Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
  • C09D5/22—Luminous paints
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
  • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
  • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
  • C09K11/57—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing manganese or rhenium
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
  • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
  • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
  • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
  • C09K11/7728—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing europium
  • C09K11/77342—Silicates
• • H—ELECTRICITY
  • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
  • H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
  • H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
  • H10H20/80—Constructional details
  • H10H20/85—Packages
  • H10H20/851—Wavelength conversion means
  • H10H20/8511—Wavelength conversion means characterised by their material, e.g. binder
  • H10H20/8512—Wavelength conversion materials

Definitions

• the present invention relates to Siiicatleuchtscher, a process for their preparation and their use as conversion phosphors.
• the present invention also relates to an emission-converting material containing the conversion phosphor according to the invention and its use in light sources, in particular pc-LEDs (phosphor converted light emitting devices).
• Further objects of the present invention are light sources, in particular pc LEDs, and illumination units which contain a primary light source and the emission-converting material according to the invention.
• inorganic phosphors have been developed to spectrally adapt emissive screens, X-ray amplifiers and radiation or light sources so that they optimally meet the requirements of the respective field of application while using as little energy as possible.
• the type of excitation, d. H. the nature of the primary source of radiation and the required emission spectrum are crucial for the selection of host lattices and the
• RGB LEDs red + green + blue LEDs in which white light is generated by mixing the light of three different LEDs emitting in the red, green and blue spectral regions.
• Primary light source emits, for example, blue light which excites one or more phosphors (conversion phosphors), which in the yellow area emit light. By mixing the blue and the yellow light, white light is created. Alternatively, two or more phosphors emitting, for example, green or yellow and orange or red light may be used.
• UV LED + RGB phosphor in which a semiconductor emitting in the UV region (primary light source) emits light to the environment in which three different conversion phosphors are excited to emit in the red, green and blue spectral regions.
• a semiconductor emitting in the UV region primary light source
• three different conversion phosphors are excited to emit in the red, green and blue spectral regions.
• two different phosphors can be used which emit yellow or orange and blue.
• Binary complementary systems have the advantage of being able to produce white light with only one primary light source and, in the simplest case, only one conversion phosphor.
• the best known of these systems consists of an indium-aluminum-gallium-nitride chip as a primary light source emitting light in the blue spectral range, and a cerium-doped yttrium-aluminum garnet (YAG: Ce) as a conversion phosphor, which is excited in the blue region and emit light in the yellow spectral range.
• Indium-Gallium-Nitride LEDs have a long lifetime, low depth and high internal and external quantum efficiency.
• the main advantage of using a blue primary radiation source is the low Stokes loss on conversion to white light.
• a blue primary radiation source such as indium gallium nitride LEDs or In 3+ gas discharges
• the use of blue-emitting indium-gallium-nitride LEDs also leads to a number of difficulties, such as the strong dependency of the color point on the thickness of the phosphor layer, the strong spectral interaction between the luminophores due to the low Stokes shift and a limited choice Luminophores, since many activators or phosphors do not absorb sufficiently strong in the blue spectral range.
• near-UV LEDs as the basis for white-emitting LEDs are the focus of a number of developments in LED light sources, and the research and development of novel conversion LEDs for UV LEDs has been intensified in recent years.
• inorganic fluorescent powders which can be excited in the near UV region of the spectrum are becoming more and more important today
• silicate phosphors described below achieve this object. These phosphors can be excited in the near UV range and show emission in both the blue and the red spectral range.
• EA 1 is Ba or a mixture of Ba and Sr containing up to 20 atom% of Sr;
• EA 2 is selected from the group consisting of Ca or Sr or mixtures of these elements, with up to 20 atomic% of these elements being replaced by Mg;
• the compounds according to the invention are excitable in the near UV spectral region, preferably at about 370-420 nm, and usually exhibit emission maxima in the blue as well as in the orange or red spectral range, so that the resulting emission color can be termed magenta.
