WO2014153706A1 - Compositions transparentes comprenant un organogélateur non polymère - Google Patents

Compositions transparentes comprenant un organogélateur non polymère Download PDF

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Publication number
WO2014153706A1
WO2014153706A1 PCT/CN2013/073138 CN2013073138W WO2014153706A1 WO 2014153706 A1 WO2014153706 A1 WO 2014153706A1 CN 2013073138 W CN2013073138 W CN 2013073138W WO 2014153706 A1 WO2014153706 A1 WO 2014153706A1
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WO
WIPO (PCT)
Prior art keywords
composition
oil
ester
dextrin
fatty acid
Prior art date
Application number
PCT/CN2013/073138
Other languages
English (en)
Inventor
Zhen Xu
Manlian HUANG
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Priority to PCT/CN2013/073138 priority Critical patent/WO2014153706A1/fr
Priority to PCT/CN2014/073858 priority patent/WO2014154113A1/fr
Priority to CN201480018449.9A priority patent/CN105050574B/zh
Publication of WO2014153706A1 publication Critical patent/WO2014153706A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/001—Preparations for care of the lips
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers

Definitions

  • the present invention relates, in general, to a transparent composition for application onto a targeted substrate. More particularly, the present invention relates to a transparent composition capable of forming a gel structure, and which has a good pay-off, good stability, and shiny effect, particularly with respect to variations in temperature, and does not require the use of amide or ester- terminated polyamide as a structuring agent.
  • Conventional structured compositions typically employ various types of waxes as structuring agents in order to form user-friendly products having good pay-off (a term used to describe both the amount of product applied onto a target substrate, as well as, the way the product distributes onto the substrate), and stability properties, particularly with respect to temperature stability.
  • the problem with wax-based stick compositions is that they possess an undesirable waxy feel and inherently reduce the shine of any shine-imparting ingredients present in the stick composition. And moreover, the products with wax is not transparent.
  • compositions that have a good balance between stability and usability properties such as pay-off and spreadability, while keeping a comfort feeling during application onto a target substrate.
  • the present invention relates to a transparent composition
  • a transparent composition comprising: a) at least one non polymeric organogelator of N-acyl glutamic acid diamide having a straight or branched chain alkyl group; b) at least one ester of dextrin and a fatty acid, if needed; and c) at least one non-volatile oil phase, comprising at least one apolar oil, and at least one polar oil.
  • composition according to the present invention has the effect that it is stable under a wide range of temperatures. It has excellent pay-off effect and spreadability effect onto a target substrate during application.
  • the present invention also relates to a method of preparation of such a composition comprising the steps of: mixing the optional at least one ester of dextrin and a fatty acid in part of at least one oil phase comprising at least one apolar and at least one polar oil, heating the mixture to 50-125 ° C under agitation, until the mixture is homogeneous; mixing at least one non polymeric organogelator of N-acyl glutamic acid diamide having a straight or branched chain alkyl group in part of at least one oil phase comprising at least one at least one polar oil under the temperature of less than 150 ° C until the mixture is transparent and homogeneous; mixing the two mixtures until homogenization; adding to the mixture preferably frangrance.
  • Another object of the invention is relating to a method for treating the keratin materials, preferably the skin and/or the lip, comprising the step of applying to the keratin material the composition previously defined.
  • the transparent compositions when they are placed 0.01 m in front of a black line 2 mm thick in diameter drawn on a sheet of white paper, allow this line to be seen; in contrast, an opaque composition, i.e. a non-transparent composition, does not allow the line to be seen.
  • the term "transparent composition” can be understood as a composition which transmits at least 40% of light at a wavelength of 750 nm without scattering it, i.e. a composition in which the scattering angle of the light is less than 5° and is better still about 0°.
  • the transparent composition may transmit at least 50%, especially at least 60% and especially at least 70% of light at a wavelength of 750 nm.
