /g, or about 750 m 2 /g.
- the silica support material can comprise SBA silica, MCM silica or silica gel.
- the sulfur compounds can comprise H2S.
- Another embodiment of the present invention provides a method of preparing a sulfidized sorbent composition comprising a porous silica support material impregnated with Cu-ZnO nanoparticles, wherein the nanoparticles are essentially uniformly distributed throughout the porous silica support and sulfur compounds are adsorbed on the nanoparticles, the method comprising:
- the zinc salt can include zinc nitrate, zinc acetate, or a mixture thereof; and the copper salt can include copper nitrate, copper acetate, and a mixture thereof.
- the step of impregnating can be performed by incipient wetness impregnating.
- the step of drying can be performed by vacuum drying. The vacuum drying can be performed at room temperature.
- the calcinating can be performed by heating the dried particles to a temperature range of about 200-600 °C, or about 500 °C. The calcinating can be performed in an inert gas.
- a method of removing sulfur compounds adsorbed to the sulfidized sorbent composition comprising heating the sulfidized sorbent composition to a temperature between about 100-700 °C and passing an oxidizing agent over the sorbent composition.
- the sulfidized sorbent composition can be heated to a temperature between about 400-550 °C.
- the oxidizing agent can include air, pure oxygen, diluted oxygen, ozone, and hydrogen peroxide, or a combination thereof.
- the diluted oxygen can be 1-5 mol% oxygen in an inert carrier gas.
- the method can further include the step of passing a reducing agent over the sorbent composition after the oxidation step.
- the reducing agent can include hydrogen, methane, and carbon monoxide gas, or a mixture thereof.
- the reducing agent is hydrogen gas
- the hydrogen gas can be 1-10 mol% hydrogen in an inert carrier gas.
- the method can further include a step of passing an oxidizing agent over the sorbent composition after the reduction step.
- the oxidation-reduction-oxidation cycle can be repeated in tandem at least two times, or about three, four, five or greater than five times.
- the adsorbent can be flushed with an inert gas between each oxidation-reduction-oxidation cycle.
- the inert gas can be nitrogen gas.
- a method for removing sulfur compounds from a gas stream comprising passing the gas stream through an effective amount of a sorbent composition for an effective amount of time to produce a sulfidized sorbent composition and to reduce sulfur compounds in the gas stream to a level of less than about 1 ppm, the sorbent composition comprising a porous silica support material impregnated with CuO nanoparticles, wherein the nanoparticles are essentially uniformly distributed throughout the porous silica support.
- the gas steam can be heated to a temperature of less than about 400 °C before being passed through the sorbent composition.
- the gas stream can be heated at a temperature range of about 150 to about 250 °C.
- the sulfur compounds in the gas stream can include H2S, COS, SO2, CS2, and S2.
- the gas stream can be treated with a hydrogenating agent before being passed through the sorbent composition.
- the hydrogenation agent can be hydrogen gas.
- the sulfur compounds in the gas stream can be primarily H2S.
- the H2S concentration in the gas stream can be lower than 1%.
- the nanoparticles further include Zn.
- the Cu/Zn molar ratio can be in the range of about 20: 1 to about 1 : 1.
- the Cu-ZnO nanoparticles further comprise aluminum oxides.
- the Cu/Zn molar ratio is in the range of about 20: 1 to about 1 : 1 and the minimum Cu/Al molar ratio is 10.
- the method can further include a step of removing the sulfur compounds adsorbed to the sulfidized sorbent composition by heating the sulfidized sorbent composition to a temperature between about 100-700 °C and passing an oxidizing agent over the sorbent composition.
- the sulfidized sorbent composition can be heated to a temperature between about 400-550 °C.
- sorbent compositions are employed in filtering systems in preferred
- the filtering system may be contained in a cartridge or in a gas stream filter assembly.
- Figure 1 is a schematic representation of a desulfurization process of the invention.
- Figure 2 depicts the results of a low angle XRD experiment showing patterns of SBA- 15 and copper-zinc impregnated SBA-15.
