WO2014202877A1 - External modular device for autonomous regulation of the temperature of an enclosure - Google Patents
External modular device for autonomous regulation of the temperature of an enclosure Download PDFInfo
- Publication number
- WO2014202877A1 WO2014202877A1 PCT/FR2014/051455 FR2014051455W WO2014202877A1 WO 2014202877 A1 WO2014202877 A1 WO 2014202877A1 FR 2014051455 W FR2014051455 W FR 2014051455W WO 2014202877 A1 WO2014202877 A1 WO 2014202877A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- compartment
- communication
- enclosure
- reactor
- evaporator
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24V—COLLECTION, PRODUCTION OR USE OF HEAT NOT OTHERWISE PROVIDED FOR
- F24V30/00—Apparatus or devices using heat produced by exothermal chemical reactions other than combustion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
- F25B17/08—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type the absorbent or adsorbent being a solid, e.g. salt
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D11/00—Self-contained movable devices, e.g. domestic refrigerators
- F25D11/003—Transport containers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D11/00—Self-contained movable devices, e.g. domestic refrigerators
- F25D11/02—Self-contained movable devices, e.g. domestic refrigerators with cooling compartments at different temperatures
- F25D11/027—Self-contained movable devices, e.g. domestic refrigerators with cooling compartments at different temperatures of the sorption cycle type
Definitions
- the present invention relates to an external modular device for autonomously regulating the temperature of an enclosure consisting of an isothermal container, of the type especially intended for the transport of thermosensitive goods.
- thermosensitive products which must be kept between 2 and 8 ° C and which, during its transport, is subjected for a certain period to an external temperature of -10 ° C and then during another period at a temperature of 30 ° C etc.
- the enclosure consists of a container of high volume
- a refrigeration unit whose evaporator is able to provide the enclosure the frigories necessary for its cooling and which is also able to provide the latter with the calories necessary for its heating, and this by passing through the hot compressed fluid in the evaporator.
- Such a device can only be used on speakers of high volume.
- this system must be able to be permanently connected to a source of electrical energy which complicates of course the question of its transport.
- the use of the evaporator as heat generating means is only possible on certain types of refrigeration units.
- such devices can only work in cold production mode or hot production mode, so that the transition from one to the other mode has the risk of creating a thermal shock that could harm the system. integrity of certain heat-sensitive products.
- these devices are usually integrated speakers whose temperature is desired to control and together with them an indissociable set. It is interesting, however, to be able to have a temperature control device that can be arranged on several types of containers, including for example in order to match the power of the control device to the power required by nature transported products and climatic conditions encountered during this transport.
- the object of the present invention is to provide an external device for maintaining the temperature of an enclosure that can be mounted, possibly removably, on an enclosure whose internal temperature must be kept at a given reference value, which is completely independent of the From an energy point of view, it is able to perform its regulation function whatever the profile of the external temperature to which the chamber is subjected, this device being moreover modular and adaptable to the enclosure to be regulated.
- the subject of the present invention is thus a modular device for autonomously regulating the temperature at a determined setpoint, able to be mounted on at least one storage enclosure.
- This device is characterized in that it comprises a casing which contains a thermochemical system comprising a reservoir, possibly forming an evaporator, containing a liquefied gas able, after evaporation, to combine with a reactive product contained in a reactor, following a thermochemical reaction exothermic, the reaction product obtained being able to be regenerated by heating by releasing said gas following a reverse thermochemical reaction, the reactor and the evaporator of the thermochemical system, respectively constituting heating means and cooling means of said enclosure, and being respectively disposed in a reactor compartment and an evaporator compartment, formed in said housing, said device comprising switching means arranged in said housing and capable of:
- the casing comprises mounting means on an enclosure.
- These mounting means are not limited according to the invention. It may be straps attached to the housing and it is possible to wrap around the enclosure, hooks which cooperate with complementary means disposed on the outer surface of the enclosure or any other means of attachment to advantageously fix removably, the housing on the enclosure.
- the device may comprise means capable of placing in communication both the reactor compartment and the evaporator compartment with the storage enclosure.
