WO2014203121A1 - Procédé de traitement d'une plante par une solution comprenant un polysaccharide nanofibrillé - Google Patents
Procédé de traitement d'une plante par une solution comprenant un polysaccharide nanofibrillé Download PDFInfo
- Publication number
- WO2014203121A1 WO2014203121A1 PCT/IB2014/062131 IB2014062131W WO2014203121A1 WO 2014203121 A1 WO2014203121 A1 WO 2014203121A1 IB 2014062131 W IB2014062131 W IB 2014062131W WO 2014203121 A1 WO2014203121 A1 WO 2014203121A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- suspension
- plant
- water
- fungus
- solution
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
- C09K17/18—Prepolymers; Macromolecular compounds
- C09K17/32—Prepolymers; Macromolecular compounds of natural origin, e.g. cellulosic materials
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G18/00—Cultivation of mushrooms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G22/00—Cultivation of specific crops or plants not otherwise provided for
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G22/00—Cultivation of specific crops or plants not otherwise provided for
- A01G22/60—Flowers; Ornamental plants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/007—Modification of pulp properties by mechanical or physical means
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
- D21H11/18—Highly hydrated, swollen or fibrillatable fibres
Definitions
- the present invention relates to a method for treatment of a plant or a fungus with a solution comprising water and a nanofibrillated polysaccharide.
- controllable watering systems such as drip irrigation
- the water absorbing additive absorbs excess water and releases it through osmosis to the roots of the plants.
- the most common used water absorbing additives are water absorbing polymers, such as polyacrylamides which also are called water crystals.
- the drawbacks with water absorbing polymers are high cost, low biodegradability, toxicity and that it might be difficult to apply the water absorbing polymers evenly to the plants.
- the main objects of the present invention are to provide an improved method for providing plants or fungi with water.
- the present invention relates to a method for treating a plant or a fungus which method comprises the steps of; (i) providing a solution comprising water, (ii) adding a nanofibrillated polysaccharide to the solution thereby forming a suspension wherein the concentration of nanofibrillated polysaccharide in the suspension is above 1 ,5% by weight and (iii) subjecting the plant or fungus to said suspension in order to provide the plant or fungus with water.
- a suspension comprising a nanofibrillated polysaccharide it has been shown that the water consumption of the plant or fungus is reduced. It may be preferred that the nanofibrillated polysaccharide is
- microfibril I ated cellulose has excellent water binding properties as well as excellent water releasing properties. Furthermore, microfibrillated cellulose is biodegradable which makes it a very environmental friendly material to use.
- polysaccharide in the suspension is between 1 ,5-30% by weight, preferably between 3-10 % by weight. Concentrations below 1 ,5% by weight did not seem to give the advantage with optimal water releasing properties of the suspension. Furthermore, concentrations above 30% by weight seem to be less beneficial since the suspension almost is in solid state and the water release is very limited.
- the suspension may be in form of a gel. It may be beneficial to subject the plant or fungus to a gel formed suspension since a gel may be easier to distribute to the plant or fungus and the water loss, i.e. water being flown away from the plant or fungus is strongly reduced. It may be preferred to pour the suspension onto the plant or fungus. In this way it is possible to subject the plant or fungus to the suspension in a very easy way.
- the suspension is in solid form, preferably in the form of a sheet, composite material, foam or a powder when the plant or fungus is subjected to the suspension.
- Water is preferably thereafter added in order for the plant or fungus to be able to absorb any water from the suspension. Once water is added to the solid suspension, the nanofibrillated polysaccharide of the suspension is redispersed and absorbs the water which makes it possible for the plant or fungus to absorb the water of the suspension.
- a benefit with the present invention is that it is also possible to add different additives to the solution and/or to the suspension and due to the characteristic of the suspension, the additive will mostly be retained in the suspension until the plant or fungus can absorb it. Consequently, smaller amounts of additives are removed by waste water etc.
- a nutrition agent may be added to the solution and/or to the suspension. In this way the plant or fungus is also subjected to nutrition agents at the same time as it absorbs the water.
