WO2015019898A1 - 活性エネルギー線硬化型樹脂組成物、これを含有する下塗り用コーティング剤及び成形体 - Google Patents
活性エネルギー線硬化型樹脂組成物、これを含有する下塗り用コーティング剤及び成形体 Download PDFInfo
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- WO2015019898A1 WO2015019898A1 PCT/JP2014/069912 JP2014069912W WO2015019898A1 WO 2015019898 A1 WO2015019898 A1 WO 2015019898A1 JP 2014069912 W JP2014069912 W JP 2014069912W WO 2015019898 A1 WO2015019898 A1 WO 2015019898A1
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- KGGOIDKBHYYNIC-UHFFFAOYSA-N ditert-butyl 4-[3,4-bis(tert-butylperoxycarbonyl)benzoyl]benzene-1,2-dicarboperoxoate Chemical compound C1=C(C(=O)OOC(C)(C)C)C(C(=O)OOC(C)(C)C)=CC=C1C(=O)C1=CC=C(C(=O)OOC(C)(C)C)C(C(=O)OOC(C)(C)C)=C1 KGGOIDKBHYYNIC-UHFFFAOYSA-N 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- MHIBEGOZTWERHF-UHFFFAOYSA-N heptane-1,1-diol Chemical compound CCCCCCC(O)O MHIBEGOZTWERHF-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 1
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 208000013469 light sensitivity Diseases 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 1
- YLHXLHGIAMFFBU-UHFFFAOYSA-N methyl phenylglyoxalate Chemical compound COC(=O)C(=O)C1=CC=CC=C1 YLHXLHGIAMFFBU-UHFFFAOYSA-N 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- FVGBHSIHHXTYTH-UHFFFAOYSA-N pentane-1,1,1-triol Chemical compound CCCCC(O)(O)O FVGBHSIHHXTYTH-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 125000003003 spiro group Chemical group 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/46—Polyesters chemically modified by esterification
- C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
- C08F220/343—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate in the form of urethane links
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate
Definitions
- the present invention is an active energy ray-curable resin composition that is excellent in storage stability and further has a high level of applicability to various substrates, adhesion, and appearance and heat resistance of a cured coating film.
- the present invention relates to an active energy ray-curable resin composition suitably used as an undercoating coating agent for performing metal vapor deposition on a molded body formed by combining a plurality of resin types.
- Base materials used for such applications include BMC (bulk molding compound), PPS (polyphenylene sulfide), ALD (aluminum die cast), PBT (polybutylene terephthalate) / PET (polyethylene terephthalate) alloy resin, PC (polycarbonate). ), ABS (Acrylonitrile-Butadiene-Styrene Copolymer), PC (polycarbonate) reinforced with fillers such as glass fiber, etc., and has excellent heat resistance and impact resistance.
- plastic base materials are often used from the viewpoint of weight reduction.
- the reflector of the headlamp lens of automobile parts is a combination of a plurality of types of base materials.
- a base material with excellent heat resistance is used for the part close to the lamp light source, and a base material with excellent workability is used for the part far from the lamp light source because the base material shape is complicated.
- a coating agent depending on the type of substrate.
- the coating agent is a mixture of an alkyd resin and a (meth) acryloyl group-containing monomer.
- the two have different polarities, it is difficult to uniformly dissolve them.
- the compatibility is poor, it has been a problem to cause appearance defects such as whitening when the coating agent is cured.
- Water-based coating agents are said to be environmentally friendly, but in reality, they contain a low-molecular-weight volatile component used as a neutralizing agent, so that the working environment is not very favorable, and storage stability as a coating agent is problematic. is there.
- the problem to be solved by the present invention is an active energy ray that is excellent in storage stability and further has a high level of coating properties and adhesion to various substrates, and appearance and heat resistance of a cured coating film.
- the object is to provide a curable resin composition, an active energy ray-curable undercoating coating agent for metal vapor deposition using the same, and a molded article having an undercoat layer for metal vapor deposition that has excellent adhesion to various substrates. .
- the present inventors contain, as essential components, an oil-modified alkyd resin obtained by using two or more kinds of specific fats and oils and a compound having a (meth) acryloyl group.
- the present inventors have found that the above problems can be solved by using an active energy ray-curable resin composition to complete the present invention.
- the present invention is an active energy ray-curable resin composition containing an oil-modified alkyd resin (A) and a compound (B) having a (meth) acryloyl group, the oil-modified alkyd resin (A).
- it is an oil-modified alkyd resin having an oil length of 30 to 70 and a mass average molecular weight of 30,000 to 200,000 obtained by using two or more oils and fats (a1) having an iodine value of 100 or more.
- An active energy ray-curable resin composition, an active energy ray-curable undercoating coating agent for metal vapor deposition using the same, and a molded article having an undercoat layer made of the undercoating coating agent are provided.
- an active energy ray-curable resin composition that is excellent in coating suitability, adhesion, and storage stability to various plastic substrates. Since the oil-modified alkyd resin used in the composition has good compatibility with the compound having a (meth) acryloyl group used in combination with this, the resulting cured coating film has excellent smoothness and problems such as whitening It has excellent appearance and heat resistance, so it has excellent applicability to molded products with complex shapes and combinations of multiple types of substrates. It can be suitably used as an agent.
- two or more fats and oils (a1) having an iodine value of 100 or more are used in combination of two or more fats and oils (a1) having an iodine value of 100 or more.
