WO2015055554A1 - Principe actif pour le traitement des semences et du sol - Google Patents

Principe actif pour le traitement des semences et du sol Download PDF

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Publication number
WO2015055554A1
WO2015055554A1 PCT/EP2014/071840 EP2014071840W WO2015055554A1 WO 2015055554 A1 WO2015055554 A1 WO 2015055554A1 EP 2014071840 W EP2014071840 W EP 2014071840W WO 2015055554 A1 WO2015055554 A1 WO 2015055554A1
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methyl
seed
compound
var
formula
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PCT/EP2014/071840
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German (de)
English (en)
Inventor
Peter Jeschke
Reiner Fischer
Peter Lösel
Elke Hellwege
Olga Malsam
Wolfram Andersch
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Bayer Cropscience Ag
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Publication of WO2015055554A1 publication Critical patent/WO2015055554A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests

Definitions

  • the present application relates to the use of a known active substance for the treatment of seeds.
  • EP 0 268 915 A2 See also WO 2012/029672 Al, WO 2013/031671 A1, EP 2 628 389 A1 and EP 2 631 235 A2.
  • seed treatment methods should also include the intrinsic insecticidal or nematicidal properties of pest-resistant transgenic plants in order to achieve optimum protection of the seed and of the germinating plant with a minimum of pesticide use. It is known that active substances which are useful for the treatment of seeds or for the control of animal plant pests by application to the soil around the plant have to fulfill special requirements which can not be deduced directly from the chemical structure of the active substances.
  • an active ingredient can protect the young plant against infestation by animal early pests on aboveground plant parts and later occurring shoot pests including virus vectors (R. Altmann, Maischutz- sympatheticen Bayer 44, 1991, 159-174).
  • the active ingredient should be sufficiently soluble in water.
  • the lipophilicity of the drug should be in a moderate range to allow for a longer time, a sufficient concentration and a uniform distribution in the root area of the young plant and to form a courtyard around the rhizosphere.
  • a certain mobility of the drug is required because primarily only the young part of the root system (root hair) is capable of recording.
  • microbial degradation should be within a moderate range for the drug to be available for the plant at the required dose over an extended period of time (PC Kearney, DR Shelton, WC Koskinen, Encyclopedia of Agrochemicals, JR Plimmer, DW Gammon, NN Ragsdale (Eds.), Wiley-Interscience, Vol. 3, 2003, 1421-1441).
  • the active ingredient For use as a seed treatment agent, the active ingredient must meet other special requirements such as detachment from the seed, moderate distribution in the soil and plant tolerance.
  • Plant compatibility must meet a particularly high standard for the use of an active substance as a seed treatment agent, since the plant embryo or the young seedling is exposed to relatively high local concentrations of the active substances. Any delay in seed germination or seedling proliferation increases the risk that the seed or seedling will be attacked by disease causing organisms or soil pests. Furthermore, delaying expulsion shortens the plant growth period and may result in reduced yield (A. Jonitz, N. Leist Crop Protection News, Bayer 56, 2003, 147-172). The peculiarity of some active ingredients, in addition to reduce the growth in length of the hypocotyl, can have a serious impact on the field population (F. Brendler Kurier Issue 2, 2006, 4-7).
  • the present invention also relates to a method of protecting seeds and germinating plants from attack by pests by treating the seed with the compound of formula (I).
  • the method according to the invention for the protection of seeds and germinating plants from infestation by pests comprises a method in which the seed is treated simultaneously in one operation or sequentially with the active ingredient of formula (I) and one or more mixing partners. It also includes a method in which the seed is treated at different times with the active ingredient of the formula (I) and one or more mixing partners.
  • the invention also relates to the use of the compound of formula (I) for the treatment of seed for the protection of the seed and the resulting plant from animal pests.
  • the invention relates to seed which has been treated for protection against animal pests with the compound of formula (I).
  • the invention also relates to seed treated at the same time with the active ingredient of formula (I) and one or more mixing partners.
  • the invention further relates to seed which has been treated at different times with the active ingredient of the formula (I) and one or more mixing partners.
  • the layers containing the active ingredient of the formula (I) and one or more mixing partners may optionally be separated by an intermediate layer.
  • the invention also relates to seed in which the active compound of the formula (I) and one or more mixing partners are applied as a constituent of a coating or as a further layer or further layers in addition to a coating.
  • the invention relates to seed, which after the treatment with the compound of the formula (I) is subjected to a film coating process in order to avoid dust abrasion on the seed.
  • One of the advantages of the present invention is that because of the particular systemic properties of the compositions of the invention, treatment of the seeds with these agents not only protects the seed itself but also the resulting plants after emergence from animal pests. In this way, the immediate treatment of the culture at the time of sowing or shortly afterwards can be omitted.
  • Another advantage is that by treating the seed with the compound of formula (I) germination and emergence of the treated seed can be promoted. It is likewise to be regarded as advantageous that the compound of the formula (I) can be used in particular also in the case of transgenic seed.
  • the compound of the formula (I) can be used in combination with signal technology agents, by way of example a better colonization with symbionts, such as rhizobia, mycorrhiza and / or endophytic bacteria or fungi, takes place and / or it to an optimized nitrogen fixation comes.
  • symbionts such as rhizobia, mycorrhiza and / or endophytic bacteria or fungi
  • compositions according to the invention are suitable for the protection of seeds of any plant variety used in agriculture, in the greenhouse, in forests or in horticulture.
  • these are seeds of cereals (eg wheat, barley, rye, millet, triticale and oats), corn, cotton, soy, rice, potatoes, sunflower, coffee, tobacco, canola, rape, turnip (eg Sugar beet and fodder beet), peanut, vegetables (eg tomato, cucumber, bean, cabbage, onions and lettuce), fruit plants, turf and ornamental plants.
  • cereals eg wheat, barley, rye and oats
  • corn, soya, cotton, canola, oilseed rape and rice are examples of seeds of cereals (eg wheat, barley, rye and oats), corn, soya, cotton, canola, oilseed rape and rice.
  • transgenic seeds with the compound of the formula (I) is also of particular importance.
  • the heterologous genes in transgenic seed can be derived from microorganisms such as Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium.