• blue light is defined as light whose emission maximum lies between 400 and 459 nm, cyan light whose emission maximum is between 460 and 505 nm, green light whose emission maximum lies between 506 and 545 nm , as yellow light such, whose emission maximum lies between 546 and 565 nm, as orange light such, whose
• Emission maximum between 566 and 600 nm and is such as red light whose emission maximum is between 601 and 670 nm.
• EA 1 is selected from Ba or a mixture of Ba and Sr containing not more than 10 atom% of Sr.
• EA 1 is particularly preferably Ba.
• EA 2 is selected from Ca or Sr or a mixture of Ca and Sr or a mixture of Ca and Mg which contains at most 20 atomic% Mg or a mixture of Sr and Mg which is at most 20 atomic - contains% Mg.
• a preferred embodiment of the compounds according to formula (1) are therefore the compounds of the following formulas (2) to (4), : Eu x , Mn y (2) (Bai -z Sr 2 ) 1-x (Cai -v Mg v ) 2-y Si 3 O 9 : Eu X) Mn y (3)
• Particularly preferred embodiments of the compounds of the formula (2), (3) and (4) are the compounds of the following formulas (2a) to (2c), (3a) and (4a)
• Bai -x Ca 2- ySi 3 0 9 Eu x , Mn y (2a)
• Bai -x Sr 2- ySi 3 0 9 Eu x , Mn y (2b)
• the index y in the compounds of the formulas (1) to (4) and the above-mentioned preferred embodiments is 0.05 ⁇ y ⁇ 0.15.
• Another object of the present invention is a process for preparing a compound according to formula (1) or the preferred embodiments, comprising the steps:
• the ions EA 1 and EA 2 are preferably used in the form of the corresponding carbonates, oxides or oxalates. Carbonates are preferably used.
• Eu is preferably used in the form of the oxide Eu 2 O 3 .
• Mn is further preferably in the form of the oxalate, in particular as hydrate MnC2O "2H 2 O.
• Mn 3 can be inserted in the form of the carbonate MnCO.
• Si is used in the form of the oxide SiO 2 .
• This is amorphous SiO 2 , with preference being given to microparticles or, more preferably, to nanoparticles.
• the mixture in step a) is preferably prepared in a mortar, preferably in a solvent.
• the solvent used is preferably acetone or an alcohol, in particular ethanol, propanol or isopropanol.
• the mixture in step a) is preferably produced in an automatic mortar mill.
• the mixture Before calcining, the mixture is dried. This is preferably carried out in air first at room temperature and then in a drying oven at elevated temperature, preferably at 60-120 ° C, in particular at about 80 ° C.
• Suitable fluxes are, for example, boric acid H 3 BO 3 , ammonium fluoride NH 4 F, barium fluoride BaF 2 or calcium fluoride CaF 2 . Boric acid is preferred. Remains of the flux can also remain in the product.
• the calcination of the mixture in step b) of the process according to the invention is preferably carried out under reducing or at least under non-oxidizing conditions.
• Preferred here is a reaction time of 5 to 24 hours, more preferably from 8 to 16 hours, and a
• Temperature in the range of 1100 to 1300 ° C, more preferably from 120.0 to 1250 ° C.
• the non-oxidizing or reducing conditions are z. B. with inert gases or carbon monoxide, forming gas or hydrogen or vacuum or oxygen deficient atmosphere. Preference is given to a forming gas atmosphere, in particular with a content of 5 to 10% by volume H 2 in N 2 .
• the calcining can be carried out, for example, so that the resulting mixtures are introduced in a vessel made of boron nitride or corundum in a high-temperature furnace.
• the high temperature furnace is in a preferred embodiment a tube furnace. It is preferred if the compounds according to the invention are comminuted after the calcining step, for example by mortars.
• the average particle size d 50 of the volume distribution of the phosphors according to the invention is usually between 50 nm and 30 ⁇ m for use in LEDs, preferably between 1 ⁇ m and 20 ⁇ m.