- the device according to the invention may comprise an inlet duct and an outlet duct which will be able respectively to be connected to an inlet and an outlet of the reactor compartment and to an inlet and an outlet of the evaporator compartment. input and this output duct being respectively able to connect to an output and an input of said storage enclosure.
- the reactor compartment and / or the evaporator compartment will comprise means capable of activating the flow of air flowing through said compartments.
- the reactor compartment may comprise an inlet valve and an outlet valve which will each be able to occupy an open position in which the reactor compartment will be in communication with the outside and a closed position in which it will be isolated from the outside
- the evaporator compartment may comprise an inlet valve and an outlet valve which will each be able to occupy an open position in which the evaporator compartment will be in communication with the outside and a closed position in which it will be isolated from the outside
- the device according to the invention may comprise two reversing valves, namely an inlet valve and an outlet valve which will be able to occupy three positions, namely:
- the device according to the invention may be arranged in the upper part or in the lower part of the storage enclosure. It can also be mounted between two storage enclosures, one of these speakers can be connected to the reactor to be heated and the other can be connected to the evaporator to be cooled.
- the device according to the invention may be arranged in such a way that its reactor compartment can be placed in communication with a first enclosure and, simultaneously, its evaporator compartment can be placed in communication with a second enclosure.
- said reactor compartment is shaped so as to be placed in communication with said first enclosure and simultaneously, said evaporator compartment is shaped so as to be placed in communication with a second enclosure.
- the device comprises at least a first enclosure on which said housing is mounted. The housing can be mounted in the upper part of said first storage enclosure. Such an arrangement facilitates assembly and disassembly of the device according to the invention on the enclosure; it is possible to mount or dismount the device without moving the enclosure.
- the device comprises a second storage chamber, said reactor compartment is placed in communication with said first chamber and, simultaneously, said evaporator compartment is placed in communication with said second enclosure.
- FIG. 1 is a graph showing an exemplary temperature profile at which a container equipped with a device according to the invention can be subjected during a transport operation
- FIG. 2 is a schematic view of a container equipped with a device according to the invention in a cold production mode
- FIG. 3 is a schematic view of the container and the device according to the invention shown in FIG. 2 in a hot production mode
- FIG. 4 is a schematic view of the container and the device according to the invention shown in FIGS. 2 and 3 in a production mode of both hot and cold,
- FIGS. 5a to 5c are schematic views showing various mounting modes of the device according to the invention on a container.
- the device according to the invention is designed to make it possible to maintain an enclosure containing temperature-sensitive products at a set temperature T c determined during a given period, whatever the climatic conditions to which the latter is subjected when, for example, a transport.
- FIG. 2 to 5 there is shown in Figures 2 to 5 an example of a container forming an enclosure 1 which is intended to contain temperature-sensitive products 3 and which receives in its upper part a device 2 for autonomous regulation of the temperature according to the invention.
- the latter comprises a housing 22 (shown in broken lines in FIGS. 2 to 4) which contains a thermochemical system of known type which can be used with various salts and gases and which essentially consists of a reactor 9 containing a reactive product, consisting in this case of manganese chloride, which is mixed and compacted with an expanding binder including expanded natural graphite, the bulk density thereof being preferably between 50 kg / m 3 and 150 kg / m 3 and the mass proportion of chloride of manganese relative to the expanded natural graphite being preferably between 50% and 90%.
- a reactor 9 containing a reactive product, consisting in this case of manganese chloride, which is mixed and compacted with an expanding binder including expanded natural graphite, the bulk density thereof being preferably between 50 kg / m 3 and 150 kg / m 3 and the mass proportion of chloride of manganese relative to the expanded natural graphite being preferably between 50% and 90%.
- “Bulk density of expanded natural graphite” means the density calculated according to the following formula on the final compacted product: (mass of natural graphite mixed with a given mass of the reactive product to obtain the compacted product) / volume of the element obtained by compacting the mixture of the above-mentioned natural graphite mass with the given mass of aforementioned reagent.
- the reactor 9 is in communication, under the control of a control valve 1 1, with a tank 13 in which is stored a specific gas, consisting of ammonia, this tank acting as an evaporator.