- the inset in the figure shows wide angle patterns.
- Figure 3 shows argon adsorption-desorption isotherms for SBA-15 and Cu-ZnO- SBA-15 measured at 87 K. Pore size distribution (inset) was obtained using the NLDFT equation (silica, cylindrical pores).
- Figure 4 shows an HAADF STEM image of sulfidized Cu-ZnO-SBA-15.
- Figure 5 shows breakthrough curves of cyclic adsorption/regeneration tests on Cu- ZnO-SBA-15.
- Figure 6 shows breakthrough curves of cyclic adsorption/regeneration tests on Cu- ZnO-SBA-15.
- Figure 7 shows breakthrough curves of cyclic adsorption/regeneration tests on Cu- ZnO-silica gel.
- Figure 9 shows breakthrough curves of cyclic adsorption/regeneration (14 cycles) tests on Cu-ZnO-Ai203 adsorbent.
- the sorbent compositions of the invention can include a porous support material.
- the disclosed supports may include porous silicon dioxide materials (mesoporous silica- pore size range 2-50 nm) with ordered or disordered pore structure (e.g. SBA-15, SBA-16, MCM-41, MCM-48, KIT-6, FDU-12, and silica gel).
- silicon dioxide refers to "silica” having the formula S1O2. Silicon dioxide may form a porous support, such as porous particles, which may be impregnated with sorbent material as disclosed herein.
- the silica support material can have a median pore diameter of about 5 to about 50 nm, about 5 to about 15 nm, about 7 to about 8 nm, or about 8 nm.
- Median pore diameter can be measured using methods known to those of ordinary skill in the art, for example, by standard nitrogen or argon adsorption analysis.
- the porous silica support has a pore volume in the range of about 0.3 to about 3.0 ml/g. In some embodiments, the silica support has a surface area of about 100 to about 1000 m 2 /g, or about 750 m 2 /g. Specific surface area can be calculated using conventional methods, including the Brunauer-Emmett-Teller (BET) theory.
- BET Brunauer-Emmett-Teller
- the sorbent compositions may be impregnated with copper material.
- Copper material may include copper metal, copper oxides, and copper salts (e.g., copper nitrate and copper acetate). After the disclosed sorbent compositions have been calcined, preferably the compositions comprise copper metal or copper oxide.
- the sorbent compositions may also be impregnated with zinc material.
- Zinc material may include zinc metal, zinc oxides, and zinc salts (e.g., zinc nitrate and zinc acetate). After the disclosed sorbent compositions have been calcined, preferably the compositions comprise zinc metal or zinc oxide.
- impregnated refers to the introduction of a solution to a porous support material.
- impregnated means that the solution has permeated the support material or that the support material has become infused with the solution. "Coating” on the other hand only indicates that a layer of the solution has been deposited on the outer surface of the support material.
- the silica support is impregnated with CuO nanoparticles.
- the nanoparticles have an average diameter of about 1 to about 8 nm or about 3 to about 6 nm or about 6 nm or about 5 nm. Nanoparticle diameter can be measured using analytical methods known to those of ordinary skill in the art, for example, by transmission electron microscopy (TEM).
- TEM transmission electron microscopy
- the silica support is impregnated with Cu-ZnO nanoparticles.
- the Cu/Zn molar ratio is in the range of about 20: 1 to about 1 : 1.
- the sorbent can also be unsupported copper-zinc-aluminum oxides. Copper/zinc molar ratio is between 20: 1 to 1: 1 with a minimum Cu/Al ratio of 10.
- the nanoparticles are essentially uniformly distributed throughout the porous silica support. As used herein the term “essentially uniformly distributed” means that the nanoparticles are evenly distributed throughout the entire pore system. In some
- the nanoparticles are spaced at equally sized and maximally spaced distances. Without being bound by any theory of the invention, it is believed that the uniform distribution of the nanoparticles on the support contribute to the high stability achieved in the sorbent compositions of the invention.
- the sulfur compounds are adsorbed on the nanoparticles.
