WO2015033022A1 - Système et procédé de combustion de combustible - Google Patents

Système et procédé de combustion de combustible Download PDF

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Publication number
WO2015033022A1
WO2015033022A1 PCT/FI2014/050673 FI2014050673W WO2015033022A1 WO 2015033022 A1 WO2015033022 A1 WO 2015033022A1 FI 2014050673 W FI2014050673 W FI 2014050673W WO 2015033022 A1 WO2015033022 A1 WO 2015033022A1
Authority
WO
WIPO (PCT)
Prior art keywords
arrangement
separator
fuel
product gas
combustion plant
Prior art date
Application number
PCT/FI2014/050673
Other languages
English (en)
Inventor
Timo Honkola
Original Assignee
Valmet Power Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=51663213&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2015033022(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Valmet Power Oy filed Critical Valmet Power Oy
Priority to EP14781612.8A priority Critical patent/EP3041919B1/fr
Priority to SI201430498T priority patent/SI3041919T1/en
Publication of WO2015033022A1 publication Critical patent/WO2015033022A1/fr
Priority to HRP20171737TT priority patent/HRP20171737T1/hr

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C6/00Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
    • F23C6/04Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/02Dust removal
    • C10K1/026Dust removal by centrifugal forces
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • F23C10/02Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0916Biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1606Combustion processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643Conversion of synthesis gas to energy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/54Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/54Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C10J3/56Apparatus; Plants

Definitions

  • renewable fuels such as agro fuels, waste, or the like, as a replacing energy source.
  • Figure 1 is a schematic side view of an arrangement and method according to the invention
  • Figure 2 is a schematic side view of a second arrangement and method according to the invention.
  • Figure 4 is a schematic view of a combustion plant arrangement comprising an arrangement of the invention.
  • the gasification equipment 3 may be any gasification equipment known per se, such as a circulating fluidized bed gasifier, i.e. a CFB gasifier.
  • a circulating fluidized bed gasifier i.e. a CFB gasifier.
  • the gasification of the fuel F takes place in a reactor 7 of the gasification equipment.
  • the alkali metals contained in the fuel remain in a solid state.
  • Alkali metals in solid state flow with the fuel gas P into the separator 4, where they are removed from the product gas G.
  • the alkali metals content of the product gas to be conveyed into the combustion plant is very low, even to the extent that the product gas G is in practice preferably free of alkali.
  • the low alkali metals content of the product gas G essentially reduces, or, in practice, even abolishes altogether the corrosion risk of the combustion plant. This allows e.g. corrosion of superheaters possibly provided in the combustion plant to be reduced.
  • a particularly high amount of alkali metals is found in agro fuels.
  • a further advantage of the low temperature to be mentioned is that it is below the typical sintering temperature of alkali metals, so alkali metals are unlikely to sinter on the surfaces of the reactor 7. This allows the cleaning interval of the reactor 7 to be extended.
  • the operation of the CFB gasifier is based on recycling of the bed material. This kind of situation is achieved by increasing the flow rate of the fluidization gas to be higher than the terminal rate of the particles. As a result, the bed becomes turbulent and the particles are carried in the fluidization gas to the top part of the gasifier 7 and from there into the cyclone 6 of the gasifier.
  • the separator 4 may comprise a cyclone, or one of the other separators mentioned above, which separates solids S from the fuel gas.
  • the product gas G produced as a result of the separation is conveyed into the combustion plant.
  • the bottom ash on the bottom of the reactor 7 may contain coal. It may be removed by means of a bottom ash oxidizer 11 , such as a wind sieve known per se. The oxidizer blows air and, with it, the light coal upward for gasification in the reactor 7.
  • the combustion plant 5 may be a boiler, known per se, in which the product gas G may be burned and the generated thermal energy is recovered into water and/or steam by means of different thermal surfaces, such as the boiler walls, superheaters, boiling surfaces and economizers.
  • the combustion plant 5 may be a furnace, such as cement kiln, in which the energy obtained by burning the product gas is used for carrying out a chemical or physical process.
  • the combustion plant arrangement may comprise fuel pre- processing means 2, which may include drying means for reducing the moisture content of the wet fuel.
  • the drying means may comprise a belt drier, for example.
  • the arrangement of the invention is characterized in that: the gasification equipment comprises means for gasifying fuel to produce a product gas at a low temperature and in that the arrangement further comprises a separator arranged between the gasification equipment and the combustion plant so that substantially all the product gas flows through it from the gasification equipment into the combustion plant, the separator comprising means for purifying the product gas of solids.
  • the method of the invention is characterized by adjusting the temperature of the gasification equipment so that it is at most 800°C, conveying the fuel gas generated in the gasification from the gasification equipment into the separator, purifying the fuel of solids, whereby product gas is produced, and conveying the product gas into the combustion plant for combustion.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Feeding And Controlling Fuel (AREA)