  • the transmission measurement is made with a Cary 300 Scan UV-visible spectrophotometer from the company Varian, according to the following protocol:
  • composition is poured into a square-sided spectrophotometer cuvette with a side length of 10 mm;
  • the sample of the composition is then maintained in a thermostatically-regulated chamber at 20°C for 24 hours;
  • the light transmitted through the sample of the composition is then measured on the spectrophotometer by scanning wavelengths ranging from 700 nm to 800 nm, the measurement being made in transmission mode;
  • the percentage of light transmitted through the sample of the composition at a wavelength of 750 nm is then determined.
  • the "keratin material” according to the present invention is the skin.
  • skin we intend all the body skin, including the scalp.
  • the keratin material is the lip.
  • solid composition means the form of the composition at 20°C, and in particular the term “solid” means a composition whose hardness at 20°C and at atmospheric pressure (760 mmHg) is greater than or equal to 30 Nm "1 when it is measured according to the protocol described below.
  • the hardness of a solid composition is measured according to the following protocol.
  • composition whose hardness is to be determined is stored at 20°C for 24 hours before measuring the hardness.
  • the hardness may be measured at 20°C via the "cheese wire” method, which consists in transversely cutting a wand of product, which is preferably a circular cylinder, by means of a rigid tungsten wire 250 ⁇ in diameter, by moving the wire relative to the stick at a speed of 100 mm/minute.
  • the hardness of the samples of compositions of the invention is measured using a DFGS2 tensile testing machine from the company Indelco-Chatillon.
  • the measurement is repeated three times and then averaged.
  • L is equal to the diameter (in metres).
  • the stick is stored for 24 hours at this new temperature before the measurement.
  • anhydrous composition means a composition containing less than 2% and preferably less than 0.5% by weight of water relative to the total weight of the composition.
  • such small amounts of water may be provided by ingredients of the composition that contain it in residual amount, but are not deliberately provided.
  • the transparent composition according to the invention comprises a) at least one non polymeric organogelator of N-acyl glutamic acid diamide having a straight or branched chain alkyl group; b) at least one ester of dextrin and a fatty acid, if needed; c) at least one non- volatile oil phase, comprising at least one apolar oil and at least one polar oil.
  • the composition is free of amide or ester-terminated polyamide of formula (I)
  • X represents -N(R 1 ) 2 group or -ORi group, wherein represents C 8 -2o linear chain or branched chain alkyl group which may be same or different from each other, R 2 represents a dimer acid residue, R 3 represents an ethylenediamine residue, n represents an interger from 2 to 4.
  • the composition according to the invention is solid.
  • the composition according to the invention preferably has hardness at 20°C and at atmospheric pressure of greater than or equal to 40 Nm "1 and preferably greater than 50 Nm "1 (measured by the protocol described before).
  • the composition according to the invention especially has a hardness at 20°C of less than 500 Nm "1 , especially less than 400 Nm "1 and preferably less than 300 Nm "1 (measured by the protocol described before).
  • the composition according to the invention especially has hardness at 20°C of from 40 Nm "1 to 200 Nm "1 .
  • composition according to the invention is anhydrous.
  • Organogelator
  • the composition according to the invention comprises at least one non polymeric organogelator, being selected from N-acyl glutamic acid diamide (or dialkyl N- acylglutamide) having a straight or branched chain alkyl group.
  • An "organogelator” is defined herein to include a non-polymeric organic compound whose molecules may be capable of establishing, between themselves, at least one physical interaction leading to self-aggregation of the molecules with formation of a three-dimensional macromolecular network that may be responsible for the gelation of the liquid fatty phase.
  • gelation means structuring or, more generally, thickening of the medium, which may lead according to the invention to a fluid to pasty or even solid consistency.
  • Non polymeric organogelators used in the composition according to the invention are selected from (C 2 -C 6 ) dialkyl N-acylglutamides in which the acyl group comprises a linear C 8 to C 22 alkyl chain, ,, from (C 2 -C 6 ) dialkyl N-acylglutamides in which the acyl group comprises a branched C 8 to C 22 alkyl chain, or a micture thereof.