• the particle size is preferably determined by Coulter counter measurement.
• the compounds of the invention may be coated. Suitable for this purpose are all coating methods, as known to the person skilled in the art according to the prior art and used for phosphors. Suitable materials for the coating are, in particular, metal oxides and nitrides, in particular earth metal oxides, such as Al 2 O 3 , and earth metal nitrides, such as AlN, and SiO 2 .
• the coating can be carried out, for example, by fluidized bed processes or wet-chemical. Suitable coating methods are known, for example, from JP 04-304290, WO 91/10715, WO 99/27033, US 2007/0298250, WO 2009/065480 and WO 2010/075908.
• the aim of the coating can be a higher stability of the phosphors, for example against air or moisture.
• the goal can also be an improved coupling and decoupling of light by a suitable choice of the surface of the coating and the
• the compounds may also be coated with organic materials, for example with
• Siloxanes This may have advantages in terms of dispersibility in a resin in the manufacture of the LEDs.
• Yet another object of the present invention is the use of the compound of the invention as a phosphor or conversion luminescent material, in particular for the partial or complete conversion of the near UV emission of a light emitting diode in light with a longer wavelength.
• the compounds according to the invention are also referred to as phosphors.
• Another object of the present invention is therefore a
• Emission converting material comprising a compound of the invention.
• the emission-converting material may consist of the compound according to the invention and in this case would be equivalent to the term "conversion luminescent substance" as defined above It may also be preferred that the emission-converting material according to the invention contains, in addition to the compound according to the invention, further conversion luminescent substances In this case, the emission-converting material according to the invention preferably contains a mixture of at least two conversion phosphors, at least one of which is a compound of the invention It is particularly preferred that the at least two conversion phosphors are phosphors which emit light of wavelengths that are complementary to one another.
• the compounds according to the invention give good LED qualities.
• the LED quality is described using common parameters, such as the Color Rendering Index (CRI), the Correlated Color Temperature (CCT), lumen equivalents or absolute lumens or the color point in CIE x and y coordinates.
• CRI Color Rendering Index
• CCT Correlated Color Temperature
• lumen equivalents or absolute lumens or the color point in CIE x and y coordinates.
• the Color Rendering Index is a familiar, non-standard photometric size, which the color fidelity of an artificial light source with that of sunlight or and
• Filament light sources compare (the latter two have a CRI of 100).
• Correlated Color Temperature is a photometric quantity with unit Kelvin which is familiar to the person skilled in the art. The higher the numerical value, the higher the blue component of the light and the colder the white light of an artificial radiation source appears to the viewer.
• the CCT follows the concept of the black light emitter, whose color temperature describes the so-called Planckian curve in the CIE diagram.
• the lumen equivalent is a photometric quantity known to the person skilled in the art with the unit Im W, which describes how large the photometric luminous flux in lumens of a light source is at a certain radiometric radiation power with the unit Watt. The higher the lumen equivalent, the more efficient a light source is.
• the lumen is a photometrical photometric quantity which is familiar to the person skilled in the art and describes the luminous flux of a light source, which is a measure of the total visible radiation emitted by a radiation source. The larger the luminous flux, the brighter the light source appears to the observer.
• CIE x and CIE y represent the coordinates in the familiar CIE standard color diagram (in this case normal observer 1931), which describes the color of a light source.
• the excitability of the phosphors according to the invention extends over a wide range, which ranges from about 250 nm to 420 nm, preferably 350 nm up to about 420 nm. Usually, the maximum is the
• Excitation curve of the phosphors according to the invention at about 350 nm.
• Another object of the present invention is a light source containing at least one primary light source and at least one compound of the invention.
• the maximum emission of the primary light source is usually in the range 350 nm to 420 nm, preferably 370 nm up to about 420 nm, wherein the primary radiation is partially or completely converted by the phosphor according to the invention in longer wavelength radiation.
• the person skilled in possible forms of such light sources are known. These may be light-emitting LED chips of different construction.