Abstract

La présente invention concerne un système et un procédé de combustion de combustible. Le système (1) comprend un équipement (3) de gazéification destiné à convertir le combustible (F) en produit gazeux (G) par gazéification et une unité (5) de combustion destinée à brûler le produit gazeux (G). L'équipement (3) de gazéification comprend un moyen pour gazéifier le combustible à faible température. Le système (1) comprend également un séparateur (4) disposé entre l'équipement (3) de gazéification et l'unité (5) de combustion de sorte que pratiquement tout le produit gazeux (G), transporté à l'intérieur de l'unité de combustion, circule à partir de l'équipement (3) de gazéification à travers le séparateur et à l'intérieur de l'unité (5) de combustion. Le séparateur (4) comprend un moyen pour purifier le produit gazeux (G) de solides.
PCT/FI2014/050673 2013-09-03 2014-09-03 Système et procédé de combustion de combustible WO2015033022A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP14781612.8A EP3041919B1 (fr) 2013-09-03 2014-09-03 Système et procede pour brûler des combustibles
SI201430498T SI3041919T1 (en) 2013-09-03 2014-09-03 Arrangement and method of burning fuel
HRP20171737TT HRP20171737T1 (hr) 2013-09-03 2017-11-13 Sustav za i postupak izgaranja goriva

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20135887A FI126917B (fi) 2013-09-03 2013-09-03 Järjestely ja menetelmä polttoaineen polttamiseksi
FI20135887 2013-09-03

Publications (1)

Publication Number Publication Date
WO2015033022A1 true WO2015033022A1 (fr) 2015-03-12

Family

ID=51663213

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI2014/050673 WO2015033022A1 (fr) 2013-09-03 2014-09-03 Système et procédé de combustion de combustible

Country Status (6)

Country Link
EP (1) EP3041919B1 (fr)
FI (1) FI126917B (fr)
HR (1) HRP20171737T1 (fr)
HU (1) HUE035411T2 (fr)
SI (1) SI3041919T1 (fr)
WO (1) WO2015033022A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105588120A (zh) * 2016-03-02 2016-05-18 内蒙古金土环保科技有限公司 一种脱硫泛氧燃烧系统
WO2018133303A1 (fr) * 2017-01-23 2018-07-26 中科聚信洁能热锻装备研发股份有限公司 Procédé et appareil pour mettre en oeuvre une gazéification par combinaison d'un lit fluidisé circulant et d'un lit de pyrolyse

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4211669A (en) * 1978-11-09 1980-07-08 Exxon Research & Engineering Co. Process for the production of a chemical synthesis gas from coal
DE3217030A1 (de) * 1982-05-06 1983-11-10 BKMI Industrieanlagen GmbH, 8000 München Verfahren zur verschwelung und vergasung von kohlenstoffhaltigen feststoffen
EP0383565A1 (fr) * 1989-02-14 1990-08-22 Manufacturing And Technology Conversion International, Inc. Procédés et appareil pour réactions endothermiques
EP1136542A1 (fr) * 1998-11-05 2001-09-26 Ebara Corporation Systeme de production d'energie par gazeification d'un materiau combustible

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4676177A (en) 1985-10-09 1987-06-30 A. Ahlstrom Corporation Method of generating energy from low-grade alkaline fuels
US5536285A (en) 1993-07-12 1996-07-16 Foster Wheeler Energia Oy Ceramic filtering of gases
US5626088A (en) 1995-11-28 1997-05-06 Foster Wheeler Energia Oy Method and apparatus for utilizing biofuel or waste material in energy production
FI126542B (fi) 2008-06-13 2017-02-15 Valmet Technologies Oy Menetelmä ja laitos meesan käsittelemiseksi sekä petimateriaali
JP5535732B2 (ja) 2010-04-05 2014-07-02 三菱重工業株式会社 ボイラ設備

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4211669A (en) * 1978-11-09 1980-07-08 Exxon Research & Engineering Co. Process for the production of a chemical synthesis gas from coal
DE3217030A1 (de) * 1982-05-06 1983-11-10 BKMI Industrieanlagen GmbH, 8000 München Verfahren zur verschwelung und vergasung von kohlenstoffhaltigen feststoffen
EP0383565A1 (fr) * 1989-02-14 1990-08-22 Manufacturing And Technology Conversion International, Inc. Procédés et appareil pour réactions endothermiques
EP1136542A1 (fr) * 1998-11-05 2001-09-26 Ebara Corporation Systeme de production d'energie par gazeification d'un materiau combustible

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105588120A (zh) * 2016-03-02 2016-05-18 内蒙古金土环保科技有限公司 一种脱硫泛氧燃烧系统
CN105588120B (zh) * 2016-03-02 2018-05-11 内蒙古金土环保科技有限公司 一种脱硫泛氧燃烧系统
WO2018133303A1 (fr) * 2017-01-23 2018-07-26 中科聚信洁能热锻装备研发股份有限公司 Procédé et appareil pour mettre en oeuvre une gazéification par combinaison d'un lit fluidisé circulant et d'un lit de pyrolyse

Also Published As

Publication number Publication date
HRP20171737T1 (hr) 2018-01-26
EP3041919A1 (fr) 2016-07-13
FI126917B (fi) 2017-08-15
EP3041919B1 (fr) 2017-11-08
SI3041919T1 (en) 2018-04-30
FI20135887A (fi) 2015-03-04
HUE035411T2 (en) 2018-05-02

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