  • the present invention is particularly suitable for the treatment of transgenic seed comprising at least one - contains heterologous gene derived from Bacillus sp. comes. Most preferably, this is a heterologous gene derived from Bacillus thuringiensis.
  • seed treatment methods should also incorporate the intrinsic insecticidal properties of pest-resistant transgenic plants in order to achieve optimum protection of the seed and germinating plant with a minimum of pesticide cost.
  • the preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits").
  • traits are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products.
  • Further and particularly emphasized examples of such properties are an increased Abwehr ability of the plants against animal and microbial pests, such as insects, arachnids, nematodes, mites, snails, causes, for example.
  • toxins produced in the plants in particular those produced by the genetic material from Bacillus thuringiensis (eg by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF as well as their combinations) in the plants are produced, furthermore an increased from defensive ability of the plants against plant-pathogenic mushrooms, bacteria and / or viruses, causes eg systemically acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins, as well as increased tolerance of the plants to certain herbicidal agents, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (e.g., "PAT" gene).
  • SAR systemically acquired resistance
  • systemin phytoalexins
  • elicitors elicitors
  • transgenic plants are the important crops such as cereals (wheat, rice, triticale, barley, rye, oats), corn, soy, potato, sugar beets, sugarcane, tomatoes, peas and other vegetables, cotton, tobacco, oilseed rape, and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with particular emphasis on maize, soya, wheat, rice, potato, cotton, sugarcane, tobacco and oilseed rape, canola. Traits that are particularly emphasized are the increased resistance of the plants to insects, arachnids, nematodes and snails.
  • the compound of the formula (I) is applied to the seed alone or in a suitable formulation.
  • the seed is treated in a state where it is so stable that no damage occurs during the treatment.
  • the treatment of the seed can be done at any time between harvesting and sowing.
  • seed is used which has been separated from the plant and freed from flasks, shells, stems, hull, wool or pulp.
  • seed may be used that has been harvested, cleaned and dried to a moisture content that is storable.
  • seed may also be used which, after drying, e.g. treated with water and then dried again, for example priming.
  • the agents according to the invention can be applied directly, ie without containing further components and without being diluted.
  • suitable formulations and methods for seed treatment are known to those skilled in the art and are described e.g. in the following documents: US 4,272,417 A, US 4,245,432 A, US 4,808,430 A, US 5,876,739 A, US 2003/0176428 AI, WO 2002/080675 AI, WO 2002/028186 A2.
  • the compound of the formula (I) which can be used according to the invention can be converted into the customary seed dressing formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other seed coating compositions, as well as ULV formulations.
  • These formulations are prepared in a known manner by mixing the compound of formula (I) with conventional additives, such as conventional extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, Gibberellins and also water.
  • Dyes which may be present in the seed dressing formulations which can be used according to the invention are all dyes customary for such purposes. Both water-insoluble pigments and water-soluble dyes are useful in this case. Examples which may be mentioned under the names rhodamine B, C.I. Pigment Red 112 and C.I. Solvent Red 1 known dyes.
  • Suitable wetting agents which may be present in the seed dressing formulations which can be used according to the invention are all wetting-promoting substances customary for the formulation of agrochemical active compounds.
  • Preferably used are alkylnaphthalene sulfonates, such as diisopropyl or diisobutyl naphthalene sulfonates.
  • dispersants and / or emulsifiers which may be present in the seed dressing formulations which can be used according to the invention, all are used for the formulation of agrochemical active compounds - - Conventional nonionic, anionic and cationic dispersants into consideration.
  • nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants are, in particular, ethylene oxide-propylene oxide, block polymers, alkylphenol polyglycol ethers and tristryrylphenol polyglycol ethers and their phosphated or sulfated derivatives.
  • Suitable anionic dispersants are in particular lignosulfonates, polyacrylic acid salts and arylsulfonate-formaldehyde condensates.
  • Defoamers which may be present in the seed-dressing formulations which can be used according to the invention are all foam-inhibiting substances customary for the formulation of agrochemical active compounds.
  • Preferably usable are silicone defoamers and magnesium stearate.
  • Preservatives which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemical compositions. Examples include dichlorophen and Benzylalkoholhemiformal.
  • Suitable secondary thickeners which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemical compositions. Preference is given to cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and finely divided silica.
  • Suitable adhesives which may be present in the seed dressing formulations which can be used according to the invention are all customary binders which can be used in pickling agents.
  • Preferably mentioned are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and Tylose.
  • the gibberellins are known (see R. Wegler "Chemie der convinced- und Swdlingsbekungsstoff", Vol. 2, Springer Verlag, 1970, pp. 401-412).
  • the seed dressing formulations which can be used according to the invention can be used either directly or after prior dilution with water for the treatment of seed of various kinds.
  • the concentrates or the preparations obtainable therefrom by dilution with water can be used for dressing the seeds of cereals such as wheat, barley, rye, oats and triticale, as well as the seeds of corn, rice, rape, canola, peas, beans, cotton , Sunflower, soy and beet or vegetable seed of various nature.
  • the seed dressing formulations which can be used according to the invention or their diluted preparations can also be used for pickling seeds of transgenic plants. It can in the - -
  • the pickling is done by placing the seed in a batch or continuous mixer, adding either desired amount of seed dressing formulations, either as such or after prior dilution with water, and until the formulation is evenly distributed mix the seed.
  • a drying process follows.
  • the application rate of the seed dressing formulations which can be used according to the invention can be varied within a relatively wide range. It depends on the particular content of the compound of the formula (I) in the formulations and on the seed.
  • the application rates for the compound of the formula (I) are generally between 0.001 and 50 g per kilogram of seed, preferably between 0.01 and 15 g per kilogram of seed. mixtures
  • the compound of formula (I) may be used as such or in their formulations also in admixture with one or more suitable fungicides (see the list below), bactericides, acaricides, molluscicides, nematicides, insecticides (see list below), microbiologicals, Useful insects, herbicides, fertilizers, bird repellents, phytotonics, sterilants, synergists, safeners, semiochemicals and / or plant growth regulators to widen the spectrum of action, to extend the duration of action, to increase the speed of action, to prevent re-exposure or to prevent the development of resistance. Furthermore, such drug combinations plant growth and / or tolerance to abiotic factors such.