- the reactive product and the gas are such that the reactive product is capable, by an exothermic thermochemical reaction, during a so-called operating phase, of absorbing the gas, thus generating a reaction product, and then returning it, by a inverse thermochemical reaction, during a so-called regeneration phase, when the reaction product is heated.
- the liquid gas contained in the latter vaporizes, which absorbs a certain amount of heat, so that it is the source of a production of cold, and this gas is absorbed by the reactive material, thereby generating an exothermic chemical reaction, so that the reactor is the source of heat generation.
- the reaction product contained in the reactor 9 is heated, the absorbed gas is released by the reactive material and the latter then condenses in the evaporator 13.
- the reactor 9 and the evaporator 13 are respectively disposed in separate compartments 10 and 14 whose respective inlets 10a and 14a can be placed in communication with an inlet duct 5 in communication with an output 5a of the enclosure 1, and the outputs 10b and 14b can be placed in communication with an outlet conduit 7 also in communication with an input 7a of the enclosure 1 and this under the control of a system six distribution valves which are slaved to each other under the control of a microcontroller, not shown in the drawing and as explained below.
- one end of the inlet duct 5 is capable of being connected to the aforementioned inlets 10a and 14a, the second end of the inlet duct 5 is connected with the outlet 5a formed in enclosure 1.
- one end of the outlet duct 7 is capable of being connected to the above-mentioned outlets 10b and 14b while the other end of the outlet duct 7 is connected to an outlet 7a formed in the enclosure 1.
- the reactor compartment 10 comprises ventilation means 12 which ensure the circulation of air from its inlet 10a to its outlet 10b and propels this air, via the outlet duct 7, into the enclosure 1.
- the evaporator compartment 14 comprises ventilation means 16 which ensure the circulation of air from its inlet 14a to its outlet 14b and propels this air, via the outlet duct 7, into the chamber 1.
- the reactor compartment 9 comprises an inlet valve 17a and an outlet valve 17b which are each able to occupy an open position in which the reactor compartment 10 is in communication with the outside (FIG. 2) and a closed position in which it is isolated from the outside ( Figure 3).
- the evaporator compartment 14 comprises an inlet valve
- the system also comprises two reversing valves, namely a valve 21a input and a valve 21b output that are able to occupy three positions, namely:
- FIG. 2 a first position, represented in FIG. 2, in which they respectively put the inlet and the outlet of the evaporator 13 in communication with the enclosure 1,
- FIG. 3 a second position, shown in FIG. 3, in which they respectively put the inlet and the outlet of the reactor 9 in communication with the enclosure 1
- FIG. 4 a third position, shown in Figure 4, wherein the valves are in the middle position and respectively the inlet and the outlet of the reactor 9 and the evaporator 13 in communication with the chamber 1.
- the container equipped with the temperature control device according to the invention is first transported from its warehouse where the temperature is 15 ° C (period 1) to be loaded in the hold of an aircraft in which the temperature drops rapidly and remains at about -20 ° C for 10 hours (period 2).
- the container On arrival the container is placed on standby outside for four hours at a temperature of 40 ° C (period 3), then transferred to a shed of a cargo area where it remains at 25 ° C for 5 hours (period 4). It is then loaded in the hold of another aircraft where its temperature drops to -20 ° C for five hours (period 5) and is then transported to an outside temperature of -30 (period 6) to its place of reception.
- valves 21a and 21b clear the inlet 10a and the outlet 10b of the compartment 10 containing the reactor 9 and on the other hand the valves 17a and 17b are in the closed position vis-à-vis the outside, so as to put the compartment 10 containing the reactor 9 in communication with the enclosure 1 in order to heat the latter and, at the same time, the valves 19a and 19b are open in order to put the evaporator 13 in communication with the outside in order to evacuate to the atmosphere the cold generated by the latter.
- the valves are positioned, as shown in FIG. , in a position where it sends simultaneously in the chamber 1 of the hot air and cold air.
- the inverting valves 21a and 21b are placed in the median position and the inlet valves 17a and 19a and the outlet valves 17b and 19b provide communication with the enclosure of the inlet and the outlet at the inlet. reactor and evaporator.