- the oil-modified alkyd resin (A) having an oil length of 30 to 70 and a weight average molecular weight of 30,000 to 200,000 and a compound (B) having a (meth) acryloyl group are obtained as essential components.
- the oil-modified alkyd resin is usually a resin obtained by condensation of a saturated polybasic acid and / or an unsaturated polybasic acid and a polyhydric alcohol using a drying oil, semi-drying oil, non-drying oil or a fatty acid thereof as a modifier. It is.
- the oil-modified alkyd resin is obtained by using two or more oils and fats (a1) having an iodine value of 100 or more, and has an oil length of 30 to 70 and a mass average molecular weight of 30,000. By using up to 200,000 resins, adhesion to various plastic substrates is improved.
- Examples of the oil (a1) having an iodine value of 100 or more include kiri oil, linseed oil, dehydrated castor oil, soybean oil, safflower oil, tall oil and the like. From the viewpoint of adhesion to the substrate, linseed oil, soybean oil, safflower oil, and tall oil are preferably used.
- the molecular weight distribution range of the alkyd resin (A) to be obtained is widened, and it is easy to express adhesion to the substrate and anti-sagging, and easily obtain a composition excellent in coating suitability. Can do.
- it is possible to maintain the uniformity of the resulting oil-modified alkyd resin by using two or more types of oils and fats in combination from the raw material stage, rather than using a mixture of a plurality of types of the alkyd resins after being synthesized as an alkyd resin.
- the combination and mixing ratio of two or more kinds of fats and oils (a1) are not particularly limited, and can be appropriately set according to the intended oil length of the obtained oil-modified alkyd resin (A).
- the iodine value of the fat (a1) is 100 or more.
- the oil-modified alkyd resin (A) used in the present invention is a resin having an oil length of 30 to 70 and a mass average molecular weight of 30,000 to 200,000 obtained by using two or more types of fats and oils having a high iodine value as described above.
- the reactivity with active energy rays and the compatibility with the compound (B) having a (meth) acryloyl group described later are good, but from the viewpoint of further improving the reactivity and compatibility.
- the polyol (a2) having an ether bond in the molecule and the polybasic acid (a3) having a cyclic unsaturated group in the molecule are preferable.
- Examples of the polyol (a2) having an ether bond in the molecule include ring-opening polymerization with various cyclic ether bond-containing compounds such as ethylene oxide, propylene oxide, tetrahydrofuran, ethyl glycidyl ether, propyl glycidyl ether, and butyl glycidyl ether.
- Examples thereof include modified polyether polyols and polyalkylene glycols such as diethylene glycol, dipropylene glycol, polyethylene glycol, and polypropylene glycol, which are particularly excellent in reactivity with active energy rays and are easily available industrially. From the viewpoint, it is preferable to use polyalkylene glycol, and it is particularly preferable to use diethylene glycol or dipropylene glycol.
- the polyhydric alcohol it is preferable to use a branched alkane-type polyol having 3 or more hydroxyl groups in the molecule from the viewpoint of further improving the crosslinking density.
- the branched alkane type polyol include aliphatic polyols such as trimethylolethane, trimethylolpropane, glycerin, hexanetriol, pentaerythritol; the aliphatic polyols, ethylene oxide, propylene oxide, tetrahydrofuran, ethyl glycidyl ether, propyl Polycondensation reaction of modified polyether polyols obtained by ring-opening polymerization with various cyclic ether bond-containing compounds such as glycidyl ether and butyl glycidyl ether, the aliphatic polyols and various lactones such as ⁇ -caprolactone From the viewpoint of improving the cross-linking density and obtaining a film
- polybasic acid (a3) examples include (anhydrous) aromatic dicarboxylic acids such as phthalic acid, terephthalic acid, isophthalic acid and orthophthalic acid; alicyclic dicarboxylic acids such as hexahydrophthalic acid and 1,4-cyclohexanedicarboxylic acid.
- aromatic dicarboxylic acids such as phthalic acid, terephthalic acid, isophthalic acid and orthophthalic acid
- alicyclic dicarboxylic acids such as hexahydrophthalic acid and 1,4-cyclohexanedicarboxylic acid.
- An acid etc. are mentioned, You may use individually or in combination of 2 or more types.
- various monocarboxylic acids can be used in combination for the preparation of the molecular weight of the alkyd resin (A) to be obtained.
- a monocarboxylic acid having a cyclic structure such as benzoic acid.
- the method for producing the oil-modified alkyd resin (A) is not particularly limited, and for example, after reacting fats and oils with alcohols in the presence of a catalyst (esterification reaction or transesterification reaction), further Examples include a method in which an acid is added to cause a reaction (esterification reaction) and a method in which an oil and fat used as a raw material, an alcohol, and an acid are charged and reacted together. The progress of the reaction can be monitored by measuring the amount of water distilled by the dehydration reaction, the acid value or the hydroxyl value.
- the oil length of the oil-modified alkyd resin (A) obtained above is essential to be in the range of 30 to 70, and more preferably in the range of 40 to 60.
- the oil length is the percentage of the fat and oil component mass ratio to the total mass of unsaturated fatty acids or unsaturated fatty acid esters in the oils and carboxylic acids and fats and oils as raw materials.
- the mass average molecular weight (Mw) of the oil-modified alkyd resin (A) used in the present invention is compatible with the compound (B) having a (meth) acryloyl group and the solvent used when preparing the composition. From the viewpoint of obtaining a coating film having good solubility and a relatively low viscosity and excellent appearance, it is essential to be in the range of 30,000 to 200,000.