- sulfur compounds may include, sulfur, hydrogen sulfide (H2S), carbonyl sulfide (COS) and other sulfur compounds such as SO2, CS2, and S2.
- Organosulfur compounds of the invention include compounds such as mercaptans or those thiophenic compounds found in cracked gasolines, which include, among others, thophene, benzothiophene, alkyl thophenes, alkyl benzothiophenes, and alkyldibenzothiophenes.
- the sorbents of the invention have a high sulfur capacity.
- One method of expressing sulfur capacity is miligrams sulfur per gram of sorbent (mgS/g).
- the sorbents provide a sulfur removal capacity in the range of about 60 to about 300 mgS/g.
- the sorbent compositions may be prepared by the following steps:
- the silica support material is impregnated with an aqueous solution of zinc salt and copper salt having a molar ratio of Cu:Zn of about 2: 1.
- the zinc salt can include zinc nitrate, zinc acetate, and a mixture thereof; and the copper salt can include copper nitrate, copper acetate, and a mixture thereof.
- the sorbent composition can be converted to a sulfidized sorbent composition by passing a gaseous stream of sulfur compounds through the impregnated support material.
- the step of impregnating can be performed by incipient wetness impregnating.
- the step of drying can be performed by vacuum drying.
- the vacuum drying can be performed at room temperature.
- the calcinating can be performed by heating the dried particles to a temperature range of about 200-600 °C, or 500 °C.
- the calcinating can be performed in an inert gas.
- the sorbent compositions may be utilized in methods for treating gaseous streams, liquid streams or both.
- the sorbent composition is utilized to treat a hydrocarbon stream (e.g., a fuel stream).
- the sorbent is utilized to treat a hydrocarbon stream (e.g., a fuel stream).
- the sorbent is utilized to treat a hydrocarbon stream (e.g., a fuel stream).
- compositions are utilized for treating gaseous streams containing sulfur compounds in Claus process tail gas or remote small natural gas processing units, syngas (H2/CO) clean-up, and potential automobile exhausts.
- sulfur compounds are removed from a gas stream, by passing the gas stream through an effective amount of a sorbent composition for an effective amount of time to produce a sulfidized sorbent composition and to reduce sulfur compounds in the gas stream to a level of less than about 1 ppm (or about 1 to 3 ppm, or about 1 to 5 ppm).
- the gas steam is heated to a temperature of less than about 400 °C (or about 150 to 250 °C) before being passed through the sorbent composition.
- the gas stream (e.g., Claus tail gas) is treated with a hydrogenating agent before being passed through the sorbent composition. This ensures that a significant portion of the gas is converted to H2S.
- reducing gases present in the tail gas e.g. H2, CO, H2O
- the hydrogenation agent is hydrogen gas.
- the sulfur compounds in the gas stream are primarily H2S. In some embodiments, the H2S concentration in the gas stream is lower than 1%.
- the sorbent compositions are highly regenerable.
- "regnerability” relates to the ability of the same sorbent to be used for multiple cycles of adsorption after stripping the adsorbed species (e.g., H2S) and then to be used for subsequent cycles of adsorption.
- the sorbent compositions do not exhibit substantially reduced sulfur capacity after regeneration in comparison to a sorbent composition that has not been regenerated.
- the regenerated sorbent has a sulfur capacity that is at least about 60% of that of the sorbent composition that has not been previously used, or preferably about 70%, or 80%, or 90% or 95% of the sorbent composition that has not been previously used.
- the sorbent composition is regenerated (i.e., the sulfur compounds adsorbed to the sorbent composition are removed) by heating the sulfidized sorbent composition to a temperature between about 100-700 °C (or about 400-550 °C) and passing an oxidizing agent over the sorbent composition.
- the oxidizing agent can include air, pure oxygen, diluted oxygen, ozone, and hydrogen peroxide, or a combination thereof.
- the oxidizing agent is diluted oxygen.
- the diluted oxygen is 1-5 mol% oxygen in an inert carrier gas.