  • the compound of the formula (I) as such or in its (commercial) formulations and in the formulations prepared from these formulations in admixture with other active ingredients or semiochemicals, such as attractants and / or bird repellents and / or plant activators and / or growth regulators and / or fertilizers and / or synergists.
  • the compound of formula (I) and its compositions can be used in mixtures with agents for improving plant properties such as growth, yield and quality of the crop.
  • the compound of the formula (I) or its compositions is present in commercial formulations or in the formulations prepared from these formulations in admixture with synergists and are used as insecticides.
  • synergists is meant those compounds which enhance the activity of the compound of formula (I) without the synergist having an insecticidal / acaricidal / nematicidal action.
  • Suitable mixing partners are the following
  • Acetylcholinesterase (AChE) inhibitors such as carbamates, e.g. Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxime, Butoxycarboxime, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocarb, Isoprocarb, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Propoxur, Thiodicarb, Thiofanox, Triazamate, Trimethacarb, XMC and Xylylcarb or organophosphates, eg Acephate, Azamethiphos, Azinophos-ethyl, Azinophos-methyl, Cadusafos, Chloroethoxyfos, Chlorfenvinphos, Chlormephos, Chlorpyrifos,
  • GABA-controlled chloride channel antagonists such as cyclodiene organochlorines, e.g. Chlordanes and endosulfan or phenylpyrazoles (fiproles), e.g. Ethiprole and fipronil.
  • sodium channel modulators / voltage dependent sodium channel blockers such as pyrethroids, eg acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin , Cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lR) -trans isomers], deltamethrin, empenthrin [ (EZ) - (lR) isomers
  • nicotinergic acetylcholine receptor (nAChR) agonists such as neonicotinoids, e.g. Acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam or nicotine or sulfoxaflor.
  • nAChR nicotinergic acetylcholine receptor
  • nicotinergic acetylcholine receptor (nAChR) allosteric activators such as spinosines, e.g. Spinetoram and spinosad.
  • chloride channel activators such as avermectins / milbemycins, e.g. Abamectin, Emamectin benzoate, Lepimectin and Milbemectin.
  • Juvenile hormone mimics such as juvenile hormone analogs, e.g. Hydroprene, Kinoprene and Methoprene or Fenoxycarb or Pyriproxyfen.
  • agents with unknown or non-specific mechanisms of action such as
  • Alkyl halides e.g. Methyl bromide and other alkyl halides; or chloropicrin or sulfuryl fluoride or borax or tartar emetic.
  • Selective feeding inhibitors e.g. Pymetrozine or flonicamide.
  • mite growth inhibitors e.g. Clofentezine, hexythiazox and diflovidazine or etoxazole.
  • Insect intestinal membrane microbial disruptors e.g. Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and Bacillus thuringiensis proteins: Cryl Ab, Cryl Ac, CrylFa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34 / 35Abl.
  • Bacillus thuringiensis subspecies israelensis Bacillus sphaericus
  • Bacillus thuringiensis subspecies aizawai Bacillus thuringiensis subspecies kurstaki
  • Bacillus thuringiensis subspecies tenebrionis and Bacillus thuringiensis proteins Cryl Ab, Cryl Ac, CrylFa, C
  • oxidative phosphorylation inhibitors such as diafenthiuron or organotin compounds, e.g. Azocyclotin, Cyhexatin and Fenbutatin-oxide or Propargite or Tetradifon.
  • Nicotinergic acetylcholine receptor antagonists such as Bensultap, Cartap hydrochloride, Thiocyclam and Thiosultap sodium.
  • Type 0 inhibitors of chitin biosynthesis such as bistrifluron, chlorofluorazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.
  • inhibitors of chitin biosynthesis type 1, such as buprofezin.
  • ecdysone receptor agonists such as chromafenozides, halofenozides, methoxyfenozides, and tebufenozides.
  • Octopaminergic agonists such as amitraz.
  • (21) complex I electron transport inhibitors for example, METI acaricides, e.g. Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad and Tolfenpyrad or Rotenone (Derris).
  • METI acaricides e.g. Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad and Tolfenpyrad or Rotenone (Derris).
  • voltage dependent sodium channel blockers e.g. Indoxacarb or metaflumizone.
  • (23) inhibitors of acetyl-CoA carboxylase such as tetronic and tetramic acid derivatives, e.g. Spirodiclofen, spiromesifen and spirotetramat.
  • complex IV electron transport inhibitors such as phosphines, e.g. Aluminum phosphide, calcium phosphide, phosphine and zinc phosphide or cyanide.
  • Complex II electron transport inhibitors such as cyenopyrafen and cyflumetofen.