- the mass average molecular weight (Mw) is preferably in the range of 70,000 to 150,000 because it is easy to increase the density and is excellent in adhesion to the substrate.
- the molecular weight distribution (Mw / Mn) represented by the ratio to the number average molecular weight (Mn) is in the range of 20 to 60 from the viewpoint of following the unevenness of the substrate and adhesion to various substrates. In particular, the range of 20 to 40 is preferable.
- the hydroxyl value of the oil-modified alkyd resin (A) is preferably in the range of 60 to 140, particularly in the range of 90 to 110, from the viewpoint of good adhesion to various substrates. preferable.
- the acid value of the oil-modified alkyd resin (A) is preferably in the range of 1 to 20, particularly in the range of 5 to 15 from the viewpoint of storage stability when the composition is used. preferable.
- various organic solvents may be added to the oil-modified alkyd resin (A).
- the organic solvent include ketones such as acetone, methyl ethyl ketone (MEK), and methyl isobutyl ketone, cyclic ethers such as tetrahydrofuran (THF) and dioxolane, esters such as methyl acetate, ethyl acetate, and butyl acetate, toluene, xylene Aromatics such as carbitol, cellosolve, methanol, isopropanol, butanol, and propylene glycol monomethyl ether. These may be used alone or in combination of two or more.
- ketones such as acetone, methyl ethyl ketone (MEK), and methyl isobutyl ketone
- cyclic ethers such as tetrahydrofuran (THF) and dioxolane
- esters such as methyl acetate,
- the compound (B) having a (meth) acryloyl group used in the present invention is not particularly limited as long as it can react with the oil-modified alkyd resin (A) to obtain a cured coating film. From the viewpoint, it is preferably a compound having two or more (meth) acryloyl groups in one molecule.
- a (meth) acrylate monomer obtained by reacting a polyol and (meth) acrylic acid (2) Urethane (meth) acrylate obtained by adding a compound having a hydroxyl group and a (meth) acryloyl group to a compound having a terminal isocyanate group in the molecule, (3) At least two epoxy groups or glycidyl in the molecule Epoxy (meth) acrylate obtained by reacting a group-containing compound with (meth) acrylic acid, (4) polyol and polybasic acid Is a polyester (meth) acrylate obtained by reacting a polyester polyol obtained by condensation polymerization of the acid anhydride with (meth) acrylic acid, and (5) a copolymer acrylic polymer obtained by polymerizing an acrylic monomer or vinyl monomer with an acryloyl group. Examples thereof include acrylic acrylate obtained by pendant.
- the polyol is not particularly limited.
- (meth) acrylate monomers include, for example, ethylene glycol di (meth) acrylate, diethylene glycol di (meth) acrylate, tetraethylene glycol di (meth) acrylate, polyethylene glycol di (meth) acrylate, propylene glycol di ( (Meth) acrylate, dipropylene glycol di (meth) acrylate, polypropylene glycol di (meth) acrylate, butylene glycol di (meth) acrylate, neopentyl glycol di (meth) acrylate, ethylene oxide modified bisphenol A type di (meth) acrylate, Propylene oxide modified bisphenol A di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, glycerin di (meth) Chryrate, pentaerythritol di (meth) acrylate, ethylene glycol diglycidyl ether di (meth) acrylate
- examples of the compound having a terminal isocyanate group in the molecule include polyisocyanate or polyisocyanate exemplified as the polyol in the compound of (1) above. The thing obtained by making it react can be mentioned.
- the polyisocyanate in the above (2) may be, for example, any of aliphatic, alicyclic, aromatic and aromatic-aliphatic, such as For example, tolylene diisocyanate, 4,4′-diphenylmethane diisocyanate, xylylene diisocyanate, hexamethylene diisocyanate, lysine diisocyanate, 4,4′-methylenebis (cyclohexyl isocyanate), methylcyclohexane-2,4-diisocyanate, methylcyclohexane-2 , 6-diisocyanate, 1,3- (isocyanatomethyl) cyclohexane, isophorone diisocyanate, trimethylhexamethylene diisocyanate, dimer acid diisocyanate, dianisidine diisocyanate, phenyldi Socyanate, halogenated phenyl diisocyanate, methylene diisocyanate, ethylene diiso
- Diisocyanates such as 3-dimethoxy-4.4'-diisocyanate diphenyl, 1,4-anthracene diisocyanate, phenylene diisocyanate, 1,4-tetramethylene diisocyanate, 1,10-decanmethylene diisocyanate, 1,3-cyclohexylene diisocyanate Nurates, burettes, adducts of these diisocyanates; triisocyanates such as 2,4,6-tolylene triisocyanate, 2,4,4′-triisocyanate diphenyl ether, etc. Can.
- Examples of the compound having a hydroxyl group and a (meth) acryloyl group in the above (2) include pentaerythritol tri (meth) acrylate, dipentaerythritol penta (meth) acrylate, epoxy (meth) acrylate, 2-hydroxyethyl (meth).
- Examples of the compound having at least two epoxy groups or glycidyl groups in the molecule (3) include glycidyl ethers containing, for example, bisphenol A, bisphenol F, 2,6-xylenol, brominated bisphenol A, phenol novolac and the like.
- Type epoxy resin, glycidyl ester type epoxy resin containing dimer acid, glycidyl ester type epoxy resin containing aromatic or heterocyclic amine, alicyclic epoxy resin, acrylic resin having epoxy group or glycidyl group, etc. Can be mentioned.