  • the non polymeric organogelator is selcted from lauroylglutamic acid dibutylamide (or dibutyl lauroyl glutamide), N-2-ethylhexanoyl glutamic acid dibutylamide (or dibutyl ethylhexanoyi glutamide) or a mixture thereof.
  • Lauroylglutamic acid dibutylamide is for instance sold by the company Ajinomoto under the name GP-1 , of INCI name: Dibutyl Lauroyl Glutamide, and N-2-ethylhexanoylglutamic acid dibutylamide is for instance sold by the company Ajinomoto under the name EB-21 , of INCI name: Dibutyl Ethylhexanoyi Glutamide.
  • GP-1 of INCI name: Dibutyl Lauroyl Glutamide
  • N-2-ethylhexanoylglutamic acid dibutylamide is for instance sold by the company Ajinomoto under the name EB-21 , of INCI name: Dibutyl Ethylhexanoyi Glutamide.
  • EB-21 of INCI name: Dibutyl Ethylhexanoyi Glutamide
  • the N-acyl glutamic acid diamide with a linear alkyl chain is used in a content ranging from 0.1 % to 10%, preferably 0.5% to 5% and more preferably 1.0% to 3.0% by weight relative to the total weight of the composition.
  • N-acyl glutamic acid diamide with a branched alkyl chain is used in an amount ranging from 0.1 % to 10%, preferably 0.5% to 7% and more preferably 1.0% to 3.0% by weight relative to the total weight of the composition.
  • the composition further comprises at least one ester of dextrin if needed, preferably an ester of dextrin and a fatty acid, saturated or unsaturated, linear or branched, preferably a C 12 to C 24 fatty acid.
  • the dextrin ester is an ester of dextrine and a Ci 4 -Ci 8 fatty acid. More preferably, the dextrin ester is Dextrin Myristate, for example such as those
  • a composition according to the invention may comprise a content of dextrin ester ranging from 0.1 % to 15% by weight and preferably from 1 % to 5% by weight, if needed, relative to the total weight of the composition.
  • Non-volatile oil phase a content of dextrin ester ranging from 0.1 % to 15% by weight and preferably from 1 % to 5% by weight, if needed, relative to the total weight of the composition.
  • composition according to the invention comprises at least one non-volatile oil phase.
  • oil means any fatty substance that is in liquid form at room temperature (20-25°C) and at atmospheric pressure.
  • non-volatile oil means oil that remains on the skin or the keratin fibre at room temperature and atmospheric pressure. More specifically, a non-volatile oil has an evaporation rate strictly less than 0.01 mg/cm 2 /min.
  • the non-volatile oil phase comprises oils with high refractive index Cf about 1.48, preferably about 1.48+/-0.01. It has to be noted that the refractive index mentioned above is a final refractive index of the oil phase. There is no limitation on the refractive index of each oil in the oil phase.
  • the oils chosen to be present in the oil phase of the current invention shall reach the condition that the refractive index of the oil phase is about 1.48, preferably about 1.48+/-0.01.
  • the non-volatile oil phase comprises at least one apolar oil, preferably being a hydrocarbon-based apolar oil.
  • apolar oil means an oil whose solubility parameter at 25°C, 5a, is equal to 0 (J/cm3)1/2.
  • solubility parameters in the Hansen three-dimensional solubility space are described in the article by CM. Hansen: "The three dimensional solubility parameters", J. Paint Technol. 39, 105 (1967).
  • hydrocarbon-based oil means an oil formed essentially from, or even constituted by, carbon and hydrogen atoms, and optionally oxygen and nitrogen atoms, and not containing any silicon or fluorine atoms.
  • the non volatile apolar oils are chosen from non volatile apolar hydrocarbon-based oils free of oxygen, nitrogen atoms.
  • the viscosity of at least one apolar oil is preferably at least 200 cSt under 100°C. More preferably, the viscosity of at least one apolar of the present invention is at least 2000 cSt under 100°C, more preferably at least 5000 cSt under 100°C.
  • the nonvolatile apolar hydrocarbon-based oil may be chosen from linear or branched hydrocarbons of mineral or synthetic origin, such as:
  • the nonvolatile apolar hydrocarbon-based oil is polybutene.
  • composition according to the invention comprises from 5% to 80%, preferably from 7% to 50% and more preferably from 10% to 30% by weight of apolar oil relative to the total weight of the composition.
  • Non volatile polar oils may also comprise at least one non volatile polar oil.
  • the composition does not comprise any nonvolatile silicone oil(s).
  • silicone oil means oil containing at least one silicon atom, and especially containing Si-0 groups.
  • fluoro oil means oil containing at least one fluorine atom.
  • said nonvolatile polar oil is hydrocarbon-based oil.