  • ryanodine receptor effectors such as diamides, e.g. Chlorantraniliprole, Cyantraniliprole and Flubendiamide,
  • agents such as afidopyropene, azadirachtin, benclothiaz, benzoximate, bifenazate, bromopropylate, quinomethionate, cryolite, dicofol, diflovidazine, fluensulfone, flometoquine, flufenerim, flufenoxystrobin, flufiprole, fluopyram, flupyradifurone, fufenocide, heptafluthrin, imidaclothiz, iprodione, meperfluthrin, paichongding, Pyflubumide, pyrifluquinazone, pyriminostrobin, tetramethylfluthrin and iodomethane; furthermore preparations based on Bacillus firmus (1-1582, BioNeem, Votivo), and the following compounds: 3-bromo-N- ⁇ 2-bromo-4-chloro-6 - [
  • Fungicides The active ingredients specified here with their "common name” are known, for example, described in the "Pesticide Manual” or on the Internet (for example: http://www.alanwood.net pesticides). - -
  • inhibitors of ergosterol biosynthesis such as (1.1) aldimorph, (1.2) azaconazole, (1.3) bitertanol, (1.4) bromuconazole, (1.5) cyproconazole, (1.6) diclobutrazole, (1.7) difenoconazole, (1.8) diniconazole , (1.9) Diniconazole-M, (1.10) dodemorph, (1.11) dodemorph acetate, (1.12) epoxiconazole, (1.13) etaconazole, (1.14) fenarimol, (1.15) fenbuconazole, (1.16) fenhexamide, (1.17) fenpropidine, ( 1.18) fenpropimorph, (1.19) fluquinconazole, (1.20) flurprimidol, (1.21) flusilazole, (1.22) flutriafol, (1.23) furconazole, (1.24) furconazole cis, (1.21)
  • inhibitors of respiration such as (2.1) bixafen, (2.2) boscalid, (2.3) carboxin, (2.4) diflumetorim, (2.5) fenfuram, (2.6) fluopyram, (2.7) flutolanil, ( 2.8) Fluxapyroxad, (2.9) Furametpyr, (2.10) Furmecyclox, (2.11) Isopyrazam Mixture of the syn-epimeric racemate 1RS, 4SR, 9RS and the anti-empimidal racemate 1RS, 4SR, 9SR, (2.12) isopyrazam (anti- epimeric racemate ), (2.13) isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), (2.14) isopyrazam (anti- epimeric enantiomer 1S, 4R, 9R), (2.15) isopyrazam (syn-epimeric racemate 1RS, 4SR, 9RS)
  • inhibitors of respiration at the complex III of the respiratory chain, such as (3.1) ametoctradine, (3.2) amisulbrom, (3.3) azoxystrobin, (3.4) cyazofamide, (3.5) coumethoxystrobin, (3.6) coumoxystrobin, ( 3.5) dimoxystrobin, (3.8) enestroburine, (3.9) famoxadone, (3.10) fenamidone, (3.11) flufenoxystrobin, (3.12) fluoxastrobin, (3.13) kresoxim-methyl, (3.14) metominostrobin, (3.15) orysastrobin, (3.16) picoxystrobin , (3.17) Pyraclostrobin, (3.18) Pyrametostrobin, (3.19) Pyraoxystrobin, (3.20) Pyribencarb, (3.21) Triclopyricarb, (3.22) Trifloxystrobin, (3.23) (2E) -2
  • resistance inducers such as (6.1) acibenzolar-S-methyl, (6.2) isotianil, (6.3) probenazole, (6.4) tiadinil, and (6.5) laminarin.
  • inhibitors of amino acid and protein biosynthesis such as (7.1), (7.2) blasticidin-S, (7.3) cyprodinil, (7.4) kasugamycin, (7.5) kasugamycin hydrochloride hydrate, (7.6) mepanipyrim,
  • inhibitors of ATP production such as (8.1) fentin acetate, (8.2) fentin chloride, (8.3) fentin hydroxide and (8.4) silthiofam.
  • inhibitors of cell wall synthesis such as (9.1) benthia-valicarb, (9.2) dimethomorph, (9.3) flumorph, (9.4) iprovalicarb, (9.5) mandipropamide, (9.6) polyoxins, (9.7) polyoxorim, (9.8) validamycin A, (9.9) Valifenalate and (9.10) Polyoxin B.
  • inhibitors of lipid and membrane synthesis such as (10.1) biphenyl, (10.2) chloroben, (10.3) diclorane, (10.4) edifenphos, (10.5) etridiazole, (10.6) iodocarb, (10.7) Iprobenfos, ( 10.8) isoprothiolane, (10.9) propamocarb, (10.10) propamocarb hydrochloride, (10.11) prothiocarb , (10.12) pyrazophos, (10.13) quintoene, (10.14) tecnazene and (10.15) tolclofos-methyl.
  • inhibitors of melanin biosynthesis such as (11.1) carpropamide, (11.2) diclocymet, (11.3) fenoxanil, (11.4) fthalide, (11.5) pyroquilone, (11.6) tricyclazole, and (11.7) 2,2,2 Trifluoroethyl ⁇ 3-methyl-1 - [(4-methylbenzoyl) amino] butan-2-yl ⁇ carbamate.
  • inhibitors of nucleic acid synthesis such as (12.1) benalaxyl, (12.2) benalaxyl-M (kiralaxyl), (12.3) bupirimate, (12.4) clozylacon, (12.5) dimethirimol, (12.6) ethirimol, (12.7) furalaxyl, ( 12.8) Hymexazole, (12.9) Metalaxyl, (12.10) Metalaxyl-M (mefenoxam), (12.11) Ofurace, (12.12) Oxadixyl, (12.13) Oxolinic acid and (12.14) Octhilinone.
  • Signal transduction inhibitors such as (13.1) chlozolinate, (13.2) fenpiclonil, (13.3) fludioxonil, (13.4) iprodione, (13.5) procymidone, (13.6) quinoxyfen, (13.7) vinclozoline, and (13.8) proquinazide. - -
  • decouplers such as (14.1) binapacryl, (14.2) dinocap, (14.3) ferimzone, (14.4) fluazinam, and (14.5) meptyldinocap.
  • N-methylimidoformamide (15.152) ⁇ '- ⁇ 5-bromo-6- [1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl ⁇ -N-ethyl-N-methylimidoformamide, (15.153) N '- ⁇ 5-bromo-6 - [(1R) -1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl ⁇ -N-ethyl-N-methylimidoformamide, (15.154) N'- ⁇ 5-bromo-6 - [(1S) -1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl ⁇ -N-ethyl-N-methylimidoformamide, (15.155) N'- ⁇ 5-bromo-6 - [(cis-4-isopropylcyclohe
  • Classes (1) through (15), if capable of being functional groups, may optionally form salts with suitable bases or acids.
  • the combinations of the compound of formula (I) with said fungicides have very good fungicidal properties and can be used in the treatment of seeds, in particular for controlling phytopathogenic fungi, such as Ascomycetes and Basidiomycetes.
  • the active compounds according to the invention are particularly suitable in the treatment of seed for controlling Pyrenophora, Rhizoctonia, Tilletia and Ustilago species.