- the regulation device according to the invention can be fixed at the top of the enclosure 1. However, as shown in FIG. 5b, it can also be fixed in the lower part thereof.
- the housing 22 is either mounted on the enclosure 1 or under the latter.
- the regulating device can also be arranged between two enclosures 1 and 1 ', which has the advantage of being able to simultaneously send hot air into the chamber.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Sorption Type Refrigeration Machines (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2911469A CA2911469A1 (en) | 2013-06-18 | 2014-06-13 | External modular device for autonomous regulation of the temperature of an enclosure |
EP14734893.2A EP3011238A1 (en) | 2013-06-18 | 2014-06-13 | External modular device for autonomous regulation of the temperature of an enclosure |
JP2016520573A JP2017503136A (en) | 2013-06-18 | 2014-06-13 | External module device that automatically adjusts the temperature of the enclosure |
US14/898,192 US20160131409A1 (en) | 2013-06-18 | 2014-06-13 | External modular device for autonomous regulation of the temperature of an enclosure |
CN201480034020.9A CN105308399A (en) | 2013-06-18 | 2014-06-13 | External modular device for autonomous regulation of the temperature of an enclosure |
BR112015032006A BR112015032006A2 (en) | 2013-06-18 | 2014-06-13 | external modular device for autonomous temperature regulation of a room |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1301412 | 2013-06-18 | ||
FR1301412A FR3007114B1 (en) | 2013-06-18 | 2013-06-18 | EXTERNAL MODULAR DEVICE FOR AUTONOMOUS REGULATION OF TEMPERATURE OF AN ENCLOSURE |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014202877A1 true WO2014202877A1 (en) | 2014-12-24 |
Family
ID=48901058
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2014/051455 WO2014202877A1 (en) | 2013-06-18 | 2014-06-13 | External modular device for autonomous regulation of the temperature of an enclosure |
Country Status (8)
Country | Link |
---|---|
US (1) | US20160131409A1 (en) |
EP (1) | EP3011238A1 (en) |
JP (1) | JP2017503136A (en) |
CN (1) | CN105308399A (en) |
BR (1) | BR112015032006A2 (en) |
CA (1) | CA2911469A1 (en) |
FR (1) | FR3007114B1 (en) |
WO (1) | WO2014202877A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113654289A (en) * | 2021-08-27 | 2021-11-16 | 重庆中元汇吉生物技术有限公司 | Reagent refrigeration device and refrigeration method |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016065048A1 (en) * | 2014-10-21 | 2016-04-28 | University Of Utah Research Foundation | A climate control system and associated methods |
ITUA20163308A1 (en) | 2016-05-10 | 2017-11-10 | Bonetto S R L | ISOTHERMAL CONTAINER FOR THE TRANSPORT OF PERISHABLE FOODS |
US10619907B2 (en) * | 2017-05-31 | 2020-04-14 | Keith A. Kenneally | Refrigerated, thermally insulated, collapsible cover system, assembly and method of using to transport perishable products |
FR3115473B1 (en) * | 2020-10-22 | 2023-11-17 | Coldway Tech | Reagent for thermal machine |
FR3131548A1 (en) * | 2022-01-04 | 2023-07-07 | Sofrigam | Reagent for thermal machine using sorbent salt. |
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DE614644C (en) * | 1932-12-14 | 1935-06-14 | Siemens Schuckertwerke Akt Ges | Mechanically operated refrigerator |
DE688139C (en) * | 1932-11-16 | 1940-02-13 | Wulff Berzelius Normelli | Refrigerator equipped with periodic absorption chiller |
US2817958A (en) * | 1955-08-02 | 1957-12-31 | Wesix Electric Heater Co | Absorption system for heating or cooling a space |