  • polar oil means an oil whose solubility parameter at 25°C, 5a, is other than 0 (J/cm3)1/2.
  • oils may be of vegetable, mineral or synthetic origin.
  • hydrocarbon-based oil means oil formed essentially from, or even constituted by, carbon and hydrogen atoms, and optionally oxygen and nitrogen atoms, and not containing any silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and/or amide groups.
  • nonvolatile polar hydrocarbon oil may be chosen from the list of oils below, and mixtures thereof:
  • hydrocarbon-based plant oils such as liquid triglycerides of fatty acids containing from 4 to 10 carbon atoms, for instance heptanoic or octanoic acid triglycerides, jojoba oil, sesame oil (820.6 g/mol);
  • the carboxylic acid residue contains from 2 to 30 carbon atoms
  • the alcohol residue represents a hydrocarbon-based chain containing from 1 to 30 carbon atoms, such as isononyl isononanoate, isotridecyl isononanoate, diisostearyl malate, oleyl erucate or 2-octyldodecyl neopentanoate; isopropyl myristate;
  • Acid/Butanediol Copolymer or copolymers of polyols and of diacid dimers, and esters thereof, such as Hailuscent ISDA,
  • the said alcohols are branched; mentions maybe made of octyldodecanol such as the product with the trade name Eutanol G ® sold by the company BASF;
  • C 12 -C 2 2 fatty acids such as oleic acid, linoleic acid and linolenic acid, and mixtures thereof;
  • dialkyl carbonates the two alkyl chains possibly being identical or different, such as dicaprylyl carbonate sold under the name Cetiol CC® by Cognis; and
  • esters and polyesters of a diol dimer and of a monocarboxylic or dicarboxylic acid such as esters of a diol dimer and of a fatty acid and esters of a diol dimer and of a dicarboxylic acid dimer; mention may be made especially of the esters of dilinoleic diacids and of dilinoleyl diol dimers sold by the company Nippon Fine Chemical under the trade names Lusplan DD-DA5® and DD-DA7®, and diisostearyl malate sold by the company Lubrizol under the trade name SchercemolTM Dism Ester;
  • esters of a diol dimer and of a monocarboxylic acid may be obtained from a monocarboxylic acid containing from 4 to 34 carbon atoms and especially from 10 to 32 carbon atoms, which acids are linear or branched, and saturated or unsaturated.
  • esters of diol dimer and of dicarboxylic acid may be obtained from a dicarboxylic acid dimer derived in particular from the dimerization of an unsaturated fatty acid especially of C 8 to C34, especially C 12 to C22, in particular C 16 to C 20 and more particularly C 18 .
  • the dicarboxylic acid dimer from which the diol dimer to be esterified is also derived.
  • esters of a diol dimer and of a carboxylic acid may be obtained from a diol dimer produced by catalytic hydrogenation of a dicarboxylic acid dimer as described previously, for example hydrogenated dilinoleic diacid.
  • the composition according to the invention comprises at least one polar nonvolatile oil chosen from hydrocarbon-based polar oils, preferably chosen from ester oils and alcohol oils, and mixtures thereof.
  • the polar nonvolatile oil is octyldodecanol.
  • the hydrocarbon-based nonvolatile polar oil is present in a total content of between 1 % and 80%, preferably between 5% and 50%, more preferably between 10% and 30% relative to the total weight of the composition.
  • the nonvolatile oil may also be a fluoro oil.
  • fluoro oil means an oil comprising at least one fluorine atom.
  • perfluoro compounds means compounds in which all the hydrogen atoms have been replaced with fluorine atoms.
  • the fluoro oil according to the invention is chosen from perfluoro oils.
  • perfluoro oils that may be used in the invention, mention may be made of perfluorodecalins and perfluoroperhydrophenanthrenes.
  • the fluoro oil is chosen from
  • perfluoroperhydrophenanthrenes and especially the Fiflow® products sold by the company Creations Couliv.
  • use may be made of the fluoro oil for which the INCI name is Perfluoroperhydrophenanthrene, sold under the reference Fiflow 220 by the company F2 Chemicals.
  • the above composition is anhydrous.
  • composition of the above invention is solid.
  • composition according to the present invention may be manufactured by the known processes that are generally used in cosmetics or dermatology. It may be manufactured by the process which comprises the steps of: mixing the optional at least one ester of dextrin and a fatty acid in part of at least one oil phase comprising at least one apolar and at least one polar oil, heating the mixture to 50-125 ° C under agitation, until the mixture is homogeneous; mixing at least one non polymeric organogelator of N-acyl glutamic acid diamide having a straight or branched chain alkyl group in part of at least one oil phase comprising at least one at least one polar oil under the temperature of less than 150 ° C until the mixture is transparent and homogeneous; mixing the two mixtures until homogenization; adding to the mixture preferably frangrance.