• the primary light source is a luminescent one based on ZnO, TCO (transparent conducting oxide) or SiC
• the primary light source is a source which exhibits electroluminescence and / or photoluminescence.
• the primary light source can also be a plasma or discharge source.
• Corresponding light sources according to the invention are also referred to as light-emitting diodes or LEDs.
• the phosphors according to the invention can be used individually or as a mixture with the following phosphors familiar to the person skilled in the art. Since the phosphors according to the invention exhibit emission in the blue and red spectral range, it is particularly preferred if they are present in
• Ba 2 SiO 4 Eu 2+ , BaSi 2 O 5 : Pb 2+ , Ba x Sr 1 -x F 2 : Eu 2+ , BaSrMgSi 2 O 7 : Eu 2+ , BaTiP 2 O 7 , (Ba, Ti) 2 P 2 O 7 : Ti, Ba 3 WO 6 : U, BaY 2 F 8 : Er 3+ , Yb ⁇ Be 2 SiO 4 : Mn 2 ⁇ Bi 4 Ge 3 Oi 2 , CaAl 2 O 4 : Ce 3+ , CaLa 4 O 7 : Ce 3+ , CaAl 2 O 4 : Eu 2+ , CaAl 2 O: Mn + ,
• CaAl 4 O 7 Pb 2+ , Mn 2+ , CaAl 2 O 4 : Tb 3+ , Ca 3 Al 2 Si 3 O 12 : Ce 3+ ,
• Ca 2 B 5 O 9 Cl Eu 2+
• Ca 2 B 5 O 9 Cl Pb 2+
• CaB 2 O 4 Mn 2+
• Ca 2 B 2 O 5 Mn 2+
• CaB 2 O 4 Pb 2+
• CaB 2 P 2 O 9 Eu 2+
• Ca 5B 2 SiO 10 Eu 3+
• Cao.5Bao.5Ali2Oi 9 Ce 3+ , Mn 2+ , Ca 2 Ba 3 (PO 4 ) 3 Cl: Eu 2+ , CaCl 2 : Eu 2+ , Mn 2+ in SiO 2 , CaF 2 : Ce 3+ , CaF 2 : Ce 3+ , Mn 2+ , CaF 2 : Ce 3+ , Tb 3+ , CaF 2 : Eu 2+ ,
• CaF 2 Mn 2+
• CaGa 2 O Mn 2+
• CaGa 4 O 7 Mn 2+
• CaGa 2 S 4 Ce 3+
• CaGa 2 S 4 Eu 2+
• CaGa 2 S 4 Mn 2+
• CaGa 2 S 4 Pb 2+
• CaGeO 3 Mn 2+
• Ca 5 (PO 4) 3 Cl Eu +, Ca 5 (P0 4) 3 Cl: Mn +, Ca 5 (PO 4) 3 Cl: Sb 3+, Ca 5 (PO 4) 3 Cl: Sn 2+, ⁇ -Ca 3 (PO 4 ) 2 : Eu 2+ , Mn 2+ , Ca 5 (PO 4 ) 3 F: Mn 2+ , Ca s (PO 4 ) 3 F: Sb 3+ ,
• CaSiO 3 Pb 2+ , CaSiO 3 : Pb 2+ , Mn 2+ , CaSiO 3 : Ti 4+ , CaSr 2 (P0 4 ) 2 : Bi 3+ ,
• CdS In, Te, CdS: Te, CdWO 4 , CsF, CsI, CsI: Na + , CsI: TI,