- growth hormones may be beneficial to add growth hormones to the solution and/or to the suspension.
- the growth hormones will thus be absorbed by the plant or fungus once it absorbs the water of the suspension.
- the plant is a cut flower.
- a cut flower such as a tulip or rose
- the lifetime of the cut flowers are strongly improved at the same time as the amount of water needed is reduced.
- the plant is a plant planted in soil, such as a tree, a bush or crops. By subjecting the roots of a plant planted in soil to the suspension the amount of water need by the plant is reduced.
- This definition includes bacterial cellulose or nanocellulose spun with either traditional spinning techniques or with electrostatic spinning.
- the material is preferably a polysaccharide but not limited to solely a polysaccharide.
- a polysaccharide can be e.g. starch, protein, cellulose derivatives etc.
- microfibrillated cellulose as defined more in detail below is included in this definition.
- microfibrillated cellulose is also known as nanocellulose. It is a material typically made from wood cellulose fibers, from both hardwood or softwood fibers. It can also be made from microbial sources, e.g. seaweed fermented fibers, agricultural fibers such as wheat straw pulp, bamboo or other non-wood fiber sources. In microfibrillated cellulose the individual microfibrils have been partly or totally detached from each other.
- microbial sources e.g. seaweed fermented fibers, agricultural fibers such as wheat straw pulp, bamboo or other non-wood fiber sources.
- microfibrillated cellulose fibril is normally very thin (e.g. a width of 5-200 nm) and the length is often between 100 nm to 10 pm. However, the microfibrils may also be longer, for example between 10-200 pm, even lengths of 2000 pm can be found due to wide length distribution.
- Fibers that have been fibrillated and which have microfibrils on the surface and microfibrils that are separated and located in a water phase of a slurry are included in the definition of MFC.
- cellulose whiskers microcrystalline cellulose (MCC), microcellulose (MC), nanocrystalline cellulose (NCC), nanofibrillated cellulose (NFC) or regenerated cellulose fibers and particles are also included in the definition of MFC.
- the fibrils may also be polymer coated fibrils, i.e. a modified fibril either chemically or physically, being thus either hydrophilic or hydrophobic.
- Microfibrillated cellulose can be produced in a number of different ways. It is possible to mechanically treat cellulosic fibers forming microfibrils. The production of nanocellulose or microfibrillated cellulose with bacteria, or fermentation, is another option. It is also possible to produce microfibrils from cellulose by the aid of different chemicals and/or enzymes which will break the interfibrillar bonds, or even dissolve the fibers and fibrills.
- MFC microfibrillated cellulose
- WO2007091942 describes production of MFC by the aid of refining in combination with addition of an enzyme.
- the definition of plant includes all kind of plants with the traits of being multicellular, possessing cellulose, and having the ability to carry out photosynthesis.
- the definition includes all kind of plants that could be used in horticulture or agriculture.
- Example of plants are cut flowers, trees, bushes, plant cells, grains, crops etc.
- a fungus is a member of a large group of eukaryotic organisms that includes microorganisms such as yeasts and molds, as well as the more familiar mushrooms. These organisms are classified as a kingdom, Fungi, which is separate from plants, animals, and bacteria.
- the present invention relates to an improved method for subjecting plants or fungi to water, eventual nutrients or other additives.
- the plant or fungus is subjected to a suspension that comprises a nanofibrillated polysaccharides in an amount of at least 1 ,5% by weight (of the total weight of the suspension).
- a nanofibrillated polysaccharide such as microfibrillated cellulose
- the needed amount of water can be reduced. Due to that microfibrillated cellulose has high amounts of fixed -OH groups at the surface of the fibrils, the MFC has a great absorption capability of polar solvents, e.g. water.
- MFC can be used as a carrier and/or distributor of liquids, for example to plants. Furthermore, MFC has a very high water binding capacity which reduces the evaporation rate of water and decreased evaporation of water which strongly reduces the amount of water that needs to be added to plants in horticulture and/or agriculture.