  • Another object of the invention is relating to a method for treating the keratin materials, preferably the skin and/or the lip, comprising the step of applying to the keratin material the composition previously defined.
  • composition of the present invention is suitable to be used as a skin care, make up or cosmetic treatment product. More particularly, the composition of the present invention is in the form of make up product such as lip balm, lip stick, lip gloss, and so on.
  • a cosmetic composition according to the invention further comprises at least one compound chosen from, hydrophilic solvents, lipophilic solvents, oils, and mixtures thereof.
  • a cosmetic composition according to the invention may also comprise any additive usually used in the field under consideration, chosen, for example, from gums, anionic, cationic, amphoteric or nonionic surfactants, silicone surfactants, resins, thickening agents, structuring agents such as waxes, dispersants, antioxidants, essential oils, preserving agents, fragrances, neutralizers, antiseptics, UV-screening agents, cosmetic active agents, such as vitamins, moisturizers, emollients or collagen-protecting agents, colorants, and mixtures thereof.
  • any additive usually used in the field under consideration chosen, for example, from gums, anionic, cationic, amphoteric or nonionic surfactants, silicone surfactants, resins, thickening agents, structuring agents such as waxes, dispersants, antioxidants, essential oils, preserving agents, fragrances, neutralizers, antiseptics, UV-screening agents, cosmetic active agents, such as vitamins, moisturizers, emollients or collagen-protecting agents, color
  • the current invention comprises less than 1 %, preferably less than 0.1 % of pigments, relative to the total weight of the composition.
  • Octyldodecanol (Eutanol 30 30 30 30 30 30 30 30 30 30 30 30 30 G ® from BASF)
  • the formulation examples are prepared following the steps of: mixing dextrin myristate or dextrin palmitate respectively, at room temperature in part of tridecyl trimelitate and 10% of octyldocdecanol until homogenization under agitation; heating the mixture to 1 15°C under agitation until the mixture is transparent; mixing dibutyl lauroyl glutamide or dibutyl ethylhexanoyl glutamide respectively, in 20% of octyldocecanol at 150°C under the mixture is transparent; mixing the two mixtures together until homogenization; adding to the mixture the fragrance. Evaluation examples
  • Hardness, transparency, spreadability, comfort of use and instant moisturization are evaluated by a group of 6 panelists.
  • Invention examples 1 , 2 and 3, and comparative examples 1 and 2 are applied on the lips of the 6 panelists and scores of comfort are given to each of the examples.
  • Transparency is evaluated by placing 0.01 m of the examples in front of a black line 2 mm thick in diameter drawn on a sheet of white paper, allow this line to be seen; in contrast, an opaque composition, i.e. a non-transparent composition, does not allow the line to be seen.
  • Pay-off properties are evaluated by 5 experts by the following steps: repeatly apply the product 3 times on the same area of the forearm using the same force; weigh the weight loss of the product; measure the size of the area on the forearm where the product is applied; calculate the weight loss per square centimeter.
  • composition according to the present invention overcomes the technical issues existing in the prior art, and provides a stable, shiny, good pay-off, spreadability, instant moisturization, and comfort feel composition.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition transparente comprenant : a) au moins un organogélateur non polymère de diamide d'acide N-acryl-glutamique ayant un groupe alkyle à chaîne linéaire ou ramifiée ; b) au moins un ester de dextrine et un acide gras, si nécessaire ; et c) au moins une phase huileuse non volatile, comprenant au moins une huile apolaire, et au moins une huile polaire.
PCT/CN2013/073138 2013-03-25 2013-03-25 Compositions transparentes comprenant un organogélateur non polymère WO2014153706A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
PCT/CN2013/073138 WO2014153706A1 (fr) 2013-03-25 2013-03-25 Compositions transparentes comprenant un organogélateur non polymère
PCT/CN2014/073858 WO2014154113A1 (fr) 2013-03-25 2014-03-21 Composition transparente comprenant un organogélifiant non polymère
CN201480018449.9A CN105050574B (zh) 2013-03-25 2014-03-21 包含非聚合物型有机凝胶剂的透明组合物