• GdNb0 4 Bi 3+, GD20 2 S: Eu 3+, Gd 2 0 2 Pr 3+, Gd 2 0 2 S: Pr, Ce, F, Gd 2 0 2 S: Tb 3+, Gd 2 Si0 5: Ce 3 ⁇ KGa Oi 7 : Mn 2+ , K 2 La 2 Ti 3 O 10 : Eu, KMgF 3 : Eu 2+ , KMgF 3 : Mn 2+ , K 2 SiF 6 : Mn 4+ , LaAl 3 B 4 0i 2 : Eu 3+ , LaAIB 2 0 6 : Eu 3+ , LaAIO 3 : Eu 3+ , LaAlO 3 : Sm 3+ , LaAsO 4 : Eu 3+ , LaBr 3 : Ce 3+ , LaB0 3 : Eu 3+ , (La, Ce, Tb) PO 4 : Ce: Tb, LaCl 3 : Ce 3+ , La 2 O 3
• LaSi0 3 Cl Ce 3+
• LaSi0 3 Cl Ce 3+
• Tb 3+ LaV0 4 : Eu 3+
• La 2 W 3 Oi 2 Eu 3+
• LiAIF 4 Mn 2+ , LiA! 5 O 8 : Fe 3+ , LiAlO 2 : Fe 3+ , LiAlO 2 : Mn 2+ , LiAl 5 O 8 : Mn 2+ ,
• MgAl 2 O 4 Mn 2+ , MgSrAl 10 Oi 7 : Ce, MgB 2 O 4 : Mn 2+ , MgBa 2 (PO 4 ) 2 : Sn 2+ , gBaP 2 0 7 : Eu 2+ , MgBaP 2 0 7 Eu 2+ , n 2+ , gBa 3 Si 2 O 8 : Eu 2+ ,
• MgBa (SO 4 ) 2 Eu 2+
• Mg 3 Ca 3 (PO 4 ) 4 Eu 2+
• MgCaP 2 O 7 Mn 2+
• Mg 3 SiO 3 F 4 Ti 4+ , MgS0 4 : Eu 2+ , MgSO 4 : Pb 2+ , MgSrBa 2 Si 2 O 7 : Eu 2+ ,
• MgSrP 2 O 7 Eu 2+
• MgSr 5 (PO 4 ) 4 Sn 2+
• MgSr 3 Si 2 O 8 Eu 2+ , Mn 2+ ,
• SrB 4 0 7 Eu 2+ (F, CI, Br), SrB 4 0 7 : Pb 2+ , SrB 4 0 7 : Pb 2+ , Mn 2+ , SrB 8 O 13 : Sm 2+ , Sr x Ba y Cl z AI 2 0 4-z / 2: Mn 2+, Ce 3+, SrBaSi0 4: Eu 2+, Sr (CI, Br, l) 2: Eu 2+ in SiO 2, SRCI 2: Eu 2+ in Si0 2 , Sr 5 Cl (PO 4 ) 3 : Eu, Sr w F x B 4 O 6 .
• Sr 5 (PO 4 ) 3 Cl Sb 3+ , Sr 2 P 2 O 7 : Eu 2+ , ⁇ -Sr 3 (PO 4 ) 2 : Eu 2+ , Sr 5 (PO 4 ) 3 F: Mn 2+ , Sr 5 (PO 4 ) 3 F: Sb 3+ , Sr 5 (PO 4 ) 3 F: Sb 3+ , Mn 2+ , Sr 5 (PO 4 ) 3 F: Sn 2+ , Sr 2 P 2 O 7 : Sn 2+ , ⁇ -Sr 3 (PO 4 ) 2 : Sn 2+ , ⁇ -Sr 3 (PO 4 ) 2 : Sn 2+ , Mn 2+ (Al), SrS: Ce 3+ , SrS: Eu + , SrS: Mn SrS: Cu + , Na, SrS0 4 : Bi, SrS0 4 : Ce 3+ , SrS0 4 : Eu + , SrS
• YAl 3 B 4 O 12 Eu 3+ , Cr 3+ , YAl 3 B 4 O 12 : Th 4+ , Ce 3+ , Mn + , YAlO 3 : Ce 3+ , Y 3 Al 5 O 12-Ce Y 3 Al 5 O 2 : Cr 3+, YAI0 3: Eu 3+, Y 3 Al 5 O 12: Eu 3r, Y4AI 2 0 9: Eu 3+, Y3AI 5 O 12: Mn 4+, YAI0 3: Sm 3+, YAI0 3: Tb 3+ , Y 3 Al 5 O 2 : Tb 3+ , YAsO 4 : Eu 3+ , YBO 3 : Ce 3+ , YBO 3 : Eu 3+ , YF 3 : Er 3+ , Yb 3+ , YF 3 : Mn 2+ , Th 4+ , YF 3 : Tm 3
• Y 2 0 3 Ce 3+, Tb 3+, YOCI: Ce 3+, YOCI: Eu 3+, YOF: Eu 3+, YOF: Tb 3+, Y 2 0 3: Ho 3+, Y 2 O 2 S: Eu 3+ , Y 2 O 2 S: Pr 3+ , Y 2 O 2 S: Tb 3+ , Y 2 O 3 : Tb 3+ , YPO 4 : Ce 3 ⁇