- MFC has the property to form solid remaining materials at low solid concentrations. Due to this property, a continuous hydrostatic pressure is formed within the plant or fungus when the plant or fungus absorbs water from the suspension, compared to if the plant or fungus would absorb liquid water. This continuous hydrostatic pressure will ensure an even but yet restricted water flow to the plant or fungus. A restricted water flow from the suspension also closes the pores/epistles of the plant surface since the plant "believes" it is going into a dry season. In this way the plant decreases the water evaporation from its surface and the water consumption decreases without significantly affecting the growing rate of the plant.
- polysaccharide in the suspension is between 1 ,5-30% by weight, preferably between 3-10 % by weight of the total weigh of the suspension.
- Concentrations below 1 ,5% by weight did not seem to give the advantage with the even but yet restricted water flow from the suspension to the plant or fungus, i.e. no continuous hydrostatic pressure was formed. Furthermore, concentrations above 30% by weight seem to be less beneficial since the suspension will be in almost solid state and the water release is very limited.
- suspension may be preferred to pour the suspension onto the plant or fungus. In this way it is possible to subject the plant or fungus to the suspension in a very easy way. However, it may also be possible to add the suspension to the plant or fungus in any possible way.
- the suspension may be in form of a gel. It may be beneficial to subject the plant or fungus to a gel formed suspension since a gel may be easier to distribute to the plant or fungus and the water loss, i.e. water being flown away from the plant or fungus is strongly reduced.
- the suspension is in solid form, preferably in the form of a sheet, composite material, foam or a powder when the plant or fungus is subjected to the suspension.
- the nanofibrillated polysaccharide of the suspension is the nanofibrillated polysaccharide of the suspension.
- the suspension is in solid form when it has a concentration of between 30-100% by weight.
- the suspension will thus comprise no water or liquid. This may be beneficial when the suspension should be transported to the site where the plants or fungi to be treated are located.
- Water can either be added by drop irrigation or other water adding methods. It is also possible that water is added by rainfall. Once water is added, the nanofibrillated polysaccharide of the suspension will absorb the water or liquid and thereafter provide the plant or fungus with the water.
- the amount of water that needs to be added is decided by the dry content or concentration of the suspension. It is however important that the concentration of the suspension is above 1 ,5% by weight in order to get the desired results.
- Additives may be added to the solution and/or to the suspension. Due to the characteristic of the suspension, the additive will mostly be retained in the suspension until the plant or fungus can absorb it. Consequently, smaller amounts of additives are removed from the plant or fungus by for example waste water flows etc.
- the present invention it is thus possible to reduce the amount of needed nutrition agents, e.g. fertilizers, since the fertilizers or other additives will be retained in the suspension until it is absorbed by the plant or fungus. It is also possible to reuse unused additives after harvesting of the plant or fungus, since the additive still are retained in the suspension.
- Possible additives are nutrition agents, such as fertilizers and minerals, pesticides or biocides, or growth hormones. Examples of nutrition agents are fertilizers and minerals, e.g.
- macronutrients such as sodium, phosphorus, potassium, calcium, magnesium and sulfur and micronutrients such as iron, chloride, manganese,
- the plant is a cut flower.
- the lifetime of the cut flowers are strongly improved at the same time as the amount of water needed is reduced.
- the plant is a plant planted in soil, such as a tree, a bush or crops. By subjecting the roots of a plant planted in soil to the suspension the amount of water need by the plant is reduced.
- Tulips of Rainbow brand were used. The stems of the tulips were cut approximately 2 cm from the bottom at a 45° angle.
- Microfibrillated cellulose produced from sulphate pulp was used as a water carrier material in the samples below.
- the microfibrillated cellulose was added to a water solution in order to form a suspension with different concentrations as mentioned below.
- concentration of 3,2% by weight lasted approximately 24 hours longer compared to the tulips in tap water despite that 35% less water was added, i.e. despite less water consumption.
- the tulips in sample 3 lasted and approximately 14 hours longer compared to the tulips subjected to the suspension with a concentration of 1 , 1 % by weight (sample 2).