- glycerol triglycidyl ether trimethylolpropane triglycidyl ether, sorbitol tetraglycidyl ether, sorbitol pentaglycidyl ether, sorbitan tetraglycidyl ether, sorbitan pentaglycidyl ether , Triglycerol tetraglycidyl ether, tetraglycerol tetraglycidyl ether, pentaglycerol tetraglycidyl ether, triglycerol pentaglycidyl ether, tetraglycerol pentaglycidyl ether, pentaglycerol pentaglycidyl ether, pentaerythritol tetraglycidyl ether, triglycidyl isocyanurate, etc. be able to
- examples of the polyol, polybasic acid or acid anhydride thereof include the same as those described above.
- the compound (B) having a (meth) acryloyl group the above (1) to (5) can be used, and these are polymerized due to the participation of the unsaturated bond contained therein.
- the reaction occurs and the active energy ray is cured, but if necessary, other compounds having an unsaturated bond such as diallyl fumarate and triallyl isocyanurate can also be contained.
- the mass ratio [(A) / (B)] of the content of the oil-modified alkyd resin (A) in the active energy ray-curable resin composition of the present invention and the compound (B) having a (meth) acryloyl group is:
- a range of 20/80 to 80/20 is preferable from the viewpoint of obtaining a coating film having good compatibility and a good coating film appearance.
- the range of 70/30 to 30/70 is more preferable in that an excellent adhesion to the substrate and a tough coating film can be obtained.
- a photopolymerization initiator (C) can be contained in order to favorably advance the curing reaction with active energy rays.
- the photopolymerization initiator (C) is not particularly limited as long as it generates radicals by the action of light, and specifically includes 4-phenoxydichloroacetophenone, 4-t-butyl-dichloroacetophenone, diethoxy.
- Examples of the commercially available photopolymerization initiator (C) include Irgacure-184, 149, 261, 369, 500, 651, 754, 784, 819, 907, 1116, 1664, 1700, 1800, 1850, 2959, 4043, Darocur-1173, Lucillin TPO (manufactured by BASF), Kayacure-DETX, MBP, DMBI, EPA, OA (Nippon Kayaku Co., Ltd.) Company), BiCure-10, 55 (Stofa Chemical), Trigonal P1 (Akzo), Sandley 1000 (Sands), Deep (Apjon), Quantacure-PDO, ITX, EPD (manufactured by Ward Brenkinsop) and the like can be mentioned. These may be used alone or in combination of two or more.
- the photopolymerization initiator maintains light sensitivity satisfactorily and does not cause precipitation of crystals or deterioration of physical properties of the coating film.
- the range is preferably 0.05 to 20 parts by mass, and more preferably 0.1 to 10 parts by mass.
- an amino resin may be included as necessary to further improve the heat resistance of the resulting coating film.
- the amino resin examples include a methylolated amino resin synthesized from at least one of melamine, urea, and benzoguanamine and formaldehyde; such a methylolated amino resin, wherein a part or all of the methylol group is obtained.
- Alkyl etherified with a lower monohydric alcohol such as methanol, ethanol, propanol, isopropanol, butanol, isobutanol, and the like.
- amino resins include, for example, Cymel 303 (manufactured by Nippon Cytec Industries, Inc., methylated melamine resin), Cymel 350 (manufactured by Nippon Cytec Industries, Inc., methylated melamine resin), Uban 520 (Mitsui).
- the amino resin when used, it is preferable to contain 5 to 20 parts by mass with respect to a total of 100 parts by mass of the oil-modified alkyd resin (A) and the compound (B) having a (meth) acryloyl group in the composition.
- composition of the present invention can contain a solvent in order to dilute and facilitate coating.
- the solvent is not particularly limited, but a low surface tension solvent is preferable in order to improve wettability.
- examples of such a solvent include alcohol solvents, ketone solvents, and the like.
- ethyl acetate, butyl acetate, toluene, xylene and the like can be used in combination in view of the evaporation rate and cost.
- composition of the present invention can contain a surface conditioner.
- the surface preparation agent is not particularly limited, and examples thereof include a fluorine-based additive and a cellulose-based additive.
- the fluorine-based additive has a function of preventing repelling when applied to various substrates by reducing surface tension and increasing wettability.
- Specific examples of the fluorine-based additive include Megafac F-177 (manufactured by DIC Corporation).
- the cellulosic additive has an effect of imparting a film-forming property at the time of coating.
- the cellulose-based additive is preferably a high molecular weight product having a number average molecular weight of 15000 or more in order to reduce fluidity. Examples of such a cellulose additive include cellulose acetate-butyrate resin.
- the amount of the fluorine-based additive when the amount of the fluorine-based additive is increased, the adhesion of the deposited aluminum and the top coat is decreased, and when the amount of the cellulose-based additive is increased, the solid content of the composition of the present invention is increased. It is preferable to use a fluorine-based additive and a cellulose-based additive in combination.
- the addition amount of the surface preparation agent ranges from 0.01 to 3.0 parts by mass with respect to the total amount of fluorine-based additive and cellulose-based additive with respect to 100 parts by mass of the nonvolatile content in the composition. preferable.
- the fluorine-based additive is used alone, it is preferably in the range of 0.01 to 1.0 part by mass, and when the cellulose-based additive is used alone, it is 0.5 to 5.0 parts by mass. It is preferable that it is the range of these.