• YPO 4 Ce 3+ , Tb 3+ , YPO 4 : Eu 3+ , YPO 4 : Mn 2+ , Th 4+ , YPO 4 : V 5+ , Y (P, V) O 4 : Eu, Y 2 SiO 5 : Ce 3+ , YTaO 4) YTaO 4 : Nb 5+ , YVO 4 : Dy 3+ , YVO 4 : Eu 3+ , ZnAl 2 O 4 : Mn 2+ , ZnB 2 O 4 : Mn 2+ , ZnBa 2 S 3: Mn 2+, (Zn, Be) 2 Si0 4: Mn 2+, Zn 0.4 Cdo .6 S: Ag,
• Zn 0 .6Cdo .4 S Ag, (Zn, Cd) S: Ag, Cl, (Zn, Cd) S: Cu, ZnF 2 : Mn 2+ , ZnGa 2 O 4l ZnGa 2 O 4 : Mn 2+ , ZnGa 2 S 4 : Mn 2+ , Zn 2 Ge0 4 : Mn 2+ , (Zn, Mg) F 2 : n 2+ ,
• ZnMg 2 (P0 4 ) 2 Mn 2 ⁇ (Zn, Mg) 3 (PO 4 ) 2 : Mn 2+ , ZnO: Al 3+ , Ga 3 ⁇ ZnO: Bi 3+ ,
• Zn 2 SiO 4 Mn 2 ⁇ Zn 2 Si0 4 : Mn 2+ , As 5+ , Zn 2 Si0 4 : Mn, Sb 2 O 2 , Zn 2 SiO: Mn 2+ , P, Zn 2 Si0 4 : Ti 4 + , ZnS: Sn 2 ⁇ ZnS: Sn, Ag, ZnS: Sn 2+ , Li + , ZnS: Te, n, ZnS-ZnTe: Mn + , ZnSe: Cu + , Cl and ZnWO 4 .
• yellow and green emitting phosphors which can be combined with the compounds according to the invention are, for example, selected from the group consisting of
• the phosphors or phosphor combinations according to the invention can either be dispersed in a resin (for example epoxy or silicone resin) or, with suitable size ratios, be arranged directly on the primary light source or remotely located therefrom, depending on the application (the latter arrangement also includes the "remote phosphor technology” with).
• a resin for example epoxy or silicone resin
• the advantages of the "remote phosphor technology” are known in the art and z. For example, see the following publication: Japanese J. of Appl. Phys. Vol. 44, no. 21 (2005). L649-L651.
• the primary light source is installed at a central location and this is optically coupled to the phosphor by means of light-conducting devices, such as light-conducting fibers.
• the lighting requirements adapted lights can only be realized consisting of one or different phosphors, which can be arranged to form a luminescent screen, and a light guide, which is coupled to the primary light source realize.
• a strong primary light source at a convenient location for the electrical installation and to install without further electrical wiring, but only by laying fiber optics at any location lights of phosphors, which are coupled to the light guide.