- the regeneration step can involve several oxidation-reduction cycles.
- a reducing agent is passed over the sorbent composition after the oxidation step.
- the reducing agent includes hydrogen, methane, and carbon monoxide gas, or a mixture thereof.
- the hydrogen gas can contain 1-10 mol% hydrogen in an inert carrier gas.
- an additional step of passing an oxidizing agent over the sorbent composition after the reduction step is included.
- the oxidation-reduction-oxidation cycle can repeated in tandem at least 2 times (or 2-10 times in tandem).
- the adsorbent is flushed with an inert gas between each oxidation-reduction-oxidation cycle.
- the inert gas is nitrogen gas.
- the regeneration procedure can be sequentially performed by exposing the bed to oxidizing/reducing/oxidizing gas mixtures with flushing the bed with inert gas or steam in between.
- oxidizing gas and reducing gas can be 1-10 mol% hydrogen and 1-5 mol% O2 in balance inert gases, respectively.
- during the oxidation step converting copper sulfide to copper oxide at least some copper sulfate is formed. Sulfates can react with H2S present in the gas phase and contaminate the stream with SO2 during adsorption cycle. In order to eliminate this negative effect, sulfates can be reduced using reducing gases after oxidation.
- the metal copper In the final oxidation step, the metal copper can be converted to its oxide form which has a higher activity for sulfur removal.
- FIG. 1 A schematic showing a desulfurization process of the invention is shown in Figure 1.
- Ancillary equipment e.g., compressors, valves, heaters
- a Claus tail gas 4 is passed through a catalytic hydro-treating reactor 1 and effluent containing hydrogen sulfide 5 is passed through the online adsorption bed 2.
- the resulting effluent 7 contains sub-ppm levels of hydrogen sulfide.
- hydro-treated flow 4 is diverted to bed 2.
- an oxidizing stream 8 comprising an oxygen-containing gas in the temperature range 100-700 °C, preferably 400- 550 °C, is passed through the sulfided bed until complete regeneration (or any acceptable level) is achieved. Applying such low temperatures for regeneration is advantageous and permits construction of the sulfur removal unit with stainless steel, thereby lowering the capital cost of the unit.
- the effluent 6, containing sulfur dioxide, is returned to the Claus plant for sulfur capture.
- the method may be performed using a cyclic operation in a dual bed configuration with one active bed online until the breakthrough point is reached.
- the sorbent can then be regenerated in an oxidizing gas at temperatures up to 550°C.
- the sulfur dioxide-rich effluent can be returned to the Claus plant during the regeneration step.
- the hyro-treated stream can be directed to the second bed.
- the method can include two beds filled with sorbents of the invention working in cyclic fashion using operational procedures apparent to the skilled person.
- an adsorbent material composed of copper-zinc oxides on mesoporous silica (SBA-15) (Cu-ZnO-SBA-15) was prepared.
- SBA-15 was synthesized according to the procedure developed by Sayari et al. 1.0 mL of the above solution was added to lg SBA-15 in 0.2 mL batches. After impregnation, powders were vacuum dried at room temperature for 24h and then calcined at 500°C for 4h under a nitrogen flow of 50 mL/min.
- Argon adsorption isotherms (Figure 3) follow IV type with HI hysteresis; consistent with the mesostructure of SBA-15 with one-dimensional cylindrical channels.
- the cumulative pore volume obtained using NLDFT model on isotherms indicated that the cumulative pore volume decreased from 1.34 cc/g to 0.77 cc/g which can be attributed to the presence of nanoparticles in the pores.
- Embedding nanoparticles in SBA-15 resulted in a reduction in the median pore size from 7.9 nm to 7.6 nm.
- STEM-HAADF imaging of Cu-ZnO-SBA-15 after sulfidation revealed a very uniform distribution of copper-zinc sulfided nanoparticles ( ⁇ 5 nm) in SBA-15 ( Figure 4).
- the Cu-ZnO-SBA-15 adsorbent was exposed to a flow H2S (102 ppmv in He) at 150°C and 1 atm in a cyclic adsorption/regeneration fashion. Regeneration was conducted at 500°C under a flow of 5 mol% oxygen in nitrogen.