- the active energy ray-curable resin composition of the present invention further includes various additions such as a photosensitizer, an ultraviolet absorber, an antioxidant, a silicon-based additive, a rheology control agent, a defoaming agent, an antistatic agent, and an antifogging agent.
- a photosensitizer such as an ultraviolet absorber, an antioxidant, a silicon-based additive, a rheology control agent, a defoaming agent, an antistatic agent, and an antifogging agent.
- An agent may be contained.
- the active energy ray-curable resin composition of the present invention can be suitably used as an active energy ray-curable undercoat coating agent for metal deposition. Specifically, it is used as an undercoat layer when a metal vapor deposition layer is formed on a substrate.
- an undercoat layer when a metal vapor deposition layer is formed on a substrate.
- the active energy ray-curable resin composition of the present invention is applied onto a substrate by a method such as spray coating.
- the coating amount is preferably in the range of 5 to 60 ⁇ m after curing, and more preferably in the range of 10 to 40 ⁇ m.
- the resin composition is cured by irradiating active energy rays to form the undercoat layer.
- active energy rays include ultraviolet rays and electron beams.
- an ultraviolet irradiation device having a xenon lamp, a high-pressure mercury lamp, or a metal halide lamp as a light source can be used, and the amount of light, the arrangement of the light source, etc. are adjusted as necessary.
- it is preferable to irradiate to ultraviolet integrated light quantity is 50 ⁇ 5000mJ / cm 2, accumulated light amount is more preferably irradiated such that the 500 ⁇ 2000mJ / cm 2.
- the base material on which the undercoat layer of the present invention is installed is provided with a metal vapor deposition layer thereon, and a top coat layer and the like are further provided thereon.
- the thickness of the metal vapor-deposited layer is preferably in the range of 30 nm to 3 ⁇ m
- the thickness of the topcoat layer after curing is preferably in the range of 3 to 40 ⁇ m.
- Examples of the molded body thus obtained include an automobile reflector.
- Mass average molecular weight (Mw) and molecular weight distribution (Mw / Mn) were measured by gel permeation chromatography (GPC) under the following conditions.
- Measuring device HLC-8220GPC manufactured by Tosoh Corporation Column: TSK-GUARDCOLUMN SuperHZ-L manufactured by Tosoh Corporation + Tosoh Corporation TSK-GEL SuperHZM-M ⁇ 4 Detector: RI (differential refractometer) Data processing; Multi-station GPC-8020 model II manufactured by Tosoh Corporation Measurement conditions; Column temperature 40 ° C Solvent Tetrahydrofuran Flow rate 0.35 ml / min Standard; Monodisperse polystyrene Sample; Filtered 0.2% tetrahydrofuran solution in terms of resin solids with a microfilter (100 ⁇ l)
- Synthesis example 1 In a flask having a stir bar, temperature sensor, rectifying tube, decanter, 840 parts of linseed oil, 420 parts of soybean oil, 208 parts of benzoic acid, 525 parts of pentaerythritol, 88 parts of diethylene glycol, 843 parts of phthalic anhydride, 85 parts of xylene and 0.5 part of an organic titanium compound was charged, dry nitrogen was flowed into the flask, and heated to 230 to 250 ° C. with stirring to perform a dehydration condensation reaction.
- Synthesis example 2 In a flask equipped with a stir bar, temperature sensor, rectifying tube and decanter, 616 parts of linseed oil, 299 parts of soybean oil fatty acid, 53 parts of p-tert-benzoic acid, 211 parts of pentaerythritol, 38 parts of dipropylene glycol, 153 parts of glycerin Then, 563 parts of phthalic anhydride, 71 parts of xylene and 0.4 part of an organotitanium compound were charged, dried nitrogen was flowed into the flask and heated to 230 to 250 ° C. with stirring to carry out a dehydration condensation reaction.
- Synthesis example 3 In a flask having a stir bar, temperature sensor, rectifying tube, decanter, linseed oil 1149 parts, safflower oil 391 parts, benzoic acid 12 parts, pentaerythritol 450 parts, dipropylene glycol 91 parts, phthalic anhydride 664 parts, isophthal 149 parts of acid, 71 parts of xylene and 0.4 part of an organic titanium compound were charged, dried nitrogen was flowed into the flask and heated to 230 to 250 ° C. with stirring to perform a dehydration condensation reaction.
- Acrylic resin (X) “Acridic 56-393-BA” (manufactured by DIC Corporation, 20 parts of styrene in 100 parts of monomer mixture, glass transition temperature: 5 ° C.) was used. This is designated as acrylic resin (X).
- Comparative Alkyd Resin (Y1) In a flask having a stir bar, temperature sensor, condenser, linseed oil 1,104 parts, benzoic acid 470 parts, pentaerythritol 605 parts, phthalic anhydride 740 parts, xylene 85 parts and organic titanium 0.4 parts of the compound was charged, dry nitrogen was flowed into the flask, and heated to 220-240 ° C. with stirring to conduct a dehydration condensation reaction.
- alkyd resin (Y1).
- Alkyd resin for comparison (Y2) A flask having a stirring bar, a temperature sensor, and a condenser is charged with 1,120 parts of soybean oil, 200 parts of neopentyl glycol, 460 parts of trimethylolpropane, 1210 parts of phthalic anhydride, 85 parts of xylene and 0.4 parts of an organic titanium compound. Then, dry nitrogen was allowed to flow into the flask and heated to 220-240 ° C. with stirring to conduct a dehydration condensation reaction.
- alkyd resin (Y2).