• a lighting unit in particular for the backlight of display devices, characterized in that it contains at least one light source according to the invention, and a display device, in particular liquid crystal display device (LC display), with a backlight, characterized in that it contains at least one illumination unit according to the invention.
• a display device in particular liquid crystal display device (LC display)
• LC display liquid crystal display device
• the phosphors can also be converted into any external forms, such as spherical particles, platelets and structured materials and ceramics. According to the invention, these forms are combined under the term "shaped body.”
• the shaped body is preferably a "phosphor body”.
• Another object of the present invention is thus a molding containing the phosphors of the invention. Production and use of corresponding moldings is familiar to the person skilled in the art from numerous publications.
• Phosphors can also be used in the form of translucent ceramics, since in ceramic luminescence conversion screens the optical path length, ie the thickness of the ceramic layer, can be increased due to the reduced scattering compared to a powder layer.
• Another object of the present invention is therefore a ceramic containing at least one compound of the invention.
• the ceramic can only consist of the compound according to the invention. However, it can also contain matrix materials and / or further phosphors. Suitable matrix materials are, for example, S1O2, Y2O3 or Al2O3.
• the compounds according to the invention have a high photoluminescent quantum efficiency.
• the compounds of the invention have a high chemical stability.
• the phase formation of the samples was checked in each case by means of X-ray diffractometry.
• An X-ray diffractometer Miniflex II from Rigaku with Bragg-Brentano geometry was used for this purpose.
• Reflection spectra were determined with a fluorescence spectrometer from Edinburgh Instruments Ltd. The samples were placed in a BaS0 4 coated Ulbricht sphere and measured. Reflectance spectra were recorded in a range of 250 ... 800 nm. The white standard used was BaS0 4 (Alfa Aesar 99.998%). A 450 W Xe lamp served as the excitation source.
• the excitation spectra and emission spectra were recorded with a fluorescence spectrometer from Edinburgh Instruments Ltd, equipped with a mirror optics for powder samples.
• the excitation source used was a 450 W Xe lamp.
• the dry educt mixture was then calcined at 200 ° C for 8 h in Formiergasatmospreheat (5% H 2 /95% N 2 ).
• the mixture is first dried in air at room temperature and then at 80 ° C in a drying oven.
• the dry educt mixture was then calcined at 1200 ° C for 8 h in Formiergasatmospstone (5% H 2 /95% N 2 ).
• the mixture is first dried in air at room temperature and then at 80 ° C in a drying oven.
• the dry educt mixture was then calcined at 1200 ° C for 8 h in Formiergasatmospstone (5% H 2 /95% N 2 ).
• Example 5 Representation of Bao > 99Euo, oiCai, 5oSr 0> 4o no ; ioSi 3 0 9
• Bao , 99euo, oiCai, 5oSro, 4 oMno, ioSi 3 O9 are 2.3444 g (1.88 mmol) BaCO 3 , 0.7086 g (4.80 mmol) SrC0 3 , 0.0211 g (0.06 mmol ) Eu 2 O 3 , 1, 8016 g (18.00 mmol) CaCO 3 , 0.2148 g (1.20 mmol) MnC 2 O 4 -2H 2 O, 2.1630 g (36.00 mmol) SiO 2 and 0.0560 g (0.9051 mmol) of H 3 B0 3 in an agate mortar in acetone.
• the mixture is first dried in air at room temperature and then at 80 ° C in a drying oven.
• the dry educt mixture is then calcined at 1200 ° C for 8 h in Formiergasatmospstone (5% H 2 /95% N 2 ).
• Example 6 Representation of Bao ⁇ Euo.oiCai.so go ⁇ oMno.ioSiaOg
• Ba 0 , 99euo, oiCai, 5oMgo, 4 oMno, ioSi 3 0 9 are 2.3444 g (1.88 mmol) BaC0 3 , 0.4662 g (0.96 mmol) 4MgC0 3 » Mg (OH) 2 « 5H 2 0, 0.0211 g (0.06 mmol) Eu 2 0 3, 1, 8016 g (18.00 mmol) of CaC0 3, 0.2148 g (1, 20 mmol)
• Example 7 Production of a pc-LED using
• the near-UV semiconductor LEDs used in this example for LED characterization have an emission wavelength of 395 nm and are operated at 350 mA current.