  • Pyrenophora species such as, for example, P. allosuri, P. alternarina, P. avenae, P. bartramiae, P. bondarzewii P. bromi, P. bryophila, P. buddleiae, P. bupleuri, P. calvertu, P. calvescens var. Moravica, P. carthami, P. centranthi, P. cerastü, P. chengü, P. chrysanthemi, P. convolvuli, P. coppeyana, P. cytisi,
  • P. dactylidis P. dictyoides, P. echinopis, P. ephemera, P. eryngicola, P. erythrospila, P. euphorbiae, P. freticola, P. graminea, P. heraclei, P. hordei, P. horrida, P. hyperici, P. japonica, P. kugitangi, P. lithophila, P. lolii, P. macrospora, P. metasequoiae, P. minuartiae-hirsutae, P. moravica, P. moroczkovskii,
  • Rhizoctonia species such as Rh. aerea, Rh. alba, Rh. Alpina, Rh. Anaticula, Rh. Anomala, Rh. Apocynacearum, Rh. Arachnion, Rh. Asclerotica, Rh. Bataticola, Rh. Borealis, Rh. Callae,
  • Rh. Candida Rh. Carotae, Rh. Cerealis, Rh. Choussii, Rh. Coniothecioides, Rh. Dichotoma, Rh. Dimorpha,
  • Rh. Endophytica var. Filicata, Rh. Endophytica, Rh. Ferruginea, Rh. Floccosa, Rh. Fragariae, Rh. Fraxini, Rh. Fuliginea, Rh. Fumigata, Rh. Globularis, Rh. Goodyerae-repentis, Rh. Gossypii var. anatolica, Rh. gossypii, Rh. gracilis, Rh. grisea, Rh. hiemalis, Rh. juniperi, Rh. lamellifera, Rh. leguminicola, Rh. lilacina, Rh. lupini, Rh. macrosclerotia, Rh. melongenae, Rh.
  • Rh. monilioides Rh. montseithiana, Rh. muneratii, Rh. nandorii, Rh. oryzae, Rh. oryzae-sativae, Rh. pallida, Rh. pini-insignis, Rh. praticola, Rh. quercus, Rh. ramicola, Rh. robusta, Rh. rubi, Rh. rubiginosa, Rh. sclerotica, Rh. solani, Rh. solani f. soloka forma specialis, Rh. solani var. cedri-deodarae, Rh. solani var. fuchsiae, Rh. solani var. hortensis, Rh. stahlii, Rh.
  • subtilis var. nigra subtilis var. nigra
  • Rh. subtilis Rh. tomato, Rh. Tuliparum, Rh. Versicolor, Rh. Zeae, Tilletia species, such as T. aegilopis, T. aegopogonis, T. ahmadiana, T. airina, T. ajrekari, T. alopecuri, T. anthoxanthi, T. apludae, T. arundinellae, T. asperifolia, T. asperitolioides, T. atacamensis, T. baldrati, T. bambusae, T. banarasae, T. bangalorensis, T. barclayana, T. biharica, T.
  • T. tritici [var.] Nanifica, T. tritici f. monococci, T. tritici var. controversa, T. tritici var. laevis, T. tritici-repentis, T. triticoides, T. tuberculata, T. vetiveriae, T. viennotii, T. vittata var. burmannii, T. vittata, T. Walkeri, T. youngii, T.
  • Ustilago species such as, for example, U. abstrusa, U. aegilopsidis, U. aeluropodis, U. affinis var. Hilariae, U. agrestis, U. agropyrina, U. agrostis palustris, U. ahmadiana, U. airae-caespitosae, U alismatis, U. alopecurivora,
  • U. asinea U. altilis, U. amadelpha var. Glabriuscula, U. amphilophidis, U. amplexa, U. andropogonis-tectorum, U. aneilemae, U. anhweiana, U. anomala [var.] Microspora, U. anomala var avicularis, U. anomala var. carnea, U. anomala var. cordai, U. anomala var. muricata, U. anomala var. tovarae, U. anthoxanthi, U. apscheronica, U. arabidia alpinae, U. arctagrostis, U. arctica, U.
  • bothriochloae U. bothriochloae intermediae, U. bouriqueti, U. braziliensis, U. brizae, U. bromi-arvensis, U. bromi-erecti,
  • Hyalino bipolaris U. hydropiperis, U. hyparrheniae, U. hypodytes f. congoensis, U. hypodytes f. sporoboli, U. hypodytes var. agrestis, U. idonea, U. imperatae, U. induta, U. inouyei, U. intercedens, U. iranica, U. isachnes, U. ischaemi-akoensis, U. ischaemi-anthephoroidis, U ixiolirii, U. ixophori, U. jacksonii var. ventanensis, U. jacksonii, U.
  • jaczevskyana var. sibirica U. jaczevskyana var. typica
  • U. jaczevskyana U. jagdishwari, U. jalalainenii, U. jududana, U. Johnstonu, U. kairamoi, U. kazachstanica, U. kenjiana, U. kweichowensis, U. kyllingae, U. lachrymae-jobi, U. lepyrodiclidis, U. lidii, U. Kunststoffbergii, U. linderi, U. linearis, U. liroae, U. loliicola, U. longiflora, U.
  • microthelis U. milli, U. modesta, U. moe hemmiae, U. moenchiae manticae, U. monmerae, U. Yeti var. minor, U. morinae, U. morobiana, U. muehlenbergiae var. tucumanensis, U. muricata, U. muscari-botryoidis, U. nagornyi, U. nannfeldtii, U. nelsoniana, U. nepalensis, U. neyraudiae, U. nigra, U. nivalis, U. nuda, U. nuda var.
  • paspalidiicola U. patagonica, U. penniseti var. Verruculosa, U. perrar a, U. persicariae, U. petrakii, U. phalaridis, U. phlei, U. phlei-pratensis, U. phragmites, U. picacea, U. pimprina, U. piperi [var.] rosulata, U. poae, U. poae-bulbosae, U. poae -nemoralis, U. polygoni-alati, U. polygoni-alpini, U. polygoni-punctati, U. polygoni-serrulati, U.
  • polytocae U. polytocae-barbatae, U. pospelovii, U. prostrata, U. pseudohieronymi, U. pueblaensis, U. puellaris, U. pulverulenta, U. raciborskiana, U. radians, U. ravida, U. rechingeri, U. reticulata, U. reticulispora, U. rhei, U. rhynchelytri, U. rwandensis, U. sabouriana, U. salviae, U. sanctae-catharinae, U. scaura, U.