- Alkyd resin for comparative example (Y3) In a flask having a stir bar, temperature sensor, rectifying tube, decanter, soybean oil 1412 parts, neopentyl glycol 259 parts, trimethylolpropane 445.6 parts, adipic acid 276 parts, phthalic anhydride 559 parts, xylene 90 parts and An organic titanium compound (0.3 parts) was charged, dry nitrogen was flowed into the flask, and heated to 220 to 240 ° C. with stirring to perform a dehydration condensation reaction.
- alkyd resin having an oil length of 50 having a number average molecular weight of 3,800, a mass average molecular weight of 310,000, a hydroxyl value of 78, and an acid value of 8 was obtained. This is designated as alkyd resin (Y3).
- alkyd resin having a number average molecular weight of 3,800, a mass average molecular weight of 303,000, a hydroxyl value of 41, and an acid value of 5.1 was obtained. This is designated as alkyd resin (Y4).
- Kayalad TMPTA Trimethylolpropane triacrylate (Nippon Kayaku Co., Ltd.) Aronix M-305: A mixture of pentaerythritol triacrylate and pentaerythritol tetraacrylate (manufactured by Toagosei Co., Ltd.) NK-ester APG-200: Tripropylene glycol diacrylate (manufactured by Shin-Nakamura Chemical Co., Ltd.) Aronix M-5300: ⁇ -carboxy-polycaprolactone (n ⁇ 2) monoacrylate (manufactured by Toagosei Co., Ltd.) Cymel 303: Melamine resin (Nippon Cytec Industries, Ltd.) Cymel 307: Melamine resin (Nippon Cytec Industries, Inc.) Irgacure 651: Photopolymerization initiator (BASF) Kayacure DETX-S: Photopolymerization initiator (Nippon Kayaku Co.
- Reflective Material BMC bulk molding compound
- PPS polyphenylene sulfide
- PBT polybutylene terephthalate
- PET polyethylene terephthalate
- PC polycarbonate
- the composition prepared previously was air spray-coated on the surface of each substrate. Thereafter, the solvent is dried under conditions of 80 ° C. ⁇ 10 minutes, and an undercoat layer having a film thickness of 10 to 15 ⁇ m is formed on the substrate by irradiating ultraviolet rays with an irradiation amount of 1000 mJ / cm 2 with an 80 W / cm high-pressure mercury lamp. Undercoat layer) was formed.
- Reflector 1 180 ° C
- Reflector 2 230 ° C
- Reflector 3 200 ° C
- Reflector 4 120 ° C
- the reflective plate 1 was evaluated for appearance and adhesion after being left in a constant temperature and humidity chamber with a temperature of 50 ° C. and a humidity of 95 RH% for 240 hours.
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Abstract
Description
質量平均分子量(Mw)、分子量分布(Mw/Mn)は下記条件のゲルパーミュレーションクロマトグラフィー(GPC)により測定した。
カラム ;東ソー株式会社製 TSK-GUARDCOLUMN SuperHZ-L
+東ソー株式会社製 TSK-GEL SuperHZM-M×4
検出器 ;RI(示差屈折計)
データ処理;東ソー株式会社製 マルチステーションGPC-8020modelII 測定条件 ;カラム温度 40℃
溶媒 テトラヒドロフラン
流速 0.35ml/分
標準 ;単分散ポリスチレン
試料 ;樹脂固形分換算で0.2%のテトラヒドロフラン溶液をマイクロフィルターでろ過したもの(100μl)