• the light-technical characterization of the LED is carried out with a spectrometer from the company Instrument Systems - spectrometer CAS 140 and an associated integrating sphere ISP 250.
• the LED is characterized by determining the wavelength-dependent spectral power density. The spectrum thus obtained of the light emitted by the LED is used to calculate the color point coordinates CIE x and y.
• Example 8 Production of a pc-LED using
• Bao.TgSro.aoEuo.oiCa-i.goMno.ioSiaOg are weighed, mixed with 4 g of an optically transparent silicone and then in a
• the resulting silicone-phosphor mixture is applied by means of an automatic dispenser on the chip of a near-UV semiconductor LED and cured with heat.
• the near-UV semiconductor LEDs used in this example for LED characterization have an emission wavelength of 395 nm and are operated at 350 mA current.
• the light-technical characterization of the LED is carried out with a spectrometer from the company Instrument Systems - spectrometer CAS 140 and an associated integrating sphere ISP 250.
• the LED is characterized by determining the wavelength-dependent spectral power density.
• the spectrum thus obtained of the light emitted by the LED is used to calculate the color point coordinates CIE x and y.
• Bao , ggEuo , oiCai i5 oSro, 4 oMno, ioSi 3 0g are weighed, mixed with 4 g of an optically transparent silicone and then in a
• the resulting silicone-phosphor mixture is applied by means of an automatic dispenser on the chip of a near-UV semiconductor LED and cured with heat.
• the near-UV semiconductor LEDs used in this example for LED characterization have an emission wavelength of 395 nm and are operated at 350 mA current.
• the light-technical characterization of the LED is carried out with a spectrometer from the company Instrument Systems - spectrometer CAS 140 and an associated integrating sphere ISP 250.
• the LED is characterized by determining the wavelength-dependent spectral power density.
• the spectrum thus obtained of the light emitted by the LED is used to calculate the color point coordinates CIE x and y.
• Figure 1 powder X-ray diffractogram of Bao, ggEu 0, oiCai , 9oMno , ioSi 3 09 (top) and the reference card PDF-4 + (ICDD) 04-009-3303 of
• FIG. 5 shows powder diffractogram of Bao, g5Euo, o5Cai, goMn 0, IOSI Og 3 (above) and the reference map PDF-4 + (ICDD) 04-009-3303 Baca 2 Si 3 O 9 (below).
• FIG. 6 Reflection spectrum of Ba 0, 95Euo, o5Cai, 9 oMno , ioSi 3 0 9 .
• FIG. 9 Powder X-ray diffractogram of Bao, goEuo , ioCai , goMnO , ioSi 3 Og (top) and reference card PDF-4 + (ICDD) 04-009-3303 of FIG
• FIG. 11 Excitation spectrum of Bao, 9oEuo, ioCa i90 Mno , ioSi 3 Og
• FIG. 13 powder X-ray diffractogram of FIG
• FIG. 15 powder X-ray diffractogram of FIG
• Bao.ggEuo.oiCaLsoSro ⁇ oMno.ioSisOg (above) and the reference card 04-009- 3303 from BaCaSi 3 0 9 (below).
• FIG. 17 powder X-ray diffractogram of FIG.
• FIG. 19 Spectrum of the phosphor-converted LED described in Example 4.
• FIG. 20 Spectrum of the phosphor-converted LED described in Example 5.
• FIG. 21 Spectrum of the phosphor-converted LED described in Example 6.

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• 2014
  • 2014-04-30 WO PCT/EP2014/001162 patent/WO2014187530A1/de not_active Ceased
  • 2014-04-30 CN CN201480029157.5A patent/CN105264043B/zh not_active Expired - Fee Related
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