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Application Number Priority Date Filing Date Title
PCT/CN2013/073138 WO2014153706A1 (fr) 2013-03-25 2013-03-25 Compositions transparentes comprenant un organogélateur non polymère

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WO2014153706A1 true WO2014153706A1 (fr) 2014-10-02

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PCT/CN2014/073858 WO2014154113A1 (fr) 2013-03-25 2014-03-21 Composition transparente comprenant un organogélifiant non polymère

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2022100296A (ja) * 2020-12-23 2022-07-05 コスメッカ コリア カンパニー リミテッド 高温安定性と使用感が向上した固形状化粧料組成物及びその製造方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110891545B (zh) * 2017-05-31 2022-07-01 莱雅公司 在脂肪相中包含珍珠的皮克林乳液组合物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1074246A1 (fr) * 1999-07-23 2001-02-07 Unilever Plc Composition cosmétique contenant un agent structurant
US20050191327A1 (en) * 2003-12-24 2005-09-01 Wei Yu Cosmetic composition comprising two different hetero polymers and method of using same
US20070196306A1 (en) * 2005-07-22 2007-08-23 Nathalie Jager Lezer Process for coating eyelashes
US20130004446A1 (en) * 2010-03-10 2013-01-03 L'oreal Long-wearing non-aqueous structured color cosmetic

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2984140B1 (fr) * 2011-12-20 2014-06-20 Oreal Composition comprenant une phase grasse, un agent structurant, un compose et/ou un actif hydrophile

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1074246A1 (fr) * 1999-07-23 2001-02-07 Unilever Plc Composition cosmétique contenant un agent structurant
US20050191327A1 (en) * 2003-12-24 2005-09-01 Wei Yu Cosmetic composition comprising two different hetero polymers and method of using same
US20070196306A1 (en) * 2005-07-22 2007-08-23 Nathalie Jager Lezer Process for coating eyelashes
US20130004446A1 (en) * 2010-03-10 2013-01-03 L'oreal Long-wearing non-aqueous structured color cosmetic

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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JP7500534B2 (ja) 2020-12-23 2024-06-17 コスメッカ コリア カンパニー リミテッド 高温安定性と使用感が向上した固形状化粧料組成物及びその製造方法

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