攪拌棒、温度センサー、精留管、デカンターを有するフラスコに、亜麻仁油840部、大豆油420部、安息香酸208部、ペンタエリスリトール525部、ジエチレングリコール88部、無水フタル酸843部、キシレン85部及び有機チタン化合物0.5部を仕込み、乾燥窒素をフラスコ内にフローさせ攪拌しながら230~250℃に加熱し、脱水縮合反応を行った。酸価が10.0mgKOH/gとなったところで反応を停止し、150℃まで冷却後、混合溶剤(キシレン/トルエン=50/50(質量比))を滴下して固形分60%に希釈した。その結果、数平均分子量4,200、質量平均分子量109,000、水酸基価85、酸価10.0である油長45のアルキド樹脂(A1)を得た。
攪拌棒、温度センサー、精留管、デカンターを有するフラスコに、亜麻仁油616部、大豆油脂肪酸299部、p-tert-安息香酸53部、ペンタエリスリトール211部、ジプロピレングリコール38部、グリセリン153部、無水フタル酸563部、キシレン71部及び有機チタン化合物0.4部を仕込み、乾燥窒素をフラスコ内にフローさせ攪拌しながら230~250℃に加熱し、脱水縮合反応を行った。酸価が8.3mgKOH/gとなったところで反応を停止し、150℃まで冷却後、混合溶剤(キシレン/トルエン=50/50(質量比))を滴下して固形分60%に希釈した。その結果、数平均分子量3,400、質量平均分子量90,000、水酸基価108、酸価8.3である油長50のアルキド樹脂(A2)を得た。
攪拌棒、温度センサー、精留管、デカンターを有するフラスコに、亜麻仁油1149部、サフラワー油391部、安息香酸12部、ペンタエリスリトール450部、ジプロピレングリコール91部、無水フタル酸664部、イソフタル酸149部、キシレン71部及び有機チタン化合物0.4部を仕込み、乾燥窒素をフラスコ内にフローさせ攪拌しながら230~250℃に加熱し、脱水縮合反応を行った。酸価が8.9mgKOH/gとなったところで反応を停止し、150℃まで冷却後、混合溶剤(キシレン/トルエン=50/50(質量比))を滴下して固形分60%に希釈した。その結果、数平均分子量3,900、質量平均分子量78,000、水酸基価81、酸価8.9である油長55のアルキド樹脂(A3)を得た。
「アクリディック 56-393-BA」(DIC株式会社製、単量体混合物100部中スチレン20部、ガラス転移温度:5℃)を用いた。これをアクリル樹脂(X)とする。
攪拌棒、温度センサー、コンデンサを有するフラスコに、亜麻仁油1,104部、安息香酸470部、ペンタエリスリトール605部、無水フタル酸740部、キシレン85部及び有機チタン化合物0.4部を仕込み、乾燥窒素をフラスコ内にフローさせ攪拌しながら220~240℃に加熱し、脱水縮合反応を行った。酸価が2.6mgKOH/gとなったところで反応を停止し、150℃まで冷却後、混合溶剤(キシレン/トルエン=50/50(質量比))を滴下して固形分60%に希釈した。その結果、数平均分子量3,600、質量平均分子量52,000、水酸基価84、酸価2.6である油長40のアルキド樹脂を得た。これをアルキド樹脂(Y1)とする。
攪拌棒、温度センサー、コンデンサを有するフラスコに、大豆油1,120部、ネオペンチルグリコール200部、トリメチロールプロパン460部、無水フタル酸1210部、キシレン85部及び有機チタン化合物0.4部を仕込み、乾燥窒素をフラスコ内にフローさせ攪拌しながら220~240℃に加熱し、脱水縮合反応を行った。酸価が41mgKOH/gとなったところで反応を停止し、150℃まで冷却後、混合溶剤(キシレン/トルエン=50/50(質量比))を滴下して固形分60%に希釈した。その結果、数平均分子量3,600、質量平均分子量39,000、水酸基価20、酸価41である油長40のアルキド樹脂を得た。これをアルキド樹脂(Y2)とする。
攪拌棒、温度センサー、精留管、デカンターを有するフラスコに、大豆油1412部、ネオペンチルグリコール259部、トリメチロールプロパン445.6部、アジピン酸276部、無水フタル酸559部、キシレン90部及び有機チタン化合物0.3部を仕込み、乾燥窒素をフラスコ内にフローさせ攪拌しながら220~240℃に加熱し、脱水縮合反応を行った。酸価が8mgKOH/g以下となったところで反応を停止し、150℃まで冷却後、トルエンと酢酸エチルを滴下して固形分50%に希釈した。その結果、数平均分子量3,800、質量平均分子量310,000、水酸基価78、酸価8である油長50のアルキド樹脂を得た。これをアルキド樹脂(Y3)とする。
攪拌棒、温度センサー、精留管、デカンターを有するフラスコに、亜麻仁油1269部、ペンタエリスリトール593部、無水フタル酸880g、キシレン60部及び有機チタン化合物0.3部を仕込み、乾燥窒素をフラスコ内にフローさせ攪拌しながら220~240℃に加熱し、脱水縮合反応を行った。酸価が5.1mgKOH/g以下となったところで反応を停止し、150℃まで冷却後、トルエンと酢酸エチルを滴下して固形分50%に希釈した。その結果、数平均分子量3,800、質量平均分子量303,000、水酸基価41、酸価5.1である油長45のアルキド樹脂を得た。これをアルキド樹脂(Y4)とする。
表1に示す固形分比率(質量比)でアルキド樹脂(A)、(メタ)アクリロイル基を有する化合物(B)、必要に応じてアミン化合物を使用し、光重合開始剤(C)と、表面調整剤と、溶剤とを表1に示す固形分比率(質量比)で混合して、液状の樹脂組成物を調製した。
なお、比較例3については、表1に示す塗料組成物の固形分質量比で混合した後、イオン交換水を固形分が30%になるまで徐々に加え転相乳化させて、液状の組成物を調製した。
カヤラッドTMPTA:トリメチロールプロパントリアクリレート(日本化薬株式会社製)
アロニックスM-305:ペンタエリスリトールトリアクリレートとペンタエリスリトールテトラアクリレートの混合物(東亞合成株式会社製)
NK-エステルAPG-200:トリプロピレングリコールジアクリレート(新中村化学工業製)
アロニックスM-5300:ω-カルボキシ-ポリカプロラクトン(n≒2)モノアクリレート(東亞合成株式会社製)
サイメル303:メラミン樹脂(日本サイテックインダストリーズ株式会社製)
サイメル307:メラミン樹脂(日本サイテックインダストリーズ株式会社製)
イルガキュア651:光重合開始剤(BASF社製)
カヤキュアDETX-S:光重合開始剤(日本化薬株式会社製)
イルガキュア184:光重合開始剤(BASF社製製)
メガファックF-477:表面改質剤(DIC株式会社製)
得られた組成物を40℃で3カ月間保存し、その貯蔵安定性を目視にて観察し、以下に示す評価基準にて評価した。結果を表1に示す。