  • sporoboli tremuli U. stellariae, U. sterilis, U. stewartli, U. stipae, U. striaeformis f. agrostidis, U. striaeformis f. phlei, U. striaeformis f. poaeannuae, U. striaeformis f. poae-pratensis, U. striiformis f. hierochloes-odoratae, U. striiformis var. agrostidis, U. striiformis var. dactylidis, U. striiformis var. hold, U. striiformis var.
  • the compound of formula (I) is also good for controlling insects by casting on the ground (known in the art as “drenching"), droplet application to the soil (known in the art as “drip application”) Immersion of root system, tubers or onions (known in the art as “dip application”), by hydroponic systems or soil injection (known in the art as “Soil injection”) is suitable.
  • the present invention accordingly relates to the use of the compound of formula (I) for controlling insects by casting on the ground, in irrigation systems, as a droplet application to the soil, as a dipping application of root system, tubers or onions or by soil injection. Furthermore, the present invention relates to these applications on natural (soil) or artificial substrates (eg rock wool, glass wool, quartz sand, pebbles, expanded clay, vermiculite) in the field or in closed systems (eg greenhouses or under foil cover) and in one-year (eg vegetables , Spices, ornamental plants) or perennial crops (eg citrus plants, fruits, tropical crops, spices, nuts, wine, conifers and ornamental plants).
  • natural soil
  • artificial substrates eg rock wool, glass wool, quartz sand, pebbles, expanded clay, vermiculite
  • closed systems eg greenhouses or under foil cover
  • one-year eg vegetables , Spices, ornamental plants
  • perennial crops eg citrus plants, fruits, tropical crops, spices, nuts, wine,
  • the compound of the formula (I) is particularly suitable for combating the following species of the family of the Stink bug (Pentatomidae):
  • Antestiopsis orbitalus in soy
  • Euschistus servus in soya, corn, cotton, and rice Nezara viridula in soy, corn, cotton, cereals and rice,
  • the compound of the formula (I) is particularly suitable for controlling the following species from the family of shield bugs (Plataspidae): Megacopta cribraria in soya.
  • the compound of the formula (I) is also particularly suitable for controlling the following species of the family Eulenfalter (Noctuidae):
  • Pseudoplusia includes in cotton, corn, beets and soy, Anticarsia gemmatalis in cotton, corn , Beets and soya, Rachiplusia nu in cotton, maize, beets and soya,
  • the compound of the formula (I) is also particularly suitable for controlling the following species from the family of Plutellidae:
  • the compound of the formula (I) is also particularly suitable for controlling the following species of the family of Gelechiidae
  • Pectinophora gossypiella in cotton.
  • the compound of the formula (I) is also particularly suitable for combating the following species from the Crambidae family: chilo suppressalis in maize and rice,
  • the compound of the formula (I) is particularly suitable for combating the following species from the family of the thorns (Pyralidae):
  • the compound of formula (I) is also particularly suitable for controlling the following species of the family of Tortricidae:
  • the compound of the formula (I) is particularly suitable for controlling the following species of the family of leaf beetles (Chrysomelidae):
  • Diabrotica vir gif er a in maize and soya Diabrotica viridula in maize and soya
  • the compound of the formula (I) is particularly suitable for controlling the following species from the family of glossy beetles (Nitidulidae):
  • the compound of the formula (I) is particularly suitable for controlling the following species from the family of glossy beetles (Cryptophagidae):
  • the compound of the formula (I) is particularly suitable for controlling the following species of the aphid family (Aphididae):
  • Macrosiphum miscanthi in cereals and potatoes Metopolophium dirhodum in cereals and corn
  • the compound of the formula (I) is particularly suitable for controlling the following species of the family of the lice (Pseudococcidae):
  • the compound of formula (I) is particularly suitable for controlling the following species of the family of flower flies (Anthomyiidae): Delia coarctata in cereals, rapeseed, beets and onions, Delia floralis in cereals, rapeseed, beets and onions,
  • the compound of the formula (I) is particularly suitable for combating the following species from the family of fast beetles (Elateridae):
  • the compound of the formula (I) is particularly suitable for combating the following species of the family of the spur cicadas (Delphacidae): Laodelphax striatellus in rice,
  • the compound of the formula (I) is particularly suitable for controlling the following species from the family of the dwarf cicadas (Cicadellidae): Nephotettix cincticeps in rice,
  • the compound of the formula (I) is particularly suitable for controlling the following species of the family of white flies (Alcyrodidae). Bemisia tabaci, Bemisia argentifolu and Trialeurodes vaporariorum
  • the compound of the formula (I) is particularly suitable for controlling the following species from the order of the fringed wing (Thysanoptera):
  • a suitable preparation of active compound 1 part by weight of active compound is mixed with 9 parts by weight of empty formulation and the amount of solvent required, depending on the state of matter of the active substance. The preparation of active compound thus prepared is then dried. Depending on the desired application rate, the calculated amount of the preparation of active compound is weighed in accordance with the prepared, weighed seed quantity.
  • onion seed (Allium cepa) is pickled with the preparation of active compound and sown in sandy loam (50 grains / pot, at least 2 pots / variant). After about 3 weeks, the onion plants are infected with larvae of the onion fly ⁇ Hylemya antiqua). After 7-14 days the kill is determined in%. 100% means> that all fly larvae have been killed; 0% means that no fly larvae have been killed. - -
  • a suitable preparation of active compound 1 part by weight of active compound is mixed with 9 parts by weight of empty formulation and the amount of solvent required, depending on the state of matter of the active substance. The preparation of active compound thus prepared is then dried. Depending on the desired application rate, the calculated amount of the preparation of active compound is weighed in accordance with the prepared, weighed seed quantity.
  • Test plant ZEAMI (Grain corn)
  • active compound 1 part by weight of active compound is mixed with 4 parts by weight of empty formulation and the amount of solvent required depending on the state of aggregation of the active substance.
  • the preparation of active compound thus prepared is then dried.
  • weighed seed the - - Weighed the calculated amount of the formulation. Adding water, the corn seed is pickled and dried back.
  • the corn is sown in sandy loam. After 3 days, about 40 Diabrotica larvae are placed per pot. In addition to an untreated control with test animals, a control without test animals is included in order to determine the germination capacity of the maize seed. 6-7 days after infection, the effect is determined in% Abbott. 100%> means that all plants have germinated and grown; 0% means that no plant has accumulated.