US4199959A (en) * | 1977-03-24 | 1980-04-29 | Institute Of Gas Technology | Solid adsorption air conditioning apparatus and method |
JPS57178913A (en) * | 1981-04-27 | 1982-11-04 | Diesel Kiki Co Ltd | Car air-conditioner |
JPH0237019A (en) * | 1988-07-28 | 1990-02-07 | Matsushita Electric Ind Co Ltd | Regenerative air conditioner for vehicle |
DE19640397A1 (en) * | 1995-10-05 | 1997-04-10 | Nippon Denso Co | Air conditioning system based on reversible adsorption of coolant by solid and particularly suitable for vehicles |
FR2766262A1 (en) * | 1997-07-16 | 1999-01-22 | Soc D Const De Materiel Metall | CONTAINER IN WHICH CAN BE RELEASED AT A SELECTED MOMENT OF FRIGORIES OR CALORIES |
KR20040000768A (en) * | 2002-06-25 | 2004-01-07 | 엘지전자 주식회사 | Cooling and Heating Device Using Hydrogen Storage Alloys |
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JPH0166576U (en) * | 1987-10-22 | 1989-04-27 | ||
US5063747A (en) * | 1990-06-28 | 1991-11-12 | United States Of America As Represented By The United States National Aeronautics And Space Administration | Multicomponent gas sorption Joule-Thomson refrigeration |
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-
2013
- 2013-06-18 FR FR1301412A patent/FR3007114B1/en active Active
-
2014
- 2014-06-13 EP EP14734893.2A patent/EP3011238A1/en not_active Withdrawn
- 2014-06-13 WO PCT/FR2014/051455 patent/WO2014202877A1/en active Application Filing
- 2014-06-13 CA CA2911469A patent/CA2911469A1/en not_active Abandoned
- 2014-06-13 JP JP2016520573A patent/JP2017503136A/en active Pending
- 2014-06-13 BR BR112015032006A patent/BR112015032006A2/en not_active IP Right Cessation
- 2014-06-13 CN CN201480034020.9A patent/CN105308399A/en active Pending
- 2014-06-13 US US14/898,192 patent/US20160131409A1/en not_active Abandoned
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DE688139C (en) * | 1932-11-16 | 1940-02-13 | Wulff Berzelius Normelli | Refrigerator equipped with periodic absorption chiller |
DE614644C (en) * | 1932-12-14 | 1935-06-14 | Siemens Schuckertwerke Akt Ges | Mechanically operated refrigerator |
US2817958A (en) * | 1955-08-02 | 1957-12-31 | Wesix Electric Heater Co | Absorption system for heating or cooling a space |
US4199959A (en) * | 1977-03-24 | 1980-04-29 | Institute Of Gas Technology | Solid adsorption air conditioning apparatus and method |
JPS57178913A (en) * | 1981-04-27 | 1982-11-04 | Diesel Kiki Co Ltd | Car air-conditioner |
JPH0237019A (en) * | 1988-07-28 | 1990-02-07 | Matsushita Electric Ind Co Ltd | Regenerative air conditioner for vehicle |
DE19640397A1 (en) * | 1995-10-05 | 1997-04-10 | Nippon Denso Co | Air conditioning system based on reversible adsorption of coolant by solid and particularly suitable for vehicles |
FR2766262A1 (en) * | 1997-07-16 | 1999-01-22 | Soc D Const De Materiel Metall | CONTAINER IN WHICH CAN BE RELEASED AT A SELECTED MOMENT OF FRIGORIES OR CALORIES |
KR20040000768A (en) * | 2002-06-25 | 2004-01-07 | 엘지전자 주식회사 | Cooling and Heating Device Using Hydrogen Storage Alloys |
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CN113654289A (en) * | 2021-08-27 | 2021-11-16 | 重庆中元汇吉生物技术有限公司 | Reagent refrigeration device and refrigeration method |
Also Published As
Publication number | Publication date |
---|---|
BR112015032006A2 (en) | 2017-07-25 |
JP2017503136A (en) | 2017-01-26 |
US20160131409A1 (en) | 2016-05-12 |
CN105308399A (en) | 2016-02-03 |
EP3011238A1 (en) | 2016-04-27 |
FR3007114B1 (en) | 2015-07-17 |
FR3007114A1 (en) | 2014-12-19 |
CA2911469A1 (en) | 2014-12-24 |
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