○:溶液の外観変化が無く、塗装可能である。
×:ゲルの発生あるいは分離しており、塗装不可である。
基材として、BMC(バルクモールディングコンパウンド)、PPS(ポリフェニレンサルファイド)、PBT(ポリブチレンテレフタレート)/PET(ポリエチレンテレフタレート)アロイ、PC(ポリカーボネート)を用いた。
反射板の平滑性について、以下の評価基準にて目視で評価した。
〇:液タレやユズ肌が見られず、平滑である。
△:わずかに液タレやユズ肌見られるが、使用可能な範囲である。
×:明らかに液タレやユズ肌が見られる。
反射板の外観状態について、以下の評価基準にて目視で評価した。
○:クラックやフクレ、白化等の欠陥がない。
△:僅かにクラックやフクレ、白化等の欠陥がある。
×:はっきりとクラックやフクレ等の欠陥がある。
反射板の保護膜上に、2mm幅で10×10の碁盤目状にカッターナイフで切れ目を入れ、その上からセロハン粘着テープを貼着した後、急速に剥がす操作を行い、剥離せずに残存した碁盤目の数を数え、以下の評価基準にて評価した。
○:碁盤目の残存数が100個。
△:碁盤目の残存数が91~99個。
×:碁盤目の残存数が90個以下。
反射板1~4を以下の温度の熱風乾燥炉に入れ、96時間放置した後の、外観状態、密着性について評価した。
反射板1:180℃
反射板2:230℃
反射板3:200℃
反射板4:120℃
反射板1を温度50℃、湿度95RH%の恒温恒湿器の中で240時間放置した後の、外観状態、密着性について評価した。
Claims (10)
- 油変性アルキド樹脂(A)と、(メタ)アクリロイル基を有する化合物(B)とを含有する活性エネルギー線硬化型樹脂組成物であって、
前記油変性アルキド樹脂(A)が、ヨウ素価が100以上の油脂(a1)を2種以上併用して得られる、油長が30~70、質量平均分子量が3万~20万の油変性アルキド樹脂であることを特徴とする活性エネルギー線硬化型樹脂組成物。 - 前記油変性アルキド樹脂(A)の水酸基価が60~140の範囲である請求項1記載の活性エネルギー線硬化型樹脂組成物。
- 前記ヨウ素化が100以上の油脂(a1)が、亜麻仁油、大豆油、サフラワー油及びトール油からなる群から選ばれる油脂である請求項1又は2記載の活性エネルギー線硬化型樹脂組成物。
- 前記油変性アルキド樹脂(A)が、分子内にエーテル結合を有するポリオール(a2)と、分子内に環状不飽和基を有する多塩基酸(a3)とを用いて得られるものである請求項1~3の何れか1項記載の活性エネルギー線硬化型樹脂組成物。
- 前記分子内にエーテル結合を有するポリオール(a2)が、ポリアルキレングリコールを含むものである請求項4記載の活性エネルギー線硬化型樹脂組成物。
- 前記(メタ)アクリロイル基を有する化合物(B)が、(メタ)アクリレートモノマー、ウレタン(メタ)アクリレート、エポキシ(メタ)アクリレート、ポリエステル(メタ)アクリレート及びアクリルアクリレートからなる群から選ばれる1種以上の化合物である請求項1~5の何れか1項記載の活性エネルギー線硬化型樹脂組成物。
- 前記油変性アルキド樹脂(A)と、前記(メタ)アクリロイル基を有する化合物(B)との質量比〔(A)/(B)〕が20/80~80/20の範囲である請求項1~6の何れか1項記載の活性エネルギー線硬化型樹脂組成物。
- 更に光重合開始剤(C)を含有する請求項1~7の何れか1項記載の活性エネルギー線硬化型樹脂組成物。
- 請求項1~8の何れか1項記載の活性エネルギー線硬化型樹脂組成物を含んでなることを特徴とする金属蒸着用活性エネルギー線硬化型下塗り用コーティング剤。
- 請求項9記載の下塗り用コーティング剤からなるアンダーコート層を有することを特徴とする成形体。
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CN201480008626.5A CN105073805B (zh) | 2013-08-07 | 2014-07-29 | 活性能量射线固化型树脂组合物、含有其的底涂用涂布剂及成型体 |
JP2014555002A JP5713156B1 (ja) | 2013-08-07 | 2014-07-29 | 活性エネルギー線硬化型樹脂組成物、これを含有する下塗り用コーティング剤及び成形体 |
US14/772,206 US20160017177A1 (en) | 2013-08-07 | 2014-07-29 | Actinic-radiation-curable resin composition, primer contianing the same, and shaped article |
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Cited By (5)
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JP2017039791A (ja) * | 2015-08-17 | 2017-02-23 | Dic株式会社 | 活性エネルギー線硬化型樹脂組成物、これを含有する下塗り用コーティング剤及び成形体 |
JP2017039792A (ja) * | 2015-08-17 | 2017-02-23 | Dic株式会社 | 活性エネルギー線硬化型樹脂組成物、これを含有する下塗り用コーティング剤及び成形体 |
WO2022145375A1 (ja) * | 2020-12-28 | 2022-07-07 | 日本ペイント・オートモーティブコーティングス株式会社 | Frp用活性エネルギー線硬化性下塗り塗料組成物 |
WO2022145376A1 (ja) * | 2020-12-28 | 2022-07-07 | 日本ペイント・オートモーティブコーティングス株式会社 | Frp用活性エネルギー線硬化性下塗り塗料組成物 |
JP7341388B1 (ja) | 2022-12-26 | 2023-09-11 | 東洋インキScホールディングス株式会社 | 金属印刷用活性エネルギー線硬化型インキ組成物およびその積層体 |
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KR20180111890A (ko) * | 2016-03-11 | 2018-10-11 | 디아이씨 가부시끼가이샤 | 적층체의 제조 방법 |
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