  • a suitable preparation of active compound 1 part by weight of active compound is mixed with 9 parts by weight of empty formulation and the amount of solvent required, depending on the state of matter of the active substance. The preparation of active compound thus prepared is then dried. Depending on the desired application rate, the calculated amount of the preparation of active compound is weighed in accordance with the prepared, weighed seed quantity.
  • cotton seed ⁇ Gossypium hirsutum is pickled with the preparation of active compound and sown in sandy loam (1 grain / pot, at least 3 pots / variety). After about 2 weeks, the cotton plants are infected with the cotton aphid (Aphis gossypii). After 7 days the kill is determined in%. 100% means> that all aphids have been killed; 0% means that no aphids have been killed.
  • Solvent acetone as required To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with 9 parts by weight of empty formulation and the amount of solvent required depending on the physical state of the active substance. The preparation of active compound thus prepared is then dried. Depending on - - The desired application rate is weighed according to the prepared, weighed seed amount, the calculated amount of the preparation of active compound.
  • winter barley seed (Hordeum vulgare) is pickled with the active ingredient preparation and seeded in sandy loam (10 grains / pot, at least 2 pots / variant). After about 1 week, the barley plants are infected with a mixed population of large cereal aphid (Metopolophium dirhodum).
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration.
  • Cotton plants (Gossypium hirsutum) are grown in loamy sand and poured in the 1-2 leaf stage with an active compound preparation of the desired concentration. After one week, a mixed thrips population (Frankliniella occidentalis) is infected.
  • Nilaparvata lugens test, seed application (NILALU S)
  • a suitable preparation of active compound 1 part by weight of active compound is mixed with 9 parts by weight of empty formulation and the amount of solvent required depending on the state of matter of the active substance.
  • the preparation of active compound thus prepared is dried.
  • the calculated amount of the preparation of active compound is weighed in accordance with the prepared, weighed seed quantity.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration, whereby the volume of the earth is forced into the vessel. It must be ensured that a concentration of 40 ppm emulsifier is not exceeded in the soil. To prepare further test concentrations, it is diluted with water.
  • Savoy cabbage plants (Brassica oleraced) in soil pots infested with all stages of the Green Peach aphid (Myzus persicae) are infused with an active substance preparation of the desired concentration.
  • Diabrotica balteata - soil treatment (DIABBA B)
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether To prepare a suitable preparation of active compound, 1 part by weight of active ingredient is dissolved with solvent and emulsifier in the ratio 4: 1 and diluted with water to the desired concentration.
  • This preparation of active compound is mixed with soil.
  • For each concentration fill two 250 ml pots with treated soil and sow 5 corn kernels (Zea mays). After 3 days approximately 40 L2 larvae of the corn rootworm ⁇ Diabrotica balteata) are placed on the surface of the earth.
  • the efficiency is calculated from the number of accrued maize plants. 100% means that all 5 plants have germinated and grown; 0% means that no plant has accumulated.
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • a laboratory formulation in the range of 0.05-5% with acetone + emulsifier (4 + 1) is first prepared and then made up to a concentration of 100 ppm (1 mg a.i./ml) with water. By diluting this stock solution with water, the desired test concentrations are obtained, whereby the volume of the soil into which it is restricted must also be taken into account.
  • Cotton plants (Gossypium hirsutum) in the 1.-2. Leaf stage in Erdtmün be poured with an active compound preparation of the desired concentration. One week after drenching, the plants are infected with a mixed population of cotton aphid ⁇ Aphis gossypii). - -
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • HELIAR D Heliothis armigera - Drench Test
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • a laboratory formulation in the range of 0.05-5% is first prepared with acetone + emulsifier (4 + 1) and then with water up to a concentration of 1000 ppm (1 mg ai / ml). refilled. By diluting this stock solution with water, the desired test concentrations are obtained, whereby the volume of the soil into which it is restricted must also be taken into account.
  • Soybean plants (Glycine max) in pots in the 1st-2nd Leaf stage are cast with an active compound preparation of the desired concentration. Two weeks after drenching, a staple with 3-5 L2 larvae of the cotton budworm ⁇ Heliothis armigera) is attached to the middle of the youngest, fully developed leaf.
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • a laboratory formulation in the range of 0.05-5% with acetone + emulsifier (4 + 1) is first prepared and then made up to a concentration of 100 ppm (1 mg ai / ml) with water. By dilution of this stock solution with - -
  • Barley plants (Hordeum vulgare) in earth pots in the 1.-2.
  • Leaf stage are cast with an active compound preparation of the desired concentration. After 1 week, a mixed population infects the oat aphid ⁇ Rhopalosiphum padi).
  • a suitable preparation of active compound 1 part by weight of active compound is dissolved in an amount of solvent adapted to the physical state of the active substance. 4 parts by weight of blank formulation are added, mixed with the active substance solution and the resulting active ingredient preparation is dried. Depending on the desired application rate, the calculated amount of the preparation of active compound is weighed in accordance with the prepared, weighed seed quantity.
  • winter barley seed ⁇ Hordeum vulgare is stained with the preparation of active compound and sown in sandy loam (10 grains / pot, at least 2 pots / variant). After about 1 week - The barley plants (1st-2nd leaf stage) are infected with a mixed population of the oxtail louse (Rhopalosiphum padi).
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • Phaedon cochleariae - Drench test (PHAECO D)
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • a laboratory formulation in the range of 0.05-5% with acetone + emulsifier (4 + 1) is first prepared and then made up to a concentration of 100 ppm (1 mg a.i./ml) with water. By diluting this stock solution with water, the desired test concentrations are obtained, whereby the volume of the soil into which it is restricted must also be taken into account.
  • Cabbage plants (Brassica oleracea) in earth pots in the 1st-2nd cent. Leaf stage, are cast with an active compound preparation of the desired concentration. Two weeks after drenching, a staple with 3-5 L2 larvae of the horse radish beetle ⁇ Phaedon cochleariae) is attached to the middle of the youngest, fully developed leaf.
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether - -
  • a laboratory formulation in the range of 0.05-5% with acetone + emulsifier (4 + 1) is first prepared and then made up to a concentration of 100 ppm (1 mg a.i./ml) with water. By diluting this stock solution with water, the desired test concentrations are obtained, taking into account the volume of the earth into which it is reduced.