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Environmental Sciences (AREA)
- Organic Chemistry (AREA)
- Botany (AREA)
- Engineering & Computer Science (AREA)
- Soil Sciences (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mycology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
La présente invention concerne un procédé de traitement d'une plante ou d'un champignon lequel procédé comprend les étapes de : (i) se procurer une solution comprenant de l'eau ; (ii) ajouter un polysaccharide nanofibrillé à la solution ce qui permet de former une suspension dans laquelle la concentration du polysaccharide nanofibrillé dans la suspension est au-dessus de 1,5 % en poids et (iii) soumettre la plante ou le champignon à ladite suspension de façon à fournir à la plante ou au champignon de l'eau.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE1350743-9 | 2013-06-18 | ||
SE1350743A SE1350743A1 (sv) | 2013-06-18 | 2013-06-18 | Förfarande för att behandla en växt med en lösning innefattande en nanofibrillerad polysackarid |
Publications (1)
Publication Number | Publication Date |
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WO2014203121A1 true WO2014203121A1 (fr) | 2014-12-24 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2014/062131 WO2014203121A1 (fr) | 2013-06-18 | 2014-06-11 | Procédé de traitement d'une plante par une solution comprenant un polysaccharide nanofibrillé |
Country Status (2)
Country | Link |
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SE (1) | SE1350743A1 (fr) |
WO (1) | WO2014203121A1 (fr) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015145442A3 (fr) * | 2014-03-27 | 2016-01-14 | Melodea Ltd. | Cellulose nanocristalline utilisée comme matériau absorbant et d'encapsulation |
WO2018158677A1 (fr) * | 2017-03-01 | 2018-09-07 | Stora Enso Oyj | Milieu de culture comprenant de la cellulose microfibrillée |
WO2020059864A1 (fr) * | 2018-09-21 | 2020-03-26 | 丸紅株式会社 | Agent de lutte contre des pathogènes de plantes |
WO2020058183A1 (fr) * | 2018-09-21 | 2020-03-26 | Jassen - Kunststoffzentrum Gmbh - Apparatebau, Zuschnitte Und Formung | Matière support d'engrais, procédé pour produire un engrais et engrais |
WO2020254891A1 (fr) * | 2019-06-17 | 2020-12-24 | Total Grow LLC | Suspension aqueuse concentrée de cellulose microfibrillée comprenant des sels pour la nutrition des plantes |
US11358905B2 (en) * | 2019-01-25 | 2022-06-14 | Amvac Chemical Corporation | Microfibrillated cellulose as rheology modifier in high ionic strength agricultural formulations |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4927772B1 (fr) * | 1970-08-29 | 1974-07-20 | ||
DD159507A3 (de) * | 1980-06-05 | 1983-03-16 | Heinz Leike | Stabilisator fuer ein naehrmedium |
JPS5939789A (ja) * | 1982-08-27 | 1984-03-05 | ダイセル化学工業株式会社 | 肥料造粒方法 |
WO1992012633A1 (fr) * | 1991-01-16 | 1992-08-06 | Fmc Corporation | Vecteur pour agents actifs utilise dans la preparation de formes galenique solide |
US5643591A (en) * | 1991-01-16 | 1997-07-01 | Fmc Corporation | Solid dosage forms |
WO2001066600A1 (fr) * | 2000-03-09 | 2001-09-13 | Hercules Incorporated | Cellulose microfibrillaire stabilisee |
US6602994B1 (en) * | 1999-02-10 | 2003-08-05 | Hercules Incorporated | Derivatized microfibrillar polysaccharide |
US20110003936A1 (en) * | 2009-07-02 | 2011-01-06 | Rhodia Operations | Soil hydrophilization agent and methods for use |