- Figure 5 shows the high performance of the adsorbent towards cyclic adsorption/regeneration.
- the adsorbent showed a high level of adsorption and regenerability performances towards a simulated gas (H2S 200 ppmv, CO 300 ppmv, C2H6 300 ppmv, CH 4 0.25%, Ar 0.59%, CO2 19.88, N2 79.2) at 150°C and 1 atm ( Figure 6).
- regeneration was also conducted at 500°C under a flow of 5 mol% oxygen in nitrogen.
- Cu-ZnO-silica gel was synthesized using the same procedure described in Example 1 with 0.75 ml of copper-zinc nitrate (4 M) solution.
- Figure 8 shows the XRD pattern of Cu-ZnO-AhCh.
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US15/036,315 US10112171B2 (en) | 2013-11-15 | 2014-11-10 | Regenerable system for the removal of sulfur compounds from a gas stream |
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Cited By (5)
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WO2017065749A1 (fr) * | 2015-10-13 | 2017-04-20 | Michael Tsapatsis | Matériau adsorbant pour l'élimination de sulfure d'hydrogène |
CN106947290A (zh) * | 2017-03-31 | 2017-07-14 | 合肥悦兰信息技术有限公司 | 彩色二氧化硅粉体材料的制备方法 |
WO2018231551A1 (fr) * | 2017-06-11 | 2018-12-20 | Msa Technology, Llc | Filtre pour composés soufrés |
CN111036218A (zh) * | 2019-12-19 | 2020-04-21 | 山东京博石油化工有限公司 | 一种用于醋酸仲丁酯加氢反应的催化剂及其制备方法和应用 |
CN111097363A (zh) * | 2018-10-25 | 2020-05-05 | 中国石油化工股份有限公司 | 硫、砷、磷净化剂及其制备方法 |
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US10112171B2 (en) | 2013-11-15 | 2018-10-30 | Regents Of The University Of Minnesota | Regenerable system for the removal of sulfur compounds from a gas stream |
FR3051459B1 (fr) * | 2016-05-20 | 2021-03-19 | Centre Nat Rech Scient | Installation et procede de traitement d'un flux comprenant du sulfure d'hydrogene |
SG11201908869YA (en) * | 2017-03-24 | 2019-10-30 | Univ Minnesota | Porous nanocomposites |
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WO2017065749A1 (fr) * | 2015-10-13 | 2017-04-20 | Michael Tsapatsis | Matériau adsorbant pour l'élimination de sulfure d'hydrogène |
US20180311642A1 (en) * | 2015-10-13 | 2018-11-01 | Michael Tsapatsis | Adsorbent material for removal of hydrogen sulfide |
EP3362172A4 (fr) * | 2015-10-13 | 2019-06-12 | Tsapatsis, Michael | Matériau adsorbant pour l'élimination de sulfure d'hydrogène |
CN110022971A (zh) * | 2015-10-13 | 2019-07-16 | 明尼苏达大学董事会 | 用于去除硫化氢的吸附剂材料 |
US11311855B2 (en) | 2015-10-13 | 2022-04-26 | Regents Of The University Of Minnesota | Adsorbent material for removal of hydrogen sulfide |
CN106947290A (zh) * | 2017-03-31 | 2017-07-14 | 合肥悦兰信息技术有限公司 | 彩色二氧化硅粉体材料的制备方法 |
WO2018231551A1 (fr) * | 2017-06-11 | 2018-12-20 | Msa Technology, Llc | Filtre pour composés soufrés |
CN111097363A (zh) * | 2018-10-25 | 2020-05-05 | 中国石油化工股份有限公司 | 硫、砷、磷净化剂及其制备方法 |
CN111036218A (zh) * | 2019-12-19 | 2020-04-21 | 山东京博石油化工有限公司 | 一种用于醋酸仲丁酯加氢反应的催化剂及其制备方法和应用 |
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