  • Rice plants (Oryza sativa) in the 1.-2.
  • Leaf stage (about 14 days after sowing), are cast with an active compound preparation of the desired concentration.
  • 1 week after Drenchen the uppermost leaves (up to approach 1st leaf) of the rice plants are cut off. 8-10 equally sized rice leaves are placed in the middle of a Petri dish on wet filter paper and infected with 10 LI larvae of the striped rice borer (Chilo suppressalis).
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • a laboratory formulation in the range of 0.05-5% is first prepared with acetone + emulsifier (4 + 1) and then with water up to a concentration of 1000 ppm (1 mg ai / ml). refilled. By diluting this stock solution with water, the desired test concentrations are obtained, whereby the volume of the soil into which it is restricted must also be taken into account.
  • Cotton plants (Gossypium hirsutum) in the 1.-2.
  • Leaf stage in Erdt mün be poured with an active compound preparation of the desired concentration. One week after drenching, the plants are infected with the green peach aphid ⁇ Myzus persicae).
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • a laboratory formulation in the range of 0.05-5% with acetone + emulsifier (4 + 1) is first prepared and then made up to a concentration of 100 ppm (1 mg a.i./ml) with water. By diluting this stock solution with water, the desired test concentrations are obtained, whereby the volume of the soil into which it is restricted must also be taken into account.
  • Cabbage plants (Brassica oleracea) in earth pots in the 1st-2nd cent. Leaf stage, are cast with an active compound preparation of the desired concentration.
  • a staple with 3-5 L2 larvae of the veil moth ⁇ Plutella xylostella) is attached to the middle of the youngest, fully developed leaf.
  • a laboratory formulation in the range of 0.05-5% with acetone + emulsifier (4 + 1) is first prepared and then made up to a concentration of 100 ppm (1 mg ai / ml) with water. By dilution of this stock solution with - -
  • Potato plants Solanum tuberosum
  • Plants in soil pots in the 1st-2nd Leaf stage are cast with an active compound preparation of the desired concentration.
  • the citrus louse Plantococcus citri
  • the citrus louse is infected with a mixed population.
  • Nilaparvata lusens - Drench test (NILALU D)
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • a laboratory formulation in the range of 0.05-5% with acetone + emulsifier (4 + 1) is first prepared and then made up to a concentration of 100 ppm (1 mg a.i./ml) with water. By diluting this stock solution with water, the desired test concentrations are obtained, whereby the volume of the soil into which it is restricted must also be taken into account.
  • Rice plants (Oryza sativa) are infused with the preparation of active ingredient (2 pots / variant) and after 3 days infected with a mixed population of brown-backed rice leafhopper (Nilaparvata lugens).
  • Neyhotettix cincticeys - Drench Test (NEPHCI D)
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • a laboratory formulation in the range of 0.05-5% is first prepared with acetone + emulsifier (4 + 1) and then with water up to a concentration of 1000 ppm (1 mg ai / ml). refilled. By diluting this stock solution with water, the desired test concentrations are obtained, taking into account the volume of the earth into which it is reduced.
  • Rice plants (Oryza sativa) are infused with the active ingredient preparation (2 pots / variant) and after 3 days infected with a mixed population of green rice leafhopper (Nephotettix cincticeps).
  • Nephotettix cincticeps test seed application (NEPHCI S)
  • a suitable preparation of active compound 1 part by weight of active compound is mixed with 9 parts by weight of empty formulation and the amount of solvent required depending on the state of matter of the active substance.
  • the preparation of active compound thus prepared is dried.
  • the calculated amount of the preparation of active compound is weighed in accordance with the prepared, weighed seed quantity.
  • rice seed (Oryza sativa) is stained with the preparation of active compound and seeded in sandy loam (10 grains / pot, at least 2 pots / variant). After 1 week, the rice plants are infected with a mixed population of green rice leafhopper (Nephotettix cincticeps).
  • Example 22 Aphis glycines - Test, Seed Application (APHIGY S)
  • soybean seed (Glycine max) is pickled with the preparation of active compound and sown in sandy loam (1 grain / pot, at least 3 pots / variant). After 1 week, the soybean plants are infected with a mixed population of the soybean aphid (Aphis glycines).
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • a laboratory formulation in the range of 0.05-5% with acetone + emulsifier (4 + 1) is first prepared and then made up to a concentration of 100 ppm (1 mg a.i./ml) with water. By diluting this stock solution with water, the desired test concentrations are obtained, whereby the volume of the soil into which it is restricted must also be taken into account.
  • Corn plants (Zea mays) are infused with an active compound preparation of the desired concentration and after 3 days infected with larvae of the green rice bug (Nezara viridula). After 7 days, the phytoprotective effect against feeding in% is determined. 100% means that no damage can be seen; 0% means that the damage to the treated leaves is the same as the untreated control.
  • maize seed (Zea mays) is stained with the preparation of active compound and sown in sandy loam soil (1 grain / pot with 50 ml of soil volume, at least 2 pots / V variant).
  • the maize plants are infected with larvae of the green rice bug ⁇ Nezara viridula). After 5 days, the phytoprotective effect is determined in%. 100% means that no damage can be seen. 0% means that the damage to the treated plants corresponds to that of the untreated control.

Abstract

Le composé connu de la formule (I) est parfaitement adapté au traitement des semences de certaines cultures pour les protéger des nuisibles spéciaux et pour lutter contre les animaux nuisibles pour les végétaux par son application sur le sol et les plantes.
PCT/EP2014/071840 2013-10-14 2014-10-13 Principe actif pour le traitement des semences et du sol WO2015055554A1 (fr)

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KR20180098631A (ko) 2015-12-29 2018-09-04 메이지 세이카 파루마 가부시키가이샤 이미노피리딘 유도체를 함유하는 유해 생물 방제용 조성물

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Publication number Priority date Publication date Assignee Title
KR20180098631A (ko) 2015-12-29 2018-09-04 메이지 세이카 파루마 가부시키가이샤 이미노피리딘 유도체를 함유하는 유해 생물 방제용 조성물

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