DE202011002784U1 (de) * | 2011-02-16 | 2011-04-21 | Inotec Glienke & Glienke Gbr (Vertretungsberechtigte Gesellschafter: Peter O. Glienke | Hydrogelkomposit-Suspension |
WO2011151523A1 (fr) * | 2010-06-02 | 2011-12-08 | Upm-Kymmene Corporation | Procédé de traitement d'un matériau de type sol |
WO2013078547A1 (fr) * | 2011-12-02 | 2013-06-06 | Masdar Institute Of Science And Technology | Mélanges de cellulose présentant une rétention d'eau améliorée et utilisation de ceux-ci pour l'irrigation |
-
2013
- 2013-06-18 SE SE1350743A patent/SE1350743A1/sv not_active Application Discontinuation
-
2014
- 2014-06-11 WO PCT/IB2014/062131 patent/WO2014203121A1/fr active Application Filing
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4927772B1 (fr) * | 1970-08-29 | 1974-07-20 | ||
DD159507A3 (de) * | 1980-06-05 | 1983-03-16 | Heinz Leike | Stabilisator fuer ein naehrmedium |
JPS5939789A (ja) * | 1982-08-27 | 1984-03-05 | ダイセル化学工業株式会社 | 肥料造粒方法 |
WO1992012633A1 (fr) * | 1991-01-16 | 1992-08-06 | Fmc Corporation | Vecteur pour agents actifs utilise dans la preparation de formes galenique solide |
US5643591A (en) * | 1991-01-16 | 1997-07-01 | Fmc Corporation | Solid dosage forms |
US6602994B1 (en) * | 1999-02-10 | 2003-08-05 | Hercules Incorporated | Derivatized microfibrillar polysaccharide |
WO2001066600A1 (fr) * | 2000-03-09 | 2001-09-13 | Hercules Incorporated | Cellulose microfibrillaire stabilisee |
US20110003936A1 (en) * | 2009-07-02 | 2011-01-06 | Rhodia Operations | Soil hydrophilization agent and methods for use |
WO2011151523A1 (fr) * | 2010-06-02 | 2011-12-08 | Upm-Kymmene Corporation | Procédé de traitement d'un matériau de type sol |
DE202011002784U1 (de) * | 2011-02-16 | 2011-04-21 | Inotec Glienke & Glienke Gbr (Vertretungsberechtigte Gesellschafter: Peter O. Glienke | Hydrogelkomposit-Suspension |
WO2013078547A1 (fr) * | 2011-12-02 | 2013-06-06 | Masdar Institute Of Science And Technology | Mélanges de cellulose présentant une rétention d'eau améliorée et utilisation de ceux-ci pour l'irrigation |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015145442A3 (fr) * | 2014-03-27 | 2016-01-14 | Melodea Ltd. | Cellulose nanocristalline utilisée comme matériau absorbant et d'encapsulation |
WO2018158677A1 (fr) * | 2017-03-01 | 2018-09-07 | Stora Enso Oyj | Milieu de culture comprenant de la cellulose microfibrillée |
CN110381732A (zh) * | 2017-03-01 | 2019-10-25 | 斯道拉恩索公司 | 包含微原纤化纤维素的培养基 |
WO2020059864A1 (fr) * | 2018-09-21 | 2020-03-26 | 丸紅株式会社 | Agent de lutte contre des pathogènes de plantes |
WO2020058183A1 (fr) * | 2018-09-21 | 2020-03-26 | Jassen - Kunststoffzentrum Gmbh - Apparatebau, Zuschnitte Und Formung | Matière support d'engrais, procédé pour produire un engrais et engrais |
JPWO2020059864A1 (ja) * | 2018-09-21 | 2021-01-07 | 丸紅株式会社 | 植物病原菌防除剤 |
US11358905B2 (en) * | 2019-01-25 | 2022-06-14 | Amvac Chemical Corporation | Microfibrillated cellulose as rheology modifier in high ionic strength agricultural formulations |
WO2020254891A1 (fr) * | 2019-06-17 | 2020-12-24 | Total Grow LLC | Suspension aqueuse concentrée de cellulose microfibrillée comprenant des sels pour la nutrition des plantes |
Also Published As
Publication number | Publication date |
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SE1350743A1 (sv) | 2014-12-19 |
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